Placing Preheated Fluid Into Formation Patents (Class 166/303)
  • Publication number: 20070181301
    Abstract: A system and method for extracting hydrocarbon products from oil shale using nuclear energy sources for energy to fracture the oil shale formations and provide sufficient heat and pressure to produce liquid and gaseous hydrocarbon products. Embodiments of the present invention also disclose steps for extracting the hydrocarbon products from the oil shale formations.
    Type: Application
    Filed: November 17, 2006
    Publication date: August 9, 2007
    Inventor: Thomas B. O'Brien
  • Patent number: 7216712
    Abstract: Hydrocarbon solids are removed from an oil well by feeding into the oil well a composition comprising at least 40 vol. % dense phase carbon dioxide and at least 30 vol. % of a C1–C3 alkanol component and optionally one or more surfactants, under a pressure of 300 to 10,000 psia and a temperature of 90° F. to 120° F., holding the composition in the well to solubilize hydrocarbon solids, and then removing from the well a liquid composition comprising solubilized hydrocarbon solids and alkanol.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: May 15, 2007
    Assignee: Praxair Technology, Inc.
    Inventor: Dan Dalton
  • Patent number: 7150320
    Abstract: A process for treating produced water to generate high pressure steam. Produced water from heavy oil recovery operations is treated by first removing oil and grease. If necessary, the pH is then adjusted, normally downward, releasing at least some carbonate alkalinity as free carbon dioxide. Pretreated produced water is then fed to an evaporator. Up to 95% or more of the pretreated produced water stream is evaporated to produce (1) a distillate having a trace amount of residual solutes therein, and (2) evaporator blowdown containing substantially all solutes from the produced water feed. The distillate may be directly used, or polished to remove the trace residual solutes before being fed to a steam generator. Steam generation in a packaged boiler, such as a water tube boiler having a steam drum and a mud drum with water cooled combustion chamber walls, produces 100% quality high pressure steam for down-hole use.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: December 19, 2006
    Inventor: William F. Heins
  • Patent number: 7147057
    Abstract: Systems and methods are provided for treating a wellbore using a loop system to heat oil in a subterranean formation contacted by the wellbore. The loop system comprises a loop that conveys a fluid (e.g., steam) down the wellbore via a injection conduit and returns fluid (e.g., condensate) from the wellbore via a return conduit. A portion of the fluid in the loop system may be injected into the subterranean formation using one or more valves disposed in the loop system. Alternatively, only heat and not fluid may be transferred from the loop system into the subterranean formation. The fluid returned from the wellbore may be re-heated and re-conveyed by the loop system into the wellbore. Heating the oil residing in the subterranean formation reduces the viscosity of the oil so that it may be recovered more easily.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: December 12, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: David Joe Steele, Jody R. McGlothen, Russell Irving Bayh, III
  • Patent number: 7100994
    Abstract: A method for treating a hydrocarbon containing formation is provided. In one embodiment, heat from one or more heaters may be provided to at least a portion of the formation. Heat may be allowed to transfer from the one or more heaters to at least a part of the formation. In certain embodiments, the heat from the one or more heaters may pyrolyze at least some hydrocarbons within the formation. In an embodiment, a first fluid may be introduced into at least a portion of the formation. The portion may have previously undergone an in situ conversion process. A mixture of the first fluid and a second fluid (or a second compound) may be produced from the formation. In some embodiments, a first fluid may be provided to the formation prior to pyrolyzing hydrocarbons in the formation, and a second fluid (or a second compound) may be produced prior to pyrolyzing hydrocarbons in the formation.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: September 5, 2006
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric Pierre de Rouffignac, Kevin Albert Maher, Lanny Gene Schoeling, Scott Lee Wellington
  • Patent number: 7093655
    Abstract: A method for recovering hydrocarbon trapped in a hydrate formation, comprising the steps of (a) contacting the hydrate formation with an aqueous solution comprising from 10% to 75% by weight of a salt such as potassium formate or acetate salt to liberate hydrocarbon from the hydrate formation and producing a mixture of hydrocarbon and water vapour; (b) transporting the hydrocarbon/water vapour mixture and the aqueous solution to a separator, whereby the said aqueous solution absorbs water vapour from the mixture during the transportation step, to form a more dilute aqueous solution of the alkali metal salt, thereby inhibiting formation of hydrocarbon hydrates; (c) separating hydrocarbon from said dilute aqueous solution; (d) regenerating the aqueous solution of step (a) by heating said dilute aqueous solution to remove absorbed water vapour; and (f) recycling the regenerated aqueous solution to step (a).
