Abstract: Provided is method for concentrating ozone gas the method including the steps of: allowing ozone gas to be adsorbed onto the adsorbent by introducing ozone gas-containing raw material mixed gas into an adsorption vessel (20) that houses an adsorbent for adsorbing ozone gas; reducing a pressure in a concentration vessel (30) in a state where the concentration vessel (30) does not communicate with the adsorption vessel (20), the concentration vessel (30) being configured to be connected to the adsorption vessel (20) so as to be interswitchable between a state where the concentration vessel (30) communicates with the adsorption vessel (20) and a state where the concentration vessel does not communicate with the adsorption vessel (20); and introducing concentrated mixed gas including ozone gas with a higher ozone gas concentration than the ozone gas concentration in the raw material mixed gas into the concentration vessel (30) by desorbing the ozone gas adsorbed onto the adsorbent using a pressure difference betw

Abstract: Provided is a method for concentrating ozone gas, including the steps of: allowing ozone gas to be adsorbed onto an adsorbent in a first adsorption vessel; reducing pressure in a concentration vessel in a state where the concentration vessel does not communicate with the first adsorption vessel; discharging part of gas in the first adsorption vessel; introducing first concentrated mixed gas in the concentration vessel by desorbing ozone gas in the first concentrated mixed gas and delivering the desorbed ozone gas into the concentration vessel; allowing ozone gas to be adsorbed onto an adsorbent in a second adsorption vessel; and introducing second concentrated mixed gas into the concentration vessel in a state where the concentration vessel into which the first concentrated mixed gas is introduced and the second adsorption vessel that houses an adsorbent. Also provided is an apparatus for concentrating ozone gas for implementing the method.

Abstract: A method and system for electrodeposition of high-sp3 diamond/DLC by significantly increasing the sp3 carbon content of electrodeposited net-shape diamond, and use of same for manufacture of particulate and nanocrystalline diamond and composites.

Abstract: An electrolytic ozone generator includes an anode with a longitudinal edge, a cathode with a longitudinal edge spaced apart from the cathode, and an isolator. The isolator electrically separates the cathode from the anode and is semi-impermeable. The anode and cathode are impermeable for generating ozone in a flow area fluidly coupling longitudinal edges of the anode and the cathode. Ozone water apparatus, methods of making electrolytic ozone generators, and methods of generating ozone using electrolytic ozone generators are also described.

Abstract: Electrolytic liquid generating device (1) includes laminated body (41) in which conductive film (46) is laminated to be interposed between mutually adjacent electrodes (44, 45), and electrolytic part (40) which electrolyzes liquid. Furthermore, electrolytic liquid generating device (1) includes a passage having inflow port (71) in which liquid to be provided to electrolytic part (40) flows and outflow port (72) from which electrolytic liquid generated in electrolytic part (40) flows out. The passage is formed such that liquid flowing direction (X) crosses laminated direction (Z) of laminated body (41).

Abstract: A spray atomizing ozone water generating apparatus with gas storage ability includes a gas-water mixing chamber with atomizing water nebulizer, a delay circuit, as well as a tap water inlet valve and an ozone water outlet valve controlled by the delay circuit. Because the mixer has ozone storage ability, atomizing water nebulizer will atomize tap water sufficiently, ozone water generating apparatus according to the invention can thus produce super high concentration ozone water having a concentration more than 30 ppm.

Abstract: An electrolytic cell includes at least one free-standing diamond electrode and a second electrode, which may also be a free-standing diamond, separated by a membrane. The electrolytic cell is capable of conducting sustained current flows at current densities of at least about 1 ampere per square centimeter. A method of operating an electrolytic cell having two diamond electrodes includes alternately reversing the polarity of the voltage across the electrodes.

Abstract: Coaxial disk armatures, counter-rotating through an axial magnetic field, act as electrolysis electrodes and high shear centrifugal impellers for an axial feed. The feed can be carbon dioxide, water, methane, or other substances requiring electrolysis. Carbon dioxide and water can be processed into syngas and ozone continuously, enabling carbon and oxygen recycling at power plants. Within the space between the counter-rotating disk electrodes, a shear layer comprising a fractal tree network of radial vortices provides sink flow conduits for light fractions, such as syngas, radially inward while the heavy fractions, such as ozone and elemental carbon flow radially outward in boundary layers against the disks and beyond the disk periphery, where they are recovered as valuable products, such as carbon nanotubes.

