Sulfate Or Sulfite Patents (Class 162/181.3)
  • Patent number: 11268241
    Abstract: The present invention provides a method for reducing web break caused in preparing, by continuous paper making, a fiber sheet containing a high content of functional inorganic substance. The composite fiber sheet manufacturing method includes: generating composite fibers composed of cellulosic fibers and inorganic particles by synthesizing the inorganic particles in slurry containing the cellulosic fibers; and continuously generating a sheet by supplying composite-fiber-containing slurry including the composite fibers to a continuous paper machine. In the composite fiber generating step, at least one of (i) slurry containing cellulosic fibers having a length of 1.2 mm to 2.0 mm in an amount of 16% or more in terms of length-weighted fiber length distribution (%) and (ii) slurry containing cellulosic fibers having a length of 1.2 mm to 3.2 mm in an amount of 30% or more in terms of length-weighted fiber length distribution (%) is used.
    Type: Grant
    Filed: March 19, 2018
    Date of Patent: March 8, 2022
    Assignee: NIPPON PAPER INDUSTRIES CO., LTD
    Inventors: Ayaka Hasegawa, Moe Fukuoka, Masatoshi Oishi, Koji Ninagawa, Toru Nakatani, Shisei Goto
  • Patent number: 11015295
    Abstract: A method of making paper is described. The method includes providing a cellulosic fibrous material, the cellulosic fibrous material comprising a plurality of elongated fibers having a fiber wall surrounding a hollow interior, the fibrous material having moisture content. The method also includes adding calcium bicarbonate solution to the cellulosic fibrous material to form a pulp mixture, the calcium bicarbonate solution containing up to the saturation level of about 16% solids of calcium bicarbonate, the resulting pulp mixture having between 0.1% to 65% total solids by weight. Further, the method includes refining the pulp mixture such that at least some of the calcium ions become associated with the reactive sites in the fiber walls. Further still, the method includes forming a web from the pulp mixture and wet pressing the web.
    Type: Grant
    Filed: November 12, 2019
    Date of Patent: May 25, 2021
    Inventor: John H. Klungness
  • Patent number: 10011528
    Abstract: There are provided gypsum panels, sheets and multi-layer sheets as well as methods of preparation thereof. For example, there are provided cellulose filament-reinforced gypsum panels, sheets and multi-layer sheets and methods of preparation thereof. For example, in such gypsum panels, sheets and multi-layer sheets gypsum is bound with cellulose filaments to strengthen the gypsum panels, sheets and multi-layer sheets. The cellulose filament-reinforced gypsum panel can be, for example, a core comprising a honeycomb or corrugated structure. There are also provided aqueous suspensions comprising cellulose filaments and CaSO4.2H2O.
    Type: Grant
    Filed: October 6, 2015
    Date of Patent: July 3, 2018
    Assignee: FPINNOVATIONS
    Inventors: Gilles Dorris, Yuxia Ben, Qiaozhi An, Annie Dorris, Xiaoyu Wang
  • Patent number: 9190046
    Abstract: The present invention relates to a sound absorbing sheet having excellent sound absorbing performance and surface decorative effects. The sound absorbing sheet of the present invention is characterized by comprising a base and having an average sound absorption of 0.4 or higher in a frequency range of 200 to 2000 Hz. The permeability and air porosity of a base layer of the sound absorbing sheet of the present invention may be adjusted, thereby achieving significantly superior effects of sound absorbing performance despite the thinness of the sound absorbing sheet.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: November 17, 2015
    Assignee: LG HAUSYS, LTD.
