Prior To Charging To Carbonizing Zone Patents (Class 201/6)
  • Patent number: 4624807
    Abstract: A two-step process for producing microspherical pitch or green coke particles having an average diameter of 30-200 .mu.m from finely divided petroleum or coal pitch having a softening point of 60.degree.-220.degree. C. and a fixed carbon content of 40-75 wt %. In the first step the material pitch is fluidized in the stream of a gas substantially inert to the pitch at a temperature of 100.degree.-800.degree. C., the mixed stream is rapidly cooled to 30.degree.-400.degree. C., and microspherical pitch particles are recovered with or without separate recovery of an oily product. In the second step the pitch spheres are further subjected to thermal cracking and polycondensation by use of a fluidized bed at a temperature of 350.degree.-520.degree. C. for a retention time of 1 min. to 3 hours, and microspherical green coke particles and a light cracked oil are recovered. In both steps a pressure between the ordinary level and 10 kg/cm.sup.2 is used.
    Type: Grant
    Filed: July 26, 1983
    Date of Patent: November 25, 1986
    Assignee: Fuji Standard Research Kabushiki Kaisha
    Inventors: Terukatsu Miyauchi, Yoneichi Ikeda, Takao Nakagawa, Toshio Tsutsui, Tatsuji Kikuchi
  • Patent number: 4559060
    Abstract: A upgrading method of low-rank coal containing higher ash and moisture contents into coal decreased in ash content and decreased in moisture content and heightened in heating value includes subjecting the low-rank coal to a low-temperature dry distillation treatment, pulverizing the dry-distilled low-rank coal to form a coal-water slurry and adding a binder to the slurry to effect oil agglomeration of the coal and promote separation of the ash.
    Type: Grant
    Filed: September 21, 1983
    Date of Patent: December 17, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Katsumi Muroi, Akio Yamamoto, Yoichi Nakamura, Toshihiko Takahashi, Morihisa Maruko
  • Patent number: 4557733
    Abstract: Green coal is charred in pre- and post- treatment carbonizers, then crushed, mixed with pitch, briquetted, tempered in a tempering oven, recirculated with succeeding green coal to char in a reducing atmosphere through only the latter part of the pre-treatment carbonizer and through the post-treatment carbonizer, cooled, and separated from the as yet unbriquetted char. The pre-treatment carbonization is characterized by having air updrafted through all the airbox zones under the travelling grate.
    Type: Grant
    Filed: November 5, 1984
    Date of Patent: December 10, 1985
    Assignee: Peabody Development Company
    Inventors: Jimmy B. Smith, Julian M. Liggett
  • Patent number: 4526731
    Abstract: An apparatus for drying pellets of particulate material such as carbon black is characterized by a columnar drying vessel containing inclined trays or screens positioned so that the pellets or particulates roll from screen to screen down the column. Preferably, the pellets are subjected to countercurrent flow of drying gases while flowing down the screens. In other aspects, carbon black is pelleted with a nonaqueous liquid pelleting fluid and dried with vapors of the same pelleting fluid.
    Type: Grant
    Filed: November 29, 1983
    Date of Patent: July 2, 1985
    Inventor: E. Webb Henderson
  • Patent number: 4452670
    Abstract: Coal fines developed from the processing of coal through a preheating system are accumulated in a secondary cyclone system. The coal fines, at an elevated temperature, are mixed with a hydrocarbon organic binder and compressed into larger particles of sufficient structural integrity and mass to be fed directly through pneumatic pressure coke oven coal charging lines without significant size reduction, resulting in the elimination of fine coal build-up in one coke oven standpipes and charging mains as well as overloading of the charging liquor system.
    Type: Grant
    Filed: June 9, 1980
    Date of Patent: June 5, 1984
    Assignee: Koppers Company, Inc.
    Inventors: Joseph E. Kovacic, Michael Perch, Bernard R. Kuchta
  • Patent number: 4419186
    Abstract: The strength and density of a metallurgical coke produced in a slot coke oven are both increased by replacing at least a part of the normal loose charge in the oven with compacted materials and fragments thereof made from a mixture of particularly sized particulate fusible bituminous coal particles, non-fusible particles of a material compatible with the burden of a blast furnace, and water. During compacting the pressure and the moisture content of the mix are such that at least some water is squeezed out of the mix. The non-fusible materials that are useful include non-coking coals, poorly coking coals, other carbonaceous materials, such as coke breeze, char, anthracite, lignite, and iron oxide-bearing materials, such as iron ores and waste materials from steel plants. At least a major proportion of the fusible particles and at least a substantial proportion of the non-fusible particles are smaller than about 0.15 mm.
