Abstract: The present disclosure is directed to an anticrater additive that is useful for providing a smooth surface to a cured layer of an electrocoating composition on a substrate. The anticrater additive comprises the reaction product of a polyisocyanate with an acrylic polymer having one isocyanate reactive functional group. The acrylic polymer can be an acrylic polymer that is terminated with a chain transfer agent. Also disclosed is an electrocoat composition comprising the anticrater additive and a substrate coated with a cured layer of the electrocoat composition.

Abstract: The invention relates to methods of preparation of highly sensitive potentiometric sensors with an electroconductive polymer film as a sensing element.

Abstract: An electrolytic cell system to convert carbon dioxide to a hydrocarbon that includes a first electrode including a substrate having a metal porous dendritic structure applied thereon; a second electrode, and an electrical input adapted for coupling to a source of electricity, for applying a voltage across the first electrode and the second electrode.

Abstract: Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent.

Abstract: The present invention relates to an electrodepositable coating composition comprising a crater control additive.

Abstract: A treatment method for treating the surface of a fluid dispenser device, said method comprising the step of using chemical grafting to form a thin film on at least one support surface of at least one component part that is in contact with said fluid, said thin film preventing interactions between said fluid and said component part.

Abstract: A composition for use in electrodeposition includes a resin blend, a coalescing solvent, a catalyst, water, and a highly cross-linked microgel, wherein at least 20 percent by weight of resin solids in the composition is the highly cross-linked microgel. Another composition for use in electrodeposition includes a surfactant blend, a low ion polyol, phenoxypropanol, a catalyst, water, a flexibilizer, and a highly cross-linked microgel, wherein at least 20 percent by weight of resin solids in the composition is the highly cross-linked microgel.

Abstract: Compositions comprising compounds having an aldohexose moiety, a highly fluorinated moiety, and a nitrogen-containing functional group linking the moieties together are disclosed. The aldohexose-based fluoroadditives are effective in reducing the surface tension of water and are useful in various surfactant applications. Also disclosed are processes for making aldohexose-based fluoroadditives.

Abstract: A method of improving the material properties of a composite by electrodepositing various polymers, organic compounds or inorganic compounds onto each individual carbon (graphite) fiber strand, whether individual fiber or as a fabric to form an homogeneous chemically-bonded composite as opposed to the formation of a heterogeneous, non-chemically bonded composite. Thus, electrodeposition forms a unique discrete interface at the molecular layer (nanolayer) between the reinforcement (fiber) and the matrix (resin) over as opposed to any previous resin infusion process.

Abstract: Provided with a work electrodeposition coating method for immersing a work in a paint in an electrodeposition tank provided with a first positive electrode for supplying a low voltage and a second positive electrode for supplying a high voltage to carry out electrodeposition coating of a work surface.

Abstract: A biosensor comprising an electrically conductive substrate coated with a modified chitosan biopolymer that has been electrodeposited on the substrate, wherein said modified chitosan biopolymer comprises at least one vesicle binding molecule. The biosensor is manufactured by a method where a modified chitosan biopolymer is electrodeposited on a substrate. The method is also used to manufacture a modified chitosan biopolymer film by electrodeposition of the chitosan on the substrate and later removing the film from the substrate after electrodeposition. The resulting film can be used in bandages to treat various types of wounds. The biosensor can also be used to detect various analytes in samples.

Abstract: The invention relates to the deposition or attachment of materials to surfaces. It relates to a process for coating a surface with a first material and a second material, comprising the following steps: placing the first material on the said surface, inserting into the first material placed on the said surface precursor molecules of the second material, converting the said precursor molecules of the second material inserted into the first material into the said second material such that this second material becomes formed on the said surface to be coated and within the said first material placed on the said surface. The object of the process of the invention is to allow the deposition of materials of any type onto surfaces of any type.

Abstract: Substituted selenophene monomers, and polymers and copolymers having units derived from a substituted selenophene are disclosed. Also provided are methods of making and using the same.

Abstract: A method for enhancing the friction resistance properties of a substrate comprising a step consisting of grafting onto all or part of the surface of said substrate a polymer organic film of the non-substituted polyphenylene type as well as to the thus prepared substrate.

Abstract: A method for producing an electrode having immobilized ?-conjugated ligands is provided. The method includes bringing an aqueous solution into contact with an electrically conductive base material, the aqueous solution including ?-conjugated ligands and at least one of (i) a surfactant, and (ii) a water-soluble molecule having a structure different from that of the ?-conjugated ligands, the water-soluble molecule having a ?-conjugated structure, and immobilizing the ?-conjugated ligands on the base material.

