Heavy Metal Soap Containing Patents (Class 208/239)
  • Patent number: 10767118
    Abstract: A scavenger composition comprising a carrier and an active metal, wherein the carrier is present in an amount of about 1.0 wt % to about 99.0 wt. %, based on total weight of the composition, and the active metal is present in an amount of about 1.0 wt % to about 99.0 wt. %, based on total weight of the composition, wherein the active metal is a metal salt or metal chelate, and wherein the metal is chosen from iron, copper, molybdenum and zinc.
    Type: Grant
    Filed: January 6, 2017
    Date of Patent: September 8, 2020
    Assignee: Innophos, Inc.
    Inventors: Jean Valery Martin, Giovanni Onnembo, Evelyn Olanipekun, Kevin Kempton, Arbnor Ibraimi, William Carton
  • Patent number: 9480946
    Abstract: A transition metal carboxylate scavenger may be used to scavenge contaminants from systems from mixed production and/or gas, either dry or wet hydrocarbon gas. The contaminants scavenged or otherwise removed may include, but are not necessarily limited to, H2S, mercaptans, sulfides, and combinations thereof. Suitable transition metal carboxylates in the scavenger include, but are not limited to, zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.
    Type: Grant
    Filed: March 21, 2014
    Date of Patent: November 1, 2016
    Assignee: BAKER HUGHES INCORPORATED
    Inventors: Sunder Ramachandran, Scott E. Lehrer, Vladimir Jovancicevic
  • Patent number: 8246813
    Abstract: The invention provides a method of removing sulfides from viscous petroleum streams such as asphalt, crude oil, and oil slurry using zinc octoate in which the molar ratio of zinc complexed with octanoic acid is not 1:2. Because zinc has a +2 charge and carboxylic acid has a ?1 charge, it was previously assumed that all zinc octoates must have a 1:2 ratio of zinc moieties to carboxylic acid. Zinc octoate formulations however, that contain a non 1:2 ratio, and those with 2.1:3 to 1.97:3 in particular, have in fact been shown to work better. In addition, these non 1:2 formulations have lower viscosity and therefore are easier to use than the previous formulations including a 1:2 ratio.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: August 21, 2012
    Assignee: Nalco Company
    Inventors: Dennis R. Compton, Samuel Jefferies, Ron Sharpe
  • Publication number: 20110139686
    Abstract: The invention provides a method of removing sulfides from viscous petroleum streams such as asphalt, crude oil, and oil slurry using zinc octoate in which the molar ratio of zinc complexed with octanoic acid is not 1:2. Because zinc has a +2 charge and carboxylic acid has a ?1 charge, it was previously assumed that all zinc octoates must have a 1:2 ratio of zinc moieties to carboxylic acid. Zinc octoate formulations however, that contain a non 1:2 ratio, and those with 2.1:3 to 1.97:3 in particular, have in fact been shown to work better. In addition, these non 1:2 formulations have lower viscosity and therefore are easier to use than the previous formulations including a 1:2 ratio.
    Type: Application
    Filed: December 15, 2009
    Publication date: June 16, 2011
    Inventors: Dennis R. Compton, Samuel Jefferies, Ron Sharpe
  • Patent number: 7632396
    Abstract: A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha and distillate streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is blended with an aqueous solution of water, a caustic, and at least one metal sulfide thereby resulting in an organic phase and an aqueous phase. The blended stream is then passed through a bed of solids having a suitable surface area so that a substantial amount of the sulfur moieties are removed by the aqueous phase.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: December 15, 2009
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Joseph L. Feimer, David J. LeClair, Lawrence J. Lawlor
  • Patent number: 7267760
    Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: September 11, 2007
    Inventors: Jeffrey H. Sherman, Richard T. Taylor
  • Patent number: 5674378
    Abstract: The present invention is directed to a process for the removal of elemental sulfur from fluids such as fuels, e.g. gasoline, kerosene, diesel or jet, by contacting said fluids with an immiscible treatment solution comprising water or immiscible alcohol, caustic, sulfide or hydrosulfide and optionally mercaptan, in a staged co-current mixer under conditions such that the immiscible treatment solution constitutes the continuous phase.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: October 7, 1997
    Assignee: Exxon Research & Engineering Company
    Inventors: Daniel William Kraemer, Ramesh Relumal Hemrajani
  • Patent number: 4902408
    Abstract: Hydrogen sulphide is removed using transition metal carboxylates.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: February 20, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunther Reichert, Christian Wegner