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: August 22, 2006
    Inventor: Stephen Atkinson
  • Patent number: 7086465
    Abstract: An in situ process for treating a hydrocarbon containing formation is provided. The process may include providing heat from one or more heaters to at least a portion of the formation. The heat may be allowed to transfer from the reaction zone to a part of the formation such that heat from one or more heaters pyrolyzes at least some hydrocarbons within the part of the formation. A blending agent may be produced from the part of the formation, wherein a mixture produced with the blending agent has at least one selected property.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: August 8, 2006
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, John Michael Karanikas, Kevin Albert Maher, Meliha Deniz Sumnu-Dindoruk, Harold J. Vinegar
  • Patent number: 7077199
    Abstract: An in situ process for treating an oil containing formation is provided. The process may include providing heat from one or more heaters to at least a portion of the formation. The heat may be allowed to transfer from the one or more heaters to a part of the formation such that heat from the one or more heat sources pyrolyzes at least some hydrocarbons within the part. Hydrocarbons may be produced from the formation.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: July 18, 2006
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Ilya Emil Berchenko, Eric P. de Rouffignac, Thomas David Fowler, Robert Charles Ryan, Scott Lee Wellington, Etuan Zhang
  • Patent number: 7077201
    Abstract: An evaporation based method of treating produced water from heavy oil production. A produced water from heavy oil recovery operations treated by first removing oil and grease to a desired level, preferably to about twenty parts per million, or less. If necessary, the pH is then adjusted, normally downward and by acid addition, to release at least some carbonate alkalinity as free carbon dioxide. Preferably, all non-hydroxide alkalinity is removed, or substantially so, by introducing the feedwater into a decarbonator. Feedwater is introduced into an evaporator, and the feedwater is evaporated to a selected concentration factor to produce (1) a distillate having a small amount of residual solutes, and (2) evaporator blowdown containing residual solids. Distillate may be directly used for steam generation in a once-through steam generator, or polished by ion exchange or electrodeionization prior to feed to a packaged boiler.
    Type: Grant
    Filed: November 30, 2002
    Date of Patent: July 18, 2006
    Assignee: GE Ionics, Inc.
    Inventor: William F. Heins
  • Patent number: 7037434
    Abstract: A water stream containing hardness minerals is subjected to a water treatment process using an alkali agent to precipitate the hardness minerals and to produce a softened water stream is used to create an integrated water treatment and flue gas desulfurization process. Thereafter, the softened, alkaline water stream is utilized in a scrubber to scrub a flue gas containing sulfur dioxide to produce a sulfur-lean flue gas. The invention may be applied to a steam-based bitumen recovery operation where bitumen, sour produced gas or other sulfur containing fuels are burned for producing steam for bitumen recovery. More specifically, the associated produced water from the bitumen recovery process may be softened for re-use and for utilization as a scrubbing agent for high-sulfur containing flue gas arising from the steam generators. The process provides an economically favorable process while minimizing waste disposal requirements.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: May 2, 2006
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Ronald D. Myers, Mainak Ghosh, John B. MacLeod, Michael K. Bridle
  • Patent number: 7032675
    Abstract: Methods of operating a downhole tool comprise thermally-controlling the tool by sensing a temperature and controlling the tool in response to the sensed temperature. Thermally-controlled downhole tools comprise a control element responsive to a change in temperature that control flow into, out of, or through a wellbore. Methods and systems for servicing a wellbore comprise using a thermally-controlled tool comprising a thermally-controlled valve (TCV) in a wellbore. The TCV includes a valve body comprising an injection port for allowing material to flow into or out of the wellbore and an opening/closing mechanism for regulating flow of the material through the injection port in response to a change in temperature. The valve body may be coupled to a downhole conduit. A plurality of TCV's may be arranged in the wellbore to control the injection of steam into the wellbore or the recovery of oil from the wellbore.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: April 25, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: David Joe Steele, Russell Irving Bayh, III, Joseph D. Parlin, Michael Wade Meaders, Dan P. Saurer
