Specific Propping Feature (epo) Patents (Class 166/280.1)
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Patent number: 8205675Abstract: The method disclosed herein includes the introduction of proppant-free stage and a proppant laden stage into the wellbore and/or subterranean formation. The method increases the effective fracture width and enhances fracture conductivity within the formation. Either the proppant-free stage or the proppant laden stage contains a breaker. The other stage contains a viscosifying polymer or viscoelastic surfactant to which the breaker has affinity. The proppant-free stage may be introduced prior to introduction of the proppant laden stage into the wellbore and/or formation. Alternatively, the proppant laden stage may be introduced into the wellbore and/or formation prior to introduction of the proppant-free stage.Type: GrantFiled: October 9, 2008Date of Patent: June 26, 2012Assignee: Baker Hughes IncorporatedInventors: Harold Dean Brannon, Brian N. Ward
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Publication number: 20120145390Abstract: Proppant used to keep open a fissure in a reservoir created by hydraulic or other action is disclosed. The proppant demonstrates a reduced specific gravity controlled by the geometry of the structure of the proppant. Proppant must be capable of withstanding the hydrostatic environment of the hydraulic pumping system, pass through a perforation in the casing of the well, travel into the fissure, and, upon reduction of hydrostatic pressure, withstand the closure pressure of the formation. A proppant having neutral buoyancy or substantial neutral buoyancy yet capable of withstanding the hydraulic and closure pressures is described that has a tubular structure hollow in the center with a wall of material sufficiently strong to withstand the majority of closure pressures.Type: ApplicationFiled: December 8, 2011Publication date: June 14, 2012Inventors: Joseph Buford PARSE, Bruce Donald Jette
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Publication number: 20120138295Abstract: An improved proppant and method of use are shown for use in wellbore operations in which a well is hydraulically fractured with a suitable fluid to create fractures in a surrounding subterranean formation where the proppant is used to hold the fracture open and provide a conduit for the production of fluids or gases. The improved proppant has associated therewith a chemically active adjunct material designed to react with the fracturing fluid, with the surrounding subterranean formation or with a fluid produced from the subterranean formation. The chemically active adjunct material may be an ion exchange resin which reacts with any multivalent ions released into solution by reaction of the fracturing fluid with the surrounding formation or with any multivalent ions dissolved in formation fluids, in order that these fluids being produced from the well will not contain these ions, requiring more exotic treatment procedures on the well surface.Type: ApplicationFiled: November 18, 2011Publication date: June 7, 2012Inventor: Rudolf J. Novotny
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Patent number: 8188013Abstract: This invention relates to the use of degradable fibers, and more particularly, to self-degrading fibers and their associated methods of use and manufacture. In one embodiment, the present invention provides a self degrading fiber comprising: an outer shell, and a core liquid.Type: GrantFiled: March 11, 2009Date of Patent: May 29, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Michael N. Mang, Bradley L. Todd
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Patent number: 8186431Abstract: Prior to a hydraulic fracturing treatment, the requisite apparent viscosity of a transport fluid, ?fluid, containing a proppant for a desired propped fracture length of a fracture, DPST, may be estimated in accordance with Equation (I): ?fluid=(1/A)×qi×(1/DPST)B×(CTRANS)×(?SGPS)×(d2prop)??(I) wherein: A is the multiplier and B is the exponent from the Power Law equation of velocity of the transport slurry vs. distance for the fracture geometry; qi is the injection rate per foot of injection height, bpm/ft; CTRANS is the transport coefficient; ?SGPS is SGprop?SGfluid, SGprop being the specific gravity of the proppant and SGfluid being the specific gravity of the transport fluid; and dprop is the median proppant diameter, in mm.Type: GrantFiled: September 23, 2011Date of Patent: May 29, 2012Assignee: Baker Hughes IncorporatedInventor: Harold Dean Brannon
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Publication number: 20120118566Abstract: Methods and systems of fracturing subterranean formations to are provided comprising pumping metacritical phase natural gas into a subterranean formation to create or extend one or more fissures in the formation. Methods and systems may further comprise maintaining or increasing pressure of the metacritical phase natural gas in the formation by pumping more metacritical phase natural gas into the fissures to hold the fissures open. Methods and systems may further comprise delivering a proppant into the subterranean formation. Disclosed methods and systems may be used to extract hydrocarbons from subterranean formations without the use of liquids.Type: ApplicationFiled: January 26, 2012Publication date: May 17, 2012Applicant: Expansion Energy, LLCInventor: David Vandor
