Including Degassing Patents (Class 210/718)
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Patent number: 11286190Abstract: The invention discloses and claims various methods for the treatment of various wastewater streams of varying chemical composition using sonication in combination with a variety of other methods, including nucleation, ozonation, flocculation, clarification, adsorption, polishing, and filtration. The methods disclosed and claimed are useful in the treatment of industrial wastewater, brackish water, seawater, and for the treatment of oil and gas-well water as well as wastewater from hydraulic gas-fracturing processes for the production of oil and natural gas.Type: GrantFiled: April 16, 2020Date of Patent: March 29, 2022Assignee: Columbia Water Holdings, Inc.Inventors: Benjamin Roberts, Lee Shull, Michael P. Mehlhoff
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Patent number: 11161761Abstract: A mobile sewage treatment and water reclamation system for rapid deployment to augment existing wastewater systems and/or provide interim service in lieu of permanent facilities, includes: (a) a denaturing stage wherein raw sewage is first ground into suspendable grit, its pH lowered to kill acid-sensitive bio-organisms and raised to kill base-sensitive bio-organisms, and then neutralized; (b) a clarifying stage employing an inverted-cone tank to circulate the solution after injection with chemicals to flocculate small particles for collection in a layer for siphoning off; and (c) a disposal stage wherein clarified water passes through media filters to remove remaining solids and odors, the effluent water being clean enough for irrigation, aquatic life and discharge into waterways; and wherein sterile sludge is pressed into semi-dry solids, then dried, crushed, powdered and bagged for use as high-nitrate biomass fertilizer or for fossil-fuel power co-generation applications.Type: GrantFiled: February 23, 2019Date of Patent: November 2, 2021Inventors: Daniel R. Smith, Kenneth A. Roberson, Jr.
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Patent number: 10710916Abstract: A mobile sewage treatment and water reclamation system for rapid deployment to augment existing wastewater systems and provide interim service in lieu of permanent facilities, includes: (a) denaturing stage wherein raw sewage is first ground into suspendable grit, its pH first lowered to kill acid-sensitive bio-organisms, then raised to kill base-sensitive bio-organisms, and then neutralized; (b) clarifying stage employing an inverted-cone tank to circulate the solution after injection with chemicals to flocculate small particles for collection in a layer for siphoning off; and (c) disposal stage wherein clarified water passes through media filters to remove remaining solids and odors, the effluent water being clean enough for irrigation, aquatic life and discharge into waterways; and wherein sterile sludge is pressed into semi-dry solids, then dried, crushed, powdered and bagged for use as high-nitrate biomass fertilizer or for fossil-fuel power co-generation applications.Type: GrantFiled: March 15, 2014Date of Patent: July 14, 2020Assignee: E3 WATER, LLCInventors: Daniel R. Smith, Kenneth A. Roberson, Jr.
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Patent number: 10230119Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.Type: GrantFiled: February 25, 2018Date of Patent: March 12, 2019Assignee: L3 Open Water Power, Inc.Inventors: Jason R. Kovacs, Ian S. McKay, David H. Porter, Thomas B. Milnes
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Patent number: 10023828Abstract: A method of decarbonating fermented liquids in-line may include directing a carbonated malt-based liquid through a nozzle, and directing the carbonated malt-based liquid from the nozzle into a space maintained at a partial vacuum pressure. The method may further include maintaining the carbonated malt-based beverage in the space until substantially all of the carbon dioxide dissolved within the carbonated malt-based beverage has been removed to provide a non-carbonated liquid, and removing the non-carbonated liquid from the space at substantially the same rate that the carbonated malt-based liquid is directed into the space.Type: GrantFiled: January 21, 2016Date of Patent: July 17, 2018Assignee: Anheuser-Busch, LLCInventors: Jerome Pellaud, Patrick O'Riordan, Neeraj Sharma, Frank Z. Hellwig, Wilfried Lossignol, Aaron Penn
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Patent number: 9688559Abstract: The present invention relates in general to a process of removing phosphorus in various forms of suspended solids or dissolved ions, fluoride, and arsenic impurities from water streams in a multi-stage procedure via the use of additives, pH control, and physical separation, resulting in a water stream with <50 ppb phosphorus, <3 ppm fluoride, and <1 ppm arsenic.Type: GrantFiled: June 12, 2015Date of Patent: June 27, 2017Assignee: Pattison Sand CompanyInventors: David A. Aubry, Daniel R. Matlick
