Smoke Or Weather Composition Contains Resin Patents (Class 149/117)
  • Patent number: 10717685
    Abstract: A multispectral smoke obscurant composition effective in reducing transmittance in the visual, infrared, and ultraviolet regions of the electromagnetic spectrum, comprising at least one metal organic framework (“MOF”), at least one fuel, at least one oxidizer, and optionally one or more additives selected from the group consisting of binders, coolants, and accelerants. The MOF or MOF composite is present from about 10 to 90 weight percent of the smoke obscurant composition, while the fuel and the oxidizer in combination comprise about at least 10 weight percent of the smoke obscurant composition.
    Type: Grant
    Filed: April 18, 2019
    Date of Patent: July 21, 2020
    Assignee: The United States of America as Represented by the Secretary Of the Army
    Inventors: Amee L Polk, Zachary B Zander, Danielle L Kuhn, Gregory W Peterson, Jared B DeCoste
  • Patent number: 9650308
    Abstract: A reduced toxicity baseline screening smoke composition and method includes a mixture of lithium perchlorate and boron. The mixture may further include a burn rate modifier and any of an inorganic chloride coolant and a carbonate coolant. The lithium perchlorate may be in the range of 75% to 95% parts by weight. The boron may be in the range of 5% to 25% parts by weight. The any of an inorganic chloride coolant and a carbonate coolant may be in the range of 5% to 25% parts by weight. The mixture may include boron oxide.
    Type: Grant
    Filed: March 12, 2015
    Date of Patent: May 16, 2017
    Assignee: The United States of America as Represented by the Secretary of the Army
    Inventor: Amee W LaBonte
  • Patent number: 7743807
    Abstract: A tread rubber composition for tires, including a sublimation dye that is activated by heat generated by frictional contact with a road surface to generate smoke having various colors at a wavelength of about 39-76×10?6 cm (390 nm to 760 nm) in a frequency range of about 39.5˜77×1013 vps (39.5×1013 Hz to 77×1013 Hz. In addition, a tire including the tread rubber composition and a method of manufacturing the tread rubber composition are also provided. According to the current invention, the tread rubber composition included in the tire can generate smoke having a single color or mixed colors selected from among various colors, therefore obtaining smoke that gives optimal enjoyment and satisfies requirements of drivers at motor sports events, such as drifting.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: June 29, 2010
    Assignee: Kumho Tire Co., Inc.
    Inventor: James L. Palombo
  • Patent number: 6558487
    Abstract: A smoke generating composition including at least one smoke generating material and an effective amount of a polymerized monosaccharide or disaccharide as a binder. The polymerized monosaccharide or disaccharide serves the dual purpose of being both a binder and a fuel to provide a more efficient and safer smoke generating composition.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: May 6, 2003
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Raef M. Tadros
  • Patent number: 6414040
    Abstract: A composition for generating smoke, consisting essentially of at least one chlorine compound having a chlorine content of at least 56% by weight of the chlorine compound, and a mixture of at least one metal oxide and at least one metal. The metal oxide is an alkaline-earth metal oxide and the metal is an alkaline-earth metal. The molar fraction of alkaline-earth metal, based on the total number of moles of alkaline-earth metal and alkaline-earth metal oxide, is between 0.33 and 0.67. Preferably, the chlorine compound is hexachloroethane. Also preferably, the molar fraction of the mixture of alkaline-earth metal and alkaline-earth metal oxide in the composition is between 0.37 and 0.91. The alkaline-earth metal comprises particles having an average size of 50-100 &mgr;m and particles having an average size of 150-300 &mgr;m.
