By Chemically Modifying Or Inhibiting Dispersed Constituent Patents (Class 210/668)
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Patent number: 5011609Abstract: The disclosure pertains to an oil decontamination and water recycling system which is designed to prevent oil, grease, and fuel contamination of ground or surface water and to return the clean water in a single pass for reuse. Water contamination results from pressure or steam cleaning of grit, scale, oil, grease and fuel contaminated equipment. The system is a closed loop separation, filtration and absorption system which removes these contaminants and most other petroleum products. The free oils are discharged to a holding barrel and the solids are removed from the settlement tank and drained off from the centrifugal separator. The petroleum based contaminants such as oil, grease and fuel are absorbed mechanically by a cartridge filter for easy disposal.Type: GrantFiled: May 25, 1989Date of Patent: April 30, 1991Inventor: Ronald G. Fink
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Patent number: 5010181Abstract: A particle which is capable of removing heavy metal ions from aqueous solution, which comprises chitin having formed thereon a layer of chitosan, wherein the particle has a size of from 0.2 to 1.5 cm, and the chitosan layer on the surface thereof has a depth of form 0.01 microns to 10% of the particle diameter.Type: GrantFiled: March 28, 1988Date of Patent: April 23, 1991Inventor: Robert W. Coughlin
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Patent number: 5002670Abstract: A method for continuously neutralizing quantities of acidic and alkaline waste materials is disclosed. Acidic and alkaline quantities are successively passed through the same weak ion exchanger. The passage of each of the quantities effectively neutralizes that quantity in the ion exchanger while, at the same time, effectively regenerates the exchanger for use in neutralizing the next successive quantity of waste material passed therethrough. Relatively highly acidic and highly alkaline waste materials are first neutralized in a holding vessel before being passed into the ion exchanger.Type: GrantFiled: July 24, 1989Date of Patent: March 26, 1991Assignee: Crane CompanyInventor: Jack B. Pratt
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Patent number: 4997546Abstract: Hydroperoxides can be removed from a lubricating oil by contacting the oil with a heterogenous hydroperoxide decomposer. This extends the useful life of the oil and the equipment being lubricated. In a preferred embodiment, the hydroperoxide decomposer is incorporated on a substrate immobilized within the lubrication system of an internal combustion engine.Type: GrantFiled: September 7, 1989Date of Patent: March 5, 1991Assignee: Exxon Research and Engineering CompanyInventors: Harold Shaub, Darrell W. Brownawell, Arthur DiBenedetto
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Patent number: 4990260Abstract: A method and apparatus for removing contaminants in waters used for industrial cleaning. The method and apparatus begins with water which has been purified to level of approximately 18 megaohms resistivity with total inorganic dissolved solids to 1 part per trillion and total organic dissolved carbon contaminants in the range of approximately 100 parts per billion, and purifies it to a level of approximately 18 megaohms resistivity with total inorganic dissolved solids to 1 part per trillion and total organic dissolved carbon contaminants in the range of approximately 10 parts per billion. The method and apparatus includes means for inducing cavitation in the water and irradiating the water with ultraviolet radiation to thereby cause the oxidizable contaminants to be oxidized and therefore removed before the water is used for industrial cleaning.Type: GrantFiled: January 28, 1988Date of Patent: February 5, 1991Assignee: The Water Group, Inc.Inventor: Joseph Pisani
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Patent number: 4976870Abstract: In photographic processing apparatus for developing, bleaching-fixing and washing photographic materials, a predetermined quantity of fresh wash water is supplied into a washing tank every time a predetermined amount of the photographic materials have been washed. The fresh wash water is provided by deionizing city water and is reservoired in a replenisher tank. In order to detect a predetermined loss of the fresh wash water in the replenisher tank, a conductivity increasing material is dissolved in the fresh wash water in the replenisher tank when a predetermined quantity of the deionized water is supplied so as to electrically connect a pair of electrodes disposed at a predetermined depth of the replenisher tank. A sterilizer is mixed in the fresh wash water to prevent bacterial growth in the replenisher tank.Type: GrantFiled: May 26, 1989Date of Patent: December 11, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Haruo Takase, Kazushige Uenaka, Akira Abe, Yoshihiro Fujita