  • Patent number: 7017661
    Abstract: A coal formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. Synthesis gas may be produced from the formation in a batch manner or in a substantially continuous manner.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: March 28, 2006
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, George Leo Stegemeier, Kevin Albert Maher, Etuan Zhang, Thomas David Fowler, Robert Charles Ryan, Robert Martijn Van Hardeveld
  • Patent number: 6997518
    Abstract: An oil shale formation may be treated using an in situ thermal process. Heat may be provided to the treatment area. Fluids may be injected into the formation to remove a component within the formation. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. In some embodiments, fluids may be injected prior to production of formation fluids. Alternatively, fluids may be injected after production of formation fluids.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: February 14, 2006
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric Pierre de Rouffignac, Kevin Albert Maher, Lanny Gene Schoeling, Scott Lee Wellington
  • Patent number: 6987083
    Abstract: Xanthan gels hydratable in brine, methods of making these xanthan gels, and methods of using these compositions in subterranean formation applications, such as gravel packing, are provided herein.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: January 17, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Max L. Phillippi, Richard W. Pauls
  • Patent number: 6978837
    Abstract: Methods and apparatus for producing methane gas from a hydrate formation. A column of modified material substantially filling a wellbore extending into the hydrate formation. The column of modified material is permeable to gases. A heat source extends into the column of modified material and is operable to provide heat to the hydrate formation so as to release methane gas from the hydrate formation. Methane gas flow through the column of modified material to a gas collector, which regulates the flow of gas to a production system.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: December 27, 2005
    Inventor: Charles R. Yemington
  • Patent number: 6966374
    Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may reduce the viscosity of at least some hydrocarbons within the selected section. A gas may be provided to the selected section of the formation. The gas may produce a flow of hydrocarbons within the selected section. A mixture of hydrocarbons may be produced from the selected section.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: November 22, 2005
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Meliha Deniz Sumnu-Dindoruk, Scott Lee Wellington
  • Patent number: 6964300
    Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may pyrolyze at least some hydrocarbons within the selected section. A temperature proximate a selected portion of a heater well may be selectively limited to inhibit coke formation at or near the selected portion. A mixture of at least some hydrocarbons may be produced through the selected portion of the heater well.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: November 15, 2005
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric Pierre de Rouffignac, John Michael Karanikas, Meliha Deniz Sumnu-Dindoruk, Scott Lee Wellington
  • Patent number: 6955221
    Abstract: Hydrocarbon liquids are transported from a subsea welihead to an above-surface hydrocarbon processing facility along a pipe-in-pipe flowline. The flowline is a pipe placed coaxially within an outer carrier pipe and the annulus between the pipes is filled with thermally insulating material. The hydrocarbon liquids have their temperature maintained above solidification/precipitation temperature by heat from an active heating system. Hot liquid, preferably hot water, is passed along the annulus, either along a single pipe or multiple pipes installed in the insulation-filled annulus, or along an inner annulus formed by a water pipe added concentrically around the hydrocarbon-transporting inner pipe, inside the outer insulation-filled annulus. The water or other suitable liquid can be heated in a heater at or adjacent the subsea wellhead, or by a water heater in the above-surface hydrocarbon processing facility.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: October 18, 2005
    Assignee: Stolt Offshore Inc.
