Superconductor Preparation Involving Electrolytic Marking, Electroforming Or Electrolytic Coating, Or Composition Therefor Patents (Class 205/51)
  • Patent number: 9343649
    Abstract: The invention provides a method for preparing superconducting cavities, the method comprising causing polishing media to tumble by centrifugal barrel polishing within the cavities for a time sufficient to attain a surface smoothness of less than 15 nm root mean square roughness over approximately a 1 mm2 scan area. The method also provides for a method for preparing superconducting cavities, the method comprising causing polishing media bound to a carrier to tumble within the cavities. The method also provides for a method for preparing superconducting cavities, the method comprising causing polishing media in a slurry to tumble within the cavities.
    Type: Grant
    Filed: April 3, 2015
    Date of Patent: May 17, 2016
    Assignee: U.S. Department of Energy
    Inventor: Charles A. Cooper
  • Patent number: 9103044
    Abstract: An object of the present invention is to provide electrolytic manganese dioxide to be used as a cathode active material for an alkali-manganese dry cell, which has a high alkali potential and is provided with a high reactivity and packing efficiency as a cathode for the cell, and which is excellent in the middle rate discharge characteristic, and electrolytic manganese dioxide excellent in the high rate discharge characteristic and the middle rate discharge characteristic, which will not cause corrosion of metal materials, and a method for its production. In the present invention, electrolytic manganese dioxide having an alkali potential of at least 280 mV and less than 310 mV, and FWHM of at least 2.2° and at most 2.9°, is used. It is preferred that of the electrolytic manganese dioxide, the (110)/(021) peak intensity ratio in the X-ray diffraction peaks is at least 0.50 and at most 0.80, and the (110) interplanar spacing is at least 4.00 ? and at most 4.06 ?.
    Type: Grant
    Filed: August 23, 2010
    Date of Patent: August 11, 2015
    Assignee: TOSOH CORPORATION
    Inventors: Kazumasa Suetsugu, Kenichi Takahashi, Akinori Eshita
  • Publication number: 20140353159
    Abstract: A method and apparatus for producing lithium iron arsenic superconductor materials. An example of the method comprises providing at least one cathode comprised of iron arsenic, providing at least one anode comprised of a chemically inert material, placing the at least one cathode and at least one anode into an electrolyte comprised of molten lithium chloride and/or lithium bromide, and applying a voltage such that electrical current flows between the at least one anode and the at least one cathode.
    Type: Application
    Filed: June 4, 2013
    Publication date: December 4, 2014
    Inventors: Milan Majoros, Maria Kanuchova, Michael D. Sumption, Edward W. Collings
  • Patent number: 8785035
    Abstract: A composition for making a contact contains predetermined amounts of cobalt and sulfur and has a predetermined average particle size. The composition for making the contact includes a nickel-cobalt alloy containing 20% by weight to 55% by weight of cobalt, and 0.002 part by weight to 0.02 part by weight of sulfur with respect to 100 parts by weight of the nickel-cobalt alloy, the composition having an average particle size of 0.10 ?m to 0.35 ?m. The contact made with the composition may be included in a connector.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: July 22, 2014
    Assignee: OMRON Corporation
    Inventors: Kuniyoshi Maezawa, Yoko Ishikawa
  • Patent number: 8586506
    Abstract: Methods of producing one or more biaxially textured layer on a substrate, and articles produced by the methods, are disclosed. An exemplary method may comprise electrodepositing on the substrate a precursor material selected from the group consisting of rare earths, transition metals, actinide, lanthanides, and oxides thereof. An exemplary article (150) may comprise a biaxially textured base material (130), and at least one biaxially textured layer (110) selected from the group consisting of rare earths, transition metals, actinides, lanthanides, and oxides thereof. The at least one biaxially textured layer (110) is formed by electrodeposition on the biaxially textured base material (130).
