Abstract: A hollow porous membrane with a reduced cost and excellent separation characteristic, water permeability, and mechanical strength and a process of producing the hollow porous membrane with an excellent adhesive property between a support and a porous membrane layer at a low cost are provided. The hollow porous membrane includes a porous membrane layer in which dense layers are disposed in the vicinities of an outer surface and an inner surface. In the process of producing the hollow porous membrane, membrane-forming dopes of a first membrane-forming dope and a second membrane-forming dope, which contain the material of the porous membrane layer and a solvent, are successively applied and stacked onto the outer circumferential surface of a hollow support and the applied membrane-forming dopes are simultaneously coagulated.

Abstract: A membrane comprising a blend of a sulfonated poly(aryl ether) and a phenyl amine compound along with methods for making and using the same. Many additional embodiments are described including applications for such membranes.

Abstract: An organic/inorganic composite membrane may include hydrophilic inorganic particles dispersed in an organic polymer matrix having finger-like pores. The hydrophilic inorganic particles may be present at a higher concentration near one surface of the membrane having a higher density than the other surface of the membrane having a lower density.

Abstract: A treatment system and a method for removal of at least one halogenated compound, such as PCBs, found in contaminated systems are provided. The treatment system includes a polymer blanket for receiving at least one non-polar solvent. The halogenated compound permeates into or through a wall of the polymer blanket where it is solubilized with at least one non-polar solvent received by said polymer blanket forming a halogenated solvent mixture. This treatment system and method provides for the in situ removal of halogenated compounds from the contaminated system. In one embodiment, the halogenated solvent mixture is subjected to subsequent processes which destroy and/or degrade the halogenated compound.

Abstract: Technologies are generally described for composite membranes which may include a porous graphene layer in contact with a porous support substrate. In various examples, a surface of the porous support substrate may include at least one of: a thermo-formed polymer characterized by a glass transition temperature, a woven fibrous membrane, and/or a nonwoven fibrous membrane. Examples of the composite membranes permit the use of highly porous woven or nonwoven fibrous support membranes instead of intermediate porous membrane supports. In several examples, the composite membranes may include porous graphene layers directly laminated onto the fibrous membranes via the thermo-formed polymers. The described composite membranes may be useful for separations, for example, of gases, liquids and solutions.

Abstract: A method for forming a filter in a fluid flow path in a microfluidic device is provided. The method includes introducing a photopolymerization reaction solution into the microfluidic device; and performing polymerization of photopolymerization reaction solution to form a filter in the fluid flow path in a microfluidic device.

Abstract: A crystalline polymer microporous membrane containing a crystalline polymer microporous film containing a crystalline polymer, and having an asymmetric pore structure; fluorine alcohol covering at least part of an exposed surface of the crystalline polymer microporous film; and a crosslinking agent, wherein the fluorine alcohol is crosslinked with assistance of the crosslinking agent.

Abstract: A method for fabricating a flexible free-standing ultrathin (nano) or thin protein membrane that includes (1) keeping a dilute metal (Cd, Cu or Zn) nitrate or chloride solution under neutral or weak basic pH to spontaneously form metal (Cd, Cu or Zn) hydroxide nanostrands; (2) mixing the metal (Cd, Cu or Zn) hydroxide nanostrands and protein solution to obtain composite nanofibers made of protein and the metal (Cd, Cu or Zn) hydroxide nanostrands; (3) filtering the obtained dispersion of composite nanofibers on a filter; (4) cross-linking the proteins contained in the composite nanofibers by a bifunctional cross-linker; and (5) removing the metal (Cd, Cu or Zn) hydroxide nanostrands.

Abstract: Disclosed herein are a composite semipermerable membrane and a method for producing the same. The composite semipermeable membrane comprises a microporous support membrane and a separation functional layer provided on the microporous support membrane, wherein the separation functional layer contains a condensation product produced by condensation of at least one selected from the group consisting of ions of trialkoxysilanes each having an imidazolium group and a conjugated base of a polymer having at least one acidic group. The composite semipermeable membrane achieves excellent selective separation of divalent ions over monovalent ions, and is suitable for use in various water treatment fields such as seawater desalination and drinking water production.

