Plural Or Combined With Additional Distillation Patents (Class 208/354)
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Patent number: 10835837Abstract: Processes and systems for separating a mixture of three or more chemical components into multiple product streams each enriched in one of the components are provided herein. In some aspects, the present invention relates to processes for the separation of a chemical mixture including at least a heavy key component, an intermediate key component, and a light key component to form a product stream enriched in the light key component, a product stream enriched in the intermediate key component, and a product stream enriched in the heavy key component. Systems described herein may include one or more thermally coupled distillation columns including, for example, a dividing wall column, or a plurality of distillation columns arranged in a thermally integrated configuration.Type: GrantFiled: April 26, 2019Date of Patent: November 17, 2020Assignee: Eastman Chemical CompanyInventors: Craig Alan Hoyme, Robert Scott Huss
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Patent number: 10792583Abstract: The present invention relates to the fractionation technology that is used to create purified phenol and acetone products. More specifically, the present invention relates to a fractionation technology that is used to create crude acetone and crude phenol streams using a dividing wall column intended to remove cumene, alpha-methyl styrene and water from the product side of the wall.Type: GrantFiled: March 28, 2019Date of Patent: October 6, 2020Assignee: UOP LLCInventors: Russell C. Schulz, Chad A. Williams, James W. Harris, Nikunj Manubhai Patel
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Patent number: 10435636Abstract: A method and apparatus for the reduction of fouling in a crude unit. Chemicals containing Phosphorous are understood to be utilized in the production or transportation of certain types of crude oils. It is believed that the elevated levels of phosphorus are contributing to the excessive fouling observed in the preheat exchanger circuits and crude heaters.Type: GrantFiled: March 7, 2017Date of Patent: October 8, 2019Assignee: Marathon Petroleum Company LPInventors: James F. Johnson, Gregory A. Cantley, Phillip Ryan Adams
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Patent number: 8986537Abstract: Provided are multiple correlations for relationships between MI value for a brightstock extract and the distillation cut point temperature used for separation of the vacuum resid that is used to form the brightstock extract. Based on these correlations, a BSE having a desired MI value can be formed based on an adjustment of the distillation cut point temperature. A first correlation establishes a relationship between a fractional weight boiling temperature for a vacuum resid fraction and a distillation cut point temperature for separating the vacuum resid fraction from at least one distillate fraction in a feedstock. A second correlation establishes a relationship between a fractional weight boiling temperature for a brightstock extract derived from the vacuum resid fraction, and the fractional weight boiling temperature for the vacuum resid fraction. A third correlation has been established between the fractional weight boiling temperature for the brightstock extract and a mutagenicity index value.Type: GrantFiled: March 14, 2013Date of Patent: March 24, 2015Inventors: Cristina M. Sircar, Keith K. Aldous, James J. Freeman, Katy O. Goyak
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Patent number: 8986536Abstract: The present invention provides a method and an apparatus for recovery of spent lubricating oil. The evaporation of hydrocarbon fractions from spent lubricating oil is carried out in three steps. The first step is at approximately 150-1030 mbar and between 70-240° C. in which is greater than 99% water, greater than 99% of ethylene glycol and greater than 50% of hydrocarbon molecules with normal boiling point up to 310° C. are evaporated from spent oil. The second step is operated at 6-30 mbar and 200-2900 C in which predominantly gasoil and light vacuum gasoil fractions are evaporated. The third step is operated at 250-320° C. and 0.5-15 mbar in which mainly heavy vacuum gasoil (boiling range of 425 to 570° C. on ASTM D-1160 test) is evaporated from spent oil.Type: GrantFiled: November 8, 2010Date of Patent: March 24, 2015Inventor: Rohit Joshi
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Patent number: 8940154Abstract: A system and process for the preparation of high quality gasoline through recombination of catalytic hydrocarbon includes fractionator and extractor. The upper part of the fractionator is equipped with light petrol pipeline, the lower part of the fractionator is equipped with heavy petrol pipeline, the middle part of the fractionator is equipped with medium petrol pipeline. The medium petrol pipeline is connected with a medium petrol extractor, the upper part of the medium petrol extractor is connected with the medium petrol raffinate oil hydrogenation unit through the pipeline, the lower part of the medium petrol extractor is connected with the medium petrol aromatic hydrocarbon hydrogenation unit through the pipeline.Type: GrantFiled: November 6, 2008Date of Patent: January 27, 2015Inventor: Ranfeng Ding
