Abstract: A scavenger composition comprising a carrier and an active metal, wherein the carrier is present in an amount of about 1.0 wt % to about 99.0 wt. %, based on total weight of the composition, and the active metal is present in an amount of about 1.0 wt % to about 99.0 wt. %, based on total weight of the composition, wherein the active metal is a metal salt or metal chelate, and wherein the metal is chosen from iron, copper, molybdenum and zinc.
Type:
Grant
Filed:
January 6, 2017
Date of Patent:
September 8, 2020
Assignee:
Innophos, Inc.
Inventors:
Jean Valery Martin, Giovanni Onnembo, Evelyn Olanipekun, Kevin Kempton, Arbnor Ibraimi, William Carton
Abstract: A transition metal carboxylate scavenger may be used to scavenge contaminants from systems from mixed production and/or gas, either dry or wet hydrocarbon gas. The contaminants scavenged or otherwise removed may include, but are not necessarily limited to, H2S, mercaptans, sulfides, and combinations thereof. Suitable transition metal carboxylates in the scavenger include, but are not limited to, zinc octoate, zinc dodecanoate, zinc naphthenate, and combinations thereof.
Type:
Grant
Filed:
March 21, 2014
Date of Patent:
November 1, 2016
Assignee:
BAKER HUGHES INCORPORATED
Inventors:
Sunder Ramachandran, Scott E. Lehrer, Vladimir Jovancicevic
Abstract: The invention provides a method of removing sulfides from viscous petroleum streams such as asphalt, crude oil, and oil slurry using zinc octoate in which the molar ratio of zinc complexed with octanoic acid is not 1:2. Because zinc has a +2 charge and carboxylic acid has a ?1 charge, it was previously assumed that all zinc octoates must have a 1:2 ratio of zinc moieties to carboxylic acid. Zinc octoate formulations however, that contain a non 1:2 ratio, and those with 2.1:3 to 1.97:3 in particular, have in fact been shown to work better. In addition, these non 1:2 formulations have lower viscosity and therefore are easier to use than the previous formulations including a 1:2 ratio.
Type:
Grant
Filed:
December 15, 2009
Date of Patent:
August 21, 2012
Assignee:
Nalco Company
Inventors:
Dennis R. Compton, Samuel Jefferies, Ron Sharpe
Abstract: The invention provides a method of removing sulfides from viscous petroleum streams such as asphalt, crude oil, and oil slurry using zinc octoate in which the molar ratio of zinc complexed with octanoic acid is not 1:2. Because zinc has a +2 charge and carboxylic acid has a ?1 charge, it was previously assumed that all zinc octoates must have a 1:2 ratio of zinc moieties to carboxylic acid. Zinc octoate formulations however, that contain a non 1:2 ratio, and those with 2.1:3 to 1.97:3 in particular, have in fact been shown to work better. In addition, these non 1:2 formulations have lower viscosity and therefore are easier to use than the previous formulations including a 1:2 ratio.
Type:
Application
Filed:
December 15, 2009
Publication date:
June 16, 2011
Inventors:
Dennis R. Compton, Samuel Jefferies, Ron Sharpe
Abstract: A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha and distillate streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is blended with an aqueous solution of water, a caustic, and at least one metal sulfide thereby resulting in an organic phase and an aqueous phase. The blended stream is then passed through a bed of solids having a suitable surface area so that a substantial amount of the sulfur moieties are removed by the aqueous phase.
Type:
Grant
Filed:
May 6, 2005
Date of Patent:
December 15, 2009
Assignee:
Exxonmobil Research and Engineering Company
Inventors:
Joseph L. Feimer, David J. LeClair, Lawrence J. Lawlor
Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
Abstract: The present invention is directed to a process for the removal of elemental sulfur from fluids such as fuels, e.g. gasoline, kerosene, diesel or jet, by contacting said fluids with an immiscible treatment solution comprising water or immiscible alcohol, caustic, sulfide or hydrosulfide and optionally mercaptan, in a staged co-current mixer under conditions such that the immiscible treatment solution constitutes the continuous phase.
Type:
Grant
Filed:
June 11, 1996
Date of Patent:
October 7, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
Daniel William Kraemer, Ramesh Relumal Hemrajani