Abstract: The present invention provides an ozone generator comprising an anode and a cathode provided on each side of a fluororesin type cation exchange membrane, the anode being a conductive diamond electrode having conductive diamond on the surface, wherein water is supplied to an anode compartment, DC current is supplied between the anode and the cathode to electrolyze water to evolve ozone from the anode compartment and hydrogen from a cathode compartment, the conductive diamond electrode comprising a substrate having a plurality of convexo-concave and a conductive diamond film coated on the surface of the substrate is applied as the conductive diamond electrode, and a close packed layer of ion exchange resin particles or the fluororesin type cation exchange membrane with notch is closely adhered to the surface of the anode side of the fluororesin type cation exchange membrane.

Abstract: Provided herein are systems and methods for separation of particulate from water using ultrasonically generated acoustic standing waves.

Abstract: An electrochemical system and method are disclosed for On Site Generation (OSG) of oxidants, such as free available chlorine, mixed oxidants and persulfate. Operation at high current density, using at least a diamond anode, provides for higher current efficiency, extended lifetime operation, and improved cost efficiency. High current density operation, in either a single pass or recycle mode, provides for rapid generation of oxidants, with high current efficiency, which potentially allows for more compact systems. Beneficially, operation in reverse polarity for a short cleaning cycle manages scaling, provides for improved efficiency and electrode lifetime and allows for use of impure feedstocks without requiring water softeners. Systems have application for generation of chlorine or other oxidants, including mixed oxidants providing high disinfection rate per unit of oxidant, e.g. for water treatment to remove microorganisms or for degradation of organics in industrial waste water.

Abstract: Electrode devices and systems for use in liquid environments, including associated methods are provided. In one aspect, for example, an electrode device for use in a liquid environment can include a proton exchange membrane having a first side and a second side, a first electrode including a carbon material, where the first electrode is positioned at the first side of the proton exchange membrane, and a second electrode including a carbon material, where the second electrode positioned at the second side of the proton exchange membrane opposite the first electrode. The proton exchange membrane spaces the first electrode and the second electrode at a distance of less than or equal to about 100 microns apart.

Abstract: A method for producing ozone-water includes steps of providing a cathode and an anode so as to interpose a solid polymer film therebetween, and electrolyzing water. A conductive diamond having one of a porous structure and a mesh structure is used as the anode. Ozone-water of an intermediate to high temperature is produced by electrolyzing water of an intermediate to high temperature.

Abstract: An electrode comprising an electrically conducting diamond plate wherein the diamond plate comprises at least one elongate aperture and having an aperture edge length per unit working area of the diamond plate of greater than about 4 mm/mm2, electrolysis cells comprising such electrodes, methods of treating water using such electrolysis cells and a method of production of ozone are disclosed.

Abstract: The present invention provides an electrochemical apparatus for processing a fluid comprising: an electrode; a solid electrolyte; and means for providing forced flow through the apparatus of a fluid to be processed, wherein the apparatus is arranged such that when the fluid to be processed is introduced into the apparatus there exists at least one three phase interface between the electrode, the solid electrolyte and the fluid to be processed and such that the fluid forming part of the three phase interface undergoes forced flow through the apparatus, and methods in which the electrochemical apparatus is used.

Abstract: A hearing aid dehumidifier and disinfectant chamber. The chamber comprises an enclosure, including a vapor permeable wall, adapted to removably enclose a hearing aid. In vapor transmitting relationship with the vapor permeable wall is an electrochemical ozone generator, which is designed to draw water vapor from inside the enclosure and electrolyze it into at least ozone, which is discharged into the enclosure. Drawing the water vapor from the enclosure dries the hearing aid. The electrochemical action ceases when all water vapor is removed. Bathing the hearing aid in ozone for at least until the ozone decomposes, sterilizes the hearing aid, inside and out.

Abstract: A system and method for disinfecting contact lenses produces ozone from the water in which the contact lenses are submerged, thus avoiding the need to supply ozone from an external source. Ozone is created by an electrolytic cell including a diamond electrode, which is submerged in the water with the contact lenses to be disinfected. The diamond electrode may include a number of fingers, and may be fabricated from a diamond blank.

