Abstract: A rotary counter-current solid/fluid contact apparatus is developed to enhance the efficiency of adsorption, ion exchange and regenerative heat exchange. The counter-current apparatus uses a rotor to direct fluids to multiple stationary columns. By the action of the rotor, counter-current flows of a fluid phase and a solid phase can be achieved for a combined adsorption and desorption cycle, or a combined heating and cooling cycle. The apparatus allows not only countercurrent solid-fluid flows based on columns in series, but also countercurrent solid-fluid flows in the length of each individual column. A method is also disclosed.

Abstract: A rotary counter-current solid/fluid contact apparatus is developed to enhance the efficiency of adsorption, ion exchange and regenerative heat exchange. The counter-current apparatus uses a rotor to direct fluids to multiple stationary columns. By the action of the rotor, counter-current flows of a fluid phase and a solid phase can be achieved for a combined adsorption and desorption cycle, or a combined heating and cooling cycle. The apparatus allows not only countercurrent solid-fluid flows based on columns in series, but also countercurrent solid-fluid flows in the length of each individual column. A method is also disclosed.

Abstract: A system and method that includes flowing brine containing a metal ion through a reactor that includes porous particles having metal ion imprinted polymer having selective binding sites. The system and method further include discharging the brine from the reactor, contacting the porous particles with water, and pressurizing the reactor with carbon dioxide. The carbon dioxide reacts with the adsorbed metal ions to form a metal carbonate solution, where the metal carbonate solution can then be continuously purified with ion exchange. The method can include recycling eluent from the ion exchange back into the system for re-use. The method further includes depressurizing the reactor to precipitate metal carbonate from the metal carbonate solution and discharging the metal carbonate solution from the reactor.

Abstract: A fluid purification device includes a screen plate, a first filtration layer, a second filtration layer, a third filtration layer, a main body, and a dispensing plate. The screen plate has a plurality of inflow holes for filtering particles in fluid passing therethrough. Around a periphery of the screen plate, several convex sections are arranged and spaced apart from one another. The main body is hollow and has an open top and an open bottom opposite to the open top. Around an inner wall of the open top, several concave sections are arranged and spaced apart from one another. The concave section is shaped in conformity with the convex section, so that the screen plate can be secured to the open top of the main body.

Abstract: A system and process for nitrate reduction from a water source. The process includes the steps of passing nitrate contaminated water through a strong acid cation exchange resin to reduce cations. The effluent is thereafter passed through a weak base anion exchange resin in order to reduce nitrate content. The strong acid cation exchange resin is regenerated, and the weak base anion exchange resin is also regenerated.

Abstract: Embodiments of the present invention provide systems and methods for purifying produced water, comprising a closed loop cation exchange unit, a closed loop anion exchange unit, and an intermediate degasifier.

Abstract: A method of removing chromium from water using a weak base anion exchange resin at a pH above about 5 includes the step of periodically reducing a flow of the water through the ion exchange resin for a rest period, such that a secondary mechanism of chromium removal predominates, wherein chromium ions are removed from the weak base anion exchange groups and precipitated inside the ion exchange resin. In an alternative embodiment, rather than resting, the ion exchange resin is periodically conditioned with an acid so as to enhance the secondary mechanism.

Abstract: A process according to various approaches includes flushing an intermediate transfer line at first flow rate during a first portion of the step-time interval. The process also includes flushing the intermediate transfer line at as second different flow rate during a second portion of the step-time interval so that a greater volume of fluid is flushed from the intermediate transfer line during one of the first portion and the second portion of the step-time interval than during the other of the first portion and the second portion of the step-time interval.

Abstract: The invention provides a process for separating a solution from magnetic resin portions, particles and/or fines by passing a solution containing the resin portions, particles and/or fines through a bed of particulate magnetic material.

Abstract: A process according to various approach includes flushing an intermediate transfer line between the first intermediate transfer line and the extract stream transfer line away from the adsorptive separation chamber to remove residual fluid from intermediate transfer line. The process may include directing the residual fluid flushed from the intermediate transfer line to a recycle stream to introduce the residual fluid into the adsorptive separation chamber.

