Abstract: Methods for making efficient use of steam in a steam-assisted gravity drainage (SAGD) process for recovering heavy oils from tar sands and similar petroleum deposits are disclosed. The methods utilize a surfactant to generate steam foam in ways that maximize efficient use of steam. In some aspects, steam foam is used in water layers or gas caps that reside above steam chambers to prevent loss of steam from the steam chamber. The predominant use of relatively dry steam in SAGD processes makes it challenging to find ways to introduce surfactants and generate steam foam. However, decreasing the mobility of the steam by converting at least some of it to foam allows the wellbore and steam chambers above the injection site to be more fully developed, provides for more effective heat transfer to the heavy oil and rock, improves production, and allows recovery of the heavy oil with a minimum amount of steam usage.

Abstract: A method for detecting incremental oil production from an oil-bearing reservoir includes taking a baseline sample of the oil and analyzing the baseline sample of oil to establish a baseline compositional signature for the oxygen-containing organic compounds in the oil. In addition, the method includes commencing a low salinity waterflood by injecting a low salinity water into the reservoir from an injection well. Further, the method includes recovering oil from a production well. Still further, the method includes taking post-flood samples of the oil produced from the production well over time. The method also includes analyzing the post-flood samples of oil to establish post-flood compositional signatures for the oxygen-containing organic compounds in the oil. Moreover, the method includes identifying a difference between one or more of the post-flood compositional signatures and the baseline compositional signature that is characteristic of incremental oil released by the low salinity waterflood.

Abstract: The present invention relates to an in situ staged steam extraction method for removing petroleum products from a heavy oil or bitumen reservoir from subterranean locations. Specifically, each injection stage comprises a different steam composition. A steam composition may consist essentially of steam or may comprise one or more enhanced oil recovery agent.

Abstract: The invention provides methods for mobilizing and recovering petroleum from subterranean formations by in situ combustion.

Abstract: A system and method for gasification of a feedstock in a subterranean formation to produce syngas is described. An injection well is completed in the formation to inject an oxidant, provide an ignition source and convey the feedstock that includes water and one or more of a biomass, waste plastic, coal, bitumen and petcoke. Volatized hydrocarbons and gaseous reaction products are simultaneously withdrawn from a producer well from the subterranean formation to the surface. This syngas product is treated at the surface for power generation or conversion to transportation fuels and/or plastics. This method provides a low capital cost gasification unit which is capable of processing a variety of feedstock mixtures.

Abstract: A method of producing heavy oil from a heavy oil formation by combining electromagnetic heating to achieve fluid communication between wells, following by in situ combustion to mobilize and upgrade the heavy oil.

Abstract: The present invention relates to methods of treating heavy crude oil on the surface or in situ. The methods of the present invention include: (a) mixing the heavy crude oil with a solvent; (b) subjecting the mixture to ultrasonic vibrations; and (c) subjecting mixture treated with ultrasonic vibrations to microwave energy.

Abstract: The inhibition of anionic surfactant retention phenomena in an oil reservoir, especially in a carbonate-based or argillaceous reservoir, by the use of at least one compound corresponding to the formula R—O-(A)m-H, in which R is a hydrocarbon-based group comprising from 6 to 40 carbon atoms, A is a hexose or pentose unit, and m is a non-zero number ranging from 1 to 10, is described herein.

Abstract: The present invention provides a grease composition or a lubricating oil composition which is capable of effectively preventing hydrogen brittleness-caused peeling from occurring on a rolling surface of a rolling bearing, is excellent in durability in a high temperature and speed operation, and can be used for a long time. A grease-packed bearing (1) has an inner ring (2), an outer ring (3), and a plurality of rolling elements (4). A sealing member (6) for sealing a grease composition (7) is provided at openings (8a) and (8b) disposed at both axial ends of the inner ring (2) and the outer ring (3). The grease composition (7) includes a base grease composed of a base oil and a thickener and an additive added to the base grease. The additive contains at least one compound selected from among plant-derived polyphenolic compounds and compounds formed by decomposition thereof.

Abstract: An enhanced oil recovery technique that combines gas injection with EM radiation to heat and mobilize heavy oil at least until fluid communication is achieved.

