Anode Contains Precious Metal Or Free Carbon Patents (Class 204/196.38)
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Patent number: 11187670Abstract: Embodiments relate generally to systems and methods for preventing reaction between a sealing material (epoxy) and an electrolyte material within a carbon monoxide (or other gas) sensor. In general, the electrochemical sensor disclosed herein comprises a gas diffusion working electrode, a counter electrode, and optionally, a reference electrode. Each electrode is in contact with an aqueous electrolyte. The gas sensor may comprise a tab located proximate to gaps in the housing of the sensor, wherein the tab prevents any sealing material that fills the gaps from entering the interior of the housing. In some embodiments, the tab may be attached to a counter electrode. In some embodiments, the housing may comprise a slot located about the gaps, wherein the tab fits into the slot of the housing.Type: GrantFiled: January 29, 2016Date of Patent: November 30, 2021Assignee: HONEYWELL INTERNATIONAL INC.Inventors: Ling Liu, Yan Zhang, Na Wei, Fucheng Zhang
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Patent number: 10103395Abstract: A hydrogen extraction system is provided. The extraction system can comprise a compressor for compressing a gas mixture comprising hydrogen and a desulfurization unit for receiving the compressed gas mixture. The system can also comprise a hydrogen-extraction device for receiving a reduced-sulfur gas mixture and a hydrogen storage device for receiving an extracted hydrogen gas. A method of extracting hydrogen from a gas mixture comprising natural gas and hydrogen, and a method of determining an energy price are also provided.Type: GrantFiled: November 17, 2016Date of Patent: October 16, 2018Assignee: Nuvera Fuel Cells, LLCInventors: Darryl Pollica, Scott Blanchet, Zhijiang Li
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Patent number: 10037836Abstract: A technique for manufacturing slickline with a jacket of enhanced bonding. The technique may include roughening an outer surface of a metal core and applying an initial insulating polymer layer to the roughened core in a non-compression manner such as by tubing extrusion. The insulated core may then be heated and run through a set of shaping rollers. Thus, the grip between the polymer and the underlying metal core may be enhanced at a time following the initial placement of the polymer on the core. In this manner, processing damage to the underlying core surface which might adversely affect maintaining the grip may be minimized. Other techniques such as powder spray delivery of the initial polymer layer may also be utilized in a similar manner.Type: GrantFiled: April 3, 2015Date of Patent: July 31, 2018Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Joseph Varkey, Burcu Unal Altintas, Jushik Yun, Dong Yang, Sheng Chang, Ramnik Singh
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Patent number: 9546095Abstract: The invention provides a preparation process of transition metal boride, comprising the following steps: A) aluminum is put in a reactor, inert gas is fed into the reactor after evacuation, the reactor is heated up to 700 to 800° C. and then added with dry potassium fluoborate or sodium fluoborate, monomer boron and cryolite are generated by rapid stirring and reaction for 4 to 6 hours, and the molten liquid at the upper layer is sucked out and the monomer boron is obtained by means of separation; and B) the obtained monomer boron is added with transition metal for reaction at the temperature from 1800 to 2200° C. in order to generate corresponding transition metal boride.Type: GrantFiled: January 22, 2014Date of Patent: January 17, 2017Assignee: SHENZHEN SUNXING LIGHT ALLOYS MATERIALS CO., LTD.Inventors: Xuemin Chen, Jun Yang, Zhihong Li, Weiping Wu
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Publication number: 20140339075Abstract: The use, in corrosion protection systems, dewatering systems, and systems to reduce biofouling, of an anode which comprises a conductive polymer composition comprising a polymer and, mixed with the polymer, a conductive filler which comprises an exfoliated graphite.Type: ApplicationFiled: January 5, 2013Publication date: November 20, 2014Inventors: Ray F. Stewart, John Lahlouh
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Publication number: 20140251793Abstract: Mixed-metal-oxide (MMO) coated precious-metal tape is installed directly on concrete surfaces using an electrically non-conductive adhesive with semi-conductive coating or overlay, thereby obviating the need for slots or holes to the concrete structures which are not subject to direct moisture. The tape anodes may be installed on the concrete surfaces exposing metals without developing an electrical short circuit between the anode and the metals due to the non-conductive adhesive. The semi-conductive layer over the metal tape can distribute the CP current uniformly to the entire concrete surface without developing electrical short circuit. Overall the invention provides for quick and low cost installation on many concrete structures. Interconnections between the tape anodes and bare metal distribution elements may be made with conductive adhesive or spot welding.Type: ApplicationFiled: March 7, 2013Publication date: September 11, 2014Applicants: SAE INC., MUI CO.Inventors: Miki Funahashi, B. Todd Sirola
