In A Moving Bed Patents (Class 201/32)
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Patent number: 11148322Abstract: A material distribution apparatus and preparing an artificial stone plate using the material distribution apparatus includes a belt material distribution device including a material distribution hopper and a conveying belt. The conveying belt is located at a lower portion of the material distribution hopper. An upper surface of the conveying belt is inclined. The material distribution hopper has a first wall and a second wall. The first wall is an inclined wall with an upper end away from the second wall. A discharge outlet is provided below the second wall. An upper portion of the second wall is vertically mounted, and a lower portion of the second wall has a circular arc portion and a discharge portion which forms the discharge outlet with a surface of the conveying belt therebetween.Type: GrantFiled: March 25, 2016Date of Patent: October 19, 2021Assignee: Veegoo Technology Co., Ltd.Inventor: Feizhou Deng
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Patent number: 11008519Abstract: A method of retorting oil shale is provided, comprising: continuously feeding oil shale into a retorting unit; heating the retorting unit using renewable electrical energy; converting the oil-shale kerogen into kerogen oil; conveying a cross-flow sweep gas across a moving bed of the oil shale, to carry the kerogen oil out of the retorting unit; recovering the kerogen oil; and recovering spent oil shale. The combination of electrical heating and cross-flow retorting achieves uniform heating to optimize the production of hydrocarbons. A system for retorting oil shale is also provided, comprising: a retorting unit; an inlet for continuously feeding oil shale; electrical-energy elements within the retorting unit; an inlet for conveying a cross-flow sweep gas through the retorting unit; and an outlet for the cross-flow sweep gas carrying the kerogen oil. The principles of the invention may be applied to ex situ systems, in situ systems, or hybrid systems.Type: GrantFiled: August 18, 2020Date of Patent: May 18, 2021Assignee: Kerogen Systems, IncorporatedInventors: Otto John Schneider, Paul S. Owen
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Patent number: 10519380Abstract: This invention provides a process for producing a crude oil composition from oil sand using a solvent comprised of a hydrocarbon mixture to extract or remove only a portion of the bitumen on the oil sand. The solvent type and the manner by which the extraction process is carried out has substantial impact on the quality of the extracted oil component. The solvent is designed so that it has the desired Hansen solubility parameters that enable the partial extraction of the desired oil composition. The solvent is further designed so that it can be comprised of multiple hydrocarbons having the appropriate boiling point ranges that enable the solvent to be easily recovered and recycle, without the need to externally provide for solvent make-up.Type: GrantFiled: October 13, 2011Date of Patent: December 31, 2019Assignee: EPIC OIL EXTRACTORS, LLCInventors: Edward L. Diefenthal, Richard D. Jordan, Richard H. Schlosberg
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Patent number: 10364393Abstract: The invention relates to an apparatus and method for the production of densified charcoal from organic material that can be used for example as chemical reagents, fuels, or absorbents. The reaction vessel defines a flow path extending from the input to the vessel, through to the output from the vessel, in which the thermal decomposition of the organic material progresses as the organic material passes through the reaction vessel. The vessel includes a reaction zone for autogenous reaction of organic material in a reaction bed of the organic material. Pressure can be applied to the bed of organic material to increase the density of the resultant charcoal. Acoustic emitters may also be used to enhance the densification process.Type: GrantFiled: June 21, 2012Date of Patent: July 30, 2019Assignee: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATIONInventor: Alexandre Vladimirovich Deev
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Thermal process to transform contaminated or uncontaminated feed materials into useful oily products
Patent number: 9828553Abstract: The process is for thermally treating a feed material. The process comprises at least one step performed in a rotating kiln operating under positive pressure with a pressure control system and wherein in the process a sweep gas, that is an inert gas or a substantially non-reactive gas, is injected into the rotating kiln or in the feed stream entering the rotating operating kiln; or at least one step performed in a rotating kiln operating under positive pressure managing system; or at least one step performed in a rotating kiln wherein a sweep gas is injected in the rotating kiln or in the feed stream entering the rotating operating kiln. In step a), or in b) or in step c), the conditions of the thermal treatment are managed in order that the exit stream, after cooling, result in at least one liquid phase that is preferably essentially an oily liquid phase.Type: GrantFiled: February 6, 2013Date of Patent: November 28, 2017Assignee: ENVIROLLEA INC.Inventor: Lucie B. Wheeler -
