Ge Germanium Patents (Class 148/DIG58)
  • Patent number: 6110829
    Abstract: An aluminum fill process for sub-0.25 .mu.m technology integrated circuits that has a reflow temperature less than 400.degree. C. that has low alloy resistivity and excellent electromigration characteristics. The aluminum allow is composed of Al-1% Ge-1% Cu.
    Type: Grant
    Filed: October 23, 1997
    Date of Patent: August 29, 2000
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Paul Raymond Besser, Robin W. Cheung, Guarionex Morales
  • Patent number: 5846867
    Abstract: A method of producing a bipolar transistor includes the step of forming an emitter contact layer containing a high concentration of impurity by means of plasma doping or solid-state diffusion without causing diffusion of impurity in a base layer. This makes it possible to realize a thin base layer having a high impurity concentration.The invention also provides a method of producing a semiconductor device including a bipolar transistor and another device element such as a resistor element including a polysilicon layer containing an activated impurity in such a manner that both the bipolar transistor and the device element are disposed on the same single substrate, the method including the steps of: forming a polysilicon layer containing an activated impurity on the surface of a substrate; and then forming a base layer of the bipolar transistor. This method prevents the base layer from being affected by heat treatment on the polysilicon layer.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: December 8, 1998
    Assignee: Sony Corporation
    Inventors: Takayuki Gomi, Hiroaki Ammo
  • Patent number: 5753541
    Abstract: A method for fabricating a silicon-germanium thin film field effect transistor (TFT) with a high carrier mobility and a high on/off ratio. An amorphous silicon layer, an amorphous germanium layer and a gate insulating film are successively layered on an insulating substrate on which a pair of source and drain electrodes are formed. Next, the amorphous silicon layer and the amorphous germanium layer are converted into polycrystalline layers by thermal annealing at a temperature higher than 600.degree. C. or laser annealing. Then, a gate electrode is formed on the gate insulating film.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: May 19, 1998
    Assignee: NEC Corporation
    Inventor: Kousaku Shimizu
  • Patent number: 5693574
    Abstract: A process for the laminar joining of two or more silicon semiconductor slices (wafers) under the effect of pressure and heat, in which a thin layer of a semiconductor-compatible material is applied to at least one of the surfaces to be joined.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: December 2, 1997
    Assignee: Deutsche Aerospace AG
    Inventors: Gunther Schuster, Klaus Panitsch
  • Patent number: 5616515
    Abstract: A resonant tunneling diode (400) made of a germanium quantum well (406) with silicon oxide tunneling barriers (404, 408). The silicon oxide tunneling barriers (404, 408) plus germanium quantum well (406) may be fabricated by oxygen segregation from germanium oxides to silicon oxides.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 1, 1997
    Assignee: Texas Instruments Incorporated
    Inventor: Yasutoshi Okuno
  • Patent number: 5591653
    Abstract: The present invention is directed to a thin film transistor (TFT) structure having a channel region formed of a crystallized SiGe and is to provide a thin film transistor having a large carrier mobility. In this case, a channel region (4) is formed of a crystallized SiGe thin film.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: January 7, 1997
    Assignee: Sony Corporation
    Inventors: Toshiyuki Sameshima, Masaki Hara, Naoki Sano, Dharam Pal Gosain, Setsuo Usui
  • Patent number: 5489550
    Abstract: A germanium-containing compound may be used as an additive to dopant source gas to improve the direct GPD (Gas-Phase Doping) processes. This invention involves a gas-phase doping method for semiconductor wafers, including the steps of providing a semiconductor wafer, and exposing the surface of the wafer to a process medium comprising a dopant gas in order to dope the surface of the wafer, wherein the process medium also comprises a germanium-containing compound gas. Preferably, the process medium also comprises a carrier gas, where the carrier gas is hydrogen. The germanium-containing gas can be germane, digermane, or other suitable germanium-containing compound. The wafer and dopant gas may also be exposed to a plasma source, and the wafer may be heated in a rapid thermal processing reactor. Some advantages over conventional GPD processes include faster desorption of byproducts and incorporation of dopant atoms, shallower junctions, shorter cycle times, and lower processing temperatures.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: February 6, 1996
    Assignee: Texas Instruments Incorporated
    Inventor: Mehrdad M. Moslehi
  • Patent number: 5476813
    Abstract: In a method of manufacturing a bonded semiconductor substrate, a SiGe mixed crystal layer, a silicon layer containing N-type impurities, a SiGe mixed crystal layer containing N-type impurities of high concentration, and a silicon layer containing N-type impurities of high concentration are formed in this order on a top surface of a silicon substrate by an epitaxial growth process to form a first semiconductor substrate. A silicon oxide film is formed on a surface of a silicon substrate to form a second semiconductor substrate. The first and second semiconductor substrates are bonded to each other by heat treatment, with their top surfaces contacting each other. The first semiconductor substrate is etched from the back surface thereof until the SiGe mixed crystal layer is exposed, and the SiGe mixed crystal layer is etched until the silicon layer containing N-type impurities is exposed. This method prevents the thickness of the element forming layer from varying.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: December 19, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Hiroshi Naruse
  • Patent number: 5401674
    Abstract: A method is provided for reducing growth of silicide and the temperatures necessary to produce silicide. Germanium is implanted at a concentration peak density depth below the midline and above the lower surface of a metal layer receiving the implant. Subsequent anneal causes germanide to occupy an area above growing silicide such that consumption of silicon atoms is reduced, and that silicide is formed to a controlled thickness.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: March 28, 1995
    Assignee: Advanced Micro Devices
    Inventors: Mohammed Anjum, Ibrahim Burki, Craig W. Christian
  • Patent number: 5312766
    Abstract: Germanium is used to significantly enhance the drift mobilities of minority carriers in the channels of N-channel and P-channel metal-oxide-semiconductor (MOS) transistors with silicon substrates. Germanium processing is also used to enhance the source/drain contact conductance for MOS devices. Methods are disclosed for forming the germanium-rich interfacial layer utilizing a germanium implant and wet oxidation or growing a silicon-germanium alloy by molecular beam epitaxy.
