Reactant Contains Phosphorus, Silicon, Or Sulfur Atom, Or Contains Metal-to-carbon Bond Patents (Class 252/182.3)
  • Patent number: 7312297
    Abstract: A treatment composition for making acquisition fluff pulp in sheet form, having a cross-linking agent and an anti-hydrogen-bonding agent. The cross-linking agent may be a polycarboxylic acid, aldehyde, urea-based derivatives or a mixture thereof. The anti-hydrogen-bonding agent may be a silicon polymer terminated with at least one quaternary amine functional group. A method of making acquisition fluff pulp using the treatment composition involves treating a cellulosic base fiber with a treatment composition solution to impregnate the fiber with the treatment composition, and then drying and curing the impregnated fiber. The resultant acquisition fluff pulp may be utilized in an acquisition layer and/or an absorbent core of an absorbent article intended for body waste management.
    Type: Grant
    Filed: February 16, 2005
    Date of Patent: December 25, 2007
    Assignee: Rayonier TRS Holdings, Inc.
    Inventor: Othman A. Hamed
  • Publication number: 20070272894
    Abstract: Tetraaromatic diamine compounds having the general formula: are provided wherein a is 0-3; b, c and d independently are integers from 0-5, R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a substituted or unsubstituted C3 to about C30 ring, saturated, partially unsaturated or fully unsaturated, optionally substituted with one or more heteroatoms, a is 0-3; b, c and d independently are integers from 0-5, R3, R4, R5 and R6 are independently hydrogen, a straight or branched C1-C30 alkyl or alkylene group optionally substituted with one or more substituents, a substituted or unsubstituted C3-C12 cycloalkyl, a substituted or unsubstituted C5-C25 aryl, a substituted or unsubstituted C6-C25 arylalkyl, a straight or branched C1-C30 alkoxy group optionally substituted with one or more substituents or two R4 substituents and/or two R5 substituents and/or two R6 substituents on adjacent carbon atoms of the aromatic ring associated therewith can be joined together to form
    Type: Application
    Filed: February 13, 2007
    Publication date: November 29, 2007
    Inventor: Qinggao Ma
  • Patent number: 7173180
    Abstract: A silane composition for preparing a semiconductor thin films of a solar cell is disclosed. The silane composition contains a polysilane compound represented by the formula SinRm (n is an integer of 3 or more, m is an integer of n to (2n+2) and an m number of R's are each independently a hydrogen atom, alkyl group, phenyl group or halogen atom, with the proviso that when all the m number of R's are hydrogen atoms and m=2n, n is an integer of 7 or more), and at least one silane compound selected from cyclopentasilane, cyclohexasilane and silylcyclopentasilane.
    Type: Grant
    Filed: April 17, 2006
    Date of Patent: February 6, 2007
    Assignee: JSR Corporation
    Inventors: Hiroshi Shiho, Hitoshi Kato
  • Patent number: 7067069
    Abstract: A silane composition for preparing a semiconductor thin films of a solar cell is disclosed. The silane composition contains a polysilane compound represented by the formula SinRm (n is an integer of 3 or more, m is an integer of n to (2n+2) and an m number of R's are each independently a hydrogen atom, alkyl group, phenyl group or halogen atom, with the proviso that when all the m number of R's are hydrogen atoms and m=2n, n is an integer of 7 or more), and at least one silane compound selected from cyclopentasilane, cyclohexasilane and silylcyclopentasilane.
    Type: Grant
    Filed: August 13, 2002
    Date of Patent: June 27, 2006
    Assignee: JSR Corporation
    Inventors: Hiroshi Shiho, Hitoshi Kato
  • Patent number: 7012148
    Abstract: Compositions and methods for using these compositions to produce high yields of thionated compounds are provided.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: March 14, 2006
    Assignee: Trustees of Dartmouth College
    Inventor: Thomas J. Curphey
  • Patent number: 7005083
    Abstract: A process for preparing alkyllithium compounds by reacting a sodium-lithium alloy with alkyl halides at temperatures of about 50 to 125° C.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: February 28, 2006
    Assignee: SQM Lithium Specialties Limited Partnership, LLP
    Inventors: Carlos F. Nakousi, Thomas R. Currin, Jr.
