Vacuum Deposition (includes Molecular Beam Epitaxy Patents (Class 148/DIG169)
  • Patent number: 4755484
    Abstract: A semiconductor contact system controls the boundary recombination velocity and optimizes the semiconductor transport phenomena and includes a microcrystalline layer of doped semiconductor microcrystals surrounded by a semiconductor oxide. The microcrystalline layer is acceptor and oxygen doped to provide unipolar hole transport and donor and oxygen doped to provided unipolar electron transport. The oxygen doping is implanted several atomic layers into the semiconductor to form a gradient between the semiconductor and microcrystalline layer to preserve the semiconductor monocrystalline lattice. The thickness of the microcrystalline film is adjusted to be thick enough to control the effective chemostatic potential terminating the semiconductor and thin enough to enhance the series microcrystalline film resistance.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: July 5, 1988
    Assignee: Texas Instruments Incorporated
    Inventor: Patrick A. Curran
  • Patent number: 4745088
    Abstract: The vapor phase growth on semiconductor wafers is carried out by an apparatus in which a multiplicity of semiconductor wafers are held by a holder so that the semiconductor wafers lie one over another in a vertical direction, and are rotated together with the holder, the holder is placed in a heater disposed in a reaction vessel, a raw material gas supply nozzle and a raw material gas exhaust nozzle are provided within the heater so that the semiconductor wafers are interposed between the gas supply nozzle and the gas discharge nozzle, and the gas supply nozzle and the gas discharge nozzle have gas supply holes and gas discharge holes, respectively, so that a raw material gas can flow on each semiconductor wafer in horizontal directions. When the temperature of the heater is raised by a heating source to heat the semiconductor wafers, the raw material gas is supplied from the gas supply holes to each semiconductor wafer, and thus a uniform layer is grown on each semiconductor wafer from the raw material gas.
    Type: Grant
    Filed: February 19, 1986
    Date of Patent: May 17, 1988
    Assignees: Hitachi, Ltd., Kokusai Elect. Co. Ltd.
    Inventors: Yosuke Inoue, Takaya Suzuki, Masahiro Okamura, Noboru Akiyama, Masato Fujita, Hiroo Tochikubo, Shinya Iida
  • Patent number: 4689093
    Abstract: Process for preparing a photoelectromotive force member by forming a photoelectric conversion layer on a substrate by: (a) generating an active species by the action of microwave energy on a substance in a space leading to a film forming space containing a substrate; (b) generating a precursor by the action of microwave energy on a substance in a space situated within the space for generating the active species; and (c) introducing the resulting active species and precursor into the film forming space to chemically react them and to form the photoelectric conversion layer.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: August 25, 1987
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shunichi Ishihara, Keishi Saito, Shunri Oda, Isamu Shimizu
  • Patent number: 4664063
    Abstract: An apparatus for growing a compound semiconductor on a substrate by molecular beam epitaxy, includes a growth chamber, and Knudsen cells, disposed in the growth chamber, for generating molecular beams of source materials for the compound semiconductor independently. An ion gauge is disposed in the growth chamber, for measuring intensities of the molecular beams. A heater disposed in the growth chamber heats the substrate to a growth temperature of the compound semiconductor. A heating element heats the heater and the ion gauge to evaporate contamination materials including the source materials deposited on said substrate heating means and said measuring means after the growth of the compound semiconductor. An evacuater is provided to evacuate the growth chamber to a vacuum.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: May 12, 1987
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yasuo Ashizawa, Naoharu Sugiyama
  • Patent number: 4659401
    Abstract: A method and apparatus for forming epitaxial thin film layers on substrates having abrupt transitions between layers of different composition or layers of different or like composition with different degrees of doping included therein. Gaseous reactants containing the desired elements to be included in the first film layer are injected into a CVD reaction chamber containing a substrate. The substrate is heated to a temperature high enough to obtain an epitaxial deposit, but low enough so as not to cause decomposition of the reactants. Once the gaseous reactant flows reach steady-state, an electric discharge or plasma is created in the gases to initiate the decomposition reaction and obtain a deposit. In this way, no transient effects are present. Once the deposit has attained sufficient thickness, the electric discharge is turned off to abruptly terminate deposition.