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Publication number: 20140224670Abstract: To provide an anode, corrosion-protecting structure of a concrete constructions using this, and a corrosion protection method capable of protecting electrical corrosion, with little generation of gas due to electrolysis of water or chlorine compounds, by decreasing as far as possible the amount of processing performed on the structural body in on-site construction work and suppressing the voltage that is conducted therethrough to a low level. [Solution] A corrosion-protecting structure (1) is constituted by attaching an anode (10) to the surface layer (3) of a corrosion-protecting body (4) through a first electrolyte layer (12) on one face of a conductive layer (11) formed as a sheet. The electrolyte is formed as a sheet. The first electrolyte layer (12) having adhesiveness is attached to the conductive layer (11) and the surface layer (3) of the corrosion-protecting body (4).Type: ApplicationFiled: August 24, 2012Publication date: August 14, 2014Applicants: FUJIMOROI KOGYO CO., LTD., SHO-BOND CORPORATIONInventors: Yasuto Ishikawa, Shirou Yamamoto, Hirokazu Iiduka, Jun Suzuki, Tsutomu Nakamura, Norimasa Mimura, Yuichi Futaki
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Publication number: 20130284604Abstract: Apparatus and methods for electroplating metal onto substrates are disclosed. The electroplating apparatus comprise an electroplating cell and at least one oxidization device. The electroplating cell comprises a cathode chamber and an anode chamber separated by a porous barrier that allows metal cations to pass through but prevents organic particles from crossing. The oxidation device (ODD) is configured to oxidize cations of the metal to be electroplated onto the substrate, which cations are present in the anolyte during electroplating. In some embodiments, the ODD is implemented as a carbon anode that removes Cu(I) from the anolyte electrochemically. In other embodiments, the ODD is implemented as an oxygenation device (OGD) or an impressed current cathodic protection anode (ICCP anode), both of which increase oxygen concentration in anolyte solutions. Methods for efficient electroplating are also disclosed.Type: ApplicationFiled: April 24, 2013Publication date: October 31, 2013Inventors: Tighe A. Spurlin, Charles L. Merrill, Ludan Huang, Matthew Thorum, Lee Brogan, James E. Duncan, Frederick D. Wilmot, Marshall R. Stowell, Steven T. Mayer, Haiying Fu, David W. Porter, Shantinath Ghongadi, Jonathan D. Reid, Hyosang S. Lee, Mark J. Willey
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Patent number: 8557089Abstract: An anode assembly for an impressed current cathodic protection system is disclosed. The anode assembly is arranged to protect a structure in a body of water. It includes an anode, an anode support and a base and is arranged to be electrically connected to the cathodic protection system. The base is a weighted member. The anode comprises a spherical hollow titanium body coated with a mixed metal oxide and filled with a non-conductive material. The anode support is an elongated titanium tube that projects upward from the base. The anode is welded on the top portion of the support to be disposed above the bed of the body of water. The anode assembly is connected to the cathodic protection system by an electrical connector mounted in a box.Type: GrantFiled: February 6, 2012Date of Patent: October 15, 2013Assignee: Matcor, Inc.Inventor: William R. Schutt
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Publication number: 20130168261Abstract: It is described a metal anode for cathodic protection in form of mesh ribbon having meshes whose holes are of rhomboidal shape, characterised by having such holes of rhomboidal shape arranged with the major diagonal oriented along the direction of the ribbon length and by the fact that the side edges along the ribbon length are free from cutting protrusions. It is also described a method for obtaining such anode.Type: ApplicationFiled: September 15, 2011Publication date: July 4, 2013Applicant: INDUSTRIE DE NORA S.P.A.Inventors: Corrado Mojana, Simone Tremolada
