Cellulose Derivative (e.g., Cellulose Ester) Patents (Class 162/177)
  • Patent number: 6030443
    Abstract: A paper coating composition has therein an optical brightening agent (OBA) and a water-soluble non-ionic polysaccharide derivative, exhibiting a solution viscosity in water of less than 1500 cps when dissolved at 5% polymer concentration, wherein the paper coating provides improved optical brightness as compared to the same formulation without said non-ionic, polysaccharide derivative. A paper coated with this composition has an optical brightness value of greater than 70.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: February 29, 2000
    Assignee: Hercules Incorporated
    Inventors: Eric F. Bock, Charles L. Burdick, L. Drake Walsh
  • Patent number: 6030495
    Abstract: Novel substantially odor-free polymeric thiol-containing antioxidant compounds suitable for preventing light induced brightness reversion or yellowing of pulps and papers and polymeric materials are described. The novel compounds are based on a polymeric backbone having thiolactate or thioglycolate groups grafted onto the ends thereof and are soluble in water or alcohol.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: February 29, 2000
    Assignee: Queens's University at Kingston
    Inventors: Jeffrey K. S. Wan, M. Catherine Depew
  • Patent number: 6001165
    Abstract: A coating composition for a recording material and a process for producing the recording material are provided, wherein the coating composition includes an aluminum alkoxide, a binder and a hydrophilic solvent.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: December 14, 1999
    Assignee: Oji-Yuka Synthetic Paper Co., Ltd.
    Inventors: Nobuhiro Shibuya, Toshiyuki Hirabe, Koichi Asami, Masahiro Satoh, Hajime Kanbara
  • Patent number: 5997690
    Abstract: A smooth-textured non-woven, superabsorbent particle-impregnated fibrous structure is disclosed. The web exhibits an improved smooth surface texture. The structure contains from 50% to 80% of ion sensitive SAP having a particle size of less than 200 microns, wood pulp fibers and cellulose acetate fibers, each in preferred specified amounts indicated herein. The superabsorbent, ion sensitive polymer particle-impregnated fibrous structure is made from an aqueous, wet-lay process in which an aqueous furnish comprises solids of fibers and superabsorbent, ion sensitive polymer and dissolved salt, such as preferrably, Na.sub.2 SO.sub.4. The furnish is passed over a moving foraminous support, such as a Fourdrinier wire, and a wet web structure is formed, followed by drying.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: December 7, 1999
    Assignee: BASF Corporation
    Inventor: G. Thomas Woodrum
  • Patent number: 5993530
    Abstract: A thermally-decomposable, biodegradable resin composition is dispersed and stabilized in water optionally along with additives to give an aqueous dispersion of the resin composition. In the dispersion, the base polymer consists substantially of a water-insoluble starch-type, biodegradable resin. The dispersion is usable in various fields of papermaking, non-woven fabric production, film and sheet production and woven fabric production, in those of dispersed adhesive production, and in those of metal processing, plastic processing, wood processing and stone processing.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Japan Corn Starch Co., Ltd.
    Inventors: Hideyuki Tanaka, Nobuhiro Hosokawa, Nobuyuki Sugtura, Masato Takahara
  • Patent number: 5935384
    Abstract: A water-disintegrable paper which can be used in the same way as the ordinary toilet paper and shows excellent water disintegrability, wiping out property, feel, and moisture retaining property is provided, the water-disintegrable paper comprising: a water-disintegrable body paper; one or more components selected from glycerol, diglycerol, polyethylene glycol having an average molecular weight in a desired range, sorbitol, propylene glycol, 1,3-butylene glycol, glycine betaine, pyrrolidone carboxylic acid, pyrrolidone carboxylic acid salt, maltitol, and sodium lactate, as a humectant; and one or more components selected from sodium carboxymethylcellulose, a starch, a denatured starch, guar gum polyvinyl alcohol, and polyacrylamide, as a dry paper strength additive.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: August 10, 1999
    Assignee: Kawano Paper Co. Ltd
    Inventor: Kenji Taniguchi
  • Patent number: 5916420
    Abstract: The present invention relates to a thin printing paper with a weight per unit area in the range below 49 g/m.sup.2 and which contains wood and which is provided with surface pigmentation and which incorporates a mixture of a swellable coating silicate (sodium bentonite) and, for the remainder, conventional coating pigments as the pigment and which, in addition, contains only bonding agent that is a natural organic bonding agent, essentially starch. Even if only lightly calendered, the paper is equally well suited for rotogravure printing and for rotary offset printing. It is preferred that the paper also contain a proportion of processed fibres obtained from old-paper.