Abstract: A method for forming a molecularly imprinted polymer biosensor includes: (a) preparing a reaction solution including an imprinting molecule, a functional monomer, an initiator, and a crosslinking agent; (b) disposing the reaction solution in a space between upper and lower substrates each of which is made of a light-transmissible material; (c) disposing on the upper substrate a photomask having a patterned hole; (d) irradiating the reaction solution through the patterned hole of the photomask and the upper substrate so that the reaction solution undergoes polymerization to form a polymer between the upper and lower substrates; (e) removing the upper substrate after the polymer is formed on the lower substrate; and (f) extracting the imprinting molecule from the polymer so that a patterned molecularly imprinted polymer film is formed on the lower substrate.

Abstract: Composite membranes including a coating of polyalkylene oxide and biguanide compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and a biguanide-type compound. In another embodiment, the coating comprises a polymer including alkylene oxide repeating units and one or more biguanide functional groups.

Abstract: The present invention generally relates to gas separation membranes and, in particular, to high selectivity fluorinated ethylene-propylene polymer-comprising polymeric blend membranes for gas separations. The polymeric blend membrane comprises a fluorinated ethylene-propylene polymer and a second polymer different from the fluorinated ethylene-propylene polymer. The fluorinated ethylene-propylene polymers in the current invention are copolymers comprising 10 to 99 mol % 2,3,3,3-tetrafluoropropene-based structural units and 1 to 90 mol % vinylidene fluoride-based structural units. The second polymer different from the fluorinated ethylene-propylene polymer is selected from a low cost, easily processable glassy polymer.

Abstract: A composition comprises a crosslinked poly(meth)acrylate comprising two or more poly(meth)acrylate backbones covalently linked to a bridging group, the backbones comprising i) respective first repeat units, each of which comprises a first side chain ester moiety comprising a hydrophilic poly(alkylene oxide) chain segment, ii) respective second repeat units, each of which comprises a second side chain ester moiety directly linked to the bridging group through a linking group selected from the group consisting of carbamate groups, urea groups, and thiocarbamate groups, and iii) respective third repeat units, each of which comprises a hydrophobic side chain moiety not directly linked to any bridging group. Composite filtration membranes having a selective layer that comprises the composition exhibit useful anti-fouling and/or salt rejection characteristics.

Abstract: Composite membranes including a coating of polyalkylene oxide and acetophenone compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and an acetophenone compound. In another embodiment, the coating comprises a polymer including alkylene oxide repeating units and one or more acetophenone functional groups.

Abstract: A method of making a water vapor transport membrane is described. The method can include providing two sheets, each sheet comprising a support layer with an ionomer layer thereon; applying a solvent to at least one sheet; and contacting the ionomer layers of the two sheets to form a composite membrane comprising a composite ionomer layer between the two support layers. A composite membrane is also described.

Abstract: A microporous organic-inorganic hybrid membrane based on silica of the invention has an average pore diameter of less than 0.6 nm, and comprises bridging organosilane moieties of the formula ?O1.5Si—CHR—SiO1.5? or ?O1.5Si—CH(CH3)—SiO1.5?. The membrane can be used in the separation of hydrogen from mixtures comprising hydrogen and CH4, CO2, CO, N2, and the like, and in the separation of water from alcohols having 1-3 carbon atoms, optionally in the presence of an inorganic or organic acid.

Abstract: The present invention is intended to provide a composite membrane excellent in both durability and moisture permeability. The present invention provides a composite membrane formed by laminating a layer of a moisture-permeable resin on one surface of a hydrophobic porous membrane, the composite membrane being characterized in that the layer of the moisture-permeable resin is included in a reinforcing porous membrane.