  • Patent number: 6994800
    Abstract: Volatile liquid precursors are provided for use in the formation of alkali metal-containing materials. The compound includes an alkali metal and an amide ligand and is a liquid at a temperature of less than about 70° C.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: February 7, 2006
    Assignee: President and Fellows of Harvard College
    Inventors: Roy G. Gordon, Randy N. R. Broomhall-Dillard
  • Patent number: 6936184
    Abstract: A conductive member for OA equipment (electrophotographic apparatus or electrostatic recording apparatus) which is obtainable from a composition comprising a non-ether-based polyurethane, carbon black and bis(trifluoromethanesulfonyl)imidolithium. The conductive member shows very stable conductivity in the volume resistivity range of 105 to 1012 ?·cm, the conductivity of which is less dependent on the voltage applied and varies only slightly during continuous energization and upon changes in environmental factors such as temperature and humidity.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: August 30, 2005
    Assignee: Bando Chemical Industries, Ltd.
    Inventors: Takahiko Okazaki, Makoto Hasegawa, Takashi Miki, Takayuki Nagase, Hiroyuki Inai
  • Patent number: 6878310
    Abstract: A stabilizer composition, suitable for use in polyvinyl chloride compositions, can be formed by reacting a mixture of monoalkyltin trichloride, such as butyltin trichloride, and dialkyltin dichloride, such as dibutyltin dichloride, with at least one carboxylic acid, such as 2-ethylhexanoic acid, and 2-mercaptoethanol, in the presence of base, followed by reaction of the resulting product with a sulfide reagent, such as sodium sulfide. The final composition comprises a complex mixture of alkyl tin carboxylates and/or mercaptides, and of monoalkyltin sulfides and dialkyltin sulfides.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: April 12, 2005
    Assignee: Akzo Nobel N.V.
    Inventor: Henry J. Barda
  • Patent number: 6861011
    Abstract: Methyllithium is prepared by reacting chloromethane with a dispersion lithium metal in an aromatic organic solvent with methyltetrahydrofuran.
    Type: Grant
    Filed: November 7, 2003
    Date of Patent: March 1, 2005
    Assignee: Chemetall Foote Corporation
    Inventors: Mark J. Hintze, Jing Q. Wen
  • Publication number: 20040227127
    Abstract: Silica surfaces are contacted with compositions containing organosilicon compounds to prepare modified silica fillers. The compositions contain only organosilicon compounds which are monomeric dichlorosilanes and trialkoxysilanes. The treating compositions may be (i) mixtures or blends of dialkyldichlorosilanes, and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces, or (ii) mixtures or blends of substituted dialkyldichlorosilanes in which the substituted dialkyldichlorosilanes are free of hydrocarbon or organofunctional groups reactive with silica surfaces, and trialkoxysilanes free of hydrocarbon or organofunctional groups reactive with silica surfaces. These mixtures and blends contain dialkyldichlorosilanes and trialkoxysilanes in a weight ratio of 1:0.1 to 1:2, respectively.
    Type: Application
    Filed: June 22, 2004
    Publication date: November 18, 2004
    Inventors: Lisa Marie Boswell, Csilla Kollar, Anthony Revis, Anil Kumar Tomar
  • Patent number: 6787067
    Abstract: The present invention provides a multi-component granular additive for polyolefins which has a strength and a function which enable the additive to be dust-free and be of components-in-granule type. It comprises 10 parts by mass of a nucleating agent comprising an alkali metal salt or hydroxyaluminum salt of an aromatic monocarboxlylic acid or comprising an alkali metal salt or hydroxyaluminum salt of an acid aromatic phosphoric ester compound, 1 to 50 parts by mass of a phenolic antioxidant, 5 to 50 parts by mass of polyproylene, and 0 to 500 parts by mass of one or more optional additive components other than the nucleating agent and the phenolic antioxidant.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: September 7, 2004
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Toshinori Yukino, Takashi Takeuchi, Naoko Tanji, Etsuo Tobita
  • Patent number: 6761832
    Abstract: This invention relates to a process for the production of dithiophosphoric acid poly-sulfide mixtures, which is characterized in that dithiophosphoric acid disulfides are reacted with sulfur at elevated temperatures. The dithiophosphoric acid polysulfide mixtures produced using the process according to the present invention are used as sulfur donors for the vulcanization of natural and synthetic rubbers and in the latex vulcanization of natural and synthetic rubber latex.