    Type: Grant
    Filed: June 10, 1985
    Date of Patent: April 21, 1987
    Assignee: Massachusetts Institute of Technology
    Inventors: L. Rafael Reif, Clifton G. Fonstad, Jr.
  • Patent number: 4640720
    Abstract: A method of manufacturing a semiconductor device, in which method a plurality of epitaxial layers are deposited by molecular beam epitaxy. A significant problem in such a method is the variation in the flux emitted by an effusion cell after the shutter associated with that cell has been opened, this resulting in undesired variations in the composition in the thickness direction of the epitaxial layer being grown. In a method according to the invention, when the shutter of a molecular beam source is opened, the rate of input of heat to that source is increased by a predetermined value so that the temperature of that source does not change substantially as a result of the opening of that shutter, and when the shutter is closed the rate of input of heat to that source is reduced by the predetermined value.
    Type: Grant
    Filed: April 22, 1985
    Date of Patent: February 3, 1987
    Assignee: U.S. Philips Corporation
    Inventor: Charles T. Foxon
  • Patent number: 4637129
    Abstract: A method of device fabrication using selective area regrowth Group III-V compound semiconductors with tungsten patterning is described.
    Type: Grant
    Filed: July 30, 1984
    Date of Patent: January 20, 1987
    Assignee: AT&T Bell Laboratories
    Inventors: Gustav E. Derkits, Jr., James P. Harbison
  • Patent number: 4636268
    Abstract: Epitaxial layers of semiconductor materials such as, e.g., III-V and II-VI materials are deposited on a substrate under high-vacuum conditions. Molecules of a compound of a constituent of such material travel essentially line-of-sight towards the substrate admixed to a carrier gas such as, e.g., hydrogen. For III-V layers the use of compounds, such as, e.g., trimethyl- and triethylgallium, trimethyl- and triethylindium, triethylphosphine, and trimethylarsine is advantageous and economical in the manufacture of electronic and opto-electronic devices.
    Type: Grant
    Filed: November 30, 1984
    Date of Patent: January 13, 1987
    Assignee: AT&T Bell Laboratories
    Inventor: Won-Tien Tsang
  • Patent number: 4622083
    Abstract: A molecular beam epitaxial growth process, for growth of III-V compounds, wherein a substrate is heated approximately to growth temperature before the group III cell is fully heated. That is, for example, to grow gallium arsenide, the arsenic cell would be heated, the arsenic cell's shutter opened, and the substrate heated up to growth temperature (e.g. 600 C), before the gallium cell is heated up. After the gallium cell is heated up, its shutter is opened, and epitaxial growth proceeds.
    Type: Grant
    Filed: March 11, 1985
    Date of Patent: November 11, 1986
    Assignee: Texas Instruments Incorporated
    Inventor: Hung-Dah Shih
  • Patent number: 4597159
    Abstract: A semiconductor device is manufactured by forming a first insulating film on a surface of a semiconductor substrate of a first conductivity type, and a first nonmonocrystalline silicon film is formed on the first insulating film. A second insulating film is deposited on the first nonmonocrystalline silicon film by CVD, sputtering or molecular beam method. An impurity is then ion-implanted in the first nonmonocrystalline silicon film through the second insulating film. The second insulating film is then removed to expose the surface of the first nonmonocrystalline silicon film doped with the impurity, and a thermal oxide film is formed on the exposed portion of the first nonmonocrystalline silicon film. Subsequently, a second nonmonocrystalline silicon film is formed on the thermal oxide film, and a third insulating film is formed on the second nonmonocrystalline silicon film.