    Inventor: Gabriel André Bursaux
  • Patent number: 6948562
    Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a selected section of the formation. The heat provided to the selected section may pyrolyze at least some hydrocarbons in the selected section. A blending agent may be produced from the selected section. A portion of the blending agent may be adapted to blend with a liquid to produce a mixture with a selected property.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: September 27, 2005
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Kevin Albert Maher, Margaret Ann Messier, Bruce Edmunds Roberts, Meliha Deniz Sumnu-Dindoruk, Harold J. Vinegar
  • Patent number: 6932155
    Abstract: A process for producing hydrocarbons through a heater wellbore positioned in a hydrocarbon containing formation. The in situ treatment process may include providing heat from one or more heaters to at least a portion of the formation. The heat may be allowed, in some embodiments, to transfer from one or more heaters to a selected section of the formation. Heat that is allowed to transfer to the selected section may pyrolyze at least some of the hydrocarbons within the selected section. The process may include, in some embodiments, selectively limiting a temperature proximate a selected portion of a heater wellbore to inhibit coke formation at or near the selected portion. In some embodiments fluids may be produced at certain locations of a heater wellbore such that coke formation is inhibited.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: August 23, 2005
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Eric Pierre de Rouffignac, John Michael Karanikas, Scott Lee Wellington
  • Patent number: 6896054
    Abstract: A wellbore method which, in certain aspects, includes providing a fluid with microorganisms and introduction apparatus for introducing the fluid into an earth formation bearing hydrocarbons to facilitate removal of the hyrdrocarbons, effecting heat exchange between the fluid and a heat transfer medium that has traversed an earth loop of an earth loop heat exchange system, the earth loop extending from an earth surface down into the earth and the heat transfer medium flowable through the earth loop and transfer apparatus for transferring heat between the fluid and the heat transfer medium; and, in certain aspects wherein effecting the heat exchange between the fluid and the heat transfer medium prolongs life of and/or enhances activity of the microorganisms.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: May 24, 2005
    Inventor: Guy L. Mcclung, III
  • Patent number: 6883607
    Abstract: A process for the recovery of hydrocarbons from a hydrocarbon bearing formation having an extraction chamber where the extraction chamber has an extraction surface. The process has the steps of heating a solvent, such as propane, and then placing the solvent into the extraction chamber at a temperature and a pressure sufficient for the solvent to be in a vapor state in the chamber and to condense on the extraction surface. The next step is to produce a liquid blend of solvent and heavy oil and then to separate the solvent from said heavy oil. Then the solvent is purified, before being re-injected into the formation again. The purification step removes less condensable fractions from the solvent to ensure a purity that is high enough to support continued heat transfer at extraction conditions. The pressure and temperature are set to levels to cause less condensable fractions to drain away with the liquid bitumen and solvent blend that is produced, thus mitigating heat transfer poisoning.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: April 26, 2005
    Assignee: N-Solv Corporation
    Inventors: John Nenniger, Emil Nenniger
  • Patent number: 6877555
    Abstract: An oil shale formation may be treated using an in situ thermal process. Heat may be provided to a portion of the formation. Heat may be allowed to transfer from one or more heat sources to a section of the formation. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation through a production well. Conditions at the production well may be controlled to inhibit coking at or near the production well.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: April 12, 2005
    Assignee: Shell Oil Company
    Inventors: John Michael Karanikas, Eric Pierre de Rouffignac, Harold J. Vinegar, Scott Lee Wellington
  • Patent number: 6854809
    Abstract: A method for solution mining nahcolite, capable of extracting nahcolite from geological formations lean in nahcolite comprising injecting high pressure water (which may include recycled aqueous solution of bicarb and sodium carbonate) at a temperature of at least 250° F. into the formation, dissolving nahcolite in the hot water to form a production solution and recovering the production solution. The invention also includes the processing of the production solution to provide sodium carbonate and, optionally, sodium bicarbonate, comprising: decomposing the sodium bicarbonate portion of the hot aqueous production solution to form a hot aqueous solution of sodium carbonate; evaporating water from the hot aqueous solution comprising sodium carbonate to form a concentrated solution of sodium carbonate; producing sodium carbonate monohydrate from the concentrated solution of sodium carbonate by crystallization; and dewatering and calcining the sodium carbonate monohydrate to produce anhydrous sodium carbonate.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: February 15, 2005
    Assignee: American Soda, LLP
    Inventors: Max E. Ramey, John S. McEwan, Kevin L. Green, Charles L. Yates, Allan L. Turner, Michael A. Rockendal, Irvin P. Nielsen, Michael P. Hardy, Rex Goodrich
  • Publication number: 20040256105
    Abstract: A system for heating drilling, completion, and/or stimulation fluids including acidizing liquids but not limited to; entering or exiting a wellbore, the system including a principal heat exchange vessel; a first inlet for introducing heat transfer media into fluid flow lines within the vessel; an outlet for flowing the heat transfer media from the vessel; a second inlet for introducing fluids returning from or returning to the well bore for receiving heat from the heating fluid within the fluid flow lines in the vessel; an outlet for flowing the heated downhole fluids from the vessel to be returned down the borehole; a heater for heating the heating fluid to a desired temperature before returning the heating fluid to the heat exchange vessel. Optimally, the drilling or completion fluid would be heated to 50° to 60° F. above ambient temperature.