    Type: Grant
    Filed: February 10, 2000
    Date of Patent: July 13, 2004
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Ludger Heiliger, Alfred Pauli, Joachim Hegmann, Clemens Schudok, Thomas Früh
  • Patent number: 6743764
    Abstract: This invention addresses methods and compositions for providing alkyl diphenyl oxide sulfonic acid blends at useful viscosities for use in surfactants such as DOWFAX-containing surfactants. The low viscosity alkyl diphenyl oxide sulfonic acid blend is made by admixing a fatty acid having a carboxylic chain length between 1 and 12 (e.g., formic acid, acetic acid, propionic acid, butanoic acid, pentanoic acid, valeric acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, or dodecanoic acid into an alkyl diphenyl oxide sulfonic acid reaction product to provide between about 5 weight percentage and about 50 weight percentage of fatty acid in the admixture.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: June 1, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: David E. Wallick, Timothy J. Gallagher
  • Patent number: 6686489
    Abstract: A liquid precursor for forming a transparent metal oxide thin film comprises a first organic precursor compound. In one embodiment, the liquid precursor is for making a conductive thin film. In this embodiment, the liquid precursor contains a first metal from the group including tin, antimony, and indium dissolved in an organic solvent. The liquid precursor preferably comprises a second organic precursor compound containing a second metal from the same group. Also, the liquid precursor preferably comprises an organic dopant precursor compound containing a metal selected from the group including niobium, tantalum, bismuth, cerium, yttrium, titanium, zirconium, hafnium, silicon, aluminum, zinc and magnesium. Liquid precursors containing a plurality of metals have a longer shelf life. The addition of an organic dopant precursor compound containing a metal, such as niobium, tantalum or bismuth, to the liquid precursor enhances control of the conductivity of the resulting transparent conductor.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: February 3, 2004
    Assignee: Symetrix Corporation
    Inventors: Jolanta Celinska, Carlos A. Paz de Araujo, Joseph D. Cuchiaro, Jeffrey W. Bacon, Larry D. McMillan
  • Patent number: 6677268
    Abstract: An improved catalyst based on cobalt and/or rhodium dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: January 13, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Gerhard Hillebrand, Andre Hirschauer, Dominique Commereuc, Helene Olivier-Bourbigou, Lucien Saussine
  • Patent number: 6545059
    Abstract: Method for the treatment of mineral fillers using organic phosphate treatment agents. Treated mineral fillers obtained by said method and suspension of these treated mineral fillers in polyols. Use of these suspensions in the manufacture of flexible, semirigid, or rigid polyurethane foams used for the manufacture of molded or nonmolded objects.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: April 8, 2003
    Assignee: Omya S.A.
    Inventors: Jean-Pierre Fichou, Maurice Husson, Georges Ravet, Pierre Blanchard
  • Patent number: 6495708
    Abstract: The present invention relates to novel aluminosiloxane compounds which have the characteristics to be prepared from waste silicone compounds and to be advantageously used as siloxylating agent for various organic and inorganic materials, processes for preparation thereof, and uses thereof.
    Type: Grant
    Filed: February 14, 2001
    Date of Patent: December 17, 2002
    Inventors: Jae-Kun Yang, Jeong-Ryeon Han
  • Patent number: 6482483
    Abstract: A composition comprising tris(hydroxymethyl)phosphine or phosphorus-containing salts or condensates of those salts with nitrogen-containing compounds coated or absorbed onto a solid or porous substrate is disclosed. The salts or condensates are based on tetrakis(hydroxymethyl)phosphonium salts. The substrate has a melting point greater than 70° C. and is an optionally hydroxyl-substituted di- or polycarboxylic acid. The compositions may be used with water soluble film forming polymers to make sachets or bags containing sachets or bags of these phosphorous-containing compositions along with sachets or bags of compositions that are incompatible with these phosphorous-containing compositions.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: November 19, 2002
    Assignee: Rhodia Consumer Specialties Limited
    Inventors: Stephen David Fidoe, Christopher David Imrie, Christopher Raymond Jones, Robert Eric Talbot
  • Patent number: 6399820
    Abstract: The present invention relates to a process and a reagent useful for the synthesis of sulphanilide which is perhalogenated on the carbon borne by the sulphur atom of the sulphanilide function. This persulphonylation process is characterized in that it comprises a step of placing a nucleophile, whose nucleophilic atom is a nitrogen, in contact with a reagent comprising, for successive or simultaneous addition, a heavy halide of sulphonyl, advantageously sulphonyl chloride, and an organic base comprising a trivalent atom from column V whose lone pair is conjugated directly or indirectly to a bond, and in that the organic part of the said sulphonyl is perhalogenated, advantageously perfluorinated, on the carbon borne by the sulphur. Application to the synthesis of intermediates for organic chemistry.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: June 4, 2002
