With Physical Separation Of Solid By-product From Removed Admixture Patents (Class 201/3)
  • Patent number: 11826729
    Abstract: Disclosed are a photocatalyst and application thereof in environmentally friendly photocatalytic treatment of a power battery. The photocatalyst is obtained by loading Ag—TaON on a hollow glass microsphere, wherein a mass ratio of the Ag—TaON to the hollow glass microsphere is 1:5 to 10. According to the invention, the Ag—TaON and the hollow glass microsphere are compounded, the hollow glass microsphere has better light permeability, which avoids mutual shielding between catalysts, such that the photocatalyst filled in a reactor is fully excited, which is capable of effectively improving a light utilization rate, thus improving the catalytic conversion efficiency of the photocatalyst.
    Type: Grant
    Filed: April 30, 2021
    Date of Patent: November 28, 2023
    Assignees: Guangdong Brunp Recycling Technology Co., Ltd., Hunan Brunp Recycling Technology Co., Ltd., Hunan Brunp EV Recycling Co., Ltc.
    Inventors: Haijun Yu, Ting Peng, Yinghao Xie, Xuemei Zhang
  • Patent number: 11697771
    Abstract: A system for producing biomass vinegar and charcoal includes a furnace, which has an outer shell defining a lower combustion chamber and an upper heating chamber, and an inner tank removably received in the heating chamber. A cooling pond has a cooling region to accommodate the inner tank. A condenser in a collection barrel condenses smoke gases from the inner tank to produce biomass vinegar. A first temperature sensing pipeline removably connects the inner tank, After the biomass is carbonized, the first temperature sensing pipeline is removed from the inner tank, and the inner tank is moved to the cooling region to be cooled by a sprinkler.
    Type: Grant
    Filed: January 10, 2022
    Date of Patent: July 11, 2023
    Assignee: NATIONAL CHUNG CHENG UNIVERSITY
    Inventors: Shi-Ming Huang, Chih-Yuan Kuo
  • Patent number: 11236904
    Abstract: Provided are: a useful bed medium for a fluidized bed with good fluidity, the bed medium being usable in a fluidized bed furnace using biomass material and coal material as fuel; and a useful bed medium for a fluidized bed with good durability, the bed medium not easily forming an agglomerate of its particles, and being resistant to collapsing. The bed medium for a fluidized bed in a fluidized bed furnace for combusting or gasifying the fuel is formed of artificially-produced spherical refractory particles containing not less than 40% by weight of Al2O3 and not more than 60% by weight of SiO2 and having an apparent porosity of not more than 5%, and a ratio by weight of agglomerated particles in the bed medium is not more than 20% after three heat treatment tests on the bed medium at 900° C. for 2 hours under coexistence with the fuel.
    Type: Grant
    Filed: March 19, 2020
    Date of Patent: February 1, 2022
    Assignee: Itochu Ceratech Corporation
    Inventors: Hiroshi Makino, Jun Sakamoto, Takayuki Kameda, Reiku Aoyama, Shunichi Sato, Yoji Okumura
  • Patent number: 10934490
    Abstract: Disclosed is a process and plant for producing biocoal in which biogenous starting material located in retorts is pyrolyzed and the flammable pyrolysis gases formed by the pyrolyses are burned to generate hot flue gases. The retorts are introduced consecutively into at least one reactor chamber and by use of the flue gases the pyrolyses are performed therein. The retorts are at least largely closed toward entry of hot flue gases and the heating of the starting materials located in the retorts by the flue gasses is effected only indirectly via the heating of the retorts.
    Type: Grant
    Filed: September 20, 2017
    Date of Patent: March 2, 2021
    Inventors: Leo Schirnhofer, Holger Knautz
  • Patent number: 10240091
    Abstract: Provided herein is a method for devolatizing a solid feedstock. The solid feedstock is treated to a produce a particle size laying between 1 cm3 and 100 cm3. The solid feedstock is passed into a device connected to an outlet of a compaction screw auger comprising an assembly including a solid feedstock injector, a retort, a side arm for injecting a heated gas comprising hydrogen, and a process auger. The solid feedstock is contacted with the heated gas at a temperature of 500° C. to 1000° C. for a time of 60 seconds to 120 seconds, whereby the solid feedstock is converted into a gas stream and a solid stream.
    Type: Grant
    Filed: February 9, 2017
    Date of Patent: March 26, 2019
    Assignee: D4 Energy Group, Inc.
