Column Patents (Class 202/158)
  • Patent number: 5846386
    Abstract: Highly purified ammonia for use in semiconductor manufacturing is prepared on-site by drawing ammonia vapor from a liquid ammonia reservoir, passing the vapor through a filter capable of filtering out particles of less than 0.005 micron in size, and scrubbing the filtered vapor in a high-pH aqueous scrubber.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: December 8, 1998
    Assignee: Startec Ventures, Inc.
    Inventors: Joe G. Hoffman, R. Scott Clark
  • Patent number: 5846387
    Abstract: Highly purified HCl for use in semiconductor manufacturing is prepared on-site by drawing HCl vapor from a liquid HCl reservoir, and scrubbing the filtered vapor in a low-pH aqueous scrubber.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: December 8, 1998
    Assignee: Air Liquide Electronics Chemicals & Services, Inc.
    Inventors: Joe G. Hoffman, R. Scot Clark
  • Patent number: 5837105
    Abstract: A tray design for use in a separation column for distilling or fractionating a feed stream is provided that incorporates co-current contact of the liquid and vapor streams and their subsequent separation on each tray. Located on the trays are a plurality of co-current vapor and liquid contacting sections including a volume of the tray in which vapors and liquid can be in co-current contact. Also located on the trays are a plurality of de-entrainment devices for separating entrained liquids from a vapor stream, the de-entrainment devices having an inner and an outer side, the inner side being adjacent to the co-current contacting sections. The tray design further incorporates a plurality of liquid downcomers, having an upper portion and a lower portion, where the upper portion.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: November 17, 1998
    Assignee: Mobil Oil Corporation
    Inventors: Berne K. Stober, Raymond M. Sowiak
  • Patent number: 5800791
    Abstract: Column baffles (1) for suspensions with precipitating substances which are provided for a substance transfer between the suspension and a vapour phase moving in a counter-flow. The baffles include membrane-like elements (2, 3; 5) which, on the one hand, bring about a cascade-like formation of liquid curtains with respect to the suspension and, on the other hand, with respect to the vapour phase, for chicanes for strong changes of direction for the vapour flow which lead to the formation of eddies in the vapour phase. In accordance with the invention, the membrane-like elements are made from a flexible material and are secured at few sites in the column (100) such that an oscillating movement or fluttering movement of the elements can be excited by the flowing media, in particular by eddies in the vapour phase.
    Type: Grant
    Filed: August 9, 1995
    Date of Patent: September 1, 1998
    Assignee: Sulzer Chemtech AG
    Inventors: Stuart Ainscow, Rolf Sittkus
  • Patent number: 5785820
    Abstract: A system for purification and generation of hydrofluoric acid on-site at a semiconductor device fabrication facility. An evaporation stage (optionally with arsenic oxidation) is followed by a fractionating column to remove most other impurities, an Ionic Purifier column to suppress contaminants not removed by the fractionating column, and finally the HF Supplier (HFS).
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: July 28, 1998
    Assignee: Startec Ventures, Inc.
    Inventors: Joe G. Hoffman, R. Scot Clark
  • Patent number: 5785819
    Abstract: In a distillation column for separating a liquid mixture into a plurality of pure fractions, the distillation column being divided into 2 parts, a feed part and a take-off part, in its middle region by a separation effective in the longitudinal direction, the separation consists of two walls with a gas space in between, the distance between the two walls being from 1 to 50 mm, preferably from 3 to 10 mm.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: July 28, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Kaibel, Manfred Stroezel, Joachim Pfeffinger
  • Patent number: 5783047
    Abstract: A monotube or multitube 2 is coupled to a body shell 1 via tube plates 3a and 3b at both ends, so that a tube interior 4 and a tube exterior 5 of the monotube or multitube 2 are isolated from each other. A difference is made in operating pressure between the tube interior 4 and the tube exterior 5, so that one of the tube interior 4 and the tube exterior 5 is used as a lower-pressure column and the other is used as a higher-pressure column. A wall of the tube is used as a heat transfer surface, so that heat is transferred from the higher pressure side (higher temperature side) to the lower pressure side (lower temperature side).
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: July 21, 1998
    Assignees: Kimura Chemical Plants Co., Ltd., Kansai Chemical Engineering Co., Ltd., Maruzen Petrochemical Co., Ltd.