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Patent number: 8176981Abstract: A composition comprising a nonionic fluorinated polymeric surfactant having a weight average molecular weight of least 100,000 grams per mole, the nonionic fluorinated polymeric surfactant comprising: divalent units independently represented by formula (I): in a range from 30% to 65% by weight, based on the total weight of the nonionic fluorinated polymeric surfactant; and divalent units independently represented by formula (II): in a range from 70% to 35% by weight, based on the total weight of the nonionic fluorinated polymeric surfactant. Rf is a perfluoroalkyl group having from 3 to 4 carbon atoms; R and R2 are each independently hydrogen or alkyl of 1 to 4 carbon atoms; R1 is alkyl of 16 to 24 carbon atoms; and n is an integer from 2 to 11. Foams comprising the nonionic fluorinated polymeric surfactant and a liquid hydrocarbon and methods of making and using the foams are also disclosed.Type: GrantFiled: January 18, 2008Date of Patent: May 15, 2012Assignee: 3M Innovative Properties CompanyInventors: Patricia M. Savu, Michael J. Sierakowski
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Publication number: 20120111563Abstract: The invention discloses a storable composition for oilfield application including a slurry of a carrier fluid and a particulate blend made of proppant; the particulate blend comprising at least a first amount of particulates having a first average particle size between about 100 and 5000 ?m and at least a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size; such that a packed volume fraction of the particulate blend exceeds 0.74 and the particulate blend volume is sufficient to substantially avoid settling of the particulate in the carrier fluid.Type: ApplicationFiled: November 8, 2010Publication date: May 10, 2012Inventors: Carlos Abad, Marieliz Garcia-Lopez De Victoria, Kevin W. England, Isaac Aviles
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Publication number: 20120111565Abstract: The invention discloses a method of treating a subterranean formation of a well bore, including the steps of providing a first treatment fluid substantially free of macroscopic particulates; pumping the first treatment fluid into the well bore at different pressure rates to determine the maximum matrix rate and the minimum frac rate; subsequently, pumping the first treatment fluid above the minimum frac rate to initiate at least one fracture in the subterranean formation; providing a second treatment fluid comprising a second carrier fluid, a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 ?m and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.Type: ApplicationFiled: November 8, 2010Publication date: May 10, 2012Inventors: Marieliz Garcia-Lopez De Victoria, Carlos Abad
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Patent number: 8171992Abstract: Prior to a hydraulic fracturing treatment, ?SGPS for a desired propped fracture length, DPST, may be estimated wherein ?SGPS=SGprop?SGfluid (SGprop being the specific gravity of the proppant and SGfluid being the specific gravity of the transport fluid) in accordance with Equation (I): ?SGPS=(A)×(1/qi)×(DPST)B×(1/CTRANS)×(1/d2prop)×(?fluid)??(I) wherein: A is the multiplier and B is the exponent from the Power Law equation of velocity of the transport slurry vs. distance for the fracture geometry; qi is the injection rate per foot of injection height, bpm/ft; CTRANS is the transport coefficient; dprop is the median proppant diameter, in mm.; and ?fluid is the apparent viscosity of the transport fluid, in cP.Type: GrantFiled: September 23, 2011Date of Patent: May 8, 2012Assignee: Baker Hughes IncorporatedInventor: Harold Dean Brannon
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Patent number: 8167039Abstract: Prior to a hydraulic fracturing treatment, the requisite median diameter of a proppant, dprop, into a fracture of defined length, DPST, may be estimated in accordance with Equation (I): (dprop)2=(A)×(1/qi)×(DPST)B×(1/CTRANS)×(1/?SGPS)×(?fluid)??(I) wherein: A is the multiplier and B is the exponent from the Power Law equation of velocity of the transport slurry vs. distance for the fracture geometry; qi is the injection rate per foot of injection height, bpm/ft; CTRANS is the transport coefficient; ?SGPS is SGprop?SGfluid, SGprop being the specific gravity of the proppant and SGfluid being the specific gravity of the transport fluid; and ?fluid is the apparent viscosity of the transport fluid, in cP.Type: GrantFiled: September 23, 2011Date of Patent: May 1, 2012Assignee: Baker Hughes IncorporatedInventor: Harold Dean Brannon
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Patent number: 8167043Abstract: A method for well treatment by forming a temporary plug in a fracture, a perforation, a wellbore, or more than one of these locations, in a well penetrating a subterranean formation is provided, in which the method of well treatment includes: injecting a slurry comprising a degradable material, allowing the degradable material to form a plug in a perforation, a fracture, or a wellbore in a well penetrating a formation; performing a downhole operation; and allowing the degradable material to degrade after a selected time such that the plug disappears.Type: GrantFiled: August 8, 2008Date of Patent: May 1, 2012Assignee: Schlumberger Technology CorporationInventors: Dean M. Willberg, Marina Bulova, Christopher N. Fredd, Alexey Vostrukhov, Curtis L. Boney, John Lassek, Ann M. W. Hoefer, Philip F. Sullivan
