Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 20 to 80 wt % of acrylonitrile, from 20 to 80 wt % of monomers selected from the group consisting of esters of acrylic acid, from 0 to 10 wt % of methacrylonitrile, from 0 to 40 wt % of monomers selected from the group consisting of esters of methacrylic acid, the total amount of acrylonitrile and esters of acrylic acid constituting from 50 to 100 wt % of said ethylenically unsaturated monomers, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and isopentane. The invention further relates to the production and use of the microspheres.

Abstract: The invention provides a method of recovering and recycling waste coating color from papermaking coating process for use as wet end filler. The inventive method overcomes many technical challenges inherent in using waste coating colors as wet end filler such as the coatings having fine pigments that hurts sheet strength more than regular filler, having strong anionic charge and tendency to disturb wet end chemistry, causing excessive foaming, and containing a large amount of hydrophobic binder particles that tend to agglomerate in the white water and deposit on papermaking equipment. The method involves mixing the coatings with fresh filler particles, adding de-foaming agent, adding cationic coagulant, then preflocculating the mixture. This process causes fresh filler particles, pigments and binders in waste coating color to agglomerate together and form stable flocs with defined particle size distribution.

Abstract: The invention relates to a process for producing paper, board and cardboard of high dry strength by separately adding a polymer comprising vinylamine units and a polymeric anionic compound to a paper pulp, dewatering the pulp and drying the paper products, which comprises using as polymeric anionic compound at least one copolymer obtainable by copolymerizing (a) at least one N-vinylcarboxamide of the formula in which R1 and R2 are H or C1- to C6 alkyl, (b) at least one monoethylenically unsaturated monomer comprising acid groups, and/or the alkali metal, alkaline earth metal or ammonium salts thereof, and if appropriate (c) other monoethylenically unsaturated monomers, and if appropriate (d) compounds having at least two ethylenically unsaturated double bonds in their molecule.

Abstract: To effectively impart sizing performance to paper, while reducing the amounts of an internal sizing agent and aluminum sulfate, a papermaking additive comprises a mixture of an amphoteric copolymer having a hydrophobic group whose quaternization ratio is 40% by mole or more, and in which the ratio of the anion equivalent to the cation equivalent is 0.1 to 90%, and a calcium carbonate filler. The filler is one in which suitable water repellency is imparted to the filler. Hence, by adding this to pulp slurry, followed by a wet papermaking, the filler is efficiently adsorbed onto pulp fibers having anionic property, so that effective sizing performance can be imparted to the paper by using a smaller amount thereof than the internal sizing agent, while reducing the amounts of the internal sizing agent and the aluminum sulfate.

Abstract: A method for producing paper, cardboard or similar materials, comprising, separately or in a mixture, adding to a fibrous suspension: at least one main retention agent comprising a cationic (co)polymer, and at least one dual retention agent comprising a crosslinked cationic (co)polymer obtained in the form of a dispersion and placed in solution prior to its introduction into the fibrous suspension with gentle stirring. The crosslinked cationic (co)polymer having—a UL viscosity of between 1.3 and 2.7 cps, preferably between 1.5 and 2.4 cps, and—an apparent cationicity ratio of between 25 and 75%. Optionally, before or after the dual agent or the main retention agent are added, one or more tertiary retention agent(s) selected from the group comprising mineral particles and organic polymers carrying anionic charges, is added to the suspension.

Abstract: Process for the production of filler-containing papers and filler-containing paper products by addition of an aqueous suspension of at least one finely divided polymer-pigment hybrid to a paper stock and drainage of the paper stock with sheet formation, the polymer-pigment hybrid being obtainable by milling an aqueous suspension of at least one inorganic pigment in the presence of at least one binder and, if appropriate, by drying the aqueous suspension thus obtainable and redispersing the dried polymer-pigment hybrid in water, and the use of the polymer-pigment hybrids thus obtainable as a filler for the production of filler-containing paper or filler-containing paper products.