    Inventors: Kazumasa Aso, Hiroshi Matsuo, Hideo Noda, Tomoaki Takada, Nobuyuki Kobayashi
  • Patent number: 5776316
    Abstract: A liquid redistribution system for redistributing liquid descending in a packed distillation column in which liquid is distributed from one side of the column to the other side of the column and vice-versa. To this end, a plurality of parallel, spaced apart liquid distributor elements provide inlet openings for receiving the liquid as it descends and outlet openings located on the underside of the distributor elements for discharging the liquid from the inlet openings. Channels provide flow communication between the inlet and outlet openings.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: July 7, 1998
    Assignee: The BOC Group, Inc.
    Inventors: Richard W. Potthoff, Alan C. Burton
  • Patent number: 5766519
    Abstract: An absorber for absorbing a vapor into a sorbent liquid comprised of a sequential plurality of highly effective and intensified locally cocurrent sorptions, but with non-cocurrent flow of vapor and liquid between the individual sorptions. The structure containing the locally cocurrent upflow is preferably comprised of enhanced heat transfer surface, making the sorption diabatic, further enhancing the intensification, and improving the sorption efficiency. Referring to FIG. 1, vertical cylinders (1) and (2) form an annulus which is divided into multiple compartments by partitions. Vapor is injected into the bottom portion of each compartment by injection ports (10), resulting in cocurrent upflow absorption. The compartments are pressure equalized with a common vapor space via equalization ports (6). This approach to absorption can be accomplished in a vertical cylindrical annulus as described above, in a horizontal cylindrical annulus, in plate fin exchangers, and others.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: June 16, 1998
    Inventor: Donald C. Erickson
  • Patent number: 5766423
    Abstract: A gas drying method is disclosed in which gas streams are dehydrated to low dew points by contacting the wet gas with a dry liquid desiccant, with the liquid desiccant regenerated by heating it in a reboiler containing an internal reboiler vapor condenser and stripping it with a stripping agent that is dried with solid desiccant.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: June 16, 1998
    Assignee: OPC Engineering
    Inventor: Robert Sherwood Smith
  • Patent number: 5755934
    Abstract: Highly purified ammonia for use in processes for the production of high-precision electronic components is prepared on-site by drawing ammonia vapor from a liquid ammonia reservoir, passing the vapor through a filter capable of filtering out particles of less than 0.005 micron in size, and scrubbing the filtered vapor in a high-pH aqueous scrubber.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: May 26, 1998
    Assignee: Startec Ventures, Inc.
    Inventors: Joe G. Hoffman, R. Scot Clark
  • Patent number: 5755933
    Abstract: An integrated distillation column having a partitioned stripping or absorption section is presented. The integrated stripping/distillation column comprises a single shell housing a refluxed absorption section and a reboiled stripping section. The stripping section is partitioned by a vertical wall into first and second separate portions having upper end in fluid communication the absorption section. The stripping portions include fluid isolated lower ends having separate reboilers. In the integrated absorption/distillation column, the absorption section is partitioned and separate reflux loops are provided for each portion of the absorption section. In such a manner, a two column distillation process can be combined into one for achieving space and equipment savings.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: May 26, 1998
    Assignee: The M. W. Kellogg Company
    Inventors: Thomas P. Ognisty, David B. Manley
  • Patent number: 5730843
    Abstract: A contact structure, useful as a distillation structure, has a rigid frame made of two substantially vertical duplicate grids spaced apart and held rigid by a plurality of substantially horizontal rigid members and a plurality of substantially horizontal wire mesh tubes mounted to the grids to form a plurality of fluid pathways among the tubes. For use as a catalytic distillation structure, which serves as both the distillation structure and the catalyst, at least a portion of the wire mesh tubes contain a particulate catalytic material. The catalyst within the tubes provides a reaction zone where catalytic reactions may occur and the wire mesh provides mass transfer surfaces to effect a fractional distillation. The spacing elements provide for a variation of the catalyst density and loading and structural integrity.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: March 24, 1998
    Assignee: Chemical Research & Licensing Company
    Inventors: Willibrord A. Groten, Derwyn Booker, Clifford S. Crossland
  • Patent number: 5730002
