Abstract: A problem to be solved of the present invention is to provide a diverting agent which gradually dissolves in water. The present invention relates to a diverting agent containing a polyvinyl alcohol-based resin and a method of filling a fracture using the diverting agent.

Abstract: Various embodiments disclosed relate to surfactant compositions for treatment of subterranean formations and produced oil. In various embodiments, the present invention provides a method of treating a subterranean formation including placing in the subterranean formation a surfactant composition. The surfactant composition includes an alkanolamide surfactant and an alkoxylated alcohol surfactant. The surfactant composition also includes an ionic surfactant, a nonionic surfactant, or a combination thereof.

Abstract: A system and method for injecting bailer content utilizing a dump bailer having an elongated, flexible bailer receptacle secured between a head assembly and an injection assembly. Disposed within the dump bailer are first and second piston assemblies, each of which includes a piston having a central fluid passage with a pressure actuated flow control mechanism in the form of a rupture disk disposed along the fluid passage of the piston. An electric, positive displacement pump within the head assembly draws wellbore fluid into the dump bailer assembly to drive the first piston assembly towards the second piston assembly so as to release bailer content into a wellbore. The elongated flexible bailer receptacle may be a hose stored on a bailer receptacle reel, which hose may be paid out by the reel to a length that corresponds with a volume of bailer content to be released into the wellbore.

Abstract: A variety of systems, methods and compositions are disclosed. A method may comprise introducing a fracturing fluid into a subterranean formation, wherein the fracturing fluid comprises an aqueous based fluid, a proppant composition, an oxidizing breaker, and halloysite nanotubes, wherein the oxidizing breaker is positioned within the halloysite nanotubes; and reducing a viscosity of the fracturing fluid.

Abstract: Core-shell particles for treatment of subterranean formations are provided. A method may include placing in the subterranean formation a composition including a core-shell particle including a hydrophilic core and a hydrophobic shell.

Abstract: A method for sealing a loss circulation zone of a subterranean well includes delivering a loss circulation product into a wellbore of the subterranean well. The loss circulation product has a solvent, a fibrous material, and a first reactant. The fibrous material traps the first reactant to form a porous cake across a fracture of the loss circulation zone. A second reactant is delivered into the wellbore of the subterranean well, the second reactant passes through the porous cake and reacts with the first reactant, reducing a porosity of the porous cake across the fracture so that the loss circulation product seals the loss circulation zone.

Abstract: A system and method for forming mineral or proppant in-situ in fractures in a geological formation via a fracturing fluid. The mineral or proppant is formed from rock in the geological formation.

Abstract: Compositions, methods, and systems for mitigating annular pressure buildup in a wellbore. A method comprises introducing a spacer fluid into an annulus of the wellbore, wherein the spacer fluid comprises an aqueous base fluid, an acid swellable polymer, and a hydrolysable ester. The method further comprises allowing or causing to allow at least a portion of the spacer fluid to remain in the annulus; and allowing or causing to allow a temperature to increase in the annulus to the temperature sufficient to hydrolyze the hydrolysable ester; wherein hydrolysis of the hydrolysable ester produces an acid; wherein the acid reacts with the acid swellable polymer to produce a salt; and wherein the produced salt has a thermal expansion coefficient less than that of the aqueous base fluid.

Abstract: The present disclosure relates to fracturing fluids that use friction reducers. The composition of the present disclosure is a slurry comprising a water-soluble polymer suspended in an oil-based vehicle with the aid of a suspension agent and a surfactant. Specifically, the water-soluble polymer is polyacrylamide and the oil-based vehicle is petroleum distillate. The surfactant is an ethoxylated nonionic emulsifier. The surfactant can be a fatty chain EO/PO (ethylene oxide propylene oxide) and/or oxylated propoxy copolymer. The suspension aid is any variation of diblock copolymers based on styrene and ethylene/propylene. The composition may also contain a dispersant such as organophilic clay or a synthetic alternative as the suspension agent.