    Type: Grant
    Filed: December 11, 1981
    Date of Patent: December 6, 1983
    Inventor: Fritz O. Wienert
  • Patent number: 4412841
    Abstract: Compacted carbonaceous shapes are produced by mixing a particulate carbonaceous material with a binder, forming green shapes from the mixture, and heating the green shapes by induction heating or microwave heating or a combination thereof. The process is particularly adapted for making formcoke.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: November 1, 1983
    Assignee: Inland Steel Company
    Inventors: William Du Broff, George H. Craig, Timothy A. Veslocki
  • Patent number: 4410472
    Abstract: A method for making spherical binderless pellets using a rotating drum mixer whereby at least a portion of the particles comprising the pellets is comprised of coking coal particles.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: October 18, 1983
    Assignee: Aluminum Company of America
    Inventors: Donald K. Grubbs, Andrew T. Kochanowski
  • Patent number: 4388152
    Abstract: A process for producing a distillable hydrocarbonaceous stream, fuel gases and blast furnace grade coke from a heavy, high sulfur, crude oil by producing delayed coke from at least a portion of the crude oil; crushing at least a portion of the coke to provide a finely divided coke feedstock to a briquetting operation where the finely divided coke is briquetted using crude oil or topped crude oil as a binder to produce briquettes of a size from about 3/4 inch to about 3 inches with the resulting briquettes being passed to a high temperature vertical calciner where the solids are desulfurized to produce a strong blast furnace grade coke. The distillable stream and fuel gas stream are recovered from the delayed coking operation, the vertical calciner and optionally a crude oil topping operation. In some instances coke particles in the size range from about 3/4 inch to about 3 inches may be passed directly to the calciner without crushing and briquetting.
    Type: Grant
    Filed: January 21, 1982
    Date of Patent: June 14, 1983
    Assignee: Conoco Inc.
    Inventors: George E. Wasson, Frank W. Theodore, Lyndon D. Boyer, Matthew C. Sooter
  • Patent number: 4385962
    Abstract: Production of coke from coal is improved by mixing self-feeding coal with compacted non self-feeding coal prior to carrying out the coking process. Preferably, there is about 10% to about 60% by weight of the non self-feeding coal based on the total charge. Binders may be used and it is preferred that the non self-feeding coal be preheated to approximately 150.degree. C. to 250.degree. C. prior to mixing. In the event that an aqueous emulsion is used as the binder, the preheating step may be omitted. Coke of superior abrasion resistance is obtained by the foregoing method.
    Type: Grant
    Filed: June 16, 1981
    Date of Patent: May 31, 1983
    Assignee: Ruhrkohle Aktiengesellschaft
    Inventors: Wilhelm Stewen, Wilhelm Weskamp
  • Patent number: 4356004
    Abstract: A process for forming charging fuel into agglomerates for the pressure gasification of coal, comprises the steps of mixing fine, granular charging fuel with a binder outside the pressure reactor, subjecting the mixture, in a pressure vessel, to the pressure prevailing in the reactor, and feeding agglomerates produced from the mixture to the fixed bed of the reactor from above. The mixture is made with a binder which hardens when heated and is kept below hardening temperature during subsequent subjection to pressure until fed to the reactor, the agglomerates being produced by hardening of the binder in the heat prevailing in the reactor above the fixed bed.
    Type: Grant
    Filed: July 7, 1980
    Date of Patent: October 26, 1982
    Inventor: Artur Richter
  • Patent number: 4354903
    Abstract: A three-cycle process as disclosed for drying and preheating coking coal using the heat from cooled coke. Cooling gas is passed over hot coke to heat the cooling gas and cool the coke. The heated cooling gas is then passed through a waste heat boiler and then back to the hot coke in a coke cooling chamber. This completes the first closed cycle. Water is supplied to the waste heat boiler to form steam. The steam is supplied to a fluidized bed of wet coal to indirectly preheat and dry the wet coal in a second cycle. The wet coal is fluidized using fluidizing gas which converts water in the wet coal into steam. Some of the steam is condensed from the combination of fluidizing gas plus steam and then the fluidizing gas is returned to the bed. Steam from the waste heat boiler is also supplied to the fluidizing gas before it re-enters the bed to heat the fluidizing gas.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: October 19, 1982
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs
  • Patent number: 4352720
    Abstract: The process for the production of molded metallurgical coke from dried coal or fine coal mixtures with a low swelling index particularly highly volatile fine coal comprises mixing normal washed fine coal or fine coal mixtures of a grain size of from 0 to 10 mm and a swelling index of not more than 5 with a binder, pressing the mixture into briquettes, oxidizing the briquettes in a continuous material flow stream, and coking the oxidized briquettes continuously in an oven chamber by supplying indirectly and exhausting the coke oven gases with a temperature of 300.degree. to 1200.degree. C.
