Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.

Abstract: A subterranean location accessed via a wellbore is treated with an oilfield fluid containing a viscosifying agent which is a polymer and a cross-linking agent which can undergo the Diels-Alder reaction to form a gel. Conditions at the subterranean location alter fluid viscosity by bringing about the Diels-Alder reaction to increase viscosity or the retro Diels-Alder reaction to decrease the viscosity of the gel.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising dissymmetric bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions comprising polycationic quaternary ammonium compounds that comprise dissymmetric bis-quaternary compounds. In yet another aspect, the present technology provides polycationic quaternary ammonium compounds comprising a carboxylate functional polycationic quaternary ammonium compound. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C.

Abstract: Providing a solution of at least one salt capable of reacting with a set cement to form a solid phase comprising a precipitate or an expanded phase of the cement; contacting a region of the set cement to be repaired with the solution so as to form the solid phase in voids in the region of the set cement to be repaired.

Abstract: Wellbore treatment kits are provide that include a polymeric solution for placement in a wellbore that penetrates a subterranean formation and an activator for causing a polymer to precipitate out of the polymeric solution when it contacts the polymeric solution, wherein the resulting precipitate is capable of at least partially blocking a flow of a wellbore servicing fluid into the subterranean formation. The wellbore servicing fluid may be, for example, a drilling fluid, a cement composition, a workover fluid, or combinations thereof. The polymeric solution may comprise, for example, a poly vinyl pyrrolidone aqueous solution, and the activator may comprise, for example, a formate brine. When desirable, the precipitate may be easily and quickly removed from the subterranean formation by dissolving it in fresh water.

Abstract: Disclosed embodiments relate to methods of completing wells in subterranean formations. An exemplary embodiment comprises forming an artificial barrier to water flow, wherein the artificial barrier is located at or above a hydrocarbon-water interface between a water-bearing formation zone and a hydrocarbon-bearing formation zone. The exemplary embodiment further comprises consolidating a portion of the hydrocarbon-bearing formation zone, wherein the artificial barrier is located between the consolidated portion of the hydrocarbon-bearing formation zone and the water-bearing formation zone.

Abstract: A method and composition for treating a subterranean formation with a fluid, including forming a fluid including a particulate and an organosilane with the chemical formula RnSiX4-n, wherein n is equal to 1, 2, or 3, R is an organic functional group, and X is a halogen, alkoxy, or acetoxy group, introducing the fluid into a subterranean formation with exposed surfaces, and modifying the wettability of a surface of the particulate or subterranean formation or both. A method and composition for treating a subterranean formation with a fluid including forming a fluid comprising a particulate and an organosilane, introducing the fluid into a subterranean formation with exposed surfaces, and modifying the wettability of the proppant or surfaces or both, wherein the wettability modification degrades.

Abstract: Methods are provided for reducing the loss of a wellbore servicing fluid to a subterranean formation. A polymeric solution and an activator may be contacted in the formation, thereby forming a precipitate to at least partially block fluid from flowing further into the formation. The fluid may be, for example, a drilling fluid, a cement composition, a workover fluid, or combinations thereof. The polymeric solution may comprise a polyvinylpyrrolidone aqueous solution, and the activator may comprise a formate brine. In one embodiment, the polymeric solution and the activator are contacted before completing a drilling operation in the wellbore. In another embodiment, they are contacted before completing a primary cementing operation in the wellbore. In yet another embodiment, they are contacted before completing a secondary cementing operation in the wellbore. When desirable, the precipitate may be easily and quickly removed from the subterranean formation by dissolving it in fresh water.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions that comprise polycationic quaternary ammonium compounds comprising bis-quaternary compounds. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C. when the amount of the one or polycationic quaternary compounds is less than about 10% by weight based on the total weight of the composition.

Abstract: The invention is directed to a method for controlling driving fluid breakthrough caused by zones of pressure communication, i.e., a matrix bypass event (“MBE”) or a wormhole, having a void space and possibly areas of enhanced permeability (a halo region) associated with the void space, within a subterranean formation arising from use of a driving fluid in reservoirs where heavy/viscous oil is being produced. In particular, the method is directed to remediation of pressure communication between injection and production wells used to produce heavy/viscous oil by way of a waterflood operation combined with a cold production method. Direct or rapid communication of water between the injector and producer wells makes the waterflood recovery process virtually ineffective and limits the production of oil from the reservoir.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In one aspect, the present technology provides polycationic quaternary ammonium compounds that comprise bis-quaternary compound. The bis-quaternary compounds of the present technology can be symmetric or dissymmetric. In another aspect, the present technology provides viscoelastic well bore treatment fluids comprising water, and at least one polycationic quaternary ammonium compound that comprises a bis-quaternary compound. In another aspect, the present technology provides polycationic carboxylates. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or 110° C.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a cement composition comprising: cement; a surfactant composition comprising: an ethoxylated alcohol ether sulfate in an amount in the range of about 60 to about 64 parts by weight, a first alkyl or alkene amidopropyl betaine in an amount in the range of about 30 to about 33 parts by weight, and a second alkyl or alkene amidopropyl betaine in an amount in the range of about 1 to about 5 parts by weight; a gas; and water.

