Reactant Contains Phosphorus, Silicon, Or Sulfur Atom, Or Contains Metal-to-carbon Bond Patents (Class 252/182.3)
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Patent number: 7312297Abstract: A treatment composition for making acquisition fluff pulp in sheet form, having a cross-linking agent and an anti-hydrogen-bonding agent. The cross-linking agent may be a polycarboxylic acid, aldehyde, urea-based derivatives or a mixture thereof. The anti-hydrogen-bonding agent may be a silicon polymer terminated with at least one quaternary amine functional group. A method of making acquisition fluff pulp using the treatment composition involves treating a cellulosic base fiber with a treatment composition solution to impregnate the fiber with the treatment composition, and then drying and curing the impregnated fiber. The resultant acquisition fluff pulp may be utilized in an acquisition layer and/or an absorbent core of an absorbent article intended for body waste management.Type: GrantFiled: February 16, 2005Date of Patent: December 25, 2007Assignee: Rayonier TRS Holdings, Inc.Inventor: Othman A. Hamed
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Publication number: 20070272894Abstract: Tetraaromatic diamine compounds having the general formula: are provided wherein a is 0-3; b, c and d independently are integers from 0-5, R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a substituted or unsubstituted C3 to about C30 ring, saturated, partially unsaturated or fully unsaturated, optionally substituted with one or more heteroatoms, a is 0-3; b, c and d independently are integers from 0-5, R3, R4, R5 and R6 are independently hydrogen, a straight or branched C1-C30 alkyl or alkylene group optionally substituted with one or more substituents, a substituted or unsubstituted C3-C12 cycloalkyl, a substituted or unsubstituted C5-C25 aryl, a substituted or unsubstituted C6-C25 arylalkyl, a straight or branched C1-C30 alkoxy group optionally substituted with one or more substituents or two R4 substituents and/or two R5 substituents and/or two R6 substituents on adjacent carbon atoms of the aromatic ring associated therewith can be joined together to formType: ApplicationFiled: February 13, 2007Publication date: November 29, 2007Inventor: Qinggao Ma
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Patent number: 7173180Abstract: A silane composition for preparing a semiconductor thin films of a solar cell is disclosed. The silane composition contains a polysilane compound represented by the formula SinRm (n is an integer of 3 or more, m is an integer of n to (2n+2) and an m number of R's are each independently a hydrogen atom, alkyl group, phenyl group or halogen atom, with the proviso that when all the m number of R's are hydrogen atoms and m=2n, n is an integer of 7 or more), and at least one silane compound selected from cyclopentasilane, cyclohexasilane and silylcyclopentasilane.Type: GrantFiled: April 17, 2006Date of Patent: February 6, 2007Assignee: JSR CorporationInventors: Hiroshi Shiho, Hitoshi Kato
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Patent number: 7067069Abstract: A silane composition for preparing a semiconductor thin films of a solar cell is disclosed. The silane composition contains a polysilane compound represented by the formula SinRm (n is an integer of 3 or more, m is an integer of n to (2n+2) and an m number of R's are each independently a hydrogen atom, alkyl group, phenyl group or halogen atom, with the proviso that when all the m number of R's are hydrogen atoms and m=2n, n is an integer of 7 or more), and at least one silane compound selected from cyclopentasilane, cyclohexasilane and silylcyclopentasilane.Type: GrantFiled: August 13, 2002Date of Patent: June 27, 2006Assignee: JSR CorporationInventors: Hiroshi Shiho, Hitoshi Kato
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Patent number: 7012148Abstract: Compositions and methods for using these compositions to produce high yields of thionated compounds are provided.Type: GrantFiled: September 25, 2001Date of Patent: March 14, 2006Assignee: Trustees of Dartmouth CollegeInventor: Thomas J. Curphey
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Patent number: 7005083Abstract: A process for preparing alkyllithium compounds by reacting a sodium-lithium alloy with alkyl halides at temperatures of about 50 to 125° C.Type: GrantFiled: August 8, 2001Date of Patent: February 28, 2006Assignee: SQM Lithium Specialties Limited Partnership, LLPInventors: Carlos F. Nakousi, Thomas R. Currin, Jr.