    Type: Grant
    Filed: October 27, 1980
    Date of Patent: October 5, 1982
    Assignee: Firma Carl Still GmbH & Co., KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Klaus Urbye
  • Patent number: 4342622
    Abstract: In a formed coke process of the type in which carbonization and calcination of coal is carried out prior to briquetting, the hot calcined char is cooled by means of a hydrogen-rich gas at superatmospheric pressure so as to effect concurrent cooling and desulfurization of the char. High sulfur coal containing 1.5 to 4 wt. % sulfur can be used while obtaining a char and a formed coke product with a sulfur content of 0.8 wt. % or less. The cooling can be done in two stages: (1) a first stage in which sulfur removal and cooling to a temperature not lower than about 800.degree. F. are accomplished with a hydrogen-rich gas, and (2) a second stage in which further cooling to about 200.degree. F. or less is accomplished with an inert gas.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: August 3, 1982
    Assignee: Inland Steel Company
    Inventor: Michael O. Holowaty
  • Patent number: 4318779
    Abstract: Blast furnace coke containing low grade coal in a high blending ratio is manufactured by a method which comprises blending not less than 60% of a blended coal having an adjusted total moisture content of not more than 4% with not more than 40% of briquettes and carbonizing the resultant mixture.The blended coal consists essentially of not less than 80% of coking coal and not more than 20% of low grade coal. When coking coal of a kind which has its coking property segregated according to its grain size distribution is pulverized and classified by sifting and the portion of fine particles is used as mixed with the coking coal, the blending ratio of the low grade coal in the blended coal can be increased to up to 35%. The briquettes consist essentially of not less than 10% of coking coal and not more than 90% of low grade coal.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: March 9, 1982
    Assignees: Sumikin Coke Company Ltd., Sumitomo Metal Industries Limited
    Inventors: Michio Tsuyuguchi, Keiji Kubo, Hiromichi Takahashi
  • Patent number: 4305788
    Abstract: The process for the production of molded metallurgical coke from dried coal or fine coal mixtures with a low swelling index particularly highly volatile fine coal comprises mixing normal washed fine coal or fine coal mixtures of a grain size of from 0 to 10 mm and a swelling index of not more than 5 with a binder, pressing the mixture into briquettes, oxidizing the briquettes in a continuous material flow stream, and coking the oxidized briquettes continuously in an oven chamber by supplying indirectly and exhausting the coke oven gases with a temperature of 300.degree. to 1200.degree. C.
    Type: Grant
    Filed: March 28, 1980
    Date of Patent: December 15, 1981
    Assignee: Firma Carl Still GmbH & Co KG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Klaus Urbye
  • Patent number: 4288293
    Abstract: In the fluidized carbonization and calcination of coal to form a reactive coal calcinate for admixture with bituminous binder for briquetting, curing, and coking to produce form coke, the improvement of recovering medium BTU gases in the overheads by using as the fluidizing medium oxygen diluted with steam or carbon dioxide and removing the steam or carbon dioxide from the overheads.
    Type: Grant
    Filed: April 14, 1980
    Date of Patent: September 8, 1981
    Assignee: FMC Corporation
    Inventor: Erik Saller
  • Patent number: 4282066
    Abstract: Coal, either as coal fines or as coal briquettes, is introduced into a coking chamber and is thereat exposed to microwave radiation to transform the coal into hot coke. Preferably, the microwave radiation is at a frequency of from twenty to 3000 MHz. The hot coke is then passed to a cooling zone whereat photocells absorb radiant energy from the hot coke and transform the thus absorbed radiant energy into electricity.
    Type: Grant
    Filed: March 22, 1979
    Date of Patent: August 4, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Horst Fach, Hayri Ergun
  • Patent number: 4272323
    Abstract: Briquettes, particularly molded briquettes of pitch-bound coal, are formed and introduced into a coking chamber of an indirectly heated chamber oven. The oven is then operated to form the briquettes into coke. Prior to the introduction of the briquettes into the chamber, the interior walls of the chamber are uniformly heated to a temperature t.sub.K .congruent.1000+[1000B-175].times.[1.23+0.1283(W-3)], wherein: B equals the width (in meters) of the coking chamber, and W equals the initial water content (in weight %) of the briquettes.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: June 9, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Robert Tettweiler, Hayri Ergun
  • Patent number: 4272322
    Abstract: A method of manufacturing charcoal comprising the steps of mixing at least one kind of material selected from the group including coffee pulps, almond husks, orange peelings, walnut shells and bean jam waste etc. with paper sludge, molding the resultant mixture in any desired configuration, and then allowing the resultant moldings to subject to dry distillation at a temperature of about 300.degree. to 600.degree. C.An apparatus for carrying out the abovementioned method comprising a double-walled housing including an inner wall and an outer wall the space between the inner and outer walls being filled with water, the space surrounded by the double-walled housing being divided by a partition wall extending to a predetermined height from the base of the housing into a combustion chamber and a carbonization chamber.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: June 9, 1981
    Inventor: Masahiro Kobayashi
  • Patent number: 4268417
    Abstract: Activated carbon is made by forming a slurry of carbonaceous and non-carbonaceous fine particles, preferably finely divided non-caking coal, in a suspension liquid, preferably water, comprised of at least 60 percent suspension liquid by weight. Preferably, the geometric mean particle size of the fine particles dispersed in the suspension liquid is less than 150 microns. A free-flowing liquid, which is liquid below 80.degree. C. and preferably below 20.degree. C., lyophobic to the suspension liquid and the non-carbonaceous fine particles and lyophilic to the carbonaceous fine particles, is added to the slurry to form a mixture where less than 20 percent by weight of the free-flowing liquid and the carbonaceous and non-carbonaceous fine particles is free-flowing liquid. The resulting mixture is then agitated to preferentially agglomerate the carbonaceous fine particles to form discrete agglomerates, while the non-carbonaceous fine particles remain substantially unagglomerated in the slurry.
