Amine- Or Amide-aldehyde Patents (Class 162/166)
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Patent number: 7300545Abstract: A water-soluble polymer dispersion, process for producing the same and a method of use therefor. In particular, the water-soluble polymer dispersion is one comprising water-soluble polymer fine particles of 100 ?m or less diameter having at least one ionic property selected from among cationic, amphoteric, nonionic and anionic properties together with a polyalkyleneimine and/or a product of polyalkyleneimine modification wherein according to necessity an appropriate amount of water-soluble inorganic salt is incorporated. The provided process enables easily performing the production in dispersed form by means of production facilities of low cost. The obtained water-soluble polymer dispersion is excellent in storage stability and exhibits satisfactory fluidity and solubility so as to enable use in papermaking raw material pretreatments added to papermaking raw materials prior to machine operation and also for enhancement of freeness, increase of sizing degree and enhancement of yield.Type: GrantFiled: February 25, 2003Date of Patent: November 27, 2007Assignee: Hymo CorporationInventors: Takumi Ohara, Emiko Odaka, Ryousuke Yonemoto
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Patent number: 7172678Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8–C25 alkyl.Type: GrantFiled: June 17, 2003Date of Patent: February 6, 2007Assignee: GAF Materials CorporationInventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
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Patent number: 7144474Abstract: Fiber treated with an organic nonpolymeric binder is combined with superabsorbent particles in order to bind the particles to the fiber. The nonpolymeric organic binder comprises binder molecules that include at least one functional group capable of forming a hydrogen bond or a coordinate covalent bond with the particles and at least one functional group capable of forming a hydrogen bond with the fiber. The superabsorbent particles have a hydrogen or coordinate covalent bonding functional site. The binder serves to bind the particles to the fiber through formation of hydrogen and/or coordinate covalent bonds.Type: GrantFiled: August 15, 2000Date of Patent: December 5, 2006Assignee: Weyerhaeuser Co.Inventors: Michael R. Hansen, Richard H. Young, Sr.
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Patent number: 7090745Abstract: A composition includes at least one hydrophilic polymer containing primary (—NH2) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.Type: GrantFiled: September 23, 2002Date of Patent: August 15, 2006Assignee: University of PittsburghInventors: Eric J. Beckman, W. Eamon Carroll, Toby Chapman, Kristen E. Minnich, Dennis Sagl, Richard J. Goddard
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Patent number: 6998016Abstract: The present invention is a through-air-drying process for producing a fibrous web that possesses not only softness and absorbency but also strength. The method of the present invention monitors and controls the overall charge in the headbox.Type: GrantFiled: December 20, 2001Date of Patent: February 14, 2006Assignee: Fort James CorporationInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Patent number: 6840006Abstract: Accelerated degradation of mulching paper, formed from cellulose fibers impregnated with a hydrophobic resin to provide weather resistance, comprises spraying the paper with an enzyme solution which degrades both the resin and the cellulose.Type: GrantFiled: April 30, 2003Date of Patent: January 11, 2005Assignee: Ahlstrom Research & ServicesInventors: Joseph Dussaud, Léonie Bouvier
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Publication number: 20040256068Abstract: A composite sheet material, useful as a component of roofing shingles, and a process of making same, which includes a glass fiber web bound with a thermosetting resin which includes a fatty acid amide having the structural formula RCOONH2, where R is a C8-C25 alkyl.Type: ApplicationFiled: June 17, 2003Publication date: December 23, 2004Applicant: BUILDING MATERIALS INVESTMENT CORPORATIONInventors: V. Robert Canfield, Robson F. Storey, Betty C. Roberts
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Patent number: 6815497Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.Type: GrantFiled: February 2, 2000Date of Patent: November 9, 2004Assignee: Fort James CorporationInventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
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Patent number: 6812281Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, polyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as dialdehydes or zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.Type: GrantFiled: July 13, 2001Date of Patent: November 2, 2004Assignee: Fort James CorporationInventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