    Inventors: Gil Ho Kang, Seong Moon Jung, Ju Hyung Lee, Joo Hwan Seo
  • Publication number: 20150122429
    Abstract: A method for the production of cellulose having a low lignin content characterized by a combination of the measures that a) a lignocellulosic material is treated with an aqueous solution comprising a C1-6-alcohol and having a pH from 10 to 14 at a temperature of below 100° C., whereupon the aqueous solution, in which lignin split off from the lignocellulose is present in dissolved form, is separated from the solid which represents a material enriched with cellulose and hemicellulose, b) hemicellulose is removed from the material of a) enriched with cellulose and hemicellulose, c) the material obtained in b), which is hemicellulose depleted, is treated with an alkali sulfite, an alkaline earth sulfite or ammonium sulfite, in particular Na2SO3 and/or with oxygen in aqueous alkaline solution, whereby lignin dissolves and cellulose having a low lignin content is obtained; as well as cellulose which can be produced by the method.
    Type: Application
    Filed: April 24, 2013
    Publication date: May 7, 2015
    Applicant: ANNIKKI GMBH
    Inventors: Alexander Dybov, Florian Boeck
  • Patent number: 8974636
    Abstract: A fluff pulp or other pulp, comprises a multivalent cationic metal ion selected from the group consisting of Al+3, B+3, Mn+2, Cu+2, Cu+3, Zn+2, Sn+2, Sn+4, water-soluble salt thereof, or combination thereof; an amine-containing anti-static agent; and pulp. Methods of making and using the pulp, as well as articles therefrom, are provided.
    Type: Grant
    Filed: June 13, 2013
    Date of Patent: March 10, 2015
    Assignee: International Paper Company
    Inventors: James E. Sealey, Peter M. Froass, Sylvie Marie Rita Carriere
  • Publication number: 20150041085
    Abstract: One aspect of the invention relates to a pulp composition made from agricultural renewable fibers (ARF) having low Kappa number with unexpected quality sufficient for papermaking (e.g., high strength parameters and high freeness). Another aspect of the invention relates to an ARF pulp having ISO brightness of 60% or higher, and unexpected quality sufficient for papermaking (e.g. high strength parameters and high freeness). Another aspect of the invention relates to a pulp composition made from a pulping process comprising using a high concentration of anthraquinone (AQ). The pulping process can use wood or nonwood fibers (e.g., bagasse and corn stover) to provide pulp having good paper-making quality.
    Type: Application
    Filed: October 23, 2014
    Publication date: February 12, 2015
    Inventors: Brent A. Hawkins, Fred Martin
  • Publication number: 20150041087
    Abstract: One aspect of the invention relates to an article of manufacture made from a pulp composition comprising an ARF pulp. In one embodiment, the pulp composition made from agricultural renewable fibers (ARF) having low Kappa number with unexpected quality sufficient for papermaking (e.g., high strength parameters and high freeness). In another embodiment, the ARF pulp has ISO brightness of 60% or higher, and unexpected quality sufficient for papermaking (e.g. high strength parameters and high freeness). In another embodiment, the ARF pulp is made from a pulping process comprising using a high concentration of anthraquinone (AQ).
    Type: Application
    Filed: October 23, 2014
    Publication date: February 12, 2015
    Inventors: Brent A. Hawkins, Fred Martin
  • Patent number: 8926797
    Abstract: Process for the production of paper, board and cardboard having high dry strength by addition of (a) at least one trivalent cation in the form of a salt, (b) at least one water-soluble cationic polymer and (c) at least one water-soluble amphoteric polymer to the paper stock, draining of the paper stock with sheet formation and subsequent drying of the paper products, the water-soluble cationic polymer (b) being selected from the group consisting of the (i) polymers comprising vinylamine units and (ii) polymers comprising ethylenimine units.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: January 6, 2015
    Assignee: BASF SE
    Inventors: Christian Jehn-Rendu, Ellen Krueger, Hans-Joachim Haehnle, Martin Ruebenacker, Norbert Schall, Thomas Muehlenbernd
  • Patent number: 8871058
    Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: October 28, 2014
    Assignee: International Paper Company
    Inventors: James E. Sealey, Brent A. Fields
  • Patent number: 8840760
    Abstract: The object of the process of the invention is to increase the retention of starch in the sheet of paper in order to reduce operating costs and increase the physical characteristics of the paper. To that end, it has been envisaged that trivalent cationic salts are added, metered into the slurry or in the process for obtaining starch in powder form or by mixing a percentage of trivalent salts in powder form with the starch in powder form, seeking the solution of said salts in the slurry, so that they dissolve during the dispersion of the slurry in the process for obtaining the sheet of paper. Organic polymers such as polyacrylamides, polyvinylamides and polydadmacs could optionally be applied in addition to said salts.
