Abstract: A method for assessing an integrity of metal tubular structures may comprise receiving one or more inputs, applying an algorithm to automatically select an appropriate model for a given corrosion scenario, applying a combined model including semi-empirical and multiphase flow corrosion characteristics to the one or more inputs, determining one or more corrosion parameters of either an internal pipe wall, an external pipe surface, or both, applying a corrosion correlation value to the one or more corrosion parameters to produce one or more correlated corrosion parameters, and storing the one or more correlated corrosion parameters on a computer readable medium. A system may comprise an information handling system which may comprise at least one memory operable to store computer-executable instructions, at least one communications interface to access the at least one memory, and at least one processor.

Abstract: The present disclosure relates to methods, apparatuses, and systems to measure one or more electrical signals from a cultured cell layer. In some embodiments, such electrical signals can be indicative of transport or lack of transport of an agent through the cell layer.

Abstract: A biocompatible medical device may include an electrochemical sensor including a common reference electrode; at least one counter electrode; and a work electrode platform comprising a plurality of respective work electrodes, each respective work electrode electrically coupled to the common reference electrode and comprising a respective reagent substrate configured to react with a respective analyte to produce a respective signal indicative of a concentration of the respective analyte; and processing circuitry operatively coupled to the electrochemical sensor, and configured to receive from the electrochemical sensor a plurality of signals from the plurality of respective work electrodes; identify the respective signal corresponding to a respective selected work electrode; and process the identified signal to determine the concentration of the respective analyte associated with the respective selected work electrode.

Abstract: A system for cabling infrastructure that includes at least one port, at least one shutter, at least one sensor and a gateway is provided. The port is configured to be selectively coupled to a connector. Each shutter is configured to have an open state that allows access to an associated port and a closed state that covers the port. Each sensor is configured to sense the open state and the closed state of an associated shutter and generate shutter state signals that include information relating to a current sensed state of the associated shutter and an identification of a port that is associated with the associated shutter. The gateway is in wireless communication with each sensor to receive the shutter state signals. The gateway is configured to communicate the shutter state signals that indicate a change in a state of an associated shutter to a remote location.

Abstract: A method for detecting corrosion on a conductive object includes submerging a surface of the conductive object at least partially in an aqueous solution, flowing current through the surface of the conductive object by forming a voltage differential across the surface, varying the voltage differential across the surface while monitoring the current through the surface of the conductive object, determining a total charge corresponding to a corrosion level of the surface of the conductive object based on current versus voltage levels. The corrosion level may further be utilized in selecting a cleaning process to remediate the corrosion of the surface based on the corrosion level and in applying a protective corrosion barrier to on at least part of the surface after the cleaning process.

Abstract: The invention is directed to a real-time, zero resistance ammeter (ZRA) galvanic corrosion detection instrument that is adapted to measure corrosion under atmospheric conditions. The instrument may be used in accordance with methods for selecting materials based on environmental conditions and electrolyte chemistries. The electrochemical ZRA test cell of the invention may further be used to determine galvanic corrosion susceptibility, aid in forecasting corrosion, and determine the extent of corrosion based on environmental factors.

Abstract: A multi electrode sensor that provides in-situ, real time measurements for molten salts and other process fluids such as real-time concentration and salt level measurements for nuclear systems such as molten salt reactors, nuclear reprocessing facilities utilizing molten salts and concentrated solar power systems. The sensor has multiple electrodes with unique lengths which are connected to a potentiostat. Measurements are taken when the electrodes are immersed in the process fluid.

Abstract: A biosensor system determines an analyte concentration of a biological sample using an electrochemical process without Cottrell decay. The biosensor system generates an output signal having a transient decay, where the output signal is not inversely proportional to the square root of the time. The transient decay is greater or less than the ?0.5 decay constant of a Cottrell decay. The transient decay may result from a relatively short incubation period, relatively small sample reservoir volumes, relatively small distances between electrode surfaces and the lid of the sensor strip, and/or relatively short excitations in relation to the average initial thickness of the reagent layer. The biosensor system determines the analyte concentration from the output signal having a transient decay.

