Quenching Char With An Inert Material Patents (Class 201/39)
  • Patent number: 4662895
    Abstract: A method and apparatus of cooling retort coke is disclosed which provides for cooling hot coke from a coking chamber by direct heat exchange with fine-grained material, preferably coal, and the subsequent separation of the fine-grained material from lump coal which would form the cooling step.
    Type: Grant
    Filed: May 9, 1985
    Date of Patent: May 5, 1987
    Assignee: Firma Carl Still GmbH & Co. K.G.
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4647341
    Abstract: A dry coke cooling apparatus comprises an antechamber with a bottom hole for charging coke into a cooling chamber which accommodates vertical outer cooling walls and inner cooling walls which extend within the coke charge. The lower part accommodates coke discharge equipment and conduits for supplying circulated cooling gas which passes upwardly through the charge, to be exhausted at the top. The inner cooling walls are supported on hollow beams which are cooled by the circulated cooling gas directly or indirectly.
    Type: Grant
    Filed: December 20, 1984
    Date of Patent: March 3, 1987
    Assignee: Firma Carl Still GmbH & Co.KG
    Inventors: Kurt Lorenz, Horst Dungs, Gerd Nashan, Dieter Breidenbach, Josef Volmari
  • Patent number: 4634500
    Abstract: The present invention provides a method of quenching heated coke in a coke drum. Quench water is fed into the coke drum to cool the coke, and the stress in the coke drum wall is monitored during the quenching. The rate of feeding the quench water into the coke drum is regulated to prevent the stress in the coke drum wall from exceeding a predetermined limit. The stress is monitored by measuring either the longitudinal thermal gradient or the rates of change in the drum wall temperature over time.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: January 6, 1987
    Assignee: Foster Wheeler Energy Corporation
    Inventors: John D. Elliott, Steven P. King
  • Patent number: 4614567
    Abstract: Method and apparatus for detection and selective after-quenching of red hot pockets in previously quenched hot coke lying on a coke bench, in which the temperature of the coke is sensed and recorded over the entire surface or area of the coke bench by temperature sensors installed thereabove, and if excessively hot coke portions or local areas are found, only those excessively hot coke portions are acted upon for after-quenching automatically in controlled manner with a focused water jet or spray using only a minimum amount of water for as short a time as possible.
    Type: Grant
    Filed: June 12, 1985
    Date of Patent: September 30, 1986
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Dieter Stahlherm, Reimer Haack, Wilhelm Stewen, Helmut Lukaszewicz
  • Patent number: 4606793
    Abstract: A method is disclosed for operating a carbonization plant in which coking furnaces are periodically charged with preheated coal and the obtained coke is subjected to a dry cooling by a gaseous cooling medium, heat discharged from the dry cooling of the coke is used for the preheating of the coal, involving preheating the coal in a traveling bed drier having a heat exchange tube that is heated with hot gas or waste-heat vapor from the dry cooling of the coke. Preferred embodiments include withdrawing exhaust gas-containing vapors produced in the traveling bed drier from different levels; and superposing a fluidized bed drier upon the traveling bed drier.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: August 19, 1986
    Inventors: Vladan Petrovic, Karl Schmid, Henner Schmidt-Traub
  • Patent number: 4559107
    Abstract: A method of dry cooling coke using a coke transporting bucket which has a removable cover with an exhaust pipe extending from the interior of the bucket to an exterior exhaust connection and a cooling shaft for the coke comprises directing red hot coke into the bucket, covering the bucket with the cover and transporting the coke to the cooling shaft and connecting the exhaust pipe to the exhaust system while the bucket is in the shaft and emptying the bucket into the cooling shaft. The coke transporting bucket comprises a container having a bottom discharge which is closable by a flap and a removable cover which seats around the rim of the container to seal it. An exhaust pipe is carried by the cover and it extends into the interior thereof for removing gases from within the bucket and delivering them to an exterior connection which is connectable to an exhaust line.
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: December 17, 1985
    Assignee: Firma Carl Still GmbH & Co. KG.
    Inventors: Kurt Lorenz, Engelbert Bruns, Gerd Osterholt
  • Patent number: 4556455
    Abstract: A method for the dry cooling of coke comprises transferring the coke from the coke oven to a special bucket which is moved over a charging hole of a cooling pit. The space between the bucket and the charging hole is closed off and sealed against the atmosphere and a shutter which closes the top of the charging hole is moved upwardly and then transversely off the charging hole to open it as an intermediate charging guide piece is moved in position between the hole and the bucket for the transfer of the coke therebetween. The space between the bucket and the charging hole is sealed by a frame of a sluicing device in which the shutter and the intermediate charging hole guidepiece is movable. The device advantageously runs on wheels which are located outside the frame which seals the sapce between the charging bucket and the charging pit. The frame of the sluicing device advantageously includes a sealing element which engage into a recess seal combined around the charging hole.