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: September 23, 2014
    Assignee: Oriol Gracia Grandia
    Inventor: Oriol Gracia Grandia
  • Patent number: 8834680
    Abstract: The present invention relates to a filler composition comprising a) a filler, b) a cationic inorganic compound, c) a cationic organic compound, and d) an anionic polysaccharide, wherein the filler is present in an amount of at least about 1% by weight, based on the total weight of the composition, the anionic polysaccharide is present in an amount of about 1 to about 100 kg/ton, based on the weight of filler, and wherein the composition is substantially free from fibers.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: September 16, 2014
    Assignee: AKZO Nobel N.V.
    Inventors: Patrik Simonson, Michael Persson
  • Patent number: 8747617
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of a first flocculating agent to an aqueous dispersion of filler particles followed by shearing of the dispersion, followed by addition of a second flocculating agent to the dispersion and further shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution. In addition, a neutralizing coagulant can be added to the dispersion to partially or completely neutralize the charge of the filler before the first flocculating agent is added.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: June 10, 2014
    Assignee: Nalco Company
    Inventors: Weiguo Cheng, Ross T. Gray
  • Patent number: 8673117
    Abstract: A degrading agent composition for use in manufacturing a tissue product generally includes a degrading agent, a degradation inhibiting carrier, and a non-ionic surfactant. The non-ionic surfactant stabilizes the viscosity of the composition as a function of time. The degrading agent composition can be used in combination with a temporary wet strength agent to produce a tissue product exhibiting high initial wet tensile strength and desirable decay properties. Processes for forming the tissue product and pumpable fluids containing the degrading agent composition are also disclosed.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: March 18, 2014
    Assignee: Kemira Oyj
    Inventors: Scott Rosencrance, Yuping Luo, Vladimir Grigoriev
  • Patent number: 8663427
    Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: March 4, 2014
    Assignee: International Paper Company
    Inventors: James E. Sealey, Brent A. Fields
  • Publication number: 20140034259
    Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.
    Type: Application
    Filed: April 24, 2012
    Publication date: February 6, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Daniel C. Kraiter
  • Publication number: 20130306261
    Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process. The method improves the efficiency of dewatering aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to dewatering aids. The dewatering aid holds the paper fibers together tightly and is not wasted on the filler particles.
    Type: Application
    Filed: May 25, 2012
    Publication date: November 21, 2013
    Inventors: Yulin ZHAO, Jun LI, Qing Long RAO, Weiguo CHENG
  • Patent number: 8585864
    Abstract: Flame retardant composite materials are provided which include at least one first paper which comprises carbon nanofibers and graphite oxide particles. The composite materials may further include at least one second paper which comprises carbon nanofibers. The composites may further include one or more structural material layers sandwiched between the first and second papers. Occupant structures are also provided with fire and smoke retardant surfaces composed of carbon nanofibers/graphite oxide particles papers at least partially surrounding occupants of the occupant structures.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: November 19, 2013
    Assignee: Florida State University Research Foundation, Inc.
    Inventors: Chuck Zhang, Zhiyong Liang, Ben Wang, Qiang Wu
  • Publication number: 20130299110
    Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process The method improves the efficiency of drainage aids or wet web strength aids or wet strength aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a those additives. The drainage additive or wet web strength additive or wet strength aid holds the cellulose fibers together tightly and is not wasted on the filler particles.
