Anions Patents (Class 210/683)
  • Patent number: 11747727
    Abstract: An object of the present invention is to provide a chemical liquid which makes it possible to form a thinner resist film having a uniform thickness on a substrate by using a small amount of resist composition and demonstrates excellent defect inhibition performance. Another object of the present invention is to provide a pattern forming method. A chemical liquid of the present invention contains a mixture of two or more kinds of organic solvents and an impurity metal containing one kind of element selected from the group consisting of Fe, Cr, Ni, and Pb, in which a vapor pressure of the mixture is 50 to 1,420 Pa at 25° C., in a case where the chemical liquid contains one kind of the impurity metal, a content of the impurity metal in the chemical liquid is 0.001 to 100 mass ppt, and in a case where the chemical liquid contains two or more kinds of the impurity metals, a content of each of the impurity metals in the chemical liquid is 0.001 to 100 mass ppt.
    Type: Grant
    Filed: April 22, 2019
    Date of Patent: September 5, 2023
    Assignee: FUJIFILM Corporation
    Inventors: Tetsuya Kamimura, Satomi Takahashi
  • Patent number: 11731108
    Abstract: The subject invention pertains to proteins are purified by a mixed-mode chromatography system formed by attaching a ligand with cation exchange and hydrophobic 1,3-dioxoisoindolin-2-yl group functionalities to a large-pore support matrix, the only linkage between the ligand and the support matrix being a chain having a backbone of one, two, three, four, or five atoms between the hydrophobic group and the support matrix.
    Type: Grant
    Filed: March 17, 2022
    Date of Patent: August 22, 2023
    Assignee: BIO-RAD LABORATORIES, INC.
    Inventors: Christopher Belisle, Jiali Liao, Edwin Lozano
  • Patent number: 11583830
    Abstract: A process for recovery of lithium ions from a lithium-bearing brine includes contacting the lithium-bearing brine with a lithium ion sieve (where that LIS includes an oxide of titanium or niobium) in a first stirred reactor to form a lithium ion complex with the lithium ion sieve, and decomplexing the lithium ion from the lithium ion sieve in a second stirred reactor to form the lithium ion sieve and an acidic lithium salt eluate.
    Type: Grant
    Filed: June 8, 2020
    Date of Patent: February 21, 2023
    Assignee: STANDARD LITHIUM LTD.
    Inventor: Craig Johnstone Brown
  • Patent number: 11577963
    Abstract: Provided is a method of preparing a sparsely pillared organic-inorganic hybrid compound. The method of preparing an organic-inorganic hybrid compound includes: preparing a compound having a gibbsite structure by a method other than a hydrothermal synthesis method, using a trivalent metal cation source, an alkali imparting agent, and a first solvent (S10); and preparing an organic-inorganic hybrid compound by a method other than a hydrothermal synthesis method, using the compound of the gibbsite structure, a divalent metal cation source, dicarboxylic acid, and a second solvent (S20).
    Type: Grant
    Filed: June 25, 2020
    Date of Patent: February 14, 2023
    Assignee: Innonep Inc.
    Inventors: Jisoon Ihm, Seok Hwan Park
  • Patent number: 11572292
    Abstract: Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H2O2 and .OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe3+ and 5 to 15% wt. Cu2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H2O2 to .OH to enhance the degradation.
    Type: Grant
    Filed: March 12, 2020
    Date of Patent: February 7, 2023
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Chanbasha Basheer, Hakimu Nsubuga
  • Patent number: 11505659
    Abstract: A method of producing treated ion exchange resin material includes exposing an enclosed vessel containing ion exchange resin and a pre-treatment solution to high energy radiation. The treated ion exchange resin material has reduced organic impurities or total organic carbon (TOC).
    Type: Grant
    Filed: December 2, 2020
    Date of Patent: November 22, 2022
    Assignee: Evoqua Water Technologies LLC
    Inventor: Marty Wilkes
  • Patent number: 11479488
    Abstract: A nano zero valent iron biological coupling device for organic wastewater includes a continuous flow stirred reactor, a flocculation sedimentation device and a membrane bioreactor arranged in series. A nano zero valent iron feeding device is arranged in the continuous flow stirred reactor, a flocculant and a coagulant aid are arranged in the flocculation sedimentation device, and a microbial reaction liquid is arranged in the membrane bioreactor. A nano iron biological coupling process includes: S1, placing the organic wastewater in the continuous flow stirred reactor, adding the nano zero valent iron, stirring and mixing; S2, placing the organic wastewater treated after S1 in the flocculation sedimentation device; S3, placing the organic wastewater treated after S2 in the membrane bioreactor and interacting with the microbial reaction liquid; S4, performing a membrane separation on the organic wastewater treated after S3 in the membrane bioreactor to obtain purified organic wastewater.