Abstract: A hybrid porous structured material may include a porous region (that forms a nanopore structure) and a non-porous region. The porous region may form a stacked structure where a plurality of spherical bodies are stacked so as to contact each other in three dimensions. The non-porous region may form a structure that fills a gap between the plurality of spherical bodies of the porous region.

Abstract: Filtration media including at least one layer of nanofibers having average diameters less than 1000 nanometers with optional scrim layer(s) are disclosed for filtering particulate matter in liquid. The media achieve flow rates of at least 0.055 L/min/cm2 at relatively high levels of solidity. The media have also advantageously been found to have non-diminishing flow rates as differential pressures increase between 2 psi (14 kPa) and 15 psi (100 kPa).

Abstract: Described is the application of layer-by-layer (LbL) electrostatic assembly techniques to electrospun nanofibers in order to fabricate novel, breathable electrospun fiber-based chemical and biological detoxifying protective fabrics and filters. The combination of layer-by-layer electrostatic assembly and electrospinning technique allows one to take advantage of high specific surface area, light weight and breathability of electrospun fiber mats while simultaneously providing the versatility to incorporate different functional polyelectrolytes to achieve multifunctional coatings for both chemical and biological protection together. The functionalized fiber mats can be incorporated into breathable chemical and biological protective fabrics, filters and masks. In addition, LbL electrostatic coating of porous non-woven materials provides the versatility to generate multifunctional polymer-based membrane materials for other applications.

Abstract: A method and an apparatus for separating suspended matter from liquid includes a concentrator filter that draws the liquid out of the suspension while the filter kept unblocked by a sparging filter that allows scrubbing of the concentrator filter by gas bubbles. This invention can be used to replace cross-flow filtration and centrifugation in the bioprocess industry and to reduce the volume of suspensions to concentrate the yield of the end product in the chemical industry.

Abstract: This disclosure discloses a method and a device for the detection of heavy metal ions in water. The method includes: providing a detection material, wherein the detection material includes a hydrophilic layer which is at least partially covered by a hydrophobic layer formed from a long-chain compound selected from the group consisting of a long-chain thiol, a long-chain fatty acid and combinations thereof, and wherein a detection area is an area covered by the hydrophobic layer, and the detection area has a surface having an initial contact angle with water of more than or equal to about 120°; contacting the detection area with an aqueous solution sample; determining whether the surface of the detection area has a hydrophobicity-hydrophilicity change after contact with the aqueous solution sample; and deciding whether heavy metal ions exist in the aqueous solution sample according to the determination.

Abstract: Disclosed is a composite semipermeable membrane, which comprises a separation functional layer on a microporous support, and in which the separation functional layer is made of a condensation product of a polymer that has acidic groups and a trialkoxysilane groups having an imidazolium structure in side chains. The composite semipermeable membrane has excellent selective separation performance for divalent ions over monovalent ions, while exhibiting excellent long-term durability. Also disclosed is a method for producing the composite semipermeable membrane. The composite semipermeable membrane is suitable for uses in various water treatment fields such as the desalination of seawater and the production of drinking water. In addition, the composite semipermeable membrane does not deteriorate as much as conventional composite semipermeable membrane even in cases where the membrane is sterilized by having chlorine-containing raw water permeate therethrough continuously or intermittently.

Abstract: The present invention is directed to microfiltration and ultrafiltration membranes comprising a microporous material. The microporous material comprises: (a) a polyolefin matrix present in an amount of at least 2 percent by weight, (b) finely divided, particulate, substantially water-insoluble silica filler distributed throughout said matrix, said filler constituting from about 10 percent to about 90 percent by weight of said coated microporous material substrate, (c) at least 20 percent by volume of a network of interconnecting pores communicating throughout the coated microporous material, and (d) at least one coating composition applied to at least one surface of the membrane to adjust the surface energy of the membrane.

Abstract: Versions of the invention include compositions and methods for making them that include a polymeric porous membrane with one or more atmospheric pressure microwave plasma modified surfaces. The modified porous membrane is stable, non-dewetting, and retains its mechanical strength.