    Type: Grant
    Filed: September 30, 1999
    Date of Patent: July 2, 2002
    Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNO
    Inventors: Christoffel Adrianus Van Driel, Adriana Petronella Martina Leenders, Arnold Barend Leeuwenburgh, Elisabeth Schonewille
  • Patent number: 5780765
    Abstract: The invention is directed to an electrical ignitor for a model rocket, including two insulated lead wires, with each lead wire having an uninsulated end. An element wire interconnects the uninsulated ends from each lead wire. The element wire forms a plurality of turns around one of the insulated lead wires. A pyrogen compound surrounds the element wire.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: July 14, 1998
    Inventor: Jerry F. Dyben
  • Patent number: 5656794
    Abstract: In a continuously burning pyrotechnic composition, compounds of graphite serve as additional components that are capable of thermal expansion in the C-axis perpendicular to the lattice plane and expand in the reaction zone of the pyrotechnic composition, being released with the reaction products of the burning pyrotechnic composition. This permits production of camouflage smokes that are effective in the optically visible range, the IR range and the MMW-RADAR range of electromagnetic radiation.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: August 12, 1997
    Inventors: Uwe Krone, Klaus Moller, Ernest Shulz
  • Patent number: 5610359
    Abstract: A method of generating nontoxic smoke is taught. The method comprises: (a) submerging a nontoxic smoke creating device in a liquid coolant while preventing entry of coolant into said device; said device includes a composition which comprises: (1) a first reactant selected from the group consisting of potassium chlorate, potassium perchlorate, potassium dichromate, cesium nitrate, and potassium nitrate; and (2) a second reactant serving as a reduction agent; (b) activating said smoke creating device by reacting said composition comprising said first reactant and said second reactant, to create solid particulate products having a diameter of about one micron or less which create the nontoxic smoke; and (c) passing said solid particulate products into said coolant through at least one downwardly directed tuyere hydraulically connected at or near the top of said device without any accompanied destruction of said nontoxic smoke creating device.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: March 11, 1997
    Inventors: Yechiel Spector, Esther Jacobson, Vida Naishtut, Michael Vittenberg, Zohar Beinert
  • Patent number: 5522320
    Abstract: Smoke-producing compositions are disclosed that combine the low toxicity of an organic acid smoke and the high obscuration effect of a red phosphorus (RP) smoke. Phosphoric acid produced by RP is neutralized by an acid scavenger added to at least one of the RP or organic acid smoke formulations. To prevent chemical reaction between ingredients of the two smoke-producing formulations, they are separated in the apparatus of the present invention such that only the resulting smokes mix. Very small amount of a RP smoke formulation increases the obscuration index of organic acid smokes comparable to conventional hygroscopic chloride (HC) smokes.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: June 4, 1996
    Assignee: Thiokol Corporation
    Inventor: David R. Dillehay
  • Patent number: 5360162
    Abstract: A method for precipitating atmospheric water by means of multicomponent aerosols, including iodide based complex multicomponent aerosol compositions. The compositions comprise a solid mass formed by a compacted mixture of silver iodide and the iodides, iodates, and periodates of alkali metals, lead, copper, barium; ammonia, barium chromate, and selected oxidizers such as ammonium perchlorate, and fuels such as poly-p-phenylene, phenol formaldehyde resin, epoxide resin, and shellac and mixtures thereof. The compositions, upon burning, produce an aerosol effective to promote atmospheric water precipitation.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: November 1, 1994
    Assignee: Alberta Ltd.