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Patent number: 9446974Abstract: Methods and systems for treatment of wastewater. In some embodiments, the system may comprise one or more modules such as an electrochemical module, an electrocoagulation module, a flotation module, an evaporation module, and an ultrafiltration module. One or more detection modules may also be provided to analyze the concentration of one or more wastewater components in the wastewater. Data from such modules may be used to adjust one or more operational parameters or conditions in the treatment system. The system may also comprise one or more features designed to minimize adverse effects on the environment, such as avoiding adding chemicals to the stream, extracting salt or other chemicals for re-use, and/or use of carbon dioxide gas from on-site combustion processes.Type: GrantFiled: February 6, 2014Date of Patent: September 20, 2016Assignee: EnergySolutions, Inc.Inventors: Tim Milner, Lu Liu, Paul Sylvester
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Patent number: 9234507Abstract: Provided is a steam characteristics automatic measuring device capable of automatically, ideally also continuously measuring the characteristics of steam taken from a production well, without being affected by interfering components, such as hydrogen sulfide gas and carbon dioxide gas contained in large quantities in steam taken from under the ground, which enables the operator to continuously understand the characteristics of steam and support a smooth operation of a geothermal power plant. The device has a silica monitor for measuring a concentration of silica included in a condensate obtained by cooling steam taken from under the ground; an electrical conductivity meter for automatically measuring the electrical conductivity thereof; a pH meter for automatically measuring the pH value thereof; and a data processing transmitter for automatically transmitting data measured by each of the monitor and meters.Type: GrantFiled: October 2, 2009Date of Patent: January 12, 2016Assignees: Fuji Electric Co., Ltd., Geothermal Engineering Co., Ltd., Nikkiso Co., Ltd.Inventors: Ichiro Myougan, Yasuyuki Hishi, Toshiaki Aoki
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Publication number: 20150122740Abstract: The present disclosure relates, according to some embodiments, to systems and methods of fluid treatment systems. Fluid treatment systems and methods thereof may be operable to remove contaminants and optionally reduce hardness. A fluid treatment system may comprise a feed stream configured to provide a contaminated fluid, a concentrate tank configured to receive the contaminated fluid from the feed stream, a filtration unit configured to receive the contaminated fluid from the concentrate tank, and a permeate stream operable to receive a treated fluid from the filtration unit. A concentrate tank may be operable to reduce hardness of the contaminated fluid. A filtration unit may be operable to filter contaminants from the contaminated fluid.Type: ApplicationFiled: November 1, 2013Publication date: May 7, 2015Inventors: Anthony L. Powell, Brian E. Butters
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Patent number: 8877690Abstract: A method of treating a wastewater is provided and can be used, for example, to treat a gas well production wastewater to form a wastewater brine. The method can involve crystallizing sodium chloride by evaporation of the wastewater brine with concurrent production of a liquor comprising calcium chloride solution. Bromine and lithium can also be recovered from the liquor in accordance with the teachings of the present invention. Various metal sulfates, such as barium sulfate, can be removed from the wastewater in the production of the wastewater brine. Sources of wastewater can include gas well production wastewater and hydrofracture flowback wastewater.Type: GrantFiled: August 31, 2011Date of Patent: November 4, 2014Assignee: ProChemTech International, Inc.Inventor: Timothy Edward Keister
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Publication number: 20140263081Abstract: This invention relates to the field of water purification and desalination. In particular, embodiments of the invention relate to systems and methods of removing essentially all of a broad spectrum of impurities from water in an automated industrial process that requires minimal cleaning or maintenance during the course of several months to several years, with relatively high yields of product water per unit of input water, flexibility with respect to energy sources, compact design with a low industrial foot-print, the ability to recover valuable by-products, and ultra-low energy requirements.Type: ApplicationFiled: September 7, 2012Publication date: September 18, 2014Applicant: Sylvan Source,Inc.Inventor: Eugene Thiers
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Publication number: 20140251922Abstract: Method for removing hydrogen sulfide from fluids such as oil and gas well drilling, treatment, and production fluids and effluents from hydrocarbon operations and mineral mining operations. The sulfide scavenger used in the method is a gluconate salt other than ferrous gluconate. The gluconate salt is added to the fluid along with an iron source if iron is not already in the fluid. The gluconate reacts with the iron and forms iron gluconate in the fluid, which in turn reacts with the hydrogen sulfate to form iron sulfide which may be readily removed from the fluid.Type: ApplicationFiled: March 6, 2013Publication date: September 11, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Cato Russell McDaniel, Carl J. Thaemlitz