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Patent number: 4960711Abstract: An apparatus for quantitative determination of trihalomethanes comprises a separation unit containing two channels in contact with each other via a microporous membrane that will not react with trihalomethanes, a reaction unit for heating a carrier solution that has passed through the separation unit, a cooling unit for cooling the carrier solution that has undergone complete reaction; and a detection unit for determining the quantity of a fluorescent substance in the carrier solution. A method for quantitative determination of trihalomethanes comprises flowing a sample solution or a mixture thereof with a reducing agent through one of the two channels in the separation unit, flowing the carrier solution through the other channel, heating the carrier solution that has passed through the separation unit and to which an alkaline nicotinamide or a derivative thereof has been added, cooling the carrier solution, and subjecting the cooled solution to fluorimetry.Type: GrantFiled: January 30, 1989Date of Patent: October 2, 1990Assignee: Fuji Electric Co., Ltd.Inventors: Toyoaki Aoki, Kouji Kawakami, Yoshiharu Tanaka, Hiroshi Hoshikawa
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Patent number: 4960575Abstract: Geothermal steam is condensed with a sulfite solution to abate hydrogen sulfide. A portion of the hydrogen sulfide is converted in the condensation in the presence of soluble cationic polymeric catalysts to soluble sulfur compounds while avoiding elemental sulfur and carbonate formation. The remainder of the hydrogen sulfide is incinerated and the sulfur dioxide in the incinerator effluent is absorbed in an alkaline solution to form the sulfites for the geothermal steam condensation. By maintaining stoichiometric ratios, the hydrogen sulfide is substantially converted to soluble thiosulfate without the use of chelates, peroxides or makeup sulfites.Type: GrantFiled: June 1, 1989Date of Patent: October 2, 1990Assignee: The Dow Chemical CompanyInventors: Stephen A. Bedell, Larry H. Kirby
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Patent number: 4917709Abstract: A simplified, single component resin bed is coupled with a permeation tube and bottle. The permeation bottle contains an ionic species and a dissolved gas. The apparatus makes unnecessary a multi-component resin ion exchange column for solvent pH control in electrolytic conductivity detection as applied to gas chromatography.Type: GrantFiled: August 27, 1987Date of Patent: April 17, 1990Assignee: O. I. CorporationInventors: Randall C. Hall, Karl M. Williams
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Patent number: 4904390Abstract: A method for varying the capacity for a specific chemical element of an ion exchanger used for cleaning a liquid from a loop includes varying the chemical status of the element in the liquid to be cleaned immediately upstream of the ion exchanger by adding given substances. The given substances added are removed immediately downstream of the ion exchanger. The chemical element may be antimony, the loop may be the primary loop of a pressurized water reactor plant and the liquid may be primary coolant.Type: GrantFiled: April 4, 1988Date of Patent: February 27, 1990Assignee: Siemens AktiengesellschaftInventors: Werner Schweighofer, Christian M. Z. Schwabedissen, Brigitte Siewert-Posielek, Karl Habeck, Klaus Seifert
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Patent number: 4898676Abstract: Polymerized salts of polymerizable anionic monomers with cationic germicides are chemically grafted onto activated carbon in a manner to form a permanent, covalent bond thereon. The grafting of such germicides onto the activated carbon imparts permanent bacteriostatic properties thereto and the resulting bacteriostatic activated carbon can be used for the purification of drinking water over prolonged periods of time. The passage of contaminated water across this activated carbon chemically grafted with the polymerized salt of the cationic germicide results in purification of the water which remains free of elevated bacteria counts often associated with "first flush" effluents. Mere absorption of such or any germicide into the pores of the activated carbon results in desorption and leaching out of the germicide into the effluent.Type: GrantFiled: September 14, 1988Date of Patent: February 6, 1990Assignee: Puro Corporation of AmericaInventors: Carl Horowitz, Mohan Sanduja, Michael Dichter, deceased
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Patent number: 4888118Abstract: A process and apparatus employing nylon 4 for the purification of water comprising the steps of contacting the water with iodine in a first treatment zone; nylon 4 complexed with iodine rather than elemental iodine is preferably used and is contacted by the water in the first treatment zone where it releases iodine at levels sufficient to purify the water. The treated and purified water is then contacted with nylon 4 in a second treatment zone where the iodine is removed from the water. The apparatus comprises a conduit having an inlet and an outlet, with a first treatment zone containing nylon 4 material complexed with iodine and a second downstream treatment zone containing nylon 4. The nylon 4 material used in both treatment zones can be in any form, preferably a form having a high surface area. A suitably restrained moistened fine powder may be used as may be textured or untextured, drawn or undrawn, staple fiber, knitted or non-woven fabrics or pulp (fibrils).Type: GrantFiled: April 18, 1988Date of Patent: December 19, 1989Assignee: Nyodine Products, Inc.Inventors: Carl E. Barnes, Arthur C. Barnes