    Type: Grant
    Filed: February 16, 1984
    Date of Patent: December 3, 1985
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Engelbert Bruns, Gerd Osterholt
  • Patent number: 4529483
    Abstract: A process for utilizing waste heat and producing water gas during cooling of red-hot coke, in two stages, is indicated. In a first, dry cooling stage, a mixture of water gas and steam passes the coke charge, is recooled in a heat sink and recirculated into the first cooling stage, whereby it is possible to take off a part quantity of the gas mixture. In a second, wet cooling stage, water is fed into a quench zone and the steam formed is passed through the coke charge partially into the first cooling stage and partially released into the surroundings or fed back into the second cooling stage or partly released into the surroundings and partly fed back into the second cooling stage. Both the mixture of water gas and steam in the first cooling stage and the quench water or the steam formed from it in the second cooling stage are passed through the coke charge from the inside outwards.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: July 16, 1985
    Assignee: Hartung, Kuhn & Co. Maschinenfabrik GmbH
    Inventor: Richard A. Jung
  • Patent number: 4519874
    Abstract: A sealing system primarily for use with a superatmospheric upflow oil shale retort is comprised of a first and second vertical vessel, with a first sealing screw being employed to transport the particles as a continuous bed from the first to the second vessel, and with a second sealing screw to transport the particles from the second vessel to discharge. In the first vessel, shale particles are cooled by contact with water, which usually generates noxious gases, such as hydrogen sulfide. These noxious gases are removed from the sealing system by the purging action of two sealing gas streams, the first sealing gas removing the bulk of the noxious gases from the first vessel, and the second sealing gas removing residual noxious gases from the second vessel.The shale particles are discharged to the environment from the second sealing screw in a dry condition, with a minimum emission of noxious gases.
    Type: Grant
    Filed: April 14, 1983
    Date of Patent: May 28, 1985
    Assignee: Union Oil Company of California
    Inventor: Rick V. Bertram
  • Patent number: 4512850
    Abstract: Process and apparatus for wet-quenching of hot-coke unloaded from a coke producing oven use water quenching from exclusive overhead tanks in two distinct consecutive phases so as to minimize the wasteful coke-dust generated and so as to limit the final maximum-water content in the produced coke. A high rate of water flow under controlled pressure head is used for a short period of time in the initial phase wherein coke-dust particles generated and rising in the water vapor cloud are washed down and prevented from entering the quenching hood; in a second and final stage, a low rate of water flow is maintained for a longer period of time wherein owing to the hot surface of coke having been already cooled in the first phase, coke-dust is not generated as much, and, the required limits for final water content can easily be maintained.
    Type: Grant
    Filed: December 22, 1981
    Date of Patent: April 23, 1985
    Assignee: Ruhrkohle Aktiengesellschaft
    Inventor: Wilhelm Mosebach
  • Patent number: 4505809
    Abstract: A process for extracting hydrocarbons from oil shale comprising the steps of subjecting oil shale under superatmospheric pressure in the presence of hydrogen and steam, to low temperature hydrogenating distillation; separating the resulting fluid distillation mixture into liquid and gaseous products; and returning water and hydrogen separated from the fluid distillation mixture to the low temperature distillation; in which:heat is drawn-off from the hot oil shale, after treatment in a low temperature hydrogenating distillation reactor, by the shale being sprayed wtih water whereby saturated steam is produced in decreasing pressure stages;the saturated steam of the pressure stages and water extracted during product separation are fed into the individual stages of a multi-stage compressor driven by a gas turbine, and are then delivered via a steam supply line to the reactor;the gas turbine is fuelled by supplying separated-off gaseous distillation products thereto; andthe exhaust gases of the gas turbine are fe
    Type: Grant
    Filed: October 31, 1983
    Date of Patent: March 19, 1985
    Assignee: Kraftwerk Union Aktiengesellschaft
    Inventors: Gerd Brunner, Rainer Hoffmann, Konrad Kunstle
  • Patent number: 4492042
    Abstract: Disclosed are methods for drying coking coals to be charged in coke ovens utilizing a heating medium which recovers the sensible heat contained in the gas generated in the coke ovens as a heating source for drying coking coals to a desired moisture content. Chiefly based on the moisture of coking coals before drying, the flow rate of the heat medium to the coke dryer is controlled or a hot blast generated in a separate heating system is used for the drying.