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Patent number: 8167042Abstract: Methods of forming gravel packs while reducing fluid loss to the surrounding subterranean formation. The methods involve suspending gravel that has been coated with a tackifying agent and degradable fines into a low viscosity carrier fluid and then placing that suspension into a subterranean formation so as to form a gravel pack wherein, as the gravel pack is placed, the degradable fines to de-adhere from the gravel and to fill at least a portion of the pore spaces within the gravel pack so as to reducing fluid loss through the gravel pack.Type: GrantFiled: November 18, 2009Date of Patent: May 1, 2012Assignee: Halliburton Energy Services, Inc.Inventor: Bradley L. Todd
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Publication number: 20120090840Abstract: A substance and method for treating a subterranean formation using hydraulic fracturing is provided. The method includes treating a formation with a non-metallic deformable proppant that may be substantially deformable, “elastically flexible”, or “plastically compressible.” The method may include the steps of injecting a carrier fluid into the formation at a pressure and a flow rate sufficient to create or open an existing fracture or fracture network in the formation, and placing at least a portion of the deformable proppant in the fracture by way of the carrier fluid so that the deformable proppant forms substantially a partial monolayer in the fracture, and reducing the pressure and/or the flow rate sufficiently to allow the fracture in the formation to at least partially close, wherein at least a portion of the deformable proppant remains in the fracture to prop open at least a portion of the fracture.Type: ApplicationFiled: October 28, 2011Publication date: April 19, 2012Inventors: Robert Gordon Fulton, Adolph Joseph John Peskunowicz, Garnet Ross Olson
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Patent number: 8151876Abstract: Disclosed are processes for improving recovery of product from a subterranean carbonaceous deposit wherein there has been a reduction in product recovery from a production well, the processes comprising treating the deposit with a liquid that contains at least one of an oxoacid ester of phosphorous or an oxoacid acid ester of sulfur.Type: GrantFiled: August 7, 2009Date of Patent: April 10, 2012Assignee: Ciris Energy, Inc.Inventor: Robert A. Downey
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Patent number: 8141637Abstract: Solid material required at a subterranean location is supplied from the surface suspended in a carrier liquid and agglomerated below ground by means of a binding liquid. To achieve agglomeration, the binding liquid and the particulate solid are similar to each other but opposite to the carrier liquid in hydrophilic/hydrophobic character. The solid and the binding liquid may both be hydrophobic while the carrier liquid is hydrophilic, or vice versa. The solid may be hydrophobically surface modified to render it hydrophobic. The binding liquid may be provided as a precursor which converts to the binding liquid below ground to trigger agglomeration after arrival at the subterranean location. The agglomerates may function as proppant heterogeneously placed in a fracture of a reservoir, or may serve to block an unwanted path of flow. The binding liquid may polymerise after agglomeration so as to stabilise and strengthen the agglomerates.Type: GrantFiled: August 11, 2009Date of Patent: March 27, 2012Assignee: Schlumberger Technology CorporationInventors: Evgeny Barmatov, Jill Geddes, Trevor Hughes, Dean Willberg, Bruce Mackay
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Patent number: 8136593Abstract: Methods suitable for use in a subterranean formation utilizing particulates coated with both a tackifier and a resin.Type: GrantFiled: August 7, 2009Date of Patent: March 20, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Jimmie D Weaver, Philip D. Nguyen
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Patent number: 8134432Abstract: Provided is a system and method for enabling pressure or acoustic waves to induce magnetostrictive volume or shape change, providing greater control over magnetopropants. A coating material and the spacing between a magnetopropant and a magnetic particle are selected such that a certain pressure causes change in the relative distance of magnetopropant and magnetic particle, thereby changing the amount of magnetostriction. The coating material, magnetopropant, and magnetic particle are assembled to form a pressure sensitive magnetopropant. Given this structure, changes in pressure will cause a fluctuation of the amount of magnetostriction. In a pore space environment, this causes a change in pore space with resulting change in permeability and, hence, changes in fluid flow.Type: GrantFiled: February 21, 2011Date of Patent: March 13, 2012Inventor: Charles Saron Knobloch