    Type: Application
    Filed: June 22, 2004
    Publication date: December 23, 2004
    Inventor: Perry A. Lopez
  • Patent number: 6779606
    Abstract: A system for heating drilling, completion, and/or stimulation fluids including acidizing liquids but not limited to; entering or exiting a wellbore, the system including a principal heat exchange vessel; a first inlet for introducing heat transfer media into fluid flow lines within the vessel; an outlet for flowing the heat transfer media from the vessel; a second inlet for introducing fluids returning from or returning to the well bore for receiving heat from the heating fluid within the fluid flow lines in the vessel; an outlet for flowing the heated downhole fluids from the vessel to be returned down the borehole; a heater for heating the heating fluid to a desired temperature before returning the heating fluid to the heat exchange vessel. Optimally, the drilling or completion fluid would be heated to 50° to 60° F. above ambient temperature.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: August 24, 2004
    Inventor: Perry A. Lopez
  • Publication number: 20040149433
    Abstract: A process and system for recovering hydrocarbonaceous products from in situ oil shale formations. A hole is drilled in the oil shale formation and a processing gas inlet conduit is positioned within the hole. A processing gas is pressurized, heated, and introduced through the processing gas inlet conduit and into the hole. The processing gas creates a nonburning thermal energy front within the oil shale formation so as to convert kerogen in the oil shale to hydrocarbonaceous products. The products are withdrawn with the processing gas through an effluent gas conduit positioned around the opening of the hole, and are then transferred to a condenser wherein a liquid fraction of the products is formed and separated from a gaseous fraction.
    Type: Application
    Filed: February 3, 2003
    Publication date: August 5, 2004
    Inventor: Ronald E. McQueen
  • Patent number: 6769485
    Abstract: A coal formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. Production wells may be operated at selected temperatures to obtain a desired synthesis gas composition.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: August 3, 2004
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, Ilya Emil Berchenko, George Leo Stegemeier, Robert Martijn Van Hardeveld
  • Patent number: 6761216
    Abstract: A coal formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. After pyrolysis, the portion may be heated to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the portion to generate synthesis gas. Synthesis gas may be produced from the formation in a batch manner or in a substantially continuous manner.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: July 13, 2004
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, George Leo Stegemeier, Ajay Madhav Madgavkar, Robert Martijn Van Hardeveld
  • Publication number: 20040129418
    Abstract: The invention relates to a method for treating subterranean formation comprising providing distributed temperature sensors, injecting a treatment fluid and monitoring the temperature across the treatment interval during the injection process.
    Type: Application
    Filed: July 28, 2003
    Publication date: July 8, 2004
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Virginia Jee, Nicolas Flamant, Hubertus Thomeer, Sarmad Adnan, Michael Gay
  • Patent number: 6752208
    Abstract: Methods of reducing proppant flowback during production of fluids form subterranean formations are provided. Compressed sieves made from a shape memory material are introduced into hydraulic fracturing opera into hydraulic fractures in subterranean formations during hydraulic fracturing operations or subsequent thereto. The heat of the formation, or introduced heat, triggers the return of the sieves to their previous uncompressed shape and size. The sieves thereby wedge themselves into position within the fractures and serve to filter proppant and formation fines from produced fluids.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: June 22, 2004
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Philip D. Nguyen
  • Patent number: 6739394
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. Synthesis gas may be produced from the formation in a batch manner or in a substantially continuous manner.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: May 25, 2004
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, John Michael Karanikas, Ilya Emil Berchenko, George Leo Stegemeier, Kevin Albert Maher, Thomas David Fowler, Robert Charles Ryan, Lanny Gene Schoeling, Robert Martijn Van Hardeveld
  • Patent number: 6733636
    Abstract: A method of treating produced water from heavy oil production to provide feedwater for the production of high quality steam. A produced water from heavy oil recovery operations is initially treated by first removing oil and grease to a desired level, preferably to about twenty parts per million, or less. The pH is then adjusted, normally downward and by acid addition, to release at least some carbonate alkalinity as free carbon dioxide. Preferably, all non-hydroxide alkalinity is removed, or substantially so, by introducing the feedwater into a decarbonator. In some cases, the pH may be raised (without, or subsequent to decarbonation, depending upon water chemistry) preferably by caustic addition, to maintain silica solubility in the feedwater.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: May 11, 2004
    Assignee: Ionics, Inc.