    Inventors: David Earle Hayward, Marvin Ronnie Baker
  • Patent number: 9914897
    Abstract: Provided herein are methods of optimizing energy recovery from oilseeds. The methods disclosed provide at least the ability to swell oilseeds and disrupt the cell walls (hulls) without changing the functionality and quality of oil; the process integration of removing the impurities from oilseeds, oil extraction, protein hydrolysis, and green coal production to maximize the energy recovery in the form of crude oil, polypeptides, oligopeptides, amino acids, and/or green coal from oilseeds; and heat integration during processing stages including subcritical water pretreatment, oil extraction, subcritical water post-treatment, and subcritical water carbonization to minimize the process heat requirement.
    Type: Grant
    Filed: May 15, 2017
    Date of Patent: March 13, 2018
    Assignee: Tyton Biosciences, LLC
    Inventors: Sandeep Kumar, Peter J. Majeranowski
  • Patent number: 9328312
    Abstract: Provided herein are methods of optimizing energy recovery from oilseeds. The methods disclosed provide at least the ability to swell oilseeds and disrupt the cell walls (hulls) without changing the functionality and quality of oil; the process integration of oil extraction and green coal production to maximize the energy recovery in the form of crude oil and green coal from oilseeds; and heat integration during processing stages including subcritical water pretreatment, oil extraction, and subcritical water carbonization to minimize the process heat requirement.
    Type: Grant
    Filed: October 15, 2013
    Date of Patent: May 3, 2016
    Assignee: Tyton Biosciences, LLC
    Inventors: Sandeep Kumar, Sergiy Popov, Peter J. Majeranowski, Igor Kostenyuk
  • Publication number: 20150083570
    Abstract: The present disclosure provides methods and systems for coal liquefaction and obtaining a high quality coke from a low rank coal extract. A method of obtaining a high quality coke from a low rank coal extract may include exposing coal to a hydrogenated vegetable oil in the presence of a coal-derived solvent to form a slurry, elevating the temperature of the slurry to facilitate liquefying the coal and liberating a volatile matter, separating the insoluble components from the slurry to obtain a de-ashed coal extract that is quinoline insoluble-free, distilling the coal extract under vacuum to obtain a pitch with a suitable softening point, and coking the pitch to obtain a coke. The coke may be at least one of an anisotropic coke, a metallurgical coke, a graphite coke, an anode coke, and a needle coke.
    Type: Application
    Filed: October 14, 2014
    Publication date: March 26, 2015
    Inventors: Alfred H. Stiller, Peter G. Stansberry
  • Patent number: 8986507
    Abstract: Methods, devices and systems for continuously converting biomass are described herein. A device has a feed section for holding a moving bed of biomass, namely wood, having a drying section, a flame zone for degassing, and a, smolder zone for carbonizing the biomass into a solid converted product, namely charcoal. The device includes a tank for collecting the solid converted product arranged below a grate and coupled with the feed section in a gas-tight manner. The system comprising the device, a biogas plant and/or a combined heat and power plant conveys the liquid converted product, namely pyroligneous acid or acetic acid, to the biogas plant and/or the solid converted product, namely charcoal, to the combined heat and power plant.
    Type: Grant
    Filed: March 10, 2010
    Date of Patent: March 24, 2015
    Assignee: European Charcoal AG
    Inventor: Bernd Schottdorf
  • Publication number: 20150014142
    Abstract: A method for processing wastewater is provided. The method includes pretreating a flow of the wastewater using at least one of a softening/clarification system, a sludge handling system, a filtration system, and an ammonia stripping system, evaporating the pretreated flow to produce at least a distillate and an evaporator brine; separating the evaporator brine to produce a liquid recycle stream and salt crystal mixture; and channeling the liquid recycle stream to a feed stream. The method eliminates the salt drying process that significantly reduces the costs of construction and operation of the standard zero process water discharge process.
    Type: Application
    Filed: September 19, 2014
    Publication date: January 15, 2015
    Inventors: Dinh-Cuong Vuong, James Scott Kain
  • Patent number: 8877995
    Abstract: Pyrolysis fuels and methods for processing pyrolysis fuel are provided. In one embodiment, a method of processing pyrolysis fuel converts biomass to pyrolysis fuel including pyrolysis oil and char particles. Also, the method includes resizing a portion of the char particles so that substantially all resized char particles have a largest dimension no greater than about 5 microns.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: November 4, 2014
    Assignee: UOP LLC
    Inventors: Lance Awender Baird, Stanley Joseph Frey
  • Patent number: 8859831
    Abstract: A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H2, CH4, CO, CO2, ammonia and hydrogen sulfide.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: October 14, 2014
    Assignee: Gas Technology Institute
    Inventors: Terry L. Marker, Larry G. Felix, Martin B. Linck, Michael J. Roberts
  • Patent number: 8835704
    Abstract: A biomass pyrolysis process is provided in which biomass feedstock is mixed with a heat carrier. The heat carrier at least partly comprises char. The ratio by weight of biomass to char is in the range 1:1 to 1:20. The process may be carried out by in a screw/auger pyrolysis reactor in which the solid feedstock components are conveyed along the reactor by a first screw. A second screw conveys at least a portion of the solid products of the biomass pyrolysis back to a heat transfer medium input port. Thus, the heat transfer medium includes char from the biomass pyrolysis.