Abstract: A separation membrane includes a membrane comprising a polymer, characterized in that a functional layer is formed on the surface in one side of the membrane, the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface of the preceding functional layer is 0.1% (by atomic number) or more but not more than 10 (% by atomic number), and the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface opposite to the functional layer is not more than 10 (% by atomic number). A separation membrane module suffering from little sticking of organic matters, proteins, platelets and so on is provided with the separation membrane as a built-in membrane.

Abstract: The problem to be solved by the present invention is to provide a filter medium for a water treatment filter having contradictory characteristics, that is, hydrophilicity and chemical resistance, and a long life, and to provide the production method thereof. A filter medium for a water treatment filter according to the present invention is characterized in comprising a porous base material having a hydrophilic coating layer; wherein the hydrophilic coating layer has a cross-linked hydrophilic polymer and a high electron density part; a hydrophilic polymer in the cross-linked hydrophilic polymer is cross-linked with an aliphatic saturated hydrocarbon group which may contain one or more functional groups selected from a group consisting of an ether group, a hydroxy group and an amino group; the high electron density part has ? electrons; and the high electron density part is covalently bonded to the cross-linked hydrophilic polymer.

Abstract: A membrane with rejection properties for mono and divalent-salts, BOD and COD good resistance to cleaning chemicals and maintaining high permeability for water. A polymeric coating prepared from polydopamine or hydroquinone or catechol or mixtures thereof, is deposited. In another embodiment, coating process steps and conditions are taught to achieve thickness control to tune the rejection properties of the membranes.

Abstract: An object of the present invention is to provide a composite semipermeable membrane which has excellent chemical resistance, separation performance, and water permeability, and the composite semipermeable membrane has the following structure. The present invention provides a composite semipermeable membrane in which an separation function layer is formed on a microporous supporting membrane, wherein the separation function layer is formed from (A) a silicon compound in which a reactive group having an ethylenically unsaturated group and a hydrolyzable group are directly bonded to silicon atoms, and (B) a compound having an ethylenically unsaturated group other than the silicon compound, by condensation of the hydrolyzable group of the silicon compound (A) and polymerization of the ethylenically unsaturated group of the silicon compound (A) and the ethylenically unsaturated group of the compound (B) having the ethylenically unsaturated group.

Abstract: Membranes including at least two sets of fibers having different average diameters, as well as methods of using and methods of making the membranes are disclosed.

Abstract: A polymeric membrane for separating oil from water has a pore size of 0.005 ?m to 5 ?m, a thickness of 50 ?m to 1,000 ?m, a water contact angle of 0° to 60°, an oil contact angle of 40° to 100°. The membrane contains a hydrophobic matrix polymer and a functional polymer that contains a hydrophobic backbone and side chains. The side chains each have an oleophobic terminal segment and a hydrophilic internal segment. The weight ratio of the matrix polymer to the functional polymer is 99:1 to 1:9. Also disclosed is a method of making the above described membrane.

Abstract: Composite membranes including a coating of polyalkylene oxide and triazine compounds along with various methods for making and using the same. In one embodiment, the composite membrane comprises a thin film polyamide layer including a coating of a reaction product of a polyalkylene oxide compound and a triazine compound.

Abstract: A composite semipermeable membrane comprising a porous support membrane on which a separating functional polyamide layer resulting from the polycondensation reaction of polyfunctional aromatic amines with polyfunctional acid halides is formed, wherein the separating functional polyamide layer has carboxy groups, amino groups, phenolic hydroxyl groups, and azo groups, wherein XA, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a feed water contact surface of the separating functional polyamide layer (an A surface), is in the range 0.5 or less, and XB, the ratio of the amino groups (molar equivalent of the amino groups/(molar equivalent of the azo groups+molar equivalent of the phenolic hydroxyl groups+molar equivalent of the amino groups)) on a permeate-side surface of the separating functional polyamide layer (a B surface), i.e.

