Abstract: Provided are cost-effective methods and systems for producing a low molecular weight reactive lignin from a lignocellulosic biomass. The process is rapid and the reactive lignin is easily separated from carbohydrates and other components of the biomass at low cost. This clean lignin product has a very low molecular weight, good hydroxyl content, and low ash and sulfur, making it valuable to many applications.

Abstract: The present disclosure relates to a process for treating a feedstock containing tall oil, the process including separation of a light stream from the feedstock, followed by removal of a heavy fraction from the feedstock, in which process the separation of the light stream from the feedstock a fractionator is used and at least one product is collected from the light stream. The disclosure also relates to an apparatus for use in the process and use of a fractionator in dehydration of a feedstock containing tall oil.

Abstract: The present invention relates to a method for increasing the reactivity of lignin, wherein the method comprises the following steps: a) forming, under heating at a temperature of 71-94° C., an aqueous dispersion comprising alkali and lignin, wherein the alkali comprises a hydroxide of an alkali metal; and b) heating the dispersion formed in step a) at a temperature of 50-95° C. for producing alkalated lignin.

Abstract: A method for preparing a black liquor according to the present invention comprises digesting a tobacco raw material under an alkaline condition to obtain the black liquor. Further, a method for preparing a flavor component-containing liquid according to the present invention comprises digesting a tobacco raw material under an alkaline condition, separating the obtained digesting product into a black liquor and a tobacco fiber, and desalinating the black liquor to obtain the flavor component-containing liquid.

Abstract: A mixture of green banana and ripe banana.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes.

Abstract: There is provided a process for recovery of lignin from black liquor that contains either soluble or dispersed lignin, generating a “liquid-lignin” at high yield. Lignin at elevated pH is precipitated by reducing the pH of the black liquor stream with carbon dioxide, at elevated temperature and pressure, creating two bulk fluid phases: a dense liquid-lignin phase and a light lignin-depleted phase. The dense liquid-lignin phase is separated and washed with a strong acid to displace metal cations from the lignin, creating a low-salt, randomly shaped lignin. If needed, especially for lignin recovered from kraft papermaking black-liquor streams, an oxidation step is included to eliminate negative odor for high value green chemistry applications.

Abstract: The present invention provides derivatives of native lignin having certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having certain aliphatic hydroxyl content.

Abstract: A saccharide-solution producing apparatus 11A according to the present invention is a saccharide-solution producing apparatus for producing a saccharide solution 22 derived from a carbohydrate-based material 21, and includes a saccharide-solution controlling unit 15A that controls the saccharide solution derived from the carbohydrate-based material 21, a cellulosic biomass saccharifying unit 16 that saccharifies hydrothermally treated biomass obtained by hydrothermally decomposing a cellulosic biomass material 35 that contains a lignin component and a hemicellulose component, and produces a diluted saccharide solution 37, and a diluted-saccharide-solution supply pipe L11 that mixes the diluted saccharide solution 37 produced by the cellulosic biomass saccharifying unit 16 into the saccharide-solution controlling unit 15A. With this configuration, it is possible to improve production efficiency of the saccharide solution 22 and to realize cost reduction.

Abstract: The present invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The preparation method comprises: pulping a fibrous biomass, heating the biomass, maintaining the elevated temperature for 1 minute or longer, separating the cellulosic pulp to form a lignin-rich material, and recovering derivatives of native lignin. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.

Abstract: The method is for separation of lignin from original black liquor (BLIN) having the following phases in sequence; a first precipitation phase (PR1) for precipitation of lignin by a first acidification of the original black liquor by adding a first acid or mixture of acids (G1a); followed by a second precipitation phase (PR2) for precipitation of lignin by a further acidification of the original black liquor by adding a second acid or mixture of acids (G1b). The first phase is implemented to lower the pH while avoiding any larger amount of precipitation, i.e. less than 2-5%, while the second phase is implemented in order to obtain the larger part of the precipitation. In total is 40-70% of the total lignin content of the original black liquor precipitated while the residual black liquor after precipitation is still strongly alkaline.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes. The aqueous extract in embodiments including a water extract step is separated into acetic acid and hemicellulose sugar aqueous solutions.