Patent number: 9681667Abstract: The present invention relates to a composition of granulated or pelletized endomycorrhizal fungi spores coated with a covering of mineral clays and binders with calcium sulphate monohydrate and the production and use thereof in agriculture.Type: GrantFiled: December 10, 2014Date of Patent: June 20, 2017Inventor: José Luis Miranda Valencia
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Patent number: 9017521Abstract: A process for heat treatment of a solid, with a coolant solid, in which a stage for mixing the solid with the pre-heated coolant solid is carried out, with the coolant solid being a solid hydrocarbon. The solid hydrocarbon is ground, before the mixing stage with the solid, to obtain a solid hydrocarbon powder with a grain size of between 20 ?m and 300 ?m. The solid is ground, before the mixing stage with the coolant solid, to obtain solid pellets with a thickness of between 1 mm and 30 mm, a width of between 1 mm and 40 mm, and a length of between 1 mm and 100 mm. The mixing is carried out at a temperature of between 80° C. and 700° C.Type: GrantFiled: May 6, 2010Date of Patent: April 28, 2015Assignee: IFP Energies NouvellesInventors: Elena Garcia Sanz, Matthieu Rolland
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Patent number: 9005402Abstract: The present technology describes apparatus, systems, and methods for the thermal decomposition of carbonaceous feedstocks through continuous pyrolysis. A reciprocating reactor is described that includes an inner reactor pipe and an outer reactor pipe. The outer reactor pipe has a first portion that surrounds the inner reactor pipe forming an annulus space, and a second portion that extends beyond the inner reactor pipe and forms a turnaround zone. The inner reactor pipe defines an inner reactor zone that produces partially reacted carbonaceous feedstock, and the annulus space defines an outer reactor zone that produces product gases and solids.Type: GrantFiled: March 16, 2012Date of Patent: April 14, 2015Assignee: Interra Energy, Inc.Inventors: Thomas R. Del Monte, Eren K. Yar
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Patent number: 8986507Abstract: Methods, devices and systems for continuously converting biomass are described herein. A device has a feed section for holding a moving bed of biomass, namely wood, having a drying section, a flame zone for degassing, and a, smolder zone for carbonizing the biomass into a solid converted product, namely charcoal. The device includes a tank for collecting the solid converted product arranged below a grate and coupled with the feed section in a gas-tight manner. The system comprising the device, a biogas plant and/or a combined heat and power plant conveys the liquid converted product, namely pyroligneous acid or acetic acid, to the biogas plant and/or the solid converted product, namely charcoal, to the combined heat and power plant.Type: GrantFiled: March 10, 2010Date of Patent: March 24, 2015Assignee: European Charcoal AGInventor: Bernd Schottdorf
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Patent number: 8969638Abstract: A styrene monomer reclamation process and system is described. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream.Type: GrantFiled: September 28, 2011Date of Patent: March 3, 2015Assignee: Fina Technology, Inc.Inventors: Jon Tippet, James R. Butler, James Assef, John Ashbaugh, Jason Clark, Michel Duc, Jean-Bernard Cary
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Patent number: 8888961Abstract: A pyrolysis device and process to convert a carbonaceous feedstock to a carbon solid and pyrolysis gas, and processes for refining the resulting carbon solid and pyrolysis gases. The pyrolysis process may include introducing a carbonaceous feedstock into a pyrolysis processor having a vertical rotary tray processor, heating the feedstock to a temperature above about 790° F., removing a carbon material from a bottom of the pyrolysis processor, and removing a pyrolysis gas from a top of the pyrolysis processor.Type: GrantFiled: October 13, 2010Date of Patent: November 18, 2014Assignee: Reklaim, Inc.Inventors: Joel Horn, Daniel F. Kapral, William J. Langley, Jr., Thomas A. Reynolds
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Patent number: 8869420Abstract: This invention presents a versatile and continuous drying technology that utilizes controlled heat combined with forced air supply for drying a feedstock. The dryer virtually divided top-down into different zones, each having definite heated air distribution rate to secure desired condition for drying of the feedstock. The heat source of the dryer is waste heat, either provided by the feedstock itself through exothermic heat generated by the feedstock or reclaimed waste heat or solar heat. The discharge system of the dryer is a fail-safe discharge system, which ensures equal residence time for the feedstock through all the zones.Type: GrantFiled: January 2, 2013Date of Patent: October 28, 2014Inventor: Mousa Mohammad Nazhad