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Publication number: 20140353216Abstract: A column for consecutive extractive distillations, in particular of crude hydrocarbon mixes comprising aromatic, naphthene and paraffin hydrocarbons. The invention also relates to methods for separating and recovering the components of a crude hydrocarbon mix comprising aromatic, naphthene and paraffin hydrocarbons by consecutive extractive distillations provided by means of the column for consecutive extractive distillations, to which the invention also relates.Type: ApplicationFiled: December 14, 2012Publication date: December 4, 2014Applicant: SIME S.R.L.Inventors: Luciano Scibola, Stefano Favilli
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Patent number: 8709238Abstract: Crude tall oil is subjected to a distillation process that substantially removes impurities. The process produces a combined pitch and a distillate of free fatty acids and rosin acids from two vacuum columns. The distillate stream is amenable to further downstream hydroprocessing.Type: GrantFiled: May 18, 2012Date of Patent: April 29, 2014Assignee: UOP LLCInventor: John A. Petri
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Patent number: 8618344Abstract: A process is disclosed for enhanced recovery of propylene and LPG from the fuel gas produced in Fluid catalytic cracking unit by contacting a heavier hydrocarbon feed with FCC catalyst. In the conventional process, the product mixture from FCC main column overhead comprising naphtha, LPG and fuel gas, are first condensed and gravity separated to produce unstabilized naphtha, which is subsequently used in the absorber to absorb propylene and LPG from fuel gas. However, the recovery of propylene beyond 97 wt % is difficult in this process since unstabilized naphtha already contains propylene of 5 mol % or above. In the present invention, C4 and lighter components from unstabilized naphtha are first stripped off in a separate column to obtain a liquid fraction almost free from propylene (<0.1 mol %) and other LPG components. Such a stripped liquid fraction, after cooling to 20° C. to 30° C.Type: GrantFiled: June 9, 2010Date of Patent: December 31, 2013Assignee: Reliance Industries LimitedInventors: Manoj Yadav, Sukumar Mandal, Asit Kumar Das, Yogesh Gupta, Minaz Makhania, Gobind Tulsi, Shailendra Arora, Shubhangi Jaguste
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Publication number: 20130306518Abstract: Crude tall oil is subjected to a distillation process that substantially removes impurities. The process produces a combined pitch and a distillate of free fatty acids and rosin acids from two vacuum columns. The distillate stream is amenable to further downstream hydroprocessing.Type: ApplicationFiled: May 18, 2012Publication date: November 21, 2013Applicant: UOP LLCInventor: John A. Petri
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Patent number: 8337672Abstract: The invention relates to the oil processing industry and can be used for producing vacuum in a vacuum petroleum distillation column. The inventive method involves pumping out a vapor-gas medium from the column by of a gas-gas ejector in such a way that a vapor-gas mixture is formed at the entry thereof and supplying said mixture to a condenser for producing a gas mixture and a vapor phase condensate. The gas mixture is supplied from the condenser to a liquid-gas jet apparatus and the condensate is delivered to an additional separator. A hydrocarbon-containing condensate is removed from the additional separator for the intended use thereof and a water-containing condensate is fed to a steam generator for producing steam by supplying heat of a hot distillate evacuated from the vacuum column. The thus obtained steam is used in the gas-gas ejector as a high-pressure gas.Type: GrantFiled: November 6, 2008Date of Patent: December 25, 2012Inventor: Valery Grigorievich Tsegelsky
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Patent number: 8110094Abstract: A dewatered ethanol residue regenerable and non-regenerable sorbent for the removal of acid gas from hydrocarbon production gas streams and the process for the removal of acid gas from hydrocarbon gas. The process includes the steps of obtaining residue from the distillation of ethanol; de-watering the residue; mixing the de-watered residue with an amine; and, contacting the hydrocarbon gas with the dewatered residue/amine mixture.Type: GrantFiled: December 31, 2008Date of Patent: February 7, 2012Assignee: Intevep, S.A.Inventors: Alfredo Viloria, Rafael Yoll, Yanine González, Mónica Román, José Biomorgi
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Patent number: 8093440Abstract: An improved process for separating a hydrocarbon bearing feed gas containing methane and lighter, C2 (ethylene and/or ethane), and heavier components into a fraction containing predominantly methane and lighter components and a fraction containing predominantly C2 and heavier hydrocarbon components including the steps of cooling and partially condensing and delivering the feed stream to a separator to provide a first residue vapor and a first liquid containing C2, directing a first part of the first liquid containing C2 into a heavy-ends fractionation column wherein the liquid is separated into a second hydrocarbon bearing vapor residue and a second liquid product containing C2; further cooling the second part of the first liquid containing C2 and partially condensing the second hydrocarbon bearing vapor residue; combining the cooled second part of the first liquid and partially condensed second hydrocarbon-bearing vapor residue and directing them to a second separator effecting a third residue and a third liType: GrantFiled: June 4, 2009Date of Patent: January 10, 2012Assignee: Linde Process Plants, Inc.Inventors: Ronald D. Key, William G. Brown