Abstract: A temporary matrix is provided in treating a subterranean formation by providing a composition comprising a matrix forming material and a matrix degrading material. The matrix degrading material is capable of degrading the matrix after a period of time when subjected to existing or induced conditions of the subterranean formation. The composition is placed into a wellbore penetrating the subterranean formation. The composition is allowed to form a matrix within the wellbore, whereby the matrix at least one of significantly reduces the passage of fluid across or near the matrix or provides structural strength. A treatment operation is performed on the subterranean formation or wellbore and the degrading material is allowed to degrade the matrix.

Abstract: A method of treating a subterranean formation includes pumping into a cased, perforated wellbore that intersects the formation an invert emulsion kill fluid, the invert emulsion kill fluid comprising: an oleaginous continuous phase; a non-oleaginous discontinuous phase; an emulsifier; at least one degradable material; and at least one bridging material; contacting the formation with the kill fluid; and allowing the degradable material to at least partially degrade.

Abstract: Wellbore fluid containing a base fluid and a particulate bridging agent comprised of melamine. A method is also described of forming a removable filter cake on the walls of a wellbore that penetrates a porous and permeable rock formation by placing in the wellbore a wellbore fluid containing a base fluid and melamine, and permitting the melamine to deposit from the wellbore fluid onto or into the walls of the wellbore to form the filter cake, whereby fluid loss to the formation through the removable filter cake is reduced.

Abstract: A method is given for reducing fluid loss in downhole operations such as drilling and completion. A composition containing a fusing solid is injected into the fluid loss flow path; the fusing solid fuses at formation temperature when the injection pressure is released and the formation matrix surfaces forming the flow path close on the composition. The fusing solid is gilsonite, or a similar material, or resin coated particles. The composition may optionally contain one or more of fibers, flakes, an activator, and a dispersant.

Abstract: A sol of metallic alkoxide is pumped into a desired location in a wellbore and allowed to gel, creating solids in-situ. The sol is either unstabilized, requiring rapid placement before gelling, or the sol is stabilized, permitting off-site mixing. Sols can be stabilized with either surfactant or with interfacial polymers. Large concentrations of surfactant can be placed in the sol to create templates around which gelation occurs, creating porous solids.

Abstract: A method of treating a subterranean formation penetrated by a wellbore is accomplished by introducing a fluid into the wellbore containing a combined fluid loss additive and breaker. The combined fluid loss additive and breaker is formed from particles of an organic peroxide provided on a substrate. The particles are sized to facilitate fluid loss control. A treatment operation is carried out wherein a treatment fluid viscosified with a polymer is introduced into the formation through the wellbore.

Abstract: A lost circulation composition for use in a wellbore comprising a crosslinkable polymer system and a filler.

Abstract: A method for well treatment by forming a temporary plug in a fracture, a perforation, a wellbore, or more than one of these locations, in a well penetrating a subterranean formation is provided, in which the method of well treatment includes: injecting a slurry comprising a degradable material, allowing the degradable material to form a plug in a perforation, a fracture, or a wellbore in a well penetrating a formation; performing a downhole operation; and allowing the degradable material to degrade after a selected time such that the plug disappears.

Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising dissymmetric bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions comprising polycationic quaternary ammonium compounds that comprise dissymmetric bis-quaternary compounds. In yet another aspect, the present technology provides polycationic quaternary ammonium compounds comprising a carboxylate functional polycationic quaternary ammonium compound. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C.

Abstract: Methods and compositions that include a method of cementing comprising providing a cement composition comprising water, a hydraulic cement, and an additive comprising at least one additive selected from the group consisting of a stevia retarder and inulin; placing the cement composition in a subterranean formation; and permitting the cement composition to set in the formation.

Abstract: A method for treating a subterranean formation penetrated by a wellbore that includes injecting an alkali silicate into the wellbore; injecting a solid micronized silicate-precipitating agent into the wellbore; and allowing the alkali silicate and the solid micronized silicate-precipitating agent to react to form a silicate gel is disclosed.