    Type: Grant
    Filed: August 26, 1982
    Date of Patent: January 8, 1985
    Assignee: Nippon Steel Corporation
    Inventors: Norio Otabe, Yoshiaki Shimakawa, Hiroshi Uematsu
  • Patent number: 4486269
    Abstract: Cooling of a gas-permeable loose material having highly temperature-dependent coefficient of thermal conductivity is performed in a shaft-shaped chamber with use of a gaseous cooling medium so that the loose material is fed from above downwardly in a counter stream against a stream of the gaseous medium supplied from below upwardly. The stream of the gaseous medium is subdivided into two partial streams, and one of the partial streams is supplied into the lower part of the chamber, whereas the other of the partial streams is supplied into a region in which the loose material has at least a temperature above which the coefficient of thermal conductivity of the loose material in dependence upon the temperature greatly increases.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: December 4, 1984
    Assignee: Krupp-Koppers GmbH
    Inventor: Friedrich Jokisch
  • Patent number: 4470878
    Abstract: In a coking process, coal to be coked is preheated in a cascaded whirling bed drier into which the coal is charged from above and exposed to an indirect heat transfer while whirling in a coal-stream mixture. Hot gas applied to the heating pipes in respective cascades of the drier is branched off from the total amount of hot gases discharged from a dry cooler in which hot coke from the coke oven is cooled by recirculating cooler gas constituted by a partial gas stream discharged from the cascades of the drier and reunited with the other partial stream subject to a heat exchange for generating steam. Steam from the whirling beds is discharged from the cascaded drier, separated from the entrained dust particles, and then the excessive steam is drained in a branch conduit and the remaining steam is compressed and reintroduced into the lowermost whirling bed in the drier.
    Type: Grant
    Filed: February 22, 1983
    Date of Patent: September 11, 1984
    Assignee: Krupp-Koppers GmbH
    Inventors: Vladan Petrovic, Karl Schmid, Friedrich Jokisch, Heinz Rotthaus
  • Patent number: 4469557
    Abstract: Green petroleum coke is partly devolatilized by transporting horizontally in static bed form through a furnace over a series of air box zones including a minority of zones adjacent the input end of the furnace and a majority remote from the input end and further devolatilized by soaking in a shaft furnace until at least most of the residual volatiles are driven off. From the shaft furnace the devolatilized coke is water quenched and steam produced in the quencher is mixed with downdrafted gases from said furnace to cool the same and prevent premature combustion.
    Type: Grant
    Filed: February 17, 1983
    Date of Patent: September 4, 1984
    Assignee: Peabody Development Company
    Inventors: Chris V. Schweer, Jimmy B. Smith
  • Patent number: 4461673
    Abstract: An apparatus and process are provided for depressurizing, cooling, and, optionally, moisturizing retorted oil shale produced in an oil shale retort operated at superatmospheric pressure. Hot retorted oil shale particles are gravitated from the retort and into an elongated, multichambered vessel. In the upper chambers of the vessel the particles are partially cooled by contact with a controlled flow of liquid water. The water, having been totally vaporized, is removed from the particles at a rate which prevents the substantial flow of gases between the vessel and the retort. In the lower chambers of the vessel, the particles are first stripped of entrained hydrocarbon gas by gravitating through a countercurrently flowing stream of stripping gas and then brought to ambient pressure by gravitating through a long, narrow seal leg. Optionally, the depressurized and partially cooled particles are then further cooled and moisturized by admixing with a controlled flow of liquid water.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: July 24, 1984
    Assignee: Union Oil Company of California
    Inventors: Roland F. Deering, Roland O. Dhondt, deceased, John E. Hines
  • Patent number: 4437936
    Abstract: A process for utilizing waste heat and for obtaining water gas during the cooling of incandescent coke ejected from a chamber oven is described, this process being in two stages. In the first stage, the coke is dry-cooled with a mixture of water gas and water vapor as the cooling gas. This is circulated, and from the circuit the desired waste heat and the desired water gas are extracted. In the second stage, the coke is wet-cooled with water. The water vapor formed is taken off and returned to the environment and/or to the second stage.
    Type: Grant
    Filed: March 23, 1982
    Date of Patent: March 20, 1984
    Assignee: Hartung, Kuhn & Co. Maschinenfabrik GmbH
    Inventor: Richard A. Jung
  • Patent number: 4416733
    Abstract: A dry quenching apparatus for hot coke has an upright housing having openings for charging and discharging the coke. An annular header for exhausting gases from the quenching zone is arranged in the middle portion of the housing. In the lower portion of the housing there is an annular header for supplying a cooling agent and communicating through corresponding passages with a distributor disposed above the annular header for supplying a cooling agent and centrally of the housing. An annular distribution header is arranged above the annular header for supplying a cooling agent and has vertical partition walls dividing the distribution header into sections. Each section has at least one opening through which the annular header for supplying gases and the annular distribution header communicate. At least one opening in each section accommodates a flow governor for a cooling agent.