    Type: Grant
    Filed: September 25, 2020
    Date of Patent: October 25, 2022
    Assignee: TONGJI UNIVERSITY
    Inventors: Nuo Liu, Weixian Zhang, Airong Liu, Jing Liu
  • Patent number: 11420161
    Abstract: A system for removing undesirable compounds from contaminated air includes a biofilter having an alkaline material introduction system and a fuzzy-logic based controller. A contaminant, such as hydrogen sulfide, is removed from contaminated air by passing the contaminated air through the biofilter.
    Type: Grant
    Filed: May 29, 2020
    Date of Patent: August 23, 2022
    Assignee: Evoqua Water Technologies LLC
    Inventor: James Vaughan Harshman
  • Patent number: 11213812
    Abstract: Hybrid sorbent on the base of anion-exchange polymeric matrix with HFO for selective sorption of arsenic characterized in that, HFO exists in matrix as particles, which at most are amorphous ferrihydrite, fraction of which is not less than 80%, preferably more than 90% from total mass of HFO. The object of the invention and the technical result achieved with the use of the invention is to develop new hybrid sorbent with HFO with increased sorption kinetics of two arsenic forms As(III) and As(V) simultaneously.
    Type: Grant
    Filed: June 9, 2018
    Date of Patent: January 4, 2022
    Inventors: Evgeniya Sergeyevna Vasil'Yeva, Aleksandr Gennadievich Mitilineos, Yuriy Evgenievich Kazakevich, Iuliia Anatolievna Remizova
  • Patent number: 10934511
    Abstract: The embodiments disclose a method including bottling alcoholic beverages with selected ingredients including alcohol neutral spirits, alcohol and whisky, beer, wine, ingredients to add flavors and nutritional additive ingredients to benefit the health of an alcoholic beverage drinker, wherein a selection of alcohols includes vodka, tequila, gin, rum, brandy and other alcoholic spirits, wherein a selection of ingredients to add flavors includes flavorings including fruit flavorings, an artificial sweetener, and natural sweetener, wherein a selection of nutritional additive ingredients includes vitamins, minerals, fulvic acid, humic acid, ulmic acid and a purified and sanitized black water with humic acid and fulvic acid molecules in a mixed solution, and wherein bottling includes a bottling electronic monitoring, at least one control network, at least one bottling quality control process and a bottling labeling and packaging process and devices.
    Type: Grant
    Filed: April 7, 2019
    Date of Patent: March 2, 2021
    Inventors: Louise Wilkie, Jacqueline Wilkie
  • Patent number: 10882965
    Abstract: A method of producing treated ion exchange resin material includes exposing an enclosed vessel containing ion exchange resin and a pre-treatment solution to high energy radiation. The treated ion exchange resin material has reduced organic impurities or total organic carbon (TOC).
    Type: Grant
    Filed: September 14, 2016
    Date of Patent: January 5, 2021
    Assignee: Evoqua Water Technologies LLC
    Inventor: Marty Wilkes
  • Patent number: 10850995
    Abstract: Provided is a filtration aid used when filtering, for example, sludge generated in a purification treatment process for water such as industrial wastewater and including a pulverized product of Corchorus olitorius, wherein a median diameter of the pulverized product is 150 micrometers or greater.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: December 1, 2020
    Assignee: DEXERIALS CORPORATION
    Inventors: Masato Hasegawa, Ryu Shimada
  • Patent number: 10722864
    Abstract: A manganese dioxide nanowire @ multidimensional mesoporous metal-organic framework adsorbent and application method thereof for removing heavy metals from water. A multidimensional mesoporous metal-organic framework material is prepared from metal ions and organic ligands by means of a self-assembly reaction; a manganese dioxide nanowire is prepared from manganese salt and thiosulfate by means of reaction in a reaction kettle. The adsorbent possesses not only the characteristics of a multidimensional mesoporous metal-organic framework material, such as reticulated pore adaptation, a large specific surface area, and abundant reaction sites, but also the oxidative and catalytic properties of manganese dioxide nanowire.