    Type: Grant
    Filed: March 7, 1979
    Date of Patent: May 19, 1981
    Assignee: American Minechem Corporation
    Inventor: Leonard Messer
  • Patent number: 4263100
    Abstract: A method reducing fine dust emission during the time that predried and preheated coal is charged into coke ovens comprises directing wet coal to be carbonized into direct contact with a hot process gas so that the coal is transported dry and heated, directing the hot process gas with the heated coal to a plurality of different separators in succession with the first separator being set to separate only around from 80 to 90% of the total amount of the coal and without separating the fine dust, and a subsequent separator separate the remaining amount of the solid matter including the fine dust, compacting the dust removed from all of the separators and mixing them together, and charging the compacted mixed dust into the coke oven. The apparatus for effecting the invention includes a material separator which is designed as a gravity separator or gravity sifter which is arranged to discharge into a connection between the mixed and compacted dust separator in separate additional separators.
    Type: Grant
    Filed: September 20, 1979
    Date of Patent: April 21, 1981
    Assignee: Firma Carl Still GmbH & Co. KG.
    Inventors: Dieter Stalherm, Janos Bocsanczy
  • Patent number: 4259157
    Abstract: Abrasion-proof coke forms are produced from bituminous coal, brown coal, or peat in the form of briquets, by preheating the briquets, dehydrating or predrying them, carbonizing them and then cooling them in at least three separate stages in which the briquets are dehydrated indirectly by subjecting them to indirect temperature conditions, producing a temperature gradient in the briquets. The briquets are automatically fed into a shaft tower which includes an upper drying shaft portion made up of a plurality of stacked radiators which include tube elements for the passing of a heating fluid, such as steam, therethrough and which define vertical shaft passages through which the briquet forms are passed downwardly and into a carbonizing shaft which has separate gas channels for directing heating gases therethrough and to a heating flue and which subsequently includes a lower cooling zone through which the briquets pass and then into a discharge channel where they are delivered for classification.
    Type: Grant
    Filed: April 17, 1979
    Date of Patent: March 31, 1981
    Assignees: Firma Carl Still GmbH & Co. KG, Rheinische Braunkohlenwerke Aktiengesellschaft
    Inventors: Kurt Lorenz, Horst Dungs, Hans B. Koenigs, Roman Kurtz
  • Patent number: 4259158
    Abstract: A method of producing abrasion resistant coke from brown coal briquets in a shaft furnace comprises charging the coke briquets into the top of the furnace and removing coke from the bottom of the furnace while directing inert hot combustion gases into the furnace and through the briquets at a plurality of vertically spaced levels throughout the height of the shaft furnace. Gases are directed at temperatures to effect and successively lower stages of the furnace the preheating, predrying, carbonization, and cooling of the charge.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: March 31, 1981
    Assignees: Firma Carl Still GmbH & Co. KG, Rheinische Braunkohlenwerke AG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Roman Kurtz, Hans-Joachim Kersting
  • Patent number: 4248669
    Abstract: The present invention is an improvement in the known process of making a coking feedstock from non-caking or weakly caking coals for slot-type coke ovens wherein the coal is subjected to solvent extraction; and at least the non-distillable extract in the effluent slurry product, after removal of part or all of the solvent, is mixed with carbonaceous solids to serve as a binder therefor. The improvement resides in the use of fluidizer char (which is produced by the low temperature carbonization of coal in a fluidized bed) as the carbonaceous solids. The fluidizer char is preferably mixed with the coal extract slurry (after removal of solvent) in a liquid state at elevated temperatures under pelletizing and non-carbonizing conditions. The pelletized product, after cooling and crushing, is suitable as part or all of the coking feedstock for coke ovens.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: February 3, 1981
    Assignee: Continental Oil Company
    Inventors: Frank W. Theodore, George E. Wasson, William A. Jasulaitis, Everett Gorin
  • Patent number: 4243488
    Abstract: Metallurgical coke is made from coking a blend of coal which is comprised of reformed coal and another suitable coking coal. Reformed coal hereof is preferably made by the method which comprises dissolving at least one component selected from the group consisting of bituminous coal, subbituminous coal, brown coal and lignite in a hydrocarbon solvent, and recovering a reformed coal from said solution.
    Type: Grant
    Filed: July 17, 1978
    Date of Patent: January 6, 1981
    Assignee: Mitsui Coke Co., Ltd.