    Type: Grant
    Filed: June 16, 1982
    Date of Patent: November 22, 1983
    Assignee: Giprokox
    Inventors: Evgeny P. Likhogub, Stanislav S. Sergeev, Alexandr N. Minasov
  • Patent number: 4409067
    Abstract: A column of hot coke from a shaft furnace moves downwardly into a vessel which it fills and forms a pile. A gap is left between the angle of repose of the coke surface and the upper portion of the vessel. Water is sprayed onto hot coke as it enters the vessel. The gap is vented to an exhaust duct. A baffle near the center of the vessel deflects the material to the sides and creates a void in the center of the vessel, which void is also vented to the exhaust duct. More water is sprayed on the coke adjacent the void. Steam pressure in the vessel is reduced by a fan which pulls steam through the exhaust ducts. The steam pressure is regulated by a pressure controller which modulates a damper in the exhaust duct. A temperature controller regulates the flow of quench water to the vessel. This regulates the temperature and moisture content of the material being cooled.
    Type: Grant
    Filed: May 5, 1982
    Date of Patent: October 11, 1983
    Assignee: Peabody Coal Company
    Inventor: Jimmy B. Smith
  • Patent number: 4407699
    Abstract: A process and apparatus for the dry cooling of coke involves the provision of a vessel having therein first and second zones in full communication with each other. Hot coke from a coking operation is introduced into the first zone and is passed through the first and second zones. Raw coke oven gas from the coking operation is introduced into the first zone, thereby reducing the temperature of the coke, while cleaning the raw coke oven gas to form cleaned coke oven gas. The cleaned coke oven gas is removed from the first zone, cooled, and then directly or indirectly utilized as a heat carrier gas introduced into the second zone to therein further reduce the temperature of the coke. The thereby further cooled coke is removed from the second zone.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: October 4, 1983
    Assignee: Didier Engineering GmbH
    Inventors: Claus Flockenhaus, Dietrich Wagener, Erich Hackler, Stefan Smieskol, Manfred Galow, Joachim Meckel, Dieter Breidenbach
  • Patent number: 4406746
    Abstract: In a coke dry shaft cooler having a smaller receiving chamber, and therebelow, a larger cooling chamber, a wear-resistant inward projection is provided at the transition between the two chambers to overcome difficulties caused by uneven particle distribution within the cooler.
    Type: Grant
    Filed: February 5, 1982
    Date of Patent: September 27, 1983
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventors: Wilhelm Danguillier, Jurgen Tietze, Wolfgang Grams, Heinz Thubeauville
  • Patent number: 4396461
    Abstract: A process for quenching hot coke in a one-spot coke quench car. The process utilizes a unique arrangement of pipes and spray nozzles to quench the hot coke in a substantially watertight coke quench car having a sloping bottom. A plurality of pipes are directed downwardly from a header mounted on the bench side of the quench car to provide solid streams of water onto the shallow coke bed portion at the top of the sloped bottom for a portion of the quench period. After an initial period a flow of water from a plurality of spray nozzles mounted on additional headers is directed onto the substantially horizontal deep coke bed portion for the remainder of the quenching period. The unvaporized quench liquid is retained in the watertight car until the completion of the quench cycle when it is rapidly drained away.
    Type: Grant
    Filed: August 3, 1981
    Date of Patent: August 2, 1983
    Assignee: Bethlehem Steel Corporation
    Inventors: Victor A. Neubaum, deceased, S. Robert Schwartz, Robert C. Fetterman, William E. Swan, Jr.
  • Patent number: 4389283
    Abstract: An improved method and apparatus for making coke wherein the coal is heated by the walls of a multi-cell chamber means and wherein said walls are heated by electric induction in the absence of air; the raw gases from the coal are directed to a by-product plant. The coal is introduced into said chamber means and the coke is discharged from said chamber means in such a way as to provide positive displacement of both the coal and the coke to overcome the sticking and bridging properties of the coal and the coke within said chamber means. Also improved provisions are included for insuring the sealing of said chamber means while operating said chamber means under a positive pressure in order to increase the efficiency of the conversion of coal to coke without causing pollution. The coal, after being coked, is quenched to a temperature below its ignition point before being exposed to the atmosphere to prevent it from burning in order not to cause pollution nor lose yield.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: June 21, 1983
    Inventor: Albert Calderon
  • Patent number: 4371425
    Abstract: Coke is dry cooled in a shaft-like cooler by gases conveyed through the coke. The cooler comprises a top antechamber below a charging opening, a cooling chamber under the antechamber and having a gas inlet and a coke outlet at the bottom end. Between the antechamber and the cooling chamber, there is a cylindrical wall having a gas inlet. The cooling chamber is divided by radial walls which abut a central masonry core and divide the chamber into three shaft-like chambers to insure uniform descending of the coke. A prop is placed at the center of each component shaft for deflecting the descending coke from a central region. Cooling gas is supplied through a pipe having a downwardly-directed opening below a central masonry core. Additional cooling gas is supplied by an annular chamber surrounding a cone at a coke outlet of the cooling chamber.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: February 1, 1983
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventors: Wilhelm Danguillier, Wolfgang Grams, Jurgen Tietze
  • Patent number: 4370202
    Abstract: A coke cooler and method of operating the cooler is disclosed for dry cooling hot glowing coke through the recovery of the sensible heat of the hot glowing coke. The apparatus includes a vertically elongated vessel having walls partially formed with integral heat exchange tubes for the passage of a liquid coolant and a shroud having an internal prechamber mounted in the upper end of the vessel for receiving a charge of the hot glowing coke. The shroud cooperates with the vessel to provide a annular passage for fluid flow therebetween of a gas which directly contacts the hot glowing coke for direct cooling while liquid coolant is passed through the tubes for indirectly cooling the coke.