    Type: Grant
    Filed: November 7, 2017
    Date of Patent: July 28, 2020
    Assignee: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences
    Inventors: Ruiping Liu, Meipeng Jian, Huan Wang, Bao Liu, Huijuan Liu, Jiuhui Qu
  • Patent number: 10517893
    Abstract: The present invention provides a pharmaceutical composition for treating a patient suffering from or predisposed to hyperphosphatemia, which contains Mg—Fe—Cl HCln. In one embodiment, the Mg—Fe—Cl HCln is shown in formula (I). The phosphorus uptaking capacity of the pharmaceutical composition is greater than 100 ppm/(g/L). The present invention further provides a method for treating a patient suffering from or predisposed to hyperphosphatemia by using said pharmaceutical composition. The present invention further provides a method of manufacturing the pharmaceutical composition.
    Type: Grant
    Filed: August 25, 2017
    Date of Patent: December 31, 2019
    Assignees: CHANGHUA CHRISTIAN MEDICAL FOUNDATION CHANGHUA CHRISTIAN HOSPITAL, National Chung Hsing University
    Inventors: Jun-Yen Uan, Hung-Ming Wu
  • Patent number: 10429311
    Abstract: Methods and systems for colorimetrically analyzing a liquid medium by analyzing chemical test strip images are provided. The liquid medium can be industrial water in an industrial water system. Image analyzing software carries out the analysis. The results of the analysis can be used to diagnosing a chemical treatment regimen of the industrial water system. A chemical test strip holder can be used to enhance reliability and repeatability of the imaging process and/or subsequent analysis.
    Type: Grant
    Filed: December 7, 2017
    Date of Patent: October 1, 2019
    Assignee: Ecolab USA Inc.
    Inventor: Robert S. Walicki
  • Patent number: 10421670
    Abstract: The embodiments disclose a device for sanitizing and purifying at least one purified potable water source supply and suspending humic acid and fulvic acid molecules in a mixed solution, at least one separate sanitary facilities to maintain sanitation of mixing and bottling processes of the mixed solution, at least one sanitizing device for preventing an opportunity for contamination to take place including bacterial and microbial growth throughout the mixing and bottling processes, at least one testing device for monitoring sanitized conditions of bottled beverage products in the mixing and bottling processes, and at least one mixing and bottling device for mixing and bottling of the mixed solution for creating black colored water beverages for human consumption.
    Type: Grant
    Filed: September 6, 2018
    Date of Patent: September 24, 2019
    Inventors: Louise Wilkie, Jacqueline Wilkie
  • Patent number: 10384167
    Abstract: The invention relates to repairing and/or modifying a surface of a membrane in osmotically driven membrane systems by the introduction of one or more substances to the membrane.
    Type: Grant
    Filed: February 10, 2016
    Date of Patent: August 20, 2019
    Assignee: OASYS WATER LLC
    Inventors: Zachary Helm, Homayoun Moaddel, John Charest, Peter F. Moran
  • Patent number: 10351930
    Abstract: The present invention according provides a method of recovering silver from silver containing halide solutions, comprising the steps of: (a) providing an ion exchange column comprising a weak anion exchange resin; (b) introducing the silver containing halide solution to the ion exchange column to absorb silver in the weak anion exchange resin; (c) washing the loaded ion exchange resin with a first washing solution to rinse off absorbed zinc and optionally at least part of copper; (d) washing the loaded ion exchange resin with a second washing solution to rinse off remaining copper; and (e) optionally washing the loaded ion exchange resin with a third washing solution to rinse off absorbed lead; and (f) eluting the loaded ion exchange resin with an eluent to remove silver from the resin and to obtain a silver containing solution.