Abstract: A sensor device includes first and second electrodes, a coating film and a functional element. The first electrode includes a first metallic material in which either a first passivation film forms on a surface thereof or the first passivation film present on the surface thereof is lost, in association with changes in the pH of a measurement site. The second electrode includes a second metallic material different from the first metallic material, and is spaced apart from the first electrode. The coating film includes a third metallic material different from the first and second metallic materials. The coating film covers at least the first or second electrode. The functional element is configured to measure a difference in electric potential between the first and second electrodes that changes depending on presence or absence of each of the first passivation film and the coating film in association with the changes in pH.

Abstract: A mobile terminal and a control method of a mobile terminal are provided. The mobile terminal and control method provide a user interface allowing for a user to easily and effectively control the mobile terminal through an interaction between a case and the mobile terminal when the mobile terminal is accommodated in the case in a lock mode.

Abstract: A method to evaluate the corrosion resistance of a can to a content includes filling the can with the content to form a specimen, setting the specimen in an apparatus capable of blocking an outside atmosphere from entering the specimen, optionally saturating the content with nitrogen gas to expel dissolved oxygen present in the content, thereafter while maintaining the temperature of the content at a constant temperature in the range of 25 to 60° C., applying a constant potential that is more anodic than an immersion potential by 50 mV to 200 mV to the can of the specimen, and evaluating the corrosion resistance of the can to the content based on the accumulated amount of electricity generated during a time appropriately selected from 6 to 48 hours immediately after the application of the constant potential.

Abstract: An apparatus and method for monitoring cathodic protection of a protected object that includes a probe with five segments in series. The cathodic protection is provided by a system with a power supply that impresses current onto the protected object. An anode is included with the system that is also connected to the power supply. The third and fifth segments are in electrical communication through a frangible connection; that over time galvanically corrodes to electrically isolate the third and fifth segments. The second segment, which is a permanent isolator, is set between the first and third segments. The third segment is selectively connected with the protected object. When the third segment is selectively disconnected from the protected object, measuring the potential difference between the third segment and the first segment yields a value for object polarization that is void of IR error.

Abstract: A method and apparatus for testing workpiece overcoats is described.

Abstract: A system and method capable of performing online corrosion monitoring of a component installed in a gas turbine. A sensing device is located so that electrodes thereof are exposed to an operating environment within the gas turbine section containing the component. The electrodes are formed of a material so that the component and electrodes similarly respond to corrosive agents within the gas turbine section. The electrodes are electrically insulated from each other and each electrode is operable as an anodic electrode or a cathodic electrode, depending on the extent of corrosion thereat, so that each electrode has an electrical potential value, voltages exist across the electrodes, electric currents flow between the electrodes, and the electrical potential/current values correspond to corrosion behaviors at the anodic electrodes.

Abstract: A biosensor system determines an analyte concentration of a biological sample using an electrochemical process without Cottrell decay. The biosensor system generates an output signal having a transient decay, where the output signal is not inversely proportional to the square root of the time. The transient decay is greater or less than the ?0.5 decay constant of a Cottrell decay. The transient decay may result from a relatively short incubation period, relatively small sample reservoir volumes, relatively small distances between electrode surfaces and the lid of the sensor strip, and/or relatively short excitations in relation to the average initial thickness of the reagent layer. The biosensor system determines the analyte concentration from the output signal having a transient decay.

Abstract: A computer system and method for predicting the aqueous phase CO2 corrosion rate of a pipe useful in the production and transportation of oil and gas. Input parameter values corresponding to water chemistry and physical fluid and pipe properties are received. Based on these input parameter values, the system and method derive current-voltage relationships for multiple cathodic reduction reactions according to an electrochemical model of the corrosion reaction, and a current-voltage relationship for the anodic oxidation reaction of iron dissolution. A current density is obtained, at the intersection of an extrapolation of the anodic current-voltage relationship and an extrapolation of the summed cathodic current-voltage relationships. The predicted corrosion rate is then calculated from the obtained current density. The effects of secondary parameters such as scale and flow regime, and the efficacy of a corrosion inhibitor, can also be evaluated.

Abstract: A sample measurement device (110), in which a biosensor (30) having an electrode is mounted, voltage is applied to the electrode, and the concentration of a specific component in a sample deposited on the biosensor (30) is measured, comprises a voltage source (19) configured to apply voltage to the electrode, a time measurement component (22), and a controller (18) configured to control the voltage to be applied and measure the concentration of the specific component. The time measurement component (22) measures a detection time, which is the length of time between the mounting of the biosensor (30) and the deposition of a sample on the biosensor (30). The controller (18) changes a set value for measuring the concentration of a specific component according to the detection time. Consequently, measurement accuracy can be improved regardless of the temperature of the biosensor (30).