Abstract: The present invention can provide an electrode member having a substrate member and a coating member. The substrate member can be made of a material selected from the group consisting of titanium, gold coated titanium and other inert conducting materials. The coating member can have a tin dioxide modified by antimony. The electrode member of the present invention can be used for direct generation of ozone in water or through water into a gaseous state.

Abstract: An electrolytic cell includes at least one free-standing diamond electrode and a second electrode, which may also be a free-standing diamond, separated by a membrane. The electrolytic cell is capable of conducting sustained current flows at current densities of at least about 1 ampere per square centimeter. A method of operating an electrolytic cell having two diamond electrodes includes alternately reversing the polarity of the voltage across the electrodes.

Abstract: A method for keeping ozone of high concentration while turning on an electrolysis-type ozone device is provided with an ozone generator, a pure water tank, a pipe, another pipe, the other pipe, an ozone gas delivery pipe, and a DC power supply that provides electricity for the ozone generator and the controlling valve. When the ozone generator is turned off for a period, the DC power supply continues providing a half-loaded current for the ozone generator to operate; wherein, the half-loaded current is half smaller than a full-loaded current. When a predetermined time is reached, the DC power supply instantly offers the full-loaded current to the ozone generator, thereby triggering the ozone generator to automatically operate. The method automatically turns on the ozone generator to produce new ozone gas after the ozone device is turned off and stops discharging the ozone gas or the ozone water.

Abstract: The present invention provides a manufacturing method of normal saline solution and cleansing apparatus for contact lens, more particularly, a cleansing apparatus for contact lens comprising: a lens receiver for accommodating lenses, at least one electrode unit including a negative electrode and a positive electrode which set apart from the negative electrode each other, a power supply for supplying electric current to the negative electrode and the positive electrode, thereby effectively disinfecting and sterilizing viruses and bacteria and to remove foreign substances within the short time and protein on contact lenses in the lens receiver by oxidants generated by electrolysis in the electrode unit.

Abstract: Novel bismuth based mixed metal oxide materials with pyrochlore structure are disclosed as anodes for electrolytic generation of ozone and perchlorate salts. These materials have high electrical conductivity and excellent stability in acidic electrolytes. These materials are more environmentally friendly than lead dioxide and less expensive than platinum.

Abstract: The present invention provides: a membrane-electrode assembly having a first electrode having a shape of a rod-form or a cylindrical-form, a strip-form diaphragm covering the periphery of the first electrode, and a second electrode disposed on a surface of the strip-form diaphragm; an electrolytic unit containing the membrane-electrode assembly; an electrolytic water ejecting apparatus containing the electrolytic unit; and a method of sterilization using the membrane-electrode assembly.

Abstract: The present invention provides a method of sterilization with an electrolytic water, including: electrolyzing a raw water with an electrolytic unit including: a cathode; and an anode at least having a part containing a conductive diamond to prepare an electrolytic water; and ejecting the electrolytic water to a substance to be sterilized, and an electrolytic water ejecting apparatus.

Abstract: A method for producing ozone-water includes steps of providing a cathode and an anode so as to interpose a solid polymer film therebetween, and electrolyzing water. A conductive diamond having one of a porous structure and a mesh structure is used as the anode. Ozone-water of an intermediate to high temperature is produced by electrolyzing water of an intermediate to high temperature.

Abstract: The present invention provides an electrochemical apparatus for processing a fluid comprising: an electrode; a solid electrolyte; and means for providing forced flow through the apparatus of a fluid to be processed, wherein the apparatus is arranged such that when the fluid to be processed is introduced into the apparatus there exists at least one three phase interface between the electrode, the solid electrolyte and the fluid to be processed and such that the fluid forming part of the three phase interface undergoes forced flow through the apparatus, and methods in which the electrochemical apparatus is used.

