Abstract: Processes for pyrolyzing hydrocarbonaceous material are provided. A process for pyrolyzing hydrocarbonaceous material includes charging a reactor with a feed material comprising hydrocarbonaceous material, heating the feed material, and collecting liquid product from the reactor which is anaerobic in operation. At least 5% of the organic carbon atoms which are not present in an aromatic ring of a compound of the feed material are present in an aromatic ring of a compound in a liquid portion of the product.

Abstract: This method of upgrading a biomass comprises: an upgrading step for performing upgrading treatment of a cellulose based biomass with an oxygen/carbon atomic ratio of at least 0.5, in presence of water and under a pressure of at least saturated water vapor pressure, and reducing said oxygen/carbon atomic ratio of said biomass to no more than 0.38, and a separation step for separating an upgraded reactant obtained from said upgrading step into a solid component and a liquid component.

Abstract: Various embodiments of a process for pyrolyzing hydrocarbonaceous material are provided. In one embodiment the process for pyrolyzing hydrocarbonaceous material includes charging a reactor with a feed material comprising hydrocarbonaceous material, heating the feed material, and collecting liquid product from the reactor which is anaerobic in operation. At least 5% of the organic carbon atoms which are not present in an aromatic ring of a compound of the feed material are present in an aromatic ring of a compound in a liquid portion of the product.

Abstract: A conventional method of pyrolytically decomposing plastic to make low-molecular compounds is poor in efficiency of use of energy due to high heating temperatures (at least 600° C. and 800° C. at maximum). The invention provides that a functional powder is heated to a predetermined temperature and pieces of plastic to be disposed are caused to be contacted with the heated powder, the functional powder including a powder which does in an aqueous solution state show alkalinity, and a photo-catalyst effect powder.

Abstract: For thermally treating waste and/or residual materials, in particular fiber glass, glass silk, glass wool and glass mat coated with organic materials, a drum (1) with embedded elements is used to make the materials circulate. In this drum the materials are heated up to a temperature at least equal to the carbonization and/or evaporation temperature of the coatings but lower than the softening temperature of the materials. The waste or residual materials are preferably increasingly disaggregated in the drum and are heated by a stream of hot gas which flows in the drum from the discharge side (11) to the inlet side (4) and has its highest temperature at the discharge side.

Abstract: An improved process for producing a formed activated coke for simultaneous desulfurization and denitrification, which includes passing a ground coal through a tubular or cylindrical carbonization retort by using a hot gas stream, to subject the coal to preliminary carbonization to obtain a semi-coke, adding a caking agent to the semi-coke and forming the mixture, subjecting the formed material to carbonization to obtain a formed coke, and transferring the formed coke from the top to the bottom of a vertical multi-tubular retort of indirect heating and cooling (cooling is optional) type that includes a distribution section, a heating section, an activation section and a cooling section (the distribution section and the cooling section are optional) arranged in this order (the distribution section is at the top), to activate the formed coke.

Abstract: An improvement is proposed in an anisotropically electroconductive adhesive composition comprising an insulating adhesive resin as a matrix and electroconductive carbon particles dispersed in the matrix used for electrically connecting oppositely facing electrode terminals on various kinds of electronic devices and circuit boards. Different from conventional spherical carbon particles, the conductive particles used here are carbon particles each having a plurality of projections on the surface as formed, for example, by the high-temperature calcination of spherical carbon particles blended with a tar or pitch. By virtue of the projections on the carbon particles, the electric connection formed by using the inventive adhesive composition is very reliable and durable even under adverse ambient conditions involving a high temperature, high humidity, vibrations and mechanical shocks by virtue of the anchoring effect by the projections.

Abstract: A two-step process for producing microspherical pitch or green coke particles having an average diameter of 30-200 .mu.m from finely divided petroleum or coal pitch having a softening point of 60.degree.-220.degree. C. and a fixed carbon content of 40-75 wt %. In the first step the material pitch is fluidized in the stream of a gas substantially inert to the pitch at a temperature of 100.degree.-800.degree. C., the mixed stream is rapidly cooled to 30.degree.-400.degree. C., and microspherical pitch particles are recovered with or without separate recovery of an oily product. In the second step the pitch spheres are further subjected to thermal cracking and polycondensation by use of a fluidized bed at a temperature of 350.degree.-520.degree. C. for a retention time of 1 min. to 3 hours, and microspherical green coke particles and a light cracked oil are recovered. In both steps a pressure between the ordinary level and 10 kg/cm.sup.2 is used.

Abstract: Coal fines developed from the processing of coal through a preheating system are accumulated in a secondary cyclone system. The coal fines, at an elevated temperature, are mixed with a hydrocarbon organic binder and compressed into larger particles of sufficient structural integrity and mass to be fed directly through pneumatic pressure coke oven coal charging lines without significant size reduction, resulting in the elimination of fine coal build-up in one coke oven standpipes and charging mains as well as overloading of the charging liquor system.