Abstract: A system and method for the high temperature in-situ determination of corrosion characteristics of a molten metal on an alloy under study is provided which takes place within an insulated furnace. A graphite crucible provided in the furnace contains an electrolyte formed from a molten salt of a metal halide. A reference electrode formed from the same metal as the electrolyte is immersed in the electrolyte solution in the graphite crucible. A beta-alumina crucible containing a molten metal is also provided within the furnace and preferably within the graphite crucible. A measuring electrode formed from the alloy under study is immersed in the molten metal. Standard electrochemical techniques are used to measure and analyze the electrochemical effects of corrosion of the molten metal on the alloy.

Abstract: The invention relates to novel methods and compositions for the detection of analytes using the nuclear reorganization energy, ?, of an electron transfer process.

Abstract: The invention relates to novel methods and compositions for the detection of analytes using the nuclear reorganization energy, ?, of an electron transfer process.

Abstract: The invention relates to novel methods and compositions for the detection of analytes using the nuclear reorganization energy, ?, of an electron transfer process.

Abstract: The present invention provides a method and apparatus for estimation of general and localized corrosion penetration rates of metallic materials and objects. The invention can also be used to discriminate between general and localized corrosion. A one, two or three electrode probe having electrodes (101, 102, 103) made of the same material as the material being monitored is located in the same corrosive environment as the material being monitored. An electrochemical harmonic analysis is performed and electrochemical noise signals are monitored, and the resulting responses are analyzed and compared to discriminate between general and localized corrosion attack and to determine a localized corrosion penetration rate. A law frequency sine wave is applied to the working electrode. Harmonic analysis of the electrode response provides information regarding the general corrosion rate and the stern-geary constant.

Abstract: Described is a method for electrochemically patterning a microelectrode array (MEA) with at least two different kinds of macromolecules. Said method comprising the steps of: providing a platform with a surface that comprises individually addressable conductive microelectrode surfaces; covering said platform surface with an adlayer of resistant polymer; desorbing said adlayer from a first kind of conductive microelectrodes intended for the selective adsorption of a first kind of macromolecules, in particular proteins, by applying a potential; subjecting the desorbed surfaces to the first macromolecule under conditions such that said first macromolecule adsorbs to said desorbed surfaces, and repeating the desorption/adsorption steps with a second or further kind of macromolecules until all kinds of desired macromolecules are adsorbed. A microchip array produced by the inventive method is also described. Such chip arrays can be used to study a large diversity of biological interactions, e.g.

Abstract: The present invention provides a method and apparatus for instrumental analysis in remote locations. In one embodiment, the present invention provides a method of controlling cathodic protection being applied to a metal structure having a surface disposed in an electrolytic environment comprising electrically connecting a metal coupon to the surface of the metal structure, positioning the metal coupon at a predetermined position relative to the surface of the metal structure and within the electrolytic environment, applying a cathodic protection agent to the surface of the metal structure to effect cathodic protection of the surface of the metal structure, measuring a cathodic protection indication proximate to the metal coupon, comparing the cathodic protection indication with a predetermined value, and adjusting the cathodic protection agent being applied to the surface of the metal structure in response to the comparison.

Abstract: The present invention provides a method of testing a cryogenic metal tank before it is put into service, in which said method said tank (1) is filled with water and appropriate measurements are performed where necessary, the method being characterized in that the following steps are performed: filling said metal cryogenic tank (1) with sea water; and providing the bottom and side metal walls (2, 3) of said tank (1) that are constituted essentially by bare steel, with temporary cathodic protection by injecting an electric current into anodes disposed within said tank (1) once said anodes become immersed. Advantageously, a first anode array (51) is placed in the immediate vicinity of the bottom of the tank using support means (52), said support means (52) and said first anode(s) (51) preferably being removable.

Abstract: A method for testing a cathodic protection system is disclosed where the system includes a cathodic protection rectifier configured to apply a voltage across a pipeline and a reference point. The method includes measuring a magnitude of an output voltage of the cathodic protection rectifier, transmitting to a site remote from the rectifier, the measured output voltage magnitude using a cellular control channel, receiving the transmitted measurement at the remote site, and using the transmitted measurement to determine whether the cathodic protection system is operational.