    Type: Grant
    Filed: May 14, 2009
    Date of Patent: September 16, 2014
    Assignee: Aston University
    Inventors: Andreas Hornung, Andreas Apfelbacher
  • Patent number: 8828191
    Abstract: A method and apparatus for pyrolytic destruction of polymer products including whole vehicle vulcanised rubber tires is disclosed. The apparatus 111 has a reaction chamber 153 into which a tire can be placed, and immersed for pyrolytic decomposition in a molten alloy of zinc with a minor proportion of aluminium. The apparatus 111 has a heated reservoir 155 in which the alloy is maintained in a molten state, and from where it can be transferred to the reaction chamber 153 to immerse the tire. Fluid hydrocarbon byproducts are drawn off for condensation and recovery, and solid zinc sulphides are also recovered. Where steel belted tires are processed, carbon and steel residues are also recovered.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: September 9, 2014
    Inventor: Michael John Shaw
  • Publication number: 20140224636
    Abstract: A coal separation unit for a gasification system includes a vessel having a top portion and a bottom portion, a first inlet configured to receive a feed stream including at least coal and ash from a grinding unit, a second inlet configured to receive a wash fluid stream, a first outlet configured to convey a low-ash feed stream, and a second outlet configured to convey an ash-rich stream. In operation, the feed stream is washed with the wash fluid stream in the separation unit to separate at least a portion of the ash from the coal. The separated ash settles to the bottom portion of the vessel and is conveyed via the second outlet as the ash-rich stream. The separated coal floats to the top portion of the vessel and is conveyed via the first outlet to a gasification unit as the low-ash feed stream.
    Type: Application
    Filed: February 11, 2013
    Publication date: August 14, 2014
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Vijayalakshmi Shah, Sudharsanam Krishnamachari, Annavarapu Vijay Bharat Sastri
  • Patent number: 8795475
    Abstract: There is described a system and method for recycling carbon-containing material, in particular tires and plastics materials. The system includes a heating arrangement for anaerobically heating carbon containing material to produce carbon-containing gases. A condensing arrangement is also used to condense a proportion of the carbon-containing gases to provide condensed gases and non-condensed gases. In addition, a recirculating arrangement is provided for recirculating the non-condensed gases into the heating arrangement. Further systems and methods for pre- and post-processing of the carbon-containing material are also disclosed and products of the systems and methods are also described.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: August 5, 2014
    Assignee: Used Tyre Distillation Research Limited
    Inventors: Richard Hutchins, Michael Walker, Paul Archer
  • Publication number: 20140076707
    Abstract: A closed system for gaining sellable petroleum coke pieces out of solidified petroleum coke in a coke drum unit, comprises a coke drum unit containing solidified petroleum coke; a coke crushing unit for crushing petroleum coke into sellable petroleum coke pieces; a closed slurry pipe leading petroleum coke slurry to a closed slurry pit; a dewatering bin unit for receiving petroleum coke slurry from the slurry pit, for collecting the sellable petroleum coke pieces and for leading filtered water and petroleum coke fines out of it; a closed drain water pit, separate from the slurry pit, for receiving the filtered water and the petroleum coke fines from the dewatering bin unit; a water settling tank receiving the filtered water and the petroleum coke from the drain water pit and for separating the petroleum coke fines from the water such that the petroleum coke fines collect in the bottom part of the water settling tank, and for leading the petroleum coke fines into the slurry pit where they mix with the petroleu
    Type: Application
    Filed: July 14, 2011
    Publication date: March 20, 2014
    Inventor: Ralf Gast
  • Publication number: 20130206571
    Abstract: The present invention concerns low energy requiring methods for processing low cellulosic biomass materials into oil, char and liquid components. One method comprises the steps of subjecting the biomass to hydrothermal carbonization under specified reaction conditions for producing a combined char and oil fraction as well as an aqueous fraction, separating the combined oil and char fraction from the aqueous fraction by filtration; separating the combined oil and char fraction into individual oil and char fractions using an organic solvent for forming an oil depleted char fraction and a liquid oil and solvent solution, and separating the liquid oil and solvent solution into individual oil and solvent fractions by distillation.