    Type: Grant
    Filed: November 19, 1980
    Date of Patent: January 25, 1983
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4366026
    Abstract: In the continuous production of coke or semicoke from coal grains and/or fines an inclined air-tight rotating tubular oven is fed with coal grains and/or fines from a hopper. As the coal grains and/or fines progress down the rotating oven they are heated by a stoichiometric mixture from a burner and converted into coke or semicoke having a volatile content of from 1% to 20%. During the heating of the coal grains and/or fines the interior of the oven is maintained under a slightly elevated pressure in relation to the atmosphere. The coke or semicoke is then extracted from the oven and passed to an extinguishing device where the coke or semicoke is extinguished to prevent recombustion.
    Type: Grant
    Filed: October 16, 1981
    Date of Patent: December 28, 1982
    Assignee: Hoilleres du Bassin de Larraine
    Inventor: Gustave Leyendecker
  • Patent number: 4358345
    Abstract: An arrangement for feeding glowing coke has a cooling shaft into which coke and cooling gas are received, a coke transporting container arranged on the shaft and having a closable bottom opening, and a closing device arranged in the cooling shaft below the coke transporting container and including a housing sealed from atmosphere, and a closing plate which is raisable and lowerable and also displaceable in substantially horizontal direction in the housing.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: November 9, 1982
    Assignee: Krupp-Koppers GmbH
    Inventor: Johannes Lorrek
  • Patent number: 4358343
    Abstract: Preheated bulk material capable of coking is quenched by flowing the quenching liquid through the loose bulk material, whereby the bulk material is substantially closed off relative to the atmosphere. The liquid is applied to the top of the bulk material in a quenching chamber which is closed at its top by a sealed cover and which has an open grating for a horizontal bottom. The steam formed by the quenching liquid and, if formed, any excess quenching liquid are drawn off from the quenching chamber through the open grating. The total quantity of quenching liquid to be supplied as a function of time is controlled by a valve through a control signal depending on the chemical and physical properties constituting bulk material characteristics prior to the heating of the coal. The control signal also takes into account the type of the intended heat treatment in the form of quenching characteristics.
    Type: Grant
    Filed: January 18, 1982
    Date of Patent: November 9, 1982
    Assignee: Hartung, Kuhn & Co. Maschinenfabrik GmbH
    Inventors: Franz Goedde, Rudolf Redlich, Johann Riecker
  • Patent number: 4354903
    Abstract: A three-cycle process as disclosed for drying and preheating coking coal using the heat from cooled coke. Cooling gas is passed over hot coke to heat the cooling gas and cool the coke. The heated cooling gas is then passed through a waste heat boiler and then back to the hot coke in a coke cooling chamber. This completes the first closed cycle. Water is supplied to the waste heat boiler to form steam. The steam is supplied to a fluidized bed of wet coal to indirectly preheat and dry the wet coal in a second cycle. The wet coal is fluidized using fluidizing gas which converts water in the wet coal into steam. Some of the steam is condensed from the combination of fluidizing gas plus steam and then the fluidizing gas is returned to the bed. Steam from the waste heat boiler is also supplied to the fluidizing gas before it re-enters the bed to heat the fluidizing gas.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: October 19, 1982
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4352720
    Abstract: The process for the production of molded metallurgical coke from dried coal or fine coal mixtures with a low swelling index particularly highly volatile fine coal comprises mixing normal washed fine coal or fine coal mixtures of a grain size of from 0 to 10 mm and a swelling index of not more than 5 with a binder, pressing the mixture into briquettes, oxidizing the briquettes in a continuous material flow stream, and coking the oxidized briquettes continuously in an oven chamber by supplying indirectly and exhausting the coke oven gases with a temperature of 300.degree. to 1200.degree. C.