Abstract: The present invention provides a process for fractionating lignocellulosic biomass, comprising: digesting a biomass feedstock in the presence of a solvent for lignin, an acid, and water, to produce cellulose-rich solids; separating and washing the cellulose-rich solids with a wash solvent; washing the cellulose-rich solids with water, to generate washed cellulose-rich solids and a wash liquor comprising fines, wherein the wash liquor is introduced to or in contact with a classifier to remove the fines; and separating the fines and recycling the remaining water. The classifier may include a screen with mesh size in the range of 10 to 500, such as 200. The washed cellulose-rich solids will typically have a lower Kappa number (lignin content) and ash content compared to cellulose-rich solids from a process without a classifier that removes fines.

Abstract: A method for the production of cellulose having a low lignin content characterized by a combination of the measures that a) a lignocellulosic material is treated with an aqueous solution comprising a C1-6-alcohol and having a pH from 10 to 14 at a temperature of below 100° C., whereupon the aqueous solution, in which lignin split off from the lignocellulose is present in dissolved form, is separated from the solid which represents a material enriched with cellulose and hemicellulose, b) hemicellulose is removed from the material of a) enriched with cellulose and hemicellulose, c) the material obtained in b), which is hemicellulose depleted, is treated with an alkali sulfite, an alkaline earth sulfite or ammonium sulfite, in particular Na2SO3 and/or with oxygen in aqueous alkaline solution, whereby lignin dissolves and cellulose having a low lignin content is obtained; as well as cellulose which can be produced by the method.

Abstract: The object of the present invention is to provide a method for producing fine fibers and a sheet containing fine fibers, whereby fiber refinement (fibrillating) of a fiber material is facilitated, freeness and dehydration performance of slurry containing fine fibers obtained after fiber refinement (fibrillating) is favorable and resistance to yellowing of the fine fibers is improved. The present invention provides a method for producing fine fibers, comprising at least the steps of: (a) introducing electrostatic and/or steric functional substituents into a fiber material to obtain substituent-introduced fibers; (b) subjecting the substituent-introduced fibers to mechanical treatment; and (c) eliminating some or all of introduced substituents from the substituent-introduced fine fibers obtained in step (b) to obtain fine fibers from which substituents have been eliminated.

Abstract: A method for treating a cellulosic material comprising extracting the cellulosic material with an extractant to selectively extract hemicellulose therein and separating the extracted hemicellulose to form a cellulosic product comprising less hemicellulose than the cellulosic material. The extractant comprises an amine oxide and a non-solvent. The cellulosic product retains the cellulosic fiber morphology.

Abstract: The present invention provides a process for fractionating biomass into its individual components. The process includes pretreating a biomass which may include mechanically altering the fibers and/or contacting the biomass with a solvent to provide a fluidized biomass. The pretreated fluidized biomass may be subjected to high frequency pulses and shear forces without denaturing one or more components of the biomass to provide a first liquid fraction and a first fractionated biomass. The first liquid fraction may then be isolated or separated from the first fractionated biomass. The biomass may be separated, isolated or purified into lignin, extractives for use in pharmaceuticals or nutraceuticals, cellulose, hemicellulose, and other sugars and proteins.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes. The aqueous extract in embodiments including a water extract step is separated into acetic acid and hemicellulose sugar aqueous solutions.

Abstract: A process of separating one or more components of corn fiber that comprises contacting the corn fiber with an extraction fluid that comprises at least one weak acid, increasing the temperature of the resulting mixture of fiber and fluid to solubilize hemicellulose of the corn fiber into the fluid, cooling the mixture, and separating the cooled extraction mixture into a soluble fraction comprising dissolved hemicellulose and an insoluble fraction comprising cellulose.

Abstract: A process for treating a cellulosic material comprising extracting the cellulosic material with an extractant to selectively extract hemicellulose therefrom and separating the extracted hemicellulose to form a cellulosic product comprising less hemicellulose than the cellulosic material. The extractant comprises a cellulose solvent and a co-solvent. The cellulosic product advantageously retains its cellulosic fiber morphology. The processes involve separating and recovering the hemicellulose and separating and recycling various process streams employed in the process.