Abstract: A method for manufacturing a medical product comprising a hollow body (2), wherein at least part of a wall of the hollow body (2) is coated at least on the inside with a layer comprising a polymer; at least the part of at least the inside of the wall of the medical product is brought into contact with a mixture (6) of the polymer and the polymer is deposited from the mixture (6) on at least the part of the inside of the wall. And a medical product comprising a hollow body (2) with a wall consisting of one or more structural elements (16), at least a section of the wall being coated with a layer (15) comprising native chitosan, wherein both on the inside and the outside of the hollow body (2) at least some of the one or more structural elements (16) of the wall of the hollow body (2) are at least partly coated with the native chitosan layer (15). And a method for electrodepositing a polymer on an electrode from an acidic mixture of the polymer, wherein the mixture (6) comprises a multibasic acid.

Abstract: A composition comprising a fluorinated pyridinium cationic compound of formula (I) wherein Rf is R1(CH2CH2)n—, R1 is a C7 to C20 perfluoroalkyl group interrupted by at least one catenary oxygen atom, each oxygen bonded to two carbon atoms, n is an integer of 1 to 3, and R is H, C1 to C5 linear or branched alkyl, or C1 to C5 linear or branched alkoxy, having surfactant properties for lowering surface tension in an aqueous medium or solvent medium, and for use as a foaming agent.

Abstract: The present disclosure relates to an improved electrocoating coating composition wherein the improvement is the addition of a non-water reducible anticrater agent. The non-water reducible anticrater agent is a polyester that is the reaction product of an aliphatic carboxylic acid anhydride, a monofunctional epoxy compound, a monofunctional alcohol and a polyepoxide. The improved electrocoating composition provides cured coatings that have fewer craters and have a smooth surface when compared to coatings utilizing other anticrater additives.

Abstract: The present invention concerns a method for preparing an organic copolymer film on electrically conductive or semi-conductive surfaces in two steps. The first step includes electrolysis of an electrolytic solution containing an adhesion primer, in contact with a surface. The second step corresponds to the reaction, at the surface obtained previously, of a solution containing the following species: a protic solvent, and a “radically polymerizable” monomer. The polymerizable monomer is solubilized in micellar form. The surfaces obtained with the use of this method, and their applications apply to preparation of microelectronic components, biomedical devices or screening kits, as well as kits for preparing an organic copolymer film on an electrically conductive or semi-conductive surface.

Abstract: Disclosed are: a chemical conversion treatment solution for metal surfaces, which enables the formation of a chemical conversion coating film having excellent corrosion resistance and adhesion properties on metal base materials even though the solution does not contain chromium and fluorine, comprising at least one compound (A) selected from a water-soluble titanium compound and a water-soluble zirconium compound and an organic compound (B) that has multiple functional groups and can serve as a stabilizing agent, and which has a pH value of 2.0 to 6.5, wherein the content of the compound (A) is 0.1 to 10 mmol/L, and the content of the organic compound (B) is 2.5- to 10-fold larger than the content of the metal in the compound (A) by mole; and a method for treating the surface of a metal base material or a structure or body using the chemical conversion treatment solution for metal surfaces.

Abstract: A pharmaceutical composition is provided comprising a vitamin E derivative, an anionic phopholipid-binding protein, an anionic phospholipid and a sterol. Also provided is a method for preparing a composition for delivering a cargo to a subject comprising a) forming liposomes from a vitamin E derivative, an anionic phospholipid-binding protein such as annexin, an anionic phospholipid such as phosphatidylserine and a sterol; and b) encapsulating the cargo in the liposomal composition.

Abstract: Methods for the generation of hydrogels formed by electrodeposition of an electroaddressable polymer are described. The hydrogels may contain one or more cell populations electroaddressed or electroaddressable to a location within the hydrogel and where the cells of the cell populations are entrapped by the hydrogel and are capable of expansion within the hydrogel and may be releasable from the hydrogel. Further provided are electroaddressable polysaccharide blends for the in-film expansion of a cell population, allowing probing of the cells and formation of immunocomplexes. Further provided are methods of using hydrogels containing electroaddressed or electroaddressable cell populations in in-film bioprocessing methods such as cell-based biosensing, protein-based biosensing, and in studies of cell signaling.