    Abstract: A gas containing at least two constituents A and B having different temperatures is fractionated by carrying out at least the two cooling and contacting phases as follows:a) during a first stage, said gas is at least partly cooled to cause condensation of at least a first liquid fraction and said gas is brought into contact with said liquid fraction in at least a first zone of contact and heat exchange Z1, and at least a liquid fraction enriched in constituent A and at least a gaseous fraction are collected at the outlet of said first zone of contact and heat exchange Z1,b) during a second stage, said gaseous fraction from stage a) is at least partly cooled to cause condensation of at least a second liquid fraction and said gaseous fraction is brought into contact with said second liquid fraction in at least a second zone of contact and heat exchange Z2, and at least a liquid fraction enriched in constituent B and at least a gaseous fraction are collected at the outlet of said second zone.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: March 24, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Claude Collin, Alexandre Rojey
  • Patent number: 5722258
    Abstract: A liquid-vapor contact apparatus has pairs of vertical outer walls disposed in the manner of the vertical faces of a cuboid. The apparatus includes a plurality of spaced, parallel, vertical plates. Between each pair of adjacent plates there is a packing comprising a vertical array of corrugated liquid-vapor contact elements of the type that are used in structured packing. The corrugations in each element slope from top to bottom in a direction opposed to that in which the corrugations in contiguous elements slope. The two outermost plates form the walls of the apparatus. The walls comprise alternate edge portions of plates and of spacer bars. The plates define first and second sets of passages, respectively. One set of passages performs a first fractionation duty, and the other set another fractionation duty.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: March 3, 1998
    Assignee: The BOC Group plc
    Inventor: William H. Aitken
  • Patent number: 5718127
    Abstract: A liquid-vapour contact apparatus has pairs of vertical outer walls disposed in the manner of the vertical faces of a cuboid. The apparatus includes a plurality of spaced, parallel, vertical plates. Between each pair of adjacent plates there is a packing comprising a vertical array of corrugated liquid-vapour contact elements of the type that are used in the assembly of structured packing, and having the apexes of the elements in fluid tight engagement with the respective plates. The corrugations in each element slope from top to bottom in a direction opposed to that in which the corrugations in contiguous elements slope. The two outermost walls form the walls of the apparatus. The other walls comprise alternate edge portions of plates and of spacer bars. Liquid is distributed appreciably evenly between the passages formed by adjacent vertical plates at the top of the apparatus and flows over the elements and effectively vertically downwards.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: February 17, 1998
    Assignee: The BOC Group plc
    Inventor: William H. Aitken
  • Patent number: 5709780
    Abstract: An integrated distillation column having a partitioned stripping or absorption section is presented. The integrated stripping/distillation column comprises a single shell housing a refluxed absorption section and a reboiled stripping section. The stripping section is partitioned by a vertical wall into first and second separate portions having upper end in fluid communication the absorption section. The stripping portions include fluid isolated lower ends having separate reboilers. In the integrated absorption/distillation column, the absorption section is partitioned and separate reflux loops are provided for each portion of the absorption section. In such a manner, a two column distillation process can be combined into one for achieving space and equipment savings.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: January 20, 1998
    Assignee: The M. W. Kellogg Company
    Inventors: Thomas P. Ognisty, David B. Manley
  • Patent number: 5690708
    Abstract: In a column for contacting upwardly flowing gas with downwardly flowing liquid, a horizontal tray includes a plate provided with a tubular gas/liquid contact device. The tubular gas/liquid contact device includes a contact section located below the plate, a separation section located above the contact section, and an outlet section located above the separation section and above the plate. The contact section is closed at its bottom, the wall of the contact section is provided with a plurality of tangential gas inlets and a liquid delivery tube opens into the lower end of the contact section. The outlet section has a gas permeable wall provided with a coalescer and the top of the outlet section is provided with a cover.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: November 25, 1997
    Assignee: Shell Oil Company
    Inventors: Anton Matthijs Danckaarts, Enno Frank Wijn
  • Patent number: 5679312
    Abstract: A reactive stripping process for continuously carrying out chemical reactions while separating the reactants from the reaction products is provided. The process comprises passing liquid reactants and an inert stripping gaseous stream in a reactor column (1) having a plurality of perforated trays (2) provided therein and interconnected by a plurality of downcomers (3), screens (4 and 5) provided on the trays (2) and the top openings of the downcomers (3). The trays (2) and downcomers (3) are associated with the screens (4 and 5) to form a chamber optionally provided with a solid particulate or liquid catalyst (6) therein. A reactive stripping apparatus for performing such a process is also provided. According to the invention, at least one reaction product and the reaction mixture having different boiling points can be separated in order that chemical reactions proceed continuously as desired.
