Abstract: This invention relates to a method and apparatus for the separation of bitumen crude petroleum from oil bearing solid materials and the collection of all the vapors produced, as multiple fractionated hydrocarbons.

Abstract: A process and apparatus are disclosed for purification of petroleum coke to produce an economical low sulfur product suitable for electrode production. Finely ground green coke is treated on an enclosed circular grate apparatus and subjected to sequential treatments in which hot gases are passed through a deep permeable bed of coke on the grate in a series of separate treating zones including a preheat zone, a heating and calcining zone, a desulfurizing zone in which hydrogen rich gas is passed through the heated bed, a reduction gas generation zone in which hydrocarbon and steam pass through hot coke to form hydrogen, and a cooling zone.Adequate temperatures for calcination and desulfurization are achieved and the proper heating rate is obtained without overheating the metal parts of the hearth by use of radiant and hot gas heating means in the calcining zone and in the desulfurizing zone and by introducing the air and/or fuel gas near the bottom of the coke bed.

Abstract: Apparatus for progressively burning biomass material comprising a retort defining a chamber, a linearly moving grate bed enclosed within the chamber with a space below and a space above for respectively supplying primary air to the lower side of the grate and for collecting gases generated by progressive distillation of the biomass material at the upper side of the grate. Primary air is supplied to the underside of the grate bed at different pressures lengthwise of the grate by a distribution chamber extending lengthwise of the grate of V-shaped cross section containing at its bottom a Venturi opening through which air is delivered to the distribution chamber from successive longitudinally-arranged plenum chambers which, in turn, are supplied with air through conductors connected to a primary air source, each of which contains a damper. The grate may be horizontal or inclined.

Abstract: A method of producing abrasion resistant coke from brown coal briquets in a shaft furnace comprises charging the coke briquets into the top of the furnace and removing coke from the bottom of the furnace while directing inert hot combustion gases into the furnace and through the briquets at a plurality of vertically spaced levels throughout the height of the shaft furnace. Gases are directed at temperatures to effect and successively lower stages of the furnace the preheating, predrying, carbonization, and cooling of the charge.

Abstract: This disclosure is directed to an economical system for the pyrolysis of municipal solid waste to recover valuable by-products while reducing the putrecibility and bulk of the residue requiring disposal. Prior to this treatment, the solid waste has been processed to remove most of the metallic components, and shredded, which steps are not part of the invention disclosed. The pyrolysis and by-product recovery technology is complicated by (a) the inherent variability of the chemical and physical characteristics of the shredded solid waste as received at the pyrolysis plant and (b) the relatively low heat value of said waste as thus received.

Abstract: A process comprising heating coal in a substantially air-free environment to liberate volatile materials and produce coke, condensing at least some of the volatile materials so liberated to liquefied products and dispersing the coke therein to form a coke slurry, feeding the coke slurry to a slurry pipeline, and pumping the coke slurry through the pipeline to a destination.Apparatus comprising a tube furnace having an external heating means for indirectly heating powdered coal therein in a substantially air-free environment to a temperature adequate to liberate volatile materials and produce coke, means to feed powdered coal to the furnace under pressure and force the volatile materials and coke produced in the furnace through the furnace to a condensing means in which at least some of the volatile materials are condensed with the coke dispersed therein to form a coke slurry, and means to convey the coke slurry from the condensing means to a pipeline for transport to a destination.

Abstract: Adjacent alternating rows of relatively coarse and fine coal are deposited onto a horizontal moving grate running through a coking furnace.

Abstract: Method of mixing particulate materials comprising contacting a primary source and a secondary source thereof whereby resulting mixture ensues; preferably at least one of the two sources has enough motion to insure good mixing and the particulate materials may be heat treated if desired.Apparatus for such mixing comprising an inlet for a primary source, a reactor communicating therewith, a feeding means for supplying a secondary source to the reactor, and an inlet for the secondary source. Feeding means is preferably adapted to supply fluidized materials.