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Publication number: 20120055670Abstract: A thermophilic mannanohydrolase enzyme may be used as an enzyme breaker for fracturing fluids containing hydratable polymers of guar and underivatized guar. The amino acid sequence of the mannanohydrolase is at least 90% homologous to the amino acid sequence of SEQ ID NO:2.Type: ApplicationFiled: November 10, 2011Publication date: March 8, 2012Inventor: Charles David Armstrong
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Patent number: 8127850Abstract: An increase in effective propped lengths is evidenced in hydraulic fracturing treatments by the use of ultra lightweight (ULW) proppants. The ULW proppants have a density less than or equal to 2.45 g/cc and may be used as a mixture in a first proppant stage wherein at least one of the proppants is a ULW proppant. Alternatively, sequential proppant stages may be introduced into the formation wherein at least one of the proppant stages contain a ULW proppant and where at least one of the following conditions prevails: (i.) the density differential between the first proppant stage and the second proppant stage is greater than or equal to 0.2 g/cc; (ii.) both the first proppant stage and the second proppant stage contain a ULW proppant; (iii.) the rate of injection of the second proppant stage into the fracture is different from the rate of injection of the first proppant stage; or (iv.) the particle size of the second proppant stage is different from the particle size of the first proppant stage.Type: GrantFiled: April 4, 2011Date of Patent: March 6, 2012Assignee: Baker Hughes IncorporatedInventors: Harold Dean Brannon, William Dale Wood, Randall Edgeman, Allan Ray Rickards, Christopher John Stephenson, Doug Walser, Mark Malone
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Publication number: 20120048538Abstract: In some embodiments, a method of obtaining information about at least one variable existing at a target location in an underground well bore and/or surrounding subterranean formation includes delivering a plurality of signal generating devices to the target location(s), emitting at least one detectable signal from the target location and receiving at least one such signal. Information about the variable(s) is derived from at least some of the received signals.Type: ApplicationFiled: February 18, 2011Publication date: March 1, 2012Applicant: Baker Hughes IncorporatedInventor: Harold Dean Brannon
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Patent number: 8119576Abstract: Treatments and compounds useful in subterranean formations are discussed, with particular attention to those utilizing ceramic coated particulates. Certain embodiments pertain to particulates and particulate packs with ceramic coatings of subatomic thickness. Of these, certain methods may utilize ceramic coatings on particulates in a subterranean formation, certain methods may utilize ceramic coatings on particulate packs in a subatomic formation, and certain compounds may provide the features of both ceramic coatings and particulates.Type: GrantFiled: October 6, 2009Date of Patent: February 21, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Enrique A. Reyes, Jimmie D. Weaver, Hongyu Luo
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Publication number: 20120031613Abstract: Articles and methods utilizing radiation susceptible materials are provided herein. In one aspect, a proppant, a treatment fluid, or both, may comprise a radiation susceptible material. In another aspect, a method is provided comprising disposing in a formation fracture, a proppant and/or a treatment fluid that comprises a radiation susceptible material, irradiating the radiation susceptible material with neutrons, measuring gamma-radiation emitted from the radiation susceptible material in a single pass, and determining formation fracture height from the measured gamma-radiation. The single-pass may be a continuous process or a periodic process.Type: ApplicationFiled: October 14, 2011Publication date: February 9, 2012Inventor: John W. Green
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Patent number: 8109336Abstract: In a method of hydraulically fracturing a hydrocarbon-bearing subterranean formation, a proppant stage is introduced into the fracture which contains a gaseous fluid and an ultra lightweight proppant suspended in a viscosified aqueous fluid. The gaseous fluid of the proppant stage contains at least about 90 volume percent of the combination of gaseous fluid and aqueous fluid. A pad fluid may first be introduced into the formation, the pad fluid containing a gaseous fluid and, optionally, an aqueous fluid. The gaseous fluid of the pad fluid mixture typically contains at least 70 volume percent of the mixture.Type: GrantFiled: March 28, 2011Date of Patent: February 7, 2012Assignee: Baker Hughes IncorporatedInventors: Richard S. Wheeler, Chandler C. Newhall, Roger R. Myers, Brian Ward, Brian B. Beall, Harold D. Brannon
