Scale Or Corrosion Determination Patents (Class 166/250.05)
  • Patent number: 11193345
    Abstract: A downhole tool, for removing sections of metal tubing, said downhole tool comprising at least one conductive element being arranged to corrode a section of metal tubing using an electrolytic process, said conductive element being made of electric conductive material, an apparatus to establish a connection to the metal tubing, and a source of electrical power.
    Type: Grant
    Filed: May 27, 2020
    Date of Patent: December 7, 2021
    Assignee: INNOVATION ENERGY AS
    Inventors: Carlos J. Delgado, Pal Viggo Hemmingsen, Bjarne Bugten, Marcus Fathi, Astrid Bjørgum, Nils-Inge Nilsen
  • Patent number: 11035211
    Abstract: A system for chemical treatment of producing hydrocarbon wells and other equipment. In one example arrangement, a number of treatment fluids are stored in treatment fluid reservoirs, and a number of carrier fluids are stored in carrier fluid reservoirs. Each reservoir has an associated valve, such that the fluids can be selectively drawn from the reservoirs and pumped to a treatment target. The treatment fluid reservoirs may be connected to a treatment fluid manifold, and the carrier fluid reservoirs may be connected to a carrier fluid manifold. Fluids drawn from the reservoirs may be directed to a distribution manifold and delivered to specific treatment targets using valves on outlets of the distribution manifold.
    Type: Grant
    Filed: February 19, 2021
    Date of Patent: June 15, 2021
    Assignee: WELL-FOCUSED TECHNOLOGIES, LLC
    Inventor: Warren Sundet
  • Patent number: 11002132
    Abstract: Systems, methods and devices for analyzing a sample of fluid extracted from a hydrocarbon-producing geological formation to detect a quantitative amount of hydrogen sulfide or disclosed. The systems methods and devices involve including a scavenger within a sample compartment to react with the hydrogen sulfide therein. The concentration of hydrogen sulfide in the sample may be derived as a function of the amount of scavenger remaining in the sample after reaction with hydrogen sulfide, an amount of byproduct of a reaction between the scavenger and the hydrogen sulfide, or an amount of hydrogen sulfide as measured following a secondary reaction that releases the hydrogen sulfide from the scavenger.
    Type: Grant
    Filed: August 1, 2019
    Date of Patent: May 11, 2021
    Assignee: Halliburton Energy Services, Inc.
    Inventors: William Wade Samec, Cato Russell McDaniel
  • Patent number: 10914161
    Abstract: A corrosion measuring tool for controlling corrosion in an oil well with a tubing has a hollow cylindrical barrel, a hollow element, an expandable sleeve, at least one coupon for corrosion measurement and an elongated member. The hollow element is located at the upper end of the hollow cylindrical barrel and has a conical upper portion and a cylindrical lower portion. The cylindrical lower portion is slidable within the barrel. The cylindrical lower portion has linkage and sliding retention. An expandable sleeve is located at the upper end of the hollow cylindrical barrel, below the conical upper portion. The sleeve has a fastener. Movement of the hollow element relative to the barrel in a downward direction causes the conical upper portion to expand the expandable sleeve. Movement of the hollow element in an upwardly direction releases the expandable sleeve to separate the fastener from the tubing.
    Type: Grant
    Filed: July 1, 2019
    Date of Patent: February 9, 2021
    Assignee: YPF SOCIEDAD ANONIMA
    Inventors: Gianni Pietravalli, Eduardo Yoldes
  • Patent number: 10385664
    Abstract: Provided is a chemical injection pump that is installed below an electric submersible pump. In general, the chemical injection pump is either driven by an electric motor that draws power from the electric submersible pump motor or from energized fluid leaving the electric submersible pump output port. The electric submersible pump provides electric or hydraulic power to run the chemical injection pump. Therefore, no surface chemical injection pump is required and hence less space is needed.
    Type: Grant
    Filed: June 30, 2017
    Date of Patent: August 20, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Jinjiang Xiao, Hattan Banjar
  • Patent number: 10317331
    Abstract: Systems and methods for detection of pipe characteristics, such as defect detection of downhole tubulars and overall thickness estimation of downhole tubulars (e.g., pipes such as casing and/or production tubing).
    Type: Grant
    Filed: November 6, 2016
    Date of Patent: June 11, 2019
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Baris Guner, Burkay Donderici, Ilker R. Capoglu
  • Patent number: 10107062
    Abstract: A system including a frac head system, including a frac head configured to retain portions of an isolation sleeve that separates frac fluid from tubing.