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Patent number: 7993435Abstract: A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the bottoms are maintained under conditions to effect at least partial visbreaking. The visbroken bottoms may be steam stripped to recover the visbroken molecules while avoiding entrainment of the bottoms liquid. An apparatus for carrying out the process is also provided.Type: GrantFiled: September 15, 2006Date of Patent: August 9, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, George J. Balinsky, James N. McCoy, Paul F. Keusenkothen
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Patent number: 7982086Abstract: A process for fractionating isobutene from normal butenes, including: introducing hydrogen and a feed stream comprising isobutene, 1-butene, and 2-butene into a first column including a reaction zone containing a hydroisomerization catalyst operating at a first pressure and concurrently: (i) converting at least a portion of the 1-butene to 2-butene, and (ii) separating isobutene from the 2-butene; recovering a first overheads fraction comprising isobutene from the first column; recovering a first bottoms fraction comprising isobutene, 2-butene, and unreacted 1-butene from the first column; introducing the first bottoms fraction into a top portion of a second column comprising a fractionation column operating at a second pressure lower than the first pressure; separating the first bottoms into a second overheads fraction comprising isobutene and 1-butene and a second bottoms fraction comprising 2-butene; compressing the second overheads fraction; and introducing the compressed second overheads fraction to a loType: GrantFiled: February 3, 2009Date of Patent: July 19, 2011Assignee: Catalytic Distillation TechnologiesInventor: Martinus J. Almering
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Patent number: 7973209Abstract: Processing schemes and arrangements for the catalytic cracking of a heavy hydrocarbon feedstock and obtaining light olefins substantially free of carbon dioxide via amine treatment and employing fractionation processing are provided.Type: GrantFiled: September 28, 2006Date of Patent: July 5, 2011Assignee: UOP LLCInventors: Gavin P. Towler, John P. Brady, William J. Lechnick, Michael A. Schultz
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Patent number: 7820033Abstract: A process for increasing ethylene yield in a cracked hydrocarbon is provided. A hydrocarbon feed stream comprising at least 90% by weight of one or more C4-C10 hydrocarbons can be heated to provide an effluent stream comprising at least 10% by weight propylene. The effluent stream can be selectively separated to provide a first stream comprising heavy naphtha, light cycle oil, slurry oil, or any combination thereof and a second stream comprising one or more C4-C10 hydrocarbons. The second stream can be treated to remove oxygenates, acid gases, water, or any combination thereof to provide a third stream comprising the one or more C4-C10 hydrocarbons. The third stream can be selectively separated to provide a product stream comprising at least 30% by weight propylene. At least a portion of the product stream can be recycled to the hydrocarbon feed stream to increase ethylene yield in the effluent stream.Type: GrantFiled: April 30, 2007Date of Patent: October 26, 2010Assignee: Kellogg Brown & Root LLCInventors: Curtis N. Eng, Yonglin Yang
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Patent number: 7763165Abstract: Processing schemes and arrangements are provided for the processing a heavy hydrocarbon feedstock via hydrocarbon cracking processing with selected hydrocarbon fractions being obtained via fractionation-based product recovery.Type: GrantFiled: December 21, 2006Date of Patent: July 27, 2010Assignee: UOP LLCInventor: Michael A. Schultz
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Patent number: 7708956Abstract: A method and an apparatus for removing sulfur hydrocarbon compounds from a naphtha stream and for simultaneously removing sulfur hydrocarbon compounds from two streams is described. A separator vessel having a top, a bottom, a primary feed inlet and a co-feed inlet is disposed vertically above the primary feed inlet. The separator vessel further includes a catalyst bed disposed between the co-feed inlet and the top. A primary feed stream comprising sulfur hydrocarbon compounds is delivered through the effluent inlet and a vaporized co-feed stream that also comprises sulfur hydrocarbon compounds is delivered through the co-feed inlet. Vaporized sulfur hydrocarbon compounds from the primary feed stream with the vaporized co-feed stream pass upwardly through the desulfurization catalyst bed. Sulfur hydrocarbon compounds from both primary feed and co-feed stream are at least partially converted to hydrogen sulfide and non-sulfur containing hydrocarbons in the catalyst bed.Type: GrantFiled: September 7, 2007Date of Patent: May 4, 2010Assignee: UOP LLCInventors: Richard K. Hoehn, Giles R. Maddox, David A. Lindsay