Abstract: The present invention relates to a metal or alloy substrate having a modified surface, and more particularly a stainless steel substrate, produced by the use of an electrochemical process. The invention also relates generally to a method for producing a stable and covalent association between self-assembled layers and a surface of a metal substrate, and more particularly a stainless steel substrate. The metal or alloy substrate, and more particularly the stainless steel substrate, is modified by the covalent attachment of self-assembled monolayers on the surface by using an electrochemical process. These functionalized self-assembled monolayers provide a link to irreversibly attach or immobilize an active or nonactive agent.

Abstract: The present invention concerns the area of surface coatings in the form of organic films, the coatings being in the form of organic films. It most especially relates to a method for forming copolymer organic films by electrochemical grafting on electrically conductive or semi-conductive surfaces using electrolytic aqueous solutions containing at least one protic solvent, at least one radically polymerizable monomer and at least one surfactant. The invention also concerns surfaces obtained with the use of this method, their applications especially for preparation of microelectronic components, biomedical devices or screening kits, as well as the electrolyte solution used in the course of the method.

Abstract: Embodiments herein provide a membrane that is a product of a phenol crosslinked with one or more compounds containing an allyl group. The phenol may be electropolymerized with the allyl-containing compounds to form the crosslinked polymer. Suitable allyl-containing compounds include allylphenol, allylalcohol, allylamine, and allylcarbamide. A membrane may have one type of allyl-containing compound, or, alternatively, two or more types of compounds. As used in an analyte sensing device, a membrane formed from a crosslinked phenol may provide improved interference exclusion, peroxide response, stability, and/or solvent resistance.

Abstract: The use of at least one diazonium salt bearing an initiator function, for forming an undercoat obtained by grafting a graft derived from the diazonium salt and bearing an initiator function at the surface of a conductive or semiconductive material on the undercoat, and for forming on the undercoat a polymeric layer obtained by polymerization, in particular free radical polymerization, in situ of at least one monomer, initiated from the initiator function.

Abstract: The invention provides a protected metal anode architecture comprising: a metal anode layer; and an organic protection film formed over and optionally in direct contact with the metal anode layer, wherein the metal anode layer comprises a metal selected from the group consisting of an alkaline metal and an alkaline earth metal, and the organic protection film comprises a reaction product of the metal and an electron donor compound. The invention further provides a method of forming a protected metal anode architecture.

Abstract: An electrodeposition coating composition comprises an unhydrolyzed or at least partially hydrolyzed polyvinyl formamide polymer for improved edge coverage of the coating when plated onto a conductive substrate. The plated coating can be cured.

Abstract: A method includes: immersing a semiconductive substrate in an electrodeposition composition, wherein at least 20 percent by weight of resin solids in the composition is a highly cross-linked microgel component, and applying a voltage between the substrate and the composition to form a dielectric coating on the substrate. A composition for use in electrodeposition includes a resin blend, a coalescing solvent, a catalyst, water, and a highly cross-linked migrogel, wherein at least 20 percent by weight of resin solids in the composition is the highly cross-linked microgel. Another composition for use in electrodeposition includes a surfactant blend, a low ion polyol, phenoxypropanol, a catalyst, water, a flexibilizer, and a highly cross-linked migrogel, wherein at least 20 percent by weight of resin solids in the composition is the highly cross-linked microgel.

Abstract: A method of improving the material properties of a composite by electrodepositing particular polymers, organic compounds or inorganic compounds onto electrically conductive fibrous substrates, whether individual fibers or as a fabric, to form composites of improved structural properties and having particular physical properties such as being ice phobic, fire resistant, or electrically conductive.

Abstract: There is provided a resin composition for plating use in which all of plating adhesion strength, moldability, impact resistance, and low coefficient of linear expansion are excellent; and a resin plated product. The resin composition for plating use of the present invention is characterized by including a graft copolymer (A) formed by graft polymerizing a specific monomer component onto a rubber-like polymer (d) constituted of a conjugated diene-based rubber, and a specific copolymer (B), wherein a proportion of the rubber-like polymer (d) is 10 to 20% by mass, relative to the combined total of the graft copolymer (A) and the copolymer (B) which accounts for 100% by mass, and also 1 to 8 parts by mass of an antioxidant (C) having a melting point of 25 to 100° C. is added, relative to the combined total of the graft copolymer (A) and the copolymer (B) which accounts for 100 parts by mass.