Abstract: A process for separating a product from a multicomponent feedstream to an adsorption apparatus or system is described. The apparatus or system may comprise a moving-bed or a simulated moving-bed adsorption means. The product comprises at least one organic compound, such as an aryl compound with alkyl substitutes. In embodiments the conduits used to supply the feedstream to the apparatus or system are flushed with media of multiple grades. The improvement is a more efficient use of the desorbent. In embodiments the process achieves improvements in one or more of efficiency of adsorption separation, capacity of adsorption apparatus systems, and purity of product attainable by adsorption process.

Abstract: The present invention relates to a lithium recovery device comprising a separator reservoir and manganese oxide, a lithium recovery method using the same, and a lithium adsorption/desorption system. The separator reservoir includes a vacant space therein and an outer wall made of a polymer or a membrane of other useful materials. The manganese oxide is contained, as an adsorbent, in the vacant space inside the separator reservoir. The lithium adsorption/desorption system enables lithium recovery through adsorption and desorption of lithium dissolved in seawater using a lithium adsorbent prepared with the manganese oxide in one system, wherein the manganese oxide can be used as a lithium adsorbent with high lithium selectivity. The invention uses a separator reservoir including an outer wall made of a porous polymer or a membrane of other useful materials.

Abstract: Methods and apparatus for removing contaminants from liquid using a continuously circulating stream of purifying media are disclosed. In one embodiment the method includes mixing a regenerated purifying media with a contaminated liquid containing diverse contaminants; co-currently transporting the purifying media and the contaminated liquid in a mixed state; removing, using the purifying media, while co-currently transporting the purifying media and the contaminated liquid, contaminants from the contaminated liquid so as to produce a mixture of a decontaminated liquid and a contaminated purifying media; and separating contaminated purifying media from the decontaminated liquid. In addition, the contaminated purifying media is contacted in counter current fashion with a regenerant solution so as to produce a regenerated purifying media and the regenerated purifying media is returned to the mixing step, whereby the continuously circulating purifying media selectively removes contaminants from the liquid.

Abstract: A novel apparatus for an ion exchange system is provided. The apparatus comprises a first column for housing a first fluidized bed through which particles are flowed countercurrently to an ion-containing fluid to yield ion-loaded particles, a second column through which the ion-loaded particles are flowed countercurrently to an eluent fluid to yield regenerated particles, and a transport section which transfers the regenerated particles for re-introduction into the first column to repeat the ion exchange cycle in a continuous manner. A continuous method of ion exchange is also provided.

Abstract: The invention provides a system and process for separating residual magnetic resin from a liquid stream by passing the stream through or over permanent magnets located within the stream wherein the process also includes a means for releasing any resin retained by the permanent magnets and capturing the released resin.

Abstract: Embodiments of the invention provide a twin tank water treatment system and method. The water treatment system includes first tank with a first set of sensors and a first resin bed, a second tank with a second set of sensors and a second resin bed, and a valve assembly with a flow meter and a controller in communication with the first set of sensors, the second set of sensors, and the flow meter. The method includes determining when the resin beds are exhausted based on input from the flow meter, the sensors, and a water hardness setting.

Abstract: An apparatus and method for regenerating spent ion exchange resin is described. In one method, a fresh regenerant solution comprising sodium ions and chloride ions is prepared, and passed across spent cation exchange resin to regenerate the spent resin. To recover the spent regenerant solution, a regenerant treatment composition is added to the spent solution to form precipitate flocs, which are then separated out of the regenerant solution. The concentration of at least one of the sodium or chloride ions in the regenerant solution can also be adjusted to form fresh regenerant solution which can be reused.

Abstract: A ballasted sequencing batch reactor system for treating wastewater including one or more sequencing batch reactors. A weighting agent impregnation subsystem is configured to mix biological flocs and weighting agent to form weighted biological flocs. A weighting agent recovery subsystem is configured to recover weighting agent from the weighted biological flocs and reintroduce the recovered weighting agent to the weighting agent impregnation subsystem.