Abstract: A plugging device, well system and method. In one example, a wrap, band or other type of binding is utilized to secure together multiple fibers, tubes, filaments, films, fabrics or lines of the plugging device. In another example, fibers, tubes, filaments, films, fabrics or lines are fused, adhered or bonded to an outer surface of a body of the plugging device. In other examples, a material of the plugging device may become more rigid or swell in a well. A plugging device may comprise a body loosely enclosed in a bag, wrapper or other enclosure.

Abstract: A system and method for forming minerals or proppant in situ in fractures in a geological formation via a frac fluid and hydrothermal synthesis.

Abstract: It is common to require oil-well treating chemicals to be introduced into subterranean geological formations over the well's drilling, stabilization and extraction phases. The timely controlled and uniform release of such chemicals throughout the fluid bed vastly enhances their effectiveness. A method is disclosed for introducing such oil-well treating chemicals throughout the subterranean formation by encapsulating the chemicals within engineered composites, which are introduced into the subterranean formations along with the other fluids. These engineered composites are formed to slowly release the oil-well treating chemicals once they are in the subterranean formations as the engineered composites slowly dissolve.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well. A Portland cement clinker may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement choker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: The present invention relates to a method to form or obtain a high performance aqueous phase polymer fluid, which is a seawater-based drilling fluid for well drilling in low gradient formations. It is formulated based on liquid state polymer chemical products, easy to aggregate, and quickly mixed; a preparation and homogenization process that reduces preparation times, designed to drill hydrocarbon-producing deposits, focusing on minimizing damages to the producing formations, with a high rate of circulation loss in naturally fractured deposits. The system is environmentally-friendly, it complies with the main functions required of drilling fluids, while also providing a high inhibition control by swelling and dispersion of clay zones, due to the polymeric nature of the materials with which it is formulated. It is a fluid that does not contain solids in its formulation and provides an excellent transport and cleaning of drilling shears in the well.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: Provided is a method and composition for the in-situ generation of synthetic sweet spots in tight-gas formations. The composition can include gas generating compounds, which upon activation, exothermically react to generate heat and gas. The method of using the composition includes injecting the composition into a tight-gas formation such that upon activation, the heat and gas are generated, resulting in the formation of fractures and microfractures within the formation.

Abstract: A system and methods for breaking friction reducers in subterranean formations in-situ during hydraulic fracturing operations are disclosed. A method of fracturing a subterranean formation is disclosed, including providing a well treating fluid, adding a friction reducer into a water phase of an emulsion, adding a breaker into the water phase, and injecting the well treating fluid into the subterranean formation at a pressure sufficient to fracture the subterranean formation and invert the emulsion and double emulsion, thereby allowing the breaker to break the friction reducer. A friction reducer-breaker system for breaking a friction reducer polymer in-situ is also disclosed, including an oil phase, a water phase including friction reducer polymers and breakers in double emulsion dispersed throughout the water phase, wherein the emulsion and double emulsion are configured to invert under shear, thereby providing for mixing between the friction reducer polymers and the breakers.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: A composition and method required for providing a fracturing fluid pumped down a well bore and into a subterranean formation under conditions of pressure that will fracture the subterranean formation is described. More specifically, the composition increases the recovery of hydrocarbons from a geological formation penetrated by a well bore, wherein the composition includes a fracturing fluid that is liquid carbon dioxide (LCO2) with proppant to aid transport of the proppant in suspension, and thereby create a fracture using a fracturing fluid which is the thickened composition containing fumed silica. When the composition is without a proppant, the viscosity of the composition is increased in order to improve the fracturing operation through aspects such as increased fracture width and reduced fluid leak-off.