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Patent number: 6770169Abstract: A method for improving the balance of tensile strength and tear strength of cured urea formaldehyde (UF) resin-bound glass fiber nonwoven mats; the glass fiber nonwoven mats produced by the method, and a phosphate-containing binder composition useful in the method. The mats are useful in, for example, the manufacture of roofing shingles.Type: GrantFiled: March 8, 2001Date of Patent: August 3, 2004Assignee: Dow Reichhold Specialty Latex LLCInventor: Karen L. Wallace
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Patent number: 6743335Abstract: A method of reducing the level of malodorous amines emitted by paper when exposed to an alkaline environment is provided, which comprises making the paper so that it does not contain ammonium groups that are bonded to any polymer contained in the paper by only one chemical bond. Laminates which emit reduced levels of amines and which are comprised of this paper are also provided. In a preferred embodiment, the paper is sized with a sizing emulsion comprised of alkenyl succinic anhydride and a cationic water-soluble polymer having ammonium groups that are attached to the polymer by at least two chemical bonds.Type: GrantFiled: November 5, 2002Date of Patent: June 1, 2004Assignee: Bayer Chemicals CorporationInventors: Robert J. Proverb, Michael J. Scanlon
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Publication number: 20040079501Abstract: A method of making a spirally wound dry bonded paperboard structure. The method includes adding a radio frequency active adhesive to the paperboard pulp stock during the paperboard fabrication process to first produce an RF active adhesive impregnated paperboard. The impregnated paperboard is then exposed to an RF energy field prior to or during winding, which activates the adhesive. The invention eliminates the need to apply a water-based adhesive to the paperboard prior to forming the structure, thereby reducing water migration into the paperboard.Type: ApplicationFiled: October 23, 2002Publication date: April 29, 2004Inventors: Jeremy E. Morin, Krishnaraju Varadarajan
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Patent number: 6699359Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.Type: GrantFiled: February 2, 2000Date of Patent: March 2, 2004Assignee: Fort James CorporationInventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
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Patent number: 6699360Abstract: A process for the manufacture of single-ply, absorbent paper product, printed on before or after embossing on the Yankee side, air side, or both sides, having a serpentine configuration; low sidedness; a basis weight of at least about 12.5 lbs. per 3000 square foot ream; a specific total tensile strength between 40 and 200 g/3 inches/lb per 3000 square foot ream; a cross direction specific wet tensile strength between 2.75 and 20.0 g/3 inches/lb per 3000 square foot ream; an MD tensile to CD tensile ratio between 1.25 and 2.75; a specific geometric mean tensile stiffness between 0.5 and 3.2 g/inch/% strain per pound per 3000 square foot ream; a friction deviation of less than 0.250; a sidedness parameter of less than 0.30; and a printed sidedness value of &Dgr;E of less than 2.Type: GrantFiled: October 3, 2002Date of Patent: March 2, 2004Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Patent number: 6673205Abstract: The present invention uses hydrophobically modified polyaminamide with standard wet strength agent to produce a softer and more absorbent paper material. The hydrophobically modified polyaminamide is substantive to cellulosic fibers, thus is able to carry polyethylene glycol esters or ethers, a non-substantive material to cellulosic fiber as stable complexes, into the paper product.Type: GrantFiled: May 10, 2001Date of Patent: January 6, 2004Assignee: Fort James CorporationInventor: Bruce Jerome Kokko
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Patent number: 6666951Abstract: An improvement in the process for the production of articles from lignocellulosic material and a formaldehyde based resin binder comprising the step of treating the lignocellulosic material prior to combining it with the binder by exposing the lignocellulosic material to an acidic environment.Type: GrantFiled: April 10, 2001Date of Patent: December 23, 2003Inventor: Darren J. Kostiw