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Patent number: 7670573Abstract: A process for decoking of a process that cracks hydrocarbon feedstock containing resid and coke precursors, wherein steam is added to the feedstock to form a mixture which is thereafter separated into a vapor phase and a liquid phase by flashing in a flash/separation vessel, separating and cracking the vapor phase, and recovering cracked product. Coking of internal surfaces in and proximally downstream of the vessel is controlled by interrupting the feed flow, purging the vessel with steam, introducing an air/steam mixture to at least partially combust the coke, and resuming the feed flow when sufficient coke has been removed. An apparatus for carrying out the process is also provided.Type: GrantFiled: October 16, 2006Date of Patent: March 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, Arthur R. Di Nicolantonio, James M. Frye, Subramanian Annamalai, Nicholas G. Vidonic
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Patent number: 7641870Abstract: Hydrocarbon feedstock containing resid is cracked by a process comprising: (a) heating the hydrocarbon feedstock; (b) mixing the heated hydrocarbon feedstock with steam and optionally water to form a mixture stream; (c) introducing the mixture stream to a flash/separation apparatus to form i) a vapor phase at its dew point which partially cracks and loses/or heat causing a temperature decrease and partial condensation of the vapor phase in the absence of added heat to provide coke precursors existing as uncoalesced condensate, and ii) a liquid phase; (d) removing the vapor phase as overhead and the liquid phase as bottoms from the flash/separation apparatus; (e) treating the overhead by contacting with a hydrocarbon-containing nucleating liquid substantially free of resid and comprising components boiling at a temperature of at least about 260° C. (500° F.Type: GrantFiled: January 25, 2008Date of Patent: January 5, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Richard C. Stell, Nicholas G. Vidonic
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Patent number: 7568363Abstract: A process for treating a crude containing natural gas comprising supplying the crude to a stabilization unit to obtain a gaseous stream and crude oil; supplying a compressed, gaseous stream at a low temperature to the bottom of a first column; partly condensing the first gaseous overhead stream, returning the liquid phase to the first column and supplying the methane-rich stream to a liquefaction plant; supplying an expanded bottom stream at a low temperature to the top of a second column; removing from the top of the second column a second gaseous overhead stream, and removing from the bottom of the second column a liquid bottom stream; vaporizing part of the bottom stream and introducing the vapor into the bottom of the second column; and introducing the remainder of the bottom stream into a crude oil stream at an appropriate point in or upstream of the stabilization unit, wherein the amount of heat removed from the first gaseous overhead stream is so adjusted that the concentration of C5+ in the first gaseType: GrantFiled: November 19, 2007Date of Patent: August 4, 2009Assignee: Shell Oil CompanyInventor: David Bertil Runbalk
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Patent number: 7351324Abstract: The present invention relates to a liquid fuel blended by dissolving crude pentane into the heavy oil with different proportions, and applied to different combustion system respectively; the fuel thus formed is easily dissolved, volatilized, atomized and vaporized into fine vapor articles, so it will burn completely to not only increase the heat value but also reduce the pollution without producing the dense smoke like common heavy oil combustion furnace. In addition, alkanes with low price, low octane value and high volatility substitute or blend with the crude pentane to become a liquid fuel having suitable initial boiling point, viscosity and fluidity as well as low price and low pollution, which is much better than common diesel oil.Type: GrantFiled: January 24, 2003Date of Patent: April 1, 2008Inventor: Hong-Lin Chen
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Patent number: 7311813Abstract: This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column.Type: GrantFiled: March 20, 2003Date of Patent: December 25, 2007Assignee: Ineos USA LLCInventors: Rian Reyneke, Michael Foral, Christos G. Papadopoulos, Jeffrey S. Logsdon, Wayne W. Y. Eng, Guang-Chung Lee, Ian Sinclair
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Patent number: 7273542Abstract: The present invention relates to a process and apparatus for recovering product from reactor effluent of a reactor for a hydrocarbon feedstream. An indigenous C4 stream is used as lean oil in a demethanizer, which facilitates significant cost and operational savings. C4 bottoms from a downstream depropanizer is used as lean oil recycle.Type: GrantFiled: April 4, 2003Date of Patent: September 25, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: David J. Duhon, John E. Asplin
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Patent number: 7172686Abstract: Methods of separating components of a mixture, such as crude oil, are disclosed which increase the yield of individual components while decreasing the yield of residue. In one method, a heated mixture is fed to a column, a vapor stream is withdrawn from the column and separated, and a portion of the vapor stream is recycled back to the column. In another method, a mixture is separated into streams composed substantially of components having light, intermediate or heavy molecular weight and/or low, intermediate or high boiling point, respectively, and the streams are fed into the column at different positions. In both methods, individual light, intermediate and/or heavy molecular weight and/or low, intermediate and/or high boiling point component streams are then selectively withdrawn from the column.Type: GrantFiled: March 12, 2003Date of Patent: February 6, 2007Assignee: The Board of Regents of the University of OklahomaInventors: Shuncheng Ji, Miguel J. Bagajewicz