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Publication number: 20140311883Abstract: A method and an apparatus for pyrolysing a solid organic feed material are disclosed. Solid organic material is moved through a reaction chamber and exposed to a temperature profile within the chamber that dries and pyrolyses the organic material and releases water vapour and a volatile products gas phase. The water vapour phase and the volatile products gas phase are moved counter-current to the solid organic material so that the water vapour phase and condensable components of the volatile products gas phase condense in cooler upstream sections of the chamber and form a liquid water product and a separate liquid oil product. The liquid water product is discharged via an outlet along the length of the chamber and a dried and pyrolysed solid product is discharged from a downstream outlet in the chamber.Type: ApplicationFiled: June 30, 2014Publication date: October 23, 2014Inventors: Lazar Strezov, Steven Robert Osborn, Joseph George Herbertson, Gary Kenneth Ellem
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Patent number: 8821692Abstract: Method for fast pyrolysis of lignocellulose including: mechanically comminuting the lignocellulose to lignocellulose particles; at least one of completely drying and preheating the lignocellulose particles; mixing the lignocellulose particles with heat transfer particles so as to provide a mixture; heating the heat transfer particles, prior to the mixing, to a temperature between 500° C. and 650° C.; and heating, in a pyrolysis reactor with oxygen excluded, the lignocellulose particles using the heat transfer particles so as to establish a temperature between 400° C. and 600° C. for 1 to 50 seconds and so as to react the lignocellulose particles so as to provide pyrolysis coke, pyrolysis condensate, and pyrolysis gas.Type: GrantFiled: June 22, 2006Date of Patent: September 2, 2014Assignee: Karlsruher Institut fuer TechnologieInventors: Edmund Henrich, Friedhelm Weirich, Eckhard Dinjus
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Patent number: 8795475Abstract: There is described a system and method for recycling carbon-containing material, in particular tires and plastics materials. The system includes a heating arrangement for anaerobically heating carbon containing material to produce carbon-containing gases. A condensing arrangement is also used to condense a proportion of the carbon-containing gases to provide condensed gases and non-condensed gases. In addition, a recirculating arrangement is provided for recirculating the non-condensed gases into the heating arrangement. Further systems and methods for pre- and post-processing of the carbon-containing material are also disclosed and products of the systems and methods are also described.Type: GrantFiled: December 19, 2007Date of Patent: August 5, 2014Assignee: Used Tyre Distillation Research LimitedInventors: Richard Hutchins, Michael Walker, Paul Archer
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Patent number: 8784616Abstract: A process for the controlled gasification of a carbonaceous feedstock includes pyrolizing the feedstock by conveying the feedstock through a retort surrounded by a plurality of successive heating chambers each comprising an axially adjustable chamber separation wall and each operated at a predetermined temperature, wherein a predetermined dwell time of the feedstock in each of the plurality of successive heating chambers is controlled by a conveyance rate of the feedstock through the retort and a position of each of the axially adjustable chamber separation walls to produce a gas product and a solid product. The gas product includes methane and noxious chemicals and the solid product includes carbon, and the pyrolizing step is controlled using feedback related to constituents of the gas product.Type: GrantFiled: June 8, 2010Date of Patent: July 22, 2014Assignee: Tucker Engineering Associates, Inc.Inventor: Richard D. Tucker
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Patent number: 8741108Abstract: A reactor (9) for the pyrolysis of carbon-containing waste material such as rubber chips includes a cylindrical air-tight reactor vessel (10) which has an inlet through which rubber chips (4) are introduced into the reactor vessel and an outlet (60) through which oil distillate can be discharged therefrom. The reactor vessel has a cooling jacket through which cooling water flows for cooling an inner shell (40) of the vessel. The chips (4) are deposited onto a support tray (70) and displaced towards a rear end of the reactor vessel by a chain conveyer (89). The chips (4) are heated on the tray (40) causing decomposition of the chips into a vapor and amorphous carbon. The vapor condenses when it contacts the inner shell (40) and runs down the sides of the vessel (10) towards a lower side thereof before being discharged through the outlet (60).Type: GrantFiled: August 3, 2006Date of Patent: June 3, 2014Assignee: Gecco Group (Proprietary) LimitedInventor: John Lindsay Dinnematin
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Publication number: 20130341175Abstract: A improved solar biochar reactor, system including the reactor, and methods of forming and using the reactors and systems are disclosed. The methods and system as described herein provide sufficient solar energy to a biochar reactor to convert animal waste or other biomass to biochar in a relatively cost-effective manner.Type: ApplicationFiled: March 15, 2013Publication date: December 26, 2013Applicant: The Regents of the University of Colorado, a body corporateInventors: Karl G. Linden, Alan W. Weimer, R. Scott Summers, Allan Lewandowski