    Type: Grant
    Filed: May 11, 2016
    Date of Patent: October 23, 2018
    Assignee: Cameron International Corporation
    Inventors: Thomas George Roesner, Craig Lawrence Cotton
  • Patent number: 9587171
    Abstract: The present invention relates to a process for treating a subterranean formation wherein a fluid containing an ammonium salt of glutamic acid N,N-diacetic acid (GLDA) or methylglycine N,N-diacetic acid (MGDA) is introduced into the formation.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: March 7, 2017
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana De Wolf, James N. Lepage, Hisham Nasr-El-Din, Mohamed Ahmed Nasr-El-Din Mahmoud, Edwin Rudolf Antony Bang, Noble Thekkemelathethil George
  • Patent number: 9556731
    Abstract: An immersion probe is described that includes sensing elements that allow for hydrate inhibitor dosage to be more efficiently provided into gas and/or oil wells. The immersion probe allows for detection of first appearance of water in a multiphase flow in a well, measuring the amount of inhibitor in water within the well, determining an accurate water-cut, and measuring other property such as water salinity. Accordingly, with the known water-cut, salinity and the water flow rate inferred from the inhibitor injection flow rate and inhibitor-in-water fraction, a correct dosage of the inhibitor can be injected to the well in order to prevent hydrate formation, while reducing overdosing. Water flow rate may also be inferred from an independently measured liquid flow rate and the immersion-probe measured water cut.
    Type: Grant
    Filed: November 13, 2014
    Date of Patent: January 31, 2017
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventor: Cheng-Gang Xie
  • Patent number: 9546959
    Abstract: A method and system that characterizes hydrogen sulfide in petroleum fluid employs a tool that includes a fluid analyzer for performing fluid analysis (including optical density (OD) for measuring carbon dioxide concentration) of a live oil sample, and a storage chamber for an analytical reagent fluidly coupled to a measurement chamber. An emulsion from fluid of the sample and the reagent is produced into the measurement chamber. The reagent changes color due to pH changes arising from chemical reactions between components of the sample and the reagent in the measurement chamber. The tool includes an optical sensor system that measures OD of a water phase of the emulsion at one or more determined wavelengths. The pH of the water phase is derived from such OD measurements. The pH of the water phase and the carbon dioxide concentration in the sample is used to calculate hydrogen sulfide concentration in the sample.
    Type: Grant
    Filed: September 16, 2011
    Date of Patent: January 17, 2017
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Kentaro Indo, Michael M. Toribio, Shu Pan
  • Patent number: 9296631
    Abstract: Alkyl phosphonates prepared from amino acids suitable for use in inhibiting scale. The phosphonates are obtained as reaction mixtures where the level of alkyl phosphonation is deliberately controlled to provide only partial alkyl phosphonation of the amino acid. The resulting alkyl phosphonates exhibit improved environmental properties compared to the fully substituted species, while still exhibiting acceptable efficacy in the control of scale. The compositions possess advantages over existing phosphonates in that they exhibit higher biodegradation by method OECD 306. They also offer lower toxicity to marine life compared to the fully substituted species and are not expected to bioaccumulate.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: March 29, 2016
    Assignee: Ecolab USA Inc.
    Inventors: Scot H. Bodnar, Henry C. Fisher, Andrew Frederick Miles, Curtis D. Sitz
  • Patent number: 9033036
    Abstract: Embodiments may take the form of a tool string sub. The tool string sub may include a longitudinally extending tubular housing having an outside surface and an inside surface. A stepped circumferential portion of the inside surface of the housing bisects the interior surface of the housing. A degradation part is connected adjacent to the stepped portion of the housing and is supported by the housing and at least one moveable support part protruding inward and beyond the inner surface of the housing. The support part has a first position where the degradation part is at first stress and a second position where the degradation part is at a second stress greater than the first stress. At least one end of the tool string sub is adapted to connect with a tool string.
    Type: Grant
    Filed: May 12, 2011
    Date of Patent: May 19, 2015
    Assignee: Schlumberger Technology Corporation
    Inventors: Christian Wilkinson, Indranil Roy, Stephane Hiron
  • Patent number: 8967253
    Abstract: A downhole formation fluid pumping and a sampling apparatus are disclosed that may form part of a formation evaluation while drilling tool or part of a tool pipe string. The operation of the pump is optimized based upon parameters generated from formation pressure test data as well as tool system data thereby ensuring optimum performance of the pump at higher speeds and with greater dependability. New pump designs for fluid sampling apparatuses for use in MWD systems are also disclosed.
