Biodegradable Patents (Class 220/DIG30)
  • Patent number: 6001439
    Abstract: The invention provides a stretch blow molded container formed from a thermoplastic resin material which comprises polyglycolic acid having(a) a repeating unit represented by the following formula (1): ##STR1## (b) a melt viscosity, .eta.* [as measured at a temperature of (the melting point, Tm of the polymer+20.degree. C.) and a shear rate of 100/sec] of 500-100,000 Pa.multidot.s;(c) a melting point, Tm of at least 180.degree. C.;(d) a melt enthalpy, .DELTA.Hm of at least 20 J/g; and(e) a density of at least 1.50 g/cm.sup.3 as measured in an unoriented, crystallized form,wherein the stretch blow molded container has tensile strength (in a circumferential direction) of at least 100 MPa and a carbon dioxide permeability (as measured at a temperature of 23.degree. C. and 80% relative humidity; in terms of the thickness of 50 .mu.m) of 300 cc/m.sup.2 .multidot.day.multidot.atm or smaller at the body sidewall thereof, and a production process thereof.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: December 14, 1999
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yukichika Kawakami, Nobuo Sato, Mitsuru Hoshino, Toshitaka Kouyama, Zenya Shiiki
  • Patent number: 5783271
    Abstract: A process for the production of biodegradable aliphatic polyester particles by (co)polymerizing 2-oxetanone or a mixture containing at least 80% by weight of 2-oxetanone and up to 20% by weight of a cyclic ester or cyclic ether other than 2-oxetanone in the presence of a polymerization initiator supported on a carrier in which an ion polymerization initiator is supported on poly(2-oxetanone) in a liquid medium having a solubility parameter of about 15 to about 18 MPa.sup.1/2 and being capable of dissolving 2-oxetanone, and in a polymerizing apparatus having an internal surface formed of a material which is free of polarity or whose polarity is very small, to form a particulate aliphatic polyester; and a biodegradable aliphatic polyester melt-extrusion film, which comprises the biodegradable aliphatic polyester having a weight average molecular weight of 20,000 to 2,000,000, and having a water vapor transmission rate of 300 to 700 g/m.sup.2 .multidot.24 hours.multidot.25 .mu.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: July 21, 1998
    Assignee: Tokuyama Corporation
    Inventors: Haruo Nishida, Mitsuhiro Yamashita, Norikazu Hattori, Yoshiki Ochi, Tetsuo Kuwaki
  • Patent number: 5759569
    Abstract: Biodegradable articles such as diaper topsheets, diaper backsheets, garbage bags, tampon applicators, disposable syringes and the like that are made from trans-1,4-polyisoprene and like trans-polymers. These articles can also be made from blends of these trans-polymers with other biodegradable components such as starch.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: June 2, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Bryn Hird, John Collins Dyer, David Harry Melik
  • Patent number: 5691015
    Abstract: A composite film bag 1 for packaging comprises a composite film of a water-insoluble film 2 and a water-soluble polyvinyl alcohol film 3 which are adhered to one another to such an extent that the former film 2 can easily be peeled off from the latter film 3 and which are formed into a bag so that the water-insoluble film 2 serves as an outer layer of the bag and the water-soluble polyvinyl alcohol film 3 serves as an internal layer thereof. A powdery or liquid agricultural chemical agent 6 is packed in the composite film bag 1 and the opening of the bag is sealed. Upon practical use, the outer water-insoluble film 2 is peeled off to expose the internal film 3 and the internal film 3 as such, while containing the agricultural chemical agent 6, is introduced into water. Thus, the internal film is dissolved in water and in turn the content 6 thereof is released and accordingly dissolved in water. The composite film bag 1 is not broken at all even when it is exposed to a low temperature condition.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: November 25, 1997
    Assignee: Aicello Chemical Co., Ltd.