    Type: Application
    Filed: May 12, 2011
    Publication date: August 15, 2013
    Inventors: Steven M. Heilmann, Kenneth J. Valentas, Marc Von Keitz, Frederick J. Schendel, Paul A. Lefebvre, Michael J. Sadowsky, Laurie A. Harned, Lindsey R. Jader
  • Patent number: 8404909
    Abstract: A method of biomass pyrolysis is described which includes chemical looping of combustion char so that carbon dioxide can be captured from the combustion of the char as well as producing useable compounds from pyrolyzing biomass in a pyrolysis reactor including a metal oxide carrier particles which is in operative cooperation with a char combustor and oxidation reactor and separator for separating carbon dioxide from the flue gas produced by the char combustor.
    Type: Grant
    Filed: December 9, 2009
    Date of Patent: March 26, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Raja A Jadhav
  • Patent number: 8323456
    Abstract: A process and system for removing bound water from bio-oil by azeotropic distillation. The process includes combining a bound-water-containing bio-oil with an azeotrope agent and subjecting the resulting treated bio-oil to azeotropic distillation under reduced pressure. The azeotropic distillation removes a substantial portion of the bound water from the bio-oil, thus producing a water-depleted bio-oil that is less corrosive, more stable, and more readily miscible with hydrocarbons.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: December 4, 2012
    Assignee: KiOR, Inc.
    Inventors: Ronny W. Lin, Robert Bartek
  • Patent number: 8308912
    Abstract: A method for pyrogasification of organic wastes that employs a vertical furnace filled with metal masses in the shape of metal toroids (2) previously raised to a high temperature (500 to 1100° C.) and organic materials to be pyrolyzed. It also employs a furnace for heating toroids transported by an Archimedes screw driven by a gear motor, as well as a separator for recovering the mineral residues, whereby separation between the toroids and residues is effected with the aid of a screen and an Archimedes screw driven by a gear motor.
    Type: Grant
    Filed: May 25, 2010
    Date of Patent: November 13, 2012
    Inventors: Francois Hustache, Alain Chantelat
  • Patent number: 8226798
    Abstract: A method of forming a pyrolysed biocarbon from a pyrolyzable organic material is delineated. The method involves the conversion of pyrolyzable organic materials to biocarbon for subsequent use. A carbonization circuit is employed with individual feedstock segments being advanced through the circuit. The method facilitates user manipulation of rate of advancement of the feedstock through the circuit, selective collation of volatiles from pyrolyzing feedstock, selective exposure of predetermined feedstock segments to collated volatiles as well as thermal recovery and redistribution as desired by the user. This results in the capacity for a customizable biocarbon product, the latter being an auxiliary feature of the methodology.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: July 24, 2012
    Assignee: Alterna Energy Inc.
    Inventors: Hendrik van Aardt, Phil Marsh, Hugh McLaughlin
  • Publication number: 20120103780
    Abstract: The present invention relates to a carbonization process of rubber products such as shredded waste tyre and the like in a sealed carbonizing vessel (200) whose operating pressure is below atmospheric pressure and under controlled high temperature environment while continuously being moved in a defined path at a controlled speed thus enabling shredded tyre to be fed constantly into the vessel (200) while the by-products of the carbonization process are continually discharged.
    Type: Application
    Filed: July 15, 2010
    Publication date: May 3, 2012
    Applicant: ADVANCED PYROTECH SDN. BHD.
    Inventors: Mazlan Ali, Siti Fatimah Mohd Shariff, Christopher John Webb
  • Publication number: 20120097517
    Abstract: A method for pyrogasification of organic wastes that employs a vertical furnace filled with metal masses in the shape of metal toroids previously raised to a high temperature (500 to 1100° C.) and organic materials to be pyrolyzed. It also employs a furnace for heating toroids transported by an Archimedes screw driven by a gear motor, as well as a separator for recovering the mineral residues, whereby separation between the toroids and residues is effected with the aid of a screen and an Archimedes screw driven by a gear motor.
    Type: Application
    Filed: May 25, 2010
    Publication date: April 26, 2012
    Inventors: Francois Hustache, Alain Chantelat
  • Publication number: 20120012451
    Abstract: A green process and system are disclosed for utilizing a biomass filter aid in the filtration of a bio-oil. The process comprises filtering a bio-oil containing residual solids from a conversion reaction in the presence of the biomass filter aid to produce a filtered bio-oil. The biomass filter aid facilitates efficient removal of residual solids from the bio-oil. The spent biomass filter aid containing the residual solids may be recycled as a conversion feedstock or used as a combustion heat source in the biomass conversion system.