    Inventors: Hidehiko Sugimura, Keichiro Koba
  • Patent number: 4239500
    Abstract: A process for the utilization of tar-dust which is separated from the gases derived from gasification of granular fuel under pressure, especially of bituminous coal, and in which the tar-dust separated from the gases is fed back into the pressure gasification cycle of the fuel. The tar-dust is added as a binder in the pelletization of the fine grained portions of the fuel and is fed in pellet form into the generator. Apparatus for carrying out the process comprises a pressure generator having a feed device for granular fuel, a tar-dust separator, and a pelletizing device connected by a tar-dust coveying pipe to the tar-dust separator, for the pelletizing of fine grains of fuel with tar-dust as a binder, the pelletizing device conveying the green pellets produced thereby into the feed device. The granular fuel is screened to pass only that portion below a predetermined grain size to the pelletizer, the remaining portion being fed directly to the generator.
    Type: Grant
    Filed: March 14, 1979
    Date of Patent: December 16, 1980
    Assignee: Steag A.G.
    Inventor: Wolfgang Ratzeburg
  • Patent number: 4235830
    Abstract: Means and method of operating a tunnel kiln in which green carbon articles are baked in the ware (article) space of a baking zone by heat produced by the combustion of fuel directed to chambers adjacent the zone. The combustion chambers are connected in fluid communication with flues extending lengthwise of the kiln, the flues having a pressure gradient that extends lengthwise of the flues. The method of the invention includes the step of changing the pressure gradient within the flues such that a pressure differential between the combustion chambers and the ware space is effected that causes products of combustion to flow into the ware space from the combustion chambers in amounts sufficient to impede and prevent the deposition of coke formations on the walls of the space without burning the carbon articles.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: November 25, 1980
    Assignees: Aluminum Company of America, Pullman Incorporated
    Inventors: Robert F. Bennett, Warren D. Brown, Clarence L. Patterson, John C. Sorensen
  • Patent number: 4234386
    Abstract: Binder is added to any finely divided coal which can be made to coalesce on heating, the particles are formed into any shape desired for its end usage, and pyrolyzed under conditions carefully controlled to limit the rate of temperature rise of the shaped forms.
    Type: Grant
    Filed: March 22, 1979
    Date of Patent: November 18, 1980
    Inventor: Harold T. Stirling
  • Patent number: 4233117
    Abstract: Bodies are press-molded from a mixture of particulate fuel and a binder. These bodies are heated to a temperature between about 600.degree.-900.degree. C. in a rotary furnace to degas them. The degassing is carried out without subjecting the bodies to mechanical stresses and without permitting combustion of the expelled volatile gases. The resulting shaped coke has a greatly improved abrasion resistance.
    Type: Grant
    Filed: September 5, 1978
    Date of Patent: November 11, 1980
    Assignee: Bergwerksverband GmbH
    Inventors: Harald Juntgen, Karl Knoblauch, Josef Degel, Dieter Zundorf, Klaus Giessler
  • Patent number: 4231844
    Abstract: A method of producing abrasion resistant coke from brown coal briquets in a shaft furnace comprises charging the coke briquets into the top of the furnace and removing coke from the bottom of the furnace while directing inert hot combustion gases into the furnace and through the briquets at a plurality of vertically spaced levels throughout the height of the shaft furnace. Gases are directed at temperatures to effect and successively lower stages of the furnace the preheating, predrying, carbonization, and cooling of the charge. Gases are collected in each of the preheating and predrying stages by the use of a tubular suction arm which extends substantially across the width of the furnace and includes a performated bottom and sidewalls which extend partly below the bottom and are provided with a saw-tooth configuration so as to withdraw the gases through the space below the bottom and through the perforations of the bottom and to effect entrainment of dust from the charge in so doing.
    Type: Grant
    Filed: March 9, 1979
    Date of Patent: November 4, 1980
    Assignees: Firma Carl Still GmbH & Co. KG, Rheinische Braunkohlwerke AG
    Inventors: Heinrich Weber, Kurt Lorenz, Horst Dungs, Roman Kurtz, Hans-Joachim Kersting
  • Patent number: 4225391
    Abstract: A method of preparing coals for coking in a conventional coke oven includes agglomerating the loose coal, in combination with a binder, into flakes, mixing the flakes with non-agglomerated coal, and charging the mixture into the coke oven in the conventional manner. The method provides for the utilization in a conventional coke oven, of coals that are marginal in coking quality, greater bulk densities of the coal as charged into a conventional coke oven, acceptable shatter resistance and physical stability of the coke produced, and acceptable carbonization pressure on the coke oven walls.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: September 30, 1980
    Assignee: Koppers Company, Inc.
    Inventors: Michael Perch, Alex Peterson, Jr.
  • Patent number: 4218288
    Abstract: An apparatus for compacting, degassing and carbonizing carbonaceous agglomerates, the apparatus comprising a rotary kiln having an agglomerate inlet means for introducing green agglomerates into the kiln near the inlet of the kiln and a heating medium inlet for introducing a heating medium comprising a finely divided solid into the kiln at a preselected location intermediate the inlet end of the kiln and the outlet end of the kiln to produce a mixture at a temperature above the carbonizing temperature of the agglomerates and a sieve positioned to receive the products from the rotary kiln and separate the heating medium and the compacted, degassed, carbonized agglomerate product. A method for producing compacted, degassed, carbonized carbonaceous agglomerates by the use of the apparatus is also disclosed.