    Type: Grant
    Filed: October 27, 1980
    Date of Patent: October 5, 1982
    Assignee: Firma Carl Still GmbH & Co., KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Klaus Urbye
  • Patent number: 4344822
    Abstract: A process for quenching hot coke in a one-spot coke quench car. The process utilizes a unique arrangement of pipes and spray nozzles to quench the hot coke in a substantially watertight coke quench car having a sloping bottom. A plurality of pipes are directed downwardly from a header mounted on the bench side of the quench car to provide solid streams of water onto the shallow coke bed portion at the top of the sloped bottom for a portion of the quench period. After an initial period a flow of water from a plurality of spray nozzles mounted on additional headers is directed onto the substantially horizontal deep coke bed portion for the remainder of the quenching period. The unvaporized quench liquid is retained in the watertight car until the completion of the quench cycle when it is rapidly drained away.
    Type: Grant
    Filed: October 31, 1979
    Date of Patent: August 17, 1982
    Assignee: Bethlehem Steel Corporation
    Inventors: S. Robert Schwartz, William E. Swan, Jr., Robert C. Fetterman, Victor A. Neubaum, deceased
  • Patent number: 4342622
    Abstract: In a formed coke process of the type in which carbonization and calcination of coal is carried out prior to briquetting, the hot calcined char is cooled by means of a hydrogen-rich gas at superatmospheric pressure so as to effect concurrent cooling and desulfurization of the char. High sulfur coal containing 1.5 to 4 wt. % sulfur can be used while obtaining a char and a formed coke product with a sulfur content of 0.8 wt. % or less. The cooling can be done in two stages: (1) a first stage in which sulfur removal and cooling to a temperature not lower than about 800.degree. F. are accomplished with a hydrogen-rich gas, and (2) a second stage in which further cooling to about 200.degree. F. or less is accomplished with an inert gas.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: August 3, 1982
    Assignee: Inland Steel Company
    Inventor: Michael O. Holowaty
  • Patent number: 4338160
    Abstract: A plant for pre-heating by fluidizing and for milling coking coal in a treatment chamber is combined, by means of heat a exchanger interposed in a circuit for recirculating heat-conveying gas, with a plant for the dry quenching of hot coke in a quenching chamber. The flow, through the heat exchanger, of recycled quenching fumes of the coke is regulated in dependence on the rate at which the coal is introduced into the treatment chamber by a screw conveyor. An auxiliary heat combustion chamber permits precise control of the temperature in the treatment chamber.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: July 6, 1982
    Assignee: Charbonnages de France
    Inventors: Serge Delessard, Roger M. Puff
  • Patent number: 4338161
    Abstract: An apparatus and arrangement is disclosed for cooling glowing coke in a dry circuit which utilizes a cooling chamber divided by cooling walls into a plurality of parallel vertically extending cooling channels. The cooling walls are supplied with a cooling medium for indirectly cooling the glowing coke. A coke discharge mechanism in the form of a chute having a comb-like end and paddle wheels between the teeth of the comb is provided at the bottom of each cooling channel to discharge coke from the cooling chamber in a controlled fashion to an underlying after-chamber. Each cooling channel is provided with cooling gas for directly cooling the glowing coke. An arrangement utilizing the apparatus supplies cooling gas directly to the cooling channels which, after passing out of the cooling chamber, passes into a waste heat boiler which is supplied with water so that it is heated by the now hot cooling gas to produce steam.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: July 6, 1982
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4328072
    Abstract: Continuous dry quenching of coke is carried out with an inert gas circulated through hot coke in a vertical chamber and through a heat exchanger. The vertical chamber comprises a top prechamber below a charging opening and a quenching chamber which is below the prechamber. The quenching chamber has a bottom gas entry and a bottom coke discharge. A gas exit between the prechamber and the quenching chamber supplies gas to the heat exchanger. A gas entry and/or a gas exit communicating with the top of the prechamber is used to control the flow of gas so that the temperature of the gas removed from the vertical chamber remains constant during quenching operations when there is a disturbance to the flow of coke.
    Type: Grant
    Filed: November 30, 1979
    Date of Patent: May 4, 1982
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventors: Erich Pries, Heinz Thubeauville
  • Patent number: 4322269
    Abstract: A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculating to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate-water mixture is suitable for reuse as the condensation spray water.
    Type: Grant
    Filed: May 14, 1981
    Date of Patent: March 30, 1982
    Assignee: Didier Engineering GmbH.
    Inventors: Dietrich Wagener, Claus Flockenhaus, Manfred Blase
  • Patent number: 4317703
    Abstract: A pyrolysis process and system produces a solid residue and a clean, enriched fuel gas. In the process, the pyrolytic oil and filter cake are recycled in such a manner as to produce products of optimal value, and to minimize the need for servicing and downtime of the system. Recycling of water recovered in the process may also be employed to achieve enrichment of the gaseous product. The process may be carried out in such a manner as to produce a non-polluting wastewater stream that can be discharged directly from the system.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: March 2, 1982
    Assignee: American Can Company
    Inventors: Mack D. Bowen, Kenneth R. Purdy
  • Patent number: 4312712
    Abstract: A coke car is moved along a battery of coke ovens to a location for receiving coke from an oven chamber while the car is stationary and for moving to beneath a quenching tower. The coke car includes a generally square box-like container having side walls sealed with a floor that is pivoted about a horizontal axis to bear against seal members. The horizontal axis is spaced from the wall of the car adjacent the coke bench by a distance less than the distance between the axis and the wall of the car adjacent the oven platform. The seal members are disposed on the top of part of the floor which moves away from a side wall during pivotal movement and seal members are disposed on the bottom of a floor part which moves upwardly along a wall of the container during pivotal movement.
