Polymerized Conjugated Diene Patents (Class 149/19.9)
  • Patent number: 11421084
    Abstract: Disclosed are latexes, suspensions, and colloids having a cationic antimicrobial compound complexed with an anionic surfactant. The surfactant may have greater affinity for the antimicrobial compound than other anionic surfactants and other anions in the latex, suspension, or colloid that contribute to disperse phase stability to prevent disrupting the dispersions. Dispersions containing the antimicrobial compound may therefore have a shelf life comparable to dispersions that are otherwise identical but lack the cationic antimicrobial compound and its complexed anionic surfactant. Coatings made with the complexes can exhibit essentially undiminished antimicrobial activity.
    Type: Grant
    Filed: July 24, 2020
    Date of Patent: August 23, 2022
    Assignee: Poly Group LLC
    Inventors: Thomas E. Hopkins, Craig A. Kalmer
  • Patent number: 9732552
    Abstract: Vacuum insulating glass (VIG) units, edge seals for VIG units and methods for forming the edge seals are provided. The VIG units include an edge seal that includes a viscous material, which serves to restrict the rate at which gas permeates into a vacuum space defined between the glass sheets of the VIG unit. The edge seals are configured to allow the glass sheets to move laterally relative to one another when the glass sheets experience differential thermal strain and further configured such that viscous shear occurs within at least a portion of the viscous material when there is relative lateral movement between the glass sheets.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: August 15, 2017
    Inventor: Robert S. Jones
  • Patent number: 9434611
    Abstract: Provided is a packaged hydrogen-generating agent, the hydrogen-generating reaction of which is highly stable and repeatable, and which preferably is resistant to influence from changes in the environmental temperature. Also provided are a method for manufacturing said package, and a hydrogen generation method. The packaged hydrogen-generating agent is provided with: a hydrogen-generating agent (1); a covering material (2) which encloses the hydrogen-generating agent (1) and allows deformation; and a water-absorbing body (3), part of which is in contact with the hydrogen-generating agent (1). The covering material (2) preferably covers at least the area around the contact part (3a) where the water-absorbing body (3) and the hydrogen-generating agent (1) are in contact, so as to create a firm attachment at the contact part (3a).
    Type: Grant
    Filed: April 21, 2010
    Date of Patent: September 6, 2016
    Assignee: AQUAFAIRY CORPORATION
    Inventors: Masakazu Sugimoto, Masaya Yano
  • Patent number: 8986473
    Abstract: The invention is a composition for a high burning-rate solid rocket propellant, where the composition includes a binder compounded with a soluble energetic additive; a metallic fuel; and an oxidative fuel. The resulting composition has a tactical Class 1.3 hazard rating, and a linear regression rate that is substantially equivalent to a tactical Class 1.1 hazard rating obtainable using solid rocket propellants. The composition may include a heat-conducting element, a plasticizer, a curing component, a combustion catalyst, and curing catalyst.
    Type: Grant
    Filed: September 3, 2008
    Date of Patent: March 24, 2015
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: John M. Kelley, Robert C. Gill
  • Publication number: 20140090756
    Abstract: A method of forming composite materials includes mixing a first metal precursor with a chelating agent to form a first metal-chelate complex. The first metal-chelate complex is added to a polymer binder having terminating hydroxyl groups to form a polymer binder-first metal-chelate. The polymer binder first metal-chelate complex is mixed with an aluminum precursor. The aluminum precursor decomposes forming aluminum nanoparticles dispersed in a continuous phase material having metallic aluminum cores. At least one of the first metal-chelate complex and the first metal is dissolved in the continuous phase. The aluminum nanoparticles can have a passivating coating layer thereon provided by the polymer binder, or can have a passivating coating layer formed by including an epoxide, alcohol, carboxylic acid, or amine in the adding that forms passivating compound(s) which add further protection that can provide complete protection from oxidation of the metallic aluminum cores by air.
    Type: Application
    Filed: March 12, 2013
    Publication date: April 3, 2014
    Applicant: University of Central Florida Research Foundation, Inc.
    Inventor: University of Central Florida Research Foundation, Inc.