    Type: Grant
    Filed: June 4, 2015
    Date of Patent: July 16, 2019
    Assignee: OUTOTEC (FINLAND) OY
    Inventors: Kari Valkama, Mika Haapalainen, Mikko Tyster, Sami Virolainen
  • Patent number: 10239963
    Abstract: This invention relates to no-salt and mixed salt suspension polymerization processes for water-soluble monomers and resins and relates to catalysts produced from the same.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: March 26, 2019
    Assignee: ROHM AND HAAS COMPANY
    Inventors: Takashi Masudo, Robert J. Olsen, Garth R. Parker, Jr., Jose A. Trejo
  • Patent number: 10182586
    Abstract: The use of a material in the production of a beverage, wherein the material particles are added in the course of the production process to a starting material or an intermediate product of the beverage and are then separated off again prior to finishing of the beverage, wherein the particles of the material are characterized in that they at least partially comprise a silicate, wherein the silicate particles with respect to the total weight of the particles have a proportion of at least one metal ion in the range of between 1.5 and 30% by weight, wherein the at least one metal ion is selected from a metal ion of the elements La, Ce, Cu, Ag, Zn, Sn, Ca, Mg, Fe and Mn.
    Type: Grant
    Filed: October 29, 2013
    Date of Patent: January 22, 2019
    Assignee: ERBSLÖH GEISENHEIM AG
    Inventors: Jürgen Fröhlich, Volker Müller, Anne Besier
  • Patent number: 10183879
    Abstract: The invention is directed to a method for the removal of mercury and selenium from sulfate-containing waste water. The method may include the following steps: a) a mercury- and selenium-contaminated waste water with a known sulfate concentration is provided, b) barium sulfate (BaSO4) is precipitated from the provided waste water by the addition of a predefined amount of Ba2+ ions to the waste water, c) BaSO4 (if necessary together with other solids) is separated obtaining a low-solid waste water, d) the low-solid waste water is fed to an ion exchanger for the removal of mercury obtaining a waste water with a reduced mercury content, e) selenium and/or selenium compounds are removed from the waste water with the reduced mercury content and f) a sulfate-containing solution or solid is added to the waste water with a reduced selenium and/or selenium compound content in order to precipitate barium sulfate.
    Type: Grant
    Filed: June 13, 2014
    Date of Patent: January 22, 2019
    Assignee: STEAG ENERGY SERVICES GMBH
    Inventors: Luis Fernando Piedra-Garza, Thomas Lauer, Magdalena Hilger
  • Patent number: 10150908
    Abstract: A method of depleting a given analyte from a water source is provided. The method is applicable to water used in oil recovery, water used in natural gas recovery, the treatment of water wells, and for water used in hydraulic fluids for fracturing processes, such as water to be used in proppants or fracking fluids. The method involves depleting an analyte from a water source, said method comprising contacting a water source with a superparamagnetic or paramagnetic nanoparticle; complexing the analyte with the particle; and removing the analyte-particle complex by applying a magnetic field so as to provide a water source with depleted analyte content. The depleted water can then be pumped into one or more connecting injection well(s) in an oil field pushing the crude oil 10 towards one or more production well(s) thereby allowing for enhanced oil recovery from the production wells.
    Type: Grant
    Filed: September 30, 2014
    Date of Patent: December 11, 2018
    Assignee: TOTAL E&P DANMARK A/S
    Inventors: Kristian Mogensen, Martin Vad Bennetzen
  • Patent number: 10138410
    Abstract: A method of depleting an ion from a water source is provided. The method is applicable to water used in oil recovery, water used in natural gas recovery, the treatment of water wells, and for water used in hydraulic fluids for fracturing processes, such as water to be used in proppants or fracking fluids. The method involves depleting an ion from a water source, said method comprising contacting a water source with a superparamagnetic or paramagnetic nanoparticle; complexing the ion with the particle; and removing the ion-particle complex by applying a magnetic field so as to provide a water source with depleted ion content. The depleted water can then be pumped into one or more connecting injection well(s) in an oil field pushing the crude oil towards one or more production well(s) thereby allowing for enhanced oil recovery from the production wells.
    Type: Grant
    Filed: September 30, 2014
    Date of Patent: November 27, 2018
    Assignee: TOTAL E&P DANMARK A/S
    Inventors: Martin Vad Bennetzen, Kristian Mogensen
  • Patent number: 9963359
    Abstract: The invention relates to a process for recovering bromide from a halide-containing aqueous stream, comprising the steps of: providing a feed of halide-containing aqueous stream; contacting an anion-exchange resin with said feed, to form halide-loaded resin; treating said halide-loaded resin with a regenerant and subsequently with a rinse to produce, in succession, a chloride-rich solution, a mixed chloride/bromide solution, a bromide-rich solution and an essentially halide-free solution; directing said mixed chloride/bromide solution to said feed; processing said bromide-rich solution to recover one or more bromide products; and utilizing said essentially halide-free solution for regenerant dilution and/or rinsing of said resin. An apparatus for carrying out the process is also disclosed.