Abstract: A process for the production of paper, board and cardboard by draining a paper stock containing interfering substances in the presence of polymers which contain vinylamine units and which have an average molar mass Mw of at least 1 million, a high-consistency stock first being prepared, at least one polymer containing vinylamine units and having an average molar mass Mw of at least 1 million and a degree of hydrolysis of from 1 to 20 mol % being metered into the high-consistency stock, the high-consistency stock being diluted to a low-consistency stock by adding water, and the low-consistency stock being drained, and the use of hydrolyzed homo- or copolymers of N-vinylcarboxamides having a degree of hydrolysis of from 1 to 20 mol % and an average molar mass Mw of at least 1 million in the production of paper, board or cardboard as an additive to a high-consistency stock containing interfering substances, for reducing deposits in the wire part, press section and drying section of paper machines.

Abstract: Agglomerated hollow particle latex is employed as a filler in the wet end of the paper-making process to provide paper with improved properties.

Abstract: A product comprising cellulosic fibers, 0.0001 to 0.03 moles of a water soluble metal salt per 100 grams of cellulosic fiber, based on the oven dry weight of the cellulosic fiber, water and a quantity quaternary ammonium salt to provide 100 to 3000 ppm of quaternary ammonium salt in solution. A process for making the product.

Abstract: The present invention relates to a process for producing paper which comprises: (i) providing an aqueous suspension comprising cellulosic fibers, (ii) adding to the suspension after all points of high shear: a first polymer being a cationic polymer having a charge density above 2.5 meq/g; a second polymer; and a third polymer being an organic or inorganic anionic polymer; and (iii) dewatering the obtained suspension to form paper.

Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.

Abstract: The present invention relates to a process for producing paper which comprises: providing an aqueous suspension comprising cellulosic fibers, adding to the suspension, after all points of high shear, a cationic polysaccharide; and a polymer P2 being an anionic polymer; and, dewatering the obtained suspension to form paper.

Abstract: The instant invention relates to storage stable solutions of optical brighteners based on certain salt forms of anilino-substituted bistriazinyl derivatives of 4,4?-diaminostilbene-2,2?-disulphonic acid which do not need extra solubilising additives.

Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The method provides for the addition of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple, discrete additions of initiator. Additionally, a process for preparation of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple discrete additions of initiator is disclosed.

Abstract: The present invention relates to methods for manufacturing paper or paperboard with improved strength, the methods comprising the addition of the reaction product of a cationic polyacrylamide and an aqueous aldehyde generating compound or a glyoxal releasing compound, or glyoxal itself, prepared at the mill site at high concentrations, then diluted and added into a fiber furnish prior to forming or drying of the paper or paperboard sheet.

Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises sequential addition of high and low molecular weight flocculating agents to an aqueous dispersion of filler particles followed by shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution.

Abstract: The invention relates to an aqueous dispersion useful for internal sizing or surface sizing in the production of paper, comprising at least one cellulose reactive sizing agent selected from the group consisting of ketene dimers and multimers, at least one cellulose non-reactive sizing agent and at least one emulsifier selected from the group consisting of oxyalkylene phosphate and sulfate esters and salts thereof. The invention further concerns a process for its preparation, use thereof, and processes for the production of paper.

Abstract: A composition and process suitable for making acoustic tiles are disclosed. Certain embodiments of the composition comprise: perlite; inorganic material selected from the group consisting of calcium sulfate, calcium carbonate, clay and mixtures thereof; a binder selected from the group consisting of starch, a combination of starch and cellulosic fibers, latex, kraft paper gel and mixtures thereof; optionally mineral wool; optionally gypsum; and cellulosic fiber, wherein at least a portion of the cellulosic fiber and at least a portion of the inorganic material are pulp and paper processing waste comprising cellulosic fiber, clay and calcium carbonate. Certain embodiments of the process comprise: forming an aqueous slurry; continuously flowing slurry onto a moving foraminous wire to form a cake; dewatering the cake to form a base mat; and drying the base mat.