    Type: Grant
    Filed: September 12, 1995
    Date of Patent: June 29, 1999
    Assignee: Haindl Papier GmbH
    Inventors: Hartmut Wurster, Hans-Peter Hofmann
  • Patent number: 5873978
    Abstract: Provided is a recording paper having a feeling of plain paper suitable for ink jet recording with water-base ink, with the recording paper having in both machine and cross directions an irreversible shrinkage factor of from -0.10% to +0.10% when it is put under an environment that the relative humidity thereof is changed from 35% to 90% and further changed to 35%.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: February 23, 1999
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yoshihiro Kuroyama, Yoichi Yamazaki, Yasunori Nanri
  • Patent number: 5849155
    Abstract: The invention describes a method for dispersion of cellulose based fibers in water. The raw material, which particularly may be recycled paper, is first wetted with water. By a combination of addition of hydrocolloid which binds water, and strong kneading at high solid content, the mixture is transformed into a modulable paste. The high viscosity of the paste effectively conveys the shear forces of the kneading machine to make the fibers flexible and tear them apart. When the kneading is terminated, the hydrocolloid prevents the fibers from reassociation into fiber bundles.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: December 15, 1998
    Assignee: E. Khashoggi Industries, LLC
    Inventor: Stein Gasland
  • Patent number: 5849153
    Abstract: A water-dispersible sheet and a cigarette using the sheet are disclosed. The sheet comprises a water-resolvable base paper made from fibrous raw materials and a water-dispersible coating layer containing water-soluble polymer and an alkaline compound. The sheet is also produced through an impregnation treatment for a water-resolvable base paper with a coating mixture containing water-soluble polymer and an alkaline compound, wherein said water-resolvable base paper is made from a mixture of water-dispersible fibers and fibrous carboxymethyl cellulose acid or fibrous carboxyethyl cellulose acid. The gas-permeability of the water-dispersible sheet is controlled by the water-dispersible coating layer or the impregnation treatment.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: December 15, 1998
    Assignees: Mishima Paper Co., Ltd., Japan Tobaco Inc.
    Inventors: Yoshiaki Ishino, Masato Shishikura, Toru Tsujimoto, Susumu Minamisawa
  • Patent number: 5824190
    Abstract: Compositions containing hydrophilic polyacrylamide and hydrophobic surface size agents and the methods for using such compositions in paper and board to improve printability, sizing and strength are provided in the instant invention.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: October 20, 1998
    Assignee: Cytec Technology Corp.
    Inventors: Gerald Guerro, David Dauplaise, Rajiv Bazaj
  • Patent number: 5795439
    Abstract: The instant invention is directed to a process for making a non-woven, wet-laid, superabsorbent polymer-impregnated structure. The process generally comprises the steps of: mixing; deliquifying; and drying. Specifically, fibers, superabsorbent polymers, and a liquid are mixed to form a furnish. The liquid is treated with a means for inhibiting the swelling of the superabsorbent polymer. Then, the furnish is deliquified to form a preformed structure. The preformed structure is dried to form the non-woven, wet-laid, superabsorbent polymer-impregnated structure.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: August 18, 1998
    Assignee: Celanese Acetate LLC
    Inventors: Joanne M. Euripides, Lessie C. Phillips, Steven F. Nielsen
  • Patent number: 5770711
    Abstract: A derivatized polysaccharide in which at least a portion of the active hydrogens originally present in the polysaccharide are substituted by monovalent aliphatic groups containing at least two carboxylic acid groups to an extent sufficient to provide a degree of substitution of at least about 0.1. The monovalent aliphatic groups contain from 4 to about 10 carbon atoms. The polysaccharide may be cellulose. At least a portion of the carboxylic acid groups present in the derivatized polysaccharide may be crosslinked permanently or reversibly. The monovalent aliphatic groups containing at least two carboxylic acid groups may be derived from 2,3-epoxysuccinic acid; 1,2-epoxypropane-1,2,3-tricarboxylic acid; 2-(epoxyethyl)-succinic acid; or mixtures thereof. Also provided is a method of preparing a derivatized polysaccharide.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: June 23, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Sharon Linda Greene, Rosann Marie Kaylor, Kenneth Raymond Smith
  • Patent number: 5770528
    Abstract: The present invention is directed to a method of producing methylated hydroxypropylcellulose (m-HPC). By controlling the degree of methylation, one can manipulate the lower critical solution temperature (LCST) of the m-HPC polymer to below room temperature and thereby stabilize the polymer in water above about 30.degree. C. The present invention is also directed to binder compositions, fibrous substrates, water-dispersible products and thermoformable products containing the m-HPC polymer.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: June 23, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Pavneet Singh Mumick, Yihua Chang