    Type: Grant
    Filed: August 1, 2005
    Date of Patent: November 19, 2013
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Raghu N. Bhattacharya, Sovannary Phok, Priscila Spagnol, Tapas Chaudhuri
  • Patent number: 8389444
    Abstract: A method of producing a thin layer, high-temperature superconductor strip is disclosed. In the method, a metal salt solution is formed and coated onto a substrate including a high-temperature superconductor layer. Heat is then applied directly or indirectly to the solution. The metal salt solution may contain a metal-organic salt solution or a metal inorganic metal salt solution. When an inorganic metal salt solution is utilized, a reducing solution may also be applied to the HTSC layer prior to heating. In addition, nano-sized metal particles may be added to the metal salt solution and/or the reducing solution.
    Type: Grant
    Filed: July 23, 2008
    Date of Patent: March 5, 2013
    Assignee: BASF SE
    Inventor: Michael Baecker
  • Patent number: 7811461
    Abstract: The invention relates to a water treatment apparatus, method and system for use in the treatment of an open or closed body of water including water in a vessel, pipe, reservoir, river, chamber, lake or similar bodies of water, the water being retained in a water containment means being referenced or tied to ground potential, the apparatus including an energisable material defined as an active electrode being configured and arranged for placement in the body of water, the active electrode being adapted to be energised or electrostatically charged with a negative electrostatic voltage charge from a power supply means, in use, to induce and set up an electrostatic field in the water causing contaminants in the water effected by the induced charge to bond and be removed from the water.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: October 12, 2010
    Assignee: Iogenyx Pty Ltd
    Inventor: Andrew Peter Musson
  • Publication number: 20100167084
    Abstract: Methods of producing one or more biaxially textured layer on a substrate, and articles produced by the methods, are disclosed. An exemplary method may comprise electrodepositing on the substrate a precursor material selected from the group consisting of rare earths, transition metals, actinide, lanthanides, and oxides thereof. An exemplary article (150) may comprise a biaxially textured base material (130), and at least one biaxially textured layer (110) selected from the group consisting of rare earths, transition metals, actinides, lanthanides, and oxides thereof. The at least one biaxially textured layer (110) is formed by electrodeposition on the biaxially textured base material (130).
    Type: Application
    Filed: August 1, 2005
    Publication date: July 1, 2010
    Applicant: Midwest Research Institute
    Inventors: Raghu N. Bhattacharya, Sovannary Phok, Priscila Spagnol, Tapas Chaudhuri
  • Patent number: 7338921
    Abstract: An electrode is steeped in a solution of Mg and B and a negative voltage is applied to the electrode so as to precipitate superconductive MgB2 on the electrode. Superconductive MgB2 is easily manufactured in various forms and at low costs without any special device.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: March 4, 2008
    Assignee: National Institute for Materials Science
    Inventors: Hideki Abe, Hideaki Kitazawa, Akiyuki Matsushita
  • Patent number: 7294250
    Abstract: A very small amount of copper chloride or zinc oxide is added to a mixture of magnesium chloride, potassium chloride, sodium chloride and magnesium borate, a mixed salt is melted under heat, electrodes are inserted into a molten salt and a metallic material employed as a cathode is electroplated with a magnesium diboride (MgB2) film.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: November 13, 2007
    Assignee: Japan Atomic Energy Research Institute
    Inventors: Hideki Abe, Hideaki Kitazawa, Kenji Yoshii, Junichiro Mizuki
  • Patent number: 7060174
    Abstract: A method for electrochemical synthesis of a superconducting boron compound MgB2 which comprises the steps of preparing a powder mixture of magnesium chloride, sodium chloride, potassium chloride and magnesium borate, drying the mixture by electrical heating at a temperature of 400° C. or below under an inert gas atmosphere, and further heating the mixture electrically at a temperature of 400° C. or above so that it is melted and undergoes chemical reaction.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: June 13, 2006
    Assignees: Japan Atomic Energy Research Institute, National Institute for Materials Science
    Inventors: Kenji Yoshii, Junichiro Mizuki, Hideki Abe, Hideaki Kitazawa, Akiyuki Matsushita
  • Patent number: 7048840
    Abstract: The invention relates to a method for metal coating the surface of high temperature superconductors with a copper-oxygen base structure. The aim of the invention is to achieve a method as above, which requires a low production complexity, serves for the production of contacts with a low electrical and/or thermal transfer resistance and which increases the stability of the metallization. Said aim is achieved whereby copper is applied to give low-ohmic contacts, and the linked achievement of a stable metallization between the HTS and the electrical and/or thermal coupling. Further advantageous effects are achieved with the method whereby the copper is applied in the form of copper alloys, in particular as copper-nickel or copper-zinc alloys. On applying the method it is furthermore of advantage for the creation of fine grained surface coatings to overlay the galvanic cell with a permanent and/or alternating magnetic field.