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: October 21, 1997
    Assignees: China Petro-Chemical Corporation, Tianjin University
    Inventors: Shiyi Jin, Jitang Yuan, Zongli Zhang, Huisheng Lu, Lianshun Wang, Jinzhu Yin
  • Patent number: 5670026
    Abstract: A method of in-service cleaning an operating column by inserting into the column a lance through which a compatible liquid is dispensed at a pressure of at least about 5000 psig. Also disclosed is apparatus which comprises a column through which a fluid can pass, nozzles mounted on the outside of the column, where each nozzle comprises a flange welded to the column and a valve bolted to the flange, a lance which can be inserted through the nozzles into the column and means for dispensing a liquid through the lance at a pressure of at least about 5000 psig.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: September 23, 1997
    Inventor: Charles R. Rutan
  • Patent number: 5653126
    Abstract: A packing material capable of improving the uniformity of liquid distribution and of achieving a preferable gas-liquid contact reaction, even in the case where the specific surface area of the packing material is small, includes a plurality of projections provided on the surface of a thin plate, and a plurality of holes provided respectively between the projections. In one embodiment, the transfer extension of each projection is larger than a longitudinal extension thereof, so that descending liquid flows downward while being transversely dispersed by the projection. The holes are provided between the projections so that they do not obstruct the transfer dispersion of liquid at the projection. Moreover, the holes accelerate the transverse dispersion of liquid, or the dispersion of liquid between front and rear surfaces of the thin plate, by the surface tension of the liquid. As a result, excellent uniformity of liquid distribution can be obtained on the surface of the thin plate.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: August 5, 1997
    Assignee: Hitachi, Ltd.
    Inventors: Susumu Harada, Satihiro Yoshimatsu, Kazuo Someya, Naruyasu Okamoto
  • Patent number: 5649433
    Abstract: An improved cryogenic liquefied gas container, or a so-called cold evaporator (CE) for containing a plurality of different liquefied gases such as oxygen and nitrogen gases can be installed on a site with a limited surface area and can store the gases at a substantially equal and constant temperature level to ensure a stable gas supply to consumers that may include medical facilities and manufacturing plants. A plurality of inner tanks 4 are vertically arranged and surrounded by an insulation layer 3 in an outer shell 2 in order to economically utilize the site. The temperature of the high boiling point liquefied gas LG1 contained in the upper inner tank 4a and hence the internal pressure of the upper inner tank are stabilized by means of a heat exchanger section 11 to which the low boiling point liquefied gas LG.sub.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: July 22, 1997
    Assignee: Daido Hoxan Inc.
    Inventors: Hiroaki Suzuki, Yuji Morimoto, Yasuo Tanaka, Taturu Yamauchi
  • Patent number: 5647961
    Abstract: A system for decontaminating and separating individual refrigerants from a mixture of refrigerants contaminated with solids, liquids and non-condensible gasses, includes three stages. In the first stage, solid and liquid contaminants are removed. In the second stage, the mixture of refrigerants passes through a condensation column where successive condensation stages remove individual refrigerants from the mixture of refrigerants. The remaining mixture of refrigerants passes through a third stage where non-condensible gas contaminants are removed.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: July 15, 1997
    Assignee: Tom Nicol
    Inventor: Spencer G. Lofland
  • Patent number: 5645692
    Abstract: A method and apparatus for stabilizing crude oil at the outlet of a well, including at least one separation step wherein the crude oil is pressure distilled in at least one distillation column into at least two cuts, i.e., a C.sub.1-5 hydrocarbon gas cut recovered at the top of the column and a stabilized crude oil cut recovered below the point where the original crude oil was injected into the column. The method advantageously includes at least one decompression step before the separation step.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: July 8, 1997
    Assignee: Elf Aquitaine Production
    Inventors: Jean-Paul Gourlia, Jacques Tournier Lasserve, Georges Bihn-Cirlot, Jean Vandermeersch
  • Patent number: 5643421
    Abstract: A gas drying method is disclosed in which gas streams are dehydrated to low dew points by contacting the wet gas with a dry liquid desiccant, with the liquid desiccant regenerated by heating it and stripping it with a stripping agent that is dried with solid desiccant.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: July 1, 1997
    Assignee: OPC Engineering, Inc.