  • Publication number: 20120132099
    Abstract: A primer composition that includes red phosphorus having an acid scavenger and a polymer thereon. The primer composition includes at least one other component that is substantially free of lead. The other component is at least one oxidizer, or at least one oxidizer and at least one of at least one secondary explosive composition and at least one energetic binder. The primer composition optionally includes at least one element having an ionic charge to ionic radius ratio of 4 or of 8, such as magnesium, zirconium, aluminum, silicon, titanium, tungsten, alloys thereof, and combinations thereof. The red phosphorus and the at least one oxidizer are present in the primer composition at approximately stoichiometric amounts. An ordnance element including the primer composition is also disclosed.
    Type: Application
    Filed: August 19, 2008
    Publication date: May 31, 2012
    Inventors: Randall T. Busky, Tod R. Botcher, Joel L. Sandstrom, Jack A. Erickson
  • Patent number: 8029630
    Abstract: The present invention concerns a composition for a pyrotechnic compound that can be used as a thermal fuse in a gas generator comprising a pyrotechnic charge, said pyrotechnic compound having a self-ignition temperature that is lower than that of the pyrotechnic charge of the generator so as to be capable of initiating combustion of the pyrotechnic charge in the event of abnormal heating of the generator before said pyrotechnic charge reaches its self-ignition temperature. This composition is characterized in that it can be metered out and deposited in the form of an adhesive onto any appropriate support of the generator.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: October 4, 2011
    Assignee: SME
    Inventors: Frederic Marlin, Gerard Marino
  • Publication number: 20110168306
    Abstract: The invention relates to a cast explosive composition comprising a polymer-bonded explosive and a defoaming agent, and to a process for reducing the number and/or total volume of voids in a cast explosive composition comprising the steps of: combining a polymer-bonded explosive and a defoaming agent; and casting the explosive composition. The defoaming agent may be used for reducing the number and/or total volume of voids in a cast explosive composition and the cast explosive composition may be used in an explosive product.
    Type: Application
    Filed: August 27, 2009
    Publication date: July 14, 2011
    Applicant: BAE Systems PLC
    Inventors: Ronald Edward Hollands, Ian Ewart Paterson Murray
  • Publication number: 20110056598
    Abstract: An explosive composition is provided comprising an explosive agent, a solid fuel and a polymeric adherent wherein the explosive agent, solid fuel and polymeric adherent are dispersed throughout the composition.
    Type: Application
    Filed: April 28, 2009
    Publication date: March 10, 2011
    Inventors: Alan Twomey, Michael Twomey
  • Patent number: 7743807
    Abstract: A tread rubber composition for tires, including a sublimation dye that is activated by heat generated by frictional contact with a road surface to generate smoke having various colors at a wavelength of about 39-76×10?6 cm (390 nm to 760 nm) in a frequency range of about 39.5˜77×1013 vps (39.5×1013 Hz to 77×1013 Hz. In addition, a tire including the tread rubber composition and a method of manufacturing the tread rubber composition are also provided. According to the current invention, the tread rubber composition included in the tire can generate smoke having a single color or mixed colors selected from among various colors, therefore obtaining smoke that gives optimal enjoyment and satisfies requirements of drivers at motor sports events, such as drifting.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: June 29, 2010
    Assignee: Kumho Tire Co., Inc.