Abstract: A method of forming a bioelectronic device including a protein on an electrically conductive substrate, by electro-depositing aminopolysaccharide chitosan on the substrate while applying a cathodic voltage to the substrate, to form an aminopolysaccharide chitosan film thereon, applying an anodic voltage to the substrate in the presence of NaCl to activate the aminopolysaccharide chitosan film so that it is reactive with protein. The method also optionally includes reacting the aminopolysaccharide film, after activation thereof, with the protein, so that the protein assembles on and is coupled to the substrate, thereby forming a bioelectronic device. The protein can include single or multiple protein species, and including biosensing proteins. Additional methods include biosensing of electrochemically active compounds either present in a sample or generated during a biological recognition event and devices useful in such methods.

Abstract: The present invention is directed to an electrodepositable coating composition comprising a non-solubilized zinc compound in an amount of at least 0.61 weight % based on the total resin solids of the electrodepositable coating composition.

Abstract: The present disclosure relates to a coating composition that can be applied to a conductive substrate via an anodic electrodeposition process, a substrate coated with the coating composition and a process for applying the coating to a substrate. The coating composition comprises an aqueous dispersion of at least partially neutralized copolymer comprising ?-olefin and unsaturated carboxylic acid. After a layer of the coating has been applied to the substrate, it can be heated to cure the coating and form a crosslinked network that provides a durable chip and corrosion resistant finish.

Abstract: A method of improving the material properties of a composite by electrodepositing particular polymers, organic compounds or inorganic compounds onto electrically conductive fibrous substrates, whether individual fibers or as a fabric, to form composites of improved structural properties and having particular physical properties such as being ice phobic, fire resistant, or electrically conductive.

Abstract: The invention relates to an aqueous coating composition containing (A) at least one organic binder that can be dispersed in water and contains cationic groups, and (B) 0.05-10 wt. %, in relation to the solid body content of the aqueous coating composition, of a water-dilutable vinylpyrrolidone copolymer. Said vinylpyrrolidone copolymer (B) contains vinylpyrrolidone monomer units and vinylacetate monomer units in a molar ratio of 0.3:0.7-0.7:0.3, preferably 0.4:0.6-0.6:0.4 and has an average molecular weight of less than 200.000 g/mol.

Abstract: The invention relates biosensor comprising a conductive or semi-conductive support and an intercalator polymer, wherein the intercalator polymer comprises monomer units of formula (I) wherein P is an electropolymerizable moiety selected among the group consisting in pyrrole, acetylene, phenol, aniline, thiophene, carbazole and azulene; Sp is a spacer, and Im is an intercalator. The invention also relates to a method for the detection of a DNA sequence with the biosensor, comprising the steps of: hybridizing the DNA sequence with a DNA probe for forming a dsDNA incubating the biosensor with the dsDNA for anchoring the dsDNA to the intercalator detecting the quantity of dsDNA on the biosensor.

Abstract: Object: To provide a coated article in which an electrodeposition coating film formed on an untreated steel sheet exhibits excellent corrosion resistance, in particular, excellent hot salt water immersion resistance at 55° C.; and a multilayer coating film formed by a 3-coat 1-bake coating method on the electrodeposition coating film, which is formed on the untreated steel sheet, exhibits excellent corrosion resistance in a combined corrosion cycle test. Means for Achieving the Object: The present invention provides a cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), metal compound (C), and nitrogen oxide ion (E), wherein metal compound (C) is contained in an amount of 10 to 10,000 ppm calculated as metal, and nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm relative to the mass of the cationic electrodeposition coating composition.

Abstract: This invention relates to methods and articles using compounds, polymeric compounds, and compositions for semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. A compound may contain repeating units {MB(ER)(ER)} and {MA(ER)(ER)}, wherein MA is a combination of Cu and Ag, each MB is In or Ga, each E is S, Se, or Te, and each R is independently selected, for each occurrence, from alkyl, aryl, heteroaryl, alkenyl, amido, silyl, and inorganic and organic ligands.

Abstract: This invention relates to methods and articles using compounds, polymeric compounds, and compositions used to prepare semiconductor and optoelectronic materials and devices including thin film and band gap materials. This invention provides a range of compounds, polymeric compounds, compositions, materials and methods directed ultimately toward photovoltaic applications, transparent conductive materials, as well as devices and systems for energy conversion, including solar cells. In particular, this invention relates to polymeric precursor compounds and precursor materials for preparing photovoltaic layers. In particular, this invention relates to molecular precursor compounds and precursor materials for preparing photovoltaic layers including CAIGAS.