    Inventor: Robert Sherwood Smith
  • Patent number: 5614065
    Abstract: An apparatus for separating a first component of a process stream from a second component of a process stream in a single vessel has been developed. The single vessel apparatus has a membrane contactor dividing the vessel into an upper portion and a lower portion where the membrane contactor is a material providing selective permeation of fluid components and restricting passage of at least one component to the upper portion of the vessel, and a plurality of vertically spaced apart distillation contactors disposed within the vessel for vapor and liquid distillation located in the lower and/or upper portion of the vessel. The benefit is the production of a process stream that is of high first component purity at reduced capital equipment costs.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: March 25, 1997
    Assignee: UOP
    Inventor: Terry L. Marker
  • Patent number: 5612007
    Abstract: An apparatus useful for preparing aromatic carboxylic acids by the exothermic liquid-phase oxidation reaction of an aromatic feedstock compound is disclosed, wherein energy is efficiently recovered from the exothermic oxidation reaction.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: March 18, 1997
    Assignee: Amoco Corporation
    Inventor: Kenneth J. Abrams
  • Patent number: 5603809
    Abstract: A spinning band device for use in a distillation process including a particular pattern of apertures. The band is made of of an elongated strip, either metal screen or Teflon, twisted about its longitudinal center. Both embodiments contain frayed or jagged edges to create turbulences within a mixture and scrape the inner wall of a distillation column. The novel features of this band are the large apertures, which a situated on the longitudinal centerline for the metallic embodiment and scattered on the outer face for the Teflon embodiment, combined with the use of a plurality of spinning blades. Experimental testing and empirical data has proven this type of band to yield a significant increase in fractionating efficiency over the conventional two bladed bands without apertures.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: February 18, 1997
    Inventor: Roger R. Roark, Sr.
  • Patent number: 5593548
    Abstract: A column having a region for reaction with distillation of fluid streams is provided with structures which include distillation trays that allow for the accumulation of liquid from a liquid stream and the passage of a vapor stream through the liquid for interaction therewith. The structures include catalyst beds which extend downwardly from the trays and are housed within at least partially perforate containers. A portion of the liquid on the tray is catalytically reacted as it is driven through the catalyst bed by the liquid head created by the accumulated liquid. Another portion of the liquid may be directed through a bypass which also extends downwardly from the tray and allows the liquid to bypass the catalyst bed so that higher volumetric flow rates can be achieved. A still further portion of the liquid can be directed to a zone between adjacent catalyst beds or within a catalyst bed for developing a liquid head to force the liquid laterally through the catalyst bed.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: January 14, 1997
    Assignee: Koch Engineering Company, Inc.
    Inventors: Neil Yeoman, Ronald Pinaire, Michael A. Ulowetz, Timothy P. Nace, David A. Furse
  • Patent number: 5580425
    Abstract: A column for performing thermal separations and/or chemical reactions with a vertical cylindrical outer column wall surrounding an inner volume, which is subdivided by a median vertical separating wall into two volume halves, wherein mass exchange packs are arranged, whereby an overheated liquid can be introduced in the column, whereby for the separation of the overheated liquid into liquid and vapor on the separating wall a box is mounted, wherein abuts a duct traversing the outer column wall and supplying the overheated liquid, whereby the box has a mist collector in its upper region and a liquid outlet in its lower region.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: December 3, 1996
    Assignee: Julius Montz GmbH
    Inventors: Helmut Jansen, Jochen Leben, Thomas Rietfort, Egon Zich
  • Patent number: 5565066
    Abstract: The present invention is a single vessel apparatus for separating at least a first component from a second component of a process stream. The apparatus has a vertically-elongated vessel which contains a plurality of vertically spaced apart distillation contactors for vapor and liquid distillation and an adsorbent-retaining volume defined at least in part by a solids-impermeable member located above the contactors for passing a fluid into the retaining volume. The apparatus also contains a mechanism for adding adsorbent above the solids-impermeable member and a mechanism for withdrawing adsorbent particles from the retaining volume to contact the fluid with adsorbent particles and to provide at least intermittent downward gravity flow of adsorbent particles through the retaining volume and to selectively adsorb a portion of the fluid.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: October 15, 1996
    Assignee: UOP
    Inventors: Terry L. Marker, Santi Kulprathipanja, Simon H. Hobbs