    Inventor: Slavko Mentus
  • Patent number: 5154782
    Abstract: A composition which is capable of producing an obscuring white smoke is disclosed which employs a dicarboxylic acid as the primary smoke producing agent. It is found that by using a dicarboxylic acid smoke producing agent, a generally non-toxic and non-corrosive smoke is achieved. Also included within the composition are a binder, a fuel or coolant, and an oxidizer. The binder may be any one of a number of binders such as nitrocellulose or a polymer binder. A low energy fuel is preferred in order to minimize heat and flame produced. Such fuels may include, for example, starch, dextrose, lactose, sucrose, or sulphur. The presently preferred oxidizer is KCLO.sub.3. Other substances may also be added to the composition. For example, sodium bicarbonate may be added to act as a buffer for the KCLO.sub.3 and as a further coolant. In some cases it may also be desirable to add aluminum for purposes of producing more uniform burning and increased thermal conductivity through out the composition.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: October 13, 1992
    Assignee: Thiokol Corporation
    Inventors: Graham C. Shaw, Daniel B. Nielson, Leon L. Jones, Stanley G. Summers
  • Patent number: 4812180
    Abstract: High intensity yellow smoke and flame flare compositions are manufactured a procedure which closely parallels that of solid rocket propellants. These compositions use similar ingredients to those used in solid rocket propellants. These compositions are castable whereas conventional flares consist of pressed flare charges. Both colored flame and smoke are produced from the same composition. A liquid curable binder composition is selected from triethylene glycol succinate or carboxyl-terminated polybutadiene crosslinked with O,NN-tris(2,3-epoxypropyl)-4-aminophenol, and hydroxyl-terminated polybutadiene crosslinked with isophorone diisocyanate. The color producing ingredient is a first inorganic salt of lead iodide which can be further enhanced by an additive of a reactive source of iodine selected from iodine pentoxide and iodoform. A second inorganic salt is selected from inorganic oxidizing salts consisting of potassium perchlorate and amononium perchlorate.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: March 14, 1989
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: David C. Sayles
  • Patent number: 4724018
    Abstract: The invention pertains to a smoke-producing pyrotechnical composition which is designed for the production of a smoke screen that prohibits the transmission of infrared radiance from a target to a pick-up.It includes a compound which generates, through thermal decomposing, carbon particles of which the size is included between about 1 and 14 .mu.m, and an oxidoreducing system which reacts at a temperature that exceeds 1000 degrees C. and a binding agent. The compound which generates carbon particles can be hexachloroethane, hexachlorobenzene, naphtalene, anthracene, or their mixture; the reducing agent can be a metal powder (magnesium) and the oxidizer hexachlorobenzene and/or hexachloroethane.An application to the execution of smoke-producing devices.
    Type: Grant
    Filed: July 27, 1983
    Date of Patent: February 9, 1988
    Assignee: Etat Francais
    Inventors: Andre Espagnacq, Gerard D. Sauvestre
  • Patent number: 4719856
    Abstract: The pyrotechnic device comprises a projectile, a ground mounted device or a floating device whose casing contains a charge of titanium or other suitable combustible metal-containing material, charcoal, or other reducing agent and gunpowder such that, following ignition, infra-red emitting particles are emitted to form an infra-red radiating screen. The carbon reduces oxidation of the combustible material prior to emission.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: January 19, 1988
    Assignee: Pains-Wessex Limited
    Inventor: Nigel F. Joslin
  • Patent number: 4719857
    Abstract: The pyrotechnic device comprises a projectile, a ground mounted device or a floating device whose casing contains a charge of particulate material, for example a combustible silicon-containing material in particular mixed with titanium or other suitable combustible metal-containing material and gunpowder such that, following ignition, infra-red emitting particles are emitted for forming an infra-red radiating screen.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: January 19, 1988
    Assignee: Pains-Wessex Limited
    Inventor: David J. Spring
  • Patent number: 4653690
    Abstract: The disruption of a thermal inversion and formation of cumulus clouds is duced by the ignition of a pyrotechnic composition containing an alkali earth metal. The combined heats of hydration, condensation and combustion of the composition disrupt the thermal layer allowing the passage of warm moist air into a zone of cooler air. The formation of cumulonimbus or cumulus clouds results.
    Type: Grant
    Filed: November 5, 1984
    Date of Patent: March 31, 1987
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Pierre St. Amand, Larry A. Mathews
  • Patent number: 4534810
    Abstract: A smoke-producing composition which will produce a dense smoke in about 5 conds and continues to produce a visible cloud having a duration of about 10 minutes for military screening operations in the field. The composition has critical limits in proportions and particle size for effective and efficient use in the 81 mm mortar cartridge. The composition consists essentially of 75 to 90 parts red phosphorus of 10.+-.5.mu. in size, 10 to 20 parts sodium nitrate of 30.+-.15.mu., and 4 to 10 parts of an epoxy binder. All parts being by weight.