Abstract: A method of treating a subterranean formation includes introducing a viscosified treatment fluid into a subterranean formation, the treatment fluid including an aqueous fluid, a gelling agent, and a crosslinker including a copolymer with an interpenetrating monomer and organic bound metal ions. A composition includes an aqueous fluid, a gelling agent; and a crosslinker including a copolymer with an interpenetrating monomer and organic bound metal ions.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: Portland cement clinker LCMs that include Portland cement clinker to mitigate or prevent lost circulation in a well are provided. A Portland cement clinker LCM may include Portland cement clinker, Portland cement, a carrier fluid, and an inorganic consolidation activator. Another Portland cement clinker LCM may include Portland cement clinker and a crosslinked fluid, such as a polyuronide crosslinked via calcium ions or a polysaccharide crosslinked via divinyl sulfone. Yet another Portland cement clinker LCM may include Portland cement clinker and polymer fibers or particulate glass. Methods of lost circulation control using a Portland cement clinker LCM are also provided.

Abstract: A method for controlling fluid loss into the pores of an underground formation during fracturing operations is provided. Nanoparticles are added to the fracturing fluid to plug the pore throats of pores in the underground formation. As a result, the fracturing fluid is inhibited from entering the pores. By minimizing fluid loss, higher fracturing fluid pressures are maintained, thereby resulting in more extensive fracture networks. Additionally, nanoparticles minimize the interaction between the fracturing fluid and the formation, especially in water sensitive formations. As a result, the nanoparticles help maintain the integrity and conductivity of the generated, propped fractures.

Abstract: Techniques for well testing include providing an amount of a chemical material to a location in a wellbore; reacting the chemical material to generate an exothermic chemical reaction at the location in the wellbore; and fracturing the formation by the exothermic chemical reaction.

Abstract: Pumpable process-fluid compositions and methods for establishing hydraulic isolation in cemented subterranean wells comprise more than 1 wt % polyacrylamide and a non-metallic crosslinker. Upon entering voids and cracks in or adjacent to a cement sheath, and contacting the set-cement surfaces, the compositions react and form a seal that prevents further leakage.

Abstract: A method of treating a subterranean formation via well bore may include introducing a plurality of particles into the subterranean formation via the well bore, each particle having a substrate and a layer of cement on the substrate. The cement may be in a state of suspended hydration and the method may include introducing moisture to the subterranean formation via the well bore. The method may also include allowing the particles and the moisture to contact one another. Contact between the particles and the moisture may cause the cement to move from a state of suspended hydration to a state of secondary hydration.

Abstract: A hydraulic fracturing composition includes: a superabsorbent polymer in an expanded state; a plurality of proppant particles disposed in the superabsorbent polymer; a well treatment agent, and a fluid to expand the superabsorbent polymer into the expanded state. A process for treating a well with well treatment agent includes disposing a hydraulic fracturing composition comprising the well treatment agent in a well. The well treatment agent can be a scale inhibitor, tracer, pH buffering agent, or a combination thereof.

Abstract: Disclosed are compositions derived of mixtures of choline ion salts (typically choline chloride) in aqueous solution with suspended particulates of sparingly soluble borate minerals or with alkali or alkaline earth borate salts, boric acid and its ester derivatives and salts, or other aqueous soluble borate forms. These compositions are useful as cross-linkers for polysaccharides and other biopolymers and particularly as used in subterranean treatment fluids for completion and stimulation of oil and gas wells. Advantages of the compositions are the combination into a single package of the properties of clay stabilizing actives (choline ion) and crosslinking actives (borates, etc.), in relatively high concentrations, and these compositions are easy to handle, being stable and pumpable at low temperatures, and with attractive environmental profiles. Also disclosed are the analogous choline solutions mixed with metallic cross-linking ions know in the art such as Zr+, Ti4+, Al3+, & Fe3+.

Abstract: A fracturing method comprises: pumping a first stream of liquefied petroleum gas and gelling agent with a first frac pressure pump; pumping a second stream of lubricated proppant with a second frac pressure pump; combining the first stream and the second stream within a wellhead into a combined stream; pumping the combined stream into a hydrocarbon reservoir; and subjecting the combined stream in the hydrocarbon reservoir to fracturing pressures. A fracturing apparatus comprises: a first frac pressure pump connected to a first port of a wellhead; a second frac pressure pump connected to a second port of the wellhead; a frac fluid source connected to simply a stream of frac fluid comprising liquefied petroleum gas to the first frac pressure pump; a gel source connected to supply a gelling agent into the frac fluid; and a proppant supply source connected to supply lubricated proppant to the second frac pressure pump.