Abstract: Methods and systems for employing softened acidified water sources from an acid regenerated ion exchange resins are disclosed. Various methods of dispensing and/or using the softened acidic water generated by an acid regenerate-able ion exchange resin are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, including water conditioning agents, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

Abstract: Methods and systems for acid regeneration of ion exchange resins are disclosed. Acid resins designed for use in a variety of cleaning application using a water source use a treated, softened, acidic water source according to the invention. Various methods of using the softened acidic water generated by acid regenerate-able ion exchange resins are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

Abstract: An apparatus and method permit continuous separation of an adsorbate from a processing material containing solid particles, sticky substances and water-soluble proteins, alone or in combination, without pretreatment. The processing is carried out while a loop adsorbent is circulated. An adsorbate is adsorbed, not by supply of the processing solution through the adsorbent, but by contact thereof with the adsorbent. In addition, the adsorbent after desorption of the adsorbate is cleaned. As a result, the apparatus and the method achieve continuous processing and separation of the adsorbate even from a processing material containing solid particles, sticky substances and water-soluble proteins alone or in combination without pretreatment.

Abstract: The present disclosure provides a method for adsorption/desorption of lithium ions from brine, which employs a counter current decantation process in adsorption/desorption of lithium ions, thereby achieving an adsorption rate of 65±5% and a desorption rate of 95±3%. The method includes supplying brine into one of a plurality of adsorption reactors, adsorbing lithium ions to an adsorbent by supplying the adsorbent to the adsorption reactor to which the brine is supplied and forcing the brine and the adsorbent to sequentially flow backwards inside the respective adsorption reactors, and desorbing the lithium ions from the brine by forcing the adsorbent to which the lithium ions are adsorbed to sequentially flow backwards inside a plurality of desorption reactors. Here, the brine and the adsorbent are stirred by a stirrer to maintain the adsorbent in an intermediate state instead of settling or floating inside the respective adsorption reactors.

Abstract: The present disclosure is directed towards systems and methods for the treatment of wastewater. A system in accordance with one particular embodiment may include a vacuum filter band system configured to receive a saturated ion exchange resin tank and to apply a water rinse to the resin to generate a resin slurry. The vacuum filter band system may further include a vacuum filter band configured to receive the resin slurry. The vacuum filter band system may also be configured to generate a mixed metal solution. The system may further include a metal specific purification system including a plurality of purification units configured to receive a continuous flow of the mixed metal solution, each of the purification units configured to target a particular metal from the mixed metal solution. Numerous other embodiments are also within the scope of the present disclosure.

Abstract: A regeneration circuit for the in situ regeneration of an inline adsorbent filter, said filter being part of a normal circuit that is configured to remove one or more contaminant from a fluid circulated through a machine; the regeneration circuit includes a regeneration unit configured to remove one or more contaminant from a contaminated fluid creating a regenerated fluid, such that in operation the regenerated fluid is pumped from the regeneration unit and through the filter extracting the or each contaminant from the filter creating the contaminated fluid, this contaminated fluid then returns to the regeneration unit for contaminant removal, the pressure and flow rate of the regenerated fluid through the filter are maintained at a level that ensures minimal damage to the filter; said machine is isolated from the inline filter during regeneration.

Abstract: The present invention provides a method and a device for dewatering a hydraulic fluid of a hydraulic system, in particular in the aerospace sector, comprising a container which has a sorbent, a feed which supplies the hydraulic fluid from the hydraulic system to the container for the hydraulic fluid to be passed through the sorbent such that it can be dewatered in a dewatering mode of the device, and a return which returns the dewatered hydraulic fluid from the container to the hydraulic system in the dewatering mode of the device. The hydraulic fluid can be dewatered continuously and very efficiently by the method and the device according to the invention.

Abstract: The present invention is a method for treating contaminated water streams resulting from the production of coal-bed-methane. The method of treating contaminated water streams typically includes the steps of: providing a reaction vessel that contains a bed of weak acid cation ion exchange resin beads; introducing the contaminated water stream to the reaction vessel; allowing for the exchange of hydrogen ions for sodium ions; removing the ion exchanged treated water from the reaction vessel; stopping the stream of contaminated water; and regenerating the weak cation exchange resin.

