Abstract: A method of inhibiting degradation of an extractant by utilizing several auxiliary means in the DSX process: includes (a) preparing adjustment of the concentration of an extractant of a DSX solvent to a certain range; (b) extracting a metal contained in a pregnant leached solution by adjusting the ratio of the extractant and the diluent in the DSX solvent to a certain range; (c) measuring the pH of the aqueous phase solution by separating mixture into the aqueous phase solution and the organic phase solvent using a settler after step of extracting; (d) controlling the pH by adding soda ash (Na2CO3) so as to maintain the pH of the aqueous phase solution to be 3 to 7; and (e) scrubbing with scrubbing solution having a zinc concentration of 2 to 20 g/L by zinc sulfate (ZnSO4) to remove the manganese from the organic phase solvent containing the extracted metal.

Abstract: In the electrolytic refining of lead in a sulfamate bath, the production of a white residue is suppressed, and a decrease in the lead concentration in the electrolytic solution is suppressed. A method for electrolytically refining lead in a sulfamate bath, comprising performing electrolytic refining at a decomposition rate of sulfamic acid controlled at 0.06%/day or less.

Abstract: A method for synthesis of nanostructured metal oxide powders. The method comprises converting the metallic material into a precipitate of metal hydroxide by an electrochemical reaction and calcinating the metal hydroxide to form the metal oxides. The method of the invention is also used for the development of cermet particulates and topological insulator particles.

Abstract: The invention is directed to a method for producing metal-containing particles, the method comprising subjecting an aqueous solution comprising a metal salt, Eh, lowering reducing agent, pH adjusting agent, and water to conditions that maintain the Eh value of the solution within the bounds of an Eh-pH stability field corresponding to the composition of the metal-containing particles to be produced, and producing said metal-containing particles in said aqueous solution at a selected Eh value within the bounds of said Eh-pH stability field. The invention is also directed to the resulting metal-containing particles as well as devices in which they are incorporated.

Abstract: The invention is directed to a method for producing metal-containing (e.g., non-oxide, oxide, or elemental) nano-objects, which may be nanoparticles or nanowires, the method comprising contacting an aqueous solution comprising a metal salt and water with an electrically powered electrode to form said metal-containing nano-objects dislodged from the electrode, wherein said electrode possesses a nanotextured surface that functions to confine the particle growth process to form said metal-containing nano-objects. The invention is also directed to the resulting metal-containing compositions as well as devices in which they are incorporated.

Abstract: Proposed is a method for collecting valuable metal from an ITO scrap including a step of collecting tin by subjecting the ITO scrap to electrolysis. Further proposed is a method for collecting valuable metal from an ITO scrap including the steps of providing an ITO electrolytic bath and a tin collecting bath, dissolving the ITO scrap in the electrolytic bath, and thereafter collecting tin in the tin collecting bath. Additionally proposed is a method for collecting valuable metal from an ITO scrap including the steps of dissolving the ITO scrap by subjecting it to electrolysis as an anode in electrolyte, precipitating only tin contained in the solution as tin itself or a substance containing tin, extracting the precipitate, placing it in a collecting bath, re-dissolving this to obtain a solution of tin hydroxide, and performing electrolysis or neutralization thereto in order to collect tin.

Abstract: Proposed is a method for collecting valuable metal from an ITO scrap in which a mixture of indium hydroxide and tin hydroxide or metastannic acid is collected by subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and roasting this mixture as needed to collect the result as a mixture of indium oxide and tin oxide. This method enables the efficient collection of indium hydroxide and tin hydroxide or metastannic acid, or indium oxide and tin oxide from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.

Abstract: Proposed is a method for collecting valuable metal from an ITO scrap including the steps of subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and collecting indium or tin as oxides. Additionally proposed is a method for collecting valuable metal from an ITO scrap including the steps of subjecting the ITO scrap to electrolysis in an electrolytic bath partitioned with a diaphragm or an ion-exchange membrane to precipitate hydroxide of tin, thereafter extracting anolyte temporarily, and precipitating and collecting indium contained in the anolyte as hydroxide. With the methods for collecting valuable metal from an ITO scrap described above, indium or tin may be collected as oxides by roasting the precipitate containing indium or tin. Consequently, provided is a method for efficiently collecting indium from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.