Abstract: A treatment method for a hydrocarbon well includes placing a well treatment fluid containing a viscosifying agent in the well and, using the viscosifying agent, attaining a first viscosity of the fluid in the well. The method includes combining a porphyrin compound with the fluid and, using the porphyrin compound, decreasing viscosity of the fluid in the well to a second viscosity less than the first viscosity. A hydrocarbon well treatment fluid includes an aqueous carrier fluid, a polymer viscosifying agent, and a chlorophyll compound.

Abstract: The present invention provides a method of isolating a selected reservoir zone in a subterranean reservoir comprising at least the step of squeezing a treatment fluid into the selected reservoir zone, the treatment fluid comprising: a viscosifying agent; a fluid loss control agent; and a particulate material. The invention further provides a treatment fluid comprising a base fluid; a viscosifying agent; at least 20 kg/m3 of a fluid loss control agent; and a particulate material.

Abstract: A method of hydraulic fracturing, and tracer composites for use in the fracturing procedure, for tracing the production of crude oil or other hydrocarbon liquid products from one or more fractured zones. The tracer composites preferably include an oil soluble tracer adsorbed onto a solid carrier material. A non-water soluble coating is preferable also included on the composite over the tracer compound.

Abstract: A gel-forming corrosion inhibiting composition may be employed to protect a metal article from corrosion. The gel-forming corrosion inhibitor composition is combined with water and delivered to an enclosed space at least partially defined by the metal article. Subsequent to delivery, the combination forms a gel to sustainably fill the enclosed space, thereby protecting the metal article from corrosion.

Abstract: Liquid hydrocarbons are gelled by the introduction of a phosphate ester and a crosslinking agent for use in oil recovery. Generally a proppant, delayed gel breaker and other modifiers are added to the gelled hydrocarbon to improve the oil recovery process. The phosphate ester used in this method and composition for oil recovery has low volatility and good stability during hydrocarbon distillation resulting in improved distillation efficiency in a refinery.

Abstract: Disclosed is a composition and a method for cementing a casing in a borehole of a well using an aqueous cementing composition comprising (a) water, (b) a cementing composition comprising (i) a hydraulic cement, (ii) a hydrophobically modified polymer, (iii) a dispersant, and optionally (iv) one or more other additives conventionally added to aqueous cementing compositions useful in cementing casings in the borehole of wells. Preferably the hydrophobically modified hydroxyethyl cellulose has an ethylene oxide molar substitution of from 0.5 to 3.5, a hydrophobe degree of substitution of from 0.001 to 0.025, and a weight-average molecular weight of from 500,000 to 4,000,000 Daltons and the dispersant is sulfonated polymer, melamine formaldehyde condensate, a naphthalene formaldehyde condensate, a branched or non-branched polycarboxylate polymer.

Abstract: Subterranean formations are subjected to hydraulic fracturing with an aqueous fracturing fluid having guar or a derivative thereof, a borate crosslinking agent and proppant. The fracturing fluid is prepared in a blender and then pumped into the wellbore through an entrance site. The apparent viscosity of the fluid decreases distally from the entrance site such that (i) the apparent viscosity of the fracturing fluid 100 feet from the entrance site is less than 10 percent of the apparent viscosity of the fracturing fluid at the entrance site; (ii) the apparent viscosity of the fracturing fluid 15 minutes after introduction into the entrance site is less than 15% of the apparent viscosity of the fracturing fluid at the entrance site; or (iii) the apparent viscosity of the fracturing fluid is less than 10 cP within 15 minutes after being introduced through the entrance site.