    Type: Application
    Filed: June 17, 2013
    Publication date: November 14, 2013
    Inventors: Yulin Zhao, Jun Li, Qing Long Rao, Weiguo Cheng
  • Publication number: 20130280545
    Abstract: Compositions such as filled and coated papers may include microfibrillated cellulose and inorganic particulate material.
    Type: Application
    Filed: November 9, 2011
    Publication date: October 24, 2013
    Applicant: IMERYS MINERALS LIMITED
    Inventors: John Claude Husband, Per Svending, David Robert Skuse
  • Patent number: 8465624
    Abstract: A fluff pulp or other pulp, comprises a multivalent cationic metal ion selected from the group consisting of Al+3, B+3, Mn+2, Cu+2, Cu+3, Zn+2, Sn+2, Sn+4, water-soluble salt thereof, or combination thereof; an amine-containing anti-static agent; and pulp. Methods of making and using the pulp, as well as articles therefrom, are provided.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: June 18, 2013
    Assignee: International Paper Company
    Inventors: James E. Sealey, Peter M. Froass, Sylvie Marie Rita Carriere
  • Patent number: 8460513
    Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: June 11, 2013
    Assignee: International Paper Company
    Inventors: James E. Sealey, Brent A. Fields
  • Publication number: 20130139987
    Abstract: The invention relates to a fiber web and a method for preparing it. The fiber web comprises a filler-containing base web, which is possibly coated with a pigment-containing coating layer. According to the invention, 5-100% of the filler in the base web is made up of cellulose fibrils or lignocellulose fibrils with light-scattering material particles deposited thereon. These coated cellulose fibrils or lignocellulose fibrils constitute at maximum approx. 70% of the weight of the base web. The base web according to the invention contains more than 20% less retention agents than does a web which has the same formation but in which more than 95% of the filler is made up of filler particles known per se.
    Type: Application
    Filed: November 14, 2012
    Publication date: June 6, 2013
    Inventors: Petri SILENIUS, Jari MEURONEN, Markku LESKELA
  • Patent number: 8440053
    Abstract: A method for inhibiting deposition of multivalent saturated fatty acids on paper sizing equipment and/or devices which use a paper surface sizing composition containing one or more surface sizing starches and a source of multivalent cations, such as a multivalent metal drying salt, by including a C16 or higher saturated fatty acid solubilizing and dispersing surfactant in the paper surface sizing composition. Also, a paper surface sizing system for carrying out this method.
    Type: Grant
    Filed: April 2, 2010
    Date of Patent: May 14, 2013
    Assignee: International Paper Company
    Inventors: Michael F. Koenig, Ascencion L. Koenig, Ewa Gertruda Bucher
  • Patent number: 8404084
    Abstract: A filler treatment process enhances the fixation of anionic latex on filler in a short time. Anionic polymer dispersions (latex) are added to papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. The anionic latexes applied by this process are totally and irreversibly fixed or bound onto the filler particles and the treated filler particle agglomerate to form an aggregated filler slurry which is stable over time. The latex-treated filler slurry can be added to papermaking furnishes at any point prior to the headbox of the paper machine or stored for later use. The latex-treated filler slurry improves filler retention, only slightly reduces sheet strength and improves sizing performance.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: March 26, 2013
    Assignee: FPInnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Patent number: 8354003
    Abstract: The present invention relates to a porous fiber product, which contains chemical pulp or wood fibers, between which structural filler particles are attached, as well as to a method of manufacturing this product, wherein filler drops are produced in a spray dryer from the aqueous solution of the filler, the drops forming filler particles when the water evaporates, the particles being attached to the chemical pulp or wood fibers.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: January 15, 2013
    Assignee: Nordkalk Oy Ab
    Inventor: Pentti Virtanen
  • Patent number: 8343312
    Abstract: Process for the production of filler-containing papers and filler-containing paper products by addition of an aqueous suspension of at least one finely divided polymer-pigment hybrid to a paper stock and drainage of the paper stock with sheet formation, the polymer-pigment hybrid being obtainable by milling an aqueous suspension of at least one inorganic pigment in the presence of at least one binder and, if appropriate, by drying the aqueous suspension thus obtainable and redispersing the dried polymer-pigment hybrid in water, and the use of the polymer-pigment hybrids thus obtainable as a filler for the production of filler-containing paper or filler-containing paper products.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: January 1, 2013
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Mahr, Dieter Meck, Rainer Blum, Ralf Hemel, Norbert Gispert, Juergen Schmidt-Thuemmes, Christoph Hamers
  • Publication number: 20120318471
    Abstract: The invention relates to a process for the preparation of a pigment-cellulosic fibre composite, wherein the pigment comprises an inorganic pigment which comprises local cationic charges, said process comprises contacting an aqueous cellulosic fibre suspension and inorganic pigment particles such that crystals of said pigment are attached to the surface of the fibre, said crystals having a size of at most 5 ?m. The produced composite product can be used as a filler pigment or coating pigment in the production of paper.