    Type: Grant
    Filed: January 30, 1984
    Date of Patent: August 13, 1985
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Charles A. Knapp
  • Patent number: 4503004
    Abstract: A method of molding a red phosphorous pyrotechnic mix containing an epoxy nder, which is markedly improved by the addition of silica.
    Type: Grant
    Filed: March 12, 1984
    Date of Patent: March 5, 1985
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Peter D. Mirabella
  • Patent number: 4455178
    Abstract: A smoke generating pyrotechnic composition of the type comprising an oxidizing agent--reducing agent system, a sublimable organic dye and including a binder additionally, contains a carbazate of general formula ##STR1## in which R represents a straight-chained or branched-chained alkyl group comprising 1 to 5 carbon atoms as cooling agent, inter alia. The composition is suitable, when the binder is a synthetic resin and includes such additional components as organic plasticizer and possibly a hardener and a metal oxide catalyst, for use in the production of cast smoke generating pyrotechnic products.
    Type: Grant
    Filed: July 11, 1983
    Date of Patent: June 19, 1984
    Assignee: Etat Francais represente par le Delegue General pour l'Armement
    Inventor: Georges Sedat
  • Patent number: 4447278
    Abstract: The subject of the invention is a castable pyrotechnic composition of the type producing smoke with a colored or colorless flame comprising in particular an oxidation-reduction pair and a chlorinated binder. The binder is a high chlorine content resin. It is constituted by the association of a polymerizable chlorinated monomer with a copolymerized or non-copolymerized chlorinated polymer, the resulting mixture being subjected to polymerization at a moderate temperature, said binder then containing 30 to 70% by weight of chlorine.
    Type: Grant
    Filed: July 26, 1982
    Date of Patent: May 8, 1984
    Assignee: Etat Francais represente par le Delegue General pour l'Armement
    Inventor: Georges A. Sedat
  • Patent number: 4376001
    Abstract: A smoke generating composition consisting essentially of metallic oxide ammonium perchlorate, an organic chlorine donor and a plasticizer and a buffering agent. The metallic oxide includes zinc oxide as one of its components and ammonium perchlorate as well as polychloroisoprene as components of the chlorine donor. All of the components are mixed in such proportions that a neutral fog within the range of pH 5-7 is formed.
    Type: Grant
    Filed: August 6, 1980
    Date of Patent: March 8, 1983
    Assignee: Nico-Pyrotechnik Hanns-Juergen Diederichs KG.
    Inventors: Uwe Krone, Klaus Moeller
  • Patent number: 4366010
    Abstract: The invention relates to a smoke-producing pyrotechnic composition and its applications.The composition comprises the following main components:at least one first compound selected from the group consisting of potassium or sodium chlorate;at least one second compound selected from the group consisting of guanidine nitrate;metallic oxides;at least one epoxyaliphatic resin, whether or not plasticized; andat least one sublimable organic coloring substance.It is used primarily in pyrotechnics, in particular for the production of colored smokes.
    Type: Grant
    Filed: July 15, 1980
    Date of Patent: December 28, 1982
    Inventor: Georges A. Sedat
  • Patent number: 4328117
    Abstract: The invention relates to a process for opacifying a gaseous medium transparent to optical and thermal radiation.It is characterized in that it consists in diffusing in the medium, for example the atmosphere, an aerosol such as boron trichloride (BCl.sub.3).The invention applies to the field of electro-optical countermeasures.
    Type: Grant
    Filed: May 20, 1980
    Date of Patent: May 4, 1982
    Assignee: Thomson-Brandt
    Inventor: Pierre Godefroy
  • Patent number: 4225368
    Abstract: This invention relates to organic dye compositions of improved mechanical properties and to a method of coating the dye with an inert coating material which enables the production of pour-castable colored smoke-producing compositions of high solids loading, particularly when a red dye e.g. Disperse Red 9, is employed.