    Type: Grant
    Filed: July 19, 2011
    Date of Patent: March 3, 2015
    Assignee: Schlumberger Technology Corporation
    Inventors: Reinhart Ciglenec, Steven G. Villareal, Albert Hoefel, Peter Swinburner, Michael J. Stucker, Jean-Marc Follini
  • Patent number: 8950481
    Abstract: A method of analyzing a wellbore fluid that includes treating a wellbore fluid with an emulsifying fluid, the emulsifying fluid comprising: a hydroxylated ether; an amphoteric chemotrope; and testing the treated wellbore fluid for at least one of turbidity and total suspended solids is disclosed. Methods of cleaning wellbores are also disclosed.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: February 10, 2015
    Assignee: M-I LLC
    Inventors: Eugene Dakin, Hui Zhang, Bethicia B. Prasek
  • Patent number: 8430162
    Abstract: A technique facilitates monitoring of conditions which are prone to cause scale precipitation around downhole equipment. The technique also enables a local, downhole reaction to the potential for precipitation of scale. A downhole scale monitoring and inhibition system may be provided with a measurement module and injection module. The measurement module monitors at least one downhole parameter indicative of the potential for scale formation. In response to data output from the measurement module, the injection module is operated to provide downhole, local injections of an inhibitor chemical.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: April 30, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Spyro Kotsonis, Syed A. Ali, Ives Loretz
  • Patent number: 8430161
    Abstract: Methods of producing a sour hydrocarbon gas via production tubing intersecting a reservoir, are described, one method including contacting an underground reservoir with an aqueous composition optionally comprising an additive, the reservoir comprising hydrocarbons and sulfur compounds; displacing the composition into the reservoir by forcing a fluid (which may be a non-hydrocarbon gas, or inert gas, or nitrogen, or argon, or mixture thereof), into the reservoir, or into the production tubing; and producing at least some of the hydrocarbons and sulfur compounds from the reservoir through the production tubing, the composition wetting the production tubing and preventing substantial deposition of elemental sulfur thereon.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 30, 2013
    Assignee: BP Corporation North America Inc.
    Inventors: Derry Eddy, Kean Zemlak
  • Publication number: 20130087328
    Abstract: A disclosed downhole optical sensor system includes at least one optical sensor positioned in a borehole and coupled to an interface via a fiber optic cable. Each of the optical sensors includes a waveguide for conducting light, and a reagent region positioned between the waveguide and a fluid in the borehole to absorb a portion of the light from the waveguide, the portion being dependent upon a concentration of a chemical species in the fluid. A described method for operating a well includes deploying one or more downhole optical sensors in a fluid flow path in the well, probing the one or more downhole optical sensors from a surface interface to detect concentrations of one or more chemical species, and deriving a rate of scale buildup or corrosion based at least in part on the detected concentrations.
    Type: Application
    Filed: October 5, 2011
    Publication date: April 11, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: John L. Maida, JR., Etienne M. Samsom, Rory D. Daussin, Thomas D. Welton
  • Publication number: 20130008649
    Abstract: A method of providing information regarding erosion in an oil and/or a gas production system, which system includes at least one equipment/piping, the method including the steps of obtaining CFD results regarding hot spots in the equipment/piping from a CFD analysis of the equipment/piping for a range of pressures, flow rates and sand rates; and to, during production, obtaining data regarding erosion rates in a particular location in the system; and combining the data regarding erosion rates and CFD results to estimate and monitor sand erosion rates in the hot spots of the system. Further disclosed is a module performing the method steps as well as a computer program.
    Type: Application
    Filed: June 22, 2012
    Publication date: January 10, 2013
    Inventors: Gaute Yddal Vestbostad, Astrid Kristoffersen, Nicholas Josep Ellson, Inge Wold
  • Publication number: 20110277995
    Abstract: A tool string sub. A longitudinally extending tubular housing has an outside surface and an inside surface. A stepped circumferential portion of the inside surface of the housing bisects the interior surface of the housing. A degradation part is connected adjacent to the stepped portion of the housing and is supported by the housing and at least one moveable support part protruding inward and beyond the inner surface of the housing. The support part has a first position where the degradation part is at one stress and a second position where the degradation part is at a second stress greater than the first stress. At least one end of the tool string sub is adapted to connect with a tool string.