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Patent number: 4883596Abstract: A carbonaceous absorbent to be used for the removal of a pyrogen dissolved in water is disclosed. The absorbent is obtained by carbonizing porous beads of a cross-linked polymer. This absorbent is favorably used for the removal of endotoxin in the production of pure water from deionized water resulting from the treatment with iron-exchange resins.Type: GrantFiled: March 11, 1988Date of Patent: November 28, 1989Assignee: Tokyo Organic Chemical Industries, Ltd.Inventors: Wataru Agui, Shuji Tamura, Hiroshi Kuyama, Yoshiya Kurachi, Masahiko Abe, Yukihiro Kaneko, Keizo Ogino
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Patent number: 4876014Abstract: A method for purifying water or other aqueous media in which a stream of the aqueous media is introduced into a fixed bed of a purification media and turbulent flow through the fixed bed is induced to permit intimate contact between the aqueous media and the purification media. Also disclosed is an apparatus for purifying the aqueous media which includes an outer housing having an inlet aperture and an outlet aperture; a multi-chamber purification unit disposed within the housing, and means for measuring the purity of aqueous media treated within the multi-chamber unit.Type: GrantFiled: March 21, 1988Date of Patent: October 24, 1989Assignee: Water Systems Development CorporationInventor: William S. Malson
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Patent number: 4863637Abstract: A new process for treating waste liquids of acid decontamination agent is disclosed which comprises the steps of neutralizing a waste liquid of acid decontamination agents with an alkali, filtering out suspended matter from the neutralized waste liquid using a filter, removing inhibitors from the filtered waste liquid by adsorption with activated charcoal, removing radioactive ions from the waste liquid treated by activated charcoal with a chelate resin, concentrating the chelate resin-treated waste liquid by evaporation, and bituminizing the concentrate obtained in the preceding step.Type: GrantFiled: October 25, 1988Date of Patent: September 5, 1989Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Hiroyo Matsumoto, Akira Kakimoto, Iwao Nakayasu, Kazuo Yonekura
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Patent number: 4863608Abstract: A new process step for purifying water from a small amount, particularly a last trace amount, of organic impurities included in total organic carbon (TOC) content is incorporated into known processes for the preparation of ultra pure water comprising one or more previous filtration steps and a series of purification steps known per se. The new step comprises irradiating the water to be treated with a light in the presence of a photocatalyst comprising an inorganic semiconductor selected from TiO.sub.2, SrTiO.sub.3 and CdS in fine particulate form and a noble metal and/or an oxide thereof selected from Pt, Pd, Ru, RuO.sub.2 and Rh deposited on said semiconductor particles for a period of time sufficient to oxidatively decompose the organic impurities, resulting in a decrease in TOC content of the water to a level lower than the minimum detection level of TOC detectors, typically <0.05 mg C/l or <0.01 mg C/l depending upon the sensitivity of particular detectors available up to date.Type: GrantFiled: March 9, 1988Date of Patent: September 5, 1989Assignee: Nomura Micro Science Co., Ltd.Inventors: Tomoji Kawai, Hisao Satoh, Yoshiharu Ohta
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Patent number: 4861489Abstract: A water recirculating system is which (a) water is continuously re-circulated through the system for the prime purpose of causing evaporation from the circulating water: and (b) such water is caused during its flow through an open part of said system through which part atmospheric air may flow to impinge on one or more solid surfaces whereby to increase the free water surface area available for evaporation and at a speed sufficient to release small water droplets from the water flow into the surrounding atmosphere. The system includes in serial relation with the water flow path a decontamination means (64) which comprises a chamber through which the circulating water may flow and in which there is provided an ion releasing means (80.Type: GrantFiled: June 1, 1987Date of Patent: August 29, 1989Assignee: Safety First LimitedInventors: Thomas R. Swift, Dennis H. Desty
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Patent number: 4824577Abstract: A process is described for removing phenol and formaldehyde from one aqueous waste stream and melamine and formaldehyde from a second aqueous waste stream with the process being adaptable for treating either stream or both streams simultaneously using a urotropination reaction to render formaldehyde removable by carbon adsorption.Type: GrantFiled: August 17, 1987Date of Patent: April 25, 1989Inventor: Klaus Schwitzgelbel
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Patent number: 4818411Abstract: A deoxygenation process includes the steps of adding hydrazine to a liquid containing dissolved oxygen, passing the liquid through a bed of activated carbon to catalyze a reaction between the dissolved oxygen and hydrazine whereby carbon contaminants are added to the liquid, and removing the contaminants. In another embodiment, unreacted hydrazine that remains in the liquid following the catalysis is removed by passing the liquid through an ion exchange resin. In still another embodiment, an activated carbon-catalyzed deoxygenation process employing hydrazine is practiced on a mobile platform and the process further includes the steps of transporting the apparatus to a regenerating station for regeneration. The invention also includes apparatus for carrying out the process.Type: GrantFiled: July 26, 1985Date of Patent: April 4, 1989Assignee: Ecolochem, Inc.Inventors: Richard C. Dickerson, William S. Miller