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Publication number: 20130240344Abstract: Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas, and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas, and recycled contaminants.Type: ApplicationFiled: March 15, 2013Publication date: September 19, 2013Applicant: THERMO TECHNOLOGIES, LLCInventors: Dennis E.J. Johnson, Grigori A. Abramov, Richard A. Kleinke, Marcus A. Wiley
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Publication number: 20130228445Abstract: A method and apparatus is described for the efficient conversion of carbonaceous feedstock including municipal solid waste into a product gas through gasification. More specifically, a horizontally-oriented gasifier having one or more lateral transfer system for moving material through the gasifier is provided thereby allowing for the horizontal expansion of the gasification process such that there is sequential promotion of feedstock drying, volatization and char-to-ash conversions.Type: ApplicationFiled: February 13, 2013Publication date: September 5, 2013Applicant: PLASCO ENERGY GROUP INC.Inventors: Andreas Tsangaris, Kenneth Craig Campbell, Douglas Michael Feasby, Mao Pei Cui, Zhiyuan Shen, Geoffrey Dobbs
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Publication number: 20130168223Abstract: The object of the invention is a method and an apparatus relating to the dry distillation of raw biomaterial and to the recovery of different compounds as a continuous process. In the method according to the invention, raw material is dry distilled in at least two separate dry distillation zones maintained in pressures and/or temperatures different from each other. A multi-layer dry distiller pertaining to the apparatus according to the invention consists of at least two separate dry distillation tubes maintained in different pressures and/or temperatures from each other to implement different dry distillation zones.Type: ApplicationFiled: September 7, 2011Publication date: July 4, 2013Inventor: Juha Huttunen
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Patent number: 8470134Abstract: A process for treating coal includes introducing coal into a chamber and passing an oxygen deficient sweep gas into contact with the coal, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to the coal indirectly by heating the chamber, wherein the heating of the coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. The proportion of heat supplied to the coal by the sweep gas is less than 40% of the total heat supplied to the coal. The sweep gas is then removed from the chamber and treated to remove condensable components of the coal.Type: GrantFiled: September 10, 2009Date of Patent: June 25, 2013Assignee: C2O Technologies, LLCInventor: Franklin G. Rinker
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Patent number: 8444828Abstract: A pyrolyzer and method is provided for devolatizing coal and other volatile materials. The pyrolyzer has a pyrolyzer furnace housing having at least two screws laterally positioned adjacent and overlapping rotatably mounted within the furnace for moving volatile material through the pyrolyzer furnace housing. The screws have hollow drive shafts with a diverter inside for converging heated fluid to heat the volatile material moving through the pyrolyzer furnace housing. A combustion chamber combusts fuel to create heated exhaust gas for directing through the hollow drive shafts to heat the volatile material. The pyrolyzer furnace housing may have a double wall with a cavity between, capable of receiving heated fluid for further heating of volatile material moving through the pyrolyzer furnace housing.Type: GrantFiled: December 19, 2007Date of Patent: May 21, 2013Assignee: Nucor CorporationInventor: Richard A. Wolfe
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Patent number: 8414743Abstract: A method and a device for the thermal decomposition of an initial material, in particular, for the decomposition of meat and bone meal, oil sludges, for example, from cleaning tankers, autofluff (also called autofluffy), basic glycerin, for example, from biodiesel production, paint sludges from paint shops, contaminated soils, coated wood, and plastics such as plexiglass. According to the present method, organic initial materials are thermally decomposed very completely in nearly all cases. The very complete decomposition is achieved by adding foreign particles such as metal spheres to the initial material which is being thermally decomposed.Type: GrantFiled: April 30, 2008Date of Patent: April 9, 2013Assignee: Gebr. Lodige Maschinebau GmbHInventors: Alfons Schmidt, Hans-Jürgen Sickelmann, Armin Grob
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Patent number: 8394240Abstract: A process for treating bituminous coal includes providing dried, pulverized coal, and treating the pulverized coal in a vessel with a gas stream having an oxygen content sufficient to form oxides on surface of coal particles. The treated coal is transferred into a pyrolyzing chamber and passed into contact with an oxygen deficient sweep gas, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to the coal indirectly by heating the chamber, wherein the heating of coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. Some of the oxides are converted into paramagnetic mineral components, which are removed from coal to form a coal char having reduced ash and sulfur.Type: GrantFiled: September 10, 2009Date of Patent: March 12, 2013Assignee: C2O Technologies, LLCInventor: Franklin G. Rinker