Abstract: A steam environmentally generated drainage system and method for producing hydrocarbons from a formation using in situ steam generation and gravity drainage. The system and method includes a first well as a circulation and production well, a second well as a circulation, injection and combustion well, and a third well as an injection well. The second well is configurable to have a fuel tubing, a gas tubing, and an igniter. The third tubing injects a vaporizable fluid into the formation so as to be vaporized by combustion gases created by the in situ combustion in the second well. Hydrocarbon fluids are produced from the first well and lifted to the surface for process. The third well can be configured to also produce combustion gases so as to control a gas chamber pressure of a gas chamber created by the rising combustion gases.

Abstract: A downhole steam generation apparatus and method of use are provided. The apparatus may include an injection section, a combustion section, and an evaporation section. The injection section may include a housing, injector elements, and injector plate. The combustion section may include a liner having channels disposed therethrough. The evaporation section may include conduits in fluid communication with the channels and the combustion chamber, and a nozzle operable to inject a fluid from the channels to the combustion chamber in droplet form. A method of use may include supplying fuel, oxidant, and fluid to the apparatus; combusting fuel and oxidant in a chamber while flowing the fluid through a plurality of channels disposed through a liner, thereby heating the fluid and cooling the liner; and injecting droplets of the heated fluid into the chamber and evaporating the droplets by combustion of the fuel and the oxidant to produce steam.

Abstract: A method for producing steam includes combusting a fuel and an oxidant to generate heat in a combustion stream, and injecting impure water into the combustion stream such that the heat produces a steam stream including particulate matter precipitated from the impure water. A steam generator includes a combustion chamber that has an initial section including an oxidant feed that is substantially free of nitrogen and a fuel feed, and downstream from the initial section at least one liquid water feed.

Abstract: A method for extracting energy from hydrocarbons located in a geologic reservoir is presented, including the steps of: oxidizing the hydrocarbons; extracting heat generated from oxidizing the hydrocarbons, relocating oxidized gases away from the oxidizing hydrocarbons; and replenishing oxygen towards the oxidizing hydrocarbons. The extraction of heat further includes: evaporating a liquid; transferring the evaporated liquid to the surface; and recovering low-NaCl, low-precipitate water from the evaporated liquid. The replenishing of oxygen towards the oxidizing hydrocarbons further includes: generating oxygen from water; and transferring the generated oxygen toward the oxidizing hydrocarbons; and combining hydrogen derived from the generating step with surface oxygen, whereby heat and low-precipitate, pure water is produced.

Abstract: High permeability channels or wormholes found in hydrocarbon reservoirs having hydrocarbon-bearing formations can be remediated by heating the formation with dry, hot flue gases, injecting produced water into the formation through an injection well, and forming steam within the formation and spaced away from the injection well. The steam can be created at a steam generation interface occurring between a dry, hot gaseous drive front and an injected water front. Managing a quality of the steam formed along the steam generation interface, by increasing the combustion gas flow rate or decreasing the rate of water injection, allows for the initiation of precipitation and controlled deposition of solids dissolved in the produced water.

Abstract: The invention describes a method for treating near-wellbore zones involving the steps of injecting a magnesium metal with a catalyst into the desired area of the formation to be treated. Subsequently, combustive-oxidizing solution (COS) is injected into the zone of the formation to be treated. The COS initially reacts with the magnesium, which in turn initiates a vigorous oxidation reaction of the COS. The reaction gases and heat produced by the COS oxidation reaction are harnessed to enhance the productivity of the well by creating fractures in the treatment zone and by melting of paraffin and resin deposits in the treatment zone. As a final step, acid is injected into the formation to react with the formation thereby further enhancing the porosity of the fractures. In one embodiment, the COS uses ammonium nitrate as the oxidizer, and in another, urea or ethylene glycol may be added as a reaction fuel.

Abstract: A system and method for cracking, hydrogenating and extracting oil from underground deposits includes a gasifier, an injection well and a production well. The gasifier creates high pressure, high temperature syngas. The pressurized syngas flows through an injection well into a deposit of oil under the ground to crack and hydrogenate the oil to produce upgraded oil with a reduced density and viscosity. The production well of the system receives the reduced density and viscosity oil, transports it above the ground where it may be further separated into a portion that may be sold and a portion that can be gasified in the gasifier.

