Benzene Rings Linked By Direct Bond Patents (Class 252/299.66)
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Patent number: 8968840Abstract: The present invention relates to a liquid-crystalline medium based on a mixture of polar compounds having negative dielectric anisotropy (??), which is distinguished by the fact that it has a value for the ratio ?1/?n2 in the range 6-45 with a clearing point of >60° C. and a ?? of ??2.3. Media of this type are particularly suitable for electro-optical displays having active-matrix addressing based on the ECB, PA LCD, FFS or IPS effect.Type: GrantFiled: June 28, 2011Date of Patent: March 3, 2015Assignee: Merck Patent GmbHInventors: Melanie Klasen-Memmer, Sabine Schoen
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Patent number: 8968597Abstract: A liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat or that is suitably balanced between at least two of the characteristics, is described. The liquid crystal composition includes a compound having three or more polymerizable groups as a first component and a compound having one or two polymerizable groups as a second component in a suitable ratio, and that may include a specific compound having a large negative dielectric anisotropy and a low minimum temperature as a third component or a specific compound having a small viscosity or a high maximum temperature as a fourth component.Type: GrantFiled: August 6, 2013Date of Patent: March 3, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshimasa Furusato, Subaru Kawasaki, Eriko Kurihara
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Publication number: 20150053891Abstract: A composition contains three or more compounds represented by general formula (i) below. (In the formula, Ri1 represents an alkyl group having 1 to 8 carbon atoms, and one or nonadjacent two or more —CH2— in the alkyl group may be each independently substituted by —CH?CH—, —C?C—, —O—, —CO—, —COO—, or —OCO—; mi1 represents 1 or 2; Ai1 represents a 1,4-cyclohexylene group or a 1,4-phenylene group which may have a fluorine atom or a chlorine atom substituted for a hydrogen atom, when mi1 represents 1, Ai1 represents a 1,4-phenylene group which may have a fluorine atom or a chlorine atom substituted for a hydrogen atom, and when mi1 represents 2 and a plurality of Ai1 are present, Ai1 may be the same or different, and Xi1 represents a hydrogen atom, a fluorine atom, or a chlorine atom.Type: ApplicationFiled: December 27, 2012Publication date: February 26, 2015Applicant: DIC CorporationInventors: Joji Kawamura, Makoto Negishi, Masahiro Niwa
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Patent number: 8962104Abstract: The present invention provides a liquid crystal display panel that suppresses the temperature dependence of transmittance-gradation characteristics and thus overcomes problems in which significant changes in transmittance-gradation characteristics are caused by the effects of environmental temperature and a light source to lead to the degradation of display performance, and a liquid crystal display device including the liquid crystal display panel. The liquid crystal display panel of the present invention includes a liquid crystal medium containing a plurality of liquid crystal compounds each having a negative dielectric constant anisotropy, the liquid crystal medium being held between a first substrate and a second substrate that are located opposite each other, and a side of each of the substrates in contact with the liquid crystal medium having vertical alignment properties for the liquid crystal compounds.Type: GrantFiled: September 13, 2011Date of Patent: February 24, 2015Assignees: Sharp Kabushiki Kaisha, DIC CorporationInventors: Toshihiro Matsumoto, Yuichi Kawahira, Masayuki Kanehiro, Shoutarou Kawakami, Gou Sudou
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Patent number: 8962105Abstract: To provide a liquid crystal composition satisfying at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of the nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, and so forth. To provide an AM device having a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The liquid crystal composition contains a specific compound having a polymerizable group as a first component and a specific compound having a large negative dielectric anisotropy and a low minimum temperature as a second component, and may contain a specific compound having a small viscosity or a large maximum temperature as a third component, and a liquid crystal display device includes the composition.Type: GrantFiled: November 2, 2011Date of Patent: February 24, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshimasa Furusato, Eriko Kurihara, Masayuki Saito
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Patent number: 8961823Abstract: The compound represented by formula (1). For example, the rings A1, A2, A3 and A4 are 1,4-phenylene, Z1 and Z2 are alkylene having 1 to 10 carbons in which at least one —CH2— may be replaced by —O— or —CH?CH—; L1, L2 and L3 are a single bond, —COO— or —CH?CH—; G1 and G2 are —O—; s, t and u are 0 or 1; and P1 and P2 is the group (P-1), the group (P-2) or the group (P-3). M1 and M2 are hydrogen or methyl.Type: GrantFiled: December 20, 2012Date of Patent: February 24, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yasuyuki Gotoh, Mayumi Goto