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Patent number: 8354005Abstract: Apparatus for the destructive reclamation of materials and energy from municipal wastes and other raw materials through the use of Microwave induced Gasification and Pyrolysis, where the waste or raw material may be circulated once or several times through the process thus enabling the programming of different processes to differing materials and desired end products. The form employed being linear, circulating conveyors or rotating carousels that may carry trays or crucibles, some of which may be equipped with linings that absorb microwaves to enable the early charring of materials that do not initially absorb microwaves and thus will not heat up on their own.Type: GrantFiled: February 2, 2005Date of Patent: January 15, 2013Inventor: Kjell Ivar Kasin
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Publication number: 20120285814Abstract: The present technology discloses apparatus, systems, and methods for the thermal decomposition of carbonaceous feedstocks through continuous pyrolysis. A reciprocating reactor is disclosed that includes an inner reactor pipe and an outer reactor pipe. The outer reactor pipe has a first portion that surrounds the inner reactor pipe forming an annulus space, and a second portion that extends beyond the inner reactor pipe and forms a turnaround zone. The inner reactor pipe defines an inner reactor zone that produces partially reacted carbonaceous feedstock, and the annulus space defines an outer reactor zone that produces product gases and solids.Type: ApplicationFiled: March 16, 2012Publication date: November 15, 2012Inventors: Thomas R. Del Monte, Eren K. Yar
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Patent number: 8298406Abstract: An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.Type: GrantFiled: May 21, 2009Date of Patent: October 30, 2012Assignee: Coates Engineering, LLCInventors: Ralph L. Coates, L. Douglas Smoot, Kent E. Hatfield
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Patent number: 8168043Abstract: A retort apparatus includes a primary rotating pipe within a second rotating pipe within a fixed pipe (27). The interior area of the primary rotating pipe is bounded by a heated pipe. A first annulus is formed between the primary and second rotating pipes. A second annulus is formed between the second rotating pipe and the heated pipe. A third annulus is formed between the primary rotating pipe and the fixed pipe. A heater is positioned within the interior area of said primary rotating pipe. In one embodiment, an inlet gate is provided for introducing a liquid and solid mixture into the first annulus proximate the second end thereof. A first conveyor is provided to move the mixture toward the hot end of the primary rotating pipe.Type: GrantFiled: August 29, 2008Date of Patent: May 1, 2012Assignee: Eau-Viron IncorporatedInventor: James Titmas
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Publication number: 20120047975Abstract: A method and apparatus for continuously carbonizing materials while co-producing gases in a coking chamber closed to the atmosphere, having a charger at one end comprising a pushing ram surrounding a mandrel that surrounds an air or oxygen injection lance. The other end of the coking chamber collects and separates coke from gases, with coke directed to a closed quenching chamber and gases directed to a cleanup. Thermal energy for converting coal into coke derives from combusting some metallurgical coal by said lance.Type: ApplicationFiled: September 1, 2010Publication date: March 1, 2012Inventors: Albert Calderon, Terry James Laubis
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Publication number: 20110067991Abstract: A biomass pyrolysis process is provided in which biomass feedstock is mixed with a heat carrier. The heat carrier at least partly comprises char. The ratio by weight of biomass to char is in the range 1:1 to 1:20. The process may be carried out by in a screw/auger pyrolysis reactor in which the solid feedstock components are conveyed along the reactor by a first screw. A second screw conveys at least a portion of the solid products of the biomass pyrolysis back to a heat transfer medium input port. Thus, the heat transfer medium includes char from the biomass pyrolysis.Type: ApplicationFiled: May 14, 2009Publication date: March 24, 2011Inventors: Andreas Hornung, Andreas Apfelbacher
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Publication number: 20110011722Abstract: A process for treating coal includes introducing coal into a chamber and passing an oxygen deficient sweep gas into contact with the coal, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to the coal indirectly by heating the chamber, wherein the heating of the coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. The proportion of heat supplied to the coal by the sweep gas is less than 40% of the total heat supplied to the coal. The sweep gas is then removed from the chamber and treated to remove condensable components of the coal.Type: ApplicationFiled: September 10, 2009Publication date: January 20, 2011Inventor: Franklin G. Rinker