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Patent number: 4816138Abstract: The invention concerns a process for converting toxic liquid waste materials containing harmful amounts of biologically difficult to degrade toxic waste materials containing organic halogen compounds, and which also may contain organically bound oxygen, nitrogen and/or sulfur, into an innocuous hydrocarbon stream. These waste materials together with hydrogen are passed over a hydrogenating catalyst at 250.degree.-400.degree. C. and under increased pressure. The effluent of this hydrogenolysis is cooled and separated into a non-toxic liquid hydrocarbon stream, a hydrogen halogenide, ammonia, and/or a hydrogen sulfide containing stream and a gaseous stream of light hydrocarbons and hydrogen. The waste material which contains 0.5-60 weight % halogen and possibly contains up to 10% sulfur and/or small amounts of nitrogen-containing compounds is conditioned and this conditioned stream is passed, together with hydrogen under a prssure of 30-80 bar and with a LHSV of 0.5-2.5 H.sup.Type: GrantFiled: October 6, 1986Date of Patent: March 28, 1989Assignee: Kinetics Technology International B.V.Inventors: Leo Visser, Ashok S. Laghate
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Patent number: 4808316Abstract: A process for treating a waste water containing uranium and fluorine comprises a neutralizing precipitation step wherein slaked lime is added to the waste water containing uranium and fluorine and precipitate thus formed in separated and removed, and an adsorption step wherein supernatant from the neutralizing precipitation step is contacted with a chelating resin which can selectively adsorb fluorine ions and another chelating resin which can selectively adsorb uranyl ions to thereby adsorb and remove the fluorine and uranyl ions remaining in the supernatant. Eluates of the ions adsorbed by the chelating resins and waste liquors for washing and regeneration of these resins are returned to the neutralizing precipitation step. Prior to the neutralizing precipitation step, a decarbonation step may be provided for decomposing carbonate ions, if they are contained in the waste water to be treated.Type: GrantFiled: February 4, 1987Date of Patent: February 28, 1989Assignees: Unitika Ltd., Doryokuro Kakunenryo Kaihatsu JigyodanInventors: Keiichiro Otomura, Yoshikazu Ogura, Yoshiaki Echigo, Mutsunori Yamao, Tadashi Ishikura
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Patent number: 4800024Abstract: A method of treating a heavy metal and/or a radioactive metal-containing natural water or liquid such as a radioactive metal-containing wastewater stream, a potable water supply containing naturally-occuring radioactive elements, an oil containing one or more radioactive metals, or other nuclear metal-bearing liquid by contacting the radioactive heavy metal-containing liquid with a water-insoluble carboxylated cellulose-transition metal oxide mixture to separate the heavy metals from the liquid. The heavy metal and radioactive heavy metals precipitate from the liquid onto the cellulose material to form a radioactive metal-laden solid material. The radioactive metal-laden solid then is air-dried, calcined and/or admixed with a leach-resistant matrix, such as grout or asphalt, for suitable disposal.Type: GrantFiled: August 4, 1986Date of Patent: January 24, 1989Assignee: Iso-Clear Systems CorporationInventor: Geraldine S. Elfline
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Patent number: 4784772Abstract: Ultrapure water are produced and used by subjecting deionized water, which has been obtained from a deionization step making use of an ion-exchange resin, successively to a sterilization treatment, an activated carbon treatment, an ion-exchange resin treatment and a permeable membrane treatment. The water is fed from each of the steps of the treatments after at least the sterilization tretment (inclusive) to the next step through first piping made of a crystalline polyether ether ketone resin having a recurring unit of the following formula: ##STR1## The thus-produced ultrapure water is then fed through second piping, which is also made of the crystalline polyether ether ketone resin, to and through a use system of the ultrapure water.Type: GrantFiled: June 16, 1987Date of Patent: November 15, 1988Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Yoshihisa Gotoh, Toshihiko Tutumi, Toshiaki Takahashi, Katsuhiko Ito
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Patent number: 4775482Abstract: A device and related method for use in defoaming and/or removing certain impurities from a fluid stream is disclosed. The device comprises a housing having an inlet and an outlet, and a filter media disposed between the inlet and outlet comprising a fat-absorbing, nonionic hydrophobic resin. A filter sock for retaining the filter media is disposed in the housing between the inlet and the outlet. The filter above described can be used to remove lipids and other materials from the fluid stream, or alternatively, can be treated with a fatty acid and used to defoam the fluid stream.Type: GrantFiled: May 28, 1985Date of Patent: October 4, 1988Assignee: Mederi Medical Systems, Inc.Inventor: William A. Thurman