    Type: Application
    Filed: July 13, 2010
    Publication date: January 19, 2012
    Applicant: KIOR, INC.
    Inventor: Ronny W. Lin
  • Publication number: 20110301326
    Abstract: A system, method and configuration for recovering turpentine during the manufacturing of wood chips, wood pellets or other substances that may include turpentine. In general, a turpentine recovery system is used to capture turpentine from exhaust of a dryer as wood chips are being dried. Advantageously, application of the various techniques disclosed herein can result in the recovery of turpentine that can then be sold to generate revenue and, may contribute to a reduction in the capital and operation costs for emission controls for the dryer exhaust.
    Type: Application
    Filed: June 1, 2011
    Publication date: December 8, 2011
    Inventor: Robert J. Foxen
  • Publication number: 20110186415
    Abstract: The invention is an apparatus and method for recovery of energy and by-products from automobile and truck tires. The tires are heated in an oxygen poor environment, and the off gases are condensed to recover a liquid oil product and compressible natural gas. The tires are reduces to ash and steel, both of which can be feed streams for other processes. The apparatus includes a condenser with cooled plates, and oil recovery structures.
    Type: Application
    Filed: April 11, 2011
    Publication date: August 4, 2011
    Inventor: David Brent Thompson
  • Publication number: 20110120851
    Abstract: The claimed invention relates to an apparatus and method for restoring plastic, to oil, thereby efficiently recycling waste plastic. The apparatus comprises a decomposer, an oil reduction body, a cooling tank, and a filter and emission part. The decomposer comprises a decomposition space comprising an opening to receive the plastic, a heating coil inside the decomposer to heat the decomposition space to pyrolyze the plastic, and a pyrolyzing gas exhaust pipe in an upper part of the decomposer connected to the decomposition space to exhaust pyrolyzing gas produced in pyrolyzing the plastic. The oil reduction body positioned in one side of the decomposer is divided into a cooling space and a oil catchment space by a partition. The cooling space is connected to the pyrolyzing gas exhaust pipe to receive the pyrolyzing gas from the decomposition space.
    Type: Application
    Filed: March 25, 2010
    Publication date: May 26, 2011
    Inventor: Ki Jeong JEON
  • Patent number: 7935226
    Abstract: A method to remove coke from a coker drum is disclosed. The method includes the steps of impinging fluid from a fluid jet on the inside surface of the coker and then determining the vibration signal of the coker drum. The signal is then transformed to determine the amplitude versus frequency by a Fourier Transform of the vibration signal. The amplitude change of the vibration signal as it goes through a maximum, determines when the coke layer has been cut. The fluid jet is lowered into a new layer of coke.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: May 3, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Limin Song, Mark M. Disko, Jormarie Alvarez, Julio D. Lobo, Robert J. Chimenti
  • Patent number: 7935227
    Abstract: A method for collecting biomass, such as straw, and for producing a pyrolysis liquid, such as oil or tar, from the biomass, includes the step of collecting the biomass from a growth site, e.g. a field, by means of a mobile unit. The biomass is continuously fed into a pyrolysis apparatus accommodated by the mobile unit, as the mobile unit is moved across the growth site. While the biomass is processed in the pyrolysis apparatus, further biomass is simultaneously being collected. The pyrolysis apparatus may be a flash pyrolysis or fast pyrolysis apparatus relying on centrifugal forces for forcing biomass towards a reactive surface in a pyrolysis reactor. The mobile unit may be self-propelled.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: May 3, 2011
    Assignee: Danmarks Tekniske Universitet
    Inventors: Kim Dam-Johansen, Niels Bech
  • Patent number: 7931783
    Abstract: A fast pyrolysis apparatus (200) for producing pyrolysis liquid, such as oil or tar, char and pyrolysis gas from biomass, such as straw, comprises a centrifuge chamber (204) and a rotor (210) arranged to impart rotation on the biomass in the centrifuge chamber to force the biomass outwardly under the action of centrifugal forces. A furnace (206) arranged coaxially around the centrifuge chamber (204) maintains the temperature at an outer reactive wall of the centrifuge chamber at an elevated temperature to effect the pyrolysis process at or near the reactive wall. The apparatus comprises a condenser (218) arranged coaxially with and surrounded by the centrifuge chamber (204). The apparatus may be accommodated by a mobile unit for simultaneously collecting biomass from a field and processing the biomass in the apparatus.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: April 26, 2011
    Assignee: Danmarks Tekniske Universitet
    Inventors: Kim Dam-Johansen, Niels Bech, Peter A. Jensen
  • Patent number: 7922870