Abstract: The present invention provides a method and apparatus for sterilizing articles using an ozone-containing gas, where condensation of water from the sterilization atmosphere during the sterilization process is substantially prevented. The inventive sterilization method includes providing a sterilization chamber and placing an article into the sterilization chamber. The sterilization chamber is sealed prior to equalizing the temperature of the article and the atmosphere in the sterilization chamber. A vacuum is applied to achieve a preselected vacuum pressure in the sterilization chamber. Once the vacuum pressure is set, water vapour is supplied to the sterilization chamber. Ozone-containing gas is then supplied to the sterilization chamber and the sterilization chamber remains sealed for a preselected treatment period, where the sterilization chamber remains sealed throughout the whole process. Finally, vacuum in the sterilization chamber is released.

Abstract: A flow-type laboratory scale ozonolysis apparatus (100) according to the invention comprises a reservoir (104), a n feed pump (102), a mixing element (120) with two inlets and an outlet, a reactor unit (110) and a pressure-adjusting means (160), all connected into a flow path. The ozonolysis apparatus (100) further comprises an ozone source (110), as well as a dispensing valve (112) transmitting a gas stream only in a single direction and installed between the ozone source (110) and one of the inlets of the mixing element (120). The feed pump (102) of the ozonolysis apparatus (100) according to the invention is a liquid pump generating a constant volume rate, the reservoir (104) contains at least the substance, as a solute, to be subjected to the ozonolysis reaction and the reactor unit consists of first and second reactor zones differing in function from one another. In the flow path, the outlet of the first reactor zone is connected to the inlet of the second reactor zone.

Abstract: Electrochemical apparatus and methods that support periodic, non-steady state, or discontinuous operation without suffering degradation of materials or loss of efficiency. The invention provides a means for positioning one or more electrodes into contact with electrolyte and means for retracting the one or more electrodes out of contact with the electrolyte. The means for positioning and means for retracting may be the same device or different devices. The means for positioning and means for retracting may be designed to provide automatic, passive, or fail-safe retraction of the electrode upon a given shutdown condition, such as a voltage of less than one Volt being applied between the first and second electrodes, expiration of a time period, an ozone concentration greater than a setpoint ozone concentration, contact pressure of less than 5 psig, and combinations thereof.

Abstract: The present invention can provide an electrode member having a substrate member and a coating member. The substrate member can be made of a material selected from the group consisting of titanium, gold coated titanium and other inert conducting materials. The coating member can have a tin dioxide modified by antimony. The electrode member of the present invention can be used for direct generation of ozone in water or through water into a gaseous state.

Abstract: An object is to provide an electrode for electrolysis which is preferable in generation of ozone water usable in cleaning and sterilizing of water and sewage, or cleaning in a semiconductor device manufacturing process by an electrolysis process, and a method of manufacturing this electrode for electrolysis. The surface of a conductive substrate constituting the electrode for electrolysis is coated with a noble metal such as platinum or a noble metal oxide to form an intermediate layer, further a surface layer is constituted of a dielectric material on the surface of the intermediate layer, and the surface layer is provided with holes.

Abstract: There are provided an electrode for electrolysis which takes into consideration safety to human bodies and environmental pollution upon disposal of the electrode, produces ozone with high efficiency and has excellent durability, a production process of the electrode, and an active oxygen producing device using the electrode. In an electrode 5 for electrolysis which has an electrode catalyst at least on the surface and produces ozone or active oxygen in for-treatment water by electrolysis, the electrode catalyst contains a dielectric which constitutes more than 70% of the surface area of the electrode catalyst.

Abstract: The sterilization method disclosed includes the steps of providing a sterilization chamber; placing the article into the sterilization chamber; equalizing the temperature of the article and the sterilization atmosphere; sealing the sterilization chamber; applying a vacuum of a preselected vacuum pressure to the sterilization chamber; supplying water vapour to the sterilization chamber under vacuum; supplying ozone-containing gas to the sterilization chamber; maintaining the sterilization chamber sealed for a preselected treatment period; and releasing the vacuum in the sterilization chamber; whereby a vacuum pressure is used which lowers the boiling temperature of water in the sterilization chamber below the temperature in the sterilization chamber. One or more ventilating cycles can be added to the preferred method for removing the remaining ozone and humidity from the sterilization chamber.

Abstract: The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The system may be configured to operate passively with no moving parts or in a self-pressurizing manner with the inclusion of a pressure controlling device or valve in the gas outlet of the anode reservoir. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.

