Abstract: A multicomponent nanocapsule composition comprising a core particle, an oil phase encapsulating the core particle, and an aqueous phase in which the encapsulated core particle is suspended is provided. The porous particle includes a cationic surfactant encapsulated in a porous particle. The oil phase includes an anionic surfactant and a zwitterionic surfactant. A method of making a multicomponent nanocapsule composition is also provided. A method of treating a hydrocarbon-bearing formation with the multicomponent nanocapsule composition is provided. The method may include providing a multicomponent nanocapsule composition, introducing the multicomponent nanocapsule composition into the hydrocarbon-bearing formation, displacing hydrocarbons from the hydrocarbon-bearing formation by contacting the multicomponent nanocapsule composition with the hydrocarbons, and recovering the hydrocarbons.

Abstract: A method for recovering subsurface fluid from rock formations by adding an enzyme-based green solvent to a carrier fluid and injecting the enzyme-based green solvent and the carrier fluid into a production well. The enzyme-based green solvent and the carrier fluid are directed down a flow path of the production well. The solvent soaks in the production well before reversing the flow path of the production well. The enzyme-based green solvent and the carrier fluid travel up the flow path with a plurality of recovered deposits from the production well in the enzyme-based green solvent.

Abstract: Provided is an injection fluid that may include a nanoemulsion having an oil phase dispersed in an aqueous phase, and non-superparamagnetic magnetic nanoparticles that are present in the dispersed oil phase. Further provided is a method for preparing an injection fluid that may include preparing a nanoemulsion from an aqueous phase and an oil phase having non-superparamagnetic magnetic nanoparticles therein, and may be used to form nanodroplets of the non-superparamagnetic magnetic nanoparticles. Further provided is a method for tracking movement of an injection fluid. The method may include introducing a tagged injection fluid into a hydrocarbon-containing reservoir, the tagged injection fluid may be a nanoemulsion that includes: an aqueous phase, an oil phase dispersed in the aqueous phase, and non-superparamagnetic nanoparticles that are present in the dispersed oil phase; and tracking the movement of the tagged injection fluid.

Abstract: A method of estimating a real time production flowrate from a well by estimating a real time flowrate of a marker fluid in the well, and comparing the estimated flowrate with a baseline marker fluid flowrate; where the baseline marker fluid flowrate correlates to baseline production fluid flowrate. The baseline marker fluid flowrate is obtained by introducing an amount of a marker fluid in the well, monitoring the time over which the marker fluid travels a set distance, and estimating a flowrate of the marker fluid based on the monitored time and amount of marker fluid. The real time production flowrate is obtained by extrapolating the baseline production fluid flowrate by an amount derived from a comparison of the baseline and real time marker fluid flow rates.

Abstract: The invention concerns a method of marking a hydrocarbon liquid comprising the step of adding to said liquid, as a tracer compound, a compound of Formula I or Formula II: wherein at least one of R1-R6 in Formula I and at least one of R7-R14 in Formula II is selected from: i. a bromine or fluorine atom; ii. a partially or fully halogenated alkyl group; iii. a branched or cyclic C4-C20 alkyl group; iv. an aliphatic substituent linking two positions selected from R1-R6 in Formula I to one another or two positions selected from R7-R14 in Formula II to one another; or v. a phenyl group substituted with a halogen atom, an aliphatic group or halogenated aliphatic group and none of R1-R6 in Formula I and none of R7-R14 in Formula II being a sulphonate group or COOR15, where R15 represents H, C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, C3-C15 cycloalkyl or aryl.

Abstract: Method of marking a hydrocarbon liquid includes adding to the liquid, a tracer compound of Formula I or II: wherein at least one of R1-R6 in Formula I and at least one of R7-R14 in Formula II is selected from: i. a bromine or fluorine atom; ii. a partially or fully halogenated alkyl group; iii. a branched or cyclic C4-C20 alkyl group; iv. an aliphatic substituent linking two positions selected from R1-R6 in Formula I to one another or two positions selected from R7-R14 in Formula II to one another; or v. a phenyl group substituted with a halogen atom, an aliphatic group or halogenated aliphatic group and none of R1-R6 and none of R7-R14 being a sulphonate group or COOR15, where R15 represents H, C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, C3-C15 cycloalkyl or aryl.

