Ester Type Patents (Class 162/164.7)
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Patent number: 8016980Abstract: A paper product includes a paperboard comprising a substrate layer, a filler layer, and a cap layer, wherein the filler layer is disposed between the substrate layer and the cap layer, wherein the filler layer includes a filler material, wherein the cap layer includes a polylactic acid based resin, and wherein the cap layer is substantially free of filler material.Type: GrantFiled: November 25, 2008Date of Patent: September 13, 2011Assignee: Dixie Consumer Products LLCInventors: Gregory Michael Fike, Joseph Robert Pounder
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Publication number: 20110180226Abstract: The present invention is directed to a method of treatment for paper or board including an oligoester, obtained by polycondensation of a) from 40 to 52 mol % of one or more dicarboxylic acids or esters thereof, b) from 10 to 40 mol % of ethylene glycol and/or propylene glycol, c) from 3 to 20 mol % of polyethylene glycol, d) from 0.5 to 10 mol % of a water-soluble addition product of from 5 to 80 mol of an alkylene oxide with 1 mol of C1-C24-alcohols, C6-C18-alkylphenols or C8-C24-alkylamines and e) from 0.4 to 10 mol % of one or more polyols having from 3 to 6 hydroxyl groups, wherein the oligoester is applied to a paper or board. The treated paper or board exhibits increased gluability and surface energy.Type: ApplicationFiled: January 22, 2010Publication date: July 28, 2011Applicant: CLARIANT INTERNATIONAL LTD.Inventors: Gordon GRAY, Patrick DAUPHIN
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Publication number: 20110114276Abstract: A method of improving a strength property of a sheet-formed fibrous material formed from an aqueous slurry of cellulose fiber, including coating at least one face of the material with a coating formulation including a polysaccharide containing at least two carboxylic groups and low molecular weight organic mono-, di- or poly-carboxylic acid in an aqueous carrier, keeping the coated face at a temperature of 50° C. or more for a time sufficient to obtain the desired improvement including drying of the material.Type: ApplicationFiled: April 2, 2009Publication date: May 19, 2011Applicant: OrganoClick ABInventors: Armando Córdova, Jonas Fredrik Hafrén, Karl Enquist, Joseph Samec
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Publication number: 20110108225Abstract: This invention relates to paper products and/or substrates suitable for being made and/or converted into wallboard tape; which also may be known as joint tape and/or drywall tape, having a pH of at least 7.0 and containing a plurality of cellulose fibers, a wet strength additive, an alkaline sizing agent, and an anionic promoter, as well as methods of making and using the same.Type: ApplicationFiled: August 19, 2010Publication date: May 12, 2011Applicant: INTERNATIONAL PAPER COMPANYInventors: STEPHEN A. BUZZA, DENNIS W. ANDERSON, YUFENG XU, BRUCE RICHARD MCGAFFIN, CHRISTOPHER MICHAEL WILSON
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Publication number: 20110088861Abstract: The invention provides a method of recovering and recycling waste coating color from papermaking coating process for use as wet end filler. The inventive method overcomes many technical challenges inherent in using waste coating colors as wet end filler such as the coatings having fine pigments that hurts sheet strength more than regular filler, having strong anionic charge and tendency to disturb wet end chemistry, causing excessive foaming, and containing a large amount of hydrophobic binder particles that tend to agglomerate in the white water and deposit on papermaking equipment. The method involves mixing the coatings with fresh filler particles, adding de-foaming agent, adding cationic coagulant, then preflocculating the mixture. This process causes fresh filler particles, pigments and binders in waste coating color to agglomerate together and form stable flocs with defined particle size distribution.Type: ApplicationFiled: December 22, 2010Publication date: April 21, 2011Inventor: Weiguo Cheng
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Publication number: 20110048660Abstract: Process for the production of paper, board and cardboard having high dry strength by separate addition of a water-soluble cationic polymer and of an aqueous dispersion of a water-insoluble polymer having a content of acid groups of not more than 10 mol % or of an aqueous dispersion of a nonionic polymer, which dispersion has been made anionic, to a paper stock, draining of the paper stock and drying of the paper products. Preferably, the polymers are added to a paper stock which has a temperature of at least 40° C.Type: ApplicationFiled: May 14, 2009Publication date: March 3, 2011Applicant: BASF SEInventors: Anton Esser, Hans-Joachim Haehnle