    Type: Grant
    Filed: January 27, 2014
    Date of Patent: May 8, 2018
    Assignee: BROMINE COMPOUNDS LTD.
    Inventors: Emanuel Korngold, Mordechai Cohen, Mira Bergstein Freiberg, Sharon Krumbein Rubin
  • Patent number: 9790249
    Abstract: Solid base catalysts and their use for the base-catalyzed depolymerization (BCD) of lignin to compounds such as aromatics are presented herein. Exemplary catalysts include layered double hydroxides (LDHs) as recyclable, heterogeneous catalysts for BCD of lignin.
    Type: Grant
    Filed: August 4, 2015
    Date of Patent: October 17, 2017
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Gregg T Beckham, Mary J. Biddy, Jacob S. Kruger, Stephen C. Chmely, Matthew Sturgeon
  • Patent number: 9782719
    Abstract: A method of removing acid gases from a gaseous stream is provided. The acid gases may include carbon dioxide, hydrogen sulfide and/or sulfur dioxide, by example. Embodiments of the method include mixing an amine-terminated branched polymer solvent with the gaseous stream, resulting in the substantial absorption of at least some of the acid gases. The solvent is an amine-terminated branched PEG, such as by example amine-terminated glycerol ethoxylate, amine-terminated trimethylolpropane ethoxylate, and/or amine-terminated pentaerithritol ethoxylate. Embodiments of the present inventive methods further include regenerating the solvent using electrolysis.
    Type: Grant
    Filed: September 20, 2016
    Date of Patent: October 10, 2017
    Assignee: NRGTEK, INC.
    Inventor: Subramanian Iyer
  • Patent number: 9770702
    Abstract: Method for controlling metals in a liquid are described. The liquid is contacted with a hexahydrotriazine and/or a hemiaminal material, and metal is adsorbed from the liquid onto the material. The hexahydrotriazine and/or hemiaminal material may be made from a diamine and an aldehyde.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: September 26, 2017
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Gavin O. Jones, Rudy J. Wojtecki
  • Patent number: 9714178
    Abstract: Treatment of silica-laden wastewater is herein described. Unlike traditional fixed bed designs that cannot use an activated alumina sorbent due to the high volumes of sorbent needed in a fixed bed design, the herein disclosed continuous cycle enables smaller volumes of sorbent to be used and thereby enabling activated alumina to be used. Adsorption, regeneration, and rinse regions are provided. Activated alumina is provided to the adsorption region along with silica-containing wastewater. A pH below the zero point charge for alumina is set, and this causes the silica to load onto the alumina. Gravity brings the loaded alumina to the regeneration region, having a pH equal to or greater than the zero point charge of alumina such that the silica is released from the alumina. The silica and alumina are further separated in the rinse region, and the regenerated alumina can then be returned to the adsorption region.
    Type: Grant
    Filed: January 23, 2015
    Date of Patent: July 25, 2017
    Assignee: Drake Water Technologies, Inc.
    Inventor: Ronald N. Drake
  • Patent number: 9663375
    Abstract: In particular, in alternative embodiments, the invention provides for a method to recover silicofluoride and phosphate species from wastewaters, or barometric condenser waters, that are typically utilized in wet-process phosphoric acid facilities. The species are recovered via a continuous ion exchange approach that allows for economic recovery of the materials and especially with the silicofluoride component allows for the production of valuable industrial materials such as hydrofluoric acid and other fluoride salts as well as industrial-grade precipitated silica materials. Return of the treated waste water to the phos-acid plant allows for optimization of reagent usage.
    Type: Grant
    Filed: July 21, 2013
    Date of Patent: May 30, 2017
    Assignee: K-Technologies, Inc.