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Patent number: 8961824Abstract: To provide a liquid crystal composition satisfying at least one characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature thereof, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy and specific resistance, high stability to ultraviolet light and heat, or having a suitable balance regarding at least two of the characteristics; an AM device having short response time, a large voltage holding ratio and contrast ratio, and a long life. A liquid crystal composition has a nematic phase and contains a specific straight-chain compound as a first component and a specific compound having a large dielectric anisotropy as second component, and may contain a specific compound having a high maximum temperature or small viscosity as a third component and a specific compound having a high maximum temperature or large dielectric anisotropy as a fourth component, and a liquid crystal display device includes the composition.Type: GrantFiled: July 18, 2013Date of Patent: February 24, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takayoshi Yanai, Norikatsu Hattori, Hiroyuki Tanaka
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Patent number: 8962102Abstract: The invention relates to compounds of the formula I, and to a liquid-crystalline medium, preferably having a nematic phase and negative dielectric anisotropy, which comprises one or more compounds of formula I, defined herein, for use in an electro-optical display, particularly in an active-matrix display based on the VA, ECB, PALO, FFS or IPS effect, and to the use of the compounds of the formula I for the stabilization of a liquid-crystalline medium which comprises one or more compounds of the formula II and one or more compounds of the formulae III-1 to III-4, defined herein.Type: GrantFiled: April 20, 2012Date of Patent: February 24, 2015Assignee: MERCK PATENT GmbHInventors: Mark Goebel, Rocco Fortte, Detlef Pauluth
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Publication number: 20150048276Abstract: The invention relates to a liquid-crystalline medium comprising at least one compound of the formula I, in which R1 has the meanings indicated in Claim 1, and to the use thereof in liquid-crystalline media and in electro-optical liquid-crystal displays.Type: ApplicationFiled: August 13, 2014Publication date: February 19, 2015Applicant: Merck Patent GmbHInventors: Mark GOEBEL, Lars LIETZAU, Sabine SCHOEN, Andreas POHLE
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Patent number: 8956550Abstract: The present invention relates to a liquid-crystalline medium, characterized in that it contains a polymerizable component (A) containing one more polymerizable compounds and a liquid-crystalline component (B) containing one more compounds of the general formula I in which R, rings A1 and A2, Z1, Z2, Y1, Y2, X0 and r are as defined in Claim 1.Type: GrantFiled: August 20, 2013Date of Patent: February 17, 2015Assignee: Merck Patent GmbHInventors: Seung-Eun Lee, Eun Young Kim, Dong-Mee Song, Kyung-Ah Park, Sang-Hyun Park, Eun-Kyu Lee
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Patent number: 8956705Abstract: A system having a ferroelectric liquid host material and a small amount of polymer additive is provided. In an embodiment, the polymer additive improves the physical characteristics of the system. In an embodiment, the system can be used in FLC applications.Type: GrantFiled: January 28, 2010Date of Patent: February 17, 2015Assignees: California Institute of Technology, LC Vision, LLCInventors: Julia A. Kornfield, Michael Wand, Zuleikha Kurji
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Patent number: 8956549Abstract: The present invention relates to a liquid-crystalline medium, characterised in that it contains a polymerisable component (A) containing one more polymerisable compounds and a liquid-crystalline component (B) containing one more compounds of the general formula I in which R, rings A1 and A2, Z1, Z2, Y1, Y2, X0 and r are as defined in Claim 1.Type: GrantFiled: August 20, 2013Date of Patent: February 17, 2015Assignee: Merck Patent GmbHInventors: Seung-Eun Lee, Eun Young Kim, Dong-Mee Song, Kyung-Ah Park, Sang-Hyun Park, Eun-Kyu Lee
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Publication number: 20150034874Abstract: Provided is a novel material included in a liquid crystal composition that can be used in various liquid crystal display devices. A trifluorophenyl derivative represented by General Formula (G1). In General Formula (G1), Ar1 represents an arylene group having 6 to 12 carbon atoms, a cycloalkylene group having 3 to 12 carbon atoms, or a cycloalkenylene group having 3 to 12 carbon atoms; m represents 1 or 2; and R1 represents hydrogen, an alkyl group having 2 to 11 carbon atoms, or an alkoxy group having 2 to 11 carbon atoms.Type: ApplicationFiled: July 28, 2014Publication date: February 5, 2015Inventors: Momoko KATO, Yuko KAWATA, Yasuhiro NIIKURA, Tetsuji ISHITANI