Abstract: A process for hydrocarbon recovery from an oil sands reservoir having a mobile fluid zone above a bitumen zone. The process includes generating, in the bitumen zone a mobilized and through a mobility enhancing process. The process also includes recovering at least some of the original oil-in-place and injecting an oxidizing gas through an oxidizing gas injection well into the reservoir to support in situ combustion in the reservoir. The process includes generating fluid communication between the mobile fluid zone and the mobilized zone and recovering hydrocarbons mobilized by the in situ combustion using a hydrocarbon production well that is in fluid communication with the mobile fluid zone and the mobilized zone.

Abstract: A system for producing oil and/or gas from an underground formation comprising a first array of wells dispersed above the formation; a second array of wells dispersed above the formation; wherein the first array of wells comprises a mechanism to inject a miscible enhanced oil recovery formulation into the formation while the second array of wells comprises a mechanism to produce oil and/or gas from the formation for a first time period; and a means to convert at least a portion of the miscible enhanced oil recovery formulation within the formation into another compound during a second time period.

Abstract: Air and ammonia gas are introduced into a subterranean formation during the in-situ combustion to increase the mobility of hydrocarbons in a subterranean formation and facilitate recovery of the hydrocarbons from the subterranean formation. The air supports in-situ combustion of a portion of the hydrocarbon within the subterranean formation to form water and establish a combustion front. The ammonia gas contacts the hydrocarbons ahead of the combustion front and reacts in-situ with naphthenic acid in the hydrocarbon to form a surfactant. The hydrocarbons, water and surfactant then form an oil-in-water emulsion that drains more freely through the formation. A production well, in fluid communication with the hydrocarbons ahead of the combustion front, may be used to remove the oil-in-water emulsion from the subterranean formation.

Abstract: The present invention is directed towards methods and apparatus to release energy into wells using combustion of monopropellants. More specifically, this invention is directed to industrial methods to enhance the extraction of well fluids from wells by using the in-situ energy released from this inventions apparatus, methods, catalyst, and fluids blends for subterranean catalytic combustion of monopropellants.

Abstract: The present invention provides a method of recovering a hydrocarbon mixture from a subterranean formation comprising: (i) injecting an oxygen-rich gas into said formation; (ii) combusting said oxygen-rich gas in said formation thereby heating and reducing the viscosity of said hydrocarbon mixture and generating CO2-rich gas; (iii) recovering said heated hydrocarbon; and (iv) capturing at least a portion of CO2 from said CO2-rich gas.

Abstract: The present invention relates to a novel method of maintaining a steady and/or proper water-gas ratio for the wet in situ combustion process for oil recovery. In particular, the method comprises mixing water with a foaming agent, or some other colloid capable of generating foam, in addition to gas. The foam carries the water through heated reservoirs more efficiently and prevents separation from the gas. As such, more heat can be scavenged, thus an increased amount of steam is generated and transferred to the oil to increase its recovery.

Abstract: A process to recover hydrocarbons from a reservoir, where the hydrocarbons have an initial viscosity greater than 100,000 cp, preferably greater than 1,000 cp, the process including: (a) Initially injecting oxygen into the reservoir; (b) Allowing for combustion of the oxygen to vaporize connate water in the hydrocarbon reservoir; (c) Collecting hydrocarbons in a substantially horizontal production well in the reservoir and where the substantially horizontal production well has a length greater than about 800 metres.

Abstract: A process to recover hydrocarbons from a reservoir having at least one lean zone, wherein said lean zone has an initial bitumen saturation level less than about 0.6, said process including: i) Initially injecting of oxygen into said reservoir; ii) Allowing for combustion of said oxygen to vaporize connate water in said at least one lean zone; and iii) Recovering said hydrocarbons from said reservoir.

Abstract: A method for treating water at a water treatment facility is provided. In one aspect, the water has been circulated through a subsurface formation in a shale oil development area. The subsurface formation may comprise shale that has been spent due to pyrolysis of formation hydrocarbons. The method in one embodiment includes receiving the water at the water treatment facility, and treating the water at the water treatment facility in order to (i) substantially separate oil from the water, (ii) substantially remove organic materials from the water, (iii) substantially reduce hardness and alkalinity of the water, (iv) substantially remove dissolved inorganic solids from the water, and/or (v) substantially remove suspended solids from the water. The method may further includes delivering the water that has been treated at the water treatment facility re-injecting the treated water into the subsurface formation to continue leaching out contaminants from the spent shale.