    Abstract: A method and apparatus for waste tyres pyrolysis wherein whole tyres are directly heated in a tunnel type furnace with flue gases from the combustion of pyrolysis gases. The process produces thermal energy, carbon black and mineral oil. The cooled flue gases are purified from sulfur oxides before released into the atmosphere.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: April 12, 2011
    Inventors: Dimitar Nikolaev Kolev, Radka Borisova Ljutzkanova, Stefan Todorov Abadjiev
  • Patent number: 7918973
    Abstract: A process for treating solid organic materials, especially for recycling treated wood, uses energy provided by hot gases at the bottom of a reactor column to perform a distillation operation which ensures splitting of organic bonds in the material and uses, as the distillation operation progresses, constant control between a first temperature of the hot gases before they are introduced into the lower part of the reactor column and a second temperature of a layer of the material located in an area immediately above the grid of the reactor column. When the first temperature and the second temperature are identical or virtually identical, corresponding to removal of all the organic bonds of the material by evaporation and transport by the hot gases from the bottom to the top of the column, the layer of material at the second temperature is removed in order to collect a material that largely consists of carbon and constitutes a secondary raw material.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: April 5, 2011
    Assignee: Thermya
    Inventor: Jean-Sebastien Hery
  • Publication number: 20110048916
    Abstract: The invention described herein generally pertains to utilization of high power density microwave energy to reduce organic compounds to carbon and their constituents, primarily in a gaseous state. The process includes, but is not limited to, scrap tires, plastics, asphalt roofing shingles, computer waste, medical waste, municipal solid waste, construction waste, shale oil, and PCB/PAH/HCB-laden materials. The process includes the steps of feeding organic material into a microwave applicator and exposing the material to microwave energy fed from at least two linear polarized sources in non-parallel alignment to each other, and collecting the material. The at least two sources of microwave energy are from a bifurcated waveguide assembly, whose outputs are perpendicular to each other and fed through waveguide of proper impedance, such that the microwave sources are physically and electrically 90° out of phase to each other. The microwave frequency is between 894 and 1000 MHz, preferably approximately 915 MHz.
    Type: Application
    Filed: March 25, 2010
    Publication date: March 3, 2011
    Inventor: John F. Novak
  • Publication number: 20110041388
    Abstract: The invention relates to a method for carrying out pyrolysis in such manner that a first raw material is fed to a combustion boiler and a second raw material is fed to a pyrolysis reactor which are integrated together, energy fractions are formed from the raw material in the combustion boiler and gaseous and liquid product fractions are formed from the raw material in the pyrolysis reactor by fast pyrolysis.
    Type: Application
    Filed: October 8, 2008
    Publication date: February 24, 2011
    Applicant: Valtion Teknillinen Tutkimuskeskus
    Inventors: Kai Sipilä, Yrjö Solantausta, Pekka Jokela, Markku Raiko
  • Publication number: 20110011719
    Abstract: A process for treating bituminous coal includes providing dried, pulverized coal, and treating the pulverized coal in a vessel with a gas stream having an oxygen content sufficient to form oxides on surface of coal particles. The treated coal is transferred into a pyrolyzing chamber and passed into contact with an oxygen deficient sweep gas, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to the coal indirectly by heating the chamber, wherein the heating of coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. Some of the oxides are converted into paramagnetic mineral components, which are removed from coal to form a coal char having reduced ash and sulfur.
    Type: Application
    Filed: September 10, 2009
    Publication date: January 20, 2011
    Inventor: Franklin G. Rinker
  • Publication number: 20100314235
    Abstract: Heat from a concentrated solar power source is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The solar heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle or by methane steam cracking. The heat from the solar source may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of solar thermal energy sources, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat.
    Type: Application
    Filed: May 4, 2010
    Publication date: December 16, 2010
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Ramesh VARADARAJ, Michael SISKIN, Walter WEISSMAN, Mark A. GREANEY
  • Patent number: 7815775
    Abstract: A method for coke removal in delayed coker drums is provided. The method comprises the steps of draining from the drum of substantially free-flowing coke, performing a vibration signature analysis on the drum to identify whether and where any coke remains attached to the interior wall of the drum after the draining step, and cutting the coke from the areas identified by the signature analysis step.