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Patent number: 8945420Abstract: The invention relates to an electro-optical liquid-crystal display which contains, as dielectric, a liquid-crystalline medium having negative dielectric anisotropy and includes a backlight which essentially only emits light having a wavelength of 400 nm or more or has, between the liquid-crystal layer and the backlight, a cut-off filter which essentially only allows light having a wavelength of 420 nm or more to pass through. In particular, the liquid-crystalline medium comprises a) a (first) dielectrically negative component (component A) which consists of one or more dielectrically negative compounds of the formula I in which the parameters have the meanings indicated in claim 2, and a further (second) dielectrically negative component (component B).Type: GrantFiled: January 17, 2011Date of Patent: February 3, 2015Assignee: Merck Patent GmbHInventors: Atsutaka Manabe, Kazuaki Tarumi, Hubert Spreitzer, Axel Jansen, Melanie Klasen-Memmer
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Patent number: 8940185Abstract: To provide a novel liquid crystal compound having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a wide temperature range of a liquid crystal phase, a high clearing point, a good compatibility with other compounds, a large refractive index anisotropy, a large dielectric anisotropy and a small viscosity. The liquid crystal compound is provided as compound (1): wherein, for example, R1 is alkyl having 1 to 20 carbons; ring A1 and ring B1 are 1,4-cyclohexylene or 1,4-phenylene; Z1 and Z2 are a single bond, —CH2CH2—, —CH?CH— or —C?C—; L1 is fluorine; L2, Y1 and Y2 are hydrogen, fluorine or chlorine; and X1 is halogen, —C?N or alkyl having 1 to 10 carbons, and in the alkyl, arbitrary —CH2— may be replaced by —O— or —S—, and m is 1 and n is 0.Type: GrantFiled: December 20, 2010Date of Patent: January 27, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Hiroyuki Tanaka
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Patent number: 8940184Abstract: The present invention relates to polymerizable compounds, to processes and intermediates for the preparation thereof, and to the use thereof for optical, electro-optical and electronic purposes, in particular in liquid-crystal (LC) media and LC displays, especially in LC displays of the PS (“polymer sustained”) or PSA (“polymer sustained alignment”) type.Type: GrantFiled: August 30, 2010Date of Patent: January 27, 2015Assignee: MERCK PATENT GmbHInventors: Andreas Taugerbeck, Achim Goetz
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Publication number: 20150014584Abstract: The present invention relates to liquid crystal media and to high frequency components comprising same, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves.Type: ApplicationFiled: December 10, 2012Publication date: January 15, 2015Applicant: MERCK PATENT GMBHInventors: Atsutaka Manabe, Christian Jasper, Volker Reiffenrath, Constanze Brocke, Detlef Pauluth, Dagmar Klass
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Patent number: 8932484Abstract: The liquid crystal composition has a negative dielectric anisotropy, and contains a specific bicyclic compound having a large optical anisotropy and negative dielectric anisotropy as a first component and a specific tricyclic compound having a large dielectric anisotropy as a second component, and may contain a specific compound having a small viscosity as a third component, a specific compound having a large dielectric anisotropy and a small viscosity as a fourth component and a specific compound having a large dielectric anisotropy as a fifth component, and the liquid crystal display device includes the composition.Type: GrantFiled: June 2, 2011Date of Patent: January 13, 2015Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Norikatsu Hattori, Kazuhiko Saigusa
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Patent number: 8920674Abstract: To provide a liquid crystal composition satisfying at least one characteristic including a high maximum temperature of a nematic phase, a low minimum temperature thereof, a small viscosity, a large optical anisotropy, dielectric anisotropy and specific resistance, a high stability to ultraviolet light and heat, or a liquid crystal composition having a suitable balance regarding at least two characteristics; and an AM device having a short response time, a large voltage holding ratio and contrast ratio and a long life; a liquid crystal composition has a negative dielectric anisotropy and contains a compound having a low minimum temperature as a first component and a compound having a large negative dielectric anisotropy as a second component, and may contain a compound having a small viscosity as a third component and a compound having a large negative dielectric anisotropy as a fourth component, and a liquid crystal display device containing the composition.Type: GrantFiled: September 14, 2012Date of Patent: December 30, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takayoshi Yanai, Norikatsu Hattori, Hiroyuki Tanaka