    Inventor: James L. Palombo
  • Patent number: 7108758
    Abstract: An electrostatic charge reduction system including a composition having at least one energetic particle component with or without a non-conducting binder, and conducting polymer or electrically neutral polymer deposited on the energetic component in its oxidized form. The oxidation of the polymer occurs during or after the polymer deposition process.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: September 19, 2006
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Stephen Fallis, Jennifer A. Irvin
  • Patent number: 6982013
    Abstract: An electrostatic charge dissipation composition having at least one energetic particle component and at least one electrically active polymer is coated on the energetic component and thereafter, the polymer coating is oxidized. In another embodiment, the electrostatic charge dissipation composition includes at least one energetic particle component, at least one non-conducting polymer binder, and at least one electrically active polymer is coated on the energetic component/binder mixture and thereafter, the polymer coating is oxidized.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: January 3, 2006
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Stephen Fallis, Jennifer A. Irvin
  • Patent number: 6916388
    Abstract: The present invention is directed to a solid propellant for rocket motors, gas generators and comparable devices, comprising a cured composition of hydrazinium nitroformate and an unsaturated hydroxyl terminated hydrocarbon compound.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: July 12, 2005
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Jeroen Louwers, Antonius Eduard Dominicus Maria Van Der Heijden, Petrus Johannes Maria Elands
  • Patent number: 6833037
    Abstract: A thermoplastic bonded energetic material which comprises a composition which comprises: Component A: an energetic filler material; and Component B: a polymeric binder for the energetic filler material; wherein the ratio of the weight of Component A present to the weight of Component B present in the composition is in the inclusive range from 1:10 to 1991:1 and wherein Component B comprises an intimate mixture of Ingredients 1 and 2 as follows: Ingredient 1: a copolymer of ethylene and vinyl acetate; Ingredient 2: a copolymer of butadiene and acrylonitrile; the ratio of the weight of Ingredient 1 present to the weight of Ingredient 2 present in Component B being in the inclusive range from 1:10 to 10:1.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: December 21, 2004
    Assignee: BAE Systems PLC
    Inventors: Deirdre Hallam, Ronald E. Hollands, Pauline J. Holes
  • Patent number: 6808572
    Abstract: High temperature incendiary (HTI) devices and methods destroy biological and/or chemical agents. Preferably, such HTI devices include dual modal propellant compositions having low bum rate propellant particles dispersed in a matrix of a high burn rate propellant. Most preferably, the HTI device includes a casing which contains the dual modal propellant and a nozzle through which combustion gases generated by the ignited high burn rate propellant may be discharged thereby entraining ignited particles of the low burn rate propellant. In use, therefore, the high burn rate propellant will be ignited using a conventional igniter thereby generating combustion gases which are expelled through the nozzle of the HTI device. As the ignition face of the propellant composition regresses, the low burn rate particles will similarly become ignited.
    Type: Grant
    Filed: May 15, 2002
    Date of Patent: October 26, 2004
    Assignee: Aerojet-General Corporation
    Inventor: Hermann L. Miskelly, Jr.
  • Patent number: 6782827
    Abstract: High temperature incendiary (HTI) devices and methods destroy biological and/or chemical agents. Preferably, such HTI devices include dual modal propellant compositions having low burn rate propellant particles dispersed in a matrix of a high burn rate propellant. Most preferably, the HTI device includes a casing which contains the dual modal propellant and a nozzle through which combustion gases generated by the ignited high burn rate propellant may be discharged thereby entraining ignited particles of the low burn rate propellant. In use, therefore, the high burn rate propellant will be ignited using a conventional igniter thereby generating combustion gases which are expelled through the nozzle of the HTI device. As the ignition face of the propellant composition regresses, the low burn rate particles will similarly become ignited.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: August 31, 2004
    Assignee: Aerojet-General Corporation
    Inventor: Hermann L. Miskelly, Jr.
  • Patent number: 6748868
    Abstract: High temperature incendiary (HTI) devices and methods destroy biological and/or chemical agents. Preferably, such HTI devices include dual modal propellant compositions having low burn rate propellant particles dispersed in a matrix of a high burn rate propellant. Most preferably, the HTI device includes a casing which contains the dual modal propellant and a nozzle through which combustion gases generated by the ignited high burn rate propellant may be discharged thereby entraining ignited particles of the low burn rate propellant. In use, therefore, the high burn rate propellant will be ignited using a conventional igniter thereby generating combustion gases which are expelled through the nozzle of the HTI device. As the ignition face of the propellant composition regresses, the low burn rate particles will similarly become ignited.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: June 15, 2004
    Assignee: Atlantic Research Corp.
    Inventor: Hermann L. Miskelly, Jr.
  • Patent number: 6736913
    Abstract: A method for processing explosives containing a high loading of CL-20 may advantageously include a binder system having naphthenic oil and/or paraffinic oil. Solid energetic ingredients are added into the binder system and mixed to form a free-flowing suspension in which the solid energetic ingredients are homogeneously mixed and coated with the binder system. The binder system is then cured and cast to form a cross-linked explosive.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: May 18, 2004
    Assignee: Alliant Techsystems Inc.
    Inventor: Robert L. Hatch
  • Patent number: 6736912
    Abstract: A solid combustible composition for use in solid fuel air-augmented rocket engines which very substantially increases the temperature efficiency of afterburner fuel combustion with ram air, thereby greatly increasing engine performance. The improvement comprises dispersing in a matrix comprising the solid, fuel-rich organic compositions conventionally utilized in air-augmented rockets, particles containing solid oxidizable element and fluorine oxidizer compound which reacts with the element to produce gaseous subfluoride compound.