  • Patent number: 5763009
    Abstract: Improved process for producing a support for recording material comprising the steps of calendering a base paper including 1.8%-10.0% water content under nip pressure from 400 kg/cm to 3000 kg/cm at the roller temperature from 10.degree. C. to 140.degree. C., and extusion coating the base paper with melted thermoplastic resin is proposed. The support produced by the process is superior in surface smoothness and glossiness. Upon using it for a recording material, excellent image with less unevenness can be obtained without using heat calendering at excessively high temperature after the coating.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: June 9, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadahiro Kegasawa, Kazuo Ozaki, Kunio Takahashi, Katsuhiko Takada
  • Patent number: 5651862
    Abstract: Described is a wet-formed composite. The wet-formed composite is formed from a combination of fibers and absorbent material. Specifically, the wet-formed composite is formed from absorbent material and a fiber slurry wherein the absorbent material is swellable in the dispersion medium of the slurry. Also disclosed is a method of forming the wet-formed composite. The method involves forming a fiber slurry, combining an absorbent material with the fiber slurry prior to forming the composite and then forming and drying the composite. The absorbent material is swellable in the dispersion medium of the fiber slurry.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: July 29, 1997
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard Allen Anderson, Richard John Schmidt
  • Patent number: 5635028
    Abstract: Soft creped tissue paper products comprising papermaking fibers and a crepe facilitating composition are disclosed. The crepe facilitating composition comprises a bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the bonding inhibitor is a quaternary ammonium compound. The use of a bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped papermaking process comprising the addition of the crepe facilitating composition is also disclosed. The crepe facilitating composition offers the potential to improve production capacity.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: June 3, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan
  • Patent number: 5632860
    Abstract: A method for controlling foam in the papermaking operation comprising a polyether surfactant and polyethoxylated sorbitol hexaoleate.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: May 27, 1997
    Assignee: BetzDearborn Inc.
    Inventors: William A. Hendriks, Daniel J. Barnett
  • Patent number: 5624532
    Abstract: Tissue paper having an enhanced bulk softness through incorporation of an effective amount of a polyhydroxy compound is disclosed. Preferably, from about 0.1% to about 2.0% of the polyhydroxy compound, on a dry fiber weight basis. These nonionic compounds have high rates of retention when applied to wet tissue paper webs according to the process described herein. Tissue embodiments of the present invention may further comprise a quantity of strength additive, such as starch, to increase paper strength.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: April 29, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Paul D. Trokhan, Dean V. Phan
  • Patent number: 5614062
    Abstract: A process for controlling the deposition of stickies from paper stock suspensions in papermaking involving the steps of: (a) providing a paper stock suspension containing stickies; and (b) contacting the stickies in the paper stock suspension with a native starch.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: March 25, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz-Guenther Schulte, Klaus Hornfeck, Dieter Kaps
  • Patent number: 5543459
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 6, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5538595
    Abstract: Tissue paper products comprising a two component chemical softener composition and binder materials, either permanent or temporary wet strength binders, and/or dry strength binders are disclosed. The two component chemical softening composition comprises an ester-functional ammonium compound and a polysiloxane compound. Preferred ester-functional ammonium compounds include diester dialkyl dimethyl ammonium salts such as diester di(touch hardened)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polysiloxanes include amino-functional polydimethyl polysiloxanes wherein less than about 10 mole percent of the side chains on the polymer contain an amino-functional group.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: July 23, 1996
    Assignee: The Proctor & Gamble Company
    Inventors: Paul D. Trokhan, Dean V. Phan, Ward W. Ostendorf, Joel K. Monteith, Bart S. Hersko, Robert S. Ampulski
  • Patent number: 5501771
    Abstract: Homogeneous and regular paper sheets are shaped, via conventional papermaking technique, from nonpolluting papermaking compositions comprising an aqueous suspension of cellulosic papermaking fibers that also include (a) an inorganic filler material, (b) a papersizing agent and (c) a ternary retention additive which comprises (c)(1) a cationic starch, (c)(2) a polyaluminum chloride and (c)(3) an anionic silica.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: March 26, 1996
    Assignee: Elf Atochem S.A.