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Patent number: 4770783Abstract: Waste from a nuclear power plant, containing organic ion-exchange resin containing radioactive metals, is decomposed to form volatile substances by means of oxidation in an acid, aqueous liquid (8). Radioactive metal ions thus dissolved in the liquid, which are precipitable with hydroxide, are then caused to precipitate by the addition of a hydroxide (10) at a pH value of at least 9, and the metal compounds thus precipitated are separated from at least most of the liquid. Radioactive caesium and strontium ions in this liquid are removed therefrom. The liquid (24) separated from precipitated metal compounds and freed from caesium and strontium ions is released to a recipient, with the remaining substances still dissolved in it, and the precipitated metal compounds (11k, 11s) are solidified in a deposition container (22). The ion-exchange resin preferably consists at least partially of sulphonated ion-exchange resin and the hydroxide preferably of sodium hydroxide or some other alkali metal hydroxide.Type: GrantFiled: January 14, 1987Date of Patent: September 13, 1988Assignee: Aktiebolaget Asea-AtomInventors: Borje Gustavsson, Gunnar Hedin
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Patent number: 4764281Abstract: A method for treating a radioactive metal-containing natural water or liquid such as a radioactive metal-containing wastewater stream, an oil containing one or more radioactive metals, or other nuclear metal-bearing liquid by contacting the radioactive heavy metal-containing liquid with a water-in-soluble carboxylated cellulose to separate the heavy metals from the liquid. The process has been found to be unexpectedly effective on radioactive wastewaters or any other liquid containing one or more radioactive heavy metal ions such as U, Ce, Sr, Ru, Ra, Np, Tc, as well as radioactive ions such as I.Type: GrantFiled: April 7, 1986Date of Patent: August 16, 1988Assignee: Iso-Clear Systems CorporationInventor: Geraldine S. Elfline
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Patent number: 4735728Abstract: A combination of pollution control technologies are employed in the treatment of effluent from photographic processing. The technologies employed are evaporation, oxidation by photolysis and catalyzed ozone, condensation, treatment by activated carbon and electrolysis. The method includes the steps of filtering the liquid wastes, electrolytically treating the filtered liquid, evaporating the wastes to create steam and vapors, oxidizing the steam and vapors by photolysis and photolytic catalyzed ozone, and condensing the vapors and passing them through a column of activated carbon. The carbon is regenerated by oxidizing the carbon sites with ozone.Type: GrantFiled: November 28, 1986Date of Patent: April 5, 1988Assignee: Environmental Tech America, Inc.Inventor: Mark F. Wemhoff
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Patent number: 4724079Abstract: A method for purifying source water to obtain sterile, low-sodium water is described. The improved method employs ion-exchange, adsorption, filtration by particulate size, ultrafiltration, and reverse osmosis in combination with a closed holding system requiring only 2-3 ppm chlorine for sterilization. A method for storing treated water sterilized with chlorine, keeping the chlorine uniformly distributed during storage, and for removing the chlorine just prior to using the water while maintaining sterility of the water is also disclosed. An additional aspect of the invention is novel sterile filtration means, disclosed for removing chlorine from treated water, comprising a receptacle for activated carbon particles, having a water inlet and a water outlet, yet which is sealed from contamination from airborne microbes, and an effective number of carbon particles. The novel filtration means is wholly autoclavable.Type: GrantFiled: January 11, 1985Date of Patent: February 9, 1988Assignee: Gloria Stephan SaleInventors: Gloria S. Sale, Harry J. Darr, William L. Hoover
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Patent number: 4707347Abstract: A process is disclosed for the production of potassium sulfate from potassium chloride by means of a sulfate-laden anion exchanger, according to which as reaction solution, the exchanger is intensively contacted with a saturated potassium chloride solution, after saturation with potassium sulfate, and thereupon again separated, whereupon from this solution the crystals formed therein are separated, while the depleted anion exchanger is regenerated by intensive contact with a magnesium sulfate solution.Type: GrantFiled: April 17, 1986Date of Patent: November 17, 1987Assignee: Kali und SalzInventors: Sandor Vajna, Gerd Peuschel
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Patent number: 4684471Abstract: A process for water purification, intended for the purification of impure water to drinking water condition, composed of mixing 20-50 mg/l of a coagulant and 2-5 mg/l of an activated charcoal with a quantity of impure water, passing the water through a filter medium composed of thoroughly cleaned plastic fibers of polyacrylonitrile having a fineness of 4.5-9.0 deniers and a staple fiber length of 100-150 mm and a porosity of 78-85%, and treating the filtrate with active chlorine in an amount sufficient to render the filtrate potable and filtering apparatus to carry out the process.Type: GrantFiled: January 17, 1986Date of Patent: August 4, 1987Inventor: Vladimir Manojlovic