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Patent number: 8097566Abstract: Methods of forming one or more fractures in a subterranean formation penetrated by a well bore including the steps of providing a high ionic strength treating fluid that comprises water and one or more sulfonated gelling agent polymers wherein the high ionic strength treating fluid comprises one or more water soluble salts in a concentration of greater than about 8% by weight of the treating fluid, and introducing the treating fluid into the subterranean formation at a rate and pressure sufficient to create or enhance one or more fractures therein.Type: GrantFiled: August 26, 2010Date of Patent: January 17, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Jimmie D. Weaver, Billy F. Slabaugh
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Patent number: 8091637Abstract: A method for filling an annular area within a wellbore penetrated by a subterranean formation is provided. The method includes the steps of: (a) introducing a proppant into a wellbore to form a gravel pack of the proppant, wherein a specimen of the proppant has a non-globular and non-fibrous shape, and wherein the shape is further selected to provide the proppant the ability to bridge together such that the proppant has a maximum bridging span of at least 3 times larger than a largest overall dimension of the proppant specimen, where the maximum bridging span is the largest outlet hole diameter that the proppant can bridge under the weight of gravity; and (b) passing fluid through the gravel pack.Type: GrantFiled: September 9, 2010Date of Patent: January 10, 2012Assignee: Halliburton Energy Services, Inc.Inventor: Michael L. Fripp
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Patent number: 8082992Abstract: Methods including the steps of selecting a target fracture geometry for a portion of a subterranean formation; selecting a target tip pressure and a target back flow pressure based at least in part on a calculation for the target fracture geometry; selecting a target surface pressure and a target bottom-hole pressure based at least in part on a calculation for the target tip pressure and the target back flow pressure; and introducing a slurry fluid comprising proppant particulates into one or more fractures in the portion of the subterranean formation. The surface pressure corresponds to the target surface pressure, and bottom-hole pressure corresponds to the target bottom-hole pressure.Type: GrantFiled: July 13, 2009Date of Patent: December 27, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Bradley L. Todd, David E. McMechan, Ki Cherryl Whitt, legal representative
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Patent number: 8082994Abstract: Methods of enhancing the conductivity of fractures in subterranean formations comprising: providing a propped fracture in a subterranean formation wherein a plurality of proppant particulates reside in at least a portion of the fracture; providing a displacement fluid; introducing the displacement fluid into the propped fracture in the subterranean formation at a rate that is at least the matrix rate of the subterranean formation; and allowing the displacement fluid to displace at least a portion of the plurality of proppant particulates, thereby forming at least one channel in the propped fracture.Type: GrantFiled: December 5, 2006Date of Patent: December 27, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Richard D. Rickman, Jason Bryant, Jimmie D. Weaver
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Patent number: 8074715Abstract: Methods for setting particulate plugs in at least partially horizontal sections of well bores are disclosed. In one embodiment, a method comprises the step of selecting a deposition location for a particulate plug within the at least partially horizontal section of the well bore. The method further comprises the step of providing a pumping conduit capable of delivering slurries to the deposition location. The method further comprises the step of pumping a first slurry through the pumping conduit to the deposition location such that a velocity of the first slurry in the well bore at the deposition location is less than or equal to the critical velocity of the first slurry in the well bore at the deposition location.Type: GrantFiled: January 15, 2009Date of Patent: December 13, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Keith A. Rispler, Loyd E. East, Bradley L. Todd, David E. McMechan, Corine McMechan, legal representative
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Patent number: 8066073Abstract: Methods for treating a formation penetrated by a wellbore which improves fluid loss control during treatment. In some aspects, the treatments include preparing an aqueous fluid including one or more water inert polymers and an optional viscosifier, injecting the aqueous fluid into the wellbore at a pressure equal to or greater than the formation's fracture initiation pressure, and thereafter injecting into the wellbore a proppant laden fluid at a pressure equal to or greater than the formation's fracture initiation pressure. The water inert polymer may be a polymer such as an emulsion polymer or a latex polymer. Some methods of the invention use a fluid which may have a normalized leak off coefficient (Cw/sqrt(K)) equal to or less than about 0.0022, 0.0014, or 0.0010. A conventional fluid loss additive may or may not be used in conjunction with the treatment fluid and/or the proppant laden fluid. The water inert polymer may or may not substantially enter formation pores.Type: GrantFiled: May 27, 2009Date of Patent: November 29, 2011Assignee: Schlumberger Technology CorporationInventors: Richard D Hutchins, Marie Noelle Dessinges, Carlos Abad, Erik B Nelson