Abstract: Described herein are wireless interrogation systems and methods that rely on a complementary sensing device and interrogator. The sensing device is disposed to measure a parameter indicative of the health of a structure. A sensor reading from the sensor indicates the level of a parameter being monitored or whether one or more particular physical or chemical events have taken place. Using wireless techniques, the interrogator probes the device to determine its identity and its current sensor reading. This often includes transmission of a wireless signal through portions of the structure. When activated, the device responds with a wireless signal that identifies the device and contains information about the parameter being measured or a particular sensor state corresponding to the parameter. The identity of the device allows it to be distinguished from a number of similar devices.

Abstract: A system using tank corrosion sensors to provide for an overall assessment and monitoring of the electro-chemical corrosion and coatings condition in ships' tanks, and particularly in ships' seawater or compensated fuel tanks. The system includes reference half-cells mounted along a suspended cable and one instrumented sacrificial anode at the end of the cable to provide optimal sensing capability within a tank structure. The reference half-cells and the sacrificial anode measure a potential and current output, respectively. Together the measurements provide objective information that can be used to predict corrosion damage and coating deterioration occurring throughout the structure of the tank. The system may be used for an overall assessment and monitoring of the electro-chemical corrosion and coatings condition. In a preferred embodiment, the measurements are stored in a datalogger that is optimally contained within an associated instrument housing.

Abstract: A method for the in situ measurement of atomic hydrogen permeation into carbon steel from process streams under operating conditions of up to 3000 psi and temperatures up to 300° F. includes providing a probe assembly that includes a test specimen electrode and a negatively charged counter electrode in a fluid-tight reservoir containing an electrolyte, mounting the probe assembly directly in contact with a process stream and passing electrical conductors from the probe through a supporting, electrically non-conductive isolator positioned between a mounting assembly and the probe; maintaining a constant voltage across the electrodes and thereby directly measuring and recording permeation current flow between the probe electrodes.

Abstract: An electrochemical scale detection and control system, for on-line detection and control of nucleation and growth of inorganic scales. The system comprises sensitive microprocessor controlled electrochemical monitoring instrumentation for detecting electrochemical changes which occur as a consequence of scale nucleation, growth and removal, with subsequent processing to provide means of controlling scale inhibitor additions. The device takes measurements continuously and provides uninterrupted output of the scaling tendency. A three-element measurement probe consisting of material having little propensity for corrosion in the scaling medium of interest is used as the scale sensor.

Abstract: A monitoring method and system to monitor an environment in which an object is located includes monitoring one or more environmental factors associated with corrosion of materials in the environment. Thereafter, an exposure index representative of cumulative exposure of the object to the one or more environmental factors is determined. For example, such environmental factors may include chloride ion concentration, pH level, humidity, and temperature.

Abstract: The invention provides a device for selective molecular recognition, the device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer comprising a hyperbranched compound having:

Abstract: A method for monitoring and reducing corrosion in furnace boiler tubes measures electrochemical noise associated with corrosion mechanisms while corrosion is occurring at the surface of the tubes as they are exposed to combustion products. This noise is detected using a probe at the boiler waterwall surface that is connected to a corrosion monitor. The monitor contains a computer and software which determines a corrosion rate from the measured electrochemical noise. That rate is compared to a standard to determine if the rate is within acceptable limits. If not, the operator of the furnace or an Adaptive Process Controller (APC) is notified and adjusts one or more burners to change the combustion products that are responsible for the corrosion. Such an adjustment could be made by changing the amount of air or fuel being provided to the burner or other air slots or air ports.

Abstract: This invention describes a novel means of determining the nature (type) of corrosion in real-time. By identifying localized corrosion at the moment of pit initiation, real-time selection, and effective concentration(s) of appropriate inhibitor(s) can be delivered to an electrolytic solution before propagation of the localized corrosion. Integrating this information with a corrosion inhibitor feed system can effectively inhibit the corrosion before propagation occurs, thereby maintaining system integrity. The process embodies a method of operation wherein the electrochemical noise (ECN) and linear polarization (LPR) values are processed to compare how the corrosion signals correlate. Divergence of the corrosion rates indicates the formation of localized corrosion while continuity in signal pattern indicates generalized corrosion.