Abstract: Systems and methods for monitoring and characterizing well bores, subterranean formations, and/or fluids in a subterranean formation using well evaluation pills are provided. In one embodiment, the methods comprise: introducing a well evaluation pill into a portion of a well bore penetrating a portion of a subterranean formation; allowing the well evaluation pill to interact with one or more components in the portion of the subterranean formation; detecting a change in the composition or properties of the well evaluation pill; and determining the presence of one or more components in the portion of the subterranean formation based at least in part on the detected change in the composition or properties of the well evaluation pill.

Abstract: The present invention relates to carbon-based fluorescent nano-agent tracers for analysis of oil reservoirs. The carbon-based fluorescent nano-agents may be used in the analysis of the porosity of a formation. The nanoagents are suitable for injection into a petroleum reservoir and may be recovered from the reservoir for the determination of hydrocarbon flow rates and retention times.

Abstract: A method for placing ball sealers within a well formed within a subterranean formation for sealing holes in a casing of the well is carried out by performing at least one of two operations. The first operation involves providing a tag with at least one ball sealer or a carrier fluid containing the at least one ball sealer to facilitate monitoring of the location of the ball sealer. A tag monitoring device is provided within the well for monitoring the location of the tag. The ball sealer and carrier fluid with the tag are introduced downhole into the well. Information from the monitor device regarding the location of the tag is communicated to a remote monitoring location to the thereby provide an indication of the location of the tag within the well to a surface location. In the second operation a container is provided within the well at a known location downhole within the well. The container contains at least one ball sealer.

Abstract: A method for estimating properties of a subterranean formation penetrated by a wellbore provides for injecting a fluid with the plurality of tracer agents wherein each tracer agent is an object of submicron scale, into the wellbore and formation, flowing the fluid back from the subterranean formation and determining the properties of the formation. The properties are determined by analyzing changes in the tracers size and type distribution function between the injection fluid and produced fluid.

Abstract: A method of estimating influx profile for well fluids (oil, gas, or water) to petroleum well with influx locations to a production flow, including: arranging tracer sources with tracer materials in levels of the well, arranged downstream and exposed to the fluids in the influx zones, each of the tracer sources having even release rate to the well fluid, inducing a transient in the production rate of the entire production flow by shutting in by a valve topside, changing the local exposure times of the tracer sources to the fluid, collecting samples, downstream at known sampling times, analyzing the samples for concentration and type of tracer material from the possible sources, based on the concentrations and their sampling sequence and the well geometry, calculating influx volumes from flow models.

Abstract: Methods and apparatus to control the additives to a chemical composition for use in the oil field services industry. Specifically, a method and apparatus to determine fluid parameters for a fluid, including introducing an inert tracer in a component; forming a fluid comprising the component; observing the concentration of the tracer in the fluid; calculating the concentration of the component in the fluid; and introducing the fluid into a subterranean formation. An apparatus and method to control fluid parameters of interest for an oilfield formulation fluid such as chemical composition including introducing an inert tracer in a component; forming a fluid comprising the component; observing the concentration of the tracer in the fluid; calculating the concentration of the component in the fluid; adjusting a flow rate when forming the fluid in response to the calculating; and introducing the fluid into a subterranean formation.

Abstract: A method of servicing a wellbore comprising placing an oil-based wellbore servicing fluid comprising an electrical conductivity enhancer into the wellbore and logging the wellbore by resistivity imaging. A method of servicing a wellbore comprising introducing an oil-based drilling fluid to a wellbore, identifying a subsection of the wellbore for imaging, introducing to the subsection of the wellbore a oil-based wellbore servicing fluid comprising a carbon nanotube wherein the servicing fluid comprising the electrical conductivity enhancer mixes with the oil-based drilling fluid; and imaging the subsection of the wellbore.

Abstract: A method of tracing flow of hydrocarbon from a subterranean reservoir including forming a dispersion, injecting a hydraulic fracturing fluid containing the dispersion down a well penetrating a hydrocarbon reservoir, thereafter collecting a sample of hydrocarbon fluid flowing from the reservoir, and analysing the sample to determine whether the tracer compound is present in the sample. The dispersion includes a discontinuous condensed phase having a hydrocarbon-soluble tracer compound and a continuous phase which includes an aqueous liquid.