Abstract: A downhole steam generation system may include a burner head assembly, a liner assembly, a vaporization sleeve, and a support sleeve. The burner head assembly may include a sudden expansion region with one or more injectors. The liner assembly may include a water-cooled body having one or more water injection arrangements. The system may be optimized to assist in the recovery of hydrocarbons from different types of reservoirs. A method of recovering hydrocarbons may include supplying one or more fluids to the system, combusting a fuel and an oxidant to generate a combustion product, injecting a fluid into the combustion product to generate an exhaust gas, injecting the exhaust gas into a reservoir, and recovering hydrocarbons from the reservoir.

Abstract: Systems and methods for hydrotreating a liquid fraction of a shale oil stream using hydrogen gas that is concentrated from a gaseous fraction of the shale oil stream. The systems and methods include providing a portion of the gaseous fraction to a sorptive separation assembly and separating a concentrated hydrogen stream from the portion of the gaseous fraction within the sorptive separation assembly. The system and methods further include providing the concentrated hydrogen stream and the liquid fraction to a hydrotreater and reacting the concentrated hydrogen stream with the liquid fraction within the hydrotreater to produce the hydrotreated liquid stream. The systems and methods may include generating the shale oil stream within a subterranean formation using an in situ process, such as an in situ shale oil conversion process and/or providing a supplemental hydrogen stream to the hydrotreater.

Abstract: Synthesis gas is more effectively produced from the underground gasification of coal from a coal seam when the casing lining is cemented with a cementitious slurry containing a cementitious material, graphite and an aluminum silicate, such as metakaolin. The cementitious slurry of the cement mix sets as a cement sheath at bottomhole static temperatures less than or equal to 65° C. The set cement may withstand extreme dry heat temperatures which are greater than or equal to 800° C.

Abstract: A low electrical conductivity water-based wellbore fluid for use in drilling wells through a formation containing a clay which swells in the presence of water, said wellbore fluid that includes an aqueous base fluid; and a polymeric non-ionic tertiary amine is disclosed. Methods of using such fluids are also disclosed.

Abstract: A method for monitoring production from a methane hydrate reservoir includes obtaining a plurality of temperature measurements in a wellbore connected with the methane hydrate reservoir; and deriving a parameter relating to conversion of methane hydrate to carbon dioxide (CO2) hydrate by injection of liquid CO2, wherein the deriving uses a modeling program and the plurality of temperature measurements, wherein the modeling program uses at least one parameter relating to a thermodynamic properties that are substantially different between methane and CO2. The at least one parameter relating to thermodynamic properties may include Joule-Thomson coefficients of methane and CO2. The parameter relating to the conversion of methane hydrate to CO2 hydrate may include a ratio of methane and CO2 in a mixed fluid.

Abstract: An enhanced oil recovery method is provided. This method includes; introducing a first essentially pure oxygen stream into a subterranean hydrocarbon-bearing formation traversed by at least one injection well and at least one production well, and initiating and sustaining in-situ combustion in the vicinity of the injection well. This method also includes introducing a second essentially pure oxygen stream and a hydrocarbon-containing fuel gas stream into the combustion device of a power generation system, wherein the combustion device produces an exhaust gas stream comprising water and carbon dioxide. This method also includes separating the exhaust gas stream into a stream of essentially pure water, and a stream of essentially pure carbon dioxide, and introducing at least a portion of the essentially pure carbon dioxide stream into the subterranean hydrocarbon-bearing formation prior to initiating the in-situ combustion.

Abstract: A composition is provided for lowering a pH of a drilling fluid. The composition includes HCl, urea, complex substituted keto-amine-hydrochloride, an alcohol, an ethoxylate, and a ketone. A method of using the composition includes adding the composition to a drilling fluid for a well to assist in lowering a pH thereof. Methods are also provided for performing hydraulic fracturing of an oil or a gas well, for adjusting a pH of a drilling fluid, for adjusting and maintaining a pH of a process fluid, for solubilizing calcium carbonate in an aqueous suspension or dispersion of calcium carbonate, for removing a foulant in a fluid-handling element, and for adjusting a pH and lowering a salt level of turf.