Abstract: Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. A material including wax may be introduced into one or more wellbores. The material introduced into two or more wells may mix in the formation and congeal to form a barrier to fluid flow.

Abstract: Of the many methods and compositions provided herein, one method comprises providing a cement composition that comprises a cementitious component and an additive comprising: a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into at least a portion of a subterranean formation; and allowing the cement composition to at least partially set therein. Another method provided herein comprises providing a cement composition that comprises a cementitious component and an additive comprising a polymer, a phosphorus component, a polyvalent metal ion, an oil-based liquid, and a surfactant; introducing the cement composition into a void located in a pipe string; and allowing the cement composition to at least partially set therein. A cement composition provided herein comprises a cementitious component and an additive comprising a polymer; a phosphorus component; a polyvalent metal ion; and an oil-based liquid; and a surfactant.

Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising: placing a sealant composition comprising a cementitious material and a cationic latex into the wellbore.

Abstract: A process to prepare a stable solution of a borozirconate complex is disclosed and use of the solution in oil field applications such as hydraulic fracturing and plugging of permeable zones. The process comprises contacting zirconium complex with a first alkanolamine, then glycerol and water, then with a solution of a boron compound and a second alkanolamine. The solution is particularly suitable for use in a cross-linking composition at temperatures of 275° F. (135° C.) and higher in the subterranean formation.

Abstract: The present invention includes methods of cementing in subterranean formations using cement kiln dust in compositions having reduced Portland cement content. An embodiment of a method comprises placing a sealant composition that comprises cement kiln dust and is essentially free of Portland cement in a subterranean formation; and allowing the sealant composition to set.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a cement composition comprising: cement; a surfactant composition comprising: an ethoxylated alcohol ether sulfate in an amount in the range of about 60 to about 64 parts by weight, a first alkyl or alkene amidopropyl betaine in an amount in the range of about 30 to about 33 parts by weight, and a second alkyl or alkene amidopropyl betaine in an amount in the range of about 1 to about 5 parts by weight; a gas; and water.

Abstract: A gel-forming composition for reducing the permeability of a subterranean formation or zone comprising a water soluble polymer (e.g., Alcoflood® 935) and a polyelectrolyte gelling agent comprising a polycation (e.g., polyalkylene imine) and a polyanion (e.g., dextran sulfate) is provided. The gel-forming composition is used to delay gelation in the subterranean formation.

Abstract: Methods of servicing a wellbore include generating gas in a plugging composition in situ within a permeable zone in the wellbore, thereby improving the ability of the plugging composition to seal the permeable zone. The gas may be generated via a chemical reaction by, for example, introducing first and second reactants to the plugging composition that can react at ambient temperatures in the wellbore. In an embodiment, the first and second reactants are concurrently pumped into the wellbore via separate flow paths within two concentric conduits to the permeable zone where they are allowed to contact each other in the presence of the plugging composition. In another embodiment, the first reactant, the second reactant, and a retarder for slowing the reaction between the two reactants are concurrently pumped to the permeable zone. In yet another embodiment, one of the reactants is encapsulated to delay a reaction between the two reactants.

Abstract: Disclosed embodiments relate to compositions and methods for using a composite particulate comprising a cellulosic fiber and a filler as a lost-circulation material. An example of a method of controlling lost circulation in a subterranean method, comprises contacting a subterranean formation with a fluid comprising a base fluid and a lost circulation material, wherein the lost circulation material comprises a composite particulate, and wherein the composite particulate comprises a cellulosic fiber and a filler. An example method of cementing comprises introducing a cement composition into a well bore penetrating a subterranean formation, wherein the cement compositions comprises a cement, water, and a lost-circulation material, and wherein the lost-circulation material comprises a lost-circulation material, and wherein the lost-circulation material comprises a cellulosic fiber and a filler. Example compositions include lost-circulation materials, treatment fluids and cement compositions.

Abstract: A flexible cement stable at high temperatures contains an extender that is a finely ground bituminous coal and/or a finely ground coke prepared from coal and/or liquid hydrocarbons. Preferred cokes are made from bituminous coals and from petroleum, heavy oil, and oil from tar sands, oil shales or oil sands. The coke is present in an amount up to 100 percent by weight of cement and the particle size is preferably from 1 to 1000 microns. The coke is also effective as an extender, and the slurries and set cements have low specific gravity.