    Type: Grant
    Filed: February 7, 1992
    Date of Patent: May 17, 1994
    Assignee: National Semiconductor Corporation
    Inventors: Sheldon Aronowitz, Courtney Hart, Court Skinner
  • Patent number: 5296387
    Abstract: Germanium is used to significantly enhance the drift mobilities of minority carriers in the channels of N-channel and P-channel metal-oxide-semiconductor (MOS) transistors with silicon substrates. Germanium processing is also used to enhance the source/drain contact conductance for MOS devices. Methods are disclosed for forming a germanium-rich interfacial layer utilizing a germanium implant and wet oxidation or growing a silicon-germanium alloy by molecular beam epitaxy.
    Type: Grant
    Filed: December 2, 1992
    Date of Patent: March 22, 1994
    Assignee: National Semiconductor Corporation
    Inventors: Sheldon Aronowitz, Courtney Hart
  • Patent number: 5242847
    Abstract: Doped silicon-germanium alloy is selectively deposited on a semiconductor substrate, and the semiconductor substrate is then heated to diffuse at least some of the dopant from the silicon-germanium alloy into the semiconductor substrate to form a doped region at the face of the semiconductor substrate. The doped silicon-germanium alloy acts as a diffusion source for the dopant, so that shallow doped, regions may be formed at the face of the semiconductor substrate without ion implantation. A high performance contact to the doped region is also provided by forming a metal layer on the doped silicon-germanium alloy layer and heating to react at least part of the silicon-germanium alloy layer with at least part of the metal layer to form a layer of germanosilicide alloy over the doped regions. The method of the present invention is particularly suitable for forming shallow source and drain regions for a field effect transistor, and self-aligned source and drain contacts therefor.
    Type: Grant
    Filed: July 27, 1992
    Date of Patent: September 7, 1993
    Assignee: North Carolina State University at Raleigh
    Inventors: Mehmet C. Ozturk, Douglas T. Grider, Mahesh K. Sanganeria, Stanton P. Ashburn
  • Patent number: 5227333
    Abstract: A process for making local interconnection of devices on a semiconductor substrate is disclosed. Contact openings are defined to a plurality of devices on the substrate. A blanket layer of germanium is deposited over the substrate, followed by deposition of a blanket layer of electrically conducting material on top of the germanium layer. The conducting layer is etched first stopping at the germanium layer. Subsequently the germanium layer is etched by a different process, selective to the conductive layer and the device contact. The conducting layer is preferably one of the following materials: polysilicon, silicide, a composite of polysilicon with metal or silicide films.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: July 13, 1993
    Assignee: International Business Machines Corporation
    Inventor: Joseph F. Shepard
  • Patent number: 5205871
    Abstract: A monocrystalline germanium film is grown on a sapphire substrate with a (1102) orientation. The substrate is first pretreated to restructure the (1102) surface plane. Typically, restructuring is accomplished by either an anneal at high temperature or ion bombardment. A monocrystalline germanium layer is grown on the pretreated surface by a vapor deposition process such as molecular beam epitaxy or chemical vapor deposition.