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Patent number: 8061424Abstract: The invention provides economically effective methods for hydraulic fracturing a subterranean formation that ensure improvement of the hydraulic fracturcconductivity because of forming strong proppant clusters uniformly placed in the fracture throughout its length. One of these methods comprises: a first stage that involves injection into a borehole of fracturing fluid containing thickeners to create a fracture in the formation; and a second stage that involves periodic introduction of proppant into the injected fracturing fluid to supply the proppant into a created fracture, to form proppant clusters within the fracture to prevent fracture closure and channels for flowing formation fluids between the clusters, wherein the second stage or its sub-stages involve additional introduction of either a reinforcing or consolidation material or both, thus increasing the strength of the proppant clusters formed into the fracture fluid.Type: GrantFiled: January 27, 2006Date of Patent: November 22, 2011Assignee: Schlumberger Technology CorporationInventors: Dean M. Willberg, Matthew J. Miller, Marc Jean Thiercelin, Ivan Vitalievich Kosarev
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Patent number: 8062998Abstract: A substance and method for treating a subterranean formation using hydraulic fracturing. A non-metallic, substantially deformable, proppant particle is “elastically flexible” or “plastically compressible” and adapted for use at concentrations which will substantially create a partial monolayer.Type: GrantFiled: December 23, 2010Date of Patent: November 22, 2011Assignee: Canyon Technical Services, Ltd.Inventors: Robert Gordon Fulton, Adolph Joseph John Peskunowicz, Garnet Ross Olson
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Patent number: 8061427Abstract: A process for fracturing a selected region of a formation including: introducing a supply of fracturing fluid to the region of the formation until a first threshold is reached, adjusting the flow of the fracturing fluid to the region of the formation to reach a second threshold, adjusting the flow of the fracturing fluid to the region of the formation to reach a third threshold and ceasing flow of the fracturing fluid to region of the formation, the fracturing fluid being a non-participating gas and including a proppant in at least one of the stages of flow of the fracturing fluid.Type: GrantFiled: May 30, 2006Date of Patent: November 22, 2011Assignee: Sanjel CorporationInventors: Robert A. Jackson, Donald MacDonald
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Publication number: 20110278003Abstract: A proppant for a well treatment fluid includes discrete particles of a substrate, such as sand, coated with a resin comprising a product of the Maillard reaction between a carbohydrate and an amine and/or an ammonium compound. Different resins, in particular thermoplastic or thermosetting resins, may be blended with Maillard reaction products or applied to the substrate as separate layers. The proppant may be included in a fracturing fluid, which is injected into a subterranean formation and used to stimulate hydrocarbon production from the subterranean formation.Type: ApplicationFiled: April 15, 2011Publication date: November 17, 2011Applicant: GEORGIA-PACIFIC CHEMICALS LLCInventor: Richard A. Rediger
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Patent number: 8058213Abstract: A composite proppant having an increased buoyancy comprising a proppant substrate such as a porous ceramic or a silica sand coated with a material of a lesser actual density than the apparent density of the proppant substrate to increase the buoyancy of the composite proppant.Type: GrantFiled: May 11, 2007Date of Patent: November 15, 2011Assignee: Georgia-Pacific Chemicals LLCInventors: Richard Rediger, Jesse Petrella, Michael Joseph Aron, Bedford W. Fennell
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Publication number: 20110272156Abstract: An improvement over known hydraulic fracturing fluids. Boundary layer kinetic mixing material is added to components of fracturing fluid wherein kinetic mixing material is a plurality of particles wherein at least 25% of particles are several types, i.e., having surface characteristics of thin walls, three dimensional wedge-like sharp blades, points, jagged bladelike surfaces, thin blade surfaces, three-dimensional blade shapes that may have shapes similar to a “Y”, “V” or “X” shape or other geometric shape, slightly curved thin walls having a shape similar to an egg shell shape, crushed hollow spheres, sharp bladelike features, 90° corners that are well defined, conglomerated protruding arms in various shapes, such as cylinders, rectangles, Y-shaped particles, X-shaped particles, octagons, pentagon, triangles, and diamonds.Type: ApplicationFiled: June 23, 2011Publication date: November 10, 2011Inventor: WILLIAM L. JOHNSON, SR.