    Inventor: Lucien Bourson
  • Patent number: 5494509
    Abstract: A paper coating composition is provided having a clay-containing pigment system, a binder, a polysaccharide thickener, and at least 0.005% to 2%, based upon the weight of the polymer, of a blocking agent that serves to prevent more than 25% of the polysaccharide thickener from being adsorbed onto the clay pigment surface. This coating is applied to raw paper for producing a high quality paper with smooth and substantially free of indentations surfaces for good ink to paper transfer.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: February 27, 1996
    Assignee: Aqualon Company
    Inventors: Dirk Kruythoff, Andre H. Van Waveren
  • Patent number: 5487813
    Abstract: Soft creped tissue paper products comprising papermaking fibers and a biodegradable crepe facilitating composition is disclosed. The crepe facilitating composition is a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the biodegradable bonding inhibitor is a biodegradable quaternary ammonium compound. The use of a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped paper process comprising the addition of the crepe facilitating composition is also disclosed. The composition offers the potential to improve production capacity.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: January 30, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan
  • Patent number: 5487419
    Abstract: A process for the production of and a composition of redispersible mechanically disassembled cellulose and the resultant product, referred to as microdenominated cellulose (MDC). The process is characterized by drying the MDC in the presence of a dispersion agent. The product is characterized by a settled volume of greater than 50%, as determined on the basis of a 1% by weight suspension in water after twenty-four hours, and a water retention value of over 350%. MDC is useful as an ingredient in foods, pharmaceutical and cosmetic products.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: January 30, 1996
    Assignee: Microcell, Inc.
    Inventor: Michael K. Weibel
  • Patent number: 5474856
    Abstract: A photographic printing paper support which comprises a raw paper coated with a film-forming resin on both sides; said raw paper being a paper made from paper stock comprising (i) cationic starch, (ii) polyamidepolyamine epichlorohydrin and (iii) an epoxidized higher fatty acid amide and/or an alkylketene dimer, and optionally (iv) a metal salt of carboxymethyl cellulose and/or an acrylamide/diallylamine salt copolymer, and being adjusted to pH 6.5-8.5 and controlled so as to have a zeta potential in the range of -10 mV to +5 mV.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: December 12, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigehisa Tamagawa, Shinichiro Serizawa, Jun Naitoh
  • Patent number: 5474545
    Abstract: An absorbent article, such as a disposable diaper, sanitary napkin or tampon is disclosed, wherein the absorbent material comprises grains and the absorbent layer is biodegradable. The invention also discloses a process of making the absorbent article.
    Type: Grant
    Filed: December 7, 1992
    Date of Patent: December 12, 1995
    Inventor: Osamu Chikazawa
  • Patent number: 5474655
    Abstract: The invention relates to a process for controlling the deposition of stickies from paper stock suspensions in papermaking. According to the invention, the deposition of stickies is controlled by addition of an effective quantity of a degradation product of native starch to the paper stock suspension.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: December 12, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz-Guenther Schulte, Klaus Hornfeck, Dieter Kaps
  • Patent number: 5464472
    Abstract: The present invention relates to a fine aqueous dispersion of an organophilic sheet silicate, consisting essentially of a sheet silicate capable of cation exchange and a quaternary organic onium salt reacted therewith, which dispersion comprises from 3 to 30% by weight, based on the organophilic sheet silicate, of a water-soluble, natural polymer and/or a derivative thereof.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: November 7, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ute Horn, Guido Dessauer
  • Patent number: 5437766
    Abstract: Multi-ply facial tissue paper products comprising biodegradable chemical softener compositions and a combination of a wet strength binder, either permanent and/or temporary, and a dry strength binder is disclosed.The multi-ply facial tissue paper products contain a biodegradable chemical softening composition comprising a mixture of a biodegradable quaternary ammonium compound and a polyhydroxy compound. The multi-ply facial tissue paper products also contain an effective amount of a wet strength binder, either permanent and/or temporary, and a dry strength binder to control linting and/or to offset the loss in tensile strength, if any, resulting from the use of the biodegradable chemical softening compositions. The use of both wet strength binder, either permanent and/or temporary, and dry strength binder also improves the retention of the chemical softening composition in the sheet.