    Type: Application
    Filed: February 10, 2011
    Publication date: December 20, 2012
    Inventors: Tarja Turkki, Perttu Heiska
  • Publication number: 20120227921
    Abstract: Disclosed is a formulation and method for treating paper so that paper in landfills produces less methane than untreated paper. The method includes adding one or more nitrate salts to paper during the process of making paper, or after the paper is made. One effect of adding the nitrate salts is promoting the growth of certain bacteria which do not produce methane as they consume paper products.
    Type: Application
    Filed: January 10, 2012
    Publication date: September 13, 2012
    Inventors: SPENCER S. BRODY, BRIAN DAVIS
  • Patent number: 8252144
    Abstract: The invention relates to a flame resistant paper product and a method for manufacturing a flame resistant paper product. In an embodiment the invention is a paper product comprising a paper substrate having a first surface and a second surface and a flame retardant composition, wherein the first surface is smoother than the second surface. In another embodiment, the invention is a method for forming a flame resistant paper product comprising applying a flame retardant composition to a web of fibers having a first surface and a second surface, wherein the first surface is smoother than the second surface by at least about 70 SSU according to TAPPI T538.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: August 28, 2012
    Assignee: Wausau Paper Mills, LLC
    Inventor: Robert Steif
  • Publication number: 20120186766
    Abstract: The present invention relates to a process for manufacturing papery articles, such as paper, card and board, comprising the pH adjustment of an aqueous composition comprising at least one fiber stock by addition of methanesulfonic acid (MSA).
    Type: Application
    Filed: January 24, 2012
    Publication date: July 26, 2012
    Applicant: BASF SE
    Inventors: Stefan Fassbender, Christoph Lessig
  • Publication number: 20120080157
    Abstract: A degrading agent composition for use in manufacturing a tissue product generally includes a degrading agent, a degradation inhibiting carrier, and a non-ionic surfactant. The non-ionic surfactant stabilizes the viscosity of the composition as a function of time. The degrading agent composition can be used in combination with a temporary wet strength agent to produce a tissue product exhibiting high initial wet tensile strength and desirable decay properties. Processes for forming the tissue product and pumpable fluids containing the degrading agent composition are also disclosed.