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Publication number: 20120305386Abstract: An anode assembly for an impressed current cathodic protection system is disclosed. The anode assembly is arranged to protect a structure in a body of water. It includes an anode, an anode support and a base and is arranged to be electrically connected to the cathodic protection system. The base is a weighted member. The anode comprises a spherical hollow titanium body coated with a mixed metal oxide and filled with a non-conductive material. The anode support is an elongated titanium tube that projects upward from the base. The anode is welded on the top portion of the support to be disposed above the bed of the body of water. The anode assembly is connected to the cathodic protection system by an electrical connector mounted in a box.Type: ApplicationFiled: February 6, 2012Publication date: December 6, 2012Applicant: MATCOR, INC.Inventor: William R. Schutt
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Patent number: 8277618Abstract: The present invention relates to an electrochemical cell comprising a vibratile electrode (eg a vibratile microelectrode).Type: GrantFiled: May 9, 2007Date of Patent: October 2, 2012Assignee: The University of LiverpoolInventors: Conrad S. Chapman, Constant M. G. Van Den Berg
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Publication number: 20120000769Abstract: Electrolytic protection of steel-reinforced concrete bodies such as bridges and building facades is achieved with carbon material inserted into the concrete body. The carbon material is connected to act as a anode with the steel reinforcement as a cathode, so that corrosive chloride ions migrate away from the steel reinforcement. The carbon material is inserted so as also to act as a reinforcement. In one arrangement carbon textile material is provided between inner and outer grout-filled plastics ducts fixed around post-tensioned steel cables. In another arrangement a carbon rod, or pin, is fixed between a concrete body and a steel I-beam.Type: ApplicationFiled: September 16, 2011Publication date: January 5, 2012Applicant: SIKA TECHNOLOGY AGInventor: Graeme JONES
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Publication number: 20110299996Abstract: A gas turbine component and a method for producing an anti-erosion coating system are disclosed. The gas turbine component includes a basic material, on which an anti-erosion coating system is provided that is a multilayer system including at least one ductile metal layer and at least one hard, ceramics-containing layer for forming a partial anti-erosion system. At least one anti-corrosion layer that has a lower electrochemical potential than the basic material is provided between the partial anti-erosion system and the basic material, thus providing cathodic corrosion protection.Type: ApplicationFiled: January 30, 2010Publication date: December 8, 2011Applicant: MTU Aero Engines GmbHInventors: Thomas Uihlein, Wolfgang Eichmann, Falko Heutling
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Patent number: 8048288Abstract: Techniques are generally described herein for protecting food or beverage containers (e.g., cans) using impressed current protection. In various embodiments, containers may be received into at least one conductive bed, each bed having a complementary anode. The containers may then be electrically coupled to a first terminal (e.g., negative) of a power supply, and the anode may be electrically coupled to a second terminal (e.g., positive) of the power supply. Resultantly, protective current may be provided to the containers by the anode. Other embodiments may be disclosed and claimed.Type: GrantFiled: November 25, 2009Date of Patent: November 1, 2011Assignee: Empire Technology Development LLCInventor: Angele Sjong
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Publication number: 20110100802Abstract: An apparatus for protection of metallic materials from corrosion comprising an electrical power source (5) and a conductor (7) coupled to the power source. An anode (11) is electrically coupled to the conductor. The anode is configured to be secured proximal to the metallic materials to be protected from corrosion and has an exterior surface (13) formed predominantly of electrically conductive polymer and an interior filled with particulate carbonaceous material. The anode comprises a hollow cylinder (13) formed of electrically conductive polymer, the cylinder having an interior. A metallic tube (15) is secured to and in electrical communication with the interior of the cylinder. An anode conductor (17) is electrically coupled to the metallic tube and extends from the interior of the cylinder to the exterior of the cylinder for connection to the conductor coupled to the power source.Type: ApplicationFiled: March 26, 2009Publication date: May 5, 2011Inventor: Michael Steven Georgia