Abstract: A process for the preparation of cross-linked fluorinated polymers comprising sulfonic acid functional groups comprising the steps of: a) providing at least one fluorinated polymer (P) comprising at least one —SO3M functional group and less than 2% of —SO2F functional groups with respect to the total amount of —SO3M and —SO2F functional groups, wherein each M is selected from H and alkaline metals; and b) reacting said fluorinated polymer with at least one cross-linking agent of formula R(X)n under conditions that promote the formation of covalent bonds between the at least one functional group —SO3M of fluorinated polymer (P) and at least one functional group X of the cross-linking agent.

Abstract: Membranes are made from polymers and heat treated so that they have at least two zones with pores of different sizes. Pores with a smaller size have a lower molecular weight cut off than pores with a larger size. Zones with pores of different sizes may also be made by coating portions of membranes with polymer coatings. Membranes with pores of different sizes may be used in dialyzers for hemofiltration, hemodiafiltration, and other hemodialysis procedures. The membranes may also be used in other separation processes.

Abstract: The present invention is a technique to fabricate thin-film composite perm-selective membranes by a transfer method. The composite membranes are useful in separating liquid, vapor or gaseous mixtures by selective permeation and reduce mass transfer resistance of the support layer. Selectivity and flux are improved by reduction of the mass transfer resistance of the support layer.

Abstract: A separation membrane includes a membrane comprising a polymer, characterized in that a functional layer is formed on the surface in one side of the membrane, the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface of the preceding functional layer is 0.1% (by atomic number) or more but not more than 10 (% by atomic number), and the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface opposite to the functional layer is not more than 10 (% by atomic number). A separation membrane module suffering from little sticking of organic matters, proteins, platelets and so on is provided with the separation membrane as a built-in membrane.

Abstract: A conformal coating that resists fouling by waterborne contamination in aquatic environments, a method for fabricating the coating, and a filter having such a coating are disclosed. The coating comprises a hydrophilic polymer and a surfactant wherein the surfactant undergoes a phase change upon exposure to a saline solution. Also disclosed are in situ methods for regenerating anti-fouling filters having the fouling resistant coating.

Abstract: The present disclosure describes a method for forming microporous membranes. More specifically, vapor induced phase separation techniques are used for forming multizone microporous membranes having improved material throughput.

Abstract: A ceramic filter comprising: (a) from about 75% to about 95% by weight of diatomaceous earth; (b) from about 10% to about 20% by weight of a flux; and (c) from about 0.03% to about 0.4% by weight of a metallic compound; the percentages by weight being percentages by weight of the ceramic filter.

Abstract: A separation membrane including a polymer having a structural unit represented by the following Chemical Formula 1, and a water treatment device including a separation membrane, are useful for desalination.

Abstract: An electrochemical separation membrane and the manufacturing method thereof are disclosed. The method includes: a polymer solution preparing step to mix a polymer material, solvent and ceramic precursors thoroughly to form a polymer solution, wherein the polymer material and the ceramic precursors are dissolved uniformly in the solvent; a coating step to coat the polymer solution on a porous base material; a hydrolysis step to cause the porous base material coated with the polymer solution to contact an aqueous solution to hydrolyze the ceramic precursor into ceramic particles; and a drying step to remove the water and the solvent from the porous base material and in order to form the electrochemical separation membrane. The electrochemical separation membrane made of this method have better ion conductivity, interface stability and thermal stability based on the ceramic particles.

Abstract: A membrane distillation system is provided for distilling liquids. The membrane distillation system includes a heat generating means for heating a non-distilled liquid. The membrane distillation system further includes a microporous membrane that is asymmetric and vapor permeable. The microporous membrane includes a hydrophilic layer and a hydrophobic layer. The membrane distillation system further includes a supply means for delivering the heated non-distilled liquid to the hydrophilic layer of the microporous membrane. A collection means is further provided for collecting distilled liquid from the hydrophobic layer of the microporous membrane. A method of fabricating the microporous membrane for use in the membrane distillation system is also provided.