    Inventor: William F. Heins
  • Patent number: 6722436
    Abstract: A method and apparatus for controlling the operation of an internal combustion engine to reduce the presence of free oxygen in the exhaust gas of the engine. The method and apparatus provides for the internal combustion engine to be operated with a fuel-to-air ratio in excess of the stoichiometric ratio such that the exhaust gas from the internal combustion engine is devoid or substantially devoid of all free oxygen and excess unburned hydrocarbon fuel is expelled with the exhaust gas from the engine.
    Type: Grant
    Filed: January 25, 2002
    Date of Patent: April 20, 2004
    Assignee: Precision Drilling Technology Services Group Inc.
    Inventor: Ross Michael Krill
  • Patent number: 6715546
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. Hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a synthesis gas production temperature. A synthesis gas producing fluid may be introduced into the formation to generate synthesis gas. Production wells may be operated at selected temperatures to obtain a desired synthesis gas composition.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: April 6, 2004
    Assignee: Shell Oil Company
    Inventors: Harold J. Vinegar, Scott Lee Wellington, Eric Pierre de Rouffignac, Ilya Emil Berchenko, George Leo Stegemeier, Robert Martijn Van Hardeveld
  • Patent number: 6708763
    Abstract: The present invention generally provides a method and apparatus for injecting a compressible fluid at a controlled flow rate into a geological formation at multiple zones of interest. In one aspect, the invention provides a tubing string with a pocket and a nozzle at each isolated zone. The nozzle permits a predetermined, controlled flow rate to be maintained at higher annulus to tubing pressure ratios. The nozzle includes a diffuser portion to recover lost steam pressure associated with critical flow as the steam exits the nozzle and enters a formation via perforations in wellbore casing. In another aspect, the invention ensures steam is injected into a formation in a predetermined proportion of water and vapor by providing a plurality of apertures between a tubing wall and a pocket. The apertures provide distribution of steam that maintains a relative mixture of water and vapor.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: March 23, 2004
    Assignee: Weatherford/Lamb, Inc.
    Inventors: William F. Howard, Jackie C. Sims, Dudley L. Robinson, Ronald W. Schmidt
  • Patent number: 6708759
    Abstract: LASER-CSS provides a method to improve cyclic steam-based thermal recovery methods for heavy oils and bitumen. A key improvement over prior art consists of mixing liquid hydrocarbons into the injected steam instead of injecting such hydrocarbon as a separate slug in front of a steam stimulation cycle. The objective of the invention is to enhance field applications of Cyclic Steam Stimulation (CSS) by contacting and mobilizing more of the bitumen with the same amount of steam. This is to help increase the recovery efficiency and ultimate recovery normally achieved with conventional CSS-type process operations. The proposed LASER-CSS method utilizes existing CSS wells at some intermediate stage of reservoir depletion. Liquid hydrocarbons are directly mixed and flashed into the injected steam lines, injected into the CSS wellbores and further transported as vapors to contact heavy oil or bitumen surrounding steamed areas between adjacent wells.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: March 23, 2004
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Roland P. Léauté, Kathy E. Corry, B. Karl Pustanyk
  • Publication number: 20040040716
    Abstract: Hydrocarbon liquids are transported from a subsea wellhead to an above-surface hydrocarbon processing facility along a pipe-in-pipe flowline wherein the hydrocarbon-transporting pipe is placed coaxially within an outer carrier pipe and the annulus between the pipes is filled with thermally insulating material. The hydrocarbon liquids have their temperature maintained above solidification/precipitation temperature by heat from an active heating system in accordance with the invention. Hot liquid, preferably hot water, is passed along the annulus, either along a single pipe or multiple pipes installed in the insulation-filled annulus, or along an inner annulus formed by a water pipe added concentrically around the hydrocarbon-transporting inner pipe, inside the outer insulation-filled annulus.