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Patent number: 8815100Abstract: The present invention relates to a cyclone type liquid/gas or liquid/liquid separator having separation properties that are stabilized, even when the flow rate and the proportions of the liquid phases for separation vary, by means of a platform situated in the low portion of a cylindrical separation chamber that is fed at its top end via a tangential feed orifice. The present invention also provides an installation and a method of separating the oil and water contained in crude oil, with the help of a cyclone of the invention.Type: GrantFiled: October 25, 2006Date of Patent: August 26, 2014Assignee: Saipem S.A.Inventors: Paul Chantrel, Marc Bonnissel
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Publication number: 20140197111Abstract: Wastewater treatment methods and systems for removal of phosphorus (P) and nitrogen (N) from wastewater and for recovery of them as usable materials. Sufficient amount of dolomite lime and slaked dolomite lime is added into the wastewater to increase the pH of the wastewater to above 8.5 and to form P precipitates and to convert ammonium to ammonia in a precipitation-ammonia stripping reactor or a continuous flow precipitation reactor. The P precipitates are separated from the wastewater and recovered as usable solid material. The ammonia gas is absorbed and concentrated with acid solution in an ammonia absorption tower as usable liquid material.Type: ApplicationFiled: December 19, 2013Publication date: July 17, 2014Applicant: Chinese Research Academy of Environmental SciencesInventors: Wei MENG, Yonghui SONG
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Patent number: 8771477Abstract: Embodiments of the invention provide systems and methods for water purification and desalination. The systems have a preheater, a degasser, multiple evaporation chambers with demisters, heat pipes, and a control system, wherein the control system permits continuous operation of the purification and desalination system without requiring user intervention or cleaning. The systems are capable of recovering hear from each distillation stage, while removing, from a contaminated water sample, a plurality of contaminants including: microbiological contaminants, radiological contaminants, metals, salts, and organics.Type: GrantFiled: September 17, 2009Date of Patent: July 8, 2014Assignee: Sylvan Source, Inc.Inventor: Eugene Thiers
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Patent number: 8734653Abstract: A mercury remediation method and apparatus for reducing mercury levels in water to a nanogram per liter level that uses four treatment steps: (1) chelation; (2) oxidation; (3) reduction; and (4) air stripping, vapor/liquid separation. There is a fifth step in the process, which does not involve the wastewater. It is to scrub the stripper air of the volatile mercury in an off-gas adsorption unit or to condense volatile mercury in a cryogenic mercury trap.Type: GrantFiled: November 30, 2011Date of Patent: May 27, 2014Inventor: Terrence W. Aylesworth
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Publication number: 20140054234Abstract: A removal device for removing gas bubbles and/or dirt particles from a liquid in a liquid conduit system includes a housing having an entry and an exit and, a main ongoing flow channel which extends through the housing from the entry to the exit, a plurality of branch flow channels, each branch flow channel branching off from the main flow channel at a branch point, at least one quiet zone which is provided at the ends of the branch flow channels, at least one return flow channel for a return flow from the at least one quiet zone back to the main flow channel, where the return flow channel merges with the main flow channel at a merge point, and where the branch flow channels are defined by plates which are curved.Type: ApplicationFiled: February 17, 2012Publication date: February 27, 2014Applicant: FLAMCO B.V.Inventors: Jan Henk Cnossen, Terence Arthur Devlin
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Patent number: 8585907Abstract: An apparatus and a method for filling a container containing a dry powdered salt concentrate for use in dialysis with purified fluid and removing the trapped air or gases generated during the filling of the container, while maintaining the required fluid level in the container and without the need for evacuating gases from the container prior to filling.Type: GrantFiled: November 12, 2010Date of Patent: November 19, 2013Assignee: Fresenius Medical Care Holdings, Inc.Inventors: Wayne Raiford, Robert E. Hassard
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Patent number: 8470275Abstract: Reduced-carbon footprint concrete compositions, and methods for making and using the same, are provided. Aspects of the reduced-carbon footprint concrete compositions include CO2-sequestering carbonate compounds, which may be present in the hydraulic cement and/or aggregate components of the concrete. The reduced-carbon footprint concrete compositions find use in a variety of applications, including use in a variety of building materials and building applications.Type: GrantFiled: July 19, 2010Date of Patent: June 25, 2013Assignee: Calera CorporationInventors: Brent R. Constantz, Andrew Youngs, Terence C. Holland
