Sulphur Organic Compound Containing Patents (Class 252/391)
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Patent number: 4210552Abstract: Certain sulfonium salts are herein described which are useful corrosion inhibitors in aqueous acidic cleaning solutions, even in the presence of ferric ions.Type: GrantFiled: September 28, 1978Date of Patent: July 1, 1980Assignee: The Dow Chemical CompanyInventors: Wayne W. Frenier, William J. Settineri
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Patent number: 4209418Abstract: Compositions comprising a mixture of gelatin and a compound of the formula: ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each a group selected from the class consisting of --H, --Cl, --CHCl.sub.2, --CH.sub.2 Cl, --CCl.sub.3, --SH, --SCH.sub.3, --NH.sub.2, --NHC.tbd.N, --CH.sub.2 C.tbd.N, ##STR2## --CH.sub.2 OH, --NO.sub.2 and monovalent hydrocarbon radicals having from 1 to about 18 carbon atoms, provide effective corrosion inhibition for aqueous carboxylic acid solutions in the cleaning of metal industrial equipment.Type: GrantFiled: July 18, 1978Date of Patent: June 24, 1980Assignee: Union Carbide CorporationInventor: James D. Anderson
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Patent number: 4202706Abstract: The surfaces of articles made of aluminum, such as annodized aluminum and bare aluminum, are treated with N-alkyl-fluoroaliphaticsulfonamidophosphonic acids or salts thereof to impart corrosion resistance to said surfaces.Type: GrantFiled: March 12, 1979Date of Patent: May 13, 1980Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard G. Newell, Dale C. Perry
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Patent number: 4193882Abstract: Lubricant compositions containing, in an amount sufficient to inhibit metal corrosion, the reaction product of oleic acid and 2,5-dimercapto-1,3,4-thiadiazole.Type: GrantFiled: October 19, 1978Date of Patent: March 18, 1980Assignee: Mobil Oil CorporationInventor: Robert M. Gemmill, Jr.
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Patent number: 4188359Abstract: This invention relates to N-alkyl thioethers of quaternary ammonium derivatives of 1,4-thiazines; to the preparation thereof; and to the uses thereof for example as corrosion inhibitors, microbiocides, etc.Type: GrantFiled: December 4, 1978Date of Patent: February 12, 1980Assignee: Petrolite CorporationInventor: Patrick M. Quinlan
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Patent number: 4180469Abstract: Compositions comprising mixtures of a dithiocarbamic acid derivative and a sulfonium compound such as triphenylsulfonium chloride provide effective corrosion inhibition in acid treatment of metal in the presence of a copper complexing agent such as a thiourea.Type: GrantFiled: December 30, 1977Date of Patent: December 25, 1979Assignee: Amchem Products, Inc.Inventor: James D. Anderson
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Patent number: 4178253Abstract: A lubricating oil composition comprising 0.001% to 10%, based on the total lubricating composition, of a compound of formula I: ##STR1## wherein x is an integer from 1 to 25; R, R.sup.1 and R" are the same or different and each is hydrogen, an optionally substituted straight- or branched-chain alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 2 to 12 carbon atoms, an optionally substituted cycloalkyl residue having from 3 to 12 carbon atoms, an optionally substituted aryl residue having from 6 to 10 carbon atoms, an optionally substituted aralkenyl or aralkynyl residue each having from 8 to 12 carbon atoms, an optionally substituted aralkyl residue having from 7 to 20 carbon atoms or an optionally substituted heterocyclic residue having from 3 to 10 ring members, an alkylene residue having from 2 to 12 carbon atoms, a cycloalkylene residue having from 5 to 12 carbon atoms or an arylene residue having from 6 to 10 carbon atoms; or R is the group -(S).sub.Type: GrantFiled: April 3, 1978Date of Patent: December 11, 1979Assignee: Ciba-Geigy CorporationInventors: Peter I. Lee, Brian Holt
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Patent number: 4176059Abstract: A low toxicity, corrosion and scale inhibiting composition for use in recirculating aqueous systems, e.g. in heat exchangers, comprises from about 3-1,000 parts by weight of molybdate, from about 0.5-1,000 parts by weight of an organic cationic or non-ionic surfactant, from about 0.3-1,000 parts by weight of a water soluble polyphosphate and from about 0.05-500 parts by weight of an azole, for example tolyltriazole. The composition is water soluble or water dispersible, and is effective in very small amounts (3-3,500 ppm) for corrosion control of metals such as carbon steel, copper and aluminum exposed to circulating water.Type: GrantFiled: June 8, 1978Date of Patent: November 27, 1979Assignee: Quatic Chemicals LimitedInventor: Fumiko Suzuki