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Patent number: 6994800Abstract: Volatile liquid precursors are provided for use in the formation of alkali metal-containing materials. The compound includes an alkali metal and an amide ligand and is a liquid at a temperature of less than about 70° C.Type: GrantFiled: April 28, 2000Date of Patent: February 7, 2006Assignee: President and Fellows of Harvard CollegeInventors: Roy G. Gordon, Randy N. R. Broomhall-Dillard
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Patent number: 6936184Abstract: A conductive member for OA equipment (electrophotographic apparatus or electrostatic recording apparatus) which is obtainable from a composition comprising a non-ether-based polyurethane, carbon black and bis(trifluoromethanesulfonyl)imidolithium. The conductive member shows very stable conductivity in the volume resistivity range of 105 to 1012 ?·cm, the conductivity of which is less dependent on the voltage applied and varies only slightly during continuous energization and upon changes in environmental factors such as temperature and humidity.Type: GrantFiled: April 22, 2002Date of Patent: August 30, 2005Assignee: Bando Chemical Industries, Ltd.Inventors: Takahiko Okazaki, Makoto Hasegawa, Takashi Miki, Takayuki Nagase, Hiroyuki Inai
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Patent number: 6878310Abstract: A stabilizer composition, suitable for use in polyvinyl chloride compositions, can be formed by reacting a mixture of monoalkyltin trichloride, such as butyltin trichloride, and dialkyltin dichloride, such as dibutyltin dichloride, with at least one carboxylic acid, such as 2-ethylhexanoic acid, and 2-mercaptoethanol, in the presence of base, followed by reaction of the resulting product with a sulfide reagent, such as sodium sulfide. The final composition comprises a complex mixture of alkyl tin carboxylates and/or mercaptides, and of monoalkyltin sulfides and dialkyltin sulfides.Type: GrantFiled: November 27, 2001Date of Patent: April 12, 2005Assignee: Akzo Nobel N.V.Inventor: Henry J. Barda
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Patent number: 6861011Abstract: Methyllithium is prepared by reacting chloromethane with a dispersion lithium metal in an aromatic organic solvent with methyltetrahydrofuran.Type: GrantFiled: November 7, 2003Date of Patent: March 1, 2005Assignee: Chemetall Foote CorporationInventors: Mark J. Hintze, Jing Q. Wen
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Publication number: 20040227127Abstract: Silica surfaces are contacted with compositions containing organosilicon compounds to prepare modified silica fillers. The compositions contain only organosilicon compounds which are monomeric dichlorosilanes and trialkoxysilanes. The treating compositions may be (i) mixtures or blends of dialkyldichlorosilanes, and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces, or (ii) mixtures or blends of substituted dialkyldichlorosilanes in which the substituted dialkyldichlorosilanes are free of hydrocarbon or organofunctional groups reactive with silica surfaces, and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces. These mixtures and blends contain dialkyldichlorosilanes and trialkoxysilanes in a weight ratio of 1:0.1 to 1:2, respectively.Type: ApplicationFiled: June 22, 2004Publication date: November 18, 2004Inventors: Lisa Marie Boswell, Csilla Kollar, Anthony Revis, Anil Kumar Tomar
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Patent number: 6787067Abstract: The present invention provides a multi-component granular additive for polyolefins which has a strength and a function which enable the additive to be dust-free and be of components-in-granule type. It comprises 10 parts by mass of a nucleating agent comprising an alkali metal salt or hydroxyaluminum salt of an aromatic monocarboxlylic acid or comprising an alkali metal salt or hydroxyaluminum salt of an acid aromatic phosphoric ester compound, 1 to 50 parts by mass of a phenolic antioxidant, 5 to 50 parts by mass of polyproylene, and 0 to 500 parts by mass of one or more optional additive components other than the nucleating agent and the phenolic antioxidant.Type: GrantFiled: August 16, 2002Date of Patent: September 7, 2004Assignee: Asahi Denka Kogyo K.K.Inventors: Toshinori Yukino, Takashi Takeuchi, Naoko Tanji, Etsuo Tobita
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Patent number: 6761832Abstract: This invention relates to a process for the production of dithiophosphoric acid poly-sulfide mixtures, which is characterized in that dithiophosphoric acid disulfides are reacted with sulfur at elevated temperatures. The dithiophosphoric acid polysulfide mixtures produced using the process according to the present invention are used as sulfur donors for the vulcanization of natural and synthetic rubbers and in the latex vulcanization of natural and synthetic rubber latex.Type: GrantFiled: February 10, 2000Date of Patent: July 13, 2004Assignee: Rhein Chemie Rheinau GmbHInventors: Ludger Heiliger, Alfred Pauli, Joachim Hegmann, Clemens Schudok, Thomas Früh