    Type: Grant
    Filed: August 29, 2000
    Date of Patent: May 23, 2006
    Assignee: Adelwitz Technologiezentrum GmbH
    Inventors: Frank Werfel, Uta Flögel-Delor, Rolf Rothfeld, Dieter Wippich
  • Patent number: 7033568
    Abstract: A palladium hydride superconductor, PdyHx where yHx is 1Hx, 2Hx, or 3Hx, having a critical temperature Tc?11K and stoichiometric ratio x?1. The critical temperature is proportional to a power of the stoichiometric ratio, which is stable over periods exceeding 24 hours, temperature variations from 4K to 400K, and pressures down to 1 mbar. The palladium hydride is coated with a stabilizing material such as a metal, metal oxide, ceramic, or polymer that can bond to palladium. It can be made by electrochemically loading a palladium lattice with isotopic hydrogen in an electrolytic solution, by allowing isotopic hydrogen to diffuse into a palladium thin film in a pressure chamber, or by injecting isotopic hydrogen into a palladium thin film in a vacuum chamber. The stabilizing material can be electrochemically bonded to the surface of the palladium hydride, or deposited using chemical vapor deposition or molecular beam epitaxy.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: April 25, 2006
    Inventor: Paolo Tripodi
  • Patent number: 6932874
    Abstract: A method for producing a superconductor having a high copper to superconductor composition (Cu/SC) ratio by cross-sectional area. An assembly is prepared formed of one or more fine filaments of a superconductor composition or of a precursor component for a superconductor alloy composition, which filaments are embedded in a copper-based matrix. The assembly is electroplated with copper to increase the Cu/filament ratio in the resulting product, and thereby increase the said Cu/SC ratio to improve the stability of the final superconductor.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: August 23, 2005
    Assignee: Oxford Superconducting Technology
    Inventors: William G. Marancik, Seung Hong
  • Publication number: 20040124086
    Abstract: A method is described for the preparation of superconductor massive bodies of MgB2, having a density close to the theorical value, which comprises the following passages: mechanical activation of crystalline boron with the formation of activated powders; formation of a porous preform of said powders; assembly of the porous boron preform and massive precursors of metallic magnesium in a container and sealing thereof in an atmosphere of inert gas or with a low oxygen content; thermal treatment of the boron and magnesium as assembled above, at a temperature higher than 700° C. for a time greater than 30 minutes, with the consequent percolation of the magnesium, in liquid phase, through the activated crystalline boron powders.
    Type: Application
    Filed: October 16, 2003
    Publication date: July 1, 2004
    Inventors: Giovanni Giunchi, SERGIO CERESARA
  • Publication number: 20030178102
    Abstract: An epitaxial article and method for forming the same includes a substrate having a textured surface, and an electrochemically deposited substantially single orientation epitaxial layer disposed on and in contact with the textured surface. The epitaxial article can include an electromagnetically active layer and an epitaxial buffer layer. The electromagnetically active layer and epitaxial buffer layer can also be deposited electrochemically.