Abstract: The invention describes a method of lining a well using expandable tubing including the steps of lowering a expandable tubing in a well bore; injecting a sealant composition into said well; letting the sealant composition solidify into a deformable matrix embedding at least a bottom section of said tubing within said well; and expanding the tubing. The invention allows the creation of a high quality seal at the shoe of the expandable casing because the deformable material is highly stressed by the expansion, and it also allows for the rest of the casing to be properly supported and protected by conventional cement, without incurring excessive wait-on-cement times.

Abstract: A method of sealing a space in a wellbore formed in an earth formation comprises inserting a plurality of swellable particles into the space by pumping them in a carrier fluid, the particles being susceptible to swelling upon contact with a selected fluid, and inducing the selected fluid to contact the swelleable particles whereby the swelleable particles swell so as to form a body of swollen particles in the space.

Abstract: A method of servicing a wellbore comprising preparing a cement slurry by premixing at least one latex, at least one stabilizer, and optionally water to form a homogeneous solution, further mixing the homogeneous solution with an ionic compound, cement, and optionally additional water to form the slurry, and placing the slurry in the wellbore. A method of stabilizing latex in cement slurry containing saltwater, comprising premixing the latex with a stabilizer until a homogenous solution forms prior to contacting the latex with the saltwater. A cement slurry comprising a latex, a stabilizer, a cement, an ionic compound, and water wherein the latex and stabilizer are contacted prior to contact of the latex with the ionic compound.

Abstract: Degradable material assisted diversion (DMAD) methods for well treatment, DMAD treatment fluids, and removable plugs for DMAD in downhole operations. A slurry of solid degradable material is injected into the well, a plug of the degradable material is formed, a downhole operation is performed around the plug diverter, and the plug is then degraded for removal. Degradation triggers can be temperature or chemical reactants, with optional accelerators or retarders to provide the desired timing for plug removal. In multilayer formation DMAD fracturing, the plug isolates a completed fracture while additional layers are sequentially fractured and plugged, and then the plugs are removed for flowback from the fractured layers. In DMAD fluids, an aqueous slurry can have a solids phase including a degradable material and a fluid phase including a viscoelastic surfactant. The solids phase can be a mixture of fibers and a particulate material.

Abstract: Methods are provided including a method comprising: placing a sand control screen in the wellbore penetrating the subterranean formation, wherein the sand control screen comprises: a base pipe having at least one opening in a sidewall portion thereof; a swellable material layer disposed exteriorly of the base pipe and having at least one opening corresponding to the at least one opening of the base pipe; a telescoping perforation operably associated with the at least one opening of the base pipe and at least partially disposed within the at least one opening of the swellable material layer; and a filter medium disposed within the telescoping perforation; and introducing a consolidating agent into at least a portion of a subterranean formation. Additional methods are also provided.

Abstract: The invention provides a method of altering the properties of a drilling fluid by adding effective amounts of crushed or whole oilseeds or mixtures of crushed whole oilseeds to a drilling fluid. The crushed or whole oilseeds or mixture of crushed or whole oilseeds are selected to impart any one of or a combination of effects including but not limited to: an increase in drilling fluid emulsion stability in oil-based or invert emulsion fluids, decreased specific gravity of the drilling fluid, seepage loss control, filtration control, oil wetting and deflocculation/dispersion, of entrained solids and/or reduced torque and drag of the drilling string.

Abstract: The present invention relates, in general, to subterranean fluids, and more particularly, to subterranean drilling fluids that may be useful for reducing the production of water from a portion of a subterranean formation and/or stabilizing an unconsolidated portion of a subterranean formation while drilling. In some embodiments, the present invention provides methods of reducing the flow of water from a portion of a subterranean formation that comprise contacting the portion of the subterranean formation with an organoaluminum compound, the organoaluminum compound being capable of forming a reaction product in the presence of water. The present invention also includes methods of drilling a well bore in a subterranean formation, methods of enhancing the stability of an unconsolidated portion of a subterranean formation, methods of stabilizing an unconsolidated portion of a subterranean formation, and drilling fluids.

Abstract: Exemplary embodiments of the cement compositions comprise water, a cement, and a fluid loss control additive, the fluid loss control additive comprising a graft copolymer. The graft copolymer comprises a backbone and at least four grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride, and salts thereof. The backbone of the graft copolymer comprises a humic acid salt. Methods of cementing using exemplary embodiments of the cement compositions are also provided.