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Publication number: 20030070783Abstract: Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin with a solids content of at least 15 wt % treated with at least one enzymatic agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a gelation storage stable reduced CPD-forming resin so that the composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 24 hours at 50° C., and a pH of about 1.0 releases less than about 250 ppm dry basis of CPD for wet strength polyamine-epihalohydrin resin and less than about 100 ppm dry basis of CPD for creping polyamine-epihalohydrin resin.Type: ApplicationFiled: December 7, 2001Publication date: April 17, 2003Inventors: Richard James Riehle, Ronald Busink, Massimo Berri, Wim Stevels
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Patent number: 6517682Abstract: Method of inhibiting the deposit of sticky material on a papermill felt used in processing pulp slurry into sheets, comprising applying to the papermill felt at least one cationic polymer and at least one nonionic surfactant having an HLB of about 11 to 14.Type: GrantFiled: November 30, 2000Date of Patent: February 11, 2003Assignee: Hercules IncorporatedInventors: William A. Hendriks, Jeffrey R. Cowart
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Patent number: 6503370Abstract: Method of producing paper having a three-dimensional pattern of alternating raised and recessed portions which is given the paper in connection with impulse drying, at which the wet paper web is passed through at least one press nip (12) comprising a rotatable roll (13) which is heated and that the paper web when passing through the press nip is given a three-dimensional pattern either by means of a pattern wire (11) and/or by the fact that the heated roll (13) is provided with a three-dimensional pattern, and where the wet paper web (10) before entering said press nip (12) is given a basis weight variation in a non-random pattern.Type: GrantFiled: April 2, 2001Date of Patent: January 7, 2003Assignee: SCA Hygiene Products ABInventors: Holger Hollmark, Lennart Reiner, Thomas Billgren, Kaveh Tondkar, Mats Söderberg, Bengt Järrehult
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Patent number: 6500303Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: May 18, 2000Date of Patent: December 31, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Publication number: 20020195217Abstract: A method for retarding the deterioration rate of acidic paper is disclosed. The method includes placing an acidic paper article in a polymer film enclosure having a reservoir of deacidifying agent. The deacidifying agent migrates over time to the paper article in an amount sufficient to retard the deterioration rate of the paper. The method can further include placing in the polymer film enclosure a carrier material having a second reservoir of deacidifying agent. An article for retarding the deterioration rate of acidic paper is also disclosed. The article includes a polymer film enclosure having a reservoir of deacidifying agent. The polymer film enclosure is capable of enclosing an acidic paper article. The deacidifying agent is capable of migrating over time to the acidic paper article enclosed therein in an amount sufficient to retard the deterioration rate of the paper. The article can further include a carrier material having a reservoir of deacidifying agent.Type: ApplicationFiled: March 2, 2001Publication date: December 26, 2002Inventor: Ronald E. Johnson
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Patent number: 6494990Abstract: A paper or board is coated with a composition comprising from 30-95 parts by weight of a synthetic, carboxylated surface size containing at least about 40 mole percent of hydrophobic groups and at least about 25 mole percent of carboxylated groups such as styrene/acrylic acid copolymer, and from 5-70 parts by weight of a substantially hydrophilic polyacrylamide such as a cationic or anionic polyacrylamide.Type: GrantFiled: April 29, 1999Date of Patent: December 17, 2002Assignee: Bayer CorporationInventors: Rajiv Bazaj, Gerald Guerro, David Dauplaise
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Patent number: 6491790Abstract: A method of reducing the level of malodorous amines emitted by paper when exposed to an alkaline environment is provided, which comprises making the paper so that it does not contain ammonium groups that are bonded to any polymer contained in the paper by only one chemical bond. Laminates which emit reduced levels of amines and which are comprised of this paper are also provided. In a preferred embodiment, the paper is sized with a sizing emulsion comprised of alkenyl succinic anhydride and a cationic water-soluble polymer having ammonium groups that are attached to the polymer by at least two chemical bonds.Type: GrantFiled: May 27, 1999Date of Patent: December 10, 2002Assignee: Bayer CorporationInventors: Robert J. Proverb, Michael J. Scanlon