Abstract: A liquid filtering apparatus is placed in a vessel having a bed of filtration material, the bed comprising at least two different sizes of filter media wherein the filtration material is stratified using upper and lower spaced apart inverted cones so that the unfiltered liquid first contacts coarse grained filtration material and then finer grained filtration material. The apparatus includes an intake for introducing unfiltered liquid that includes a washbox, an airlifting tube extending from the washbox and including an intake end and means for introducing a primary gas to the airlifting tube, the airlifting tube passing through a central pipe, which extends from just below the washbox to a position just above the intake end. The apparatus is devoid of screen cartridges. Methods of filtering and cleaning the filtration material are also disclosed.

Abstract: A unit for pretreating water by heat and/or ion treatment. It provides a pretreatment unit including a direct contact heat and/or ion exchanger having a continuous or dispersed phase that includes a fluorinated liquid that is not miscible with water with a density of more than 1.25.

Abstract: Exemplary systems and methods for treating contaminated water are described. In one instance a method supplies metal salt reagents to a moving media filter in the presence of contaminated water. The method also introduces a waste stream resulting from the moving media filter upstream of the moving media filter effective to lower an average contaminant concentration of effluent water from the moving media filter.

Abstract: A liquid filtering apparatus is placed in a vessel having a bed of filtration material, the bed comprising at least two different sizes of filter media wherein the filtration material is stratified using upper and lower spaced apart inverted cones so that the unfiltered liquid first contacts coarse grained filtration material and then finer grained filtration material. The apparatus includes an intake for introducing unfiltered liquid that includes a washbox, an airlifting tube extending from the washbox and including an intake end and means for introducing a primary gas to the airlifting tube, the airlifting tube passing through a central pipe, which extends from just below the washbox to a position just above the intake end. The apparatus is devoid of screen cartridges. Methods of filtering and cleaning the filtration material are also disclosed.

Abstract: A treatment method of organic compounds included in waste water, comprising the steps of: supplying waste water to an adsorber 2 filled with an adsorbent 3 therein for adsorbing the organic compounds in the waste water by the adsorbent 3 in the adsorber 2, supplying a current between an anode 9 and a cathode 8 in water including an electrolyte in an electrolyzer 6 for electrolyzing the water including an electrolyte, and supplying an electrolyte resulting from electrolysis in the electrolyzer 6 to the adsorbent 3 in the adsorber 2 for contacting the electrolyte with the adsorbent 3, so that the organic compounds adsorbed by the adsorbent 3 are desorbed or decomposed.

Abstract: Filtration systems containing a filtration medium and methods related thereto are described herein. The filtration system includes a plurality of fibers of spoolable length, where the fibers are a carbon nanotube-infused fiber material. The filtration systems can be operated with reel-to-reel processing or in a continuous manner in order to sorb hydrophobic materials from a liquid medium. The filtration systems also include various means to remove the hydrophobic materials from the filtration medium, including press rollers and chemical extraction baths. Illustrative liquid media that can be treated with the filtration systems include, for example, hydrophobic materials admixed in an aqueous phase, bilayers (e.g., oil-water bilayers), oil in a subterranean formation, water sources containing trace organic pollutants or trace organic compounds, and fermentation broths.

Abstract: Methods and apparatus for removing contaminants from liquid using a continuously circulating stream of purifying media are disclosed. In one embodiment the method includes mixing a regenerated purifying media with a contaminated liquid containing diverse contaminants; co-currently transporting the purifying media and the contaminated liquid in a mixed state; removing, using the purifying media, while co-currently transporting the purifying media and the contaminated liquid, contaminants from the contaminated liquid so as to produce a mixture of a decontaminated liquid and a contaminated purifying media; and separating contaminated purifying media from the decontaminated liquid. In addition, the contaminated purifying media is contacted in counter current fashion with a regenerant solution so as to produce a regenerated purifying media and the regenerated purifying media is returned to the mixing step, whereby the continuously circulating purifying media selectively removes contaminants from the liquid.

Abstract: Systems, apparatus and methods for treating a contaminated fluid stream are provided. The systems may include a treatment column fluidly interconnected to a regeneration column, the regeneration column being adapted to continuously receive solid spent media from the treatment column to continuously regenerate such solid spent media.