    Inventors: William W. Berry, Thomas E. Baroody
  • Patent number: 9589690
    Abstract: A method for the cleanup of ionic species such as cobalt and nickel in nuclear power plant aqueous streams using a sequestration resin material is disclosed herein. The method includes the steps of providing a sequestration resin for removal of radioisotopes of transition metal impurities contained in the plant process streams, and distributing the sequestration resin into the plant process streams such that the sequestration resin interacts with the process streams and removes the transition metal impurities.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: March 7, 2017
    Assignee: ELECTRIC POWER RESEARCH INSTITUTE, INC.
    Inventors: Paul L. Frattini, Roger Howard Asay, Keith Paul Fruzzetti, Susan Elaine Garcia, Richard Herbert Kohlmann, Daniel Morgan Wells
  • Patent number: 9511090
    Abstract: The invention relates to a composition for use in the very rapid treatment of cell degeneration, in particular in oncologic field, characterized in that it is constituted by a compound of Potassium Bicarbonate and D-Ribose.
    Type: Grant
    Filed: December 9, 2011
    Date of Patent: December 6, 2016
    Inventor: Eliseo Garuti
  • Patent number: 9359228
    Abstract: A biodegradable iron-crosslinked alginate is useful as a remediation agent for environmental contaminants such as phosphate. When charged with phosphate, or other nutrients, the iron-functionalized alginate can be used as an agricultural fertilizer.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: June 7, 2016
    Assignee: NDSU Research Foundation
    Inventors: Achintya Bezbaruah, Talal Bakheet Almeelbi, Michael Quamme
  • Patent number: 9284205
    Abstract: An apparatus introduces partially-purified, softened makeup water into an open recirculating cooling system by injecting proportionated softened makeup water into a secondary side system (such as for filtering the system water) and connected to its primary recirculating system. Proportional unsoftened makeup water is introduced through the secondary side system lines. In particular, the present apparatus and method includes controlling proportional additions (via batch or continuously) of softened and unsoftened makeup water based on cycles of concentration of the system water, and based on characteristics (e.g. conductivity) of the unsoftened makeup water. For example, the present innovation allows the water softener equipment to be placed inside the building where components are easier to install, service, and maintain, while still resulting in optimal control for purposes of minimizing total makeup water required.
    Type: Grant
    Filed: December 24, 2013
    Date of Patent: March 15, 2016
    Inventor: Donald S. Hofmann
  • Patent number: 9216411
    Abstract: A method for inhibiting formation of nitrosamines and an anion exchange resin produced therefrom comprising providing an anion exchange resin with a nitrosating agent and applying an antioxidant to the resin to inhibit formation of nitrosamines on the anion exchange resin.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: December 22, 2015
    Assignee: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Chris Raymond Eicher, Daryl John Gisch
  • Patent number: 9199863
    Abstract: A method includes combining an aqueous solution of sodium fumarate with an aqueous solution of iron chloride to form a mixture, and obtaining an iron coordination polymer as an amorphous compound formed as a precipitate from the mixture. The iron coordination polymer may be used to bind contaminants, such as arsenate and phosphate from water.
    Type: Grant
    Filed: January 3, 2012
    Date of Patent: December 1, 2015
    Assignee: The Board Of Regents For Oklahoma State University
    Inventor: Allen Wallace Apblett
  • Patent number: 9139533
    Abstract: The present invention provides a capsule-type compound consisting of: a capsule-type divalent cation consisting of a capsule framework represented by the following formula (1) and a sulfate ion (SO42?) encapsulated in the capsule framework; and a sulfate ion (SO42?) as a counter ion to the capsule-type divalent cation. In the formula (1), R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, and R13 each independently represent a hydrogen atom or a methyl group; and M1 and M2 each independently represent Cu2+, Fe2+, Ni2+, Co2+, or Zn2+.
    Type: Grant
    Filed: January 26, 2012
    Date of Patent: September 22, 2015
    Assignee: NATIONAL UNIVERSITY CORPORATION SHIZUOKA UNIVERSITY
    Inventor: Mitsuru Kondo
  • Patent number: 9138739
    Abstract: A method for inhibiting formation of nitrosamines and an anion exchange resin produced therefrom comprising providing an anion exchange resin with a nitrosating agent and mixing a cation exchange resin with the anion exchange resin to inhibit formation of nitrosamines on the anion exchange resin.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: September 22, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Chris Raymond Eicher, Daryl John Gisch, Harlan Robert Goltz
  • Publication number: 20150076072
    Abstract: The present disclosure is directed to polymeric beads, methods of making the beads, and methods of using the beads as high-capacity anion exchange materials. In particular, the disclosure provides polymeric beads comprising a cross-linked polyamine and having a crush strength of about 250 g/bead or more. Preferably, the beads are substantially spherical. Also disclosed are polymeric beads comprising a cross-linked polyamine that has a substantial number of both strong base sites and weak base sites. Methods of using the polymeric beads in various industrial applications, such as groundwater remediation, radio waste management, municipal wastewater management, demineralization, toxin removal, mining, food refinery, research, agriculture, and the like, are also disclosed herein.