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: August 19, 1980
    Assignee: Continental Oil Company
    Inventor: Frank W. Theodore
  • Patent number: 4202734
    Abstract: An improved method for producing calcined coke agglomerates having good stability including adjusting the fluidity of coals or blends of coals to within a range of 1300 DDPM and 3000 DDPM, mixing the coals or blends of coals with char and optionally topped tar in a rotating agglomerating drum and agglomerating the mixture at a temperature between 750.degree. F. and 875.degree. F. (399.degree. C.and 468.degree. C.) for a time to form partially coked green coal agglomerates generally spherical in shape and calcining the partially coked green coal agglomerates at a temperature between 1500.degree. F. and 2000.degree. F. (815.degree. C. and 1093.degree. C). The calcined coke agglomerates are characterized by having a stability of not less than 60%.
    Type: Grant
    Filed: February 14, 1978
    Date of Patent: May 13, 1980
    Assignee: Bethlehem Steel Corporation
    Inventor: Robert R. Greenbaum
  • Patent number: 4197160
    Abstract: Process for the preparation of a moulded coke according to which agglomerates are heated in a non-oxidizing atmosphere, this process being characterized in that the agglomerates are prepared by compression from a paste containing:from 60 to 85% by weight of non-cokable coals,from 10 to 30% by weight of agglutinating coalshaving a swelling index greater than 2, andfrom 5 to 13% by weight of binder,which paste, when heated at 6.degree. C. per minute in the ARNU dilatometer gives a contraction of between 3 and 15%, preferably between 5 and 10% and a swelling of zero or near 0, and in that the agglomerates are heated in a non-oxidizing atmosphere from a temperature of about 100.degree. C. to a temperature of at least about 700.degree. C., with a rate of heating of between 7 and 14.degree. C. per minute.
    Type: Grant
    Filed: March 21, 1978
    Date of Patent: April 8, 1980
    Assignee: Houilleres du Bassin du Nord et, Due Pas-de-Calais
    Inventors: Roger Degrave, Maurice Marchasson
  • Patent number: 4186054
    Abstract: The method of producing blast furnace coke by (1) compacting a finely divided coal wherein at least about 60% by weight of the coal has a diameter of less than about 1/8 inch to form a coal compact, which compact immediately after removal from the compacting means comprises at least about 20% by weight of particles having a particle size of less than 1/4 inch in diameter; (2) breaking the thus formed compact such that the bulk density is sufficiently increased to be capable of conversion into coke suitable for use in large blast furnaces upon carbonization thereof; and (3) carbonizing the broken compact to thereby produce blast furnace coke having a minimum hardness of about 68 and a minimum stability of about 55. The compacting is preferably performed at a pressure equivalent to that achieved by passing the finely divided coal between rolls at a pressure applied to the coal of between about 20 and about 60 tons per lineal inch.
    Type: Grant
    Filed: December 30, 1977
    Date of Patent: January 29, 1980
    Assignee: United States Steel Corporation
    Inventors: William E. Brayton, Fay Fun, Luther G. Hendrickson, Ronald W. Shoenberger
  • Patent number: 4178215
    Abstract: A method of manufacturing blast furnace coke wherein said coke is obtained by a process in which coal to be used for making briquettes is mixed with a caking substance having a softening point of 40.degree.-250.degree. C. with or without a solvent having fluidity at the mixing temperature and dissolvable to said caking substance, the resultant mixture being mixed by means of a powerful mixer capable of applying mixing energy of 0.01KW/Kg or more at a temperature of 40.degree.-250.degree. C. for 1-10 minutes, while a heating medium such as steam is passed therethrough and is then subjected to briquetting with a roll press. The briquette obtained is either carbonized directly or after blending with coal ready for coke oven charging.
    Type: Grant
    Filed: September 29, 1976
    Date of Patent: December 11, 1979
    Assignees: Sumitomo Metal Industries Limited, Sumikin Coke Company Limited
    Inventors: Yoshio Kiritani, Michio Tsuyuguchi, Tetsuo Ibaragi, Katsuhiro Yano, Yoshihiko Sunami, Kunihiko Nishioka
  • Patent number: 4156595
    Abstract: A process for producing formcoke composed of char and selected binders comprising process steps in which non-oxidative thermal carbonization is employed.
    Type: Grant
    Filed: June 8, 1978
    Date of Patent: May 29, 1979
    Assignee: Peabody Coal Company
    Inventors: Robert H. Scott, Jimmy B. Smith
  • Patent number: 4148692
    Abstract: A process for producing calcined coke agglomerates characterized by having a low reactivity to carbon dioxide. The process includes calcining green coal agglomerates at a temperature within the range of 1700.degree. F. to 1950.degree. F. (927.degree. C. to 1066.degree. C.) in a calciner. The agglomerates are exposed to a gaseous atmosphere which before cracking contains not less than 20% by volume of at least one straight chain aliphatic hydrocarbon gas containing one to four carbon atoms. The gaseous atmosphere is preheated to a temperature within the range of 200.degree. F. to 700.degree. F.(93.degree. C. to 371.degree. C.) prior to being introduced into the calciner. Carbon produced when the hydrocarbon gas is cracked, is deposited as vitreous carbon on the surfaces, in the fissures and in the pores of the agglomerates. The calcined coke aggglomerates discharged from the calciner have a reactivity to carbon dioxide of between 2% to 8%.