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Publication number: 20100314061Abstract: A method for manufacturing a sheet of paper from a pulp and a sheet of paper obtained by the present method, wherein said pulp comprises a mixture of natural and/or synthetic fibers, water, and at least one aqueous suspension and/or dispersion comprising at least one mineral material, wherein said dispersion or suspension comprises, as a steric dispersing agent of at least one mineral material, at least one copolymer comprising at least one vinylic monomer, at least one non-ionic monomer, or a mixture of several monomers having formula (I) in the present method, wherein said agent limits the presence of divalent ions in the aqueous phase and said agent is not a chelating agent.Type: ApplicationFiled: October 10, 2007Publication date: December 16, 2010Applicant: COATEX S.A.S.Inventors: Olivier Guerret, Francois Dupont, Jacques Mongoin
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Publication number: 20100279061Abstract: The present invention relates to a machine for fabricating a medium for abrasive-coated grinding material, wherein at least one continuous reinforcing element in the form of a tape or a yarn is introduced continuously during wet formation of the medium.Type: ApplicationFiled: November 26, 2008Publication date: November 4, 2010Applicant: Arjowiggins ArchesInventor: Thierry Mayade
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Publication number: 20100200185Abstract: To provide a papermaking internal sizing agent capable of efficiently imparting sizing performance even in neutral papermaking which uses calcium carbonate as filler, and uses no aluminum sulfate or uses a small amount of aluminum sulfate, and also provide a paper or a paperboard obtained by using the papermaking internal sizing agent. The papermaking internal sizing agent comprises as an effective ingredient an amphoteric copolymer having hydrophobic groups and cationic groups, at least a part of the cationic groups being quaternized. Preferably, the amphoteric copolymer is obtained by polymerizing monomer ingredients that it essentially contain a hydrophobic monomer (A), a cationic monomer (B), and an anionic monomer (C) and that an anion equivalent of the monomer (C) is 0.1 to 90% of a cation equivalent of the monomer (B), in which a rate of quaternizing of the cationic groups is not less than 40% by mole. The paper or the paperboard contains the above papermaking internal sizing agent.Type: ApplicationFiled: March 6, 2008Publication date: August 12, 2010Inventors: Kazunari Sakai, Takahiro Fujiwara, Kazushige Inaoka
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Publication number: 20100175845Abstract: The instant invention relates to storage stable aqueous optical brightener/PVOH solutions of low viscosity which may be used directly by the papermaker, in that they can be metered by pump directly into a coating composition, and which provide coated papers of a surprisingly high whitenessType: ApplicationFiled: July 24, 2007Publication date: July 15, 2010Applicant: Clariant Finance (BVI) LimitedInventors: Mariela Gauto, Andrew Clive Jackson, Alec Stewart Tindal
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Publication number: 20100126685Abstract: A paper product includes a paperboard comprising a substrate layer, a filler layer, and a cap layer, wherein the filler layer is disposed between the substrate layer and the cap layer, wherein the filler layer includes a filler material, wherein the cap layer includes a polylactic acid based resin, and wherein the cap layer is substantially free of filler material.Type: ApplicationFiled: November 25, 2008Publication date: May 27, 2010Applicant: Dixie Consumer Products LLCInventors: Gregory Michael Fike, Joseph Robert Pounder
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Publication number: 20100059191Abstract: A heat, grease, and cracking resistance release paper, said release paper is composed by 55% to 68% by weight of cellulose fiber, 3% to 6% by weight of one or more sizing agents, 27% to 37% by weight of one or more fillers, and 1% to 3% by weight of one or more binding agents.Type: ApplicationFiled: September 10, 2009Publication date: March 11, 2010Applicant: Copamex, S.A. De C.V.Inventors: ESTEBAN GARCIA MELGAREJO, FABIOLA RODRIGUEZ MATA
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Publication number: 20100051220Abstract: Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.Type: ApplicationFiled: August 28, 2009Publication date: March 4, 2010Applicant: INTERNATIONAL PAPER COMPANYInventors: Yaoliang Hong, Kosaraju Krishna Mohan, Peter M. Froass, Mark Fagan, Christopher D. Anderson, Brian Boyars, Eric Scott Daniels, Victoria Laurentia Dimonie, Edward David Sudol, Andrew Klein