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Patent number: 6723231Abstract: Process to separate propene from gaseous fluid catalytic cracking products by performing the following steps: a) separating a feed mixture comprising the gaseous products, propene and other saturated and unsaturated hydrocarbons obtained in a fluid catalytic cracking process into a hydrocarbon-rich liquid fraction and a hydrogen containing gaseous fraction, b) separating the hydrogen containing gaseous fraction into a hydrogen-rich gaseous fraction and a hydrocarbon-rich gaseous fraction by means of a membrane separation, c) supplying the hydrocarbon-rich gaseous fraction obtained in step (b) to an absorber section and obtaining in said absorber section a lower boiling fraction rich in gaseous products having a boiling point of ethane or below and supplying the hydrocarbon-rich liquid fraction obtained in step (a) to a stripper section and obtaining in said stripper section a higher boiling fraction comprising propene and hydrocarbons having a boiling point higher than ethane.Type: GrantFiled: November 29, 2001Date of Patent: April 20, 2004Assignee: Shell Oil CompanyInventors: Eduard Rudolf Geus, John William Harris, Johan Jan Barend Pek
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Publication number: 20030205506Abstract: A process and apparatus are disclosed that relate generally to a process for reducing harmful or unwanted emissions during the production of asphalt, such as blue smoke. The process includes the introduction of a pump around of the wax oil fraction for re-introduction into the vacuum tower. Additional desirable features include stripping trays below the wax oil collection tray and the feed zone. The result is to produce an asphalt product that creates less blue smoke in the hot mix plant. Another desirable feature is that a product can be created that meets Performance Grade specifications with the addition of polymers or other additives.Type: ApplicationFiled: May 27, 2003Publication date: November 6, 2003Inventors: Kenneth Hucker, Sanford P. Brass
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Patent number: 6576805Abstract: The invention relates to a new process for more efficient separation and recovery of light olefins such as ethylene and propylene from a fluid catalytic cracking unit. The new process invention for recovering olefins from a mixture of cracked hydrocarbons from a fluid catalytic cracker comprises the steps of: (a) providing a mixture of cracked hydrocarbons including methane, ethylene, ethane, propylene, propane, butylene, butane and heavier hydrocarbons such as naphtha produced in a fluid catalytic cracker; (b) separating said mixture into (i) a first stream comprising substantially all of said ethane, ethylene, and methane and a major portion of said propane and propylene and (ii) a second stream comprising a portion of said butylene and butane, and a major portion of said heavier hydrocarbons; and (c) processing said first stream to recover the ethylene and propylene therefrom, and the details of such process described herein.Type: GrantFiled: June 5, 2001Date of Patent: June 10, 2003Assignee: Stone & Webster Process Technology, Inc.Inventors: Ginger S. Keady, Juan Puerto, Berj Garbouchian
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Publication number: 20030047492Abstract: A method for separating a high ethane-content product from a high methane-content feed stream including the steps of introducing a high methane-content feed stream into a first distillation column containing a plurality of vapor-liquid contact devices and generating a first bottoms stream, and introducing the first bottoms stream into a second distillation column containing a plurality of vapor-liquid contact devices and generating a second bottoms stream. Additional steps include recovering an additive stream from the second bottoms stream and injecting the additive stream into the first distillation column, and recovering a high ethane-content product from the second distillation column.Type: ApplicationFiled: September 4, 2002Publication date: March 13, 2003Inventor: Richard B. Hopewell
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Patent number: 6479720Abstract: A process for the production of alkylaromatic hydrocarbons by alkylating aromatic hydrocarbons with linear olefinic hydrocarbons is disclosed. The linear olefinic hydrocarbons are produced by dehydrogenating linear paraffinic hydrocarbons which are extracted from a heartcut that is distilled from a kerosene boiling range fraction in either a dividing wall fractionation column or in two fully thermally coupled fractionation columns. The process significantly decreases the cost of utilities in producing alkylaromatic precursors for detergent manufacture.Type: GrantFiled: December 29, 1999Date of Patent: November 12, 2002Assignee: UOP LLCInventors: Dennis E. O'Brien, Dennis H. Bielinski, Zhanping Xu
