Abstract: A method and apparatus for recovering oil from oil-containing sorbents, such as drill cuttings obtained from drilling with an oil-based mud. The method includes peptizing the substrate with an acid reagent and direct thermal desorption with combustion effluent gases at high temperature under turbulent mixing conditions. Another method disclosed includes upgrading the oil in the substrate to improve one or more of the properties of the recovered oil relative to the oil in the substrate, such as, lower aromatics content, lower sulfur content, lower functional group content, higher saturates, higher viscosity, higher viscosity index, and any combination thereof. The apparatus provides for efficient recovery of oil from the substrate with a short residence time, high throughput, low residual oil content in the treated solids and/or high percentage of oil recovery. The apparatus may be transported to a remote location for on-site treatment of drill cuttings or other oil-containing solids.

Abstract: A method and apparatus for treating for disposal oil contaminated substrates, such as drill cuttings from drilling with an oil-based mud, by steam distillation. If necessary, the contaminated substrate 10 can be pretreated with an emulsion breaker 14. The contaminated substrate 10 can be treated with steam 16 in a first mixing still 12. The substrate can be optionally treated with a second steam source 20 in a second mixing still 18. The steam provides heat to vaporize the oil, moisture to treat the substrate and water to the reaction mixture. Recoverable constituents in the vapor can be condensed in a vapor collection system 24. The treated substrate 22 is essentially free of oil and can have a controlled water content. The process exhibits low energy consumption, rapid treatment, compact equipment and a high degree of process control.

Abstract: A method and apparatus for decoking and suppressing coke formation during pyrolysis has been discovered that does not require complete shut down of the pyrolysis furnace. For the decoking step, the hydrocarbon feed is cut off to one or more coils for usually less than about three hours during which a decoking additive is added to the steam flow in that coil. This additive is comprised of an aqueous solution of a group IA metal salt and a group IIA metal salt and catalyzes the coke removal. The hydrocarbon feed continues in the other coils during this procedure. After decoking, a suppression additive also comprising group IA and IIA metals is added to the steam and hydrocarbon feed. This suppression additive will melt onto the inner surfaces of the pyrolysis furnace coils, coating the coils with a glass layer which inhibits coke formation.

Abstract: A new and improved two-stage oil bypass filter device is provided to enable effective and efficient removal of both solid particulate and volatile oil contaminants while also allowing the addition and mixing of certain oil additives as required by specific internal combustion engine or industrial applications.

Abstract: An oil reclamation device includes an evaporator head and base both of heat conductive material and defining an evaporator chamber between them. An upwardly vertically extending heating element is disposed within the evaporator base for heating oil containing contaminants within the evaporator chamber by conduction and convection to evaporate light contaminants/liquids (e.g. water, fuel or antifreeze) in the oil. A vent extends from the evaporator chamber through the head, and an oil discharge conduit provides gravity discharge from the evaporator chamber and is formed in the base. An oil inlet conduit feeds oil from the head toward the evaporator chamber, preferably through a plurality of substantially evenly spaced passages formed in the head and flaring outwardly from the oil inlet conduit to the evaporator chamber to provide flow of oil in small, distinct, spaced streams to impact a portion of a generally annular frustoconical wall element extending upwardly form the base toward the head.

Abstract: This invention discloses a method of in-service cleaning an operating column by inserting into the column a lance through which a compatible liquid is dispensed at a pressure of at least about 5000 psig. Also disclosed is apparatus which comprises a column through which a fluid can pass, nozzles mounted on the outside of the column, where each nozzle comprises a flange welded to the column and a valve bolted to the flange, a lance which can be inserted through the nozzles into the column and means for dispensing a liquid through the lance at a pressure of at least about 5000 psig.

Abstract: Process and apparatus for catalytic conversion of oils. A furnace heats a feedstock which is provided to a separator for separation of the feedstock into a gas vapor phase and a liquid phase. The liquid phase is provided under pressure to a venturi nozzle which atomizes the liquid oil. The atomized oil and the gas are each provided to a reactor such as the lower end of a riser reactor in a fluid catalytic cracking unit.

Abstract: The thermodynamic efficiency of a tar sands conditioning drum is improved by continuously and simultaneously discharging steam from all the nozzles of an array of a few relatively large nozzles distributed circumferentially around the inner drum periphery rather than selectively sparging the steam only from those nozzles beneath the tar sands pulp surface. As a result, the drum shell and components above the pulp are heated and thus heat the pulp by radiation and, after entering the pulp, by convection as well as by sparging. Hot water droplets formed continuously in the steam cloud rain onto the pulp surface to provide another highly important heat transfer mechanism. Coincidentally, mechanical reliability and economics are achieved by eliminating the sparge valve and multiplicity of smaller nozzles which characterize the prior art tar sands conditioning drums.

Abstract: A coker blow down recovery system for recovering additional useful fuel components such as C.sub.1 --C.sub.7 hydrocarbons from a coker vessel is disclosed. A significant reduction in sulfur components contained in coker blow down gases, e.g. flare gases, is also achieved.

Abstract: A closed reactor for the thermal cracking of heavy oils, having an internally mounted, rotatable injection pipe. The injection pipe is adapted to spurt preheated raw material under pressure against the inner wall surfaces of the reactor while rotating to remove coke which has deposited on the reactor walls during the previous cracking operation.

Abstract: A decoking apparatus suitable for use on a reaction vessel for the thermal cracking of heavy petroleum oils the apparatus essentially including a rotatable main injection pipe to be disposed in the reaction vessel and having a multitude of jet nozzles along its length, and a second or auxiliary injection pipe positioned in the proximity of the main injection pipe to inject a scrubbing liquid over the outer peripheral walls of the main injection pipe to prevent deposition of coke. The main and auxiliary injection pipes are both supplied with heavy petroleum oil to remove the coke deposition from the reactor wall by the heavy petroleum oil jets from the main injection pipe while wetting the exterior of the main pipe with the heavy petroleum oil injected by the auxiliary injection pipe.

Abstract: A decoking device suitable for use on a reaction vessel for the thermal cracking of heavy petroleum oils, including an assembly mounted on top of the reaction vessel and having a cylinder and a piston slidably and rotatably received in the cylinder, the cylinder and piston defining a scrubbing liquid chamber which is sealed from the outside. A scrubbing liquid is fed through the scrubbing liquid chamber to a main injection pipe to inject the liquid through a multitude of jet nozzles in the main injection pipe against the inner wall surfaces of the reaction vessel, the main injection pipe being connected to the piston for movement therewith.

Abstract: The undesirable and damaging reaction heat occurring during the blowing of asphalt is avoided by injecting water into the air inlet pipes of the reactor vessel heated by the hot asphalt surrounding them. During this, the superheated steam produced without expenditure is passed through the liquid asphalt, causing the removal of low molecular hydrocarbons formed during the blowing or stripping.

Abstract: In a deodorizing apparatus, at least the lower part of a column is surrounded at least partly by compartments which are not connected together, each compartment having means for supplying treatment fluid and means for discharging the treated material with separate control but opening into a common duct. The duct for discharging the treated material from the central column is divided into separate ducts the outlets of which open into the compartments and which are provided with separately-controlled means for carrying the material to the respective compartments.