    Inventors: Yoshinori Tsukamoto, Michio Shimizu
  • Patent number: 5296282
    Abstract: Shaped articles having a substrate of a degradable synthetic polymeric material and a discontinuous liquid repellant hydrophobic and/or oleophobic surface layer.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: March 22, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Glenn R. Evers
  • Patent number: 5294469
    Abstract: A thermoplastic polymer composition primarily comprising polylactic acid or a copolymer of lactic acids and the other hydroxycarboxylic acids than lactic acids, industrial fabrics which can be degraded into nontoxic water and carbon dioxide within a relatively short period under the natural environment, and flexible containers, water shielding sheets and resin coated-cloth ventilation tubes which are prepared from the industrial fabrics.
    Type: Grant
    Filed: June 16, 1993
    Date of Patent: March 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kazuhika Suzuki, Takayuki Watanabe, Yasuhiro Kitahara, Masanobu Ajioka
  • Patent number: 5273476
    Abstract: A toy whose entertainment value is altered when placed in water includes an outer package dissolvable in water which has an inner, sealed compartment to hide at least one novelty item therein. The outer package is comprised of a water soluble material which is sufficiently opaque to preclude visual inspection of any item disposed within the compartment, and in the preferred embodiment, is comprised of two sheets of such a material bonded together about their peripheral edge by a water soluble binding agent. The package has an outer peripheral edge or silhouette, generally corresponds in shape to the object, character, animal, animate or inanimate, etc., which is depicted on either or both exterior surfaces of the package. The novelty item(s) held within the compartment are made from a material, such as plastic, metal, etc., which is non-expandable when the package is placed in water.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: December 28, 1993
    Inventor: Alan Dorfman
  • Patent number: 5205473
    Abstract: Corrugated beverage containers and holders are which employ recyclable materials, but provide fluting structures for containing insulating air. These products are easy to hold and have a lesser impact on the environment than polystyrene containers.
    Type: Grant
    Filed: March 19, 1992
    Date of Patent: April 27, 1993
    Assignee: Design By Us Company
    Inventor: David W. Coffin, Sr.
  • Patent number: 5186321
    Abstract: An improved paperboard multiple can carrier made of multilayered laminated paperboard which has at least two layers of recycled paper and two layers of virgin paper. Tearing of the paperboard is prevented by multiple indentations or notches circumferentially extending around the orifices through which cans and fingers are inserted.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: February 16, 1993
    Inventor: Richard F. Fadus
  • Patent number: 5171308
    Abstract: The invention provides novel polyesters, fibers and films, nonwovens from the fibers and disposable products of the polyesters such as diapers. The products are degradable under the conditions typically existing in waste composting processes, have low ingredient costs and yet provide strength and toughness properties adequate for end uses such as in disposable diapers. The polyesters are based upon polyethylene terephthalate copolymerized with a non-aromatic diacid, such as adipic and glutaric acids, and containing alkali metal or alkaline earth metal sulfo groups, such as a metal 5-sulfoisophthalic acid derivative.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: December 15, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Francis G. Gallagher, Cathy J. Hamilton, Steven M. Hansen, Hyunkook Shin, Raymond F. Tietz
  • Patent number: 5171309
    Abstract: The invention provides novel polyesters, fibers and films, nonwovens from the fibers and disposable products of the polyesters such as diapers. The products are degradable under the conditions typically existing in waste composting processes, have low ingredient costs and yet provide strength and toughness properties adequate for end uses such as in disposable diapers. The polyesters are based upon polyethylene terphthalate copolymerized with a cycloaliphatic diacid, preferably hexahydroterephthalic acid, and containing alkali metal or alkaline earth metal sulfo groups, such as a metal 5-sulfoisophthalic acid derivative.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: December 15, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Francis G. Gallagher, Cathy J. Hamilton, Steven M. Hansen, Hyunkook Shin, Raymond F. Tietz
  • Patent number: 5165535
    Abstract: In a conventional cigarette packet with an inner wrapping of tin foil and paper, at least one surface of the tin foil is treated with a photocorrosive substance to the end of enhancing its biodegradability.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: November 24, 1992
    Assignee: G.D. S.p.A.