Abstract: In one embodiment, a membrane comprises: a nonporous, hydrophobic selective layer configured to be on a feed solution side of the membrane and polyethylene layer configured to be on a permeate side of the membrane, wherein the membrane is configured to selectively separate an organic component from an aqueous solution. In some embodiments, the method for separating an organic component from an aqueous stream can comprise: contacting a nonporous, hydrophobic selective layer of a membrane with the aqueous stream comprising the organic component, creating a vacuum on the side of the membrane comprising the support layer, permeating the organic component through the membrane into an exit chamber, and removing the organic component permeate from the exit chamber.

Abstract: The present invention concerns a semipermeable hollow fiber membrane having an outer wall surface, an inner wall surface and an interior lumen extending along the length thereof and having the selective layer on the outer wall surface with a surface roughness below 10 nm. According to the invention the membrane has the smallest pore size on the outer wall surface, and has an outer wall surface which is smooth, continuous and homogeneous in a nanoscopic scale and four to five distinct layers of different pore size and density. Further the present invention concerns a process for manufacturing thereof and the use thereof.

Abstract: Provided is a composite semipermeable membrane comprising a microporous support membrane and a separation functional layer formed thereon, wherein the separation functional layer is formed from Compound (A) in which a reactive group(s) having an ethylenically unsaturated group and a hydrolyzable group(s) are bonded directly to a silicon atom, Compound (B) having an ethylenically unsaturated group, the Compound (B) being different from said Compound (A), and Compound (C) having an ethylenically unsaturated group, the Compound (C) being different from said Compound (A) and (B), by condensation of hydrolyzable groups that the Compound (A) has and polymerization of ethylenically unsaturated groups that the Compound (A), the Compound (B), and the Compound (C) have, and the Compound (A), the Compound (B), and the Compound (C) satisfy the relationship of the following equation (I): |QA?QC|+|QB?QC|=|QA?QB|??(I) (QX represents an Alfrey-Price Q value of Compound X).

Abstract: The present invention provides a medical material and a blood purification apparatus each having high anti-thrombotic properties and high safety. The apparatus is produced by incorporating therein a medical material which has a hydrophilic copolymerization polymer present on a surface thereof which is to be in contact with blood, wherein particulate protuberances each having a particle diameter of 50 nm or more are present on the surface which is to be in contact with blood at a density of 3 particles/?m2 or less and the relaxation time of adsorbed water in the hydrophilic copolymerization polymer is 2.5×10?8 seconds or shorter and 5.0×10?10 seconds or longer at ?40° C.

Abstract: A method for producing of ultra-clean and high-purity electronic acetic acid is disclosed. The method including following steps: Step 1, industrial acetic acid is fast distilled; Step 2, filtering the fraction by membrane of 0.05˜0.3 ?m aperture; Step 3, rectification; Step 4, membrane filtration again. Due to the adoption of the technical scheme above, the ultra-clean and high-purity electronic grade acetic acid which purity is 99.8% is produced. The content of single metal ion is lower than 1 ppb and the content of particulates which is ?0.5 ?m is lower than 5 pcs/ml. The method of the invention will help to reduce energy consumption, to simplify the operation, and to achieve the high security.

Abstract: The present invention provides an absorbent which can remove cells present in blood including activated leukocytes such as granulocytes and monocytes, and cancer cells as well as can remove cytokines which facilitate the activation of the remaining cells, and further has no concern for pressure loss and has high configuration stability. That is, the present invention provides an absorbent which absorbs the granulocytes and the monocytes in blood, an absorbent for cancer therapy which absorbs an immunosuppressive protein and an absorbent having a bilayer structure of a net and a nonwoven fabric, having a zeta potential of ?20 mV or more, as well as a blood circulation column containing any of the absorbents filled therein.

Abstract: Manufacturing processes are provided for nano-porous polymer membranes. Also provided are intermediates suitable to obtain such membranes; polymer membranes as defined herein; shaped articles containing such membranes; and the use of such membranes, shaped articles and intermediates.