Abstract: In a method and apparatus for operating and regenerating ion exchange material a wash fluid or elution solution for rinsing the ion exchange material (1) is prepared, there is collected as a by-product of said preparation a first waste stream including cationic species to be eliminated, the ion exchange material (1) is subjected to a wash step in which there is eluted from the ion exchange material by the wash fluid or solution an anionic species to be eliminated and a second waste stream including the anionic species to be eliminated is obtained, the first waste stream (12) and the second waste stream (14) are combined to form a precipitate SW comprising a reaction product of said cationic species and said anionic species, and the precipitate is removed. The method provides an efficient means of eliminating undesired species from a circuit containing an ion exchange material to be regenerated.

Abstract: In one embodiment, a reactive filtration method includes continuously regenerating a reactive filter media while simultaneously filtering contaminants from fluid flowing through the filter media. In one embodiment, regenerating the reactive filter media comprises mixing metal granules with the filter media and agitating the mixture. In another embodiment, regenerating the reactive filter media comprises introducing a metal in the fluid flowing through the filter media and agitating the filter media. In one embodiment, a method for removing phosphorus, arsenic or a heavy metal from water includes introducing a metal salt reagent into the water at a molar ratio of 5:1 to 200:1 to the phosphorous or the arsenic in the water and passing the water through a bed of moving sand.

Abstract: It is intended to provide to provide an apparatus for separating an adsorbate, that permits continuous separation of the adsorbate from a processing material containing solid particles, sticky substances and water-soluble proteins alone or in combination without pretreatment, and a method of continuously separating the adsorbate. In the present invention, the processing is carried out, while a loop adsorbent is circulated. Specifically, an adsorbate is adsorbed, not by supply of the processing solution through the adsorbent, but by contact thereof with the adsorbent. In addition, the adsorbent after desorption of the adsorbate is cleaned. As a result, provided are an apparatus for separating an adsorbate, that permits continuous processing and separation of the adsorbate even from a processing material containing solid particles, sticky substances and water-soluble proteins alone or in combination without pretreatment and a method of continuously separating the adsorbate.

Abstract: Apparatus for treating liquid by contact with a particulate adsorbent material comprises a regeneration chamber (10) within a reservoir (2) for liquid to be treated. Adsorbent material is recycled along a path including passage through the regeneration chamber (10) and in a body of liquid in the reservoir to contact and treat the liquid. The adsorbent material is capable of regeneration, and the regeneration chamber (10) is defined between two electrodes (36, 38), which can be coupled to a source of electrical power. The treatment process can be continuous with liquid flowing through the reservoir while the adsorbent material is recycled and regenerated. Alternatively, individual quantities of liquid may be treated on a batch basis. A plurality of regeneration chambers may be arranged within a common reservoir, such as in a bank of chambers aligned along an axis thereof.

Abstract: The present invention provides a water softening device for application in a household appliance comprising a flow-through capacitor for the production of wash amplified water (WAW) from tap water, having less than 5° FH, being suitable for use in said appliance when the device is in operation; the configuration of the device is such that the capacitor can be regenerated, whereby no added substances are used. Said washing machine being suitable for use with low environmental impact detergent products.

Abstract: A method for fluid treatment that provides alternative regeneration cycles within the same fluid treatment device. A second alternative regeneration cycle is available within the same device, which has independent cycles or processes from the first regeneration cycle. The first and second regeneration cycles can be programmed at the same time and be programmed to alternatively run based upon the number of individual cycles run, the time the cycles have run, the amount of fluid that has passed through the device, or the concentration of brine and/or chlorine in the fluid within the device.

Abstract: A method of treating water to remove fluoride ions from the water, thereby to reduce the dissolved fluoride content of the water, is provided. The method includes, in a contacting step, contacting water containing dissolved fluoride ions with alumina, to cause the fluoride ions to react with and become bound to the alumina. In a regenerating step, the alumina, when spent, is regenerated to drive off fluoride ions bound thereto. The regenerated alumina is recycled to the contacting step where it is used to remove further fluoride ions from the water. The fluoride ions driven off the alumina in the regenerating step are passed on to downstream processing thereof.

Abstract: Systems, apparatus and methods for treating a contaminated fluid stream are provided. The systems may include a treatment column fluidly interconnected to a regeneration column, the regeneration column being adapted to continuously receive solid spent media from the treatment column to continuously regenerate such solid spent media.