  • Patent number: 5558746
    Abstract: A method and apparatus for quenching a gas stream in the production of vinyl chloride monomer includes the use of a knock back condenser and a plurality of column fractional distillation trays disposed within the quench column, and a liquid stream of 1,2-dichloroethane, vinyl chloride, and hydrogen chloride may be removed from the bottom column fractional distillation tray.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 24, 1996
    Assignee: Westlake Monomers Corporation
    Inventor: James E. Best
  • Patent number: 5558748
    Abstract: A plate-type distillation/condensation apparatus and a method of using same to separate at least two volatility-differing liquid or vapor components from a mixed fluid stream thereof are disclosed, wherein the apparatus contains at least one flow plate having formed on a common facial surface thereof at least one distillation/condensation chamber containing an inlet port for the mixed fluid stream; a primary flow channel in fluid communication with the inlet port; one heat exchange conduits, wherein (i) a first heat exchange conduit for a first cooling fluid is disposed in a first heat exchange contact with the primary flow channel sufficient to condense at least a portion of a first vapor component into a first condensate phase, or (ii) a first heat exchange conduit for a heating fluid is disposed in a second heat exchange contact with the primary flow channel sufficient to boil at least a portion of a first liquid component into a first vapor phase, and a second heat exchange conduit for a second cooling fl
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: September 24, 1996
    Assignee: BASF Corporation
    Inventor: Jeffrey S. Dugan
  • Patent number: 5556516
    Abstract: 1-aminopropanediol-2,3 containing 2-aminopropanediol-1,3 of less than 0.30% by weight can be prepared by the present purification process, which involves distilling a 1-aminopropanediol-2,3 containing at least 0.3% of 2-aminopropanediol-1,3 based on the weight of 1-aminopropanediol-2,3 using a distillation column, said distillation column having low pressure loss.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: September 17, 1996
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroshi Koyama, Etsuo Takemoto
  • Patent number: 5537840
    Abstract: A downflow heat exchanger, particularly applicable as the main condenser/reboiler of a double column cryogenic air separation plant, wherein liquid distribution for uniform flow is carried out above the vapor passages and the well distributed liquid is passed into the liquid passages, preferably angularly onto the bridge fins, and then down through the liquid passages cocurrently with vapor in adjacent vapor passages.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: July 23, 1996
    Assignee: Praxair Technology, Inc.
    Inventors: Vijayaraghavan Srinivasan, Michael J. Lockett, John H. Ziemer
  • Patent number: 5535877
    Abstract: A method and apparatus for removing water from a solution of water and glycol solution. The apparatus finds application in recycling of glycol wherein a water and glycol solution having as much as a 95% water content when introduced to the apparatus leaves the apparatus with a water content in the order of 40% to 60%. The glycol concentrator has a packing medium made from glass shards that provide a labyrinth through which air is circulated in one direction and thin streams of glycol are circulated in generally the opposite direction. It is believed that mixing of the thin streams of solution and air flow steams in the labyrinth results in a thin film evaporation process. The glycol concentrator apparatus has reduced energy requirements when compared with a distilling process.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: July 16, 1996
    Inventors: Peter d. Eastcott, Nicole A. Truman, Peter Truman
  • Patent number: 5518667
    Abstract: The distributor includes a pattern of irrigation points with advantageously substantially constant surface pitch over most of the irrigation area, the pattern being, typically, regular in a main region of the distributor and irregular, with associated surface regions which are also irregular in a junction region, the irrigation points delivering predetermined flow rates defined by calibrated orifices which have cross-sections chosen from a predetermined group of n cross-sections, n not being greater than four and advantageously not greater than two. This distributor is particularly applicable to packed air distillation columns.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: May 21, 1996
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude et L'Exploitation des Procedes Georges Claude
    Inventor: Jean-Yves Lehman
  • Patent number: 5512140
    Abstract: This invention discloses a method of in-service cleaning an operating column by inserting into the column a lance through which a compatible liquid is dispensed at a pressure of at least about 5000 psig. Also disclosed is apparatus which comprises a column through which a fluid can pass, nozzles mounted on the outside of the column, where each nozzle comprises a flange welded to the column and a valve bolted to the flange, a lance which can be inserted through the nozzles into the column and means for dispensing a liquid through the lance at a pressure of at least about 5000 psig.