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Patent number: 4172032Abstract: When a specific condensed phosphate glass is combined with an organic phosphate ester, an improved composition is afforded for preventing scale and corrosion in industrial cooling systems. Optionally, certain azoles are combined with the phosphate glass and phosphate ester to afford corrosion protection to non-ferrous metals.Type: GrantFiled: December 23, 1977Date of Patent: October 23, 1979Assignee: Nalco Chemical CompanyInventor: George T. Farley
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Patent number: 4171279Abstract: Polyglycolamines such as aminated polypropylene or polybutylene glycols and amine-initiated polypropylene and polybutylene glycols such as oxypropylated or oxybutylated lower alkanolamines inhibit the corrosion of ferrous metals by a nonoxidizing acid such as hydrochloric acid. Polyglycolamines of this class having an average molecular weight in the appropriate range of 300-5000 are effective inhibitors in 5-15 percent hydrochloric acid at moderately elevated temperatures.Type: GrantFiled: March 14, 1977Date of Patent: October 16, 1979Assignee: The Dow Chemical CompanyInventor: Charles W. Martin
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Patent number: 4149969Abstract: A process and a composition for inhibiting corrosion of metal parts in water systems such as in recirculating cooling towers and the like, while additionally suppressing scale formation and inhibiting corrosion of copper and copper-containing alloys which comprises adding and dissolving in the aqueous system, a controlled combination of active constituents in effective amounts comprising as essential constituents, an alkali molybdate salt, a divalent metal cation selected from the group consisting of ZN.sup.++, Mn.sup.++ and Ni.sup.++ ; 1-hydroxyethylidene-1,1-diphosphonic acid and the aqueous soluble alkali salts thereof; and an organic agent selected from the group consisting of 2-mercaptobenzothiazole and the alkali salts thereof; 1,2,3-benzotriazole, and tolyltriazole.Type: GrantFiled: March 23, 1977Date of Patent: April 17, 1979Assignee: AMAX Inc.Inventors: Dennis R. Robitaille, Mark S. Vukasovich
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Patent number: 4149980Abstract: Ashless lubricant additive compositions which contain a small but effective amount of overbased aminoguanidine sulfonate, sufficient to impart acid neutralization, antitrust, anticorrosive, dispersant, and detergent properties, are formed by reacting greater than about one mole of aminoguanidine with one mole of a hydrocarbon sulfonic acid.Type: GrantFiled: June 27, 1977Date of Patent: April 17, 1979Assignee: Standard Oil Company (Indiana)Inventors: A. Abdul-Malek, C. G. Brannen, W. C. Edmisten
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Patent number: 4146711Abstract: This invention relates to N-alkyl sulfone containing quaternary ammonium derivatives of 1,4-thiazines; to the preparation thereof; and to the uses thereof, for example as corrosion inhibitors, microbiocides, etc.Type: GrantFiled: March 13, 1978Date of Patent: March 27, 1979Assignee: Petrolite CorporationInventor: Patrick M. Quinlan
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Patent number: 4146709Abstract: This invention relates to N-alkyl thioethers of quaternary ammonium derivatives of 1,4-thiazines; to the preparation thereof; and to the uses thereof for example as corrosion inhibitors, microbiocides, etc.Type: GrantFiled: March 13, 1978Date of Patent: March 27, 1979Assignee: Petrolite CorporationInventor: Patrick M. Quinlan
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Patent number: 4142903Abstract: A corrosion resistant coating composition is provided which is a one-quart system. The composition is an asphaltic-base material containing a petroleum sulfonate and a sufficient amount of an organic solvent to impart the desired viscosity. A source of amine groups, such as a polyamide resin, is added and the resulting composition has improved adherence to the metallic substrate.Type: GrantFiled: October 25, 1977Date of Patent: March 6, 1979Inventor: Michael Antonelli, Sr.