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Patent number: 8454835Abstract: In at least one embodiment, a method for remediating oxic water having transition metal ions comprises the steps of providing oxic water having transition metal ions. The water is introduced to a chamber. The pH is adjusted to a range from 2.5 to 7.5 forming a pH-adjusted oxic water. Thiosulfate ions are introduced and reacted with the transition metal ions to form insoluble transition metal-thiosulfate species complexes, which are immobilized forming remediated oxic water.Type: GrantFiled: October 2, 2012Date of Patent: June 4, 2013Assignee: Sawaya Corp.Inventor: Frederick J. Sawaya
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Patent number: 8444859Abstract: A mechanical vessel may effectively and simultaneously displace a first undesired gas from within water with a second desired gas, and remove at least one alkaline species and oily matter from the water. The vessel raises the pH of the water and reduces the lime requirement for subsequent lime softening. The vessel receives the water containing the first gas and passes the water through a series of gasification chambers. Each gasification chamber may have a mechanism that ingests and mixes a second gas into the water thereby physically displacing at least a portion of the first gas into a vapor space at the top of each gasification chamber from which it is subsequently removed. There is an absence of communication between the vapor spaces of adjacent chambers. An acid is added to remove the alkaline species, where the first gas is an optional by-product that is also removed.Type: GrantFiled: April 13, 2012Date of Patent: May 21, 2013Assignee: Cameron International CorporationInventors: James C. T. Chen, Shaya Movafaghian
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Publication number: 20130048562Abstract: A method of treating a wastewater is provided and can be used, for example, to treat a gas well production wastewater to form a wastewater brine. The method can involve crystallizing sodium chloride by evaporation of the wastewater brine with concurrent production of a liquor comprising calcium chloride solution. Bromine and lithium can also be recovered from the liquor in accordance with the teachings of the present invention. Various metal sulfates, such as barium sulfate, can be removed from the wastewater in the production of the wastewater brine. Sources of wastewater can include gas well production wastewater and hydrofracture flowback wastewater.Type: ApplicationFiled: August 31, 2011Publication date: February 28, 2013Applicant: PROCHEMTECH INTERNATIONAL, INC.Inventor: Timothy Edward KEISTER
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Publication number: 20130026102Abstract: In at least one embodiment, a method for remediating oxic water having transition metal ions comprises the steps of providing oxic water having transition metal ions. The water is introduced to a chamber. The pH is adjusted to a range from 2.5 to 7.5 forming a pH-adjusted oxic water. Thiosulfate ions are introduced and reacted with the transition metal ions to form insoluble transition metal-thiosulfate species complexes, which are immobilized forming remediated oxic water.Type: ApplicationFiled: October 2, 2012Publication date: January 31, 2013Applicant: SAFE MINES AND WATERWAYS, LLCInventor: Safe Mines and Waterways, LLC
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Publication number: 20130023448Abstract: A method for treating hydrocarbon-servicing fluid is provided for reducing contaminants, especially bacteria, volatile and semi-volatile organics, in hydrocarbon-servicing fluids by microwaving and irradiating the fluid with ultraviolet light, with or without use of catalyst. The treated fluid can be used in upstream and downstream hydrocarbon processing operations.Type: ApplicationFiled: July 18, 2011Publication date: January 24, 2013Applicant: A3ENVIRON TECHNOLOGIES LLCInventors: Frederick J. Glasscott, Wayne F. Downey, JR., Steven M. Fisher, Mark J. McCasland, Dan R. Neal
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Publication number: 20130015142Abstract: A method of and system for treating water to reduce the level of trihalomethanes or other volatile contaminants such as radon includes the water to be treated (WTBT) being sprayed through a nozzle to aerate the WTBT to increase the air/water interface therein reducing the level of trihalomethanes in the water. In one embodiment, the pressure of the WTBT in the nozzle is adjusted and the nozzle is selected to have a nozzle orifice such that the droplet size of the water to be treated from the nozzle is less than 2000 microns SMD. In addition, the nozzle is spaced from a holding tank for receiving and collecting the sprayed water such that the surface of the treated water is specified at a particular distance based on desired treatment goals.Type: ApplicationFiled: June 11, 2012Publication date: January 17, 2013Inventors: Ethan Brooke, Michael Robin Collins
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Publication number: 20130001172Abstract: A method and apparatus for treating waste water utilizing two energized agitated electrochemical reaction reactor units (each utilizing approximately 10 amps per gallon) with a reaction time of approximately 5 minutes wherein the first reaction vessel has a pH below 7 and a second reaction vessel has a pH of above the pH of the first reaction vessel and the effluent flows from a first agitated electrochemical reaction vessel to a degassing tank and then flows to a second agitated electrochemical reaction vessel and then to a flocculation tank.Type: ApplicationFiled: September 7, 2012Publication date: January 3, 2013Inventor: Dan Prokop