    Type: Application
    Filed: May 12, 2011
    Publication date: November 17, 2011
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Christian Wilkinson, Indranil Roy, Stephane Hiron
  • Patent number: 7963324
    Abstract: A method usable with a subterranean well that includes actuating a downhole tool (a valve assembly, for example). The method also includes applying at least one of an impulse stimulus and a vibration stimulus to the tool during the actuating to enhance operation of the tool.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: June 21, 2011
    Assignee: Schlumberger Technology Corporation
    Inventor: Herve Ohmer
  • Publication number: 20100300684
    Abstract: A technique facilitates monitoring of conditions which are prone to cause scale precipitation around downhole equipment. The technique also enables a local, downhole reaction to the potential for precipitation of scale. A downhole scale monitoring and inhibition system may be provided with a measurement module and injection module. The measurement module monitors at least one downhole parameter indicative of the potential for scale formation. In response to data output from the measurement module, the injection module is operated to provide downhole, local injections of an inhibitor chemical.
    Type: Application
    Filed: May 25, 2010
    Publication date: December 2, 2010
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Spyro Kotsonis, Syed A. Ali, Ives Loretz
  • Publication number: 20090288822
    Abstract: Methods of producing a sour hydrocarbon gas via production tubing intersecting a reservoir, are described, one method including contacting an underground reservoir with an aqueous composition optionally comprising an additive, the reservoir comprising hydrocarbons and sulfur compounds; displacing the composition into the reservoir by forcing a fluid (which may be a non-hydrocarbon gas, or inert gas, or nitrogen, or argon, or mixture thereof), into the reservoir, or into the production tubing; and producing at least some of the hydrocarbons and sulfur compounds from the reservoir through the production tubing, the composition wetting the production tubing and preventing substantial deposition of elemental sulfur thereon.
    Type: Application
    Filed: May 19, 2009
    Publication date: November 26, 2009
    Applicant: BP CORPORATION NORTH AMERICA INC.
    Inventors: Derry Eddy, Kean Zemlak
  • Publication number: 20090151936
    Abstract: A technique enables the cleaning of scale from a well and the monitoring of scale removal. A scale removal tool and a radiation detector are deployed simultaneously into a wellbore having scale with a radioactive signature. The scale removal tool is used to remove deposits from a well component, e.g. from the interior of a tubular member. The radiation detector enables the measuring and monitoring of scale removal. Data related to the scale removal can be output for use by an operator to help optimize scale removal and fluid flow.
    Type: Application
    Filed: December 18, 2007
    Publication date: June 18, 2009
    Inventor: Robert Greenaway
  • Patent number: 7541817
    Abstract: A method of diagnosing corrosion risk of a buried pipe due to DC stray currents and/or AC voltages induced in soil employs a metal probe including a first, exposed part having a first specific resistivity, and a second, sealed reference part having a second specific resistivity. The probe is buried in the soil, and the AC current and voltage between the pipe and the probe are measured, from which the spread resistance is determined. The resistances of the first and second probe parts are determined by respectively passing first and second excitation currents through the first and second probe parts and measuring the voltages across them. The resistance measurements are stored, and the steps are repeated periodically. The corrosion of the first probe part is determined from the measurements according to an algorithm, and the pipe corrosion risk is diagnosed from an empirical combination of the corrosion of the first probe part, the spread resistance, and the AC voltage measured.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: June 2, 2009
    Assignee: Metricorr APS
    Inventors: Lars V. Nielsen, Folke Galsgaard
  • Patent number: 7025138
    Abstract: The present invention relates to a method and apparatus for detection of hydrogen sulfide in downhole operations. A downhole tool is provided with a coupon adapted to react at varying degrees to exposure to concentrations of hydrogen sulfide. The downhole tool is positioned in the wellbore with the coupon(s) exposed to downhole fluids. A reaction to a change in the coupon, such as coloration, is used to determine the presence and concentration of hydrogen sulfide.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: April 11, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Andrew Loris Kurkjian, Dexter Mootoo, Wes C. Wofford, Xu Wu, Timothy G. J. Jones, Russell Kane
  • Patent number: 6792796
    Abstract: A method for predicting scale deposition in a general environment has been discovered which involves providing a localized environment where scale would preferentially form, where the localized environment is adjacent the general environment. Monitoring the deposition of scale in the localized environment is performed for the purpose of taking preemptive action to prevent scale deposition in the general environment once scale begins to form, or a certain threshold is reached. Scale is removed from the localized environment so that monitoring can be performed by the probe again. Preemptive action will often be the introduction of a scale inhibiting agent into the general environment. An apparatus for practicing the method of predicting and preventing scale deposition in a general environment is also described.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: September 21, 2004