    Type: Grant
    Filed: June 26, 1979
    Date of Patent: September 30, 1980
    Assignee: Canadian Department of National Defence
    Inventors: Joseph E. G. Couture, Joseph N. A. Roy
  • Patent number: 4184901
    Abstract: A pyrotechnic composition which, when burned, produces yellow smoke and yellow flame. The composition is comprised of between 5 and 30 percent of a fuel which is either magnesium or silicon, between 65 and 85 percent of bismuth subnitrate and between 5 and 13 percent of an epoxy binder.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: January 22, 1980
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: John E. Tanner, Jr., Henry A. Webster, III
  • Patent number: 4096005
    Abstract: A pyrotechnic cloud seeding composition comprising from about 60 to about 85 weight percent silver iodate, from about 10 to about 40 weight percent of a fuel from the class consisting of aluminium and magnesium, from about 5 to about 15 weight percent binder, and from about 0.1 to about 10 percent halogenated organic compound having a melting point of at least about 50.degree. C. One illustrative compound is hexachlorobenzene.
    Type: Grant
    Filed: June 13, 1977
    Date of Patent: June 20, 1978
    Assignee: Nuclei Engineering, Inc.
    Inventor: Thomas W. Slusher
  • Patent number: 4032374
    Abstract: A non-toxic smoke composition for use in simulating fires in damage control xercises and for use in training. Transcinnamic acid is used as the smoke producing agent and is volatilized by energy from a potassium chlorate/sugar mixture which provides a low burning temperature.
    Type: Grant
    Filed: September 22, 1976
    Date of Patent: June 28, 1977
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Bernard E. Douda, John E. Tanner, Jr.
  • Patent number: H231
    Abstract: The composition of this invention is a colored-smoke pyrotechnic for use as rocket fuel which can propel a 500 gram grenade assembly along a trajectory of about 100 meters while producing a trail of intensely colored, highly visible smoke. The composition contains ammonium sulfamate, potassium chlorate, sucrose, and an organic dye. The sulfamate ingredient functions as a primary reactant, and forms a large quantity of smoke and other gaseous by-products. The potassium chlorate and sucrose exists as a mixture, and when burning produces a large amount of energy which initiates the reaction sequence. The organic dye in the composition is volatilized by the heat, and subsequently condenses in the exhaust plume to color the smoke trail.
    Type: Grant
    Filed: August 26, 1986
    Date of Patent: March 3, 1987
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Gerald P. Young
  • Patent number: H232
    Abstract: The composition of this invention contains red phosphorus, magnesium, sod nitrate, and an epoxy binder. It can optionally contain silica to aid in processing. The magnesium is used to sustain the smoke produced by the red phosphorus for a period greater than 5 minutes for screening of military operations. Further, the composition does not exhibit any increased sensitivity to impact or friction over traditional smoke-producing compositions. This is the case even though the composition contains a high-level of red phosphorus.
    Type: Grant
    Filed: August 26, 1986
    Date of Patent: March 3, 1987
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Joel H. Selzer
  • Patent number: H233
    Abstract: The present invention is an essentially non-toxic, smoke-producing, pyrotnic composition. The composition uses 1,4 benzenedicarboxylic acid which produces a superior visual screening smoke when vaporized by heat provided a reaction between suitable fuel and oxidizer. The composition additionally contains potassium chlorate and sugar. The composition burns at a low temperature without a visual flame and is suited for use in smoke grenades and smoke pots.
    Type: Grant
    Filed: August 29, 1986
    Date of Patent: March 3, 1987
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: Gene V. Tracy
  • Patent number: H367
    Abstract: A dye smoke which burns efficiently and without flame consisting essentia of a hydroxyl terminated polybutadiene binder, the biuret trimer of hexamethylene diisocyanate curative, a leucoquinizarin dye referred to as 1,4,9,10-tetrahydroxyanthracene, and ammonium iodate oxidizer. The leucoquinizarin dye is oxidized and iodinated resulting in the iodoanthraquinone derivatives which produce the colored smoke.
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: November 3, 1987
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Russell Reed, Jr., Jawaharlal Ramnarace