    Type: Grant
    Filed: October 22, 1993
    Date of Patent: August 1, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Dean Van Phan, Paul D. Trokhan, Stephen R. Kelly, Ward W. Ostendorf, Bart S. Hersko
  • Patent number: 5397435
    Abstract: Multi-ply facial tissue paper products comprising chemical softener compositions and a combination of a wet strength binder, permanent and/or temporary, and a dry strength binder is disclosed.The multi-ply facial tissue paper products contain a chemical softening composition comprising a mixture of a quaternary ammonium compound and a polyhydroxy compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polyhydroxy compounds are selected from the group consisting of glycerol, polyglycerols having a weight average molecular weight of from about 150 to about 800, polyoxyethylene glycols and polyoxypropylene glycols having a weight average molecular weight from about 200 to 1000.
    Type: Grant
    Filed: October 22, 1993
    Date of Patent: March 14, 1995
    Assignee: Procter & Gamble Company
    Inventors: Ward W. Ostendorf, Stephen R. Kelly, Paul D. Trokhan, Dean V. Phan
  • Patent number: 5354424
    Abstract: A paper product treated with a degradation product of a polysaccharide derivative comprising a mixture of oligomers of the polysaccharide derivative, a majority of said oligomers having a degree of polymerization such that the oligomer conforms to a rod-like configuration.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: October 11, 1994
    Inventors: Chokyun Rha, Maritta Timonen
  • Patent number: 5349089
    Abstract: Cationic polysaccharide derivatives are prepared by reacting a polysaccharide with a polycationic reagent having one polysaccharide reactive group and at least two cationic groups. Suitable reagents include polycationic alkyl, aryl, alkaryl, cycloaliphatic, or heterocyclic amines, some of which are novel compositions. The polycationic polysaccharide derivatives prepared from these reagents are useful in the manufacture of paper.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: September 20, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Peter T. Trzasko, Michael T. Philbin
  • Patent number: 5338406
    Abstract: A polyelectrolyte complex comprising at least one water-soluble, linear, high molecular weight, low charge density cationic polymer having a reduced specific viscosity greater than 2 deciliters/gram (at 0.05 weight % in a 2M NaCl solution at 30.degree. C.) and a charge density of 0.2 to 4 milliequivalents/gram (meq/g), and at least one water-soluble, anionic polymer having a charge density less than 5 meq/g, an aqueous system comprising the polyelectrolyte complex, a composition comprising the polymers which form the polyelectrolyte complex, and paper comprising the polyelectrolyte complex. It is also directed to a process comprising (1) forming an aqueous suspension of cellulosic fibers; (2) adding a strengthening additive so that the aforementioned polyelectrolyte complex is incorporated into the aqueous suspension of cellulosic fibers; and (3) sheeting and drying the fibers to form the desired cellulosic web.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: August 16, 1994
    Assignee: Hercules Incorporated
    Inventor: Douglas C. Smith
  • Patent number: 5334287
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: August 2, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5316623
    Abstract: A method for imparting wet strength to paper with improved water absorbency, that comprises adding to an aqueous suspension of cellulosic paper stock a neutral or alkaline-curing thermosetting wet-strength resin, a water-soluble polymer containing carboxyl groups or carboxylate ions as their alkali metal or ammonium salts, and a substantially non-thermosetting tertiary-amino polyamide-epichlorohydrin resin.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: May 31, 1994
    Assignee: Hercules Incorporated
    Inventor: Herbert H. Espy
  • Patent number: 5308663
    Abstract: A biodegradable nonwoven fabric and molded vessel suitable to throwaway use such as in domestic, wrapping, agricultural, gardening, and civil engineering field. A web of cellulose-based fibers are combined with chitosan salt and an interfiber binder comprising a combination of chitosan salt and fine cellulose, or by combined use of the interfiber binder and physical combining techniques. They are naturally decomposed by microorganisms in the soil and can dissolve the polution problems.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: May 3, 1994