Abstract: An assembly arranged in a well bore and run in conjunction with a perforated or a non perforated liner has an inflatable packer section prepared for being expanded by fluid and a valve device for opening and closing of fluid communication into the inflatable packer section. The assembly also has a fluid section connected to the inflatable packer section. The fluid section holds a fluid that is delivered into and used to inflate the inflatable packer section. An energy section in the assembly contains an energy source for delivering the fluid from the fluid section into the inflatable packer section. A triggering section includes a control for the energy source and/or the valve device. The triggering section can control the delivery of the fluid into the inflatable packer section. The triggering section also includes a communicator that signals a triggering device for initiating the expanding of the inflatable packer section.

Abstract: Through the combination of at least two polymer families, and the optimization of other components, a rubber compound has been developed for use in downhole applications that will swell in water-based fluids. A cellulose component, such as carboxy methyl cellulose (CMC), is used together with an acrylate copolymer (AC) that can increase the swelling capacity of an acrylonitrile butadiene rubber (NBR) in water to over 1000%. The amount of swelling achieved depends on physical boundaries and limitations, the salinity of the water, and the temperature.

Abstract: A swellable polymer gel composition for use in subterranean formations. The composition comprises water, a water soluble polymer, a water soluble crosslinking system and a swelling agent. The crosslinking system may be either a redox system or a chelating system. The amounts of the polymer and the crosslinking system are effective to form a substantially uniformly reacted tri-dimensional gel structure. To the gel solution, is added a swelling agent in an amount sufficient to increase the volume of the gel a predetermined percentage. The swelling agent may be a natural or a synthetic agent. A strengthening agent may be added to increase the gel strength of the composition. The composition has numerous uses and is particularly useful in oil industry applications such as plugging wells, sealing casing leaks and reducing water production from water-bearing hydrocarbon formations.

Abstract: Defoaming compositions for reducing the amount of gas present in a fluid such as a cement composition are provided. In an embodiment, a defoaming composition includes a carboxylic acid compound or an ester of a carboxylic acid compound; an alpha olefin compound; and an alcohol compound.

Abstract: Sealant compositions comprising an alkali swellable latex and a pH increasing material and methods of using the same to service a wellbore are provided. In one embodiment, the sealant composition can be used in a wellbore and includes an alkali swellable latex and a pH increasing material. The sealant composition can have a pH of from about 7 to about 14. In other embodiments, the pH increasing material includes a base-producing material. The base-producing material can include alkali and alkali earth metal carbonates, alkali and alkali earth metal bicarbonates, alkali and alkali earth metal hydroxides, alkali and alkali earth metal oxides, alkali and alkali earth metal phosphates, alkali and alkali earth metal hydrogen phosphates, alkali and alkaline earth metal sulphides, alkali and alkaline earth metal salts of silicates, alkali and alkaline earth metal salts of aluminates, water soluble or water dispersible organic amines, polymeric amine, amino alcohols, or combinations thereof.

Abstract: Three methods for improving the blocking ability of gels by improving the performance of gels in fractured reservoirs are provided. First method utilizes overload of a crosslinker, the second method utilizes a combination of crosslinker overload and aged crosslinker, and the third method utilizes a step of crosslinker pre-flush. These methods may be combined to further improve the performance of gels in fractured reservoirs. All methods utilized Chromium (III) acetate as a crosslinker. These methods outperformed the base formula of Chromium/polymer typically used in the field.

Abstract: Methods comprising: providing a treatment fluid that comprises a base fluid and a least a plurality of coated particulates, the coated particulates having been treated with a surface modification agent and coated with a hydrolysable coating; placing the treatment fluid into a subterranean formation via a well bore. Also provided are methods comprising: treating a particulate with a surface modification agent; coating the particulate with a hydrolysable coating that has an initial degradation rate to produce a coated particulate; placing the particulate in a subterranean formation; and allowing the hydrolysable coating to degrade at a second degradation rate that is slower than its initial degradation rate.

Abstract: Methods of controlling particulate migration in a portion of a subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into the portion of the subterranean formation; wherein the portion of a subterranean formation being treated has a regain permeability of at least about 70%. Methods of creating a stabilized region around a portion of a subterranean formation around a well bore having a screen or liner in place in that portion of the subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into that portion of the subterranean formation; wherein the portion of a subterranean formation being treated has regain permeability of at least about 70%.

Abstract: Cementitious slurries capable of controlling and/or preventing strength retrogression during the cementing of a formation contain a bismuth salt or derivative thereof. Bismuth trioxide is preferred. The cementitious slurry may further contain a density modifying agent and/or strength enhancer. The cementitious slurries of the invention are suitable for use over a broad temperature range of from about 45° F. to about 500° F.