Abstract: The present invention relates to a method and an apparatus for producing a fertilizer by injecting ammonia into and applying electron beam to gas containing sulfur oxides. Gas containing sulfur oxides is cooled by a heat exchanger (2) and a cooling tower (3), and thereafter introduced into a process vessel (4) in which ammonia is injected into the gas and the gas is irradiated with electron beam. The product of the ratio of the concentration of ammonia to the concentration of water in the gas prior to irradiation of the electron beam and the ratio of the concentration of ammonia to the concentration of water in the gas after irradiation of the electron beam is controlled to be of a predetermined value.
Abstract: The present invention relates to a method and an apparatus for producing a fertilizer by injecting ammonia into and applying electron beam to gas containing sulfur oxides. Gas containing sulfur oxides is cooled by a heat exchanger (2) and a cooling tower (3), and thereafter introduced into a process vessel (4) in which ammonia is injected into the gas and the gas is irradiated with electron beam. The product of the ratio of the concentration of ammonia to the concentration of water in the gas prior to irradiation of the electron beam and the ratio of the concentration of ammonia to the concentration of water in the gas after irradiation of the electron beam is controlled to be of a predetermined value.
Abstract: This invention relates to improvements in processes and catalysts for elevated temperature, gas phase, catalyzed reactions in general; it is particularly illustrated by reference to the manufacture of hydrogen cyanide.
Type:
Grant
Filed:
November 10, 1998
Date of Patent:
November 13, 2001
Assignee:
E.I. du Pont de Nemours and Company
Inventors:
Mehrdad Mehdizadeh, Theodore A. Koch, Karl Robert Krause, Sourav Kumar Sengupta, Benny Earl Blackwell
Abstract: Hydrogen cyanide is produced by reacting ammonia and a hydrocarbon gas in the presence of a platinum-group-metal catalyst while the catalyst is heated by induction heating at a frequency of 0.5 to 30 MHz.
Type:
Grant
Filed:
August 7, 1996
Date of Patent:
September 11, 2001
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Ronald Jack Riegert, Mehrdad Mehdizadeh
Abstract: A process for destroying aromatic compounds in an exhaust gas containing also sulfur dioxide, nitrogen oxides and dust, first the dust is removed at a temperature of between room temperature and 150° C. to a residual quantity of not more than 50 mg/m3,the sulfur dioxide is removed to a residual quantity of not more than 1000 mg/m3, the nitrogen oxides are removed to a residual quantity of not more than 300 mg/m3 and the exhaust gas is then subjected to electron irradiation having an energy of 3 to 10 kWh/1000 m3 exhaust gas.
Type:
Grant
Filed:
November 27, 1998
Date of Patent:
April 24, 2001
Assignee:
Forschungszenlrum Karlsruhe GmbH
Inventors:
Hanns Paur, Hartmut Mätzing, Werner Baumann, Axel Fengler
Abstract: A method of forming oxide from nitride, in which the oxidation is enhanced by illuminating the nitride material with UV light. This method produces a rapid growth of oxide and allows for the monitoring of the oxide thickness in situ. The method comprises the steps of (i) placing the nitride material on an illuminating holder; (ii) dipping the nitride material and the illuminating holder in an electrolyte; and (iii) illuminating the nitride material with a light having an energy larger than the energy gap of the nitride material. The nitride material can be connected to a conductive electrode located in the electrolyte via a galvanometer to monitor a photo current generated by the oxidation of the nitride material so as to monitor the thickness of the oxide formed on the nitride material in situ. A metal coating can be coated on the nitride material to define the oxide forming region. The pH value of the electrolyte is in a range of approximately 3 to 10, and is preferably about 3.5.
Type:
Grant
Filed:
April 7, 1999
Date of Patent:
February 20, 2001
Assignee:
Industrial Technology Research Institute
Abstract: A method and apparatus for treating gas by irradiation with an electron beam. Flue gas discharged from a fuel combustion facility is treated with an electron beam to remove sulfur oxides and/or nitrogen oxides. Ammonia is added to the flue gas and the mixed gas is irradiated with an electron beam in a process vessel. A dust collector receives the gas and collects a by-product mainly composed of ammonium sulfate and/or ammonium nitrate which is produced by the reaction in the process vessel. A gas-contacting portion extending from the process vessel to the dust collector is cooled either wholly or partly, to a dew point of the gas or below.