    Inventors: Alberto Manservigi, Antonio Gamberini
  • Patent number: 5133683
    Abstract: A toy whose entertainment value is altered when placed in water includes an outer package dissolvable in water which has an inner, sealed compartment to hide at least one novelty item therein. The outer package is comprised of a water soluble material which is sufficiently opaque to preclude visual inspection of any item disposed within the compartment, and in the preferred embodiment, is comprised of two sheets of such a material bonded together about their peripheral edge by a water soluble binding agent. The package has an outer peripheral edge or silhouette, generally corresponds in shape to the object, character, animal, animate or inanimate, etc., which is depicted on either or both exterior surfaces of the package. The novelty item(s) held within the compartment are made from a material, such as plastic, metal, etc., which is non-expandable when the package is placed in water.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: July 28, 1992
    Inventor: Alan Dorfman
  • Patent number: 5111933
    Abstract: The present invention comprises a method of providing a polymeric based compost bag formed with a relatively high percentage of thermal oxidative degradation catalyst, such as a transition metal salt, and, preferably, a process stabilizer. The stabilizer permits the use of high levels of the thermal oxidative degradation catalyst without the risk of premature accelerated degradation during manufacturing and storing. According to the present invention, the compost bags are packaged in containers which are impervious to gases and vapors thus depriving the pro-oxidant of the oxygen necessary to degrade the polymer. The package may also provide a barrier to the loss of stabilizer during storage. Also disclosed is a kit for the disposal of waste.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: May 12, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Daniel J. Di Biasi, Frederick C. Schwab
  • Patent number: 5107989
    Abstract: A container for packaging electronic components which are susceptible to damage from electrostatic discharge or fields comprises a container made of paperboard or paper having an electrically conductive coating of electrostatic shielding material on the exterior surface thereof, and a coating of inorganic non-carbonaceous electrostatic dissipative material on the interior surface thereof. The electrically conductive coating preferably has an electrical surface resistivity of less than about 10.sup.5 ohms/square, and the inorganic, non-carbonaceous, electrostatic dissipative coating has an electrical surface resistivity of greater than about 10.sup.5 ohms/square. The electrostatic shielding material is preferably a carbonaceous material, and the non-carbonaceous, electrostatic dissipative material preferably comprises particles of amorphous silica or silica-containing material coated with antimony-doped tin oxide.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: April 28, 1992
    Assignee: Conductive Containers, Inc.
    Inventor: Raymond P. Becker
  • Patent number: 5108677
    Abstract: The method includes the steps of mixing the sand and the decomposable binder to form a dough-like consistency, forming the dough-like mixture into a sheet. Cutting the sheet into silhouette shapes and then drying the shapes to form a rigid article suitable for a variety of purposes. The preferred article is coated with a decomposable waterproof sealant. Method of forming planar frangible targets as well as formed three-dimensionsl tableware and food containers are disclosed.
    Type: Grant
    Filed: May 1, 1990
    Date of Patent: April 28, 1992
    Inventor: John Ayres
  • Patent number: 5063111
    Abstract: A degradable bottle and can carrier comprising a body having a plurality of openings for receiving the bottles or cans. The body is made of a plastic material which is degradable upon exposure to ultraviolet radiation. A water soluble ultraviolet absorber is applied to the exposed surface of the carrier such that the carrier is protected from degrading under ultraviolet radiation until such time that the carrier is discarded and becomes wet by rainfall, water or snow.
    Type: Grant
    Filed: February 5, 1990
    Date of Patent: November 5, 1991
    Assignee: Owens-Illinois Plastic Products Inc.
    Inventor: Louis M. DiBello
  • Patent number: 4793474
    Abstract: A capsule for the controlled release of an active material, e.g. into soil, is described. The capsule comprises an insoluble tubular housing (11) containing a number of water soluble or biodegradable partition walls (13) defining one or more hermetically sealed compartments, (12) filled with the active material (14), e.g. an insecticide. When the capsule is in contact with water or an aqueous medium the partition walls (13) slowly dissolve or degrade thus releasing the active material after a predetermined delay.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: December 27, 1988
    Assignee: International Standard Electric Corporation
    Inventor: Cyril F. Drake
  • Patent number: 4709808
    Abstract: A group of degradable polymer compositions including admixtures of ethylene-carbon monoxide copolymer with defined proportions of high density polyethylene, linear low density polyethylene or polypropylene is disclosed. The compositions are useful for forming article carriers, containers, closures, foodtrays and the like, which show excellent mechanical and structural properties and controlled environmental degradability.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: December 1, 1987
    Assignee: Owens-Illinois Plastic Products Inc.