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Patent number: 7824523Abstract: A catalytically activated vacuum distillation system, several novel component parts of said system, a process for producing carbon based products and novel carbon black that is produced from such a system and process.Type: GrantFiled: April 17, 2006Date of Patent: November 2, 2010Assignee: Earthfirst Technologies, Inc.Inventors: Michael P Maskarinec, Bart M. Taylor
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Publication number: 20100140074Abstract: Combustible material is supplied to the reaction zone, continuously or in pulses, which the reaction zone is separated from the surrounding atmosphere, and combustible material gradually moves through the reaction zone to the reaction zone outlet, in the same direction as released gases leave the combustible material. The reaction zone is heated to the temperature, the value of which is increasing in the direction to the reaction zone outlet, however, to 12000 C as a maximum. Then, released gases are draught off separately from non-gasified residue. As an advantage, steam and/or water is supplied to combustible material and the combustible material previously charged into the reaction zone moves by acting of subsequently supplied combustible material, where the combustible material is being compressed. The equipment for pyrolytic conversion comprises one filling device (1), reactor (2) comprising the reaction zone (5), at least one heater (3, 13), and hopper (4) for non-gasified residue (8).Type: ApplicationFiled: May 12, 2008Publication date: June 10, 2010Inventors: Václav Holusa, Petr Vanicek, Ivan Koutnik, Miroslav Kaloc
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Patent number: 7569121Abstract: The present development is a multistage process for converting solid hydrocarbon resources into synthetic oil. The process comprises a raw hydrocarbon material treatment stage, followed by a pyrolysis stage, and then a synthetic liquid upgrading stage. Throughout the process, heat is transferred to the hydrocarbon resources via recyclable ceramic spheres.Type: GrantFiled: March 31, 2005Date of Patent: August 4, 2009Inventor: Clyde Wesley Devore
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Publication number: 20040167367Abstract: The invention provides a process for the production of charcoal, fuel gas, and potassium from a biomass gassifier.Type: ApplicationFiled: September 23, 2003Publication date: August 26, 2004Inventor: Fred P. Beierle
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Patent number: 6669822Abstract: The present invention relates to a waste carbonization method which produces charcoal and/or activated carbon from solid wastes, such as wood waste, and renders produced gas completely harmless. Solid wastes B are exposed to gas generated in pyrolysis gasification of other wastes A in a gasification furnace 1 to produce charcoal and/or activated carbon from the solid wastes B.Type: GrantFiled: June 7, 2001Date of Patent: December 30, 2003Assignee: Ebara CorporationInventors: Hiroyuki Fujimura, Kazuo Takano, Akira Uchino, Takahiro Ohshita, Tetsuhisa Hirose
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Patent number: 6613111Abstract: A process and method is provided for operating a small-scale high-throughput gasifier. As is known in the art, the exothermic combustion reactions can be separated from the endothermic gasification reactions. The exothermic combustion reactions can take place in or near the combustor while the endothermic gasification reactions take place in the gasifier. Heat from the exothermic zone is transferred to the endothermic reaction zone by circulation of an inert particulate solid such as sand. In order to increase efficiency by reducing heat loss from the gasifier, the gasifier is concentrically-disposed within the endothermic reaction zone of the combustor.Type: GrantFiled: November 16, 2001Date of Patent: September 2, 2003Assignee: Future Energy Resources CorporationInventor: Mark A. Paisley
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Patent number: 5725738Abstract: A method and apparatus for producing wood charcoal by pyrolysis of wood products or vegetable biomasses in general, the method including the steps of: loading the wood products, or vegetable biomasses in general, onto transport trolleys; introducing the trolleys, which contain the wood products, in a treatment tunnel wherein a pyrolysis chamber is formed; indirectly heating the wood products inside the pyrolysis chamber until pyrolysis of the wood products is obtained, with continuous extraction, from the pyrolysis chamber, of the gas generated by the pyrolysis process; and extracting the trolleys from the tunnel to unload from the trolleys the charcoal that constitutes the residue of the pyrolysis of the wood products.Type: GrantFiled: February 13, 1996Date of Patent: March 10, 1998Inventors: Osvaldo Brioni, Dario Buizza