    Assignees: Kanai Juyo Kogyo Company Limited, Director, General of Agency of Industrial Science and Technology
    Inventors: Mutuo Nakagawa, Yasuo Nakagawa, Masaaki Nishida, Jun Hosokawa, Masashi Nishiyama, Takamasa Kubo, Kazutoshi Yoshihara
  • Patent number: 5302249
    Abstract: A paper comprised of a supporting substrate with a coating comprised of a desizing component and a hydrophilic polymer, and more specifically in an embodiment the paper is comprised of a paper comprised of a supporting substrate treated with desizing agents selected from the group consisting of (1) hydrophilic poly(dialkylsiloxanes); (2) poly(alkylene glycol); (3) poly(propylene oxide)-poly(ethylene oxide) copolymers; (4) fatty ester modified compounds of phosphate, sorbitan, glycerol, poly(ethylene glycol), sulfosuccinic acid, sulfonic acid and alkyl amine; (5) poly(oxyalkylene) modified compounds of sorbitan esters, fatty amines, alkanol amides, castor oil, fatty acids and fatty alcohols; (6) quaternary alkosulfate compounds; (7) fatty imidazolines; and mixtures thereof.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: April 12, 1994
    Assignee: Xerox Corporation
    Inventors: Shadi L. Malhotra, David F. Rutland, Arthur Y. Jones
  • Patent number: 5292403
    Abstract: A method of inhibiting the deposition of organic contaminants in a pulp and papermaking system comprising adding to the system an effective amount of a detackifying composition comprising a charged polymer and an oppositely charged surfactant, with the proviso that at least the polymer or the surfactant be surface active.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: March 8, 1994
    Assignee: Betz PaperChem, Inc.
    Inventors: David D. Dreisbach, Mark E. Laurint
  • Patent number: 5281306
    Abstract: A water-disintegrable cleaning sheet comprising a web of water-dispersible fibers having incorporated thereinto a water-soluble binder having a carboxyl group; at least one metallic ion selected from the group consisting of ions of alkaline earth metals, manganese, zinc, cobalt, and nickel; and an aqueous cleaning agent containing an organic solvent, is disclosed. The sheet satisfies both water disintegrability and strength even when cotained a cleaning agent of high water content.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: January 25, 1994
    Assignee: Kao Corporation
    Inventors: Shusuke Kakiuchi, Makoto Ishii, Atsuo Nakae, Seiko Ikoma
  • Patent number: 5275698
    Abstract: A process for making paper to enhance the softness of the paper produced without reducing its dry strength comprises adding to the pulp slurry as a binder resin a cellulosic polymer that exhibits a cloud point in aqueous solution, and allowing the dissolved polymer to coalesce into fine colloidal particles at a temperature above the cloud point either before or after it is added to the slurry.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: January 4, 1994
    Assignee: Hercules Incorporated
    Inventors: Sunil P. Dasgupta, Herbert H. Espy
  • Patent number: 5238534
    Abstract: A method for the production of a fibrous web having textile length fibers wherein a fiber furnish is formed by dispersion of the fibers in an unfoamed carrier medium of water and an associative thickener of ethylene oxide base urethane block copolymers or hydroxyethylcellulose ethers having a C.sub.10 to C.sub.24 alkyl side chain in an amount within the range of from about 1 to about 150 pounds of thickener per ton of dry fiber and including an anionic viscosity modifier in the range of 10 to 500 ppm. The furnish having a consistency in the range of 0.05 to 0.2 weight percent fibers is supplied to a high speed papermaking machine for forming a fibrous web. The textile length fibers may be polyester fibers being 1.5 denier and 3/4 inches. The high speed papermaking machine may be a twin-wire papermaking machine or a suction breast roll papermaking machine or a crescent former papermaking machine.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: August 24, 1993
    Assignee: James River Corporation of Virginia
    Inventors: James H. Manning, Irwin M. Hutten
  • Patent number: 5153317