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Publication number: 20020053531Abstract: A process and apparatus are disclosed that relate generally to a process for reducing harmful or unwanted emissions during the production of asphalt, such as blue smoke. The process includes the introduction of a pump around of the wax oil fraction for re-introduction into the vacuum tower. Additional desirable features include stripping trays below the wax oil collection tray and the feed zone. The result is to produce an asphalt product that creates less blue smoke in the hot mix plant. Another desirable feature is that a product can be created that meets Performance Grade specifications with the addition of polymers or other additives.Type: ApplicationFiled: November 2, 2001Publication date: May 9, 2002Inventors: Kenneth Hucker, Sanford P. Brass
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Patent number: 6278035Abstract: An improved process for separating a hydrocarbon bearing feed gas containing methane and lighter, C2 (ethylene and/or ethane), and heavier components into a fraction containing predominantly methane and lighter components and a fraction containing predominantly C2 and heavier hydrocarbon components including the steps of cooling and partially condensing and delivering the feed stream to a separator to provide a first residue vapor and a first liquid containing C2, directing a first part of the first liquid containing C2 into a heavy-ends fractionation column wherein the liquid is separated into a second hydrocarbon bearing vapor residue and a second liquid product containing C2; further cooling the second part of the first liquid containing C2 and partially condensing the second hydrocarbon bearing vapor residue; combining the cooled second part of the first liquid and partially condensed second hydrocarbon-bearing vapor residue and directing them to a second separator effecting a third residue and a third liType: GrantFiled: March 17, 2000Date of Patent: August 21, 2001Inventors: Ronald D. Key, William G. Brown
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Patent number: 6271433Abstract: The invention relates to a new process for more efficient separation and recovery of light olefins such as ethylene and propylene from a fluid catalytic cracking unit. The new process invention for recovering olefins from a mixture of cracked hydrocarbons from a fluid catalytic cracker comprises the steps of: (a) providing a mixture of cracked hydrocarbons including methane, ethylene, ethane, propylene, propane, butylene, butane and heavier hydrocarbons such as naphtha produced in a fluid catalytic cracker; (b) separating said mixture into (i) a first stream comprising substantially all of said ethane, ethylene, and methane and a major portion of said propane and propylene and (ii) a second stream comprising a portion of said butylene and butane, and a major portion of said heavier hydrocarbons; and (c) processing said first stream to recover the ethylene and propylene therefrom, and the details of such process described herein.Type: GrantFiled: February 22, 1999Date of Patent: August 7, 2001Assignee: Stone & Webster Engineering Corp.Inventors: Ginger S. Keady, Juan Puerto, Berj Garbouchian
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Patent number: 5675054Abstract: The invention is a process for reducing capital and energy costs in ethylene recovery. Moderate pressure processing and thermally coupled fractionation steps are achieved through the use of integrator columns. Ethylene separation from cracked gas originating from ethane through gas oil feeds can now be done with thermodynamically efficient fractionation at capital cost competitive with low efficiency designs. Acetylene hydrogenation may be done before demethanization where desired, and dephlegmation is preferred to accomplish high-efficiency rectification of hydrogen and methane from ethylene. Open loop heat pumps can optionally be incorporated into the ethane/ethylene splitter fractionation step, whose desirability is controlled by optimization of capital and energy costs.Type: GrantFiled: July 17, 1995Date of Patent: October 7, 1997Inventors: David Manley, Hazem Haddad
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Patent number: 5456823Abstract: A process for the dehydration and/or desalination and simultaneous fractionation of a petroleum deposit effluent containing oil, associated gas and water which can be saline, which process comprises:(a) at least one step for separating the liquid and gaseous phases at the pressure P1 for removal of the gas, producing a gaseous fraction G1, on the one hand, which is removed and a liquid fraction L1, on the other hand, which is sent to step(b) at least one step for separating, at least partly, the two liquid phases mixed in the liquid fraction L1, the aqueous phase being partly removed and the oil phase containing a quantity of residual aqueous phase being sent to step (c);(c) at least one distillation step carried out at a pressure P2 which is less than, or at the most equal to, the pressure P1 in step (a), in a distillation zone C1, said distillation being carried out in the presence of the oil phase coming from step (b), said zone C1 comprising an internal heat exchange zone and a boiling zone, and enablingType: GrantFiled: December 30, 1993Date of Patent: October 10, 1995Assignee: Institut Francais du PetroleInventors: Christophe Lermite, Joseph Larue, Alexandre Rojey
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Patent number: 5415764Abstract: A process for further processing a residue remaining after vacuum distillation in a crude oil refinery, which entails subjecting the residue remaining after vacuum distillation to flash distillation, thereby producing a distillate and a residue.Type: GrantFiled: November 16, 1993Date of Patent: May 16, 1995Assignee: Buss AGInventor: Rolf Van der Piepen