Abstract: Pure water 3 is made to pass through a carbon dioxide contact mechanism 8, to become carbonated water 6, and is supplied to the ozone gas and hydrogen gas generation section 1, so the concentration of generated ozone gas become stable at all time. As a result, the concentration of the generated ozone gas is high and stable at all times, and high concentration can be maintained.

Abstract: The present invention can provide an electrode member having a substrate member and a coating member. The substrate member can be made of a material selected from the group consisting of titanium, gold coated titanium and other inert conducting materials. The coating member can have a tin dioxide modified by antimony. The electrode member of the present invention can be used for direct generation of ozone in water or through water into a gaseous state.

Abstract: A method for cleaning a hemodialysis system after completion of dialysis, characterized in that ozone water produced by an apparatus for producing high concentration ozone water 5 and having an average ozone concentration of not less than 15 ppm is sequentially guided to dialysate pipes of a hemodialysis system 4 after completion of dialysis including a water supply tube for dialyzing water 40, a water supply tube for dialysate 41 and a water drainage tube for dialysate 42; and ozone water having an average ozone concentration of not less than 2 ppm is drained from the water drainage tube 42. It is possible to prevent carbonates, proteins, biofilms and the like from adhering so that cleaning with excellent sterilizing property can be realized.

Abstract: A method and apparatus for producing water containing ozone by electrolysis includes an anodic electrode, a cathode electrode, and a mechanism for advancing and reversing both or at least one of the electrodes, wherein DC voltage is applied between both electrodes in the state of a solid polymer electrolyte membrane pressed by both electrodes, water flows on both sides of the solid polymer electrolyte membrane, water containing ozone is produced at the anodic electrode, and an operation for changing a pressing force is carried out, after which, the pressing force returns to an original pressing force, thereby carrying out a recovery of the solid polymer electrolyte membrane while continuing the production of the water containing ozone.

Abstract: An apparatus for generating ozone, oxygen, hydrogen, and/or other products of water electrolysis, having an electrolyte cell that can be acted upon by water. The water is delivered and carried away in a supply line communicating with the electrolyte cell, wherein a bypass line is embodied around the supply line. The electrolyte cell can be connected via the bypass line to the supply line and subjected to water from the supply line. A valve engaging the supply line and the bypass line is provided, and with the valve, the supply line and the bypass line can be opened and/or closed.

Abstract: The method of this invention for producing electrolyzed water containing ozone employs an apparatus for producing electrolyzed water from a liquid. The apparatus has two plate electrodes facing each other, a D.C. power source for applying a D.C. voltage across the electrodes and a control circuit for changing a polarity of the electrodes alternately. The method includes the step of producing electrolyzed water by changing the polarity, while a liquid is caused to flow in a flow passage between the electrodes, and the polarity is changed at an interval of time T as defined by formula (10): 0.5≦T≦(1/3)×(L/V)  (10) wherein; V: Velocity of flow of the liquid in the flow passage (cm/sec.), and L: Length of the electrodes as measured in the direction of flow of the liquid (cm).

Abstract: An ozone generator which operates at constant pressures to produce a continuous flow of ozone in an oxygen stream having from 10% to 18% by weight of ozone. The ozone generator includes one or more electrolytic cells comprising an anode/anode flow field, a cathode/cathode flow field, and a proton exchange medium for maintaining the separation of ozone and oxygen from hydrogen. The ozone generator also has an anode reservoir which vents oxygen and ozone and a cathode reservoir which vents hydrogen. The anode reservoir can be filled from the cathode reservoir while continuing to produce ozone. The ozone generator is readily configured for self-control using a system controller programmed to operate the anode reservoir at a constant pressure.

Abstract: Methods of providing ozone at a selected pressure above atmospheric pressure include supplying a purge gas supply (22) pressurized above the selected pressure to at least one ozone adsorption apparatus (12); desorbing ozone from the ozone adsorption apparatus (12) with the pressurized purge gas supply (22); and delivering a mixture of ozone and the purge gas supply (24) at the selected pressure without further compression.