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Patent number: 6743764Abstract: This invention addresses methods and compositions for providing alkyl diphenyl oxide sulfonic acid blends at useful viscosities for use in surfactants such as DOWFAX-containing surfactants. The low viscosity alkyl diphenyl oxide sulfonic acid blend is made by admixing a fatty acid having a carboxylic chain length between 1 and 12 (e.g., formic acid, acetic acid, propionic acid, butanoic acid, pentanoic acid, valeric acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, or dodecanoic acid into an alkyl diphenyl oxide sulfonic acid reaction product to provide between about 5 weight percentage and about 50 weight percentage of fatty acid in the admixture.Type: GrantFiled: June 30, 2000Date of Patent: June 1, 2004Assignee: Dow Global Technologies Inc.Inventors: David E. Wallick, Timothy J. Gallagher
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Patent number: 6686489Abstract: A liquid precursor for forming a transparent metal oxide thin film comprises a first organic precursor compound. In one embodiment, the liquid precursor is for making a conductive thin film. In this embodiment, the liquid precursor contains a first metal from the group including tin, antimony, and indium dissolved in an organic solvent. The liquid precursor preferably comprises a second organic precursor compound containing a second metal from the same group. Also, the liquid precursor preferably comprises an organic dopant precursor compound containing a metal selected from the group including niobium, tantalum, bismuth, cerium, yttrium, titanium, zirconium, hafnium, silicon, aluminum, zinc and magnesium. Liquid precursors containing a plurality of metals have a longer shelf life. The addition of an organic dopant precursor compound containing a metal, such as niobium, tantalum or bismuth, to the liquid precursor enhances control of the conductivity of the resulting transparent conductor.Type: GrantFiled: November 9, 2001Date of Patent: February 3, 2004Assignee: Symetrix CorporationInventors: Jolanta Celinska, Carlos A. Paz de Araujo, Joseph D. Cuchiaro, Jeffrey W. Bacon, Larry D. McMillan
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Patent number: 6677268Abstract: An improved catalyst based on cobalt and/or rhodium dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion.Type: GrantFiled: July 12, 2002Date of Patent: January 13, 2004Assignee: Institut Francais du PetroleInventors: Gerhard Hillebrand, Andre Hirschauer, Dominique Commereuc, Helene Olivier-Bourbigou, Lucien Saussine
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Treated mineral fillers suspensions of these fillers in polyols and their uses in polyurethane foams
Patent number: 6545059Abstract: Method for the treatment of mineral fillers using organic phosphate treatment agents. Treated mineral fillers obtained by said method and suspension of these treated mineral fillers in polyols. Use of these suspensions in the manufacture of flexible, semirigid, or rigid polyurethane foams used for the manufacture of molded or nonmolded objects.Type: GrantFiled: June 22, 1999Date of Patent: April 8, 2003Assignee: Omya S.A.Inventors: Jean-Pierre Fichou, Maurice Husson, Georges Ravet, Pierre Blanchard -
Patent number: 6495708Abstract: The present invention relates to novel aluminosiloxane compounds which have the characteristics to be prepared from waste silicone compounds and to be advantageously used as siloxylating agent for various organic and inorganic materials, processes for preparation thereof, and uses thereof.Type: GrantFiled: February 14, 2001Date of Patent: December 17, 2002Inventors: Jae-Kun Yang, Jeong-Ryeon Han
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Patent number: 6482483Abstract: A composition comprising tris(hydroxymethyl)phosphine or phosphorus-containing salts or condensates of those salts with nitrogen-containing compounds coated or absorbed onto a solid or porous substrate is disclosed. The salts or condensates are based on tetrakis(hydroxymethyl)phosphonium salts. The substrate has a melting point greater than 70° C. and is an optionally hydroxyl-substituted di- or polycarboxylic acid. The compositions may be used with water soluble film forming polymers to make sachets or bags containing sachets or bags of these phosphorous-containing compositions along with sachets or bags of compositions that are incompatible with these phosphorous-containing compositions.Type: GrantFiled: April 3, 2000Date of Patent: November 19, 2002Assignee: Rhodia Consumer Specialties LimitedInventors: Stephen David Fidoe, Christopher David Imrie, Christopher Raymond Jones, Robert Eric Talbot
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Patent number: 6399820Abstract: The present invention relates to a process and a reagent useful for the synthesis of sulphanilide which is perhalogenated on the carbon borne by the sulphur atom of the sulphanilide function. This persulphonylation process is characterized in that it comprises a step of placing a nucleophile, whose nucleophilic atom is a nitrogen, in contact with a reagent comprising, for successive or simultaneous addition, a heavy halide of sulphonyl, advantageously sulphonyl chloride, and an organic base comprising a trivalent atom from column V whose lone pair is conjugated directly or indirectly to a bond, and in that the organic part of the said sulphonyl is perhalogenated, advantageously perfluorinated, on the carbon borne by the sulphur. Application to the synthesis of intermediates for organic chemistry.Type: GrantFiled: May 15, 2001Date of Patent: June 4, 2002Assignee: Rhodia ChimieInventors: Jean-Roger Desmurs, Andr{dot over (e)} Millet, Virginie Pevere