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Patent number: 5389242Abstract: A description is given of a process for the fractionation of oil and gas on a petroleum deposit effluent, including:(a) a stage wherein the liquid and gaseous phases are separated at the gas evacuation pressure P1, producing a gaseous fraction G1, on the one hand, which is evacuated, and a liquid fraction L1, on the other hand, which is constituted at least partially of oil, sending the liquid fraction L1 to stage (b);(b) at least one distillation stage carried out at a pressure P2 which is less than or at least equal to the pressure P1 in stage (a), in a distillation zone C1 which has an internal heat exchange zone and a reboiling zone, and which permits a gaseous fraction G2 to be recovered, on the one hand, and a liquid fraction L2 to be recovered, on the other hand, which is sent to the internal exchange zone, then evacuated; and(c) at least one recompression stage at the pressure P1 of at least a part of the gaseous fraction G2 which is at least partly mixed with the gaseous fraction G2 and evacuated.Type: GrantFiled: August 7, 1992Date of Patent: February 14, 1995Assignee: Institut Francais du PetroleInventors: Christophe Lermite, Joseph Larue, Alexandre Rojey
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Patent number: 5308470Abstract: Non-carcinogenic asphalts and asphalt blending stocks are produced from reduced hydrocarbon feedstocks. Such non-carcinogenic products are produced by establishing a functional relationship between mutagenicity index and a physical property correlative of hydrocarbon type for the asphalt or asphalt blending stock and determining a critical physical property level which, when achieved, results in a product having a mutagenicity index of less than about 1.0. Process conditions are established so that a product stream achieving the desired physical property level can be produced. Non-carcinogenic asphalts and asphalt blending stocks are then processed utilizing the conditions so established.Type: GrantFiled: December 23, 1992Date of Patent: May 3, 1994Assignee: Mobil Oil Corp.Inventors: Gary R. Blackburn, Carl R. Mackerer, Timothy A. Roy
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Patent number: 5264117Abstract: Where side stream distillate strippers are used in the distillation of hydrocarbons, the required size of the distillation column and the amount of stripping gas or vapor required are reduced by passing components stripped from the distillates through a plurality of strippers in series, rather than directly back to the distillation zone.Type: GrantFiled: April 24, 1991Date of Patent: November 23, 1993Assignee: Sun Refining and Marketing CompanyInventor: Gail M. DeLong
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Patent number: 5188709Abstract: The present invention provides an apparatus for preparing and treating a heavy oil extraction solvent. A solvent fraction is separated from a crude oil and combined with a slip stream of rerun solvent taken from an extraction process solvent recycle system. The solvent fraction and rerun solvent are fractionated to provide a purified extraction solvent. The purified extraction solvent is then utilized in the heavy oil extraction process.Type: GrantFiled: November 5, 1990Date of Patent: February 23, 1993Assignee: Phillips Petroleum CompanyInventors: Richard D. Kuerston, Ronald E. Brown
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Patent number: 5164070Abstract: The recovery of distillate products from a hydrocracking process includes passing the liquid-phase portion of the reaction zone effluent into a stripping column. A naphtha sidecut stream is recovered off the stripping column and combined with the net overhead liquid of the column. These combined streams are then combined with the naphtha recovered from the primary product recovery column. This minimizes the hydrogen sulfide present in the total naphtha product.Type: GrantFiled: March 6, 1991Date of Patent: November 17, 1992Assignee: UOPInventor: William H. Munro
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Patent number: 5062948Abstract: The invention provides a method for removing mercury from a liquid hydrocarbon feed material by (a) removing those components having a higher molecular weight than the desired hydrocarbon from the feed material, (b) removing water from the feed material, and thereafter (c) removing mercury from the feed material. Mercury can be removed to an extremely low concentration of 0.001 ppm or lower from a wide variety of liquid hydrocarbon feed materials containing either a relatively large amount or a trace amount of mercury.Type: GrantFiled: February 28, 1990Date of Patent: November 5, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsu Kawazoe, Tsukasa Iida