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Publication number: 20100018660Abstract: Size press compositions and methods for producing sized paper products, including liner board, are disclosed. The size press compositions contain at least one non-reactive cationic surface sizing agent, at least one reactive sizing agent, at least one promoter resin, at least one binder, and water. The at least one non-reactive cationic surface sizing agent may be a polymer in the form of a dispersion, an emulsion or a latex with a positive zeta potential below about pH 6. The at least one reactive sizing agent may be a dispersion, an emulsion or a latex including an alkyl ketene dimer or an alkyl succinic anhydride. The at least one promoter resin may be a polyaminoamide-epichlorohydrin resin or poly (dimethyldiallylammonium chloride).Type: ApplicationFiled: July 24, 2008Publication date: January 28, 2010Applicant: Hercules Inc.Inventor: Daniel F. Varnell
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Publication number: 20100000694Abstract: The invention relates to a method for the production of flat paper products with increased relative wet tensile strength and softness from a pulp suspension in which a block copolymer is added to the pulp suspension and/or the paper product is treated during production thereof or subsequently with the block copolymer. The invention likewise relates to a paper product produced in this manner. Paper products of this type are used in particular as tissue products.Type: ApplicationFiled: July 30, 2007Publication date: January 7, 2010Applicants: FRAUNHOFER-GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG e.V., SCA HYGIENE PRODUCTS GMBHInventors: Joachim Storsberg, André Laschewsky, Stephan Eichhorn, Siegfried Stapel
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Publication number: 20090255641Abstract: A method of modifying the surface of a substrate which comprises a fibrous material. According to the present invention, the surface is brought into contact with a type of amphiphilic block copolymer which comprises one or several hydrophilic polymeric blocks and one or several hydrophobic polymeric blocks. Approximately 0.01-3 g/m2 of the amphiphilic block copolymer are applied onto the surface. With the help of the present invention, it is possible to effectively modify the surface of paper in such a manner that it produces a good surface for printing, for instance for ink-jet printing.Type: ApplicationFiled: December 1, 2006Publication date: October 15, 2009Applicant: Helsinki University of TechnologyInventors: Jukka Seppala, Arto Salminen
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Publication number: 20090188639Abstract: A water-soluble interjacent complex that includes a first water-soluble polymer and one or more water-soluble monomers polymerized to form a second water-soluble polymer in the presence of the first water-soluble polymer. The water-soluble interjacent complex forms a solution in water that is free of insoluble polymer particles. The interjacent complexes may be used to treat a waste sludge by adding an effective amount thereof to the waste sludge. The interjacent complexes may also be used in making paper by adding an effective amount thereof to a pulp or a forming sheet at a suitable location on a paper making machine. The interjacent complexes may further be used as a rheology modifier in aqueous systems by adding an effective amount thereof to an aqueous medium to effect a desired viscosity, rheology, or flow curve property.Type: ApplicationFiled: April 6, 2009Publication date: July 30, 2009Applicant: WSP CHEMICALS & TECHNOLOGY, LLCInventors: Shih-Ruey T. Chen, Valentino L. DeVito, Kevin W. Frederick
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Publication number: 20090139675Abstract: Finely divided, starch-containing polymer dispersions obtainable by emulsion copolymerization, with redox initiators, of ethylenically unsaturated monomers from the group consisting of (a) from 45 to 55% by weight of at least one optionally substituted styrene, methyl methacrylate, acrylonitrile and/or methacrylonitrile, (b) from 15 to 29% by weight of at least one C1-C12-alkyl acrylate and/or one C2-C12-alkyl methacrylate and (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer in an aqueous medium in the presence of (d) from 15 to 35% by weight of a degraded cationized starch which has a molar mass Mw of from 1000 to 65 000, the sum (a)+(b)+(c)+(d) being 100% and being based on the total solids content, processes for the preparation of such polymer dispersions by emulsion polymerization of the monomers (a), (b) and (c) in an aqueous medium with redox initiators in the presence of (d) cationic starch, and use of the starch-containing polymer dispersions as sizeType: ApplicationFiled: June 23, 2006Publication date: June 4, 2009Applicant: BASF AktiengesellschaftInventors: Hildegard Stein, Roland Ettl
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Publication number: 20090025894Abstract: Fibrous structures that exhibit a pore volume distribution such that greater than about 40% of the total pore volume present in the fibrous structure exists in pores of radii of from about 121 ?m to about 200 ?m, and methods for making such fibrous structures are provided.Type: ApplicationFiled: July 10, 2008Publication date: January 29, 2009Inventors: Steven Lee Barnholtz, Paul Dennis Trokhan, Michael Donald Suer