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Patent number: 7905993Abstract: Mixed-metal-oxide (MMO) coated precious-metal tape is installed directly on concrete surfaces using an electrically conductive adhesive, thereby obviating the need for slots, holes, cementitious grout or additional concrete. The electrically conductive adhesive is preferably formed by disposing mixed-metal-oxide (MMO) coated precious-metal particles in an adhesive layer. The tape anodes may be installed on the concrete surfaces including a shallow concrete cover or congested reinforcing steel without developing an electrical short circuit between the anode and the reinforcing steel. Overall the invention provides for quick and low cost installation on many concrete structures. Interconnections between the tape anodes and bare metal distribution elements may be made with conductive adhesive or spot welding.Type: GrantFiled: November 20, 2007Date of Patent: March 15, 2011Inventor: Miki Funahashi
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Patent number: 7879204Abstract: An anode configured for the cathodic protection of reinforced concrete structures and underground metallic structures against corrosion comprises a hollow, mixed-metal-oxide (MMO) coated form, the form having a wall with intentional gaps therethrough. A humectant is disposed in the hollow form, and a conduit between the hollow form and an ambient environment enables gasses produced by the form to escape to the environment while allowing the humectant to be periodically moistened with water or a high pH buffer solution. The form may be composed of titanium, tantalum, zirconium, niobium or alloys thereof, and the MMO coatings may be composed of titanium, tantalum, iridium, ruthenium, palladium, cobalt or mixtures thereof. The form may be a coiled wire or strip, a perforated tube, or other structure having gaps between the interior of the form and the surrounding concrete or soil.Type: GrantFiled: August 19, 2008Date of Patent: February 1, 2011Inventor: Miki Funahashi
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Patent number: 7764187Abstract: A cathodic protection device having a sacrificial anode that is intended to wear out due to corrosion and that is electrically connected to a structure to be protected against corrosion. The cathodic protection device of the present invention further includes an indication device configured to detect and indicate the wear of the sacrificial anode wirelessly, without the use of cables.Type: GrantFiled: August 16, 2007Date of Patent: July 27, 2010Assignee: Ultraflex S.p.A.Inventors: Giorgio Gai, Staiolo Alessandro
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Publication number: 20090127132Abstract: Mixed-metal-oxide (MMO) coated precious-metal tape is installed directly on concrete surfaces using an electrically conductive adhesive, thereby obviating the need for slots, holes, cementitious grout or additional concrete. The electrically conductive adhesive is preferably formed by disposing mixed-metal-oxide (MMO) coated precious-metal particles in an adhesive layer. The tape anodes may be installed on the concrete surfaces including a shallow concrete cover or congested reinforcing steel without developing an electrical short circuit between the anode and the reinforcing steel. Overall the invention provides for quick and low cost installation on many concrete structures. Interconnections between the tape anodes and bare metal distribution elements may be made with conductive adhesive or spot welding.Type: ApplicationFiled: November 20, 2007Publication date: May 21, 2009Inventor: Miki Funahashi
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Patent number: 6669837Abstract: A process for reducing the corrosion of nickel metal in an alkali metal hydroxide evaporator equipment which comprises the step of impressing a total protection potential directly upon the nickel metal material in alkali metal hydroxide evaporator that is in contact with an aqueous alkali metal hydroxide solution during evaporation of that solution; said total potential being sufficient to reduce the amount of corrosion of the nickel metal to an oxide that may dissolve in the alkali metal hydroxide solution.Type: GrantFiled: December 17, 2002Date of Patent: December 30, 2003Assignee: Sunbelt Chlor Alkali PartnershipInventors: Jonathan B. Diminnie, Sanders H. Moore, James F. Pickering, Thomas E. Corvin
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Patent number: 6514401Abstract: An anti-biofouling system adapted to be used for an underwater structure immersed in seawater is disclosed. The anti-biofouling system includes a conductive layer, comprising carbon fiber, graphite powder and binder, formed on a surface of the underwater structure for serving as an anode, a cathode, and a power supply for providing a current, thereby performing an electrolytic reaction for the anti-biofouling system such that a fouling organism is prohibited from attaching on the surface of the underwater structure.Type: GrantFiled: May 2, 2001Date of Patent: February 4, 2003Assignee: Taiwan Power CompanyInventors: San-Der Chyou, Wen-Chi Chiang, Ran Huang, Jiann-Kuo Wu