Abstract: A composition includes an alkenyl succinic anhydride sizing agent or an alkyl ketene dimer sizing agent. The alkenyl succinic anhydride sizing agent is present in an amount ranging from about 1.0 pounds per ton to about 4.0 pounds per ton. The alkyl ketene dimer sizing agent is present in an amount ranging from about 2.0 pounds per ton to about 10.0 pounds per ton. A metallic salt is also incorporated in the composition.

Abstract: A composition for treating paper products comprising protein particulate, colloidal pigment, synthetic latex polymer, and preservative is described, as well as methods and an apparatus using the composition for such treatments, and products obtained thereby. The treated paper products preferably have improved strength, water holdout, and/or ink holdout, amongst other advantages and benefits.

Abstract: An aqueous polysilicate composition comprising a polysilicate microgel based component in association with particles derived from colloidal polysilicate. The invention also concerns a process for preparing an aqueous polysilicate composition comprising mixing an aqueous colloidal polysilicate with an aqueous phase of a polysilicate microgel. The aqueous polysilicate composition is more effective than colloidal silica and is more stable than a conventional polysilicate microgel.

Abstract: They are mixtures of (a) from 1 to 99.9% by weight of a water-soluble epihalohydrin-crosslinked polyamidoamine and (b) from 0.1 to 20% by weight of at least one other cationic polymer.

Abstract: The present invention relates to methods for making modified fillers for use in a papermaking process, methods for making a paper using the modified fillers, and modified fillers and paper produced therewith. In one aspect, the present invention provides a method for making a modified filler for use in a papermaking process, which comprises applying a starch composition comprising starch to a reaction composition comprising at least one of fatty acid, rosin acid, and ammonium sulfate to form a reaction mixture; and applying a filler composition comprising a filler to the reaction mixture, whereby forming a modified filler. In another aspect, the present invention provides a method of using a modified filler in a papermaking process, which comprises applying a modified filler to a composition comprising fiber to form a mixture; and processing the mixture, whereby producing a paper.

Abstract: The present invention relates to a process for producing paper which comprises: (vii) providing an aqueous suspension comprising cellulosic fibres, (viii) adding to the suspension after all points of high shear: a first polymer being a cationic polymer having a charge density above 2.5 meq/g; a second polymer; and a third polymer being an organic or inorganic anionic polymer; and (ix) dewatering the obtained suspension to form paper.

Abstract: A paper softening composition that is capable of providing paper with excellent flexibility while suppressing decrease in paper strength. The paper softening composition contains a specific diamide diamine compound or a salt thereof and a specific amide amine compound or a salt thereof in a mass ratio of 5/95 to 90/10.

Abstract: The present disclosure relates to lecithin containing starch compositions. The disclosure also relates to processes for preparing the lecithin-containing starch compositions. Further, the disclosure relates to uses of the lecithin-containing compositions in the preparation of paper products that have oil and grease resistant properties, and/or have release properties. Further, the disclosure relates to paper products that include lecithin-containing compositions and to paper products resulting from the processes herein.

Abstract: Methods for improving the tear strength in non-woven chopped strand mats during the manufacturing process of the mats are provided. In particular, the tear strength of the mat can be improved as the mat is being formed in response to current manufacturing conditions by the addition of a water soluble polyol, such as polyvinyl alcohol, or a cationic dispersant to the binder seal pit. Alternatively, a cationic dispersant may be added to the white water chest to improve the tear strength of the chopped strand mat. The addition of polyvinyl alcohol or a cationic dispersant to the binder seal pit results in an immediate or nearly immediate improvement of the tear strength of the chopped strand mat. Both the polyvinyl alcohol and the cationic dispersant can be utilized to improve the tear strength of a chopped strand mat regardless of the type of binder or components in the white water.

Abstract: Agglomerated hollow particle latex is employed as a filler in the wet end of the paper-making process to provide paper with improved properties.

Abstract: Paper is made by providing an anionic aqueous emulsion of a size, usually a reactive anhydride size, and mixing it into a cellulosic suspension prior to drainage of the suspension to form a sheet which is then dried to provide paper (including paper board). The emulsion is preferably stabilised wholly or mainly by 0.5 to 30 parts by weight (per part by weight size) of water soluble, anionic, polymeric stabiliser, which is preferably anionic starch. Alternatively, the emulsion may be added to the cellulosic suspension while it is anionic, before mixing retention into it. The emulsion may be added to the cellulosic suspension after cationic retention aid has been added to it, the emulsion being added with, before or after mixing anionic microparticulate material or other anionic bridging aid, prior to drainage of the suspension.