Abstract: An underground reservoir is provided comprising an injection well and a production well. The production well has a horizontal section oriented generally perpendicularly to a generally linear and laterally extending, upright combustion front propagated from the injection well. The method relates to controlling location of inflow into a production well during in situ combustion. The horizontal section of the production well includes blocking agents to prevent well failure.

Abstract: A burner is arranged for access to a cavity in a target zone of a hydrocarbon reservoir. The burner is operated into the cavity to create and sustain hot combustion gases at a steady state for flowing into and permeating through the target zone. Water is injected into the target zone and permeates laterally therein. The hot combustion gases and the water in the target zone interact to form a steam drive front in the hydrocarbon reservoir.

Abstract: A burner with a casing seal is used to create a combustion cavity at a temperature sufficient to reservoir sand. The burner creates and sustains hot combustion gases at a steady state for flowing into and permeating through a target zone. The casing seal isolates the combustion cavity from the cased wellbore and forms a sealed casing annulus between the cased wellbore and the burner. Water is injected into the target zone, above the combustion cavity, through the sealed casing annulus. The injected water permeates laterally and cools the reservoir adjacent the wellbore, and the wellbore from the heat of the hot combustion gases. The hot combustion gases and the water in the reservoir interact to form a drive front in a hydrocarbon reservoir.

Abstract: A method of recovering energy from a subsurface hydrocarbon containing formation includes introducing an oxidizing fluid in a wellbore positioned in at least a first portion of the formation. At least a portion of the first portion of the formation has been subjected to an in situ heat treatment process. The portion includes a treatment area having elevated levels of coke substantially adjacent the wellbore. The pressure in the wellbore is increased by introducing the oxidizing fluid under pressure such that the oxidizing fluid substantially permeates a majority of the treatment area and initiates a combustion process. Heat from the combustion process is allowed to transfer to fluids in the treatment area. Pressure decreases in the wellbore such that heated fluids from the portion of the formation are conveyed into the wellbore. The heated fluids are transferred to a heat exchanger configured to collect thermal energy.

Abstract: A method for producing hydrocarbon fluids from an organic-rich rock formation to a surface facility is provided. The method may include heating the formation in situ to cause pyrolysis of formation hydrocarbons, and producing production fluids from the formation via two or more wells. The produced fluids have been at least partially generated as a result of pyrolysis of the formation hydrocarbons. In addition, the produced fluids comprise non-condensable fluids, or gases, which taken together have an averaged Wobbe Index which varies at a rate of more than 5% over a period of time. The method also includes controlling production from one or more of the wells such that a combination of the production fluids from the wells results in a combined gas stream that's averaged Wobbe Index varies at a rate of less than 5% over the period of time. The combined stream comprises combustible hydrocarbon fluids.

Abstract: Enhanced recovery of crude oil from an oil well is provided by in-situ cracking of an oxygenated organic compound to form hydrogen. The crude oil is then hydrogenated and hydrogenation reaction products and crude oil are recovered from the oil well.

Abstract: The invention provides methods for natural gas and oil recovery, which include the use of air injection and in situ combustion in natural gas reservoirs to facilitate production of natural gas and heavy oil in gas over bitumen formations.

Abstract: An enhanced oil recovery method is provided. This method includes; introducing a first essentially pure oxygen stream into a subterranean hydrocarbon-bearing formation traversed by at least one injection well and at least one production well, and initiating and sustaining in-situ combustion in the vicinity of the injection well. This method also includes introducing a second essentially pure oxygen stream and a hydrocarbon-containing fuel gas stream into the combustion device of a power generation system, wherein the combustion device produces an exhaust gas stream comprising water and carbon dioxide. This method also includes separating the exhaust gas stream into a stream of essentially pure water, and a stream of essentially pure carbon dioxide, and introducing at least a portion of the essentially pure carbon dioxide stream into the subterranean hydrocarbon-bearing formation prior to initiating the in-situ combustion.