    Type: Grant
    Filed: June 1, 1990
    Date of Patent: April 27, 1993
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: David J. Godbey, Syed B. Qadri
  • Patent number: 5173443
    Abstract: Methods are disclosed for making semiconductor windows which are transparent to light in the infrared range which have good electrical conductivity and are formed of a substrate material (11) having a semiconductor coating (14) having a dopant included therein. The coating is diffused, grown or deposited on one surface of the substrate and is controlled to obtain both low electrical resistivity and high infrared transmissivity. The coating can be formed of the same material as the substrate or can be a different material. Windows having particular thermal properties are formed utilizing zinc selenide and zinc sulfide as the substrate.
    Type: Grant
    Filed: June 27, 1990
    Date of Patent: December 22, 1992
    Assignee: Northrop Corporation
    Inventors: V. Warren Biricik, James M. Rowe, Paul Kraatz, John W. Tully, Wesley J. Thompson, Rudolph W. Modster
  • Patent number: 5137838
    Abstract: A P-type buried layer is described for use with planar, silicon, monolithic, epitaxial, PN junction-isolated transistors of PNP conductivity primarily for use in IC construction. The buried layer includes a high concentration of boron and gallium along with germanium, which is in sufficient concentration to inhibit impurity diffusion in the silicon epitaxial layer. This inhibition effect has been found to be sufficient to cause the combination of boron and gallium to act as slow diffusers. The result is that the performance of arsenic and antimony, in the creation of buried layers for NPN transistors. Thus, the performance of NPN transistors can be matched for PNP transistors. This means that an IC can be fabricated so that more nearly equal performance NPN and PNP transistors can be fabricated simultaneously in a common substrate.
    Type: Grant
    Filed: June 5, 1991
    Date of Patent: August 11, 1992
    Assignee: National Semiconductor Corporation
    Inventors: Amolak Ramde, Sheldon Aronowitz
  • Patent number: 5091338
    Abstract: This invention comprises a Pd layer formed on an n-type GaAs semiconductor crystals, and a Ge layer being formed on the Pd layer, characterized in that the thickness of the Pd layer is between 300 .ANG. and 1500 .ANG. and the thickness of the Ge layer is between 500 .ANG. and 1500 .ANG..In addition, this invention provides an ohmic electrode forming process for compound semiconductor crystals for forming an ohmic electrode on an n-type GaAs semiconductor crystal, comprising a first layer forming step for forming a palladium (pd) layer on a compound semiconductor crystal; a second layer forming step for forming a germanium layer (Ge) on the Pd layer; and an annealing step for annealing the Pd layer and the Ge layer by a rapid thermal annealing treatment.The Pd layer is formed between 300 .ANG. and 1500 .ANG. in the first layer forming step; the Ge layer is between 500 .ANG. and 1500 .ANG.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: February 25, 1992
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Junichi Tsuchimoto, Tooru Yamada, Takaya Miyano
  • Patent number: 5037775
    Abstract: An alternating cyclic (A.C.) method for selectively depositing single element semiconductor materials, on the surface of a substrate without depositing the material on an adjacent mask layer. A gas of a reducible compound of the material and a reducing gas, preferably hydrogen, are simultaneously flowed through a reaction chamber to deposit the material on the substrate surface and to a lesser extent on the mask layer. Then, the flow of reducing gas is interrupted to cause the reducible compound gas to etch the material which forms on the mask layer in a disproportionation reaction. The deposition and etch steps are repeated in an alternating cyclic fashion until the requisite thickness is deposited. The process may take place in a single reaction chamber, using only the reducible compound gas and pulsed flow of the reducing gas.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: August 6, 1991
    Assignee: MCNC
    Inventor: Arnold Reisman
  • Patent number: 4952446
    Abstract: This invention relates to ultra-thin semiconductor films which can be in the submicron range formed from semiconductor materials such as silicon, germanium and gallium arsenide. The films are formed by creating a thin slightly damaged surface on the polished reverse side of a film (e.g., a wafer) of the semiconductor by low dose ion implantation and then etching the semiconductor material on the front side of the film to remove the semiconductor material down to the ion implanted damaged layer. While the implanted ions can be chosen from functionally desirable ions which upon annealing remain in the film to alter the original electrical characteristics, the implanted ions can also be chosen so that upon annealing, the resultant ultra-thin semiconductor film has the same electrical characteristics as the original semiconductor material.The ion implantation changes the etching characteristics of the ion implanted layer.
    Type: Grant
    Filed: December 14, 1988
    Date of Patent: August 28, 1990
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Kevin C. Lee, Charles A. Lee, John Silcox
  • Patent number: 4946735
    Abstract: This invention relates to ultra-thin semiconductor films which can be in the submicron range formed from semiconductor materials such as silicon, germanium and gallium aresenide. The films are formed by creating a thin slightly damaged surface on the polished reverse side of a film (e.g., a wafer) of the semiconductor by low dose ion implantation and then etching the semiconductor material on the front side of the film to remove the semiconductor material down to the ion implanted damaged layer. While the implanted ions can be chosen from functionally desirable ions which upon annealing remain in the film to alter the original electrical characteristics, the implanted ions can also be chosen so that upon annealing, the resultant ultra-thin semiconductor film has the same electrical characteristics as the original semiconductor material.The ion implantation changes the etching characteristics of the ion implanted layer.