Abstract: An electrode design is provided for corrosion monitoring using electrochemical noise measurements. Electrochemical probes are used for sensing electrochemical noise voltage values and electrochemical noise current values. The electrochemical probes include a pair of working electrodes formed of the same material of the monitored metal pipes or storage vessels and a reference electrode formed of a corrosion resistant material. Each of the pair of working electrodes has a defined surface roughness. One of the pair of working electrodes has reduced roughness, whereby sensitivity to sustained localized pitting corrosion is increased in the working electrode with reduced roughness. By reducing the surface roughness of one of the pair of working electrodes, increased sensitivity to sustained localized pitting corrosion is provided while the current noise can be used to accurately measure the general corrosion rate on the unpolished electrode.

Abstract: An electrode component group for a corrosion measuring system for detecting corrosion of a metal embedded in a construction component of ion-conducting material has a rod-shaped base body having a first flange member at a first end of base body and a second flange member at a second end of base body. The base body is insertable into the construction component with the first end leading. A plurality of spacer rings is positioned on the base body between the first and second flange members. The metal electrode rings and sealing rings are arranged alternatingly between the spacer rings. Each one of the metal electrode rings have an electrical line connected to a measuring circuit external to the construction component. The electrical lines are guided inside the metal electrode rings to the second end of the base body. A device for reducing a spacing between the first and second flange members is provided.

Abstract: A method and apparatus for the indentification of corrosion in a metal object is disclosed. The method comprises analyzing the statistical distribution of signals generated between two electrodes, typically exposed to the same corrosion conditions as the metal object, and preferably analyzes the skewness and kurtosis of the signals. Neural nets are preferably used in the analysis.

Abstract: An electrochemical method for measuring localized corrosion and other heterogeneous electrochemical processes is described. A multi-sensor electrode namely the wire beam electrode, integrated by coupling all its wire terminals together, is used to simulate a conventional one-piece metal electrode surface in electrochemical behavior. The working surface of the wire beam electrode is exposed to an electrolyte as a conventional one-piece electrode to allow heterogeneous electrochemical processes such as localized corrosion to occur. Electrochemical parameters at local areas of the wire beam electrode surface are detected by means of wires located at those areas. A zero resistance ammeter is inserted between each selected wire terminal and all other coupled wire terminals to measure the coupling current flowing into or out the selected wire, and thus a coupling current distribution map is produced.

Abstract: An electrolytic test machine is used for a corrosion resistance test for a test material comprised of a metal blank and a coating film. The electrolytic test machine is constructed so that an adverse influence, due to chlorine gas generated during a test, can be inhibited. The electrolytic test machine includes an electrolytic cell in which an aqueous solution of NaCl is stored so that a test material is immersed in the aqueous solution of NaCl. An electrode is immersed in the aqueous solution of NaCl. A DC power source supplies electric current between the electrode and the test material. A chlorine gas treating device collects chlorine gas which is generated with electrolysis of the aqueous solution of NaCl and which is released out of the aqueous solution of NaCl along with the aqueous solution of NaCl. The chlorine gas treating device includes a treating pipe line, a suction pump mounted on the treating pipe line, and a chlorine gas purifying member.

Abstract: Corrosion of a metal member under heat transfer condition is monitored by using a test coupon made of the same material as that of the metal member. The test coupon may have a welded portion and a crevice. One substantial surface of the test coupon is heated by a sheet shaped heating element, and at least one portion of the other surface of the test coupon is contacted with the corrosive fluid. After detecting a status of corrosion of the test coupon, the corrosion of the metal member is monitored based on the results of the detection. In case a counter electrode or reference electrode is used, the electrode is immersed in the corrosive fluid, and electrical signals between the test coupon and the electrode are measured. Then, the corrosion of the metal member is monitored.

Abstract: A hand-held and flexible corrosion sensor is described that uses electrochemical impedance spectroscopy (EIS, also known as AC impedance) to detect coating degradation and corrosion of coated and uncoated metals. The hand-held and flexible corrosion sensor is pressed against the surface of the structure of specimen to be inspected, and may be either straight in structural configuration in the form of a pen or bent in a curved or angled manner to achieve better access to the structure. An EIS spectrum can than be obtained in the field or under arbitrary conditions and the degree of coating or material degradation can be determined from the resultant spectrum. There are no restrictions on the configuration of the structure being inspected. The area of detection is controlled by moderating the extent and degree of wetness of the surface. A dry surface will provide a localized measurement; a wet surface will allow inspection of the wetted area.