Abstract: Method and apparatus for feeding an oxidant such as air and/or a fuel rich gas within the confines of a substantially air tight enclosure employed in the heat treatment of volatile containing materials which are deposited on the floor of a rotary hearth mounted within the enclosure. A larger number of air and/or fuel rich gas inlet ports are provided in the roof of the enclosure at the outer periphery thereof than at the central or intermediate areas of the enclosure to thus provide a more oxidizing atmosphere at the outer peripheral area of the enclosure than at the central and intermediate areas of the enclosure. The oxidant is admitted into the furnace enclosure through concentrically arranged rows of inlet openings formed in the roof of the enclosure.

Abstract: A horizontal circulating carbonizer comprising an annular horizontally rotatable circulating hearth disposed rotatably, a carbonizer body covering said hearth, a coal feeder equipped on the carbonizer body, a preheating zone disposed in the vicinity of said feed coal supply opening, a carbonizing zone connected to said preheating zone, a cooling zone connected to the carbonizing zone, and a discharger of cooled coke, and a process for the preparation of coke using this horizontal circulating carbonizer.

Abstract: Distillation system for distilling shale oil. Shale is inserted into a rotating retort which displaces the shale throughut the retort extended length. The rotating retort is mounted to a multiplicity of enclosed housings through rotative bearings. The enclosed housings form discrete heating chambers to provide individual temperature zones through which the shale passes in the distilling process. The multiplicity of housings are each connected to a next consecutive housing through a conduit which permits utilization of combustion gases from a common source to heat each of the temperature zones. A thermal control mechanism is coupled to each of the enclosures to provide temperature control within a particular temperature zone. Thus, the shale in its passage through the retort is subjected or exposed to predetermined temperature ranges within each of the enclosures for a predetermined time in order to maximize the efficiency of the shale oil recovery process.

Abstract: Process and apparatus for treating a comminuted solid carbonizable material, such as comminuted municipal waste; sawdust, granulated coal, shredded tires and the like wherein the material is caused to be pyrolyzed in a horizontally disposed elongated reaction zone essentially free of any oxygen containing gases at ambient pressure and at a temperature of from 400.degree. C. to 900.degree. C. The material is passed through the reaction zone by paddle-like impellers mounted on a shaft while being subject to an indirect heat transfer relationship via a burning air fuel mixture spirally swirling within a heating zone about the reaction zone and the mixture being withdrawn from a lower portion of the heating zone. During pyrolysis, the material is chemically changed into valuable gaseous, liquid and solid products.

Abstract: Disclosed is a process and apparatus for reducing the particulate content in a gaseous stream containing entrained particulate matter and condensable hydrocarbons wherein said stream is obtained from the retorting of hydrocarbon-containing solids, particularly from retorted shale. A gaseous effluent containing condensable hydrocarbons and entrained solid particulate matter is produced during the retorting of hydrocarbon-containing solids and is discharged from a retorting vessel through a conduit containing a rotating elongate spiral-shaped element on which a portion of the particulate matter and condensable hydrocarbons form a semi-solid mass. The rotating spiral collects and conveys the semi-solid mass back into the retorting vessel for further processing thereby reducing the solid particulate content of the condensable hydrocarbon product.

Abstract: Apparatus for treating oil shale by microwave energy for recovering heated volatile fractions thereof. The microwave oven includes a sloping feeder made of glass, pyrex, or ceramic material, which feeder is reciprocated back and forth along a declining plane so as to advance slowly but progressively oil shale deposited on the top end thereof to the discharge end of the vibrator. Means are provided to evacuate volatile fractions and to feed such gases through preheater tubes to a condenser unit. The preheater tubes are disposed in line with and through the flow of incoming materials so as to tend to regulate material descent as well as preheat the shale. An additional solids heat exchanger is employed underneath the discharge end of the vibratory feeder means so as to slow the descent of the spent shale onto its ultimate conveyor as well as taking heat therefrom and from the magnetron tubes of the oven to conduct such heat upwardly to further increase the preheating effect upon incoming shale.