Abstract: A method is provided for electrochemically depositing a polysaccharide mass having a selected physical state. According to an embodiment, an electrically conductive support of a substrate is contacted with an aqueous solution including a selectively insolubilizable polysaccharide, and the selectively insolubilizable polysaccharide is electrochemically deposited on the electrically conductive support while controlling deposition conditions to form the polysaccharide mass having the selected physical state, such as that of a hydrogel. Deposition may be performed in a spatially and/or temporally controlled manner.

Abstract: The present invention is directed towards an electrocoating composition comprising a cyclic guanidine.

Abstract: The present invention relates to a method of manufacturing conductive fibers, more precisely a method of manufacturing conductive fibers comprising the steps of coating silver complex compound coating solution on non-conductive fibers to coat the fibers with silver complex compound; heating the fibers to form a silver coating layer; and forming an antioxidant layer thereon, and conductive fibers prepared by the same. The method of manufacturing conductive fibers of the present invention not only is simple and easy but also requires low production costs. So, the conductive fibers prepared by the method of the present invention are not only excellent in conductivity but also excellent in other mechanical properties such as adhesive strength of the conductive layer, fiber strength and softness, etc.

Abstract: This invention relates to the electrochemical deposition of carbon nanotubes (“CNTs”) on a substrate using an electrochemical cell. A dispersion of a complex of CNTs and an anionic polymer is neutralized and thereby caused to deposit on the anode plate of the cell.

Abstract: The invention is directed to formation and use of electroprocessed fibrin as an extracellular matrix and, together with cells, its use in forming engineered tissue. The engineered tissue can include the synthetic manufacture of specific organs or tissues which may be implanted into a recipient. The electroprocessed fibrin may also be combined with other molecules in order to deliver the molecules to the site of application or implantation of the electroprocessed fibrin. The fibrin or fibrin/cell suspension is electrodeposited onto a substrite to form the tissues and organs.

Abstract: The present invention provides an alloy film of Mn or its Fe—Mn is depositable on a metalized alumina ceramic (Al2O3-SiO3) substrate for hermetically sealed glass-metal fusion used for aircraft switch assemblies. The coefficient of thermal expansion of Fe—Mn alloys appear to be fairly low, nearer to that of glass. Fe—Mn alloy film is an alternative to Fe64—Ni36 alloy films (Invar) normally used for glass to glass fusion purposes. Fe—Mn alloy films is also depositable directly on bare Alumina (Al2O3) substrate with or without zincating pretreatment. Similarly bright, smooth coherent film of Mn—Au or Fe—Mn—Ni Au alloys is depositable from an aqueous solution of simple salt bath or on Cu substrate without the use of cyanide without bridging with zincate processes.

Abstract: A pigmented granular pigmented coating feedstock is prepared by melting a resin, which can be a solid resin based on polymerizable ethylenically unsaturated monomer or epoxy based resin, and a solid or viscous curing agent, blending the molten mass, and cooling to form a solid. The solid blend of resin and curing agent is ground to produce a granular feedstock. The feedstock is readily storable or shippable to a location for coating preparation. Alternatively a solid coating can be ground after shipping. An aqueous coating is made by dispersing the feedstock in water and mixing to form a dispersion. A salting agent and at least one additive can be added to form an aqueous coating composition. An article can be coated with the dispersion, for example, by electrodeposition.

Abstract: Disclosed are methods for making aqueous dispersions of polymer-enclosed particles, such as nanoparticles, polymerizable polymers useful in such a method, and cationic electrodepositable compositions comprising such aqueous dispersions.

Abstract: The invention relates to an anti-corrosion system for metals consisting of at least one finish or coating that can be applied to a metal, said finish or coating comprising an organic matrix. The organic matrix also contains anti-corrosion pigments, which are finely distributed throughout the organic matrix. The anti-corrosion pigments are formed from a metal alloy of at least two metals and optionally from inevitable impurities. The invention also relates to a corresponding anti-corrosion pigment.

Abstract: The invention relates to a process for forming a polymeric organic film on an electrically conductive or semiconductive surface by application of an electric potential between a gel, in contact with said surface, and said surface, the gel comprising (i) a protic solvent, (ii) compounds having colloidal properties, (iii) an adhesion primer, optionally (iv) a monomer and the potential applied being at least equal to the reduction potential of the adhesion primer. The invention also relates to said gel, to its use and to a kit for forming an organic film.