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Patent number: 8051911Abstract: Prior to a hydraulic fracturing treatment, the requisite injection rate for a desired propped fracture length of a fracture may be estimated with knowledge of certain physical properties of the proppant and transport fluid such as fluid viscosity, proppant size and specific gravity of the transport slurry as well as fracture geometry and the fracture length.Type: GrantFiled: January 18, 2010Date of Patent: November 8, 2011Assignee: Baker Hughes IncorporatedInventor: Harold Dean Brannon
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Publication number: 20110265995Abstract: One embodiment of the present invention relates to spherical ceramic elements, such as proppants, for maintaining permeability in subterranean formations to facilitate extraction of oil and gas therefrom. The strength of the ceramic element may be enhanced by combining materials having different coefficients of thermal expansion. Methods of making the ceramic elements are also disclosed.Type: ApplicationFiled: July 7, 2011Publication date: November 3, 2011Inventors: Kevin R. DICKSON, Walter T. Stephens, Tihana Fuss
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Patent number: 8034750Abstract: A cross-linking system for hydratable polymers for using is formation fracturing applications is disclosed along with methods for using same, where the cross-linking system includes a reaction product of a transition metal alkoxide or alkanolate and a borate or borate generating reagent.Type: GrantFiled: May 14, 2007Date of Patent: October 11, 2011Assignee: Clearwater International LLCInventors: Joseph Earl Thompson, Sarkis R. Kakadjian
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Publication number: 20110240293Abstract: A method of heterogeneous proppant placement in a subterranean fracture is disclosed. The method comprises injecting well treatment fluid including proppant (16) and proppant-spacing filler material called a channelant (18) through a wellbore (10) into the fracture (20), heterogeneously placing the proppant in the fracture in a plurality of proppant clusters or islands (22) spaced apart by the channelant (24), and removing the channelant filler material (24) to form open channels (26) around the pillars (28) for fluid flow from the formation (14) through the fracture (20) toward the wellbore (10). The proppant and channelant can be segregated within the well treatment fluid, or segregated during placement in the fracture. The channelant can be dissolvable particles, initially acting as a filler material during placement of the proppant in the fracture, and later dissolving to leave the flow channels between the proppant pillars.Type: ApplicationFiled: April 29, 2011Publication date: October 6, 2011Inventors: Timothy Lesko, J. Ernest Brown, Dean M. Willberg, Ivan V. Kosarev, Anatoly Medvedev
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Publication number: 20110240291Abstract: Of the many methods provided herein, one method comprises: providing at least one fracture in a subterranean formation that comprises tight gas, a shale, a clay, and/or a coal bed; providing a plasticity modification fluid that comprises an aqueous fluid and an alkaline embrittlement modification agent; placing the plasticity modification fluid into the fracture in the subterranean formation; and embrittling at least one fracture face of the fracture to form an embrittled fracture face.Type: ApplicationFiled: March 31, 2010Publication date: October 6, 2011Inventors: Richard D. Rickman, Ronald G. Dusterhoft, Dwain G. King, Jimmie D. Weaver, Michael A. McCabe
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Publication number: 20110240292Abstract: Of the many methods provided herein. one method comprises: providing at least a portion of a subterranean formation that comprises a shale; providing a plasticity modification fluid that comprises an aqueous fluid and an alkaline embrittlement modification agent; placing a pack completion assembly neighboring the portion of the subterranean formation; and embrittling at least a portion of the shale to form an embrittled shale portion.Type: ApplicationFiled: August 6, 2010Publication date: October 6, 2011Inventors: Ronald G. Dusterhoft, Jimmie D. Weaver, Richard D. Rickman, Michael A. McCabe, Dwain King
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Patent number: 8022014Abstract: A method of solubilizing/removing cellulose or chemically-modified cellulosic polymers utilized in subterranean drilling operations such as fracturing. The method involves introducing a deep eutectic solvent (DES) into a subterranean region. Deep eutectic solvents useful as cellulose solvents include quaternary ammonium compounds, including choline chloride and chlorcholine chloride, reacted with a compound selected from amides, amines, carboxylic acids alcohols, and metal halides. The DES material can be pumped downhole after fracturing operations to remove cellulosic material used, for example, to thicken fracturing fluid which is left behind in the created fractures, on the face of the formation, along the wellbore, or elsewhere within the subterranean region. The DES can be used alone or in a sequential treatment protocol, whereby the DES is introduced into the subterranean region, followed by post-treatment introduction of water, caustic, acid or anhydride into the subterranean as a flush.Type: GrantFiled: March 25, 2009Date of Patent: September 20, 2011Inventor: Richard F. Miller