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Patent number: 4683065Abstract: A method and apparatus for reducing chemical oxygen demand levels in water which includes the steps of:(a) mixing the water to be treated with at least one oxygen source;(b) contacting the water with a first, activated alumina catalyst;(c) contacting the water with a catalyst selected from the group consisting of Group VIIIB metals, Group IB metals or mixtures thereof;(d) reacting chemical contaminants in the water with the oxygen source; and finally(e) contacting the water with an adsorptive material such as activated carbon.The present invention also includes a method and apparatus for regenerating the catalyst in situ by contacting the catalyst with alkaline and acidic aqueous inorganic regeneration solutions.Type: GrantFiled: June 18, 1985Date of Patent: July 28, 1987Inventor: Morris Sheikh
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Patent number: 4676909Abstract: Noble metals are recovered from their cyanide complexes in aqueous solution by reaction with red phosphorus. To this end, red phosphorus is used in quantities of 1 to 5 weight %, based on the aqueous solution of the noble metal cyanide complex, in combination with an additional strong oxidizing agent.Type: GrantFiled: October 21, 1985Date of Patent: June 30, 1987Assignee: Hoechst AktiengesellschaftInventors: Hannsjorg Ulrich, Peter Prestin
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Patent number: 4655930Abstract: The removal of elemental oxygen with the aid of a reducing agent from a liquid coolant which circulates in one or more circulations and from which salts are to be removed simultaneously in an ion exchanger mixed-bed filter (5) can be effected without substantial additional expense in terms of apparatus by at least partially loading the anion or cation exchanger resin present in the mixed bed filter (5) with the said reducing agent. The reducing agent is added via a metering means (6) upstream of the mixed-bed filter (5) in the secondary circulation (2).Type: GrantFiled: January 29, 1986Date of Patent: April 7, 1987Assignee: BBC Brown, Boveri & Company, LimitedInventors: Albert Kuhn, Reinhard Muller
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Patent number: 4643831Abstract: A system for water treatment includes the steps of superchlorinating the water to a level sufficient to destroy bacterial content in the water very rapidly, passing the water through a sand filter in which the medium includes beads of magnesium hydroxide and subjecting different portions of the filtered water to differing degrees of filtration by an activated charcoal filter, whereby to remove a sufficient proportion of the chlorine added to the water to reduce the residual chlorine to a level sufficient to maintain the water sterile without substantially influencing the taste of the water. Preferably, the sand and charcoal filters are disposed horizontally, and the depths of the filter beds are graded horizontally to provide the differing degrees of filtration to the water.Type: GrantFiled: December 23, 1985Date of Patent: February 17, 1987Assignee: EWS Water Treatment Inc.Inventor: Brian Fletcher
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Patent number: 4629571Abstract: A layer of precoat filter aid material including powdered activated carbon removes oxygen and impurities from a liquid having hydrazine added thereto. Oxygen concentrations may be reduced to parts per billion concentrations. Suspended solids can be removed by the precoat layer, and if the precoat layer includes an active particulate material, either as a component of the precoat layer or as an underlayer, the concentration of impurities and dissolved solids in the liquid can also be reduced.Type: GrantFiled: September 11, 1985Date of Patent: December 16, 1986Assignee: The Graver CompanyInventors: Eli Salem, Robert Kunin
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Patent number: 4627920Abstract: The process consists firstly in adding, to the solution, an excess of a polyelectrolyte capable of forming an ionic association with the dissolved substance which it is desired to retain, and then in bringing the solution thus obtained into contact with a material possessing ionic groups which retain the polyelectrolyte by virtue of its ionic groups not associated with the said substance. The solution and the material can be brought into contact either by filtration or by tangential bathing. The polyelectrolyte can be retained either by ion exchange or by a charge repulsion effect.The material is advantageously a fibrous material of which the ionic groups are obtained by grafting.Type: GrantFiled: July 17, 1984Date of Patent: December 9, 1986Assignee: Institut Textile de FranceInventors: Roger Chatelin, Jean-Francois Combes, Daniel Wattiez
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Patent number: 4627921Abstract: The total organic carbon and oxygen in water may be reduced by adjusting the pH of the water to within the range of from about 4 to about 6.9 and then adding an excess of a reducing agent over the amount necessary to react with all of the organic carbon and oxygen present in the water. Preferably the water containing the reducing agent is passed over an adsorbent, absorbent activated carbon bed within a treatment unit the interior of which is anaerobic.Type: GrantFiled: April 29, 1985Date of Patent: December 9, 1986Assignee: L A Water Treatment CorporationInventors: Peter S. Meyers, Gerald Alexander