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Publication number: 20140375943Abstract: The present invention relates to polymerizable compounds, to processes and intermediates for the preparation thereof, to liquid-crystal (LC) media comprising them, and to the use of the polymerizable compounds and LC media for optical, electro-optical and electronic purposes, in particular in LC displays, especially in LC displays of the PSA (“polymer sustained alignment”) type.Type: ApplicationFiled: June 25, 2014Publication date: December 25, 2014Applicant: MERCK PATENT GMBHInventors: Martin ENGEL, Eveline BARON, Constanze BROCKE, Helga HAAS, Stephan DEROW, Christoph MARTEN, Qiong TONG
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Patent number: 8911644Abstract: A liquid crystal medium having stability to heat, light and so forth, a wide temperature range of a liquid crystal phase, a large refractive index anisotropy and a large dielectric anisotropy and an optically isotropic liquid crystal phase is described. A liquid crystal composition is characterized by exhibiting the optically isotropic liquid crystal phase and containing achiral component T containing at least one compound selected from the group of compounds represented by formula (1) as a first component, and a chiral agent: wherein, for example, R1 is alkyl having 1 to 20 carbons, L1, L2, L3, L4, L5 and L6 are independently hydrogen or fluorine, and X1 is halogen.Type: GrantFiled: September 5, 2011Date of Patent: December 16, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Shin-Ichi Yamamoto, Takafumi Kuninobu, Koki Sago, Yasuhiro Haseba
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Publication number: 20140362335Abstract: A system having a vertically-aligned negative delta E nematic liquid crystal host material and a small amount of liquid crystal polymer is provided. The liquid crystal polymer improves the switching speed of a vertically aligned nematic system without sacrificing contrast or viewing angle.Type: ApplicationFiled: August 25, 2014Publication date: December 11, 2014Applicants: LC VISION, LLC, CALIFORNIA INSTITUTE OF TECHNOLOGYInventors: Julia A. KORNFIELD, Michael WAND, Zuleikha KURJI
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Patent number: 8906472Abstract: The nematic liquid crystal composition exhibits a negative dielectric anisotropy (??), the liquid crystal composition being useful as a liquid crystal display material, and a liquid crystal display element using the same. The liquid crystal composition of the present invention has a large absolute value of the dielectric anisotropy thereof and a low viscosity. By using this liquid crystal composition, it is possible to provide a liquid crystal display element which has a high contrast, high-speed responsiveness, and good display quality in which image sticking and display defects are not generated. The liquid crystal display element using the liquid crystal composition is a useful display element which realizes both high-speed response and suppression of display defects. In particular, the liquid crystal display element is useful as a liquid crystal display element for active-matrix driving, and can be applied to, for example, a VA-type or PSVA-type liquid crystal display element.Type: GrantFiled: August 16, 2012Date of Patent: December 9, 2014Assignee: DIC CorporationInventors: Takeshi Kuriyama, Yoshinori Iwashita
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Patent number: 8906258Abstract: A thermotropic liquid crystalline polymer composition capable of exhibiting both a low melting temperature and good heat resistance without the use of conventional naphthenic acids is provided. The melting temperature may, for example, range from about 250° C. to about 400° C. Even at such low melting temperatures, the present inventors have surprisingly discovered that the ratio of the deflection temperature under load (“DTUL”), a measure of short term heat resistance, to the melting temperature may remain relatively high. The specific DTUL values may range from about 200° C. to about 300° C. The ability to form a polymer composition with the properties noted above may be achieved, at least in part, by the use of an aromatic amide oligomer.Type: GrantFiled: August 27, 2012Date of Patent: December 9, 2014Assignee: Ticona LLCInventors: Steven D. Gray, Kamlesh P. Nair, Joseph J. Grenci
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Patent number: 8906261Abstract: The present invention relates to liquid-crystalline media (LC media) comprising thiophene derivatives and to liquid-crystal displays (LC displays) containing these LC media. The media have high optical anisotropy and preferably have a content of thiophene derivatives of 25% by weight or more.Type: GrantFiled: July 1, 2011Date of Patent: December 9, 2014Assignee: MERCK PATENT GmbHInventors: Michael Wittek, Brigitte Schuler, Axel Jansen
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Patent number: 8906260Abstract: To provide a liquid crystal compound showing a large absolute value of dielectric anisotropy (|??|. A compound is represented by formula (1): wherein, in formula (1), Ra and Rb are fluorine, alkyl having 1 to 10 carbons or the like, and in the alkyl, at least one of —CH2— may be replaced by —O— or the like, however, Ra and Rb are not identical; A1, A2, A3, A4 and A5 are 1,4-cyclohexylene, 1,4-phenylene or the like, and in the groups, at least one of hydrogen may be replaced by fluorine; Z1, Z2, Z4 and Z5 are a single bond or the like; Y1, Y2, Y3 and Y4 are hydrogen, fluorine or the like; and m, n, q and r are 0, 1 or 2, and a sum of m, n, q and r is 0, 1, 2, 3 or 4.Type: GrantFiled: February 28, 2013Date of Patent: December 9, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventor: Yasuyuki Sasada