Abstract: Devolatizable fine-grained material which contains hydrocarbons is devolatilized by means of fine-grained solids which have been heated to temperatures of about 500.degree. to 1000.degree. C. The devolatilizable fine-grained material is mixed with the heated solids and is thus heated to temperatures of about 400.degree. to 900.degree. C. The mixture is passed through a dwell zone, and gaseous and vaporous devolatilization products are withdrawn and cooled. The heated solids are fed to the dwell zone as a loosened stream in a trickling and/or agitated state of motion, and the devolatilizable fine-grained material is introduced into said stream in order to be admixed thereto. The heated solids and the devolatilizable fine-grained material can be mixed in a weight ratio of 3:1 to 12:1. The stream of trickling heated solids can be deflected at least in part.

Abstract: The strength and density of a metallurgical coke produced in a slot coke oven are both increased by replacing at least a part of the normal loose charge in the oven with compacted materials and fragments thereof made from a mixture of particularly sized particulate fusible bituminous coal particles, non-fusible particles of a material compatible with the burden of a blast furnace, and water. During compacting the pressure and the moisture content of the mix are such that at least some water is squeezed out of the mix. The non-fusible materials that are useful include non-coking coals, poorly coking coals, other carbonaceous materials, such as coke breeze, char, anthracite, lignite, and iron oxide-bearing materials, such as iron ores and waste materials from steel plants. At least a major proportion of the fusible particles and at least a substantial proportion of the non-fusible particles are smaller than about 0.15 mm.

Abstract: A process for producing a distillable hydrocarbonaceous stream, fuel gases and blast furnace grade coke from a heavy, high sulfur, crude oil by producing delayed coke from at least a portion of the crude oil; crushing at least a portion of the coke to provide a finely divided coke feedstock to a briquetting operation where the finely divided coke is briquetted using crude oil or topped crude oil as a binder to produce briquettes of a size from about 3/4 inch to about 3 inches with the resulting briquettes being passed to a high temperature vertical calciner where the solids are desulfurized to produce a strong blast furnace grade coke. The distillable stream and fuel gas stream are recovered from the delayed coking operation, the vertical calciner and optionally a crude oil topping operation. In some instances coke particles in the size range from about 3/4 inch to about 3 inches may be passed directly to the calciner without crushing and briquetting.

Abstract: Production of coke from coal is improved by mixing self-feeding coal with compacted non self-feeding coal prior to carrying out the coking process. Preferably, there is about 10% to about 60% by weight of the non self-feeding coal based on the total charge. Binders may be used and it is preferred that the non self-feeding coal be preheated to approximately 150.degree. C. to 250.degree. C. prior to mixing. In the event that an aqueous emulsion is used as the binder, the preheating step may be omitted. Coke of superior abrasion resistance is obtained by the foregoing method.

Abstract: A method of reducing the sulfur content of coal, reduced to dust, by means of its own or external thermal energy and by means of rapid coking and/or rapid partial destructive distillation of the coal. The coal dust, which has been ground to less than 0.1 mm and, if necessary, preoxidized in 1 to 4 seconds at 350.degree. to 450.degree. C., is brought to a reaction temperature of 700.degree. to 1100.degree. C. This reaction temperature may be reached directly, either by means of carrier or heating gas heated to over 1000.degree. C., or by means of the partial combustion of the coal with air or oxygen, at heating rates greater than 20,000.degree. C./min. This reaction temperature may also be reached indirectly, at heating rates of less than 20,000.degree. C./min, by means of gaseous, liquid, or turbulent heating carriers. The coal dust is allowed to stand for 1 to 6 seconds at a pressure of 1 to 15 bar until the coke dust and gas which are produced separate from one another.

Abstract: A method of reducing the carbonization pressure in the coking of coal is provided which comprises randomly dispersing flakes through the coal, said flakes formed of a material that does not pass through a plastic phase such as pressed sawdust wherein the flakes have a thickness of between about 1/8" and about 3/4" and a length and width of between about 1" and about 5".

Abstract: Crushed oil shale is segregated into a major portion of relatively large particles and a minor portion of "fines," such as will pass through 1/8-inch screen openings. The large particles are subjected to retorting in an upflowing bed in countercurrent contact with a downflowing hot eduction gas, while the fines are fed onto and controllably transported across the hot planar surface of a free-standing truncated cone of spent shale at the top of the retort.