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Publication number: 20090014141Abstract: The specification discloses papers suitable for liquid electrophotographic printing (“LEP”) and a method for making such papers. According to the method, a papermaking furnish containing cellulosic fibers is formed into a fibrous web on a papermaking machine and at least partially dried. The web is then treated with a sizing composition comprising starch, an acrylic acid polymer, a polyglycerol ester, and water. The treated web is dried and calendered to a final desired caliper. Since the sizing composition is an aqueous mixture, it may be applied to the web on-line during production of the paper on the papermaking machine, thereby avoiding the expense and inconvenience of conventional off-line methods used to make existing LEP papers. The resulting paper exhibits at least 80% and preferably above 90% toner adhesion as measured by the tape pull tests used for the assessment of papers printed by LEP.Type: ApplicationFiled: July 14, 2008Publication date: January 15, 2009Inventors: Yan C. Huang, David B. Shelmidine, Jeffery R. Becker, Ernie L. Morgan
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Publication number: 20080314539Abstract: This invention relates to a process for preparing sized paper and paperboard which incorporates in the paper and paperboard at the size press size a composition comprising one or more “hydrophobic polymers” wherein hydrophobic polymers, the amount of such polymers and the weight ratio of starch to such polymer in the composition are selected such that the paper and paper board exhibits a Cobb Value equal to or less than about 25 and to a sized paper or paperboard web formed by the process.Type: ApplicationFiled: July 2, 2008Publication date: December 25, 2008Inventors: Richard Williams, Peter M. Froass, Sandeep Kulkarni
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Publication number: 20080302494Abstract: The present disclosure includes a regenerated cotton board material comprised of dry cut cotton lint fiber, and wood fiber. The regenerated cotton board material may further include non-cellulosic fibers such as synthetic fibers or other natural fibers. In an alternate embodiment, a cotton board material may be manufactured from a mixture of dry cut cotton lint fiber and a binder material. A method for forming a regenerated cotton board material according to the present disclosure includes forming an aqueous slurry fiber furnish from a combination of dry cut cotton lint fiber, and wood fiber. The fiber furnish is then wet processed, calendared to remove the bulk of the water, and dried.Type: ApplicationFiled: March 10, 2008Publication date: December 11, 2008Inventors: Kayren Joy Nunn, Marc Howard, Homan B. Kinsley
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Publication number: 20080110587Abstract: The present invention relates to surface sizing compositions, methods for making such compositions, processes for sizing paper products using such compositions, and paper products which have been sized with such compositions. In particular, the invention relates to novel surface sizing compositions comprising rosin-based component and styrene-carboxylic copolymer.Type: ApplicationFiled: November 13, 2006Publication date: May 15, 2008Inventors: Thomas M. Sisson, Camille K. Stebbins, Lourdes F. Gonzales
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Patent number: 6899921Abstract: A method for reducing back trap mottle of coated paper, comprising adjusting the absorbency of the coated surface combined with adjusting the adhesion between the coated paper surface and the ink. Polar additives are used in the paper coating to increase the polar fraction of the surface energy. The coated paper has a reduced sensitivity to back trap mottle.Type: GrantFiled: January 29, 2001Date of Patent: May 31, 2005Assignee: Sappi Maastricht B.V.Inventors: Jean Pierre Haenen, Maurice Essers
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Patent number: 6706147Abstract: The invention relates to a coated fiber mat of improved tear strength upon dividing pieces of the coated mat and the coating which comprises a cured, non-woven, fiber glass mat containing a polysiloxane wherein the fibers are fixedly distributed in a formaldehyde type binder containing a binder modifier which is a crosslinked styrene/acrylic polymer, and to a process for the preparation of the mat.Type: GrantFiled: December 9, 2002Date of Patent: March 16, 2004Assignee: Building Materials Investment CorporationInventors: Qinyun Peng, Krishna Srinivasan