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Patent number: 8895117Abstract: The present invention relates to polymerisable compounds, to processes and intermediates for the preparation thereof, to the use thereof for optical, electro-optical and electronic purposes, in particular in liquid-crystal (LC) media and LC displays having a polymer-stabilized blue phase, and in LC media for LC displays of the PS or PSA (“polymer sustained” or “polymer sustained alignment”) type, and to LC media and LC displays comprising these compounds.Type: GrantFiled: April 26, 2011Date of Patent: November 25, 2014Assignee: Merck Patent GmbHInventors: Axel Jansen, Andreas Taugerbeck, Helmut Haensel, Achim Goetz
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Publication number: 20140339472Abstract: To provide a liquid crystal composition satisfying at least one of characteristics or having a suitable balance regarding at least two of the characteristics such as high maximum temperature of a nematic phase, low minimum temperature thereof, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, large specific resistance, high stability to ultraviolet light and heat; an AM device having short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The liquid crystal composition has negative dielectric anisotropy and contains a compound having high maximum temperature as a first component and a specific compound having large negative dielectric anisotropy as a second component, and may contain a specific compound having small viscosity as a third component, and a specific compound having large negative dielectric anisotropy as a fourth component. A liquid crystal display device includes the composition.Type: ApplicationFiled: November 28, 2012Publication date: November 20, 2014Inventors: Kazuhiko Saigusa, Subaru Kawasaki, Takayoshi Yanai, Norikatsu Hattori
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Patent number: 8885124Abstract: The present invention provides a liquid crystal display device capable of preventing a decrease in voltage holding ratio (VHR) of a liquid crystal layer and an increase in ion density (ID) and resolving the problem of display defects such as white spots, alignment unevenness, image sticking, and the like. The liquid crystal display device of the present invention is characterized by preventing a decrease in voltage holding ratio (VHR) of a liquid crystal layer and an increase in ion density (ID) and suppressing the occurrence of display defects such as image sticking and the like, and is thus particularly useful for a VA-mode or PSVA-mode liquid crystal display device for active matrix driving, and can be applied to liquid crystal display devices such as a liquid crystal TV, a monitor, a cellular phone, a smart phone, and the like.Type: GrantFiled: December 14, 2012Date of Patent: November 11, 2014Assignee: DIC CorporationInventors: Masakazu Kaneoya, Kiyofumi Takeuchi, Seiji Funakura, Katsunori Shimada
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Patent number: 8883037Abstract: Chiral liquid crystal compounds of the general formula (1): in which at least one of R1 and R2 is a chiral substituent, K may be a single bond or the same as K1-5 and K1-5 denote a six-membered ring system which rings may be at least partially unsaturated, wherein the number of atoms in these rings or ring systems between the two atoms forming a part of the link to the next ring, or to one of the substituents R1 and R2, does not differ by more than one if counted in the clockwise, and in the counter-clockwise sense, starting from the same atom in each case, X1-20 denote alkyl, or alkoxy, or fluorinated alkyl, or fluorinated alkoxy groups, or atom H, or halogen atoms, mixtures comprising such chiral liquid crystal compounds, and liquid crystal displays comprising such mixtures as active ingredients.Type: GrantFiled: April 15, 2013Date of Patent: November 11, 2014Assignee: Tetragon LC Chemie AGInventors: Wolfgang Haase, Artsiom Lapanik
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Patent number: 8877092Abstract: The invention relates to a liquid-crystalline medium which comprises at least one compound of the formula I, in which R1, R1*, ring A have the meanings indicated in claim 1, and to the use thereof for an active-matrix display, in particular based on the VA, PSA, PS-VA, PALC, FFS or IPS effect.Type: GrantFiled: February 10, 2011Date of Patent: November 4, 2014Assignee: MERCK PATENT GmbHInventors: Melanie Klasen-Memmer, Volker Reiffenrath, Konstantin Schneider, Andreas Waechtler, Elvira Montenegro