Abstract: An oxygen emitter which is an electrolytic cell is disclosed. When the anode and cathode are separated by a critical distance, very small microbubbles and nanobubbles of oxygen are generated. The hydrogen forms bubbles at the cathode, which bubbles rise to the surface. The very small oxygen bubbles remain in suspension, forming a solution supersaturated in oxygen. The electrodes may be a metal or oxide of at least one metal selected from the group consisting of ruthenium, iridium, nickel, iron, rhodium, rhenium, cobalt, tungsten, manganese, tantalum, molybdenum, lead, titanium, platinum, palladium and osmium or oxides thereof. The electrodes may be formed into open grids or may be closed surfaces. The most preferred cathode is a stainless steel mesh. The most preferred mesh is a {fraction (1/16)} inch grid. The most preferred anode is platinum and iridium oxide on a support. A preferred support is titanium. Models suitable for different uses are disclosed.

Abstract: There are provided an electrode for electrolysis which takes into consideration safety to human bodies and environmental pollution upon disposal of the electrode, produces ozone with high efficiency and has excellent durability, a production process of the electrode, and an active oxygen producing device using the electrode. In an electrode 5 for electrolysis which has an electrode catalyst at least on the surface and produces ozone or active oxygen in for-treatment water by electrolysis, the electrode catalyst contains a dielectric which constitutes more than 70% of the surface area of the electrode catalyst.

Abstract: The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The system may be configured to operate passively with no moving parts or in a self-pressurizing manner with the inclusion of a pressure controlling device or valve in the gas outlet of the anode reservoir. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.

Abstract: Ozone gas having a high ozone concentration is generated by a solid electrolyte electrolytic process. An ozone solution is prepared by injecting the ozone gas into an acidic solution of pH 6 or below. The ozone solution heated at a temperature in the range of 50° to 90° C. is supplied to a contaminated object to oxidize and dissolve a chromium oxide film by an oxidizing dissolving process. The ozone solution used in the oxidizing dissolving process is irradiated with ultraviolet rays to decompose ozone contained in the ozone solution, the ozone solution is passed through an ion-exchange resin to remove ions contained in the ozone solution. An oxalic acid solution is supplied to the contaminated object to dissolve an iron oxide film by a reductive dissolving process.

Abstract: There are provided an ozone producing method and apparatus capable of significantly increasing an amount of ozone produced in for-treatment water. In the ozone producing method of the present invention, a noble metal is used as a material constituting the anode, and the for-treatment water contains halogen ions or a compound containing halogen ions.

Abstract: An electrolytic process of ozone generation using platinum-coated titanium grid as cathode, &bgr;-PbO2 deposited on the grid as anode, and batteries in conjunction with supercapacitors as a DC power source is described. No membrane is required to separate the electrodes, and a neutral salt such as NaCl is used to enhance the generation of ozone gas. The electrolytic apparatus comprising a cell, the electrodes, and a bubbler can also be inserted directly in water that needs ozone treatment. As batteries can power the ozone generation, the apparatus can be disposed at point-of-use and away from the city electricity. The electrolytic apparatus can be used for sterilization of water for pharmaceutical industry, household water supply, for surface cleaning of semiconductors, meats, fish, fruits, as well as for disinfection of SPA water and personal hygiene.

Abstract: An electric energy conversion/storage system includes an ozone generating means (12) for producing an ozonized gas from a raw material gas containing oxygen by utilizing electric energy, an ozone adsorbing/desorbing means (15) for adsorbing ozone contained in the ozonized gas and desorbing ozone from the adsorbed state, a gas circulation system for causing the raw material gas and the ozonized gas to flow through the ozone generating means (12) and the ozone absorbing/desorbing means (15) while feeding back to the ozone generating means (12) a residual part of the oxygen gas remaining after adsorption of ozone, a coolant supply means (16) for cooling the ozone adsorbing/desorbing means (15), and an ozone discharging means (29, 30) for taking out an ozone containing gas which contains ozone molecules from the ozone adsorbing/desorbing means (15) to thereby supply the ozone containing gas to an ozone consumer (23).

Abstract: The present invention provides an ozone generation and delivery system that lends itself to small scale applications and requires very low maintenance. The system preferably includes an anode reservoir and a cathode phase separator each having a hydrophobic membrane to allow phase separation of produced gases from water. The hydrogen gas, ozone gas and water containing ozone may be delivered under pressure.