Abstract: A method of treating a formation that includes exposing a region of the formation occupied by a hydrolysable gel to a hydrolyzing agent; and allowing sufficient time for the hydrolyzing agent to hydrolyze the gel. Various methods may also include the use of a swelling agent to allow for expansion of the gel.

Abstract: Water production from a subterranean formation is inhibited or controlled by pumping a fluid containing coated particles through a wellbore into the formation. The particles have been previously coated with a relative permeability modifier (RPM). Upon contact with water, the RPM coating expands or swells and inhibits and controls the production of water. The RPM may be a water hydrolyzable polymer having a weight average molecular weight greater than 100,000. The particles may be conventional proppants or gravel.

Abstract: Degradable balls for downhole use may include an incompliant degradable polymer and a compliant filler material, the incompliant degradable polymer having an elastic modulus of about 2 GPa or greater, and the compliant filler material having an elastic modulus of less than about 2 GPa. Such degradable balls may be useful in sealing segments of a wellbore and actuating wellbore tools.

Abstract: The disclosure relates to a method of delaying viscosification of a well treatment fluid within a well or within a subterranean formation penetrated by a well by introducing into the well a hydratable viscosifying agent of particulates having a minimum of 40% retention on a 60 mesh screen and a minimum of 1% retention on a 20 mesh screen.

Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.

Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil slurried together in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil having the particulate fluid loss control agents slurried within it may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the slurry is added to the fluid after it has been substantially gelled. The mineral oil/particulate slurry may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.

Abstract: Processes and systems for fracturing a formation are disclosed. Tools that may be selectively opened and closed are positioned on a tubular liner that in turn is positioned within a subterranean well bore. Separate pairs of packers are also attached to and positioned along the tubular liner so as to straddle each tool. Fracturing fluid is pumped from the surface through the tubular and open tool and past a pair of packers at a temperature and injection rate which causes contraction of the tubular liner. Thereafter, the velocity of the fracturing fluid is sufficient to set the pair of packers adjacent the open tool. Continued pumping of fracturing fluid is directed by the set packers into the adjacent subterranean environs at a pressure sufficient to fracture the subterranean environs.

Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.

Abstract: The method disclosed herein includes the introduction of proppant-free stage and a proppant laden stage into the wellbore and/or subterranean formation. The method increases the effective fracture width and enhances fracture conductivity within the formation. Either the proppant-free stage or the proppant laden stage contains a breaker. The other stage contains a viscosifying polymer or viscoelastic surfactant to which the breaker has affinity. The proppant-free stage may be introduced prior to introduction of the proppant laden stage into the wellbore and/or formation. Alternatively, the proppant laden stage may be introduced into the wellbore and/or formation prior to introduction of the proppant-free stage.

Abstract: Methods of treating a subterranean formation including providing a wellbore in a subterranean formation having at least one fracture; providing an expandable cementitious material; introducing the expandable cementitious material into the at least one fracture in the subterranean formation; curing the expandable cementitious material so as to form a cement pack, wherein the curing of the expandable cementitious material expands the expandable cementitious material such that at least one microfracture is created within the at least one fracture in the subterranean formation; and acid-fracturing the at least one fracture in the subterranean formation.

Abstract: A method for diverting fluids across a perforation tunnel in high-rate water pack operations may include providing a wellbore extending into a subterranean formation, wherein a perforation tunnel provides a fluid connection between the wellbore and the subterranean formation; providing a diverting particulate that comprises a degradable plasticized polymer coating on a particulate; placing the diverting particulate into the perforation tunnel, wherein the step of placing the diverting particulate forms a particulate pack within the subterranean formation and the perforation tunnel; allowing the degradable plasticized polymer coating to deform and fill the interstitial spaces within the particulate pack in the perforation tunnel such that the fluid conductivity between the wellbore and the subterranean formation is substantially blocked; and allowing the plasticized polymer coating to degrade over time thereby substantially restoring the fluid conductivity between the wellbore and the subterranean formation.