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Patent number: 8858830Abstract: A liquid crystal composition is described, which exhibits an optically isotropic liquid crystal phase and contains an achiral component T and a chiral dopant. The achiral component T contains, as its first component, at least one compound selected from compounds represented by formula (1) in an amount of 32 wt % to 85 wt %, wherein R1 is alkyl, for example; L1, L2, L3, L4, L5 and L6 are each independently hydrogen or fluorine; Z1 and Z2 are each independently a single bond or —CF2O—, with at least one of Z1 and Z2 being —CF2O—; and X1 is halogen, for example.Type: GrantFiled: November 29, 2012Date of Patent: October 14, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Shin-Ichi Yamamoto, Yasuhiro Haseba
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Patent number: 8860912Abstract: There is provided a liquid crystal display device capable of preventing a decrease in voltage holding ratio (VHR) of a liquid crystal layer and an increase in ion density (ID) and resolving the problem of display defects such as white spots, alignment unevenness, image sticking, and the like. The liquid crystal display device prevents a decrease in voltage holding ratio (VHR) of a liquid crystal layer and an increase in ion density (ID) and suppressing the occurrence of display defects such as image sticking and the like. The liquid crystal display device is thus useful for a VA-mode or PSVA-mode liquid crystal display device for active matrix driving. The application of the device includes liquid crystal display devices such as liquid crystal TVs, monitors, cellular phones, and smart phones.Type: GrantFiled: January 29, 2013Date of Patent: October 14, 2014Assignee: DIC CorporationInventors: Masakazu Kaneoya, Kiyofumi Takeuchi, Akira Kimura, Seiji Funakura, Katsunori Shimada
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Patent number: 8846164Abstract: A liquid crystal compound is described, which has stability to heat, light and so forth, keeps a nematic phase in a wide temperature range, has a small viscosity, a suitable optical anisotropy and a suitable elastic constant K33, and further has a large negative dielectric anisotropy and an excellent compatibility with other liquid crystal compounds. The liquid crystal compound is represented by formula (1): wherein, for example, R1 is alkyl having 1 to 10 carbons, R2 is alkoxy having 1 to 10 carbons; ring A1, ring A2 and ring A5 are 1,4-cyclohexylene, 1,4-phenylene, or 1,4-phenylene in which arbitrary hydrogen is replaced by fluorine; Z1 and Z4 are a single bond, —CH2CH2— or —CH?CH—; a, b and e are 0 or 1, and c and d is 0; X1, X2 and X4 are hydrogen, and X3 is fluorine; and L1 and L2 are fluorine.Type: GrantFiled: July 27, 2011Date of Patent: September 30, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takahiro Kubo, Hiroyuki Tanaka
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Publication number: 20140284523Abstract: A liquid crystal composition is described, which has a negative dielectric anisotropy and contains a specific compound having high stability to ultraviolet light as a first component, and may further contain a specific compound having a large negative dielectric anisotropy as a second component, a specific compound having a high maximum temperature or a small viscosity as a third component, and a specific compound having a polymerizable group as an additive component. An AM liquid crystal display device is also described, including the liquid crystal composition.Type: ApplicationFiled: March 18, 2014Publication date: September 25, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: YOSHIMASA FURUSATO, ERIKO KURIHARA
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Patent number: 8834744Abstract: The invention relates to a liquid-crystalline medium comprising one or more compounds of the formula I in which R0, X0 and L1-6 have the meanings indicated in Claim 1, and to the use thereof in electro-optical liquid-crystal displays.Type: GrantFiled: August 14, 2013Date of Patent: September 16, 2014Assignee: Merck Patent GmbHInventors: Michael Wittek, Brigitte Schuler, Reiffenrath Volker, Mark Goebel, Markus Czanta
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Patent number: 8834742Abstract: A system having a vertically-aligned negative delta E nematic liquid crystal host material and a small amount of liquid crystal polymer is provided. The liquid crystal polymer improves the switching speed of a vertically aligned nematic system without sacrificing contrast or viewing angle.Type: GrantFiled: July 29, 2011Date of Patent: September 16, 2014Assignees: California Institute of Technology, LC Vision, LLCInventors: Julia A. Kornfield, Michael Wand, Zuleikha Kurji
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Patent number: 8828508Abstract: A liquid crystal composition in which deterioration of viscosity that is associated with an increase in ?n and an increase in ?? is suppressed, and a liquid crystal display element having a markedly improved response speed by using the relevant liquid crystal composition. The liquid crystal composition has a large value of ?n and negative ??, and have large absolute values thereof. Also, the liquid crystal composition has low ?, has excellent liquid crystal properties, and exhibits a liquid crystal phase that is stable in a wide temperature range. Furthermore, since the liquid crystal composition is chemically stable to heat, light, water and the like, the liquid crystal composition is capable of low voltage driving, and is practically useful and highly reliable.Type: GrantFiled: April 5, 2012Date of Patent: September 9, 2014Assignee: DIC CorporationInventors: Haruki Ohishi, Shirou Taniguchi, Kunihiko Kotani, Kazunori Maruyama