Abstract: Processes for producing the monohydrate form of magnesium ammonium phosphate in slurry from use of environmentally friendly reactants are described. Slurry containing the monohydrate form of magnesium ammonium phosphate can be fed directly to, and mixed with, paper making feedstock, such as feedstock for cigarette paper, without transformation of the monohydrate form to the hexahydrate form of magnesium ammonium phosphate.

Abstract: This invention relates to resins useful for imparting strength to paper, the process of incorporating these resins into paper and the paper produced containing the resins. In particular the invention relates to resins useful for imparting dry-strength and wet-strength to paper under conditions of high sulfite ion concentrations.

Abstract: A method of and apparatus for feeding a chemical into a liquid flow are especially suited for use with a headbox of a paper machine, particularly for feeding a retention aid into a fiber suspension flow going to the headbox so that in a mixing apparatus feed liquid is added into the retention chemical solution, prior to introducing the solution into the fiber suspension flow guided to the paper machine. The feed liquid is preferably a circulation water from the paper mill, or another non-clean liquid from a paper mill.

Abstract: An additive for internal addition, which improves the paper qualities of a pulp sheet, such as stiffness and bulk which includes a polymer emulsion containing a natural cationic polymer (A) or synthetic cationic polymer (A?) and polymer particles (B) containing vinyl monomer-derived structural units.

Abstract: The powder composition for paper manufacturing of the invention contains a hydrophobic organic compound (A), an emulsifying and dispersing agent (B), and optionally water-soluble saccharides (C) added based on necessity and has an average particle diameter of 0.1 to 2,000 ?m.

Abstract: A process for making absorbent sheet material from recycle furnish includes treatment with a synergistic debonder composition. The debonder is capable of reducing tensile strength by 40 percent or more by way of a quaternary ammonium surfactant component and a nonionic surfactant component.

Abstract: Synthetic co-polymers having moieties capable of forming hydrogen bonds, ionic bonds, or covalent bonds with cellulose fibers and paper modifying moieties capable of modifying a paper sheet are disclosed. These synthetic co-polymers are derived from the reaction of an aldehyde functional polymer and an aldehyde reactive paper modifying agent containing a non-hydroxyl aldehyde reactive functional group.

Abstract: A method for making a fibrous composite, comprising blending a carboxyalkyl cellulose and a galactomannan polymer or a glucomannan polymer in water to provide an aqueous solution; treating the aqueous solution with a first crosslinking agent to provide a gel; drying the gel to provide a solid; comminuting the solid to provide a plurality of particles; combining at least a portion of the plurality of particles with an aqueous suspension comprising cellulose treated with a galactomannan polymer or a glucomannan polymer, and optionally a second crosslinking agent, to provide a mixture; and mixing the mixture with a water-miscible solvent to provide a fibrous composite.

Abstract: A composition includes an alkenyl succinic anhydride sizing agent or an alkyl ketene dimer sizing agent. The alkenyl succinic anhydride sizing agent is present in an amount ranging from about 1.0 pounds per ton to about 4.0 pounds per ton. The alkyl ketene dimer sizing agent is present in an amount ranging from about 2.0 pounds per ton to about 10.0 pounds per ton. A metallic salt is also incorporated in the composition.

Abstract: The present invention relates to a new paper making composition useful for reducing linting and dusting in paper, a method for reducing paper linting and dusting wherein certain phosphate esters are added to a fiber pulp during the paper making process and the novel additive composition for reducing linting and dusting in paper comprising the phosphate ester.