    Type: Application
    Filed: March 19, 2002
    Publication date: September 25, 2003
    Inventor: Amit Goyal
  • Publication number: 20030159935
    Abstract: Local electrochemical deplating of alignment mark regions of semiconductor wafers is disclosed. A tank holds an electrolytic solution. A primary cathode submersed within the solution is at least partially insulated therefrom. An electrochemically metal plated semiconductor wafer submersed within the solution acts as an anode, and has alignment mark regions. Extension cathodes submersed within the electrolytic solution are each at least partially insulated, except for a part of a first end and a second end thereof. The first end part is closely positioned over a corresponding alignment mark region, whereas the second end is situated on a corresponding exposed part of the primary cathode. A power source has its positive terminal operatively coupled to the primary cathode and its negative terminal operatively coupled to the wafer. Current from the power source electrochemically deplates the metal substantially from the alignment mark regions, substantially exposing the alignment marks within these regions.
    Type: Application
    Filed: February 23, 2002
    Publication date: August 28, 2003
    Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Chen-Ming Huang, Sen-Shan Yang
  • Patent number: 6332967
    Abstract: Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: December 25, 2001
    Assignee: Midwest Research Institute
    Inventor: Raghu N. Bhattacharya
  • Patent number: 5938910
    Abstract: Electrolytic manganese dioxide having a BET specific surface area of less than 30 m.sup.2 /g and a suspensiveness of less than 50 mg/liter is used for alkaline manganese batteries and manganese batteries to make them excellent both in initial performance and storability. The electrolytic manganese dioxide may be made by a suspension method or a clarification method.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: August 17, 1999
    Assignee: Japan Metals & Chemicals Co., Ltd.
    Inventors: Hisao Takehara, Yoshihiro Nakayama, Ryoichi Shimizugawa, Tsutomu Kishikawa, Takumi Murai, Fumiya Takahashi, Koh Takahashi
  • Patent number: 5789348
    Abstract: A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: August 4, 1998
    Assignee: Midwest Research Institute
    Inventor: Raghunath Bhattacharya
  • Patent number: 5550104
    Abstract: A method for making superconducting ceramic precursor films by electrodeposition. In the electrodeposition step, superconducting precursor metal ions are electrodeposited onto a working electrode by applying a combined direct current voltage upon which is superimposed an alternating current having a frequency of between about 5 to 100 KHz. The resulting electrodeposited film is particularly well suited for further oxidation/annealing to form a superconducting ceramic.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: August 27, 1996
    Assignee: Davis, Joseph & Negley
    Inventor: Raghu N. Bhattacharya
  • Patent number: 5547518
    Abstract: Foils used to manufacture superconductor materials can effectively be cleaned by heat treatment prior to anodization and further processing steps. The heat treatment can be in conjunction with other cleaning processes or separate.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: August 20, 1996
    Assignee: General Electric Company
    Inventors: Neil A. Johnson, Thomas R. Raber, Louis E. Hibbs, Jr., Melissa L. Murray, Mark G. Benz
  • Patent number: 5545305
    Abstract: Crystalline REBa.sub.2 Cu.sub.3 O.sub.7-x superconductors are obtained by a constant-potential or current density electrochemical deposition in an alkaline hydroxide molten flux in a three-electrode, single-compartment cell operating at a temperature below 500.degree. C.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: August 13, 1996
    Assignee: National Science Council
    Inventors: Horng-Yi Tang, Maw-Kuen Wu, Chuen-Sheng Lee, Huei-Ying Hsu
  • Patent number: 5476837
    Abstract: A process for preparing a superconducting film, such as a thallium-barium-calcium-copper oxide superconducting film, having substantially uniform phase development. The process comprises providing an electrodeposition bath having one or more soluble salts of one or more respective potentially superconducting metals in respective amounts adequate to yield a superconducting film upon subsequent appropriate treatment. Should all of the metals required for producing a superconducting film not be made available in the bath, such metals can be a part of the ambient during a subsequent annealing process. A soluble silver salt in an amount between about 0.1% and about 4.0% by weight of the provided other salts is also provided to the bath, and the bath is electrically energized to thereby form a plated film. The film is annealed in ambient conditions suitable to cause formation of a superconductor film.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: December 19, 1995
    Assignee: Midwest Research Institute
    Inventors: Raghuthan Bharacharya, Philip A. Parilla, Richard D. Blaugher
  • Patent number: 5470820
    Abstract: Processes and techniques are described for concurrent electroplating of yttrium, barium and copper from aqueous solution onto a desired substrate (e.g., nickel, nichrome or silver). Compounds of these elements are dissolved in aqueous solution with a complexing agent meeting defined criteria and then are placed in a plating cell in which the cathode is the substrate on which the elements are to be deposited. After the elements have been deposited, they are oxidized to provide the desired perovskite structure. The process may be continuous or non-continuous.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: November 28, 1995
    Assignee: Hauser Chemical Research, Inc.