    Type: Grant
    Filed: May 19, 1980
    Date of Patent: January 26, 1982
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventors: Hans-Jurgen Kwasnik, Hans-Gunter Piduch
  • Patent number: 4312711
    Abstract: A quenching car comprises an open-topped body arranged to carry a load to be quenched. At least a part of the body is composed of walls of hollow construction to receive a liquid cooling medium, such as water. The hollow walls comprise inner and outer plate-like layers separated by reinforcing members which lie internally of the hollow walls, whereby the exposed surfaces of the inner and outer layers are substantially smooth and self-draining. The body is supported by girders of box-section extending along the length of the car.
    Type: Grant
    Filed: December 5, 1979
    Date of Patent: January 26, 1982
    Assignee: Norcros Investments Limited
    Inventors: Arthur Brown, Kevin F. Murray
  • Patent number: 4310386
    Abstract: A method of and an apparatus for the dry quenching of coke comprises a band conveyor upon which the coke is transported continuously in a relatively thin layer and enclosed at least in part by a vault of quartz or other heat-transfer material which is sprayed upon its face turned away from the coke with water to produce steam which is continuously removed and used directly or indirectedly as a source of heat.
    Type: Grant
    Filed: June 9, 1978
    Date of Patent: January 12, 1982
    Assignee: Siderurgie Maritime (Maritieme Staalnijverheid) SIDMAR S.A.
    Inventor: Theophile Martens
  • Patent number: 4308102
    Abstract: Flue gas discharged from a recuperator or regenerator of a coke oven battery has the steam thereof removed by means of a direct or indirect cooling and condensation operation. After the steam is removed from the flue gas it is then passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the flue gas. The flue gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the flue gas passes only once through the system. When the temperature of the flue gas as received from a coke oven battery is extremely high, then the flue gas may be subjected to a partial cooling operation prior to the cooling and condensation operation.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: December 29, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4306941
    Abstract: A dry coke quenching process comprises the steps of preheating a coke from a coke oven to a temperature of not lower than 1200.degree. C. by way of burning over its layer a combustible gas mixed with heated air, cooling the coke first to a temperature of not lower than 700.degree. C. with a mixture of hydrocarbons and water vapor, and then with an inert gas to a temperature of from 200.degree. to 250.degree. C.An apparatus for effecting the process of the invention comprises a chamber lined from inside with refractory brick and provided with a means for introducing a combustible gas and heated air to the upper part of the chamber and for discharging combustion gases therefrom. Provided in the middle part of the chamber are means intended for a heated mixture of hydrocarbons and water vapor to pass in therethrough and for a flow of the resultant gas containing hydrogen and carbon monoxide to escape therethrough.
    Type: Grant
    Filed: July 8, 1980
    Date of Patent: December 22, 1981
    Inventors: Vasily E. Privalov, Ivan G. Zubilin, Zoltan-Ivan I. Todavchich, Nikolai K. Kulakov, Adolf N. Silka, Alexandr N. Minasov, Mikhail G. Ananievsky, Naum E. Temkin, Vyacheslav I. Solodkov
  • Patent number: 4294663
    Abstract: A method of quenching coke and scrubbing the resulting gases is disclosed in which a supply of hot coke is placed in an enclosed tower having an open top and subjected to water deposited on it from above. The water is first passed through at least one layer of a liquid gas contact body formed of corrugated sheets of material arranged with the corrugations in each adjacent sheet crossing each other. This water passes in countercurrent relation to the gases rising from the quenched coke and, as a result, particulate matter, liquid drops and water-soluble vapors in the gases are removed in the contact body. The gases passing from the contact body are then passed through a mist-eliminator structure to remove water droplets therefrom.
    Type: Grant
    Filed: June 18, 1980
    Date of Patent: October 13, 1981
    Assignee: Munters Corporation
    Inventor: Richard P. Tennyson
  • Patent number: 4289584
    Abstract: A process for quenching hot coke discharged from an oven of a battery of coke ovens into a one-spot car. The process utilizes a unique arrangement of two sets of narrow angle spray nozzles to quench the coke. In addition to quenching the coke, one set of spray nozzles initially knocks down the peak portion of the coke pile and distributes the coke so that the exposed surface of the coke is substantially level. The quench liquid discharged through the narrow angle spray nozzles contacts about 50% to about 70% of the substantially level, exposed surface of the hot coke. Sufficient openings are provided adjacent the bottom of the one-spot car to drain the quench liquid to prevent the buildup of quench liquid in the quench car.