Abstract: Corrosion is monitored by making a resistance measurement between a contact and an uncorroded or relatively uncorroded portion of the article to be monitored. Changes in the resistance measured are a result of the presence of a corrosion product, or the breakdown of protective coatings by corrosion. The contact may be a sensor washer which is held in place around a threaded stud 6 by nut 12. The washer comprises a steel ring 14 and an electrically conducting ring 18 which is insulated from ring 14 and contacted by circling 21 and conductor wire 23 in resin jacket 22. The measurement may be made on magnesium alloy gearboxes in helicopter. The alloy may be protected by a paint film so that the initial resistance measured is very high.

Abstract: A method and apparatus are provided for monitoring localized pitting corrosion in metal pipes or storage vessels. Electrochemical probes are used for sensing electrochemical noise voltage values and electrochemical noise current values. The root-mean-square electrochemical noise current and voltage values are calculated and stored for the sensed electrochemical noise voltage values and the electrochemical noise current values. The stored electrochemical noise current and voltage values are processed by transforming the stored electrochemical noise current and voltage values into power spectral density data utilizing a fast Fourier transform. A slope of the power spectral density data relative to frequency is calculated. The electrochemical probes include a pair of working electrodes formed of the same material of the monitored metal pipes or storage vessels and a reference electrode formed of a corrosion resistant material.

Abstract: An improved corrosion measurement system for determining the rate of corrosion of a fluid medium. The system is comprised of a highly sensitive excitation and amplification electronic circuitry for registering and displaying the stable and accurate measurement results. A unique unitized measurement probe is temperature stabilized using thermally inertially balanced metallic probes; the first reference element being coated with an impermeable insulating coating, the second, the corroding element, being fully exposed to the corrosive fluid medium.

Abstract: An electrode system for monitoring potentials between electrodes that includes a structure having a surface, a first electrode, a second electrode, an electrolyte, and a monitor to measure the potentials between the first and second electrodes. The first electrode is connected to the surface of the structure. The second electrode and surface of the structure are each in direct physical contact with the electrolyte so that a potential exists between the first and second electrodes. In certain embodiments, the electrode system may further include a reference electrode that is in physical contact with the electrolyte and physically isolated from the first and second electrodes so that a potential exists between the reference, first, and second electrodes. Optionally, the electrode system further includes an apparatus for measuring a background change in the potentials between electrodes and compensating for this background change.

Abstract: A method and apparatus for sensing corrosion are provided in which an interrogation unit (14) transmits interrogation pulses and receives responses. A plurality of corrosion sensors (12) are disposed in the structure to be monitored (10), each of the sensors (12) generating an output. A plurality of responders (16) are powered from the interrogation pulses, one each of the responders (16) associated with one each of the sensors (12). The responders (16) are operable to transmit responses to the interrogation pulses based on the corrosion sensors' (12) output.

Abstract: A method for monitoring cracks in a sample of materials by applying the theory that the phase angle increases in the sample of materials being tested where cracks have formed. The method is performed by preparing a solution capable of forming cracks in the sample, preparing an auxiliary electrode, then making the sample and the auxiliary electrode contact with the solution, preparing a frequency generator connecting the sample and the auxiliary electrode respectively, choosing a frequency, and turning on the frequency generator with an alternating current of the frequency, monitoring the phase angle measured in the sample, and determining the formation of cracks in the sample by checking whether the phase angle measured in the sample increases with time.

Abstract: This method and apparatus detects the potential for corrosion of pipes fabricated out of conductive material embedded in non-conductive material, due to contact between a conductive medium foreign to the pipe and the conductive material embedded within the pipe wall. The electric potential between the foreign medium and the pipe conductive material is determined. The stability of the potential is then ascertained. If the potential does not vary beyond a predetermined range over a period of time, the potential is deemed stable and is indicative of contact between the foreign medium and the conductive material within the pipe, fostering corrosion. An unstable voltage indicates lack of electrical contact.