    Type: Grant
    Filed: February 27, 1985
    Date of Patent: July 1, 1986
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Toshiro Usami, Yuuichi Mikata, Kazuyoshi Shinada
  • Patent number: 4578127
    Abstract: Single GaAs quantum well or single GaAs active layer or single reverse interface structures with Al.sub.x Ga.sub.1-x As barrier layers have improved qualities when one or more narrow bandgap GaAs getter-smoothing layers, which are thin, are grown and are incorporated in the barrier layer before and in close proximity to the active layer.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: March 25, 1986
    Assignee: AT&T Bell Laboratories
    Inventors: Arthur C. Gossard, Robert C. Miller, Pierre M. Petroff
  • Patent number: 4575924
    Abstract: The present invention teaches a process for fabrication of quantum-well devices, in which the quantum-wells are configured as small islands of GaAs in an AlGaAs matrix. Typically these islands are roughly cubic, with dimensions of about 100 Angstroms per side. To fabricate these, an n- on n+ epitaxial GaAs structure is grown, and then is etched to an e-beam defined patterned twice, and AlGaAs is epitaxially regrown each time. This defines the quantum wells of GaAs in an AlGaAs matrix, and output contacts are then easily formed.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: March 18, 1986
    Assignee: Texas Instruments Incorporated
    Inventors: Mark A. Reed, Robert T. Bate
  • Patent number: 4563807
    Abstract: Semiconductor device, such as bipolar transistor, is made by molecular beam epitaxy, wherein a emitter layer (27) and overriding contact regions (28) of polycrystalline silicon are grown continuously on a silicon substrate (23+26) without breaking high vacuum, thus eliminating the adverse interface of natural oxide film under the polycrystalline silicon layer (28) and the adverse donor-acceptor compensation while attaining a well controlled h.sub.FE and enabling a shallow emitter junction.
    Type: Grant
    Filed: April 4, 1984
    Date of Patent: January 14, 1986
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiroyuki Sakai, Toyoki Takemoto, Kenji Kawakita, Tsutomu Fujita, Atsuko Akiyama
  • Patent number: 4554030
    Abstract: A monocrystalline layer of one semiconductor material is grown onto a surface of a monocrystalline semiconductor body by means of molecular beam epitaxy. During such growth, the semiconductor body is kept at such a low temperature that a non-monocrystalline layer is obtained. The non-monocrystalline layer is then converted by a heat treatment into a monocrystalline form. Accordingly, an abrupt junction between the two semiconductor materials is obtained.
    Type: Grant
    Filed: March 2, 1984
    Date of Patent: November 19, 1985
    Inventors: Jan Haisma, Poul K. Larsen, Tim De Jong, Johannes F. Van der Veen, Willem A. S. Douma, Frans W. Saris
  • Patent number: 4550047
    Abstract: A quantity of silicon serving as a source of the element silicon for use in a molecular beam epitaxial growth apparatus where the silicon is in the form of a monocrystalline wafer with a plurality of electrically parallel filaments separated by slots that pass completely through the wafer, each filament having a length dimension that is greater than the width and height dimensions, joined at a broad contact area at each filament end and where an electric current is passed through the filaments through the broad contact areas.
    Type: Grant
    Filed: June 6, 1983
    Date of Patent: October 29, 1985
    Assignee: International Business Machines Corporation
    Inventors: Thomas N. Jackson, Peter D. Kirchner, George D. Pettit, James J. Rosenberg, Jerry M. Woodall, Steven L. Wright
  • Patent number: 4529455
    Abstract: A molecular beam epitaxy method of growing Ge.sub.x Si.sub.1-x films on silicon substrate is described.
    Type: Grant
    Filed: October 28, 1983
    Date of Patent: July 16, 1985
    Assignee: AT&T Bell Laboratories
    Inventors: John C. Bean, Leonard C. Feldman, Anthony T. Fiory