    Type: Grant
    Filed: December 3, 1979
    Date of Patent: September 15, 1981
    Assignee: Bethlehem Steel Corporation
    Inventors: David M. Chuss, James W. Scheirer
  • Patent number: 4289585
    Abstract: A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculating to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate-water mixture is suitable for reuse as the condensation spray water.
    Type: Grant
    Filed: January 16, 1980
    Date of Patent: September 15, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Manfred Blase
  • Patent number: 4288294
    Abstract: The present specification describes and claims a method and apparatus for use in cooling the solid residue of gasification of a reactor operated at a pressure above atmospheric for the gasification of carbonaceous materials. The residue of gasification is conducted out of the reactor into a cooling apparatus located therebelow and flows through the cooling apparatus from the top to the bottom thereof. A cooling liquid is introduced into the solid residue in the upper region of the cooling apparatus and is metered such that the greater portion of the heat contained in the residue is eliminated in the form of heat of vaporization, sensible heat and chemical binding energy with the resultant steam and reaction products produced. The remaining residual heat which corresponds to the difference between the desired final temperature and the temperature after cooling by the liquid, is eliminated by a gas blown into the bottom region of the cooling apparatus and/or by indirect heat exchange.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: September 8, 1981
    Inventor: Gunter Velling
  • Patent number: 4287023
    Abstract: A fixed fluidized particulate solids bed heat recovery vessel or steam generator having indirect heat exchange means within a bed of fluidized carbonaceous solids, such as coke, pelleted carbon black and the like, and introduction of a gas containing entrained solids to effect fluidization of the bed of carbonaceous solids wherein in a preferred embodiment, the reaction effluent from a carbon black reaction zone comprising carbon black suspended in a non-oxidizing gas is preferably quenched, e.g., using water and/or cooled recycled reaction effluent and is then further cooled using a fluidized fixed bed of carbonaceous solids having a cooling coil within the fluidized bed.
    Type: Grant
    Filed: August 23, 1979
    Date of Patent: September 1, 1981
    Assignee: Phillips Petroleum Co.
    Inventor: William T. Cooper
  • Patent number: 4285772
    Abstract: A low pollution, high yield system for receiving and cooling a hot charge of coke from a coke oven comprising aligning the open end of an otherwise closed coke box having its cross section, volume and surface area substantially equal to that of a charge of coke with the discharge end of a coke oven, pushing the coke directly into the coke box, enclosing the coke within the coke box to substantially isolate the coke from atmospheric oxygen and external cooling media, indirectly cooling the coke within the coke box by passing a cooling medium over the exterior surfaces of the coke box and discharging the cooled coke from the coke box. In a preferred embodiment the coke box is constructed of thin sheet metal panels supported by but not rigidly attached to a support structure and equipped with a cooling water reservoir/metering system for cooling the exterior surfaces of the box from the time the coke is pushed into the box.
    Type: Grant
    Filed: January 23, 1980
    Date of Patent: August 25, 1981
    Inventor: Edward S. Kress
  • Patent number: 4284476
    Abstract: A heat carrier gas is passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the heat carrier gas. The heat carrier gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the heat carrier gas passes only once through the dry cooling plant and the coal drying and preheating plant. The heat carrier gas may be a flue gas which is passed directly to the coke dry cooling plant without any preliminary pretreatment, and preferably is a flue gas which is supplied directly from a regenerator or recuperator of a coke oven battery. Alternatively, the heat carrier gas may be in the form of a fuel gas which is inert with respect to the hot coke, for example a waste gas or stack gas supplied from an adjacent metallurgical installation, such as a steel mill.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: August 18, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4282069
    Abstract: A coke dry quenching apparatus comprises a vertical chamber in the lower portion of which is disposed a quenching gas feeding means. The chamber has in its roof a charging hole and in its bottom a discharging gate. In the walls of the chamber is disposed a plurality of peripheral gas conduits communicated with the inner space of the chamber and with an annular collector having a common gas withdrawal conduit. According to the invention the hollow of the collector is divided by a horizontal partition provided with ports into two cavities communicating with one another, the lower cavity being communicated with the peripheral gas conduits and the upper one with the common gas withdrawal conduit.Due to the fact that the pressure of quenching gas in the lower cavity of the collector is equalized, the proposed apparatus ensures that the quenching gas flow rate through all the peripheral gas withdrawal conduits is practically equal, which provides for a uniform cooling of the whole mass of the coke being treated.
    Type: Grant
    Filed: July 22, 1980
    Date of Patent: August 4, 1981
    Inventors: Alexandr N. Minasov, Evgeny P. Likhogub, Vasily S. Kononenko