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Patent number: 8308957Abstract: A separation process for separating two or more immiscible liquids using contactors utilizing high surface area vertical hanging fibers is disclosed. This separation process is especially useful in the separation of disulfide oil formed during the oxidation of spent caustic solution that was used to remove sulfur contaminates from light hydrocarbons.Type: GrantFiled: August 3, 2010Date of Patent: November 13, 2012Assignee: Merichem CompanyInventors: Tiejun Zhang, V. Keith Turner
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Patent number: 8277648Abstract: In at least one embodiment, a remediation system for oxic water having transition metal ions includes a first chamber defining a first cavity having a first inlet and a first outlet. The first cavity includes oxic water having dissolved ions of reduced species of chalcogenides. The system also includes a second chamber in fluid communication with the first chamber. The oxic water has a pH ranging from 2.5 to 7.5 when present in the first chamber.Type: GrantFiled: May 11, 2011Date of Patent: October 2, 2012Assignee: Safe Mines and Waterways, LLCInventor: Frederick J. Sawaya
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Publication number: 20120228218Abstract: The present invention relates to a process for workup of nitrite-comprising alkaline process wastewaters from the nitration of aromatic compounds, wherein the alkaline process wastewater is acidified by addition of acids and the offgas which comprises nitrogen oxides and escapes from the acidified process wastewater is worked up, comprising the steps of a) acidifying the process wastewater by adding acid to a pH below 5, which forms an organic phase which separates out, an acidic aqueous phase and a gaseous NOx-containing phase, and b) removing the gaseous NOx-containing phase.Type: ApplicationFiled: December 13, 2010Publication date: September 13, 2012Applicant: BASF SEInventors: Ruediger Fritz, Renate Hempel, Michael Zoellinger, Holger Allardt, Reiner Reetz
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Patent number: 8252148Abstract: A mobile waste processing system and method is disclosed for processing materials in a tank, typically an underground storage tank. A mobile fluid processing module is disposed adjacent to or over the tank, and sealingly connected to the tank through a tank riser. Support equipment, which may include an electric power module, a chiller module, a heating module, and a control and monitor module, are disposed a distance from the processing module, and connected thereto. A pump and optionally a dispersal nozzle are deployed from the processing module into the tank, and effluent is extracted for processing. The processing trailer includes effluent processing equipment such as an evaporator and demister, condenser, vacuum pump, and interim storage tank. The effluent is processed, and at least a portion is removed. Some of the processed effluent may be returned to the tank.Type: GrantFiled: June 15, 2011Date of Patent: August 28, 2012Assignee: Columbia Energy & Environmental Services, Inc.Inventors: Stephen Wolfe, Brian Brendel
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Patent number: 8192631Abstract: An apparatus and method for treating raw water. The apparatus includes a vessel having an inlet for the raw water, an outlet for the skimmed water, a rotor mechanism for creating a plurality of gas bubbles within the raw water, and a disperser device operatively associated with the rotor mechanism for dispersing the plurality of gas bubbles from the rotor mechanism within the vessel. The vessel contains raw water. The gas bubbles create an oily froth on top of the raw water. The apparatus further includes a skim tray positioned about the rotor mechanism for removing the oily froth from the top of the raw water and a secondary skimmer positioned within the skim tray. An external skim tank may be configured to deliver a gas to the rotor mechanism and to receive the oily froth from the secondary skimmer.Type: GrantFiled: September 2, 2011Date of Patent: June 5, 2012Assignee: CCS Energy Services LLCInventors: Melvin O. Stacy, Mark G. Arceneaux, Eric Wingate
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Publication number: 20120125861Abstract: A method for removing hydrocarbons and scale forming compounds from tap water, contaminated aqueous solutions, seawater, and saline brines, such as produce water, comprising the addition of carbonate ions by CO2 sparging, or divalent cations, so as precipitate calcium and magnesium carbonates by adjusting pH to about 10.2, thus permanently sequestering CO2 from the atmosphere, and then removing such precipitates sequentially for either sale of disposal.Type: ApplicationFiled: April 12, 2010Publication date: May 24, 2012Applicant: Sylvan Source, Inc.Inventor: Eugene Thiers