Abstract: A remediation process that a employs improved quantitative method(s) of estimating of the volume and/or mass of contaminant in the subsurface, removal and or in situ degradation of the contamination using subsurface pulsing treatment (“SPT”) technology, and evaluation of the degree of remediation by re-applying the quantitative contaminant evaluation methods. The process uses SPT technology with the addition of a vacuum or sub-atmospheric pressure to an extraction well in order to create a push-pull effect to remove free contaminant or residual in conjunction with the pressure wave driving force created in the excitation or excitation well. The process can quantitatively measure the amount of residual contaminant, which up until now has not been possible or tractable using in situ methods, as well as measure the amount of residual that can be removed by SPT.

Abstract: A method of tracing flow of hydrocarbon from a subterranean reservoir including forming a dispersion, injecting a hydraulic fracturing fluid containing the dispersion down a well penetrating a hydrocarbon reservoir, thereafter collecting a sample of hydrocarbon fluid flowing from the reservoir, and analyzing the sample to determine whether the tracer compound is present in the sample. The dispersion includes a discontinuous condensed phase having a hydrocarbon-soluble tracer compound and a continuous phase which includes an aqueous liquid.

Abstract: A method for placing ball sealers within a well formed within a subterranean formation for sealing holes in a casing of the well is carried out by performing at least one of two operations. The first operation involves providing a tag with at least one ball sealer or a carrier fluid containing the at least one ball sealer to facilitate monitoring of the location of the ball sealer. A tag monitoring device is provided within the well for monitoring the location of the tag. The ball sealer and carrier fluid with the tag are introduced downhole into the well. Information from the monitor device regarding the location of the tag is communicated to a remote monitoring location to the thereby provide an indication of the location of the tag within the well to a surface location. In the second operation a container is provided within the well at a known location downhole within the well. The container contains at least one ball sealer.

Abstract: In an arrangement for monitoring of flow within a hydrocarbon well or reservoir by means of one or more tracers which are placed at subterranean locations such that they may be present in flow produced from the well, the analysis of the flow produced from the well is carried out using an electrochemical method, preferably voltammetry, to detect tracer chosen to undergo a detectable electrochemical reaction. The tracer may be provided as nanoparticles in the well fluid.

Abstract: A downhole screen assembly for dispensing a tracer material and methods for using the same are provided. The downhole screen assembly can include a body having a screen disposed thereabout. The downhole screen assembly can also include chamber proximate the screen. The downhole screen assembly can further include a first member disposed about the body. The first member can have a port in fluid communication with the chamber. The downhole screen assembly can further include a second member at least partially disposed on the first member. The second member can be removable and can seal the port.

Abstract: A method is disclosed having application notably towards ranking earth models responsive to dynamic heterogeneity. A plurality of earth models representing a subsurface reservoir are provided. Streamline analysis for each of the plurality of earth models is conducted. Flow Capacity (F) vs. Storage Capacity (?) curves are constructed for each of the plurality of earth models based on the streamline analysis. Dynamic heterogeneity for each of the plurality of earth models is computed from the Flow Capacity (F) vs. Storage Capacity (?) curves constructed for each of the plurality of earth models. The plurality of earth models are ranked responsive to dynamic heterogeneity.

Abstract: A fluid can be tracked in a wellbore utilizing at least one WID tag, such as an LW tag or an RFID tag, entrained in the fluid. A WID tag reader can be disposed and/or displaced in the wellbore, for example, on a drill string or a casing string. A reader can be utilized to locate the at least one WID tag in the wellbore. A reader can be housed in a drill string sub. A fluid entrained with at least one WID tag can be utilized as a tracer fluid. A WID tag can be entrained in cement or a drilling or fracture fluid.

Abstract: Delivery of a substance to a subterranean location is achieved by suspending the substance as nanoparticles in a carrier fluid in which the substance is insoluble. First a dispersible powder composition, is formed by dissolving the substance in a solvent, emulsifying the resulting solution as the dispersed phase of an emulsion, and freeze-drying the emulsion to a powder. On mixing the powder with a fluid in which the substance is insoluble, the insoluble substance becomes a dispersion of nanoparticles which is pumped to the subterranean location. At the subterranean location a tracer dispersed as nanoparticles may migrate from injected water into hydrocarbon in a hydrocarbon reservoir. Another possibility is that the carrier fluid contains polymer and the dispersed nanoparticles comprise an agent which participates in cross-linking and consequent viscosification of the polymer at the subterranean location.