    Type: Application
    Filed: September 17, 2014
    Publication date: March 19, 2015
    Inventors: Han-Ting Chang, Mamadou Samba Diallo, Daniel Sanchez, Changjun Yu
  • Publication number: 20150068291
    Abstract: The micro-solid phase extraction of haloacetic acids is a procedure that extracts haloacetic acids from aqueous solution using iron-modified rice husk silica as the stationary phase or sorbent. Rice husks provide an excellent source of silica. The sorbent is prepared by incinerating the husks to produce a powder that is treated with 1.0 M nitric acid for 24 hours to produce rice husk silica. The silica is washed with base, cetyltrimethylammonium bromide is added, and then titrated with a 10% Fe3+ solution to pH 5, which forms a gel. The gel is aged, filtered, dried, and calcined to produce a nitrate-free iron-modified rice husk sorbent. The sorbent is then packaged in porous, heat-sealed polypropylene membrane envelopes and used for extraction of HAAs from water. The HAA analytes are desorbed by ultrasonication in methanol for analysis and quantification.
    Type: Application
    Filed: September 11, 2013
    Publication date: March 12, 2015
    Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventors: CHANBASHA BASHEER, HAKIMU NSUBUGA
  • Patent number: 8974673
    Abstract: The invention relates to a method and apparatus for restoring the extractive potential of organic hydroxyoxime-based extraction solution used in the recovery of metals by liquid-liquid extraction. The method is two-stage, in which an aqueous solution of hydroxylamine or some hydroxylamine compound is used in the reaction stage, and the removal of the undesirable compounds generated in the reaction occurs in the second stage by adsorption purification. The reaction stage and the adsorptive stage are carried out in a mixing tank.
    Type: Grant
    Filed: May 26, 2010
    Date of Patent: March 10, 2015
    Assignee: Outotec Oyj
    Inventors: Erkki Paatero, Kai Jyrkkä, Sami Virolainen
  • Patent number: 8968572
    Abstract: In a device and a process for purifying water which is contaminated with sulphate ions and heavy metal ions, the water is collected in a water reservoir and a substance having basic activity in water is fed to the water reservoir in such a manner that a precipitant having heavy metal ions is precipitated from the water, wherein at least a subquantity of water is taken off from the water reservoir and is separated into pure water which is substantially freed from sulphate ions and heavy metal ions and dirty water which is enriched with sulphate ions and heavy metal ions. The dirty water is at least in part recirculated to the water reservoir, as a result of which a concentration of sulphate ions in the water reservoir is achieved such that a precipitant having sulphate ions is precipitated from the water.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: March 3, 2015
    Assignee: Siemens Aktiengesellschaft
    Inventor: Michael Riebensahm
  • Publication number: 20150053620
    Abstract: The present invention features compositions and methods for reducing the concentration of an endocrine disrupting agent in an aqueous solution. We describe compositions comprising various polymeric resins. The methods can be used to reduce the concentration of endocrine disrupting agents, including estrogens, perfluorinated compounds and bisphenol A in an aqueous solution.
    Type: Application
    Filed: August 21, 2014
    Publication date: February 26, 2015
    Inventors: Rominder P.S. SURI, Dan LIU
  • Publication number: 20150034560
    Abstract: Disclosed is a method for selectively binding and separating phosphate anions from a liquid medium by providing a cross-linked molecularly imprinted polymer including cross-linked chitosan having selective binding affinity for phosphate ions, phosphate containing molecules, or a combination of both.