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Patent number: 4564454Abstract: A self-contained sewage waste disposal system is provided including a housing structure and a toilet bowl adapted to receive human waste and fluid for diluting the waste, transporting the waste and rinsing the bowl is provided in the housing structure. A removable filter cassette is placed in the housing structure in communication with the toilet bowl. The bowl is adapted to be flushed to dump the contents into the filter cassette and to be subsequently refilled. The coarse and fine particles of solid waste material are separated from the fluid received from the bowl by filter material in the cassette. The solid material is stored in the cassette in a compact manner for subsequent disposal upon removal of the cassette from the housing.Type: GrantFiled: April 21, 1983Date of Patent: January 14, 1986Assignee: American Standard Inc.Inventors: Clifton F. Briner, William R. Bocchini, Brian Wilcockson
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Patent number: 4556492Abstract: A deoxygenation process includes the steps of adding hydrazine to a liquid containing dissolved oxygen, passing the liquid through a bed of activated carbon to catalyze a reaction between the dissolved oxygen and hydrazine whereby carbon contaminants are added to the liquid, and removing the contaminants. In another embodiment, unreacted hydrazine that remains in the liquid following the catalysis is removed by passing the liquid through an ion exchange resin. In still another embodiment, an activated carbon-catalyzed deoxygenation process employing hydrazine is practiced on a mobile platform and the process further includes the steps of transporting the apparatus to a regenerating station for regeneration. The invention also includes apparatus for carrying out the process.Type: GrantFiled: December 16, 1983Date of Patent: December 3, 1985Assignee: Ecolochem, Inc.Inventors: Richard C. Dickerson, William S. Miller
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Patent number: 4548716Abstract: A method of producing ultrapore, pyrogen-free water comprising providing a source of water, filtering the water to remove suspended solids and organics, deionizing the water to remove dissolved solids, and introducing substantially pure ozone into the deionized water at a concentration of at least two milligrams of ozone per liter of deionized water to thereby produce ultrapure, pyrogen-free water.Type: GrantFiled: July 25, 1984Date of Patent: October 22, 1985Inventor: Lucas Boeve
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Patent number: 4532045Abstract: A heat exchange system and process for reducing bleed-off are disclosed employing a weak acid cation exchange resin for treating the aqueous liquid coolant. In one such system and process, the aqueous coolant is treated with a weak acid ion exchange resin to remove alkaline salts therefrom without removing salts of strong acids; suspended solids are removed from the circulating aqueous coolant; and an effective amount of additive selected from the group consisting of scale inhibitors, corrosion inhibitors, microbiocides, and mixtures thereof is introduced into the circulating aqueous coolant so that bleed-off from said system is substantially reduced.Type: GrantFiled: July 7, 1982Date of Patent: July 30, 1985Assignee: Waterscience, Inc.Inventor: Robert J. Littmann
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Patent number: 4517096Abstract: A novel method is disclosed which enables gallium and/or indium to be selectively separated and concentrated from a solution containing them in very low concentrations together with many other metal ions in rather high concentrations. The solution is passed through a bed of a chelating ion exchange resin having an amino carboxylic acid group either immediately or after the pH adjustment. Gallium and/or indium adsorbed on the chelate resin is desorbed by eluting with a mineral acid. The eluate, after the pH adjustment, is passed through another bed of a chelating ion exchange resin having an amino carboxylic acid group, and the resin is treated with a mineral acid to elute the metal ions adsorbed on the resin to thereby recover gallium and/or indium in the form of a concentrated solution.Type: GrantFiled: April 4, 1984Date of Patent: May 14, 1985Assignees: Dowa Mining Co., Ltd., Unitika, Ltd.Inventors: Kunio Sekine, Hitoshi Masuda, Kodo Ishibashi, Masahide Hirai, Shozo Tomoshige, Kozo Kondo
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Patent number: 4514504Abstract: A quantitative method useful for field monitoring low concentrations of water soluble, polyacrylic acids in aqueous systems containing polyacrylic acids and other soluble ionic materials, such as ionic salts and phosphonates, is provided. The method involves adjusting the pH of the aqueous system to suppress the ionization of the polyacrylic acids followed by selective adsorption and concentration of the polyacrylic acids on a suitable adsorbent. Concentrated polyacrylic acids are then desorbed from the adsorbent and the concentration of the polyacrylic acids in the aqueous system is determined by conventional techniques.Type: GrantFiled: July 22, 1983Date of Patent: April 30, 1985Assignee: Rohm and Haas CompanyInventor: Alan M. Rothman