    Inventors: Dennis C. Balduff, Saleh A. Jabarin
  • Patent number: 4552484
    Abstract: This invention is a system for field disposal of human feces through the use of composting containers that prevent the spread of intestinal bacteria, including virulent pathogens, which otherwise would occur when wilderness visitors practice shallow burial of feces. This is accomplished by providing biodegradable containers and following a pre-set method of disposal.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: November 12, 1985
    Inventor: David A. Nuttle
  • Patent number: 4525100
    Abstract: There is disclosed a system for transportation of materials such as industrial wastes from a source thereof to a temporary storage and/or a permanent disposal site or the like, utilizing batch containers of maximum space-saving configurations and taking advantage of the fact that such waste materials invariably densify volume-wise during handling such as during transit from the source to the storage facility. The containers of the invention are of temporarily shape-competent fiberboard type construction or the like; but are in any case fabricated of material which is moisture-vulnerable, whereby subsequent to transport and disposal thereof they soften down and allow the contents of contiguous containers to spread out and settle down and thereby close any previously existing empty spaces therebetween.
    Type: Grant
    Filed: February 23, 1983
    Date of Patent: June 25, 1985
    Assignee: Cecos International, Inc.
    Inventors: Stanley C. Zawadzki, Jr., Robert A. Stadelmaier, John J. Perrone
  • Patent number: 4347686
    Abstract: A fin-stabilized container formed from foldable sheet material, particularly suited for aerial planting of seeds or seedlings. A cone or pyramid of sheet material is folded so as to form three or more fins at the trailing end and closure means for a container cavity at the forward end.
    Type: Grant
    Filed: June 28, 1978
    Date of Patent: September 7, 1982
    Assignee: Canadian Patents & Development Limited
    Inventor: Arthur D. Wood
  • Patent number: 4334614
    Abstract: Water-soluble wind stabilization segments are used to stabilize the winding of coils wound in a figure-8 configuration with a radial opening provided on the side of the winding such that the winding may be unwound from the inside out. The water-soluble stabilization segments dissolve when the winding is immersed in water, thereby obviating the need to physically remove such stabilization segments prior to unwinding the wound package.
    Type: Grant
    Filed: October 15, 1980
    Date of Patent: June 15, 1982
    Assignee: Windings, Inc.
    Inventor: Ronald E. Zajac
  • Patent number: 4333516
    Abstract: A corrodible container for the storage of a corrosion inhibitor to be suitably located in the coolant system of an automotive vehicle or other environment wherein the container has at least a portion thereof formed of substantially the same material as the material forming the heat exchange device in a coolant system so as to corrode when the coolant is partially or wholly replaced by a corrosive liquid such as water. More specifically, an aluminum radiator has a tendency to corrode rapidly where corrosive water is present and the container for the corrosion inhibitor has at least a portion thereof formed of aluminum foil or aluminum sheet material with a thinner portion so that the foil or thinner portion will corrode through to release the corrosion inhibitor into the coolant to minimize corrosion of the heat exchanger and coolant system.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: June 8, 1982
    Assignee: Borg-Warner Corporation
    Inventors: Robert H. Krueger, Clarence E. Albertson, Bruce P. Miglin
  • Patent number: 4275813
    Abstract: A coherent surgical-staple stack comprising a plurality of staples, bonded together in a parallel contiguous relationship by a biodegradable, absorbable plastic.
    Type: Grant
    Filed: June 4, 1979
    Date of Patent: June 30, 1981
    Assignee: United States Surgical Corporation
    Inventor: Douglas G. Noiles
  • Patent number: 4224416
    Abstract: There is disclosed an environmentally degradable plastic composition comprising an organic polymeric material having dispersed therein at least one amine compound as a readily autoxidizable organic substance.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: September 23, 1980
    Assignee: Owens-Illinois, Inc.
    Inventors: Lynn J. Taylor, John W. Tobias
  • Patent number: 4191320
    Abstract: There is disclosed a degradable article made from photodegradable polymeric or plastic compositions comprising at least one organic polymer or copolymer and at least two different aromatic carbonyl photosensitizers.