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Publication number: 20020162753Abstract: An anti-biofouling system adapted to be used for an underwater structure immersed in seawater is disclosed. The anti-biofouling system includes a conductive layer, comprising carbon fiber, graphite powder and binder, formed on a surface of the underwater structure for serving as an anode, a cathode, and a power supply for providing a current, thereby performing an electrolytic reaction for the anti-biofouling system such that a fouling organism is prohibited from attaching on the surface of the underwater structure.Type: ApplicationFiled: May 2, 2001Publication date: November 7, 2002Inventors: San-Der Chyou, Wen-Chi Chiang, Ran Huang, Jiann-Kuo Wu
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Patent number: 6423208Abstract: Control of lead contamination in residential water supplies is accomplished by cathodic protection of lead-containing piping and lead-containing fixtures. Specifically, a partially insulated wire is inserted into lead-containing service lateral piping. Application of a DC current to the partially insulated wire causes the wire to act as an anode and transforms the walls of the pipe into the cathode, thereby protecting against corrosion. Alternatively, a sacrificial anode is inserted into a lead-containing fixture. The electrical potential generated by corrosion of this sacrificial anode transforms the walls of the fixture into a cathode thereby preventing corrosion. Carbonate scaling built-up prior to the initiation of cathodic protection may be removed by temporarily blocking the water pipe and introducing cleaning chemicals.Type: GrantFiled: August 9, 2000Date of Patent: July 23, 2002Inventor: Larry L. Russell
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Patent number: 6361896Abstract: The invention relates to a device for combined purification and compression of hydrogen containing CO. Said device comprises a polymer electrolyte membrane (PEM) cell with a proton-conducting polymer membrane (3), an anode on one side of the membrane and a cathode (4) on the other side thereof. Said anode is in the form of a two-layer anode (5) which comprises a CO-oxidation-selective catalytic layer (1) on the side facing away from the membrane and an electrochemically active layer (2) for oxidation of the hydrogen to form protons on the side facing the membrane. The PEM cell also has a flat, porous gas distribution layer provided on the anode side and attached to a current collector. Consequently, the PEM cell resists differential pressures of at least approximately 10 bar. The invention also relates to a process for combined purification and compression of hydrogen containing CO using said device.Type: GrantFiled: March 4, 1999Date of Patent: March 26, 2002Assignee: Zentrum fur Sonnenenergie und Wasserstoff-Forschung Baden Wuetternberg Gemeinnuetzige StiftungInventors: Klaus Eberle, Bernd Rohland, Joachim Scholta, Raimund Stroebel
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Patent number: 6254743Abstract: This invention relates generally to an electrically conductive valve metal mesh of extreme void fraction. More particularly the invention relates in a most important aspect to an application thereof for an electrode structure in such a way as to prevent the corrosion of steel, including reinforcing steel in concrete, by cathodic protection.Type: GrantFiled: December 24, 1990Date of Patent: July 3, 2001Assignee: Eltech Systems CorporationInventors: John E. Bennett, Gerald R. Pohto, Thomas A. Mitchell
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Patent number: 6200397Abstract: A novel method and apparatus to apply a corrosion protection in the form of a zinc (or other sacrificial anodic material) tape to a tubular member such as pipe or coiled tubing to used as an underground or underwater pipeline or flow line is disclosed. The zinc tape is applied with sufficient heat and pressure to form a metallurgical bond between the zinc tape and underlying metal pipe. This allows the zinc tape to act simultaneously as a continuous protective metal barrier to the normal scrapes and nicks the pipe experiences during installation and as a sacrificial anode. The novel apparatus preheats the zinc tape with a nozzle containing heated gas such as nitrogen as it approaches the pipe surface. At the point of contact with the pipe surface, the nozzle continues heating the tape and pipe surface while a plurality of pressure rollers exert sufficient force on the zinc tape to form a metallurgical bond between the zinc tape and the pipe surface.Type: GrantFiled: November 8, 1999Date of Patent: March 13, 2001Inventor: John R. Allen