    Type: Grant
    Filed: August 27, 2007
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Glen E. Phillips, Charles John Mart
  • Publication number: 20100133085
    Abstract: There is described a system and method for recycling carbon-containing material, in particular tyres and plastics materials. The system includes a heating arrangement for anaerobically heating carbon containing material to produce carbon-containing gases. A condensing arrangement is also used to condense a proportion of the carbon-containing gases to provide condensed gases and non-condensed gases. In addition, a recirculating arrangement is provided for recirculating the non-condensed gases into the heating arrangement. Further systems and methods for pre- and post-processing of the carbon-containing material are also disclosed and products of the systems and methods are also described.
    Type: Application
    Filed: December 19, 2007
    Publication date: June 3, 2010
    Inventors: Richard Hutchins, Michael Walker, Paul Archer
  • Patent number: 7642394
    Abstract: Systems and methods for recycling waste and reclaiming beneficial and useful compositions such as organic solvents comprises a shredder, operating in an inerted or anaerobic atmosphere, which shreds the waste into smaller pieces that are fed into and indirectly heated in an anaerobic desorption unit so as to vaporize at least one organic compound associated with the waste. A vacuum means is used to transfer the organic compound vapors from the desorption unit to a water quench condensing unit that operates to produce a mixed organic compound liquid stream. The liquid organic compound and water stream is then processed in an oil and water separator. The water is separated and can be reused in the system for quenching gas vapors or inerting the desorption unit. The water-free mixed organic compound liquid stream is then fed into a multi-stage packed distillation column separating organic compound according to boiling points to produce products such as organic solvents.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: January 5, 2010
    Assignee: Pollution Control Industries, Inc.
    Inventors: Kenneth E. Carle, Kevin P. Prunsky
  • Patent number: 7632381
    Abstract: The present invention relates to a safety system during the entire delayed coker operation. The present invention preferably comprises a coke drum; a first coke drum de-header system coupled to the bottom of the coke drum; a second coke drum de-header system coupled to the top of the coke drum; a containment system coupled to the second coke drum de-header system; and a remote switching system. Hence, the present invention provides system for cutting coke within a coke drum with increased safety, efficiency and convenience.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: December 15, 2009
    Assignee: Curtiss-Wright Flow Control Corporation
    Inventor: Ruben F. Lah
  • Patent number: 7534326
    Abstract: Clamping system and method for clamping the bottom head cover of a coke drum to the bottom flange thereof are disclosed. The system and method include determining the flange stiffness or resistance to deflection resulting from the spring-like force exerted on the bottom head cover and bottom flange gasket seating surface by the gasket in its compressed state. This deflection information may then be used to estimate the minimum number of clamps needed to ensure sufficient load remains on the gasket at the midpoints between the clamps to effectively keep the gasket sealed. An appropriate number of clamps may then be disposed around the periphery of the bottom flange to clamp it to the bottom head cover. In one practical design, each clamp engages a lug attached to the periphery of the bottom head cover such that the clamp does not extend underneath the bottom head cover when clamped.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: May 19, 2009
    Assignee: ConocoPhillipcs Company
    Inventors: Brian J. Doerksen, Vance C. Green, Jinyang James Lu, Charles Schroeder, Meir Snir, Mohamad T. Ali
  • Patent number: 7481908
    Abstract: The present invention relates to a system and a process for obtaining phenanthrene of about 95% purity from coal tar distilled fraction containing crude phenanthrene by performing fractional distillation at a reduced pressure of 50 mm mercury and at a temperature range of 160-180° C. to obtain first distilled fraction containing acenaphthene and fluorene; a second distillate fraction at a temperature range of 200-230° C. containing phenanthrene, anthracene and traces of carbazole; followed by re-distilling the second distillate fraction at a temperature range of 210-224° C. to finally obtain pure phenanthrene and a residue which is again used for the recovery of residual phenanthrene by re-distillation at a temperature range of 210-224° C.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: January 27, 2009
    Assignee: Council of Scientific & Industrial Research
    Inventors: Kaushal Kishore Tiwari, Sukuru Ramakrishna Rao, Sanjay Kumar Thakur, Somnath Banerji
  • Patent number: 7459063
    Abstract: A coke drum bottom de-heading system having an internal shroud enclosure and a shroud end cap opened by a flange to a coke bottom de-heading valve capable of accepting the end of a gate valve upon actuation. Acting in coordination with the shroud enclosure to prevent the escape of steam is a gate seal assembly having a gate seal slidably engaged against the sliding gate to prevent the passage of steam thereby.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: December 2, 2008
    Assignee: Curtiss-Wright Flow Control Corporation
    Inventors: Ruben F. Lah, Gary Larsen
  • Patent number: 7399384
    Abstract: A coke drum bottom de-heading system having an internal shroud enclosure and a shroud end cap opened by a flange to a coke bottom de-heading valve capable of accepting the end of a gate valve upon actuation. Acting in coordination with the shroud enclosure to prevent the escape of steam is a gate seal assembly having a gate seal slidably engaged against the sliding gate to prevent the passage of steam thereby.