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Patent number: 6500303Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: May 18, 2000Date of Patent: December 31, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Patent number: 6447644Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: October 10, 2001Date of Patent: September 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Publication number: 20020045722Abstract: Synthetic polymers having hydrogen bonding capability and one or more polysiloxane moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: ApplicationFiled: February 7, 2001Publication date: April 18, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6368456Abstract: This invention relates to paper comprising aldehyde modified cellulose pulp prepared using nitroxyl radical mediated oxidation and further containing selected additives comprising aldehyde functional polymers or polymers containing functionality capable of reacting with aldehyde groups and having improved strength properties. This invention further relates to paper made from aldehyde modified cellulose pulp where an hydroxyl group containing polymer is added to the paper to provide wet strength properties.Type: GrantFiled: December 3, 1999Date of Patent: April 9, 2002Assignee: National Starch and Chemical Investment Holding CorporationInventors: A. Levent Cimecioglu, John S. Thomaides, Kraig A. Luczak, Robert D. Rossi
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Patent number: 6361651Abstract: The wet strength softness absorbency, absorbency rate and other valuable properties in paper products, tissues, wipes, towels, etc. can be improved by using, in the paper forming process, a cellulosic material comprising a carboxymethyl cellulose material associated with a monomeric or polymeric cationic additive material. A process of the invention comprises a fiber surface carboxymethylation and an aqueous medium followed by blending the modified fibers with a cationic additive under varying conditions and wet forming the tissue and towel products. The additive is typically a cationic additive that preferentially associates with a carboxymethyl group on the cellulose surface. The affinity between the positively charged cationic groups in the polymeric or monomeric additive material to the negatively charged carboxyl group in the carboxymethyl cellulose modified fiber improves various attributes of the paper products.Type: GrantFiled: November 23, 1999Date of Patent: March 26, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Tong Sun
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Patent number: 6355137Abstract: A paper composition comprising: at least one cationic thermosetting resin comprising the reaction product of (i) at least one polyamide having secondary amine groups made from reactants comprising at least one polyalkylene polyamine, an acid component comprising succinic acid and optionally at least one dicarboxylic acid (other than succinic acid), and (ii) epihalohydrin. The paper is capable of being repulped substantially faster than paper that is substantially the same except that it contains conventional wet strngth resin.Type: GrantFiled: October 18, 2000Date of Patent: March 12, 2002Assignee: Hercules IncorporatedInventor: Ronald R. Staib
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Patent number: 6315824Abstract: The present invention relates to a stabilized emulsified or dispersed composition comprising a hydrophobic phase and an aqueous phase, the composition being stabilized by a cationic colloidal coacervate stabilizing agent, the coacervate stabilizing agent comprising an anionic component and a cationic component, the anionic and cationic components being present in a proportion such that the composition has a zeta potential of at least about 20 millivolts. The hydrophobic phase is preferably a non-rosin sizing agent, including a reactive or nonreactive sizing agent, although mixtures of rosin and non-rosin sizing agents can form stable emulsions or dispersions using the coacervate of the invention. Methods of making and using the stable emulsions or dispersions are also disclosed, as is sized paper made using an emulsified or dispersed sizing agent stabilized with the coacervate stabilizing agent of the invention.Type: GrantFiled: December 7, 1998Date of Patent: November 13, 2001Inventor: Rodrigue V. Lauzon
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Patent number: 6309509Abstract: This invention relates to compositions, paper, thermoplastic sheets, and medical paper containing cellulose ester, alkylpolyglycoside (APG) or a mixture of APG and polyether glycol, and, optionally, cellulose. The process of incorporating APG or a mixture of APG and polyether glycol in paper composed of cellulose ester fibers and cellulose fibers and to calendaring of such paper is also disclosed.Type: GrantFiled: October 11, 1996Date of Patent: October 30, 2001Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Eric Eugene Ellery, Matthew Davie Wood
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Patent number: 6306493Abstract: There is provided laser-markable paper and board products which include micronized polymers comprising of linear aromatic polyesters and/or of linear polyarylenes having a particle size of from 0.1 to 100 &mgr;m as absorber material and material for carbonization.Type: GrantFiled: July 30, 1998Date of Patent: October 23, 2001Assignee: Merck Patent GesellschaftInventor: Alexandra Brownfield