    Assignee: Rhodia Chimie
    Inventors: Jean-Roger Desmurs, Andr{dot over (e)} Millet, Virginie Pevere
  • Patent number: 6399821
    Abstract: The invention concerns a method of sulphonation characterised in that it consists in contacting a nucleophile whose nucleophilic atom is a nitrogen atom with a reagent comprising by successive or simultaneous addition: a heavy sulphonyl halide (i.e. whose atomic number is not less than that of chlorine), advantageously suphonyl chloride; and an organic base both not capable of alkylation and lipid soluble; and the organic part of said sulphonyl is perfluorinated on the carbon carried by the sulphur. The invention is applicable to organic synthesis.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: June 4, 2002
    Assignee: Rhodia Chimie
    Inventors: Virginie Pevere, Emmanuel Marx, Laurent Gilbert
  • Patent number: 6376691
    Abstract: A liquid precursor for forming a transparent metal oxide thin film comprises a first organic precursor compound. In one embodiment, the liquid precursor is for making a conductive thin film. In this embodiment, the liquid precursor contains a first metal from the group including tin, antimony, and indium dissolved in an organic solvent. The liquid precursor preferably comprises a second organic precursor compound containing a second metal from the same group. Also, the liquid precursor preferably comprises an organic dopant precursor compound containing a metal selected from the group including niobium, tantalum, bismuth, cerium, yttrium, titanium, zirconium, hafnium, silicon, aluminum, zinc and magnesium. Liquid precursors containing a plurality of metals have a longer shelf life. The addition of an organic dopant precursor compound containing a metal, such as niobium, tantalum or bismuth, to the liquid precursor enhances control of the conductivity of the resulting transparent conductor.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: April 23, 2002
    Assignee: Symetrix Corporation
    Inventors: Jolanta Celinska, Carlos A. Paz de Araujo, Joseph D. Cuchiaro, Jeffrey W. Bacon, Larry D. McMillan
  • Patent number: 6323378
    Abstract: A method and composition are disclosed for the oxidation of aromatic substrates in the presence of oxygen, a catalyst, a proton source, and a non-gaseous reductant. In a preferred embodiment, benzene is oxidized to phenol in the presence of oxygen, a vanadyl catalyst, trifluoroacetic acid as a proton source, and ferrocene as a reductant. The method is economical, safe, and amenable to commercial scale-up.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: November 27, 2001
    Assignee: General Electric Company
    Inventor: Terence Michael Barnhart
  • Publication number: 20010033814
    Abstract: The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.
    Type: Application
    Filed: April 27, 2001
    Publication date: October 25, 2001
    Inventors: Valeriy Nicholiavich Romanovskiy, Igor V. Smirnov, Vasiliy A. Babain, Terry A. Todd, Ken N. Brewer
  • Patent number: 6303810
    Abstract: The invention relates to a process for manufacturing bis-silyl ureas which consists in reacting urea and a disilazane in an aliphatic nitrile and most particularly in acetonitrile. The process of the present invention applies particularly to the manufacture of bis(trimethylsilyl)urea from urea and hexamethyldisilazane.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: October 16, 2001
    Assignee: Atofina
    Inventors: David Reeves, Christophe Ruppin, Gilles Drivon
  • Patent number: 6300287
    Abstract: A parting agent for a copier toner is disclosed. The parting agent exhibits no loss of parting properties or generation of gel under high-temperature conditions near 200° C., and causes no problems with paper feed or the like. The parting agent is composed of a diorganopolysiloxane of the average unit formula: RaSiO4−a/2, where the R groups are the same or different and are substituted or unsubstituted monovalent hydrocarbon groups, with at least 50 mol % of the R groups being methyl groups, and 1.95 ≦a≦2.20. The diorganopolysiloxane has a viscosity of 10 to 100,000 centistokes at 25° C., and generates no more than 5 ppm (by weight) of formaldehyde per hour when kept at 200° C. in an air atmosphere.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: October 9, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Hiroki Ishikawa, Tsutomu Naganawa, Isao Ona
  • Publication number: 20010009942
    Abstract: A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 &mgr;m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.
    Type: Application
    Filed: October 16, 1998
    Publication date: July 26, 2001
    Inventors: MITSUSHI MURATA, TSUNENORI TAKAHASHI, YUKIO KATO
  • Patent number: 6231783
    Abstract: Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: May 15, 2001
    Assignee: Massachusetts Institute of Technology
    Inventors: Linda K. Molnar, T. Alan Hatton, Stephen L. Buchwald