Abstract: A method for a rapid verification of satisfactory clean-up at the end of the completion process when starting production of petroleum fluids while the completion rig is still at the well. The method includes marking one or more of separated zones along the well by one or more distinct tracers, before starting production. The tracers are added along with the completion or the clean-up fluid, and the tracers are arranged to be released by relative high concentrations from each zone to an inflowing fluid of oil or gas.

Abstract: Carbon-based fluorescent nano-agent tracers for analysis of oil reservoirs are provided. The carbon-based fluorescent nano-agents being inexpensive means of analyzing, among other properties, the porosity of a formation. The nanoagents are suitable for injection into a petroleum reservoir and can be subsequently recovered for determinations of flow rates and retention times.

Abstract: This invention relates to oil production, more specifically, oil production using the formation hydrofracturing process, and can be used for monitoring the operation of a producing oil well.

Abstract: Methods for releasing tracers into a well for diagnostic studies during subterranean-well operations comprise filling one or more hollow bodies with substances The system that comprise a cementing-plug-launching system, a drill string, casing, coiled tubing, wireline or combinations thereof. After the system is lowered into the well, the tracer substance may be remotely and safely released into the well.

Abstract: Monitoring of a wellbore which penetrates a reservoir is carried out by providing tracer material at one or more subterranean locations within or proximate the wellbore, so that tracer may enter the flow and be present in flow from the wellbore; repeatedly taking samples from the flow from the wellbore, and analyzing the samples for the presence of tracer, in the vicinity of the wellsite. Taking samples from the flow will generally be done at the surface and may be done by automatic equipment controlled by a programmed computer. The computer may be programmed to take action, such as operating a valve within the well, in response to detection of tracer. Sampling repeatedly and analyzing on site can provide information in something close to real time and thus integrates the use of tracers into an overall process of monitoring and control.

Abstract: A proppant composition comprises a non-radioactive, detectable tracer at least partially embedded in a ceramic composition. The composition may be prepared by agglomerating granules of the ceramic material and granules of the non-radioactive, detectable material to produce the particle by compression. Backflow of proppants in a fractured subterranean formation into which a plurality of particles of the proppant composition have been introduced may be tracked by analyzing a sample of the backflow by detecting for presence of the tracer in the sample.

Abstract: A method of testing the response of a subterranean formation to a formation treatment is described including the injection of a treatment fluid and the production of formation fluids from two separate boreholes or two boreholes from a single well such that the treatment fluid sweeps the formation between the two boreholes, and the use of downhole monitoring devices to determine a volume swept by the treatment fluid.

Abstract: Oilfields are stimulated by injecting an inflow stream of a fluid into an oil producing well linked to the oilfield, displacing the oil and recovering an outflow stream of fluid comprising the oil, wherein at least two streams are injected into at least two production zones of an oil well or are injected into at least two different oil producing wells from which at least two outflow streams from the two zones or wells are combined before recovering, with a scale inhibitor having detectable moieties being introduced into the oilfield(s) and/or into the fluid, and wherein two different scale inhibitors are used, dedicated to the two zones or wells, said different scale inhibitors having different detectable moieties that can be distinguished by analysis.

Abstract: A firing head assembly has a sealed chamber containing a piston, a firing pin, and an impact detonator. The firing head assembly and a perforating charge are installed within a sub and the sub is secured into a string of conduit being lowered into a wellbore. After cementing the conduit, the operator drills out the cement in the conduit, disintegrating the chamber and exposing the sealed chamber to the fluid pressure of the drilling fluid in the conduit. The drilling fluid pressure causes the piston to drive the firing pin against the detonator, which detonates the perforating charge. The operator then pumps down a logging tool to survey the well. Fluid in the conduit below the pump-down head can flow out the displacement perforation into the earth formation while the logging tool is moving downward.