    Type: Grant
    Filed: March 24, 1977
    Date of Patent: May 18, 2004
    Inventors: Jerry L. Fields, James D. Martin
  • Patent number: 6723190
    Abstract: A communication system comprises an input-output processor IOP (11) coupled to a plurality of network devices (10) and a protocol processor PP (12), both processors being coupled to a common memory (15). Memory access control means (16) resolves competition between the processors for memory access. Normally, if one of the two processors is accessing the memory, the memory control unit (16) allows that access to be completed before allowing the other processor to access the memory. But if data loss in a network device is imminent, the IOP, is granted a higher priority memory access, the memory access controller aborts (interrupts) any memory access by the PP, allowing the IOP to access the memory immediately.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: April 20, 2004
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert C. Gill, Carl Gotzmer, Pamela Carpenter, Eric Schlegel
  • Patent number: 6627014
    Abstract: An apparatus (10) for inflating an inflatable vehicle occupant protection device comprises a container (12) for storing a supply of gas. A gas (26) is stored in the container (12) at an elevated pressure. The gas comprises an oxygen rich oxidizer gas. A gas generating material (84) is stored in the container (12) and is exposed to the oxidizer gas at the elevated pressure. The gas generating material (84) comprises a cellulose based binder blended with an anti-oxidant material. An igniter (52) is provided for igniting the gas generating material (84).
    Type: Grant
    Filed: August 7, 2000
    Date of Patent: September 30, 2003
    Assignee: TRW Inc.
    Inventor: Harold R. Blomquist
  • Publication number: 20030168140
    Abstract: The compound 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine and its salts are provided together with a propellant composition including an oxidizer, a binder and 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine or its salts.
    Type: Application
    Filed: August 6, 2002
    Publication date: September 11, 2003
    Inventors: Michael A. Hiskey, David E. Chavez, Darren Naud
  • Publication number: 20030098107
    Abstract: This invention comprises a new process for developing high regression rate propellants for application to hybrid rockets and solid fuel ramjets. The process involves the use of a criterion to identify propellants which form an unstable liquid layer on the melting surface of the propellant. Entrainment of droplets from the unstable liquid-gas interface can substantially increase propellant mass transfer leading to much higher surface regression rates over those that can be achieved with conventional hybrid propellants. The main reason is that entrainment is not limited by heat transfer to the propellant from the combustion zone. The process has been used to identify a new class of non-cryogenic hybrid fuels whose regression rate characteristics can be tailored for a given mission. The fuel can be used as the basis for a simpler hybrid rocket design with reduced cost, reduced complexity and increased performance.
    Type: Application
    Filed: July 21, 1999
    Publication date: May 29, 2003
    Inventors: M. ARIF KARABEYOGLU, DAVID ALTMAN, BRIAN J. CANTWELL
  • Patent number: 6554928
    Abstract: A gas generating material (16) comprises an oxidizer, a fuel, and a binder composition. The binder composition includes a polystyrene based thermoplastic block copolymer and a thermoplastic modifier. The thermoplastic modifier is miscible with the polystyrene based thermoplastic block copolymer and has a glass transition temperature greater than about 170° C.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: April 29, 2003
    Assignee: TRW Inc.
    Inventors: Peter J. Astrauskas, David D. Ryder, Michael G. Mangum
  • Patent number: 6458227
    Abstract: The compound 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine and its salts are provided together with a propellant composition including an oxidizer, a binder and 3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine or its salts.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: October 1, 2002
    Assignee: The Regents of the University of California
    Inventors: Michael A. Hiskey, David E. Chavez, Darren Naud
  • Publication number: 20020096234
    Abstract: A gas generating material (16) comprises an oxidizer, a fuel, and a binder composition. The binder composition includes a polystyrene based thermoplastic block copolymer and a thermoplastic modifier. The thermoplastic modifier is miscible with the polystyrene based thermoplastic block copolymer and has a glass transition temperature greater than about 170° C.
    Type: Application
    Filed: November 30, 2000
    Publication date: July 25, 2002
    Applicant: TRW Inc.