    Type: Grant
    Filed: December 14, 1988
    Date of Patent: August 7, 1990
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Kevin C. Lee, Charles A. Lee, John Silcox
  • Patent number: 4843028
    Abstract: In a method for producing a spatially periodic semiconductor layer structure in the form of a superlattice composed of an alternating arrangement of strained semicondutor layers of at least two different semiconductor compositions forming at least one heterojunction, at least one of the semiconductor layers is provided with a doped layer which extends essentially parallel to the heterojunction and whose layer thickness is no greater than the thickness of the semiconductor layer in which it is produced.
    Type: Grant
    Filed: December 8, 1988
    Date of Patent: June 27, 1989
    Assignee: Icentia Patent-Verwaltungs-GmbH
    Inventors: Hans-Joest Herzog, Helmut Jorke, Horst Kibbel
  • Patent number: 4843030
    Abstract: A semiconductor processing method is provided for growing a semiconductor film from a semiconductorbearing gas on a substrate at a substrate temperature below the pyrolytic threshold of the gas. The gas is photodissociated to a collisionally stable species which migrates and travels in the gas phase the entire distance to the substrate, surving hundreds of collisions, and is pyrolyzed at the surface of the substrate and forms several monolayers of semiconductor material which is substantially more catalytically active than the substrate and which subsequently catalyzes decomposition of the gas.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: June 27, 1989
    Assignee: Eaton Corporation
    Inventors: J. Gary Eden, Kevin K. King, Viken Tavitian
  • Patent number: 4800173
    Abstract: Process for producing a valence electron controlled functional crystalline film by introducing (i) a film forming gaseous raw material, (ii) a halogen series gaseous oxidizing agent to oxidize the raw material (i), and (iii) a gaseous raw material to impart a valence electron controlling agent separtely into a reaction region of a film deposition space and chemically reacting them to generate plural kinds of precursors containing excited precursors and to let at least one kind of said precursors to act as a film forming supplier whereby said crystalline film is formed on a selected substrate being kept at a predetermined temperature in the film deposition space.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: January 24, 1989
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiro Kanai, Junichi Hanna, Isamu Shimizu
  • Patent number: 4716445
    Abstract: The heterojunction bipolar transistor has a structure of wide band-gap transistor and comprises a collector region having an N-type GaAs layer, a base region having a P-type germanium layer formed on the N-type GaAs layer, and an emitter region having an N-type semiconductor layer of mixed crystal of silicon and germanium formed on the P-type germanium layer. The mixed crystal of the N-type semiconductor layer may have a uniform distribution of silicon or a graded distribution of silicon in which a content of silicon is zero at the surface facing the P-type germanium layer and is continuously increased with distance from the surface facing the P-type germanium layer.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: December 29, 1987
    Assignee: NEC Corporation
    Inventor: Jun'ichi Sone
  • Patent number: 4589006
    Abstract: Passivation of predominantly crystalline semiconductor devices (12) is provided for by a surface coating (21) of sputtered hydrogenated amorphous semiconductor material. Passivation of a radiation detector germanium diode, for example, is realized by sputtering a coating (21) of amorphous germanium onto the etched and quenched diode surface (11) in a low pressure atmosphere of hydrogen and argon. Unlike prior germanium diode semiconductor devices (12), which must be maintained in vacuum at cryogenic temperatures to avoid deterioration, a diode processed in the described manner may be stored in air at room temperature or otherwise exposed to a variety of environmental conditions. The coating (21) compensates for pre-existing undesirable surface states as well as protecting the semiconductor device (12) against future impregnation with impurities.
    Type: Grant
    Filed: November 1, 1984
    Date of Patent: May 13, 1986
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: William L. Hansen, Eugene E. Haller
  • Patent number: H29
    Abstract: A TUNNETT (tunneling transit time) electronic device comprising a very thin injector uniformly doped at a high concentration, a thin drift region of lower doping of the same semiconductivity type, and a collector of high doping of the same semiconductivity type. A Schottky barrier is formed by placing a metal electrode on the injector and an ohmic contact may be made on the collector. In a preferred embodiment the injector is made of Ge grown on the drift region by vacuum epitaxy. The drift region is preferably GaAs grown by epitaxy on a GaAs collector.
    Type: Grant
    Filed: January 4, 1983
    Date of Patent: March 4, 1986
    Assignee: The Government of the United States
    Inventors: Aristos Christou, John E. Davey