Abstract: The invention related to process for the production of paper from an aqueous suspension containing cellulosic fibers, and optional fillers, which comprises adding to the suspension (i) a cationic vinyl addition polymer prepared by polymerizing one or more ethylenically unsaturated monomers comprising a cationic monomer; (ii) an anionic polymer having one or more aromatic groups selected from the group consisting of polymers obtained by condensation of formaldehyde with benzene-based and naphthalene-based compounds, polyurethanes, polysaccharides, and lignin-based polymers; wherein (i) and (ii) are separately added to the suspension; and (iii) a low molecular weight cationic organic polymer having a molecular weight in the range of from 2,000 to about 700,000; or an anionic microparticulate material; and forming and draining the obtained suspension on a wire.

Abstract: The present invention relates to Aluminum trihydrate slurries comprising aluminum trihydrate particles, an acrylic dispersant, citric acid, synthetic hectorite clay, optionally a compound to adjust pH, a biocide and water. These slurries may be mixed with titanium dioxide slurries to produce a stable slurry blends useful in paper and paper-board applications.

Abstract: A method of preparing a modified diallyl-N,N-disubstituted ammonium halide polymer and use of the polymer in combination with one or more high molecular weight, water soluble cationic, anionic, nonionic, zwitterionic or amphoteric polymers for increasing retention and drainage in a papermaking furnish.

Abstract: A process of preparing an aqueous composition comprising a polysilicate, wherein the composition is a substantially uniform liquid when measured at 25° C., comprising the steps of, i) providing an aqueous liquid having a source of silicate, ii) adjusting the pH of the liquid to between about 2 and about 10.5, thereby causing polymerisation of the silicate, iii) allowing sufficient time for the polymerisation to proceed to substantial completion and thereby forming a product comprising gelled material, iv) subjecting the gelled material to sufficient shear to form a substantially uniform liquid. The novel aqueous composition made by this process is useful in the manufacture of paper and paperboard either as a mineral filler or as a retention/drainage aid.

Abstract: New coated nonwoven fibrous mats having properties particularly suited for a facer on gypsum wallboard and other substrates and in laminates of various types, and the method of making the coated mat is disclosed. The mat preferably contains a major portion of glass fibers and a minor portion of a resinous binder. The coating is preferably permeable and reduces fiber dust and abrasion experienced in the past with relatively coarse, relatively inexpensive glass fibers in the mat. Contrary to previous coating methods, the coated fibrous mat is made in-line on a wet mat forming production line by applying a wet foam binder onto a wet, fibrous web followed by drying and curing in-line.

Abstract: A method of sizing paper for use in applications which require resistance to liquids comprising incorporating in the paper a size composition comprising one or more alkenyl succinic anhydride (ASA) compounds prepared from the reaction of maleic anhydride and one or more substantially symmetrical C20-C28 internal olefins.

Abstract: Additives for paper making are disclosed herein. Specifically, the additives are wax-free alternatives to conventional coatings, including ASA, AKD and optionally an acrylic containing composition. Other additives may be included in the coating, such as cationic particles or compositions. The coatings may be used at a variety of points during the paper making process, including on the calender stack and in the wet end.

Abstract: The present invention relates to a method for controlling pitch and stickies deposit in a pulp and papermaking process using crosslinked cationic polymers made by controlled addition of a water soluble radical initiator at reaction temperature with agitation for chain extension and crosslinking.

Abstract: A filter material has one or more plies of fiber layers, in particular for the production of filter bags and filter cones for infused beverages, the at least one fiber layer containing fibers or microcapsules having phase change material. Paraffinic hydrocarbons can be used as the phase change material.

Abstract: Starch dispersions comprising discrete particles of crosslinked cationic starch in an aqueous liquid can be used in papermaking. They can be used as a wet-end additive or in surface coating. The starch dispersions can be prepared by a process comprising: (a) obtaining a mixture of cationic starch and an aqueous liquid, (b) processing the mixture using shear forces in the presence of a crosslinker: and (c) adding and mixing in a hydroxylic liquid to obtain the starch dispersions.

Abstract: Enzyme-treated papermaking sludges are provided, as are methods of making the enzyme-treated sludge. Papermaking processes that incorporate the enzyme-treated papermaking sludges into papermaking pulp are also provided as are paper and paperboard products made from the resultant pulp.