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Patent number: 6488812Abstract: A synthetic polymer having hydrogen bonding capability and containing a hydrophobic aliphatic hydrocarbon moiety can reduce lint and slough in soft tissue products while maintaining softness and strength.Type: GrantFiled: December 14, 2000Date of Patent: December 3, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Fu Chen
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Publication number: 20020139501Abstract: A modified polysaccharide having enhanced surface charge. The polysaccharide is modified to include a cationic polymer, preferably a polyquaternary amine, and has a surface charge from about +5 to about +20 mV. The modified polysaccharide can be advantageous incorporated into a papermaking furnish with enhanced retention.Type: ApplicationFiled: January 17, 2002Publication date: October 3, 2002Applicant: Weyerhaeuser CompanyInventors: Michael D. Vrbanac, Sherry L. Thomson
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Publication number: 20020134521Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.Type: ApplicationFiled: December 22, 2000Publication date: September 26, 2002Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Dana Stephanie Kass
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Publication number: 20020124980Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: ApplicationFiled: October 10, 2001Publication date: September 12, 2002Inventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Patent number: 6447644Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: October 10, 2001Date of Patent: September 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
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Publication number: 20020117279Abstract: An aqueous binder composition containing a urea-formaldehyde resin modified with an additive comprising (1) styrene acrylic acid or styrene acrylate, (2) an adduct of styrene, maleic anhydride, and an acrylic acid or acrylate or (3) a physical mixture of a styrene acrylic acid or styrene-acrylate copolymer and a styrene-maleic anhydride copolymer. The resulting binder is used in the preparation of fiber mats.Type: ApplicationFiled: December 22, 2000Publication date: August 29, 2002Inventors: Stacey L. Wertz, George J. Anderson, Kurt D. Gabrielson, John B. Hines, William S. King
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Publication number: 20020117280Abstract: A method and composition are disclosed for providing a two-part polymer binder additive for a fibrous sheet by improving both its strength and durability. The polymer binder comprises both the addition of a resin system and an anionic polymer which impart both increased strength and resistance to moisture and sagging. The resin system includes a polyamidoamine-epihalohydrin resin, a latex and an anionic polymer.Type: ApplicationFiled: July 27, 2001Publication date: August 29, 2002Inventors: Matthew Howle, Karl B. Himmelberger
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Patent number: 6441240Abstract: Ethyleneamine compound(s), or mixtures thereof, are used in effective amounts to reduce or inhibit the deposition of white pitch on the paper making equipment during the processing to recycle coated paper.Type: GrantFiled: September 20, 2000Date of Patent: August 27, 2002Assignee: Huntsman Ethyleneamines Ltd.Inventor: Alan P. Croft
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Publication number: 20020112836Abstract: This invention concerns a method of increasing retention and drainage in a papermaking furnish comprising adding to the furnish an effective amount of a structurally rigid polymeric coagulant and an effective flocculating amount of a flocculant and a microparticle.Type: ApplicationFiled: December 20, 2000Publication date: August 22, 2002Inventors: William J. Ward, Andrew J. Dunham
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Publication number: 20020112831Abstract: Disclosed is a composition for softening an absorbent tissue and tissue structures softened using the composition. The composition includes an effective amount of a softening active ingredient; a vehicle in which the softening active ingredient is dispersed; an electrolyte dissolved in the vehicle; a bilayer disrupter and a high polymer. The electrolyte and the bilayer disrupter cooperate to cause the viscosity of the composition to be less than the viscosity of a dispersion of the softening active ingredient in the vehicle alone. The high polymer adds “stringiness” to the composition opening the air pressure operating window for spray application of the softening composition.Type: ApplicationFiled: November 30, 2001Publication date: August 22, 2002Applicant: The Procter & Gamble CompanyInventors: Steven Lee Barnholtz, Kenneth Douglas Vinson, Paul Joseph Coffaro, Larry Neil Mackey, Amy Jo Hamilton, Errol Hoffman Wahl, Gayle Marie Frankenbach, Yenchun Wu