Abstract: Methods are disclosed for preparing lignin from lignocellulosic biomass using rapid full or partial pressure reduction to separate and pulverize the lignin without fouling the equipment and with improved energy recovery.

Abstract: Method and apparatus for enhanced production of sugars and lignin via fractionation of lignocellulosic biomass through sequential ionic liquid pretreatment and mild alkaline treatment. The resulting biomass is easily fractionated and amenable to efficient and rapid hydrolysis and catalytic conversion to valuable products with high recovery of the enzymes used in the hydrolysis.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes. The aqueous extract in embodiments including a water extract step is separated into acetic acid and hemicellulose sugar aqueous solutions.

Abstract: Compositions comprising lignin and low levels of undesirable impurities, such as compounds containing sulfur, nitrogen, or metals, are disclosed.

Abstract: Methods and apparatus are provided for exploiting coated paper products such as coated paper cups. End products include biofuels that have a high energy density. The biofuels may be mixed with coal or other fuels and have good binding characteristics. In some embodiments, useful chemicals such as HMF are produced. The methods involve heat treatment at relatively mild temperatures and pressures under acidic conditions.

Abstract: At least one embodiment of the present inventions relates to a method of producing a softwood lignin derivative softwood lignin derivative. The method includes steps of pulping a fibrous biomass, heating the biomass, maintaining the elevated temperature for 1 minute or longer, separating the cellulosic pulp to form a lignin rich material, and recovering derivatives of native lignin wherein the derivatives have an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g. The derivatives can have a phenolic hydroxyl content of from about 2 mmol/g to about 8 mmol/g and a normalized RSI of 10 or greater. The method can be a kraft process or a modification thereof.

Abstract: The GreenBox+ technology is suitable to extract hemicellulose sugars prior to pulping of biomass into pulp products. The revenue obtainable from the sugar stream can significantly improve the economics of a pulp and paper mill. An initial extraction and recovery of sugars is followed by production of a pulp product with similar or better properties. Other co-products such as acetates and furfural are also possible. Some variations provide a process for co-producing pulp and hemicellulosic sugars from biomass, comprising: digesting the biomass in the presence of steam and/or hot water to extract hemicellulose into a liquid phase; washing the extracted solids, thereby generating a liquid wash filtrate and washed solids; separating the liquid wash filtrate from the washed solids; refining the washed solids at a refining pH of about 4 or higher, thereby generating pulp; and hydrolyzing the hemicellulose to generate hemicellulosic fermentable sugars.

Abstract: The GreenBox+ technology is suitable to extract hemicellulose sugars prior to pulping of biomass into pulp products. The revenue obtainable from the sugar stream can significantly improve the economics of a pulp and paper mill. An initial extraction and recovery of sugars is followed by production of a pulp product with similar or better properties. Other co-products such as acetates and furfural are also possible. Some variations provide a process for co-producing pulp and hemicellulosic sugars from biomass, comprising: digesting the biomass in the presence of steam and/or hot water to extract hemicellulose into a liquid phase; washing the extracted solids, thereby generating a liquid wash filtrate and washed solids; separating the liquid wash filtrate from the washed solids; refining the washed solids at a refining pH of about 4 or higher, thereby generating pulp; and hydrolyzing the hemicellulose to generate hemicellulosic fermentable sugars.

Abstract: Continuous transfer of particulate material into pressurized steam reactors is provided by “flow feeder” methods and devices. Material such as lignocellulosic biomass feedstocks are compacted into a “low density” plug, <700 kg/m3, which provides a dynamic seal against pressurized steam through exploitation of a steam condensation zone. The rate at which the steam condensation zone moves into the “low density” plug is offset by the rate at which compacted material is fed into the pressurized reactor. Preferred devices compact material within a flow feeder chamber by use of a loading device that works against counter-pressure provided by an unloading device. Compacted material is actively disintegrated and fed into the reactor by the unloading device. In preferred embodiments, compacted material is fed in a steady-state operation in which the interface between the steam condensation zone and the low pressure inlet zone remains stationary within the flow feeder chamber.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes. The aqueous extract in embodiments including a water extract step is separated into acetic acid and hemicellulose sugar aqueous solutions.