    Type: Application
    Filed: October 1, 2014
    Publication date: February 5, 2015
    Inventors: Tracy J. Terry, Andrew F. Mason, Carl A. Marrese
  • Publication number: 20150034555
    Abstract: Generally, the present disclosure provides a process for treating de-oiled oilfield produced water or de-oiled process affected water from hydrocarbon production. In particular, such water is treated with a regenerable polymeric ion exchange resin to remove water soluble ionic surfactants. The treating can involve ion-exchanging ionic polymeric membrane foulants with non-fouling soluble ionic species that can be removed by polymeric membrane.
    Type: Application
    Filed: May 8, 2014
    Publication date: February 5, 2015
    Inventors: Brian C. Speirs, Bruce K. Bartlett, Amitava Sarkar, Olusola B. Adeyinka
  • Patent number: 8945392
    Abstract: The invention employs composites of zeolite and ferric oxide hydroxide for removal of inorganic nitrogen and phosphorus wastes from animal environments.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: February 3, 2015
    Assignee: Red Lion Chem Tech, LLC
    Inventors: Michael E. Hickey, Allan D. Pronovost
  • Publication number: 20150027949
    Abstract: A method for removing nitrate ions from a solution is presented. The method includes providing a polymer comprising a protonated amine moiety and an anion derived from an acid having a pKa value greater than about 1. The method further includes contacting the polymer with the solution to bind at least a portion of the nitrate ions in the solution with the polymer, and form a polymer-nitrate complex. The method furthermore includes separating at least a portion of the polymer-nitrate complex from the solution.
    Type: Application
    Filed: July 26, 2013
    Publication date: January 29, 2015
    Applicant: General Electric Company
    Inventors: Hongchen Dong, Larry Neil Lewis, Stephen Robert Vasconcellos
  • Patent number: 8940175
    Abstract: Mass transfer sorption processes involve passage of a processed aqueous solution through a layer of granulated sorbent pre-filled with an organic liquid immiscible with either water or an aqueous solution under treatment. The apparatus for mass transfer of sorption processes is a vertical tank with inlet and outlet fittings loaded with a layer of sorbent disposed between the upper and the lower distribution and drainage systems. The industrial plant for separation of the components of aqueous solutions of inorganic substances includes the said apparatus and the apparatus for the separation of organic liquids from aqueous solutions. The latter has a casing with three chambers, the middle one of which is separated from the first outer one by a grid and from the other by a hydrophobic drainage layer. The emulsion to be separated is introduced into the middle chamber, and the separation results are derived from the outer chambers.
    Type: Grant
    Filed: November 27, 2012
    Date of Patent: January 27, 2015
    Assignee: Obschestvo s ogranichennoi otvetstvennost'yu Nauchno—tekhnologicheskaya kompaniya “Novaya khimiya”
    Inventors: Ruslan Khazhsetovich Khamizov, Anna Naumovna Krachak, Elena Borisovna Podgornaya, Sultan Khazhsetovich Khamizov
  • Patent number: 8940958
    Abstract: Method for the stabilization of contaminants within a material selected from soils, mining tailings and by-products, sludge wastes and industrial wastes, by mixing the material with an alum sludge composition. The composition includes one or more aluminum compound(s) and/or complex(es) together with a reactive carbon material.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: January 27, 2015
    Assignees: Commonwealth Scientific and Industrial Research Organisation, Ziltek Pty Ltd
    Inventor: Michael John McLaughlin
  • Publication number: 20150023889
    Abstract: Disclosed are compounds, compositions, and methods relating to fluoride aptamers, fluoride-responsive riboswitches, fluoride-regulated expression constructs, fluoride transporters, nucleic acids encoding fluoride transporters, expression constructs encoding fluoride transporters, and cells containing or including any combination of these.
    Type: Application
    Filed: September 17, 2012
    Publication date: January 22, 2015
    Inventors: Ronald Breaker, Jenny Baker, Narasimhan Sudarsan, Zasha Weinberg, Adam Roth, Tyler Ames, James Nelson
  • Patent number: 8937112
    Abstract: An aqueous fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of about 10 to about 400 nm. The dispersion has a solids content of at least about 35 to about 70 wt % and comprises about 0.03 wt % to about 10 wt % anionic polyelectrolyte dispersing agent based on the weight of fluoropolymer solids. The dispersion has a Gel Time of at least about 100 seconds.
    Type: Grant
    Filed: August 20, 2013
    Date of Patent: January 20, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Robert John Cavanaugh, Clay Woodward Jones