    Type: Grant
    Filed: August 26, 1977
    Date of Patent: April 10, 1979
    Assignee: Bethlehem Steel Corporation
    Inventors: Vincent H. K. Chu, Louis G. Benedict, Sidney V. Fox
  • Patent number: 4142941
    Abstract: A method of producing blast furnace coke from bituminous coals, particularly coals having poor coking capacities in which the coal to be carbonized is ground, predried or preheated, mixed with binders, compressed or formed into briquets having small mechanical resistances and charged into oven chambers, is characterized by fine coals or fine coal mixtures having a swelling index in mixture according to DIN 51741, smaller than 7, and preferably, below 6, and comprising more than 50% of poorly or non-baking coal having a content of volatile matter in excess of 30% or less than 20% which coals or coal mixtures are ground up to attain asurface per unit mass, according to DIN 66145, of from 400 cm.sup.2 to 1200 cm.sup.2 per gram, and with from 3% to 8% by weight of organic binders, compressing the mixture to form it into a briquet at a temperature range of from 70.degree. C. to 300.degree. C.
    Type: Grant
    Filed: September 12, 1977
    Date of Patent: March 6, 1979
    Assignee: Firma Carl Still Recklinghausen
    Inventors: Heinrich Weber, Horst Dungs, Klaus Urbye, Franz Beckmann, Hugo Schmauch, Karl H. Flasche
  • Patent number: 4141793
    Abstract: A horizontal circulating carbonizer comprising an annular horizontally rotatable circulating hearth disposed rotatably, a carbonizer body covering said hearth, a coal feeder equipped on the carbonizer body, a preheating zone disposed in the vicinity of said feed coal supply opening, a carbonizing zone connected to said preheating zone, a cooling zone connected to the carbonizing zone, and a discharger of cooled coke, and a process for the preparation of coke using this horizontal circulating carbonizer.
    Type: Grant
    Filed: November 22, 1976
    Date of Patent: February 27, 1979
    Assignee: Nissho-Iwai Co., Ltd.
    Inventors: Yutaka Aoki, Akira Hase, Jiro Ito, Hisomu Nagai
  • Patent number: 4133718
    Abstract: Rotation of a first drum member at a preselected speed intimately mixes finely divided agglomerative materials to form a loosely coherent, plastic sticky mass. The tumbling action generated by the rotating drum breaks up the loosely coherent, plastic mass into plastic particles or agglomerates which grow in size as they roll within the first drum member. The formed agglomerates are conveyed by rotation of the first drum member into a second drum member that includes an inlet portion surrounding the outlet portion of the first drum member. The second drum member has a longitudinal axis that is coplanarly aligned with the longitudinal axis of the first drum member and both drum members are independently rotated at preselected peripheral speeds with the angle of inclination of the first drum member being adjustable relative to the second drum member to control the movement of the agglomerates.
    Type: Grant
    Filed: June 23, 1977
    Date of Patent: January 9, 1979
    Assignee: Dravo Corporation
    Inventor: Louis H. Jaquay
  • Patent number: 4117098
    Abstract: Process for manufacturing an isotropic carbonaceous material having a high density and a high crushing strength which comprises the steps of (a) extracting a reformed coal from at least one component selected from the group consisting of brown coal, lignite and grass peat in the presence of hydrogen gas; (b) heating the reformed coal to produce a green coke; and (c) coking the green coke.
    Type: Grant
    Filed: June 30, 1976
    Date of Patent: September 26, 1978
    Assignees: Mitsui Mining Company, Limited, Mitsui Coke Co., Ltd.
    Inventors: Katsunobu Tatsumoto, Kenji Fukuda
  • Patent number: 4111665
    Abstract: Apparatus for the gasification under pressure of bituminous coal, especially fine coal, comprising a generator which has a container to receive the coal to be gasified and a feed device which supplies the coal to the container, while keeping the container closed off so as to maintain the pressure in the generator. The feed device includes a briquette forming device located on the container, and a continuously operable screw conveyor which feeds the coal to be gasified through the briquette forming device and directly into the container in the form of briquettes. The feed device is encapsulated and, together with the fine coal and briquettes within it, forms a gas tight closure for the container to maintain the pressure therein.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: September 5, 1978
    Assignee: Steag A.G.