    Inventors: Ray L. Hauser, Bolin Zheng, Michael Renbarger, Mark A. Lange
  • Patent number: 5455224
    Abstract: A method for producing a compound oxide superconducting thin film, comprising forming an oxide thin film on the surface of a substrate of a first metal element having a redox charge by oxidizing the metal, using the oxide thin film thus formed as an electrode for oxidation reaction of a second metal element contained in an electrolyte solution or molten salt to incorporate the second metal element in the oxide thin film, using the compound oxide thin film thus formed as an electrode to obtain a cyclic voltammogram, and electrochemically processing the compound oxide thin film at an electrolytic potential that is determined based on the cyclic voltammogram.
    Type: Grant
    Filed: March 24, 1994
    Date of Patent: October 3, 1995
    Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Hiroko Kaneko, Keiji Kaneko, Hideo Ihara, Akira Negishi, Shoji Ishibashi
  • Patent number: 5413987
    Abstract: A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals, such as nitrate salts of thallium, barium, calcium, and copper, which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of thallium in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: May 9, 1995
    Assignee: Midwest Research Institute
    Inventors: Raghunath Bhattacharya, Richard D. Blaugher
  • Patent number: 5286711
    Abstract: A method for producing an oxide superconductor comprises obtaining a cyclic voltammogram using an oxide material containing an element having a redox charge as an electrode, determining an electrolytic potential for the oxide material on the basis of the voltammogram, and electrolyzing the oxide material at the determined potential.
    Type: Grant
    Filed: March 23, 1992
    Date of Patent: February 15, 1994
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Hiroko Kaneko, Keiji Kaneko, Hideo Ihara, Akira Negishi
  • Patent number: 5244875
    Abstract: Processes and techniques are described for concurrent electroplating of yttrium, barium and copper from aqueous solution onto a desired substrate (e.g., nickel, nichrome or silver). Compounds of these elements are dissolved in solution and then placed in a plating cell in which the cathode is the substrate on which the elements are to be deposited. After the elements have been deposited, they are oxidized to provide the desired perovskite structure. The process may be continuous or non-continuous.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: September 14, 1993
    Assignee: Hauser Chemical Research, Inc.
    Inventors: Ray L. Hauser, Bolin Zheng
  • Patent number: 5162295
    Abstract: The invention provides a method for forming deposits of superconducting ceramics by sequentially electrodepositing layers of metals, of a type and in proportion suitable for forming a superconducting ceramic, to form a precursor metal deposit, followed by oxidizing the precursor deposit to form a superconducting ceramic deposit. Optionally, the electroplating steps are conducted in such a manner that a patterned precursor deposit results, to obtain a patterned superconducting deposit after oxidation.
    Type: Grant
    Filed: August 6, 1990
    Date of Patent: November 10, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Mohammad Behi, MacRae Maxfield, Ray Baughman, Helmut Eckhardt, Zafar Igbal
  • Patent number: 5120707
    Abstract: Superconducting ceramic layers are made by first electrochemically depositing metal layers containing embedded particulate matter, followed by oxidation of the precursor layer to form the desired superconducting ceramic. The embedded particulate matter may (a) furnish required constituent metals for the superconductor, (b) be a superconductor itself, which may be the same as or different from the superconductor to be formed, or (c) provide adjuvant substances for improving the properties (e.g., electrical or mechanical) of the superconducting layer being formed.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: June 9, 1992
    Assignee: Allied-Signal, Inc.
    Inventors: MacRae Maxfield, Helmut Eckhardt, Ray H. Baughman, Zafar Iqbal