Abstract: In one embodiment, a reactive filtration method includes continuously regenerating a reactive filter media while simultaneously filtering contaminants from fluid flowing through the filter media. In one embodiment, regenerating the reactive filter media comprises mixing metal granules with the filter media and agitating the mixture. In another embodiment, regenerating the reactive filter media comprises introducing a metal in the fluid flowing through the filter media and agitating the filter media. In one embodiment, a method for removing phosphorus, arsenic or a heavy metal from water includes introducing a metal salt reagent into the water at a molar ratio of 5:1 to 200:1 to the phosphorous or the arsenic in the water and passing the water through a bed of moving sand.

Abstract: A process and apparatus for continuously removing ions from solution in proportion to their prevalence in solution using an ion exchange media. The process comprises: (a) mixing fresh or regenerated ion exchange media and a feed solution containing diverse ions; (b) reacting the resulting slurry to produce a product slurry comprised of loaded ion exchange media and stripped product solution; (c) separating the loaded ion exchange media from the product slurry; (d) regenerating the loaded ion exchange media by counter current contact with a regenerant; and (e) conducting the process steps continuously and concurrently, whereby a continuous circuit is produced for dosing, loading, separating, and regenerating the ion exchange media, and whereby more concentrated ions are preferentially depleted in the product solution. An apparatus particularly adapted to practice the process and to treat sodic water is also provided.

Abstract: A process for continuous countercurrent ion exchange comprises piping a contaminated feed stream into a closed loop ion exchange contactor. The contactor is an ion exchange bed that has three or more reaction segments. The segments are comprised of at least an adsorption segment for treating the contaminated feed stream, a regeneration segment for stripping the contaminant ions from the resin bed, and a pulse segment for advancing the resin bed. Simultaneously, the feed stream is moved through the contactor in the same direction as the regeneration stream. Measuring the quality of this treated feed stream after it exits the contactor monitors the treatment capacity of the resin bed. In response to this quality measurement, the regenerated resin bed is advanced in the pulse segment of the contactor. The spent brine is recycled back to the contactor until the final effluent brine is highly concentrated. After the resin stops advancing, the feed stream and regeneration stream resume flow.

Abstract: This invention relates to a bioprocess engineering solution for a product removal process for use in a biofermentation. The invention discloses a process for withdrawing an aliquot of broth from a biofermentation vessel during at least a portion of the biofermentation, removing biocatalyst and water, chromatographically separating biofermentation products from the withdrawn broth using water as an eluent, and returning the remaining components of the broth back to the biofermentation vessel. Process chromatography permits highly selective separation of the target molecule, preventing feedback inhibition of the biofermentation.

Abstract: A process for preparing an ion-exchangeable media within a moving-bed or simulated moving-bed device, which can create a true or simulated media flow, comprising the steps of packing the bed with ion-exchangeable media and passing a solution, containing a mixture of ionic species, through the media, wherein the solution is passed partly or completely counter-current to the media flow direction such that the ionic species are loaded to a desired level upon equilibration.

Abstract: An apparatus is presented for separating chemicals using adsorption separation methods. The apparatus uses a plurality of adsorption units holding adsorbent, where the adsorption units positioned in a cylindrical spool, are serially connected and the spool is rotated to shift the relative position of the feeds and drawoffs to the apparatus.

Abstract: An ion exchange process for removing arsenic from drinking water is disclosed which uses a mixed ion regenerant and generates minimal levels of waste.

Abstract: In one embodiment, a reactive filtration method includes continuously regenerating a reactive filter media while simultaneously filtering contaminants from fluid flowing through the filter media. In one embodiment, regenerating the reactive filter media comprises mixing metal granules with the filter media and agitating the mixture. In another embodiment, regenerating the reactive filter media comprises introducing a metal in the fluid flowing through the filter media and agitating the filter media. In one embodiment, a method for removing phosphorus, arsenic or a heavy metal from water includes introducing a metal salt reagent into the water at a molar ratio of 5:1 to 200:1 to the phosphorous or the arsenic in the water and passing the water through a bed of moving sand.