    Type: Application
    Filed: May 23, 2003
    Publication date: March 4, 2004
    Inventor: Gabriel Andre Bursaux
  • Publication number: 20030127226
    Abstract: An evaporation based method of treating produced water from heavy oil production. A produced water from heavy oil recovery operations treated by first removing oil and grease to a desired level, preferably to about twenty parts per million, or less. If necessary, the pH is then adjusted, normally downward and by acid addition, to release at least some carbonate alkalinity as free carbon dioxide. Preferably, all non-hydroxide alkalinity is removed, or substantially so, by introducing the feedwater into a decarbonator. Feedwater is introduced into an evaporator, and the feedwater is evaporated to a selected concentration factor to produce (1) a distillate having a small amount of residual solutes, and (2) evaporator blowdown containing residual solids. Distillate may be directly used for steam generation in a once-through steam generator, or polished by ion exchange or electrodeionization prior to feed to a packaged boiler.
    Type: Application
    Filed: November 30, 2002
    Publication date: July 10, 2003
    Inventor: William F. Heins
  • Publication number: 20030102130
    Abstract: A method for treating a relatively permeable formation containing heavy hydrocarbons in situ may include providing heat from one or more heat sources to a portion of the formation. The heat may be allowed to transfer from the heat sources to a selected section of the formation. The transferred heat may pyrolyze at least some hydrocarbons within the selected section. A mixture may be produced from the selected section. A quality of the produced mixture may be controlled by varying a location for producing the mixture.
    Type: Application
    Filed: April 24, 2002
    Publication date: June 5, 2003
    Inventors: Harold J. Vinegar, Meliha Deniz Sumnu-Dindoruk, Scott Lee Wellington
  • Patent number: 6554067
    Abstract: A method for consolidating sand around a well, involving injecting hot water or steam through well casing perforations in to create a cement-like area around the perforation of sufficient rigidity to prevent sand from flowing into and obstructing the well. The cement area has several wormholes that provide fluid passageways between the well and the formation, while still inhibiting sand inflow.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: April 29, 2003
    Assignee: Tidelands Oil Production Company
    Inventors: David K. Davies, Julius J. Mondragon, III, Philip Scott Hara
  • Publication number: 20030062162
    Abstract: A method and apparatus for treating a subterranean well formation to stimulate the production of hydrocarbons utilizing foam diversion in the well formation. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure; and is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims under 37CFR 1.72.
    Type: Application
    Filed: September 28, 2001
    Publication date: April 3, 2003
    Inventors: Richard L. Middaugh, Jim B. Surjaatmadja
  • Publication number: 20030062164
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. The mixture produced from the formation may contain condensable hydrocarbons fluids with some nitrogen containing hydrocarbons.
    Type: Application
    Filed: April 24, 2001
    Publication date: April 3, 2003
    Inventors: Scott Lee Wellington, Harold J. Vinegar, Eric Pierre de Rouffignac, Ilya Emil Berchenko, George Leo Stegemeier, Etuan Zhang, Gordon Thomas Shahin, Thomas David Fowler, Robert Charles Ryan
  • Patent number: 6540023
    Abstract: A process for producing a diesel fuel stock from bitumen uses steam, naphtha and a hydroisomerized diesel fraction produced by a gas conversion process, to respectively (i) stimulate the bitumen production, (ii) dilute it for pipeline transport to an upgrading facility, and (iii) increase the cetane number of a hydrotreated diesel fuel fraction produced by upgrading the bitumen by blending it with the hydroisomerized gas conversion diesel fraction, to form the diesel stock. This diesel stock has a higher cetane number than that produced from the bitumen alone, and is used for blending and forming diesel fuel.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: April 1, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stephen Mark Davis, Michael Gerard Matturro
  • Patent number: 6536523
    Abstract: There is disclosed a method and apparatus for treating produced water from a heavy oil thermal recovery unit to achieve water recovery and recycle levels of greater than 80% and as high as 100% to achieve zero discharge criteria. The method includes the initial steps of capturing the waste heat energy from the high pressure steam separator located downstream of the steam generators. Further, transferring the heat energy into a heated separator and reboiler exchanger to distill oil reservoir produced water and recover distilled water and a concentrated brine or solid product. The heated separator concentrated stream is circulated through the reboiler exchanger to maintain from 1% to about 50% mass vapour in the stream returning to the heated separator and prevent fouling and scaling. The apparatus includes a low pressure waste energy separator, heated separator and vapour compressor in combination with a forced circulation circuit to generate the distilled water.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: March 25, 2003
    Assignees: Aqua Pure Ventures Inc., Alberta Energy Company Ltd.