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Patent number: 5705035Abstract: A discharge system is used with a tire liquefaction process using a reactor. The system includes a receiver receiving unreacted components, including oil coated metal from the reactor. The unreacted components are moved through a pyrolysis reactor where they are heated to a temperature sufficient to convert the unreacted hydrocarbon components to a liquid and to a gas by way of pyrolysis. The liquid and the majority of gas are drawn off from the pyrolysis reactor. Discharge apparatus connected to the pyrolysis reactor converts the remaining gas to a condensate and discharges the metal. The condensate is also removed for further use.Type: GrantFiled: May 28, 1996Date of Patent: January 6, 1998Assignee: Texaco, Inc.Inventors: Vahan Avetisian, Craig Joseph Castagnoli, Suk-Bae Cha
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Patent number: 5525196Abstract: An improved process for producing a formed activated coke for simultaneous desulfurization and denitrification, which includes passing a ground coal through a tubular or cylindrical carbonization retort by using a hot gas stream, to subject the coal to preliminary carbonization to obtain a semi-coke, adding a caking agent to the semi-coke and forming the mixture, subjecting the formed material to carbonization to obtain a formed coke, and transferring the formed coke from the top to the bottom of a vertical multi-tubular retort of indirect heating and cooling (cooling is optional) type that includes a distribution section, a heating section, an activation section and a cooling section (the distribution section and the cooling section are optional) arranged in this order (the distribution section is at the top), to activate the formed coke.Type: GrantFiled: June 14, 1994Date of Patent: June 11, 1996Assignee: Mitsui Mining Co., Ltd.Inventors: Toshihisa Yuda, Masahiro Matsuoka, Kazuhiko Hanashita, Fumiaki Furusawa, Mitsuhiro Takada
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Patent number: 5478442Abstract: A rotary hearth calciner for treating petroleum cokes with a puffing inhibitor has a horizontal or inwardly sloping hearth floor rotatable around a vertical axis for receiving particles of coke to be calcined and a central opening in the hearth floor for discharging the coke into a soaking pit. A water cooled, refractory covered feed pipe extending downward into the calciner interior has an inlet for connection to a source of petroleum coke puffing inhibitor and an outlet near the edge of the hearth central floor opening for adding the puffing inhibitor to the coke as the coke is discharged from said hearth floor. The feed pipe outlet is approximately at or below the level of the hearth floor to reduce loss of inhibitor in gas flow above the hearth floor. A puffing inhibitor such as sodium carbonate is supplied by a screw feed mechanism to the feed pipe to add the puffing inhibitor at a desired rate for reaction with the coke. The coke is normally maintained in the soaking pit for about 30 minutes at 1200.Type: GrantFiled: February 15, 1995Date of Patent: December 26, 1995Assignee: UCAR Carbon Technology CorporationInventor: Thomas H. Orac
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Patent number: 5464503Abstract: A discharge system is used with a tire liquefaction process using a reactor. The system includes a receiver receiving unreacted components, including oil coated metal, from the reactor. The unreacted components are moved through a pyrolysis reactor where they are heated to a temperature sufficient to convert the unreacted hydrocarbon components to a liquid and to gas by way of pyrolysis. The liquid and the majority of gas are drawn off from the pyrolysis reactor. Discharge apparatus connected to the pyrolysis reactor converts the remaining gas to a condensate and discharges the metal. The condensate is also removed for further use.Type: GrantFiled: October 28, 1993Date of Patent: November 7, 1995Assignee: Texaco Inc.Inventors: Vahan Avetisian, Craig J. Castagnoli, Suk B. Cha
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Patent number: 5449438Abstract: Apparatus and method for reprocessing crushed organic waste products, such as rubber waste from worn car tires, by pyrolysis, the method including pyrolytically decomposing the crushed waste products in a pyrolysis bath which is one of a bed or a bath, and which has a temperature ranging from 450.degree. to 550.degree. C., into a mixture including volatilized constituents, liquid constituents, and solid constituents; collecting at least a part of the volatilized constituents from a gas space above the pyrolysis bath and transporting the collected volatilized constituents away from the pyrolysis bath for further utilization; and introducing a gas intermittently or continuously into the gas space above the pyrolysis bath.Type: GrantFiled: July 30, 1993Date of Patent: September 12, 1995Assignee: FORMEX Trading GmbHInventors: Hermann H. W. Jagau, Richard Schimko