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Patent number: 8092656Abstract: A process for treatment of an aqueous stream to produce a low solute containing distillate stream and a high solute/solids containing blowdown stream utilizing a method to increase the efficiency of an evaporator while providing an essentially scale free environment for the heat transfer surface. Multi-valent ions and non-hydroxide alkalinity are removed from aqueous feed streams to very low levels and then the pH is increased preferably to about 9 or higher to increase the ionization of low ionizable constituents in the aqueous solution. In this manner, species such as silica and boron become highly ionized, and their solubility in the concentrated solution that is present in the evaporation equipment is significantly increased. The result of this is high allowable concentration factors and a corresponding increase in the recovery of high quality reusable water with essentially no scaling.Type: GrantFiled: October 17, 2003Date of Patent: January 10, 2012Assignee: Aquatech International CorporationInventors: Keith R. Minnich, Ramkumar Karlupudi, Richard M. Schoen
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Patent number: 8043509Abstract: Devices and methods for water purification are provided. An improved demister (70) for removing liquid or other particles from steam is disclosed. The demister can have adjustable outlets. In other embodiments, a demister apparatus is placed, at least partially, inside a boiler apparatus (310). Additionally, a filter flow indicator (401) that provides an optical indication of the efficiency of a water filter is also provided. The filter flow indicator has a viewable side passage that connects the input and output sides of a filter unit. A weighted object, such as a ball (440), can move up and down the side passage in response to the pressure differential in the filter system. The user can determine the status of the filter by viewing the location of the weighted object in the side passage. Additionally, a device and method of adding various minerals back to purified water in order to improve the flavor of the water is described.Type: GrantFiled: June 29, 2006Date of Patent: October 25, 2011Assignee: Sylvan Source, Inc.Inventor: Eugene Thiers
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Patent number: 8017019Abstract: Improved fluidized bed precipitators (20, 46, 62, 74, 108, 112, 134, 168) especially useful for the treatment of waste waters containing soluble phosphorus are provided, having upright, primary fluidized bed sections (22, 48, 64, 76, 110, 114, 136) and obliquely oriented solids settling sections (28, 54, 68, 120, 144) which enhance the settling of small particles (166) and return thereof to the fluidized bed sections (22, 48, 64, 76, 110, 114, 136). The precipitators (20, 46, 62, 74, 108, 112, 134, 168) may also be equipped with a solids detection/withdrawal assembly (178) made up of one or more pressure transducers (180, 182) operable to determine the pressures within the fluidized bed sections 22, 48, 64, 76, 110, 114, 136) as a measure of bed densities, along with a selectively operable valve (172) which may be opened to periodically remove solids without clogging.Type: GrantFiled: June 13, 2008Date of Patent: September 13, 2011Assignees: Kansas State University Research Foundation, Kansas Environmental Management Associates, LLCInventors: Gina Young Becker, Sigifredo Castro Diaz, Michael Hanson, Kylo Martin Heller, Dean Thompson
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Patent number: 7950770Abstract: This patent specification describes a droplet-ejecting head including a nozzle substrate having a plurality of nozzles for ejecting droplets, and an actuator configured to be driven to generate energy for ejecting droplets through each nozzle. The nozzle substrate is cleaned by a cleaning liquid containing microbubbles before being bonded to another member.Type: GrantFiled: February 22, 2007Date of Patent: May 31, 2011Assignee: Ricoh Company, Ltd.Inventors: Toshiroh Tokuno, Michio Umezawa, Kaichi Ueno, Kouji Ohnishi
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Patent number: 7935261Abstract: A method is provided of recycling and cleaning up oil-based waste drilling mud and cuttings contaminated with oil-based waste drilling mud. A facility for performing the method is also provided. The method includes removing the coarse solids from the mud, breaking the emulsion, separating the hydrophobic phase from the water phase and the solid phase, vaporizing all residual oil and water from the solids, and burning off the vaporized oil. The method produces a solid “soil” product that is free from oil contamination, an oil product that is fit for reuse, and clean air emissions. A thermal desorber can be used to efficiently vaporize the oil at low temperature. Optionally the water fraction of the mud can be vaporized, solutes and salts can be captured as evaporite and then be mixed with the soil product. The method has the unique advantage of producing no persistent hazardous waste.Type: GrantFiled: November 24, 2008Date of Patent: May 3, 2011Assignee: Arkansas Reclamation Company, LLCInventors: Thomas P. Jones, Richard T. Davis, Charles R. Richesin