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Patent number: 5034119Abstract: Non-carcinogenic bright stock extracts and/or deasphalted oils are produced from reduced hydrocarbon feedstocks. Such non-carcinogenic products are produced by establishing a functional relationship between mutagenicity index and a physical property correlative of hydrocarbon type for the bright stock extract or deasphalted oil and determining a critical physical property level which, when achieved, results in a product having a mutagenicity index of less than about 1.0. Process conditions are established so that a product stream achieving the desired physical property level can be produced. Non-carcinogenic bright stock extracts and/or deasphalted oils are then processed utilizing the conditions so established. A bright stock extract and a deasphalted oil substantilly free from mutagenic activity, as well as processes for their production are also provided herein.Type: GrantFiled: March 28, 1989Date of Patent: July 23, 1991Assignee: Mobil Oil CorporationInventors: Gary R. Blackburn, Carl R. Mackerer, Nigel Searle, Arshavir E. Mekitarian, Edward N. Ladov
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Patent number: 5030339Abstract: In the separation of a compressed multi-component hydrocarbon stream containing liquid and gas phases to produce a liquid product stream having a specified maximum vapor pressure and a gas product stream having a specified maximum cricondenbar, gas flaring can be reduced and other advantages obtained by the method of(i) separating the liquid and gas phases in one or more separation stages at progressively reduced pressures to produce said liquid product stream, and(ii) treating the recovered gas phase to obtain the gas product stream by partial condensation of the recovered gas phase and separation of the condensate so formed; wherein(iii) step (ii) includes the step of rectifying the recovered gas phase in a refluxing exchanger and separating the condensate so formed.Type: GrantFiled: October 13, 1989Date of Patent: July 9, 1991Assignee: Costain Engineering LimitedInventor: Bogdan A. Czarnecki
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Patent number: 4994168Abstract: The quality and yield of dewaxed, hydrotreated lube oil base stocks are improved by reducing the top temperature in the hydrotreated lube stripper so as to increase the proportion of heavy kerosene components in the lube oil base stock. The separation system provides for a two stage stripping of the lube oil fraction such that the kerosene fraction stripped from the lube product in the primary product stripper under vacuum is stripped in a second stage stripper at a higher pressure with recycle of the heavy kerosene fraction as a reflux stream to the primary vacuum stripper so that a product with improved viscosity index and flash point is separated in the primary stripper.Type: GrantFiled: October 21, 1988Date of Patent: February 19, 1991Assignee: Mobil Oil CorporationInventor: Mohsen N. Harandi
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Patent number: 4992162Abstract: The present invention provides a method and apparatus for preparing and treating a heavy oil extraction solvent. A solvent fraction is separated from a crude oil and combined with a slip stream of rerun solvent taken from an extraction process solvent recycle system. The solvent fraction and rerun solvent are fractionated to provide a purified extraction solvent. The purified extraction solvent is then utilized in the heavy oil extraction process.Type: GrantFiled: March 30, 1990Date of Patent: February 12, 1991Assignee: Phillips Petroleum CompanyInventors: Richard D. Kuerston, Ronald E. Brown
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Patent number: 4919794Abstract: A process for improving the separation of a hydrocarbon mixture is provided in which the hydrocarbon mixture is separated into fractions in a distillation zone. A liquid fraction and a portion of the vapor phase fraction are removed from the distillation zone as sidestream and introduced into a separation zone comprising a stripping gas to be stripped simultaneously. The resulting stripped vapor is recycled to an upper portion of the distillation zone.Type: GrantFiled: October 17, 1988Date of Patent: April 24, 1990Assignee: Exxon Research and Engineering CompanyInventors: Gregory M. Lipkin, Joseph L. Niedzwiecki
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Patent number: 4885063Abstract: A process and apparatus are disclosed for recovering olefins, particularly C.sub.3, C.sub.4, and C.sub.5 olefins, from gaseous mixture thereof with lower-boiling components. The olefin-containing gas mixtures is compressed and cooled to yield vapor and condensate streams, the vapor stream is further cooled forming additional condensate, both condensate streams are combined and adiabatically flash evaporated, and the remaining liquid is distilled to recover the desired olefins in a liquid bottoms products. Flash vapor, and optionally the distillation vapor product, are recycled to the compression step.Type: GrantFiled: October 19, 1988Date of Patent: December 5, 1989Assignee: Air Products and Chemicals, Inc.Inventor: Robert S. Andre
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Patent number: 4832830Abstract: A process and apparatus for separating selected C.sub.4 olefinic products from combinations thereof with lower boiling point compounds comprises partially condensing a stream containing said products and compounds, atmospherically separating said partially condensed stream to yield gas and liquid streams, stipping said liquid stream to yield stripper overhead gas and stripper bottoms liquids, and recovering said C.sub.4 olefinic and paraffinic products from said stripper bottoms liquid, all at selected temperatures and pressures adapted to produce a high recovered percentage of said desired C.sub.4 olefinic and paraffinic product.Type: GrantFiled: October 2, 1987Date of Patent: May 23, 1989Assignee: Air Products and Chemicals, Inc.Inventor: Lee J. Howard