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Publication number: 20020100566Abstract: Paper comprised of suitable amounts of a hydroxy-phenoxyether polymer is effective to provide that paper with an increase in sizing or strength. Such paper may be prepared by intermixing dispersions or solutions of hydroxy-phenoxyether polymer with the pulp slurry or web during papermaking, or by application to formed paper. Paper may be coated or laminated by applying such dispersions or solutions.Type: ApplicationFiled: December 20, 2000Publication date: August 1, 2002Inventors: Robert A. Lee, Gerald Hutchinson, Basharat Ahmad Nazir, Charles P. Klass
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Publication number: 20020096283Abstract: This invention is to provide a paper bulking promoter with which a highly bulky sheet can be obtained without impairing paper strength.Type: ApplicationFiled: September 21, 2001Publication date: July 25, 2002Applicant: Kao Corporation.Inventors: Yasushi Ikeda, Yoichi Ishibashi, Takaaki Tadokoro, Hiromichi Takahashi
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Publication number: 20020096271Abstract: A process for de-watering lime mud in a Krafft pulping process is described. The process includes an improvement which comprises adding an effective water-removal rate enhancing amount of an alkyleneamine to the lime mud prior to filtration. The preferred alkyleneamine is ethyleneamine, that is, an amine having at least one —(CR2-CR2-NH—)— unit wherein each R is independently is H or an alkyl (straight-chain, branched, or cyclic) group of from about 1 to about 10 carbon atoms. Ethyleneamines include ethylenediamine, diethylenetriamine, triethylenediamine, triethylenetetramine, tetraethylenepentamine, piperazine, aminoethylpiperazine, and ethyleneamine mixtures such as mixtures of ethyleneamine oligomers having an average molecular weight of about 200-500.Type: ApplicationFiled: September 25, 2001Publication date: July 25, 2002Inventor: Alan P. Croft
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Publication number: 20020096281Abstract: Tissue paper having a bulk between 2 and 8 g/m3 and containing an amount of a wet strength agent, wherein the tissue paper contains a wet strength agent in the form of a nitrogen-containing polymer having hydrophobic side-chains. Said tissue paper before converting has a relative wet strength value (RWS) of at least 45%.Type: ApplicationFiled: May 18, 2001Publication date: July 25, 2002Inventors: Hans Wallenius, Sussan Sandberg, Marek Gorzynski, Oliver Struck
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Patent number: 6419789Abstract: The present invention is a through-air-drying process for producing a fibrous web that possesses not only softness and absorbency but also strength. The method of the present invention monitors and controls the overall charge in the headbox.Type: GrantFiled: October 11, 1996Date of Patent: July 16, 2002Assignee: Fort James CorporationInventors: Kang Chang Yeh, Gary L. Worry, Thomas N. Kershaw, Henry S. Ostrowski
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Publication number: 20020074098Abstract: Modified condensation polymers containing azetidinium groups, such as polyamide epichlorohydrin (PAE) resins, can be combined with amphiphilic hydrocarbons containing polyethers into a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength aids that impart softness; (b) softeners that do not reduce wet strength: (c) wet strength with improved wet/dry strength ratio; (d) surface feel modifiers with reduced linting and sloughing; (e) wet strength aids with controlled absorbency; (f) wet strength aids with controlled decay rate after wetting; and (g) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.Type: ApplicationFiled: October 31, 2001Publication date: June 20, 2002Inventors: Thomas Gerard Shannon, Mike Thomas Goulet, Daniel Arthur Clarahan, Wen Zyo Schroeder
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Publication number: 20020060012Abstract: The disclosure is directed to a method of using melamine resin fibers, to an insulating material comprisingType: ApplicationFiled: December 4, 2001Publication date: May 23, 2002Inventors: Heinz Berbner, Karl Ott