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Patent number: 6291127Abstract: The invention relates to an imaging member comprising at least one image layer and a base, said base comprising a cellulose paper that has its surfaces impregnated with water dispersible ester-based condensation polymer wherein the surface of said base has a roughness of less than 2.03 &mgr;m Ra and a hydrophobicity as measured by 40/20 Acid Valley test in excess of 500 seconds.Type: GrantFiled: August 23, 2000Date of Patent: September 18, 2001Assignee: Eastman Kodak CompanyInventors: Sandra J. Dagan, Suresh Sunderrajan, Charles E. Romano, Jr., Robert A. Guistina
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Patent number: 6254724Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: July 20, 1998Date of Patent: July 3, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Patent number: 6228223Abstract: The present invention generally relates to an aqueous softening and antistatic agent composition comprising a quaternary ammounium compound and a biodegradable nonionic surfactant, which composition comprises a quaternary ammounium compound having the formula wherein R1 is a C6-C22 hydrocarbyl group; and X is halogen or SO42−, in a concentration of at least about 15% by weight. The surfactant is a linear alkoxylated fatty acid or a linear alkoxylated unsaturated alcohol. Furthermore a method for providing cellulosic materials with a reduced tendency to retain an electrostatic charge as well as providing said material with improved softness, wherein the cellulosic material is treated with said composition, and fluff obtainable from fluff pulp treated with the composition.Type: GrantFiled: July 30, 1998Date of Patent: May 8, 2001Assignee: Akzo Nobel NVInventors: Ingemar Thebrin, Lisbeth Ankarbratt
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Patent number: 6210475Abstract: The present invention is directed to paper sizing emulsions, a method of making sizing emulsions, a method of sizing paper products, such as paper and board, and paper or board made using the method and the sizing emulsions of the invention. The paper sizing emulsions of the invention contains at least one sizing agent and a cationic liquid hydroxyalkylated starch that is pumpable and at least partially degraded. Typically, before dilution for mixing with the sizing material, the starch exists as a liquid in water and contains solids in an amount up to about 30 percent by weight, and has a viscosity of up to about 30,000 cps. The starch is diluted with water, before emulsifying the sizing agent to reduce the solids to an amount suitable for emulsification, and used to emulsify the sizing agent. The resulting emulsion can then be used to size paper and board.Type: GrantFiled: September 3, 1999Date of Patent: April 3, 2001Assignee: Bayer CorporationInventors: David L. Dauplaise, Robert Joseph Proverb, Katarzyna Komarowska
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Patent number: 6207014Abstract: The invention concerns in particular a composition for a softening lotion used in fiber treatment. In the invention, the lotion composition is aqueous and liquid at a temperature of at least 5° C. and comprises, as active substances: (a) one or more saturated linear fatty alcohols having at least 16 carbon atoms, and (b) one or more waxy esters having a total of at least 24 carbon atoms. The application of the invention is to the manufacture of fibrous products such as disposable absorbent paper products.Type: GrantFiled: September 10, 1998Date of Patent: March 27, 2001Assignees: Fort James France, Sidobre SinnovaInventors: Christian de Haut, Benoit Abribat, Maria Da Silva Marques, Bruno Bret, Jean-Francois Leboeuf
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Shaped, plastic articles comprising a cellulose fiber, a cellulose ester, and a non-ionic surfactant
Patent number: 6193841Abstract: This invention relates to compositions, paper, thermoplastic sheets, and medical paper containing cellulose ester, alkylpolyglycoside (APG) or a mixture of APG and polyether glycol, and, optionally, cellulose. The process of incorporating APG or a mixture of APG and polyether glycol in paper composed of cellulose ester fibers and cellulose fibers and to calendaring of such paper is also disclosed.Type: GrantFiled: November 30, 1998Date of Patent: February 27, 2001Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Eric Eugene Ellery, Matthew Davie Wood -
Patent number: 6179962Abstract: Process for making paper having improved strength characteristics by adding to the pulp water-soluble and/or water-dispersible cationic polymer and oxidized galactose type of alcohol configuration containing polymer.Type: GrantFiled: December 31, 1997Date of Patent: January 30, 2001Assignee: Hercules IncorporatedInventors: Richard Lee Brady, Raymond Thomas Leibfried, Sr., Tuyen Thanh Nguyen