    Type: Application
    Filed: September 30, 2010
    Publication date: April 5, 2012
    Applicant: KEMIRA OYJ
    Inventors: Scott Rosencrance, Yuping Luo, Vladimir Grigoriev
  • Patent number: 8133354
    Abstract: A composition and process suitable for making acoustic tiles are disclosed. Certain embodiments of the composition comprise: perlite; inorganic material selected from the group consisting of calcium sulfate, calcium carbonate, clay and mixtures thereof; a binder selected from the group consisting of starch, a combination of starch and cellulosic fibers, latex, kraft paper gel and mixtures thereof; optionally mineral wool; optionally gypsum; and cellulosic fiber, wherein at least a portion of the cellulosic fiber and at least a portion of the inorganic material are pulp and paper processing waste comprising cellulosic fiber, clay and calcium carbonate. Certain embodiments of the process comprise: forming an aqueous slurry; continuously flowing slurry onto a moving foraminous wire to form a cake; dewatering the cake to form a base mat; and drying the base mat.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: March 13, 2012
    Assignee: USG Interiors, LLC.
    Inventor: Mirza A. Baig
  • Publication number: 20120024488
    Abstract: The invention relates to a supercalendered paper product comprising first cellu-losic fibres and a gypsum-fibre composite product as a filler pigment or coating pigment, wherein the gypsum in the gypsum-fibre composite product appears as crystals on the surface of the fibre, and wherein the gypsum crystals are obtained by contacting calcium sulphate hemihydrate and/or calcium sulphate anhydrite and an aqueous second fibre suspension. The invention also relates to a process for producing a supercalendered paper product.
    Type: Application
    Filed: April 19, 2010
    Publication date: February 2, 2012
    Inventors: Tarja Turkki, Mikko Virtanen
  • Patent number: 8101047
    Abstract: Ash composition measurements of calcium carbonate and gypsum in paper is accomplished with a dual X-ray sensor system with one X-ray source that is powered at about 5.9 KV and a second X-ray source that is powered at about 4.2 KV. Corresponding detectors measure radiation from the respective X-ray sources that is emitted from the paper. Data derived from the measurements yields the gypsum and crystal water content in the paper. The dual X-ray sensor system can be employed in conjunction with infrared total moisture measurements of paper products being manufactured on a papermaking making machine, which contain gypsum and calcium carbonate, in order to correct for the gypsum crystal water effect.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: January 24, 2012
    Assignee: Honeywell International Inc.
    Inventors: Unto Kulma, Jaakko Olavi Uusalo, Antti Paavola, Johanna Hansen, Gertjan Hofman
  • Patent number: 8025768
    Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: September 27, 2011
    Assignee: Fpinnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Publication number: 20110226432
    Abstract: A method of mixing at least two chemicals or additives into a process liquid flow flowing in a process liquid flow duct including: feeding a liquid jet to the process liquid flow in the process liquid flow duct, wherein the liquid jet is formed in a feeding device and the liquid jet flows in a transverse direction to a flow direction of the process liquid flow through the process liquid flow duct; mixing the at least two chemicals or additives together to form a mixture; feeding the mixture of the at least two chemicals or additives into the process liquid flow duct with the feeding liquid jet, and mixing the at least two chemicals or additives with the feeding liquid jet in the process liquid flow duct.
    Type: Application
    Filed: May 16, 2011
    Publication date: September 22, 2011
    Applicant: WETEND TECHNOLOGIES OY
    Inventor: Jouni MATULA
  • Publication number: 20110203485
    Abstract: Methods for treating lignocellulosic material or pigment with a reductive bleaching solution generally include washing the lignocellulosic material or pigment with a reducing agent of magnesium dithionite. The method includes at least one reductive stage and at least one peroxide stage. Also disclosed are methods for preparing dithionite solution wherein magnesium bisulfite is reduced with borohydride solution to obtain dithionite. Bleached lignocellulosic material or pigment obtained with the treatment methods are also disclosed.
    Type: Application
    Filed: October 30, 2009
    Publication date: August 25, 2011
    Applicant: KEMIRA OYJ
    Inventors: Risto Rahkola, Birgitta Peltopakka, Hannu Hämäläinen, Jonas Konn, Sari Vahlroos-Pirneskoski
  • Publication number: 20110132560
    Abstract: A gypsum-fibre composite product, wherein the gypsum appears as crystals on the surface of the fibre and wherein the gypsum crystals are obtained by contacting calcium sulphate hemihydrate and/or calcium anhydrite and an aqueous fibre suspension. Also disclosed is a process for the preparation of the gypsum-fibre composite product. The composite product can be used as a filler pigment or coating pigment in the production of paper.