    Type: Grant
    Filed: January 11, 1994
    Date of Patent: April 30, 1996
    Assignee: Occidental Chemical Corporation
    Inventor: Charles R. Rutan
  • Patent number: 5507356
    Abstract: Column having integrated heat exchangerA column is described including a column body (1) and at least one heat exchanger (2) installed directly on the column head. This heat exchanger is a plate heat exchanger which is specially arranged so that the condensing vapors and the condensate (12) generated on the exchanger surface move in one direction.A further embodiment of the invention relates to a column which contains a column body (1) and at least one plate heat exchanger installed between two trays and/or packing beds within the column, which plate heat exchanger is operated as a condenser and is situated within a collecting vessel (29) open at the top.A third embodiment of the invention relates to a column which includes a column body (1) and at least one plate heat exchanger (2), which is operated as an evaporator, and which is installed within the column between two trays and/or packing beds and/or in the bottom.The column according to the invention is distinguished by a space-saving construction.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: April 16, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Peter M. Roth, Siegfried Rewitzer
  • Patent number: 5507919
    Abstract: An apparatus and method are provided for the defluorination of a liquid hydrocarbon mixture, containing organic fluorides, produced during the conversion of hydrocarbons using a fluorine-containing catalyst. In one embodiment, both a thermal means and a contacting material are used to effectuate a more complete defluorination. The liquid hydrocarbon mixture is extracted from a distillation column and heated sufficiently in the thermal means to decompose at least some of the organic fluorides. The effluent from the thermal means is separated into a vaporous and a liquid effluent. The liquid effluent is passed to the bottom of the distillation column where it undergoes further defluorination through contact with the contacting material.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: April 16, 1996
    Assignee: Phillips Petroleum Company
    Inventors: Scott D. Love, Stone P. Washer
  • Patent number: 5501079
    Abstract: An apparatus and process for cryogenic separation of air are described which utilize a pipe distributor or a channel distributor for liquid distribution. The air separation apparatus contains a rectifying column having at least one section equipped with packing materials, wherein a liquid distributor is positioned thereabove. The main channel and/or the distributing channels of the liquid distributor are closed over at least a portion of their top. Also described is a liquid distributor for use in a mass transfer column.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: March 26, 1996
    Assignee: Linde Aktiengesellschaft
    Inventors: Helmut Kreis, Anton Moll, Karl H. Stiegler
  • Patent number: 5500096
    Abstract: The invention relates to an improved method and a novel apparatus for the concentration, separation, and purification of contaminated chemical compounds, wherein the chemical compound is less volatile than the contaminant. The distillation is performed using constant, predetermined distillation parameters.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 19, 1996
    Assignee: Alliance Pharmaceutical Corp.
    Inventor: Wallace I. Yuan
  • Patent number: 5496446
    Abstract: A reaction with distillation structure utilizes a plurality of distillation trays and catalyst containers which provide a catalytic reaction zone and a primary flow path for descending liquid streams. Catalytic reaction of the liquid streams within the catalyst reaction zone formed in the containers occurs concurrently with fractionation of the reaction products on the distillation trays. The containers may extend continuously through the reaction zone of the distillation reactor to allow for dump loading and removal of the solid particulate catalyst. Alternatively, the catalyst containers may extend from one tray toward a lower tray without passing through the latter. Structure may also be provided within the containers to influence system hydraulics through the accumulation of liquid within the catalyst bed. This is done by providing an open area interiorly of the catalyst bed into which liquid on the distillation tray is driven.
    Type: Grant
    Filed: October 13, 1993
    Date of Patent: March 5, 1996
    Assignee: Koch Engineering Company, Inc.
    Inventors: Neil Yeoman, Ronald Pinaire, Michael A. Ulowetz, Timothy P. Nace, David A. Furse
  • Patent number: 5492603
    Abstract: Disclosed is a method and apparatus for recovering acetic acid from an acetic acid/water waste stream which includes a dehydration column into which the stream is fed and a liquid-liquid extraction system for recovering acetic acid from the condensate of the overhead stream of the dehydration column. Optionally, low pressure and/or high pressure absorber systems are provided to process vapor and/or liquid streams associated with the recovery system and/or the plant in which the acetic acid is used to further the recovery of acetic acid and reduce atmospheric pollution.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: February 20, 1996
    Assignee: Glitsch, Inc.