Abstract: A method of localizing the source of a particulate produced with a fluid through a wellbore is provided, the method comprising the steps of: (A) providing marking composition comprising at least one marker that: (i) is capable of binding with a particulate; and (ii) has a detectable property distinguishable from the particulate; (B) introducing the marking composition: (i) through a wellbore; and (ii) into contact with at least a portion of a subterranean formation penetrated by the wellbore; (C) obtaining a fluid produced through the wellbore; and (D) analyzing a particulate produced with the produced fluid for the presence of the marker.

Abstract: A method for determining the extent of recovery of materials injected or otherwise introduced into oil wells or subsurface formations is practiced using a portable device. The portable device can also be used to determiner the occurrence of a predetermined condition in an oil well such as water break through in a production zone, or the opening or closing of a sliding sleeve. When, for example, water breakthrough is detected, the zone producing too much water can be plugged, using, for example, a flow-through bridge plug, if there are other producing zones further downhole.

Abstract: In a WAG flood oil is displaced from a subterranean formation by injecting water alternately with gas into a single injection completion per pattern. The ratio of water to gas injected is the WAG ratio. In this invention, two separate injection completions are used in each pattern, with one placed directly above the other. A very low WAG ratio is used for injection into the bottom extremity of the formation. A very high WAG ratio is injected into the upper interval, at as high a rate as can safely be used without fracturing the formation. In the preferred embodiment, two horizontal well bores serve as the two completion intervals. Proper design of this method gives a vertical sweep efficiency of the gas that is several-fold greater than the best of previous WAG flood designs, especially in thin formations.

Abstract: Disclosed is a method of determining the extent of recovery of materials injected into oil wells or subsurface formations. The method includes injection of one or more tracers into an oil well or into a formation. Included in the method are the steps of introducing a material of interest into the oil well or into the subsurface formation associated with the bore of the oil well; introducing a tracer into the oil well or into the subsurface formation associated with the bore of the oil well; recovering from the oil well a production fluid, analyzing the production fluid for a concentration of the chemical tracer present in the production fluid; and calculating the amount of material of interest recovered from the oil well using the concentration of the chemical tracer present in the production fluid as a basis for the calculation.

Abstract: A petroleum well having a well casing, a production tubing, a source of time-varying current, a downhole tracer injection device, and a downhole induction choke. The casing extends within a wellbore of the well. The tubing extends within the casing. The current source is located at the surface. The current source is electrically connected to, and adapted to output a time-varying current into, the tubing and/or the casing, which act as electrical conductors for providing downhole power and/or communications to the injection device. The injection device having a communications and control module, a tracer material reservoir, and an electrically controllable tracer injector.

Abstract: A method and apparatus for determining whether a tubing conveyed perforating (TCP) gun has fired by detecting a change in characteristics of the flow of an oil well. A method and apparatus detects the presence of fluorescent tracer dye to determine whether or not a TCP gun has fired. The method and apparatus detects a change is capacitance, or fiber optic electrical properties to determine whether or not a TCP gun has fired. The method and apparatus detects the number of charges fired to determine whether or not all TCP guns have fired and also provides a method and apparatus for determining the contributions of injection wells to producing wells by introducing fluorescent tracers into injection wells and detecting the presence of the fluorescent tracers at production wells. A method and apparatus is provided for placing fluorescent dye particles in a gravel pack to sense when a gravel pack is deteriorating by detecting the tracer dye particles in the well flow.

Abstract: Compositions and methods for determining the source of treatment fluids being produced from a production formation having multiple zones.

Abstract: Tracing hydraulic fractures, stimulations, selective cement jobs, etc. in oil and gas wells includes introducing into a well in a zone of interest a plurality of radio frequency transmitting elements each having an identification, moving in the well a reader tool operative for transmitting radio waves so as to generate and send a radio frequency signal for activating the radio frequency transmitting elements and thereafter to receive a signal returned from the corresponding radio frequency transmitting elements together with the identification of each radio frequency transmitting element, and analyzing data related to the sending of the radio frequency signal from the reader tool to the radio frequency transmitting element and the receiving of the radio frequency signal from the radio frequency transmitting elements with the identification of the radio frequency transmitting elements, so as to trace a corresponding hydraulic fracture, stimulation, selective cement job, etc., in the zone of interest.