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Patent number: 6399821Abstract: The invention concerns a method of sulphonation characterised in that it consists in contacting a nucleophile whose nucleophilic atom is a nitrogen atom with a reagent comprising by successive or simultaneous addition: a heavy sulphonyl halide (i.e. whose atomic number is not less than that of chlorine), advantageously suphonyl chloride; and an organic base both not capable of alkylation and lipid soluble; and the organic part of said sulphonyl is perfluorinated on the carbon carried by the sulphur. The invention is applicable to organic synthesis.Type: GrantFiled: August 7, 2001Date of Patent: June 4, 2002Assignee: Rhodia ChimieInventors: Virginie Pevere, Emmanuel Marx, Laurent Gilbert
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Patent number: 6376691Abstract: A liquid precursor for forming a transparent metal oxide thin film comprises a first organic precursor compound. In one embodiment, the liquid precursor is for making a conductive thin film. In this embodiment, the liquid precursor contains a first metal from the group including tin, antimony, and indium dissolved in an organic solvent. The liquid precursor preferably comprises a second organic precursor compound containing a second metal from the same group. Also, the liquid precursor preferably comprises an organic dopant precursor compound containing a metal selected from the group including niobium, tantalum, bismuth, cerium, yttrium, titanium, zirconium, hafnium, silicon, aluminum, zinc and magnesium. Liquid precursors containing a plurality of metals have a longer shelf life. The addition of an organic dopant precursor compound containing a metal, such as niobium, tantalum or bismuth, to the liquid precursor enhances control of the conductivity of the resulting transparent conductor.Type: GrantFiled: September 1, 1999Date of Patent: April 23, 2002Assignee: Symetrix CorporationInventors: Jolanta Celinska, Carlos A. Paz de Araujo, Joseph D. Cuchiaro, Jeffrey W. Bacon, Larry D. McMillan
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Patent number: 6323378Abstract: A method and composition are disclosed for the oxidation of aromatic substrates in the presence of oxygen, a catalyst, a proton source, and a non-gaseous reductant. In a preferred embodiment, benzene is oxidized to phenol in the presence of oxygen, a vanadyl catalyst, trifluoroacetic acid as a proton source, and ferrocene as a reductant. The method is economical, safe, and amenable to commercial scale-up.Type: GrantFiled: January 16, 2001Date of Patent: November 27, 2001Assignee: General Electric CompanyInventor: Terence Michael Barnhart
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Publication number: 20010033814Abstract: The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.Type: ApplicationFiled: April 27, 2001Publication date: October 25, 2001Inventors: Valeriy Nicholiavich Romanovskiy, Igor V. Smirnov, Vasiliy A. Babain, Terry A. Todd, Ken N. Brewer
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Patent number: 6303810Abstract: The invention relates to a process for manufacturing bis-silyl ureas which consists in reacting urea and a disilazane in an aliphatic nitrile and most particularly in acetonitrile. The process of the present invention applies particularly to the manufacture of bis(trimethylsilyl)urea from urea and hexamethyldisilazane.Type: GrantFiled: June 8, 2000Date of Patent: October 16, 2001Assignee: AtofinaInventors: David Reeves, Christophe Ruppin, Gilles Drivon
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Patent number: 6300287Abstract: A parting agent for a copier toner is disclosed. The parting agent exhibits no loss of parting properties or generation of gel under high-temperature conditions near 200° C., and causes no problems with paper feed or the like. The parting agent is composed of a diorganopolysiloxane of the average unit formula: RaSiO4−a/2, where the R groups are the same or different and are substituted or unsubstituted monovalent hydrocarbon groups, with at least 50 mol % of the R groups being methyl groups, and 1.95 ≦a≦2.20. The diorganopolysiloxane has a viscosity of 10 to 100,000 centistokes at 25° C., and generates no more than 5 ppm (by weight) of formaldehyde per hour when kept at 200° C. in an air atmosphere.Type: GrantFiled: April 27, 2000Date of Patent: October 9, 2001Assignee: Dow Corning Toray Silicone Company, Ltd.Inventors: Hiroki Ishikawa, Tsutomu Naganawa, Isao Ona
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Publication number: 20010009942Abstract: A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 &mgr;m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.Type: ApplicationFiled: October 16, 1998Publication date: July 26, 2001Inventors: MITSUSHI MURATA, TSUNENORI TAKAHASHI, YUKIO KATO
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Patent number: 6231783Abstract: Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.Type: GrantFiled: November 13, 1996Date of Patent: May 15, 2001Assignee: Massachusetts Institute of TechnologyInventors: Linda K. Molnar, T. Alan Hatton, Stephen L. Buchwald