    Inventors: Ronald G. Gualy, Wiston Lamshing, Joseph C. Gentry, Fernando Varela
  • Patent number: 5472574
    Abstract: Bands used in fractionating columns, and more specifically, to the type made from either a metal screen strip or from a Teflon sheet twisted into a helicoid. In addition to previously documented design characteristics, the present spinning band includes a number of additional, circular apertures cut into the face of the metal screen strip and Teflon sheet. The circular apertures, sequentially arranged along the centerline of the band, add to the operating efficiency of the spinning band as it is employed in a fractionation process.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: December 5, 1995
    Inventor: Roger R. Roark, Sr.
  • Patent number: 5470441
    Abstract: An apparatus for vaporizing volatile liquids comprises a packed column, a gas inlet port (for introducing a hot entrainer gas), a feed tube (for introducing a volatile liquid), a feed distributor comprising a base plate equipped with orifices (through which the liquid flows downward into the packed column) and risers (through which the formed gaseous mixture of entrainer gas and vaporized liquid flows upward), and a gas outlet port. This apparatus can be used to vaporize volatile liquids, preferably volatile tin compounds, optionally in admixture with volatile silicon compounds, wherein steam is used as the entrainer gas.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: November 28, 1995
    Assignee: Phillips Petroleum Company
    Inventor: Ronald E. Brown
  • Patent number: 5466419
    Abstract: This invention relates to a vertically disposed polymerization reactor having a series of essentially circular tray assemblies; each tray assembly having a central open vapor chimney and two split-flow paths each split-flow path containing one reverse flow path wherein the liquid polymer flow is reversed by means of a substantially semi-circular turnaround region; each tray having a liquid polymer tray inlet and a liquid polymer tray outlet for conducting a flow of the liquid polymer by means of a hydraulic gradient; each tray assembly being open at the top for escape of vapor from the liquid polymer flow to the central open vapor chimney; and each tray arranged in vertical disposition one above the other.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: November 14, 1995
    Inventors: Thomas L. Yount, Larry C. Windes, J. Wesley Adams
  • Patent number: 5464590
    Abstract: This invention relates to a vertically disposed polymerization reactor having a series of essentially circular tray assemblies; each tray assembly having a central open vapor chimney and a single flow path composed of at least two loops wherein the liquid polymer flow is reversed by means of a substantially semi-circular turnaround wall; each tray having a liquid polymer tray inlet and a liquid polymer tray outlet for conducting a flow of the liquid polymer by means of a hydraulic gradient; each tray assembly being open at the top for escape of vapor from the liquid polymer flow to the central open vapor chimney; and each tray arranged in vertical disposition one above the other.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: November 7, 1995
    Inventors: Thomas L. Yount, J. Wesley Adams, Larry C. Windes
  • Patent number: 5454913
    Abstract: A reaction with distillation structure utilizes a plurality of distillation trays and catalyst containers which provide a catalytic reaction zone and a primary flow path for descending liquid streams. Catalytic reaction of the liquid streams within the catalyst reaction zone formed in the containers occurs concurrently with fractionation of the reaction products on the distillation trays. The containers may extend continuously through the reaction zone of the distillation reactor to allow for dump loading and removal of the solid particulate catalyst. Alternatively, the catalyst containers may extend from one tray toward a lower tray without passing through the latter. Structure may also be provided within the containers to influence system hydraulics through the accumulation of liquid within the catalyst bed. This is done by providing an open area interiorly of the catalyst bed into which liquid on the distillation tray is driven.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: October 3, 1995
    Assignee: Koch Engineering Company, Inc.
    Inventors: Neil Yeoman, Ronald Pinaire, Michael A. Ulowetz, Timothy P. Nace, David A. Furse
  • Patent number: 5453165
    Abstract: A system and method for reducing hydrocarbons in wastewater includes an oil separator and a stripper tower. The tower has a housing that includes a stripper section and a condensation section. The stripper section includes a plurality of trays and steam inlet under the trays. The condensation section includes a plurality of trays and a pan tray having provisions to allow vapors to rise from the stripper section.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: September 26, 1995
    Assignee: Atlantic Richfield Company
    Inventor: David E. Bachmann