    Inventors: Peter J. Astrauskas, David D. Ryder, Michael G. Mangum
  • Patent number: 6409854
    Abstract: A high temperature incendiary composition having a reactive material of titanium, a second reactive material of boron, an oxidizer of polytetrafluoroethylene in an amount of from about 10 weight percent or less of the composition and a binder of carboxyl-terminated polybutadiene acrylonitrile in an amount of from about 5 weight percent or more. The composition is safe to handle, ignites readily, burns at a low and controlled rate and produces a very high flame temperature.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: June 25, 2002
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert C. Gill, Carl Gotzmer, Pamela Carpenter, Eric Schlegel
  • Patent number: 6402864
    Abstract: A high temperature incendiary composition having a reactive material of titanium, a second reactive material of boron, an oxidizer of polytetrafluoroethylene in an amount of from about 20 weight percent or greater of the composition and a binder of CTBN in an amount of from about 10 weight percent or less. The composition is safe to handle, ignites readily, produces low slag, burns at a low and controlled rate and produces a very high flame temperature.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: June 11, 2002
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Robert C. Gill, Carl Gotzmer, Pamela Carpenter, Eric Schlegel
  • Patent number: 6364975
    Abstract: The present invention is directed to an age-stabilized and/or strengthened ammonium nitrate propellant composition wherein the strengthening agent is selected from the group consisting of azodicarbonamide, dicyandiamide, oxamide and mixtures thereof and wherein the age-stabilizing agent is a molecular sieve having a pore size of 13 angstroms or less.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: April 2, 2002
    Assignee: Universal Propulsion Co., Inc.
    Inventors: Wayne C. Fleming, Hugh J. McSpadden, Donald E. Olander
  • Publication number: 20020036038
    Abstract: This invention comprises a new process for developing high regression rate propellants for application to hybrid rockets and solid fuel ramjets. The process involves the use of a criterion to identify propellants which form an unstable liquid layer on the melting surface of the propellant. Entrainment of droplets from the unstable liquid-gas interface can substantially increase propellant mass transfer leading to much higher surface regression rates over those that can be achieved with conventional hybrid propellants. The main reason is that entrainment is not limited by heat transfer to the propellant from the combustion zone. The process has been used to identify a new class of non-cryogenic hybrid fuels whose regression rate characteristics can be tailored for a given mission. The fuel can be used as the basis for a simpler hybrid rocket design with reduced cost, reduced complexity and increased performance.
    Type: Application
    Filed: February 17, 2000
    Publication date: March 28, 2002
    Inventors: M. Arif Karabeyoglu, David Altman, Brian J. Cantwell
  • Patent number: 6258188
    Abstract: In the development of new minimum signature ducted rocket technology, the U.S. Army MICOM Propulsion Directorate has conducted studies for the development of fuel-rich gas generators for ducted rockets. The propellant formulation goals of this study include increasing burning rate, pressure exponent, and combustion efficiency without significantly decreasing fuel value. Formulations described in this application contain an energetic nitramine-prepolymer, a range of curing agents, and zirconium hydride (ZrH2) fuel element and carbon (C) as an optional fuel element.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: July 10, 2001
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Richard C. Hatcher, William D. Stephens, Robert L. Stanley
  • Patent number: 6206988
    Abstract: Hexanitrohexaazaisowurtzitane-containing compositions which comprise hexanitrohexaazaisowurtzitane, polynitropolyacetylhexaazaisowurtzitanes and one or more of oxaisowurtzitane compounds represented by the specified formulae. The explosive compositions which contain the hexanitrohexaazaisowurtzitane-containing compositions have improved handling safety by lowering their sensitivity without degrading combustibility and detonability.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 27, 2001
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Hakobu Bazaki
  • Patent number: 6197135
    Abstract: The instant invention relates to the use of certain selected neoalkoxy organo-titanates and organo-zirconates in energetic compositions to improve their processability, physical properties, and combustion properties. The organo-titanates and organo-zirconates of the instant invention, when added to the energetic systems' matrix in advance of the introduction of particulate or other solid energetic components, improve the dispersion of the latter while reducing the energy required to achieve formulation uniformity. This enhances the processability, the physical properties, the burn characteristics and the safety and handling characteristics of the formulated composites.
    Type: Grant
    Filed: February 18, 1986
    Date of Patent: March 6, 2001
    Assignee: Kenrich Petrochemicals, Inc.
    Inventors: Salvatore J. Monte, Gerald Sugerman