    Assignee: Baker Hughes Incorporated
    Inventor: Paul Hammonds
  • Patent number: 6725925
    Abstract: A downhole cathodic protection cable system includes an attachment shoe electrically connected to a metallic structure at a distance substantially below the earth's surface, and an electrical cable having a first end connected to a connection structure substantially at the earth's surface and a second end electrically connected to the attachment shoe. The first end is connected through the connection structure to provide current to the cable sufficient to prevent substantial corrosion surrounding the attachment shoe.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: April 27, 2004
    Assignee: Saudi Arabian Oil Company
    Inventor: Abdul-Raouf M. Al-Ramadhan
  • Patent number: 6712139
    Abstract: A method of cathodic current optimization measures drill stem resistances along a well hole being drilled, correlates the drill stem resistances to respective types of underground formations at corresponding positions along the well hole, predicts a respective position of at least one anodic area on a well casing to be installed and determines an amount of cathodic current to be applied thereto.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: March 30, 2004
    Assignee: Saudi Arabian Oil Company
    Inventor: Husain M. Al-Mahrous
  • Patent number: 6668922
    Abstract: A method for designing acid treatments provides for the selection of optimal treatment for well stimulation wherein reservoir characteristics are obtained to further select the reaction kinetic data on the minerals of interests, the treatment to the reservoir is scaled up using a mathematical model and real time damage are computed based on bottomhole pressure and injection rate and compared to that predicted by the mathematical model to adjust the treatment. The model generated facilitates optimization of matrix treatments by providing a rapid quantitative evaluation of various treatment strategies for a formation. Stimulation with non-traditional fluid recipes containing mixtures of inorganic and organic acids, and chelating agents can be readily computed. The computed values can then be used in an economic model to justify the additional costs associated with the use of the non-traditional fluids.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: December 30, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Murtaza Ziauddin, Joel Robert
  • Patent number: 6467340
    Abstract: The present invention provides a system that monitors and controls the precipitation of asphaltenes in a formation fluid recovered from a subsurface formation or reservoir by using a sensor to make a direct real-time on-site measurement of the relative concentration asphaltenes from at least one location at a wellsite or in a pipeline. In a system including a fiber optic attenuated total reflectance probe for sensing asphaltenes and using a processor to compare sequential measurements, the system of the present invention can trigger the addition of additives in response to a change in asphaltene concentration in the formation fluid, preventing precipitation.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: October 22, 2002
    Assignee: Baker Hughes Incorporated
    Inventors: Christopher Gallagher, C. Mitch Means
  • Publication number: 20020050355
    Abstract: Method of predicting paraffin deposition risks during hydrocarbon production and/or transport, applicable at an early reservoir characterization and production stage.
    Type: Application
    Filed: March 22, 2001
    Publication date: May 2, 2002
    Inventors: Isabelle Kowalewski, Veronique Ruffier-Meray, Guillaume Guehenneux, Alain-Yves Huc, Emmanuel Behar
  • Publication number: 20010052414
    Abstract: A method for predicting scale deposition in a general environment has been discovered which involves providing a localized environment where scale would preferentially form, where the localized environment is adjacent the general environment. Monitoring the deposition of scale in the localized environment is performed for the purpose of taking preemptive action to prevent scale deposition in the general environment once scale begins to form, or a certain threshold is reached. Scale is removed from the localized environment so that monitoring can be performed by the probe again. Preemptive action will often be the introduction of a scale inhibiting agent into the general environment. An apparatus for practicing the method of predicting and preventing scale deposition in a general environment is also described.
    Type: Application
    Filed: January 3, 2001
    Publication date: December 20, 2001
    Inventor: Paul Hammonds
  • Patent number: 6223822
    Abstract: A sampling device for use downhole is provided comprising a hollow body (24) having a fluid inlet port (26) for fluid entry to the interior thereof, characterised by a gas extraction system (64) associated with the hollow body (24) and capable of securing as a non-volatile component at least part of a volatile component dissolved in a fluid entering the hollow body (24), the gas extraction system being removable therefrom to allow quantitative analysis of the non-volatile component to be undertaken. The gas extraction system (64) is placed in a supplementary chamber (46) having an inlet (50) and an outlet (52) which is attached to the hollow body and through which fluid passes to enter the hollow body. The gas extraction system is iron oxide to fix sulphur from volatile hydrogen sulphide for later analysis.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: May 1, 2001
    Assignee: Schlumberger Technology Corporation
    Inventor: Timothy Gareth John Jones