Abstract: Disclosed is a process for the retorting of shale and other similar hydrocarbon-containing solids in which the solids to be retorted are mixed with a hot solid heat transfer material to rapidly heat the hydrocarbon-containing solids to a high temperature and conveyed through the retorting vessel by means of a flexible, generically helical shaped, elongated, hollow longitudinal core element. The shale and heat transfer material are conveyed concurrently through a first section of a cylindrical vessel while a stripping gas is introduced into a latter section of the vessel and flows countercurrent to the movement of the two solids. The stripping gas along with entrained fines, gaseous hydrocarbons, and liquid hydrocarbons in the form of a mist are removed from a middle section of the vessel while the retorted shale is removed from the end of the vessel.

Abstract: A modified rotary kiln suitable for calcining normally solid carbonaceous material, having adapted thereto at one end a firing crown and means for admitting combustible gases or liquids and air; a feeding means for such solid carbonaceous material to be calcined adapted to the other end of the kiln; and wherein the combustion gases and solid materials travel countercurrently in the kiln during calcination, wherein: at least one series of at least two tuyeres passes through the wall of the kiln symmetrically spaced to and at about a point longitudinally in the middle one-half of the longitudinal axis of the kiln; each tuyere terminating within the kiln through a nozzle on the side of the tuyere at a height sufficient for the discharge of exterior oxidizing gases passing therethrough at a point above the bed of the carbonaceous material in the kiln, directing the exterior oxidizing gases toward the feed end at about the same acute angular direction from a line passing through the nozzle and parallel to the long

Abstract: A method and apparatus for incinerating waste material in a multiple hearth furnace having a plurality of vertically spaced hearths wherein waste material is introduced to the furnace at the top thereof and moves downwardly in a generally serpentine fashion moving alternately inwardly and outwardly across the hearths and is discharged at the bottom of the furnace, and including the steps of introducing towards the lowermost hearth thereof air in a quantity less than that theoretically required for complete combustion of the material being processed, thereafter at successively higher hearths ascertaining the temperature at each hearth and adding air thereto in quantities only sufficient to support combustion thereon, and on each hearth in the middle portion of the furnace adding only enough air to each hearth so as to maintain the temperature on that hearth under a maximum predetermined limit, and on the hearths towards the top of the furnace reducing the quantity of air added, and thence discharging the exhau

Abstract: The invention is directed to method and apparatus for treating waste material containing alkali metal in a counter-flow furnace wherein the waste material to be processed is introduced at one end thereof and the processed material is discharged from the other end, while simultaneously air is introduced and the gases of combustion are caused to flow in a counter-current direction with respect to the material being processed and are exhausted at the first end of the furnace, and wherein the furnace has a natural tendency to form zones of processing including sequentially from the first end of the furnace, a drying zone, a charring and volatile burning zone, and a fixed carbon burning zone, and wherein a maximum temperature is maintained in the furnace below about 1400.degree. F. directly adjacent the surface of the bed of material being processed.

Abstract: The present invention is directed to method and apparatus for treating waste material in a counter-flow furnace wherein the material is introduced at one end thereof and the processed material is discharged from the other end, while the gases of combustion are caused to flow in counter-current direction with respect to the material being processed and are exhausted at the first end of the furnace, and wherein the furnace has a natural tendency to form zones of processing including sequentially from the first end of the furnace, a drying zone, a charring and volatile burning zone, a fixed carbon burning zone and an ash cooling zone, a method characterized by the step of adding an oxidant including water vapor to the fixed carbon burning zone.

Abstract: An apparatus is provided for the destructive distillation of organic waste materials. An insulated sealed distillator compartment is provided having a plurality of conveyor stages for transporting the waste material through the sealed compartment while subjecting the material to a plurality of increased zones of temperature in order to completely pyrolyze the material and evolve pyrolysis gases. An auger feed apparatus supplys a continuous supply of material to the sealed distillator, while an auger discharge apparatus removes a continuous supply of solid carbonaceous residue from the distillator. The residue can be classified and separated into usable products. The evolved gases may be converted into crude oil and natural gas. A process for destructive distillation of the waste materials is also disclosed.