Abstract: A process for treating lignocellulosic biomass is described. The process includes treating particulate biomass with alkali to partially remove hemicellulose sheath on cellulose microfibrils of the biomass; and carrying out an oxidation reaction on the alkali treated biomass to form a treated biomass having a disrupted cellulose crystalline structure. The treated biomass may be further processed to form free sugars and lignin and the free sugars can be used to produce bio-ethanol or used as sugar source in fermentation processes.

Abstract: The invention relates to a process for producing a dissolving pulp from a cellulosic starting material using the kraft process, comprising the step of cooking the starting material with a cooking liquor. The process according to the invention characterized in that the starting material is exposed to a steam treatment prior to cooking and that the pulp obtained by cooking is subjected to cold caustic extraction (CCE) in the course of further processing.

Abstract: The present invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.

Abstract: The present invention provides derivatives of native lignin having certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having certain aliphatic hydroxyl content.

Abstract: The present disclosure relates to processes for recovery of derivatives of native lignin from lignocellulosic feedstocks wherein the derivatives have a certain aliphatic hydroxyl content. Surprisingly, it has been found that stable and predictable antioxidant activity is provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.

Abstract: A process of separating one or more components of corn fiber that comprises contacting the corn fiber with an extraction fluid that comprises at least one weak acid, increasing the temperature of the resulting mixture of fiber and fluid to solubilize hemicellulose of the corn fiber into the fluid, cooling the mixture, and separating the cooled extraction mixture into a soluble fraction comprising dissolved hemicellulose and an insoluble fraction comprising cellulose.

Abstract: The system is for the reception and transport of dry lime mud from a continuously operating pressurized filter in a causticization process. A tube valve is used as an outlet from the pressurized process. The tube valve has a minimum length that is twice a diameter of the tube. A column of lime mud can be held within it as a pressure lock. The column of lime mud can be caused to descend through the tube valve by controlling a difference in pressure between an inner surface and an outer surface of the tube such that the diameter of the tube expands essentially uniformly along its length by 5-10% or by at least 4-6 millimeters.

Abstract: A method and apparatus for the treatment of pulp mill condensates is described. A hollow fiber contactor, incorporating a hydrophobic membrane, was used to remove several undesirable compounds from pulp mill condensates. For example, TRS compounds and SO2 were efficiently stripped from kraft and sulphite mill evaporator condensates, respectively. Methanol was also removed from kraft mill condensates but at a lower efficiency than TRS. Furthermore, other undesirable compounds found in condensates of pulp mills that contribute to the BOD and COD loading to effluent treatment systems were also removed. These contactors are cost effective since air, vacuum or a suitable solvent or scrubbing solution can be used as the stripping medium to drive off through the membrane several undesirable compounds from the feed solution. The undesirable compounds removed can thus be burned in the recovery boiler, lime kiln or a dedicated boiler.

Abstract: An omnibus process of pulping and bleaching lignocellulosic materials in which a charge of a lignocellulosic material is biopulped and/or water extracted prior to pulping and bleaching. The lignocellulosic material may be mechanically pulped and bleached in the presence of an enzyme that breaks lignin-carbohydrate complexes. The aqueous extract in embodiments including a water extract step is separated into acetic acid and hemicellulose sugar aqueous solutions.

Abstract: A process for the production of ethanol from biomass is disclosed. The process relates to the pretreatment of corncob biomass and includes the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time. Volatile compounds are continuously vented during pretreatment. The reaction pressure is released for explosive decomposition of the corncob biomass into fibrous solids and condensate. The exposure is preferably carried out at a temperature of 190-210° C. and a pressure of 190 psig to 275 psig and an exposure time of 3 to 10 minutes.

Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process includes a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.

Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into one or more of a de-lignified cellulose stream, a sugar stream, small-chain alcohol streams and four structurally distinct classes of lignin derivatives. The modular process comprises a first processing module configured for digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for recovering small-chain alcohols and optionally a first class of lignin derivatives from the cellulosic solids fraction, a third processing module configured for recovering from the liquid fraction at least one of a second class and a third class of lignin derivatives or mixtures thereof, and waste stream comprising a fourth class of lignin derivatives. The fourth processing module may optionally recover the fourth class of lignin derivatives.

Abstract: The present invention relates to a liquid composition which comprises at least one polymer and at least one ionic liquid, the cations of which are derived from polycyclic amidine bases, and a process for isolating cellulose from cellulose-containing sources using at least one such ionic liquid.

Abstract: A process for refining and producing cellulose, lignin and xylose from biomass material comprises the following steps: pulverizing and screening the biomass material; and then dipping the biomass material in organic acid with lower boiling point and decomposing it into xylose, xylo-oligosaccharide, cellulose and lignin to make the biomass material fluidify; cooling the fluidified biomass material after finishing the reaction, adding organic solvent, and mixing uniformly and standing; separating, washing and drying the precipitation to obtain amorphous cellulose after precipitating; distilling the mother solution of precipitation of cellulose and recovering the organic acid and the resulting volatile organic substance; standing the distilled mother solution after cooling, and then separating, washing and drying the precipitation to obtain xylose and xylo-oligosaccharide after precipitating; distilling and recovering the organic solvent in the mother solution of precipitation of xylose and xylo-oligosaccharide,

Abstract: A method for preparing biomass for slurry processing. The method includes solubilizing the solid material into either a dissolved state or a suspended solid in a liquid phase, and treating the liquid phase to produce chemicals and fuels.

Abstract: A method and apparatus for the treatment of pulp mill condensates is described. A hollow fiber contactor, incorporating a hydrophobic membrane, was used to remove several undesirable compounds from pulp mill condensates. For example, TRS compounds and SO2 were efficiently stripped from kraft and sulphite mill evaporator condensates, respectively. Methanol was also removed from kraft mill condensates but at a lower efficiency than TRS. Furthermore, other undesirable compounds found in condensates of pulp mills that contribute to the BOD and COD loading to effluent treatment systems were also removed. These contactors are cost effective since air, vacuum or a suitable solvent or scrubbing solution can be used as the stripping medium to drive off through the membrane several undesirable compounds from the feed solution. The undesirable compounds removed can thus be burned in the recovery boiler, lime kiln or a dedicated boiler.

Abstract: The method and an arrangement are for dewatering and washing lime slurry before the dewatered lime mud is passed to a lime mud kiln. The lime slurry is dewatered in a pressurized lime mud filter of disc or drum type. The pressurized lime mud filter is pressurized through a compressor drawing on its suction side (s) gas phase from the filtrate tank and pressurizing on the pressurized side (p) of the compressor the pressure vessel on the lime mud side of the filter. A certain pre-determined amount of gas phase in the gas circulation system is vented and an equivalent pre-determined amount of fresh air is added to the recycled gas phase with the aim of maintaining the partial pressure of oxygen gas above a certain minimum level.

Abstract: The present invention pertains to methods for pretreatment of cellulosic biomass for bioconversion into ethanol and other biofuels and wood-based chemicals, recycling of newsprint and other paper products, microfibrillation of cellulose for use as an additive in the food and cosmetic industries, manufacturing improved hardboard, and producing and improved “super” pulp while reducing chemical usage and spent liquor generation. In particular, the instant invention employs supercritical, critical or near critical fluids with and without polar cosolvents [critical fluid, SuperFluids or SFS] for the pretreatment of cellulosic biomass.

Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into one or more of a de-lignified cellulose stream, a sugar stream, small-chain alcohol streams and four structurally distinct classes of lignin derivatives. The modular process comprises a first processing module configured for digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for recovering small-chain alcohols and optionally a first class of lignin derivatives from the cellulosic solids fraction, a third processing module configured for recovering from the liquid fraction at least one of a second class and a third class of lignin derivatives or mixtures thereof, and waste stream comprising a fourth class of lignin derivatives. The fourth processing module may optionally recover the fourth class of lignin derivatives.

Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process comprises a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.