    Type: Grant
    Filed: February 13, 2006
    Date of Patent: July 15, 2008
    Assignee: Curtiss-Wright Flow Control Corporation
    Inventors: Ruben F. Lah, Gary Larsen
  • Patent number: 7264694
    Abstract: A retort heating apparatus for processing a feed material includes a heating chamber bounded at least in part by a side wall. A plurality of baffles are at least partially disposed within the heating chamber. Each baffle includes an elongated body having a top surface, at least a portion of the top surface being arched. The plurality of baffles are vertically and horizontally spaced apart so that substantially all of the feed material that vertically passes through the heating chamber is horizontally displaced as the feed material passes by the baffles. Systems are also provided for heating the feed material within the heating chamber.
    Type: Grant
    Filed: January 29, 2004
    Date of Patent: September 4, 2007
    Assignee: Oil-Tech, Inc.
    Inventors: Byron G. Merrell, Michael R. Keller, Roger K. Noble
  • Patent number: 6953517
    Abstract: In order to make it possible for an inhomogeneous residue generated in a pyrolysis plant to be separated continuously and in as fully graded a way as possible, specially selected components are combined with one anther in an advantageous configuration. An essential element of the plant is the separation of a coarse residue in a coarse screen and the subsequent separation of the remaining residue in a zigzag separator into a light residue and a heavy residue. By use of the plant, in particular, the carbon-containing constituents are separated from the remaining residue. The individual components are mostly configured to be self-cleaning for fault-free operation.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: October 11, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventors: Joachim Boretzky, Anton Ebert, Leonhard Teschers, Winfried Von Rhein, Helmut Werdinig
  • Patent number: 6736940
    Abstract: Tire pyrolysis systems and processes are provided which include feeding tire shreds to a pyrolysis reactor, pyrolyzing the shreds in a pyrolysis reactor to produce a hydrocarbon-containing gas stream and carbon-containing solid, removing the carbon-containing solid from the reactor, directing the hydrocarbon-containing gas stream into a separator, contacting the hydrocarbon-containing gas stream with an oil spray in the separator thereby washing particulate from the hydrocarbon-containing gas stream and condensing a portion of the gas stream to oil, removing and cooling the oil from the separator, directing non-condensed gas from the gas stream away from the separator, and directing a portion of the cooled oil removed from the separator to an inlet of the separator for use as the separator oil spray.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: May 18, 2004
    Assignee: Renaissance Recycling, Inc.
    Inventors: Blaine Masemore, Robert Zarrizski
  • Publication number: 20040079628
    Abstract: Closed apparatus and processes by which carbon feedstock, is composed of a mixture of non-coking coal fines and another carbonaceous material, such as waste coke fines are disclosed. The coal and coke fines are mixed together and may be formed into solid pieces. The mixture alone or as solid pieces is fired through pyrolyzation into solid pieces of coke, with solid and gaseous by-products of pyrolyzation being recycled for use within the coke-producing closed system, thereby reducing or eliminating release of undesirable substances to the environment. A char-forming binder may or may not be added to the carbon mixture prior to pyrolyzation.
    Type: Application
    Filed: October 22, 2003
    Publication date: April 29, 2004
    Inventors: Craig N. Eatough, Jon S. Heaton, Steven R. Eatough
  • Publication number: 20030183499
    Abstract: The present invention relates to a system and a process for obtaining phenanthrene of about 95% purity from coal tar distilled fraction containing crude phenanthrene by performing fractional distillation at a reduced pressure of 50 mm mercury and at a temperature range of 160-180° C. to obtain first distilled fraction containing acenaphthene and fluorene; a second distillate fraction at a temperature range of 200-230° C. containing phenanthrene, anthracene and traces of carbazole; followed by re-distilling the second distillate fraction at a temperature range of 210-224° C. to finally obtain pure phenanthrene and a residue which is again used for the recovery of residual phenanthrene by re-distillation at a temperature range of 210-224° C.
    Type: Application
    Filed: March 26, 2002
    Publication date: October 2, 2003
    Inventors: Kaushal Kishore Tiwari, Sukuru Ramakrishna Rao, Sanjay Kumar Thakur, Somnath Banerji