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Patent number: 7867399Abstract: A method is provided of recycling and decontaminating oil-based waste drilling mud and cuttings contaminated with oil-based waste drilling mud. A facility for performing the method is also provided. The method includes removing the coarse solids from the mud, breaking the emulsion, and separating the hydrophobic phase from the water phase and the solid phase. The solids may then be treated by either or both of two approaches. One approach involves vaporizing all residual oil and water from the solids, and burning off the vaporized oil. Another approach involves at least partially vaporizing the residual oil from the solids and recondensing the oil. The method produces a solid “soil” product that is free from oil contamination (or is sufficiently decontaminated to allow reuse), an oil product that is fit for reuse, and clean air emissions. A thermal desorber or a soil dryer can be used to efficiently vaporize the oil at low temperature.Type: GrantFiled: October 30, 2009Date of Patent: January 11, 2011Assignee: Arkansas Reclamation Company, LLCInventors: Thomas P. Jones, Charles R. Richesin, Richard T. Davis
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Patent number: 7833499Abstract: A separation process for separating two or more immiscible liquids using fiber-film technology is disclosed. This separation process is especially useful in the separation of disulfide oil formed during the oxidation of spent caustic solution that was used to remove sulfur contaminates from light hydrocarbons.Type: GrantFiled: June 14, 2007Date of Patent: November 16, 2010Assignee: Merichem CompanyInventors: Tiejun Zang, V. Kenneth Turner
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Patent number: 7828979Abstract: A method for converting animal waste, in the form of waste slurry, to energy and useful byproducts. A screen mesh filters out large objects from waste slurry and the filtered slurry is chopped and fragmented to reduce binding of fibrous materials. The fragmented slurry is mixed at a rate to maintain solids in the fragmented slurry in suspension while minimizing aeration and turbulence within the mixing unit. A solids recovery unit recovers about 95% of the suspended solids. An additive is introduced into the solids recovery unit for providing agglomeration of solids particles. The recovered solids are gasified to produce at least methane/ethane gas. The produced gas is provided to an energy production unit to generate electrical and/or heat energy. Liquid remaining after the solids recovery is treated to remove undesirable contaminants to an extent in compliance with water quality standards set for animal waste flushing, animal washing and animal drinking water, as the case may be.Type: GrantFiled: May 8, 2009Date of Patent: November 9, 2010Assignee: Agricultural Waste Solutions, Inc.Inventor: Stephen R. McCorkle
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Patent number: 7815804Abstract: A method or process for treating wastewater containing high organics, silica, boron, hardness, and suspended and dissolved solids. The method includes degasifying the wastewater for the removal of dissolved gases and thereafter chemically softening the wastewater. After the chemical softening step, the wastewater is directed through a media filter or membrane which removes additional solids and precipitants. Thereafter the wastewater is directed through a sodium ion exchange that further softens the wastewater. The effluent from the ion exchange is directed through a cartridge filter and the effluent from the cartridge filter is directed through one or more reverse osmosis units. At a selected phase of the process, prior to the wastewater reaching the reverse osmosis unit or units, the pH of the wastewater is raised and maintained such that the pH of the wastewater reaching a reverse osmosis unit is at a pH greater than 10.5.Type: GrantFiled: December 12, 2006Date of Patent: October 19, 2010Assignee: OTV SA S.A.Inventor: LNSP Nagghappan
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Patent number: 7815880Abstract: Reduced-carbon footprint concrete compositions, and methods for making and using the same, are provided. Aspects of the reduced-carbon footprint concrete compositions include CO2-sequestering carbonate compounds, which may be present in the hydraulic cement and/or aggregate components of the concrete. The reduced-carbon footprint concrete compositions find use in a variety of applications, including use in a variety of building materials and building applications.Type: GrantFiled: October 22, 2009Date of Patent: October 19, 2010Assignee: Calera CorporationInventors: Brent R. Constantz, Andrew Youngs, Terence C. Holland
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Publication number: 20100258506Abstract: This invention is directed to decreasing the CO2 concentration. The invention makes use of fluids and apparatuses for diminishing CO2 concentrations of fluids.Type: ApplicationFiled: August 21, 2007Publication date: October 14, 2010Inventors: Brian Berkowitz, Ishai Dror
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Publication number: 20100219133Abstract: An emulsion treating unit and process. A subcooled boiling zone in the unit comprises a heat transfer surface to contact an emulsion at a temperature in excess of the saturation temperature of an aqueous phase in the emulsion, wherein the boiling zone is atmospherically vented. The unit also provides means for recovering an oil-rich layer from adjacent a vapor-liquid interface; and means for recovering an aqueous-rich layer from below the oil-rich layer. The process provides operation of the treating unit to heat an emulsion in the subcooled boiling zone, wherein the boiling zone is atmospherically vented, recovering an oil-rich layer and recovering an aqueous-rich layer from below the oil-rich layer. In one embodiment the boiling zone comprises a heat transfer surface having a temperature in excess of the saturation temperature of the aqueous-rich layer, wherein the vapor-liquid interface is subcooled with respect to the saturation temperature of the aqueous layer.Type: ApplicationFiled: March 2, 2010Publication date: September 2, 2010Applicant: RACIONAL ENERGY & ENVIRONMENT COMPANYInventor: Ramon Perez-Cordova