    Type: Application
    Filed: April 20, 2009
    Publication date: June 9, 2011
    Inventors: Tarja Turkki, Jonni Ahlgren
  • Publication number: 20110061827
    Abstract: The present invention relates to a porous fibre product, which contains chemical pulp or wood fibres, between which structural filler particles are attached, as well as to a method of manufacturing this product, wherein filler drops are produced in a spray dryer from the aqueous solution of the filler, the drops forming filler particles when the water evaporates, the particles being attached to the chemical pulp or wood fibres.
    Type: Application
    Filed: February 20, 2009
    Publication date: March 17, 2011
    Applicant: Kautar Oy
    Inventor: Pentti Virtanen
  • Publication number: 20100218908
    Abstract: The invention relates to a fiber web and a method for preparing it. The fiber web comprises a filler-containing base web, which is possibly coated with a pigment-containing coating layer. According to the invention, 5-100% of the filler in the base web is made up of cellulose fibrils or lignocellulose fibrils with light-scattering material particles deposited thereon. These coated cellulose fibrils or lignocellulose fibrils constitute at maximum approx. 70% of the weight of the base web. The base web according to the invention contains more than 20% less retention agents than does a web which has the same formation but in which more than 95% of the filler is made up of filler particles known per se.
    Type: Application
    Filed: October 20, 2009
    Publication date: September 2, 2010
    Inventors: Petri Silenius, Jari Meuronen, Markku Leskela
  • Patent number: 7758934
    Abstract: In web/ink-jet operations in which ink jet data is over-printed on forms prepared by offset litho, undesirable interactions between the surface size and litho-fountain are controlled by use of a PCC basesheet having a size press coating of starch and alum, the alum amount being at least 0.75% by weight.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: July 20, 2010
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Lyle A. Bays, Bruce J. Kokko, Michael A. Schmelzer, Gary L. Schroder
  • Publication number: 20100132902
    Abstract: The invention relates to a paper that is formed of a fibre-based source material and is applicable as printing paper. According to the invention, the surface of the paper is surface-treated by arranging on the surface sufficient density in such manner that the density of at least one surface layer of the paper is sufficiently high to yield a Gurley-Hill value of over 7000 s/100 ml as measured from the entire paper. Furthermore, the invention relates to a method for making paper.
    Type: Application
    Filed: April 25, 2008
    Publication date: June 3, 2010
    Applicant: UPM-Kymmene Oyj
    Inventors: Tarja Sinkko, Mikko Oksanen, Janne Varvemaa, Kyösti Haapoja, Teuvo Lappänen
  • Patent number: 7691231
    Abstract: Newsprint for offset printing having sufficient water absorption resistance to provide a clear printing image with less color registration problems upon offset printing is manufactured by coating base paper, to which aluminum sulfate (a 50% by weight Al2O3.14H2O product) is added at a ratio of less than 3.0% by weight upon paper making, with a surface treating agent mainly comprised of (A) a water-soluble macromolecular substance selected from starches, PVAs, polyacrylamides, and cellulose derivatives, (B) a copolymer obtained by the copolymerization of a styrene monomer and a cationic monomer, a water-soluble copolymer obtained by the copolymerization of a styrene monomer, a cat ionic monomer and a hydrophobic monomer, or a water-soluble copolymer obtained by treating one of these copolymers in which a tertiary amine-containing vinyl monomer is used as a cationic monomer, with a quaternizing agent.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: April 6, 2010
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Hiroshi Ono, Satoshi Ishioka, Fuminari Nonomura, Yasunori Nanri
  • Publication number: 20100078139
    Abstract: Ash composition measurements of calcium carbonate and gypsum in paper is accomplished with a dual X-ray sensor system with one X-ray source that is powered at about 5.9 KV and a second X-ray source that is powered at about 4.2 KV. Corresponding detectors measure radiation from the respective X-ray sources that is emitted from the paper. Data derived from the measurements yields the gypsum and crystal water content in the paper. The dual X-ray sensor system can be employed in conjunction with infrared total moisture measurements of paper products being manufactured on a papermaking making machine, which contain gypsum and calcium carbonate, in order to correct for the gypsum crystal water effect.