    Abstract: A composition and its method of use are disclosed for controlling rheology of an aqueous dye, which composition comprises 1-30 parts of a gum selected from the group consisting of xanthan gum, rhamsan gum, welan gum and mixtures thereof and 70-99 parts of a water soluble polysaccharide having aliginate equivalent rheology, preferably an alginate. Also disclosed is a color imparting composition for fabric or carpet printing which comprises 99-99% of an aqueous dye component and 1-10% of the rheology control component. The polysaccharide is preferably an alginate, starch, cellulosic polymer or guar gum or mixtures thereof.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: October 6, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Theresa M. Ortega, Philip E. Winston, Jr., Kenneth Clare
  • Patent number: 5112445
    Abstract: Surface sizes comprising 1) gellan gum and 2) one or more film-forming polymers such as chemically modified starch, cellulose derivatives, and polyvinyl alcohol are described. The compositions exhibit enhanced film-forming properties.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: May 12, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Philip E. Winston, Jr., Harold D. Dial, Kenneth Clare, Theresa M. Ortega
  • Patent number: 5102502
    Abstract: A process for the manufacture of highly compressed paper containing synthetic fibers with a volume weight of equal to or greater than 0.9 kg/dm.sup.3 whereby the paper sheet which comprises a mixture of cellulose and thermoplastic synthetic fibers in the ratio of 50:50 to 90:10 with a degree of grinding of 35 to 75 SR, is treated with sizing, retention and wetting agents and, if applicable, filler materials and is sized on the surface. Subsequently during a separate operational stage the sheet is subjected to a glaze finishing at surface temperatures of the calender rollers of equal to or greater than 100.degree. C. and linear roller pressures equal to or greater than 30 Kn/m.
    Type: Grant
    Filed: June 13, 1990
    Date of Patent: April 7, 1992
    Assignee: Kammerer GmbH
    Inventors: Bernd Reinhardt, Leif Frilund, Volker Viehmeyer
  • Patent number: 5079348
    Abstract: A film forming composition useful as a paper size is described which includes 1-20 parts, preferably 2-15 parts, by weight of a gum selected from the group consisting of xanthan gum, rhamsan gum, welan gum and mixtures thereof; 3-20 parts, preferably 5-17 parts, by weight of a water soluble alginate; and 60-100 parts, preferably 70-90 parts, by weight of starch, polyvinyl alcohol or carboxymethylcellulose, with the gum:alginate ratio being not greater than 1:1, preferably not greater than 1:2. The balance of the composition will primarily be water. Additives such as sodium hexametaphosphate may also be present.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: January 7, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Kenneth Clare, Philip E. Winston, Jr., Harold D. Dial, Theresa M. Ortega
  • Patent number: 5074961
    Abstract: The invention is a process for controlling pitch deposition from pulp in papermaking systems, by an effective amount of a polymer having methyl ether groups pendant to the backbone of the polymer to the pulp term "polymer". A preferred embodiment of the invention is controlling pitch deposition by adding an effective amount of a water soluble cellulose ether.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: December 24, 1991
    Assignee: Betz Laboratories, Inc.
    Inventors: David D. Dreisbach, Gilbert S. Gomes
  • Patent number: 5004791
    Abstract: Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch--O--(G).sub.m --(M)--.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: April 2, 1991
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Robert L. Billmers
  • Patent number: 4973641
    Abstract: A polysaccharide graft copolymer containing a reactive aminoethyl halide group is provided, said copolymer represented by:Sacch--g--(M).sub.a --(T).sub.bwhere Sacch is a polysaccharide base substrate, M is a repeating unit of the formula: ##STR1## where X is halogen and R is hydrogen or alkyl of 1 to 2 carbons; T is an ethylenically unsaturated comonomer, a is at least 1 and b is 0 or 1 or more, with the total of a and b being at least 2.Another embodiment provides preparing this graft copolymer by reacting the monomer in a system that is maintained at a pH level of below 7 to prevent premature reaction of the halogen on the aminoethyl halide group during the grafting procedure.
    Type: Grant
    Filed: November 18, 1988
    Date of Patent: November 27, 1990
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John J. Tsai, Eric A. Meier