Abstract: The invention relates to a method and apparatus for the heat treatment of materials on a traveling hearth mounted on a horizontal plane and rotated on a vertical axis within a substantially air-tight enclosure. The materials on the hearth are deposited thereon in separate and distinct rows and retained in separate rows while undergoing heat treatment within the enclosure. The material in one of said rows is capable of evolving volatiles when the materials are subjected to a heat treatment and the evolved volatiles rise and are dispersed in the upper portion of the enclosure where the same will combine with an oxidant such as air and/or oxygen which is admitted into this portion of the enclosure. The mixture of evolved volatiles and oxidants such as air and/or oxygen will combust in the upper portion of the enclosure.

Abstract: An improved process for the production in high yield of activated carbon particles of high activity comprises rapid removal of volatile material from the area of carbonaceous particles during the carbonization step by individually venting each hearth of a multiple hearth furnace. The carbonaceous particles which are subjected to the carbonization step are prepared from mixtures of carbonaceous material and petroleum acid sludge.

Abstract: Fine-grain fuel is carbonized at a low temperature by feeding the fuel from a hopper downwardly into the gap formed between two vertically-arranged, plate-type conveyors. The plates of each conveyor move downwardly while their back face surfaces bear against the wall of a heating chamber. The position of the heating chambers is controlled to maintain a narrow gap, e.g., 10-30 millimeters between the plates of the conveyors. The conveyors and heating chambers are located within a container wherein a pressure of up to 100 bars is maintained and a clear gas is passed countercurrently to the downward advancement of the fuel in the gap between the conveyors. Breaker rollers below the conveyors subdivide the carbonized fuel issuing from the gap for passage into a gasification chamber. Part of the gas yield is used as fuel for the heating chambers.

Abstract: A substance to be treated for the production therefrom of useful products (usually decomposition products) is formed into a bed on a perforate support, the bed having a thickness of up to about one inch. An inert atmosphere is maintained above and in contact with the bed in a substantially closed space of constant volume. The bed is heated to progressively increasing temperatures by means of a radiant heat source located in the closed space at a distance of up to one and one-half inches above the upper surface of the bed. As the bed is heated, liquid products are educted from the substance and are removed by the force of gravity from the bottom of the bed through the perforate support.

Abstract: Char from the waste liquor of a pulp manufacturing process is produced by confining the waste liquor in a container and feeding the container into an air heating furnace in a manner such that the container is contacted countercurrently with heated air without rotating or stirring the container.

Abstract: Carbonization of coal in travelling grate furnace with hot gas inlets below the grate. A refractory screen is provided above the grate to provide a flame propagation base for the volatile gases withdrawn from the coal on the grate. The combustion zone above the refractory screen provides radiant heat to vaporize volatiles present in the coal on the grate.The coal to be treated may be in the form of briquettes or an extruded slab. When an extruded slab of slurried coal is used the thermal shock on first entering the carbonization chamber results in the formation of carbon granules.

Abstract: A pyrolysing vessel in which the inlets and outlets for the charge and the pyrolysing gas are so arranged that charge and gas pass through the vessel along paths that meet substantially at right angles. The charge may descend vertically, and the vessel may taper outwardly and downwardly to aid this descent. The gas may enter and leave the vessel through grilles that can be oscillated to further aid the descent. Pyrolysing plant including the vessel may include means to take a fraction of the gas at the outlet and recycle it through a heater to the gas inlet.

Abstract: Organic and pseudo-organic materials, such as waste materials, for example, are processed in a converter system and decomposed into various usable and reusable forms. Inorganic metals and salts are treated likewise in the same converter system and processed into various usable and reusable forms. While being carried by a conveyor through a controlled atmosphere treatment chamber, virtually free from combustion supporting air or other oxidizing agents, the feed material is caused to progressively thermally break down into its more basic constituents which flow out of the material treatment chamber in a continuous liquid and gaseous vapor stream. Negative pressure is applied upstream from the material treatment chamber to lead the liquid and gaseous vapor stream through successive processing stages of collection containers, condensers and gas scrubbers. The variable negative pressure is sufficient to maintain the pressure in the material treatment chamber within a range of slightly above ambient pressure.