    Inventors: Rudolf Pasternak, Jochen Bauer
  • Patent number: 4111755
    Abstract: A fixed sulfur fuel is produced by proportioning sulfur-bearing coal and limestone in amounts which will cause the calcium in the limestone to react with a large amount of sulfur in the coal. The proportioned mixture is ground and blended and then balled or compacted to form pellets. By means of either a carbonizing or pyrolyzing technique conducted in a traveling grate machine, where the pellets are heated to at least 800.degree. F., the coal is pyrolyzed or carbonized, the limestone is calcined, and the sulfur is fixed in a calcium compound which remains stable in the ash after the pellets are burned as a fuel.
    Type: Grant
    Filed: January 27, 1977
    Date of Patent: September 5, 1978
    Assignee: McDowell-Wellman Engineering Company
    Inventors: Thomas E. Ban, Ashok D. Rao
  • Patent number: 4110169
    Abstract: A plurality of different types of raw material coal fines are sieved to a size not exceeding 1.5 mm; said sieved raw material coal fines are blended so as to satisfy the following conditions:(a) AP index: 75 at the minimum,(b) Mean maximum reflectance: 1.20% at the minimum, and(c) A [dilatation] - [contraction] value of from -2 to +5% when carbonized under conventional conditions in a horizontal type coke oven battery at a heating rate of 5.degree. C/min. (350.degree. - 600.degree. C);said blended raw material coal fines thus obtained are mixed with a binder and formed to produce a formed coal; and then, said formed coal thus obtained is charged into a horizontal type coke oven battery and carbonized, whereby a high-strength formed coke for blast furnace is a slight mutual agglomeration is manufactured.
    Type: Grant
    Filed: October 6, 1977
    Date of Patent: August 29, 1978
    Assignee: Nippon Kokan Kabushiki Kaisha
    Inventors: Gyoichi Suzuki, Sanseki Moriguchi, Takashi Miyazu, Yasuo Okuyama, Masahiro Muroya, Mamoru Yanagiuchi, Takashi Mori, Mitsutoshi Miura
  • Patent number: 4106997
    Abstract: The invention comprises methods for converting a supply of solid, naturally occurring coal and like hydrocarbon material to a plastic-like condition solely by the application of heat, and without employing any extraneous additives, and conducting the plastic-like conditioned material to a pressurized receiver.
    Type: Grant
    Filed: April 13, 1977
    Date of Patent: August 15, 1978
    Assignee: Ingersoll-Rand Research, Inc.
    Inventors: Victor Kevorkian, Francis J. Cumings
  • Patent number: 4106996
    Abstract: A method of improving the mechanical resistance of coke comprises forming a liquor of fine grained coal and oil with the oil being of from 5% to 30% of the total weight, forming coal pellets of the liquor at an increased temperature of from approximately 80.degree. to 100.degree. C, and heating the pellets to transform them into coke in a known coking process. Prior to being carbonized, the pellets are advantageously coated with a separating layer of a substance preventing agglomeration, such as hematite ore, lime, fine coke, etc.
    Type: Grant
    Filed: June 28, 1977
    Date of Patent: August 15, 1978
    Assignees: Werner Wenzel, Heinrich Wilhelm Gudenau
    Inventors: Werner Wenzel, Heinrich Gudenau, Joachim Bernt
  • Patent number: 4105501
    Abstract: With the use of low-fluidity blended raw material coal fines having a maximum fluidity of up to 20 d.d.p.m. as an inner core material, and coal fines having a maximum fluidity of at least 30 d.d.p.m. or a bituminous material having a C/H ratio of from 0.7 to 1.9 as an outer envelope material, green composite briquettes are formed by covering said inner core material with said outer envelope material. Said green composite briquettes thus formed are charged into a conventional coke oven battery and carbonized by an ordinary process, whereby a high-strength metallurgical formed coke in a slight mutual agglomeration is produced.
    Type: Grant
    Filed: October 8, 1976
    Date of Patent: August 8, 1978
    Assignee: Nippon Kokan Kabushiki Kaisha
    Inventors: Gyoichi Suzuki, Mitsutoshi Miura, Takashi Miyazu, Taro Matsushita, Yasuo Okuyama
  • Patent number: 4102750
    Abstract: Process for producing formed coke for metallurgical use from coal powder by continuously heating with a high temperature gas as heating medium for carbonizing agglomerated coal which are made of coal powder and a binder such as coal tar, pitch and petroleum asphalt, comprising providing tuyeres for introducing gas at the middle and the lower parts of an upright type carbonization oven, adjusting temperature of the gas to be supplied to the tuyere at the middle part at 600.degree. to 800.degree. C, adjusting the supply rate of the gas so as to maintain the temperature of the gas on the agglomerated coal at 300.degree. to 500.degree. C, and further adjusting the supplied heat to the lower part of the carbonization oven including the lower tuyere to amount less than 50% of the total supplied heat.
    Type: Grant
    Filed: August 16, 1976
    Date of Patent: July 25, 1978
    Assignee: Nippon Steel Corporation
    Inventors: Nobuyoshi Nishihara, Toshiaki Okuhara, Tetu Nishi, Hiroyuki Nakama, Chikara Saito, Kouichi Yuta