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Patent number: 5423951Abstract: Pieces of coke of high density and strength are made continuously from fine particles of bituminous or subbituminous or lignite coals or of mixtures thereof. The particles are generally oxygenated, mixed with water, compressed to squeeze out some of the water to obtain single bodies which are heat processed lying on a traveling grate on which they undergo drying, pyrolyzing, carbonizing and cooling.Modifications include mixing in with the coal material(s) listed above, coke fines or char or anthracite coal; or limestone; or carbon-reducible oxides such as oxidic ores of Fe, Mn, Cr and quartzite in recited important proportions. Such formed coke bodies are useable in a submerged arc furnace or in a blast furnace or in an open hearth to produce desired intermediate or end metallic products. The pieces of coke with incorporated fine limestone burn without developing SO.sub.2.Type: GrantFiled: December 17, 1991Date of Patent: June 13, 1995Inventor: Fritz O. Wienert
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Patent number: 5330623Abstract: The organic material (such as waste tire compound) is pyrolysed by pre-heating the organic material (without pyrolysis) in a preheat zone 9 by a hot gas stream; feeding pre-heated material directly to a microwave discharge zone 10 by means of conveyor 8; pyrolysing the pre-heated material in the microwave discharge zone to produce solid fission products containing elemental carbon and gaseous by-products; and recycling at least some of the latter to the hot gas stream which is supplied to the pre-heating zone.Type: GrantFiled: January 27, 1992Date of Patent: July 19, 1994Inventor: Kenneth M. Holland
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Patent number: 5318672Abstract: A method and an apparatus for heating a carbonization drum is especially used for heating a carbonization drum for a low-temperature-carbonization combustion process. Heating gas heated in a heat exchanger is guided in a heating gas loop from the heat exchanger through the carbonization drum. A heat sink is provided for cooling the heating gas. In order to control an energy supply to the carbonization drum, the heating gas is guided back again at least partially and in a controlled fashion through a bypass line, in which the heat sink is disposed, to the heat exchanger, while bypassing the carbonization drum. The heating gas can also be delivered partially and in a controlled fashion through the heat sink to the carbonization drum. A distribution of the heating gas into a maximum of three paths is ensured by a configuration of lines and control devices.Type: GrantFiled: February 7, 1992Date of Patent: June 7, 1994Assignee: Siemens AktiengesellschaftInventor: Georg Losel
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Patent number: 5212144Abstract: An improved apparatus and method for the manufacture of activated carbon wherein a carbonaceous raw material impregnated with a chemical activating agent is treated by controlling the rate of heat transfer to the particles via indirect heating of the activation furnace and simultaneously introducing a flow of independently controlled sweep gas at spaced intervals along the path of travel of the particles through the furnace to more precisely control the activation reaction and the level of densification of the particles during certain stages of treatment. In a more preferred embodiment, the particles are processed in a plurality of treatment stages related to the rate of evolution of water and/or the evolution of water and the chemical activating agent and the rates of heat transfer and the volume flow rate of sweep gas are closely controlled relative to achieving predetermined levels of densification of the particles during each treatment stage and selected levels of activation properties in the end product.Type: GrantFiled: June 1, 1992Date of Patent: May 18, 1993Assignee: Westvaco CorporationInventor: Frank R. Schwartz, Jr.
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Patent number: 5084141Abstract: The organic material (such as waste tire compound) is pyrolyzed by pre-heating the organic material (without pyrolysis) in a preheat zone 9 by a hot gas stream; feeding pre-heated material directly to a microwave discharge zone 10 by means of conveyor 8; pyrolyzing the pre-heated material in the microwave discharge zone to produce solid fission products containing elemental carbon and gaseous by-products; and recycling at least some of the latter to the hot gas stream which is supplied to the pre-heating zone.Type: GrantFiled: May 11, 1990Date of Patent: January 28, 1992Inventor: Kenneth M. Holland
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Patent number: 5082534Abstract: A rotary, continuous pyrolytic conversion system converts solid hydrocarbon containing feedstocks into gases, liquid hydrocarbons and char. A converter drum is contained within an outer drum which is in substantially air-tight relationship with an injector for introducing the feedstock in the form of bales and with a discharge chute for the solid products of pyrolysis. A casing around the outer stationary drum defines an oven chamber which is heated by combustion products. A rod extends into the injection end of the converter drum for supporting scrapers against the inner periphery of the converter drum. A crusher bar is carried in the drum at the discharge end thereof and crushes the solid products. A second pyrolysis reactor may receive the solid pyrolysis products and be operative at higher temperature than the first converter to destroy chlorinated hydrocarbons.Type: GrantFiled: March 14, 1990Date of Patent: January 21, 1992Assignee: Wayne Technology, Inc.Inventor: Fred A. Breu