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Publication number: 20110220355Abstract: Non-spherical particulates are useful in the stimulation of subterranean formations. A proppant pack composed of the non-spherical particulates exhibits greater porosity than a corresponding proppant pack composed of spherical particulates. Non-spherical particulates which are hollow and non-porous may further be at least partially filled with a chemical treatment agent including water-soluble or oil-soluble chemical treatment agents.Type: ApplicationFiled: May 24, 2011Publication date: September 15, 2011Inventors: Phillip B. Kaufman, D.V. Satyanarayana Gupta, Allan R. Rickards, Christopher J. Stephenson
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Patent number: 7971644Abstract: A system includes a hydraulic fracturing fluid including a polymeric constituent and an additive having particles including poly-vinyl acetate in an amount sufficient to control fluid loss. The system includes a formation of interest having a downhole temperature, and the particles including poly-vinyl acetate have a size and/or shape such that the poly-vinyl acetate hydrolyses at the downhole temperature. The particles may have a size and/or shape such that the particles are deformable at the downhole temperature. The poly-vinyl acetate in the particles may be a part of the particle substrate, a coating on the particles, and/or the entire particle may be poly-vinyl acetate. The poly-vinyl acetate may be included in any portion of the hydraulic fracturing fluid, or only the portion of the hydraulic fracturing fluid that is not proppant laden.Type: GrantFiled: January 20, 2009Date of Patent: July 5, 2011Assignee: Schlumberger Technology CorporationInventors: Hemant K. Ladva, Syed Ali, Mohan K. R. Panga, Richard D. Hutchins, Don Williamson
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Patent number: 7971643Abstract: Methods and compositions useful for subterranean formation treatments, such as hydraulic fracturing treatments and sand control that utilize relatively lightweight and/or substantially neutrally buoyant particulates. Particles that may be employed include particulates of naturally occurring materials that may be optionally strengthened or hardened by exposure to a modifying agent; porous materials including selectively configured porous material particles manufactured and/or treated with selected glazing materials, coating materials and/or penetrating materials; and well treating aggregates composed of an organic lightweight material and a weight modifying agent. The relatively lightweight particulate may be suspended as a substantially neutral buoyant particulate and stored with a carrier fluid as a pumpable slurry.Type: GrantFiled: December 5, 2007Date of Patent: July 5, 2011Assignee: Baker Hughes IncorporatedInventors: Harold Dean Brannon, William Dale Wood, Allan Ray Rickards, Christopher John Stephenson
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Patent number: 7972555Abstract: Methods for fabricating compressible object are described. These compressible objects may be utilized in drilling mud and with a drilling system to manage the density of the drilling mud. The method includes selecting an architecture for a compressible object; selecting a wall material for the compressible object; and fabricating the compressible object, wherein the compressible object has a shell that encloses an interior region, and has an internal pressure (i) greater than about 200 pounds per square inch at atmospheric pressure and (ii) selected for a predetermined external pressure, wherein external pressures that exceed the internal pressure reduce the volume of the compressible object.Type: GrantFiled: October 16, 2008Date of Patent: July 5, 2011Assignee: ExxonMobil Upstream Research CompanyInventors: Richard S. Polizzotti, Dennis George Peiffer, Ramesh Gupta, Norman M. Pokutylowicz, Barbara Carstensen, Michael J. Luton, Paul Matthew Spiecker
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Publication number: 20110146985Abstract: The present invention relates to glass-ceramic proppants which can be used to prop open subterranean formation fractions, as well as other uses. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the glass-ceramic proppants.Type: ApplicationFiled: December 14, 2010Publication date: June 23, 2011Applicant: OXANE MATERIALS, INC.Inventors: Yuming Xie, Dilip Chatterjee, Christopher E. Coker, Christopher Y. Fang
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Patent number: 7963330Abstract: Methods and compositions that include a resin composition having from about 5% to about 30% phenol, from about 40% to about 70% phenol formaldehyde, from about 10 to about 40% furfuryl alcohol, from about 0.1% to about 3% of a silane coupling agent, and from about 1% to about 15% of a surfactant and methods of using of that resin in controlling particulate flowback from a subterranean formation.Type: GrantFiled: December 21, 2009Date of Patent: June 21, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Johnny A. Barton, O. Marlene Isenberg
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Patent number: 7956017Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.Type: GrantFiled: May 6, 2008Date of Patent: June 7, 2011Assignee: Clearwater International, LLCInventors: Larry W. Gatlin, Frank Zamora, Jim Venditto, Sarkis Kakadjian Ranka