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Patent number: 7771684Abstract: CO2-sequestering formed building materials are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the CO2-sequestering formed building material.Type: GrantFiled: September 30, 2009Date of Patent: August 10, 2010Assignee: Calera CorporationInventors: Brent R. Constantz, Andrew Youngs, Terence C. Holland
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Publication number: 20100187180Abstract: Methods and devices for separating oil from a mixture of oil and air are provided. In various embodiments, an air/oil separator includes a cylindrical housing that creates a circular flow path of the air and oil. Further, the air/oil separator may include various flow guides that improve the air/oil separation properties of the separator. Other embodiments include a turbine engine with a lubrication system that includes the improved air/oil separator.Type: ApplicationFiled: January 29, 2009Publication date: July 29, 2010Applicant: GENERAL ELECTRIC COMPANYInventor: Robert Allen Baten
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Patent number: 7744761Abstract: Desalination methods that include carbonate compound precipitation are provided. In certain embodiments, feed water is subjected to carbonate compound precipitation conditions prior to desalination. In certain embodiments, desalination waste brine is subjected to carbonate compound precipitation conditions. In yet other embodiments, both feed water and waste brine are subjected to carbonate compound precipitation conditions. Aspects of embodiments of the invention include carbon dioxide sequestration. Embodiments of the invention further employ a precipitate product of the carbonate compound precipitation conditions as a building material, e.g., a cement. Also provided are systems configured for use in methods of the invention.Type: GrantFiled: June 27, 2008Date of Patent: June 29, 2010Assignee: Calera CorporationInventors: Brent R. Constantz, Kasra Farsad, Miguel Fernandez
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Patent number: 7736518Abstract: A cavitation device is used to heat and facilitation the separation of mixtures and emulsions of oil and water. Waste heat from the power source for the cavitation device may be utilized to elevate the temperature of incoming mixtures or emulsions. The heated mixture of emulsion is sent to a separation vessel where vapor may be removed and/or recovered, and where oil is removed as it separates into an identifiable layer. The separation vessel may be a flash tank.Type: GrantFiled: February 6, 2007Date of Patent: June 15, 2010Assignee: Total Separation Solutions, LLCInventors: Kevin W. Smith, Robert L. Sloan, Harry D. Smith, Jr.
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Patent number: 7736614Abstract: A process for removing aluminum and other metal chlorides from liquid chlorosilanes with the steps of: introducing a source of seed into a source of impure liquid chlorosilanes, initiating the crystallization of aluminum and other metal chlorides on the seed from the liquid chlorosilanes in a first agitated vessel, passing the resulting mixture of liquid and solids through a cooler into a second agitated vessel for additional crystallization, transferring the resulting mixture of liquid and solids into a solids removal device, transferring the liquid with reduced solids content to a further process or vessel and transferring the liquid with high solids content into a waste concentration device, passing the resulting liquid with reduced solids content to a further process or vessel and passing the resultant liquid with very high solids content to a waste storage vessel with agitation.Type: GrantFiled: April 7, 2008Date of Patent: June 15, 2010Assignee: Lord Ltd., LPInventor: Stephen Michael Lord
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Patent number: 7681643Abstract: A process for conditioning of wastewater treatment brines for deep well injection during recovery of heavy hydrocarbon oils in situ. High pressure steam is used to mobilize oil, which is recovered in a mixture of oil and produced water. The produced water is pre-treated by removing residual oil. The remaining water is acidified and steam stripped to remove non-hydroxide alkalinity and non-condensable gases, and is then fed to a crystallizing evaporator, where it is evaporated from a circulating brine slurry to produce (1) a distillate stream having a trace amount of residual solutes, and (2) evaporator blowdown stream containing, as dissolved or suspended solids, substantially all of the solutes from the produced water feed. The distillate stream is used as boiler feedwater, either directly or after polishing. The evaporator blowdown is conditioned to remove substantially all suspended solids and to produce a clear brine solution for deep well injection.Type: GrantFiled: September 22, 2006Date of Patent: March 23, 2010Assignee: GE Ionics, Inc.Inventor: William F. Heins