    Type: Grant
    Filed: September 27, 1977
    Date of Patent: March 4, 1980
    Assignee: Owens-Illinois, Inc.
    Inventors: Lynn J. Taylor, John W. Tobias
  • Patent number: 4136798
    Abstract: A bag constructed of biodegradable material in the form of high dry-strength and no wet-strength paper combined with water-soluble plastic material laminated to a portion of the exterior of the bag. The bag is of a size to receive a bedpan as specifically disclosed but it may also be of a size to receive an emesis pan or the like when inserted therein with the bag completely enclosing the pan to maintain the aseptic characteristics of a sterile pan by completely preventing any possible contact between the pan and the patient or excreta from a patient thereby eliminating the necessity of cleaning and sterilizing bedpans, emesis pans and the like which results in substantial saving of time, labor and cost of caring for a patient. The bag, after use, is easily separated from the pan and flushed into the sewer system through a conventional commode with the water soluble plastic being dissolved by the flushing water and the paper becoming disintegrated so that the plumbing system will not become clogged.
    Type: Grant
    Filed: August 16, 1976
    Date of Patent: January 30, 1979
    Inventor: Nathan Oberstein
  • Patent number: 4008544
    Abstract: A plastic container for planting tree seedlings in a mechanized process, and being in the shape of a projectile suitable for penetration into soil. The planting container is highly oriented in its longitudinal direction with a number of longitudinal grooves positioned on the inside, outside or both sides thereof. The grooves include slits and holes to permit drainage, egress of growing roots, and aiding in the self-destruction of the container after being injected into the ground with a seedling. The self-destruction can be further promoted by the use of stress cracking agents within the plastic material comprising the planting container.
    Type: Grant
    Filed: September 8, 1975
    Date of Patent: February 22, 1977
    Assignee: The Dow Chemical Company
    Inventors: Walter E. F. Rupprecht, Eckel R. Lane, Joseph W. Rakshys, Jr.
  • Patent number: 3938695
    Abstract: A closure lid for capping the open top of a container. The container is of a type adapted to receive a potable liquid, usually one which is dispensed within a relatively close distance of the point at which it will be imbibed. Such containers with the closure lids emplaced thereon are used for "carry-out" services, as from a luncheonette, or for "carry-about" services, as from an on-the-premises beverage source such as a coffee brewer, a milk container, a carbonated or non-carbonated liquid vessel or a supply of hot water for tea or chocolate. It is customary to cap such containers with closure lids for carry-out purposes and to remove the lids when the potable is to be consumed; indeed it is quite usual to supply lids with the containers -- although not attached -- when the containers are sold to carry-out stores and to on-the-premises facilities where there are a large number of persons.
    Type: Grant
    Filed: January 18, 1974
    Date of Patent: February 17, 1976
    Inventor: Stanley Ruff
  • Patent number: 3932319
    Abstract: Novel blends comprising biodegradable thermoplastic dialkanoyl polymer, e.g., poly(alkylene adipate), and additional material such as naturally occurring biodegradable product, e.g., tree bark; and to the novel shaped articles therefrom. In one aspect, the invention is directed to novel shaped containers fabricated from material comprising biodegradable thermoplastic dialkanoyl polymer, said containers possessing a germination medium, and optionally, a seed or seedling in such medium.
    Type: Grant
    Filed: July 15, 1974
    Date of Patent: January 13, 1976
    Assignee: Union Carbide Corporation
    Inventors: Robert A. Clendinning, James E. Potts, Walter D. Niegisch
  • Patent number: 3931068
    Abstract: Blends comprising biodegradable thermoplastic oxyalkanoyl polymer, e.g., epsilon-caprolactone polymer, and naturally occurring biodegradable product, e.g., tree bark. These novel blends are useful in the production of shaped articles such as mulch film, transplanter containers, package containers, and the like.
    Type: Grant
    Filed: July 15, 1974
    Date of Patent: January 6, 1976
    Assignee: Union Carbide Corporation
    Inventors: Robert A. Clendinning, James E. Potts, Walter D. Niegisch