Abstract: A method of preheating coal for coking comprises bringing a hot operating gas into direct contact with the coal to preheat the coal. Both the coal and the operating gas are passed into a separator and the separator is operated so as to effect the separation of the coarse preheated coal for delivery to the coke oven from the operating gases and coal dust. The operating gases and coal dust are then passed into a deduster to remove the coal dust from the operating gases. A portion of the removed dust is continuously directed into an accumulator. The dust is either supplied from the deduster or the accumulator to a combustion furnace where it is burned to generate at least a portion of the operating gas.

Abstract: Bodies are press-molded from a mixture of particulate fuel and a binder. These bodies are heated to a temperature between about 600.degree.-900.degree. C. in a rotary furnace to degas them. The degassing is carried out without subjecting the bodies to mechanical stresses and without permitting combustion of the expelled volatile gases. The resulting shaped coke has a greatly improved abrasion resistance.

Abstract: A method of preparing coals for coking in a conventional coke oven includes agglomerating the loose coal, in combination with a binder, into flakes, mixing the flakes with non-agglomerated coal, and charging the mixture into the coke oven in the conventional manner. The method provides for the utilization in a conventional coke oven, of coals that are marginal in coking quality, greater bulk densities of the coal as charged into a conventional coke oven, acceptable shatter resistance and physical stability of the coke produced, and acceptable carbonization pressure on the coke oven walls.

Abstract: Bitumen-containing material is processed by distillation with a solid heat-carrier with subsequent gasification of the distillation residue and combustion of the gasification residue in an aerofountain furnace. During gasification, the formed flue gas and ash are heated and part of ash is used as the heat-carrier. The flue gas and ash are withdrawn from the process simultaneously in the form of their suspension in air, from which the heat-carrier is isolated for the distillation process, the consumption of the heat-carrier being controlled by withdrawing part of the suspension containing fine fraction of ash before the heat-carrier is isolated.

Abstract: Process for the preparation of a moulded coke according to which agglomerates are heated in a non-oxidizing atmosphere, this process being characterized in that the agglomerates are prepared by compression from a paste containing:from 60 to 85% by weight of non-cokable coals,from 10 to 30% by weight of agglutinating coalshaving a swelling index greater than 2, andfrom 5 to 13% by weight of binder,which paste, when heated at 6.degree. C. per minute in the ARNU dilatometer gives a contraction of between 3 and 15%, preferably between 5 and 10% and a swelling of zero or near 0, and in that the agglomerates are heated in a non-oxidizing atmosphere from a temperature of about 100.degree. C. to a temperature of at least about 700.degree. C., with a rate of heating of between 7 and 14.degree. C. per minute.

Abstract: Crushed oil shale is segregated into a major portion of relatively large particles and a minor portion of "fines" which will pass through screen openings up to about 1/4 inch in size. The large particles are subjected to retorting as an upflowing moving bed in countercurrent contact with downflowing hot eduction gas, while the fines are retorted by controlled distribution over the hot upper surface of the bed of retorted large particles.

Abstract: Essentially carbon free inorganic particles formed from the decarbonization of a carbon containing solid residue of pyrolysis of comminuted organic solid waste is employed as the prime heat source for the pyrolysis of the comminuted organic solid waste.

Abstract: Delayed coke especially manufactured for use in graphite can be effectively desulfurized by calcining in a hydrocarbon fuel-fired calciner in the temperature range of 2700.degree. F. to 2900.degree. F. without adversely affecting the strength of the coke or the coefficient of thermal expansion of the graphitized coke.

Abstract: In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source fed over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue.

Abstract: A plurality of different types of raw material coal fines are sieved to a size not exceeding 1.5 mm; said sieved raw material coal fines are blended so as to satisfy the following conditions:(a) AP index: 75 at the minimum,(b) Mean maximum reflectance: 1.20% at the minimum, and(c) A [dilatation] - [contraction] value of from -2 to +5% when carbonized under conventional conditions in a horizontal type coke oven battery at a heating rate of 5.degree. C/min. (350.degree. - 600.degree. C);said blended raw material coal fines thus obtained are mixed with a binder and formed to produce a formed coal; and then, said formed coal thus obtained is charged into a horizontal type coke oven battery and carbonized, whereby a high-strength formed coke for blast furnace is a slight mutual agglomeration is manufactured.

Abstract: With the use of low-fluidity blended raw material coal fines having a maximum fluidity of up to 20 d.d.p.m. as an inner core material, and coal fines having a maximum fluidity of at least 30 d.d.p.m. or a bituminous material having a C/H ratio of from 0.7 to 1.9 as an outer envelope material, green composite briquettes are formed by covering said inner core material with said outer envelope material. Said green composite briquettes thus formed are charged into a conventional coke oven battery and carbonized by an ordinary process, whereby a high-strength metallurgical formed coke in a slight mutual agglomeration is produced.