Abstract: Proposed is a method for collecting valuable metal from an ITO scrap including the steps of subjecting the ITO scrap to electrolysis in pH-adjusted electrolyte, and collecting indium or tin as oxides. Additionally proposed is a method for collecting valuable metal from an ITO scrap including the steps of subjecting the ITO scrap to electrolysis in an electrolytic bath partitioned with a diaphragm or an ion-exchange membrane to precipitate hydroxide of tin, thereafter extracting anolyte temporarily, and precipitating and collecting indium contained in the anolyte as hydroxide. With the methods for collecting valuable metal from an ITO scrap described above, indium or tin may be collected as oxides by roasting the precipitate containing indium or tin. Consequently, provided is a method for efficiently collecting indium from an ITO scrap of an indium-tin oxide (ITO) sputtering target or an ITO scrap such as ITO mill ends arisen during the manufacture of such ITO sputtering target.

Abstract: Using a solution mining procedure, an ore (10) is treated with a solution of acetic acid and hydrogen peroxide so as to form a leachate containing lead ions. Lead ions (and other metal ions such as zinc and manganese) are stripped (22, 24, 26) by solvent extraction from the leachate to form separate aqueous solutions. The aqueous solution containing lead ions is treated electrochemically in the anodic compartment of a separated electrochemical cell (42) to form a precipitate of lead oxide. Manganese dioxide can be produced similarly (72). A precipitate of zinc hydroxide can be formed in the cathode compartment of a separated electrochemical cell (56). In the cells (42, 72) extracting lead ions and manganese ions, the cathode compartment is used to generate hydrogen peroxide (for use in making the leachant), either directly or indirectly.

Abstract: The present invention relates to a method for treating spent tin or tin/lead stripping solution used in the electronic industry, particularly in the manufacture of printed circuit boards or a lead frames. Said method comprises (i) electrolytically reducing copper ions in the solution to copper at a low temperature; (ii) electrolytically oxidizing Sn2+ and Pb2+ in the solution at a high temperature to form solid tin and lead oxides and hydroxides; (iii) separating solid tin and lead oxides and hydroxides from the solution; (iv) dissolving tin and lead oxides and hydroxides obtained in step (iii) in a strong alkali or acidic solution; and (v) electrolytically reducing the alkali or acidic solution obtained in step (iv) at a high temperature to recover metallic tin and lead. Also, the filtrate obtained in step (iii) above is useful for preparing fresh tin or tin/lead stripping solution.

Abstract: Aqueous solutions containing lead, zinc and manganese are treated to recover these metals by sequential solvent extraction steps. Solvent extractants are selected to extract preferentially lead, then zinc and then manganese in that order. Any interfering metals are removed (as by ion exchange) before extraction. The loaded extractant phases are stripped with selected acids and lead, zinc and manganese each recovered from the strip solutions. Optionally calcium can be recovered when present. A preferred type of extractant (for lead especially) is substituted monothiophosphinic acids. A closed loop system is described which is advantageous with leachate from sulphide and carbonate ores.

Abstract: A cermet inert anode having a reduced level of contaminating surface metal is disclosed. Methods for preparing cermet inert anodes and methods for treating cermet inert anodes are also disclosed. The methods generally use an oxidizing agent to convert metals on the surface of the anode to inert oxides and/or to otherwise remove the metal contaminants. The inert anodes of the present invention may be used in electrolytic reduction cells for the production of commercial purity aluminum, as well as other metals.

Abstract: Using a solution mining procedure, an ore (10) is treated with a solution of acetic acid and hydrogen peroxide so as to form a leachate containing lead ions. Lead ions (and other metal ions such as zinc and manganese) are stripped (22, 24, 26) by solvent extraction from the leachate to form separate aqueous solutions. The aqueous solution containing lead ions is treated electrochemically in the anodic compartment of a separated electrochemical cell (42) to form a precipitate of lead oxide. Manganese dioxide can be produced similarly (72). A precipitate of zinc hydroxide can be formed in the cathode compartment of a separated electrochemical cell (56). In the cells (42, 72) extracting lead ions and manganese ions, the cathode compartment is used to generate hydrogen peroxide (for use in making the leachant), either directly or indirectly.

Abstract: A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

Abstract: A process for the preparation by electrodeposition of metal oxide film and powder compounds for ferroelectric memory materials and ferrites wherein the metal oxide includes a plurality of metals. The process comprises providing an electrodeposition bath, providing soluble salts of the metals to this bath, electrically energizing the bath to thereby cause formation of a recoverable film of metal on the electrode, recovering the resultant film as a film or a powder, and recovering powder formed on the floor of the bath. The films and powders so produced are subsequently annealed to thereby produce metal oxide for use in electronic applications. The process can be employed to produce metal-doped metal oxide film and powder compounds for transparent conductors. The process for preparation of these metal-doped metal oxides follows that described above.