    Inventors: Steve Kresnyak, Alex Braun
  • Patent number: 6491096
    Abstract: The present invention provides a two phase heat generation system (10) having a primary pressure vessel (108), an, interior vessel (122) spaced from the primary pressure vessel (108) defining a water jacket cavity (124) and a combustion chamber (125), the water cavity (124) being in fluid communication with the combustion chamber (126), the combustion chamber (126) having a combustion burner (144) for controlling combustion, a delivery conduit (136) being in communication with the combustion chamber (126) for delivering gas and compressed air into the combustion chamber (126) and an outlet passage (164) being in communication with the combustion chamber (126) for delivering of a two phase product.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: December 10, 2002
    Inventor: John A. Masek
  • Publication number: 20020170714
    Abstract: A process for producing a diesel fuel stock from bitumen uses steam, naphtha and a hydroisomerized diesel fraction produced by a gas conversion process, to respectively (i) stimulate the bitumen production, (ii) dilute it for pipeline transport to an upgrading facility, and (iii) increase the cetane number of a hydrotreated diesel fuel fraction produced by upgrading the bitumen by blending it with the hydroisomerized gas conversion diesel fraction, to form the diesel stock. This diesel stock has a higher cetane number than that produced from the bitumen alone, and is used for blending and forming diesel fuel.
    Type: Application
    Filed: March 27, 2001
    Publication date: November 21, 2002
    Inventors: Stephen Mark Davis, Michael Gerard Matturro
  • Publication number: 20020144818
    Abstract: LASER-CSS provides a method to improve cyclic steam-based thermal recovery methods for heavy oils and bitumen. A key improvement over prior art consists of mixing liquid hydrocarbons into the injected steam instead of injecting such hydrocarbon as a separate slug in front of a steam stimulation cycle. The objective of the invention is to enhance field applications of Cyclic Steam Stimulation (CSS) by contacting and mobilizing more of the bitumen with the same amount of steam. This is to help increase the recovery efficiency and ultimate recovery normally achieved with conventional CSS-type process operations. The proposed LASER-CSS method utilizes existing CSS wells at some intermediate stage of reservoir depletion. Liquid hydrocarbons are directly mixed and flashed into the injected steam lines, injected into the CSS wellbores and further transported as vapors to contact heavy oil or bitumen surrounding steamed areas between adjacent wells.
    Type: Application
    Filed: April 2, 2002
    Publication date: October 10, 2002
    Inventors: Roland P. Leaute, Kathy E. Corry, B. Karl Pustanyk
  • Publication number: 20020100587
    Abstract: A closed loop heat transfer system located on the surface near the wellhead for transporting hot fluid through a tubing located in the annulus between the well casing and the outer surface of the production string. The tubing extends down along the production string to a coil submerged in the oil reservoir in the vicinity of the production pump and back to the surface for reheating and recirculation. The tubing provides heat transfer from the hot fluid to the production fluid, as well as the downhole pump and the region of the oil reservoir surrounding the pump. The system is preferably operated to transfer enough heat to the oil to prevent paraffins from coagulating and forming deposits on the production string or sucker rods, if used. The higher temperature lowers the viscosity of the oil and increases oil production.
    Type: Application
    Filed: January 26, 2001
    Publication date: August 1, 2002
    Inventor: Ken Lewis
  • Publication number: 20020084074
    Abstract: A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H2, and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat may also uniformly increase a porosity of a treated portion of the formation.
    Type: Application
    Filed: September 24, 2001
    Publication date: July 4, 2002
    Inventors: Eric Pierre de Rouffignac, Harold J. Vinegar, Scott Lee Wellington, Ilya Emil Berchenko, George Leo Stegemeier, Etuan Zhang, Gordon Thomas Shahin, Thomas David Fowler, Robert Charles Ryan