Abstract: The specification discloses apparatus and methods for recovery of coal fines and for recycling thereof incidental to a self-contained system for charging preheated coal into coke ovens. The apparatus enables a system for charging preheated coal into coke ovens to meet pollution control regulations. The apparatus comprises four circulating streams of liquid for carrying coal fines in a slurry, namely, the charge main liquor circuit, the excess recycle gas scrubber circuit, the charge line condenser circuit and the charge bin vent condenser circuit. The -28 mesh coal with the liquor from the various circuits goes to a clarifier or thickener. Floating fines from top and settled fines from the bottom of the thickener are pumped via a fines tank to filters from which the solid or coagulated fines are restored to the wet coal feed to the heaters.

Abstract: In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue and separating out the fines.

Abstract: A coke oven system is provided having a coke oven preferably with pipeline charging for converting coal into coke. Carryover fines are collected from the coke oven and preferably a preheater therefor, and then agitated by agitator means and the collected carryover fines thereby agglomerated. Preferably, the carryover fines are first mixed with water to form an aqueous mixture, and then agglomerated. The agglomerated carryover fines are then preferably separated from the aqueous mixture by separated means. The agglomerated carryover fines are preferably conditioned in dryer means and recirculated to the coke oven preferably through a preheater.

Abstract: Particulate organic solid waste is pyrolyzed in the presence of an inert particulate source of heat and a carrier gas in a pyrolysis reactor to form a carbon containing solid residue of pyrolysis, pyrolytic oils and gases. The particulate source of heat and carbon containing solid residue of pyrolysis are separated from the product stream. The particulate source of heat and carbon containing solid residue of pyrolysis are transported to a combustion zone where through partial or total combustion. The particulate source of heat is reheated to a temperature requisite for feed to the pyrolysis reactor with attendant generation of additional particulate source of heat.

Abstract: There is provided a system for segregating through comminution and classification solid waste into ferrous metal, inorganic, and organic fractions. The inorganic fraction is further classified into aluminum and glass fractions. The organic fraction is further comminuted, dried and fed to a pyrolysis system where it is converted to gas for use in drying the organic material for feed to the pyrolysis system, pyrolytic oils and char. The principal saleable products recovered are char, pyrolytic oils, glass, aluminum, and ferrous metal.

Abstract: An improved two-step fluid bed process for conditioning sized, agglomerative, high volatile bituminous coal is disclosed. The agglomerative bituminous coal is first crushed and sized for fluidization. A first treatment is conducted under oxidizing conditions at below the fusion temperature of the coal, preferably at about 600.degree. F., followed immediately by a second treatment under a non-oxidizing or inert atmosphere at preferably 800.degree. F. .+-.50.degree. F. The resulting oxidized and heat treated coal particles have a volatile content of at least 15% and are thereby rendered non-agglomerative when thereafter subjected to even higher temperatures, e.g., when making activated carbon and/or synthesis gas.

Abstract: A method of preconditioning agglomerating coal particles to substantially prevent agglomeration of a fluid-bed reaction zone in a reactor comprising preheating thd coal particles in dense phase flow, rapidly oxidizing the particles in a vertical standpipe having a regulated thermal environment, pressurizing the particles to a pressure above reactor pressure and introducing the preconditioned coal particles into the fluid-bed reactor zone at substantially reaction pressure for reaction at an elevated temperature and at reaction pressure in the presence of a reagent.

Abstract: Coal particles are heated and further particulized at a preheat stage employing a preheat gas. Some of the finer coal particles are puffed up by the preheating step. Most of the preheated coal particles are separated from the preheat gas, but some of the finer coal particles remain with the preheat gas. The coal particles separated from the preheat gas are oiled and eventually transported by a carrier gas through a pipeline into a coke oven. The preheat gas and the finer coal particles remaining therewith are separated from each other utilizing a wet scrubber at which the finer coal particles undergo flocculation. Oil vapor vented from the coal particles headed for the coke oven is directed to the wet scrubber to aid in the flocculating step. The flocculated coal particles are separated from the scrubber liquid in a flotation cell. The overflow from the flotation cell is filtered, and the filter cake comprising coal particles is employed as a fuel.

Abstract: A method and apparatus for removing oversized, unentrained char particles from a two-stage coal gasification process so as to prevent clogging or plugging of the communicating passage between the two gasification stages. In the first stage of the process, recycled process char passes upwardly while reacting with steam and oxygen to yield a first stage synthesis gas containing hydrogen and oxides of carbon. In the second stage, the synthesis gas passes upwardly with coal and steam which react to yield partially gasified char entrained in a second stage product gas containing methane, hydrogen, and oxides of carbon. Agglomerated char particles, which result from caking coal particles in the second stage and are too heavy to be entrained in the second stage product gas, are removed through an outlet in the bottom of the second stage, the particles being separated from smaller char particles by a counter-current of steam injected into the outlet.