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Patent number: 8821993Abstract: A liquid crystal composition has a negative dielectric anisotropy, and contains a specific bicyclic compound having a large optical anisotropy and a small viscosity as a first component and a specific compound having a large maximum temperature and a large dielectric anisotropy as a second component, and may contain a specific compound having a small viscosity as a third component, a specific compound having a large dielectric anisotropy as a fourth component and a specific compound having a large dielectric anisotropy as a fifth component, and a liquid crystal display device includes the composition.Type: GrantFiled: September 27, 2011Date of Patent: September 2, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Norikatsu Hattori, Yoshinari Matsumura, Hiroaki Fujita
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Patent number: 8821992Abstract: A liquid crystal formulation is described. The liquid crystal formulation comprises a first oligosiloxane-modified nano-phase segregating liquid crystalline material; and at least one additional material selected from a second oligosiloxane-modified nano-phase segregating liquid crystalline material, non-liquid crystalline oligosiloxane-modified materials, organic liquid crystalline materials, or non-liquid crystalline materials, wherein the liquid crystal formulation has an I?SmA*?SmC* phase transition, with a SmC* temperature range from about 15° C. to about 35° C., a tilt angle of about 22.5°±6° or about 45°±6°, a spontaneous polarization of less than about 50 nC/cm2., and a rotational viscosity of less than about 600 cP. Devices containing liquid crystal formulations are also described.Type: GrantFiled: October 26, 2007Date of Patent: September 2, 2014Assignees: Dow Corning Corporation, Cambridge Enterprise Ltd.Inventors: Jonathan Paul Hannington, Terry Victor Clapp, Fumito Nishida, Russel Keith King, Omar Farooq, Martin Grasmann, William Alden Crossland, Harry James Coles, Anthony Bernard Davey, Huan Xu, Oliver Hadeler, Mykhaylo Pivnenko
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Patent number: 8821757Abstract: The invention relates to a liquid-crystalline medium comprising one or more compounds of the formula (I), in which R0 has the meanings indicated in Claim 1, and to the use thereof in electro-optical liquid-crystal displays.Type: GrantFiled: January 25, 2011Date of Patent: September 2, 2014Assignee: Merck Patent GmbHInventors: Michael Wittek, Brigitte Schuler, Lars Lietzau
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Publication number: 20140239227Abstract: The present invention relates to liquid crystal media and to high-frequency components comprising same, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, in particular for microwave phased-array antennas.Type: ApplicationFiled: September 7, 2012Publication date: August 28, 2014Applicant: MERCK PATENT GMBHInventors: Atsutaka Manabe, Christian Jasper, Volker Reiffenrath, Constanze Brocke, Detlef Pauluth, Dagmar Klass
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Publication number: 20140240653Abstract: The present invention relates to the use of LC (liquid-crystal) compounds and LC media comprising them in LC displays of the PS (polymer stabilised) or PSA (polymer sustained alignment) type.Type: ApplicationFiled: May 9, 2014Publication date: August 28, 2014Applicant: MERCK PATENT GMBHInventors: Seung-Eun LEE, Eun Young KIM, Dong-Mee SONG, Eun-Kyu LEE
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Patent number: 8815117Abstract: The present invention provides a mixture for liquid crystal medium and a liquid crystal display using the same. The mixture for liquid crystal medium comprises: at least one anisotropic liquid crystal material and a polymerizable monomer which will polymerize under UV irradiation. The weight percentage of the polymerizable monomer accounts for 0.1% to 1% of the total mixture for liquid crystal medium. In the mixture for liquid crystal medium and a liquid crystal display using the same according to the present invention, by using a polymerizable monomer which will polymerize under UV irradiation and the appropriate content ratio, the polymer bump with small size and good uniformity can be obtained within the mixture for liquid crystal medium after the polymerization, which avoids the bad liquid crystal alignment and the light spot occurred at the dark state of the liquid crystal panel, and then increases the response rapid of the liquid crystal panel to obtain high contrast ratio and stable mass production.Type: GrantFiled: October 16, 2012Date of Patent: August 26, 2014Assignee: Shenzhen China Star Optoelectronics Technology Co., LtdInventors: Xing Feng, Xinhui Zhong