    Type: Application
    Filed: September 16, 2009
    Publication date: April 1, 2010
    Applicant: Honeywell International Inc.
    Inventors: Unto Kulma, Jaakko Olavi Uusalo, Antti Paavola, Johanna Hansen, Gertjan Hofman
  • Publication number: 20100044289
    Abstract: Disclosed is an integrated paper wherein the paper has capabilities and functionalities provided by both the fiber and the active agent ingredients, and a method of immobilizing the active agents within the integrated paper. The tight pore structure of the integrated paper of the present invention, a mean pore diameter of less than about 2 microns, provides short diffusion distances from a fluid to the surface of the paper ingredients by adsorption or diffusive interception making it an excellent medium for fluid filtration. The integrated paper of the present invention can further include a microbiological interception enhancing agent. The integrated paper can be formed using, preferably, wet laid paper-making processes for speed and efficiency. Also disclosed are devices utilizing the integrated paper useful in fluid filtration.
    Type: Application
    Filed: October 28, 2009
    Publication date: February 25, 2010
    Applicant: KX TECHNOLOGIES LLC
    Inventor: Evan E. Koslow
  • Patent number: 7648032
    Abstract: Disclosed herein are a method of reductively bleaching a mineral slurry comprising adding in the mineral slurry an effective amount of a formamidine sulfinic acid (FAS) and an effective amount of a borohydride to reductively bleach the mineral slurry, compositions comprising a mineral slurry, a FAS, and a borohydride, and final products comprising a mineral obtained by the method disclosed herein.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: January 19, 2010
    Assignee: Imerys Pigments, Inc.
    Inventors: Jun Yuan, Robert J. Pruett, Larry C. Powell
  • Publication number: 20090277597
    Abstract: A method for producing paper, cardboard or similar materials, comprising, separately or in a mixture, adding to a fibrous suspension: at least one main retention agent comprising a cationic (co)polymer, and at least one dual retention agent comprising a crosslinked cationic (co)polymer obtained in the form of a dispersion and placed in solution prior to its introduction into the fibrous suspension with gentle stirring. The crosslinked cationic (co)polymer having—a UL viscosity of between 1.3 and 2.7 cps, preferably between 1.5 and 2.4 cps, and—an apparent cationicity ratio of between 25 and 75%. Optionally, before or after the dual agent or the main retention agent are added, one or more tertiary retention agent(s) selected from the group comprising mineral particles and organic polymers carrying anionic charges, is added to the suspension.
    Type: Application
    Filed: April 10, 2009
    Publication date: November 12, 2009
    Applicant: SNF SAS
    Inventors: Rene Hund, Gatien Faucher
  • Publication number: 20090260152
    Abstract: A moldable paper pulp composition comprising an aqueous suspension of a base material comprising paper particles and a detergent resistant binding agent for the paper particles, in an intimate and substantially homogenous mix. Also provided are articles molded from the composition.
    Type: Application
    Filed: July 31, 2007
    Publication date: October 22, 2009
    Applicant: VERNACARE LIMITED
    Inventor: Lesley Webster
  • Publication number: 20090065162
    Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of high and low molecular weight flocculating agents to an aqueous dispersion of filler particles followed by shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution.
    Type: Application
    Filed: September 12, 2007
    Publication date: March 12, 2009
    Inventors: Weiguo Cheng, Ross T. Gray