Abstract: An apparatus, system, and method are disclosed for in-situ extraction of hydrocarbons from a hydrocarbon-bearing formation. The system includes a well drilled through a hydrocarbon-bearing formation, and a completion unit that places an injection tube near a fluid injection point near the bottom of a target zone and a production tube near a fluid production point near the top of the target zone. An isolation unit isolates the fluid injection point from the fluid production point such that injected fluid flows through the target zone. The system further includes a heat source, and a fluid that delivers thermal energy from the heat source to the hydrocarbons in the target zone to entrain the hydrocarbons in the fluid. The resulting production fluid is heated, free hydrogen is added, and the production fluid is treated on a catalytic reactor to reduce the size of the hydrocarbon chains.

Abstract: A novel method is provided for in situ combustion and recovery of oil from underground reservoirs including injecting oxygen into the reservoir at a region near the reservoir floor, establishing a combustion front wherein hot combustion gases rise at the combustion front, withdrawing hot combustion gases from a region near the reservoir ceiling, and extracting oil from a horizontal production well near the reservoir floor.

Abstract: The invention provides methods for natural gas and oil recovery, which include the use of air injection and in situ combustion in natural gas reservoirs to facilitate production of natural gas and heavy oil in gas over bitumen formations.

Abstract: The present invention is a process for recovering oil from an underground oil-containing reservoir. The process includes providing one or more injection wells for injecting a gaseous fluid (steam and air) into the reservoir, the one or more injection wells having a plurality of generally horizontal injector legs, the injector legs positioned within a first depth region in the reservoir. The process further includes providing one or more extraction wells for recovering oil from the reservoir, the one or more extraction wells having plurality of generally horizontal extractor legs, the extractor legs positioned within a second depth region in the reservoir below the first depth region and spaced between the injector legs. Gaseous fluid, typically steam, is injected through the injector legs for a first period of time; and then air is injected through at least one of the injector legs. Alternative embodiments of the invention are also described.

Abstract: A modified process for recovering oil from an underground reservoir using the an in situ combustion process. A diluent, namely a hydrocarbon condensate, is injected within a separate wellbore, or alternatively within said separate wellbore and via tubing in a horizontal wellbore portion, preferably proximate the toe, of a vertical-horizontal well pair, to increase mobility of oil.

Abstract: A method of locating and controlling subsurface coal fires is provided that includes mapping a subsurface coal bed fire using a magnetometer, where the mapping includes locating a combustion zone and an air inlet to the combustion zone of the coal bed fire, drilling an injection port from the earth surface to a previously burned zone of the combustion zone, where the injection port is disposed between the air inlet and the combustion zone, inserting a tube in the injection port, where the tube has an exterior tube seal disposed around the tube, and the exterior tube seal isolates the earth surface from the combustion zone along an exterior of the tube. The method further includes injecting an inert gas through the tube to the combustion zone, where the inert gas controls the combustion zone of the coal bed fire.

Abstract: This method deals in recovering energy in-situ from an underground resource and upgrading such resource above ground. It consists of injecting a hot gas to pyrolyze it to produce gases and liquids with high hydrogen content and a residual hot char. The gases and liquids together with the injected hot gas form a mixture of gases and liquids that is brought above ground and treated into a clean mixture of gases and liquids rich in hydrogen and then used as a chemical feedstock and/or transportation fuel. Following the pyrolyzation of the resource, carbon dioxide and air are injected into the residual hot char to convert the CO2 into 2CO+N2, which is brought above ground and treated into a clean lean gas. This lean gas is used to generate efficient electric power, heat the injected gas for pyrolysis, and convert the 2CO+N2 as a feedstock into fertilizer.

Abstract: A modified process for recovering oil from an underground reservoir using the toe-to-heel in situ combustion process. A diluent, namely a hydrocarbon condensate, is injected within a horizontal wellbore portion, preferably proximate the toe, of a vertical-horizontal well pair, or alternatively into an adjacent injection well, or both, to increase mobility of oil.

Abstract: An underground reservoir is provided comprising an injection well and a production well. The production well has a horizontal section oriented generally perpendicularly to a generally linear and laterally extending, upright combustion front propagated from the injection well. The method relates to controlling location of inflow into a production well during in situ combustion. The horizontal section of the production well includes blocking agents to prevent well failure.