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Publication number: 20020053412Abstract: Condensation polymers, such as polyamide epichlorohydrin (PAE) resins, can be combined with polysiloxanes in a single molecule to provide several potential benefits, depending upon the specific combination employed, including: (a) wet strength resins that soften; (b) softeners that do not reduce dry or wet tensile strength; (c) wet strength with improved wet/dry tensile ratio; (d) softeners/debonders with reduced linting and sloughing; (e) wet strength aids with controlled absorbency rate; and (f) Yankee dryer additives that provide surface protection and adhesion with controlled release properties.Type: ApplicationFiled: February 7, 2001Publication date: May 9, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Patent number: 6365000Abstract: The present invention is a method of making an ultra soft, multi-ply tissue from non-premium furnish using wet press technology and the product produced thereby.Type: GrantFiled: December 1, 2000Date of Patent: April 2, 2002Assignee: Fort James CorporationInventors: John H. Dwiggins, Frank D. Harper, Galyn A. Schulz, Brian J. Schuh, Michael S. Heath, T. Philips Oriaran
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Patent number: 6361652Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6361653Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculent and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 26, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6361651Abstract: The wet strength softness absorbency, absorbency rate and other valuable properties in paper products, tissues, wipes, towels, etc. can be improved by using, in the paper forming process, a cellulosic material comprising a carboxymethyl cellulose material associated with a monomeric or polymeric cationic additive material. A process of the invention comprises a fiber surface carboxymethylation and an aqueous medium followed by blending the modified fibers with a cationic additive under varying conditions and wet forming the tissue and towel products. The additive is typically a cationic additive that preferentially associates with a carboxymethyl group on the cellulose surface. The affinity between the positively charged cationic groups in the polymeric or monomeric additive material to the negatively charged carboxyl group in the carboxymethyl cellulose modified fiber improves various attributes of the paper products.Type: GrantFiled: November 23, 1999Date of Patent: March 26, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Tong Sun
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Patent number: 6358364Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.Type: GrantFiled: April 22, 2001Date of Patent: March 19, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, James E. Whitten
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Patent number: 6355137Abstract: A paper composition comprising: at least one cationic thermosetting resin comprising the reaction product of (i) at least one polyamide having secondary amine groups made from reactants comprising at least one polyalkylene polyamine, an acid component comprising succinic acid and optionally at least one dicarboxylic acid (other than succinic acid), and (ii) epihalohydrin. The paper is capable of being repulped substantially faster than paper that is substantially the same except that it contains conventional wet strngth resin.Type: GrantFiled: October 18, 2000Date of Patent: March 12, 2002Assignee: Hercules IncorporatedInventor: Ronald R. Staib
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Patent number: 6331228Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting: a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.Type: GrantFiled: May 10, 2000Date of Patent: December 18, 2001Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Publication number: 20010030031Abstract: From about 50 to about 90% by weight of fibers, in particular wood fibers, and/or pellets made from cellulose or from wood, are mixed with from about 10 to about 50% by weight of a hot-curing resin, each of the percentages by weight being based on the total weight of the mixture. Instead of a single resin it is also possible to use a mixture made from two or more hot-curing resins. The mixture made from fibers and/or pellets and resin is kneaded and homogenized and then passed on to an extruder which has various heating zones in which the mixture is heated. Care has to be taken here that the maximum temperature, arising at the extruder exit, does not exceed about 120° C., since above this temperature the resin(s) begin(s) to cure.Type: ApplicationFiled: February 20, 2001Publication date: October 18, 2001Applicant: TRESPA INTERNATIONAL B.V.Inventor: Remco Cornelis Willemse
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Patent number: 6303002Abstract: Paper, board and cardboard are produced from paper stocks which contain tacky impurities by the addition of surfactants and cationic polymers having a charge density of at least 1.5 meq/g (measured at pH 7) and a molar mass Mw of the cationic polymers of at least 15,000 and drainage of the paper stocks with fixation of the tacky impurities in the paper produced.Type: GrantFiled: October 15, 1999Date of Patent: October 16, 2001Assignee: BASF AktiengesellschaftInventors: Friedrich Linhart, Jaroslav Melzer, Hubert Meixner