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Publication number: 20140231712Abstract: A liquid crystal composition of the present invention has a liquid phase over a wide temperature range, low viscosity, good solubility at a low temperature, high resistivity and voltage holding ratio, and stability to heat and light, and can thus provide, in high yield, a liquid crystal display device having good display quality and causing little display defects such as image sticking, dropping marks, and the like. A liquid crystal display device using the liquid crystal composition of the present invention is useful, particularly useful for a liquid crystal display device for active matrix driving, because both fast response and suppression of display defects are achieved, and the liquid crystal display device can be applied to a liquid crystal display device for a VA mode, a PSVA mode, or a TN mode.Type: ApplicationFiled: August 16, 2012Publication date: August 21, 2014Applicant: DIC CORPORATIONInventor: Jouji Kawamura
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Patent number: 8808814Abstract: The liquid crystal composition includes a specific two-ring compound having a large optical anisotropy and a small viscosity as a first component, a specific three-ring compound having a high maximum temperature and a large dielectric anisotropy as a second component, and a specific compound having a large dielectric anisotropy as a third component, and may include a specific compound having a small viscosity as a fourth component, a specific three-ring compound having a large optical anisotropy and a large dielectric anisotropy as a fifth component, and a specific compound having a large dielectric anisotropy as a sixth component, and the liquid crystal display device contains this composition.Type: GrantFiled: September 27, 2011Date of Patent: August 19, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshinari Matsumura, Norikatsu Hattori
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Publication number: 20140225036Abstract: A nematic liquid crystal composition of the present invention is used in liquid crystal display devices of the TN mode, OCB mode, ECB mode, IPS mode, or VA-IPS mode. The liquid crystal composition has positive dielectric anisotropy. Since the refractive index anisotropy and the nematic phase-isotropic liquid phase transition temperature are decreased and the increase in the lower limit temperature of the nematic phase is suppressed, the viscosity of the liquid crystal composition is sufficiently low without degrading the nematic phase temperature range. The liquid crystal composition also offers excellent features such as high-speed response, good display quality, and less display failures and is thus suitable as a practical liquid crystal composition.Type: ApplicationFiled: July 31, 2012Publication date: August 14, 2014Applicant: DIC CORPORATIONInventors: Masakazu Kaneoya, Kiyofumi Takeuchi, Masashi Osawa, Kenta Tojo, Tetsuo Kusumoto
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Patent number: 8801965Abstract: The present invention provides a liquid crystal medium composition and a liquid crystal display panel manufactured with same. The liquid crystal medium composition includes a negative type liquid crystal material, a polymerizable monomer, a sensitizer, and stabilizer. The sensitizer is an organometallic complex that has an amount of 0.01%-5% of total mass of the liquid crystal composition and has a strong absorption of ultraviolet light having a wavelength of 300-450 nm. The sensitizer converts the primary wavelength range of ultraviolet light for reaction of the polymerizable monomer from 200-300 nm to 300-450 nm, staying away from the absorption band of the liquid crystal material and reducing damages caused on the liquid crystal material and the alignment material of polyimide, thereby heightening reaction efficiency and homogeneity of the polymerizable monomer and the quality and lifespan of the liquid crystal display panel.Type: GrantFiled: November 14, 2012Date of Patent: August 12, 2014Assignee: Shenzen China Star Optoelectronic Technology co., Ltd.Inventors: Xinhui Zhong, Kuancheng Lee
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Publication number: 20140217325Abstract: The present invention relates to liquid-crystalline media and to high-frequency components comprising same, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, in particular for microwave phased-array antennas.Type: ApplicationFiled: August 7, 2012Publication date: August 7, 2014Applicant: MERCK PATENT GMBHInventors: Atsutaka Manabe, Dagmar Klass
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Patent number: 8795795Abstract: The invention is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large positive dielectric anisotropy, a large specific resistance, a large elastic coefficient, a high stability to ultraviolet light and heat, or that is suitably balanced between at least two of the characteristics. As the liquid crystal display device containing the compositions is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, thus it can be used for the liquid crystal projector, liquid crystal television and so forth.Type: GrantFiled: June 6, 2012Date of Patent: August 5, 2014Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Takayoshi Yanai, Norikatsu Hattori, Tokifumi Masukawa