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Patent number: 4505823Abstract: Filter element package, method for preparing and method of using the same for treating contaminated aqueous solutions, in which the filter element is in the form of a mat consisting essentially of a wet laid, porous, non-woven matrix having randomly arranged, irregularly intersecting and overlapping cellulose fibers intermixed with polymer micro-bits. The filter mat, either alone or confronted with a supporting sheet of material, is provided in a predetermined geometrical shape and folded along perpendicular lines to form a four-layered filter element which can be displaced into a cone-shaped structure for filtering contaminated aqueous solutions. A resealable envelope is provided for enclosing the filter element and may include therein a bracing member to provide lateral support for the filter element during filtering and/or a collapsible receptacle for containing a predetermined quantity of the solution to be treated along with a packet of disinfectant for disinfecting the same.Type: GrantFiled: May 16, 1983Date of Patent: March 19, 1985Inventor: Max Klein
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Patent number: 4486390Abstract: A process is described for the recovery of uranium from ore wherein the ore is leached, the resulting leachate is passed over an anion exchange resin, and the resin is then eluted with an elution solution containing an anion capable of replacing the uranyl anion captured on the resin, followed by treatment with a sulfite-containing solution so that polythionates captured on the ion exchange resin are reacted to form essentially thiosulfate and trithionate. Preferably, the sulfite solution also contains other anions.Type: GrantFiled: June 4, 1981Date of Patent: December 4, 1984Assignee: Mobil Oil CorporationInventor: Hans-Peter C. Schmiedel
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Patent number: 4472281Abstract: A method of removing contaminating impurities, particularly haloamines, from leisure pool water is disclosed and an apparatus therefor. Pool water containing haloamine contaminants is passed into an active carbon bed of high surface area that has been treated with a reagent, for example hypohalous acid, that will convert a portion of it into a surface oxide so that the carbon either reacts with or catalyses the breakdown of the haloamines. The hypohalous acid is conveniently generated in the pool water prior to passage of it through the active carbon.Type: GrantFiled: March 9, 1983Date of Patent: September 18, 1984Inventor: John R. Kerridge
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Patent number: 4430228Abstract: A process is provided for removing impurities such as iron compounds from water, which comprises the steps of:(1) colloidalizing the iron compounds in water under conditions of high shear and decompression/compression to finely divide existing insoluble iron hydrates, and by dissolution in the water of air in sufficient amount to oxidize and form colloidally dispersed iron hydrates from the dissolved iron present, thereby providing substantially all of the iron in the form of micelles having a surface charge;(2) maintaining the water under a pressure within the range from about 10 to 500 psig;(3) then passing the water under a pressure within said range through a mass of particulate material having a surface charge capable of attracting, removing, and collecting the dispersed iron hydrates; and(4) recovering water containing less iron than the starting water, and preferably less than 0.3 PPM of iron.Type: GrantFiled: March 5, 1982Date of Patent: February 7, 1984Inventor: Laurene O. Paterson
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Patent number: 4411873Abstract: A process is described for minimizing accumulation of undesirable polythionates on an ion exchange resin used to recover uranium values from a leachate from an in situ mining operation by adding sulfite, either as a sulfite salt or as SO.sub.2, directly to the leachate or to the eluant.Type: GrantFiled: June 4, 1981Date of Patent: October 25, 1983Assignee: Mobil Oil CorporationInventor: Tsoung-Yuan Yan
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Patent number: 4396512Abstract: Improved bacteriostatic filter media mixture comprising specially treated, dried, silver-bearing, highly purified, inert material in particulate or fibrous form, such as cellulose fibers, mixed with specific proporations of powdered, activated carbon filter material. Bacterial growth in and on the filter media is inhibited by silver ions slowly eluted or dissolved from the segregated, silver-treated cellullose fibers uniformly interspersed among the carbon filter material. The treated cellulose in the mixed filter media is in an amount sufficient to provide overall filter bacteriostatic effect to passs EPA Office of Pesticides Regulations FR 41:152 for home water filtration use, and to have improved coliform bacteria suppression after stagnant periods. Adsorptive and precoatability properties of the carbon are not inhibited, and carbon densification, leading to fall-off, does not occur.Type: GrantFiled: September 15, 1980Date of Patent: August 2, 1983Assignee: Everpure, Inc.Inventors: William H. Beauman, P. Regunathan, Dennis I. Prepejchal
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Patent number: 4382862Abstract: In a cartridge for removal of impurities from water, an elongated tube is charged, between water-permeable barriers, with ion exchange resin of a type capable of removal of bacteria from water. Outside one such barrier, an inlet cap is charged with water-soluble bactericide in a shelf-stable, water-activatable form. Preferably, the bactericide is sodium salt of dichloroisocyanuric acid, in granular form.Type: GrantFiled: May 8, 1981Date of Patent: May 10, 1983Assignee: Illinois Water Treatment CompanyInventor: Terry R. Dillman