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Patent number: 4136043Abstract: Compositions which form homogeneous blends with lubricating oils and the like are produced by preparing a mixture of an oil-soluble dispersant (preferably a substantially neutral or acidic carboxylic dispersant) and a dimercaptothiadiazole, preferably 2,5-dimercapto-1,3,4-thiadiazole, usually with a diluent, especially a lubricant base liquid, and heating said mixture above about 100.degree. C. The compositions often contain dimercaptothiadiazole moieties in amounts substantially greater than stoichiometric. They are useful for suppression of copper activity and "lead paint" deposition in lubricants.Type: GrantFiled: May 16, 1974Date of Patent: January 23, 1979Assignee: The Lubrizol CorporationInventor: Kirk E. Davis
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Patent number: 4126634Abstract: Aminosulfonylcarboxylic acids and their manufacture from diamines and chlorosulfonylcarboxylic acids.Type: GrantFiled: August 1, 1977Date of Patent: November 21, 1978Assignee: BASF AktiengesellschaftInventors: Lucien Thil, Martin Fischer, Wolfgang Kindscher
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Patent number: 4102804Abstract: The corrosion of iron and steel by an aqueous sour gas conditioning solution used to remove CO.sub.2 from a gas stream is effectively inhibited by a combination of a quaternary pyridinium salt and an organic thioamide, a water-soluble sulfide or a water-soluble thiocyanate.Type: GrantFiled: March 28, 1977Date of Patent: July 25, 1978Assignee: The Dow Chemical CompanyInventors: Robert C. Clouse, Robert G. Asperger
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Patent number: 4101438Abstract: Certain sulfonium salts are herein described which are useful corrosion inhibitors in aqueous acidic cleaning solutions, even in the presence of ferric ions.Type: GrantFiled: March 22, 1976Date of Patent: July 18, 1978Assignee: The Dow Chemical CompanyInventors: Wayne W. Frenier, William J. Settineri
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Patent number: 4096085Abstract: An aqueous organic amine acid gas scrubbing system, particularly an aqueous N-methyldiethanolamine or diethanolamine acid gas scrubbing system having incorporated therein (1) a compound or mixture of compounds having the formula ##STR1## wherein n is an integer from 1 to 3, m is an integer from 2 to a number sufficient to yield a molecular weight of about 800, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently selected from the group consisting of --H, --C.sub.n' H.sub.2n' OH, --C.sub.n' H.sub.2n'+1, --C.sub.n' H.sub.2n' N(R.sub.3)R.sub.4 wherein n' is an integer from 1 to 2 and wherein R.sub.1 -R.sub.3 and R.sub.2 -R.sub.4 may be joined to form cyclic amines when n is 2; said compound being present in about 10 to about 2000 parts per million parts of treating solution; (2) copper or a copper ion yielding compound in from 0 to 1000 ppm; and (3) sulfur or a sulfur atom yielding compound in from 0 to 1000 ppm.Type: GrantFiled: October 29, 1976Date of Patent: June 20, 1978Assignee: The Dow Chemical CompanyInventors: Smallwood Holoman Jr., Robert G. Asperger, Leroy S. Krawczyk
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Patent number: 4079012Abstract: A neutral oil soluble organosulfonic acid ammonium salt formed by reaction of C.sub.1 -C.sub.26 sulfonic acid with a nitrogen base chosen from the group consisting of mono-, di-, and tertiary amines, acid addition salts of such amines, or quaternary ammonium compounds, the nitrogen base having at least one hydrocarbyl group containing from about C.sub.1 to C.sub.36 carbon atoms, is added to an oil composition to improve the load-carrying capacity of the oil composition. The sulfonic ammonium salts are particularly effective in synthetic ester lubricants used in turbine engines. The oil compositions of this invention are also compatible with the silicone and fluorosilicone seals used in such engines.Type: GrantFiled: October 4, 1976Date of Patent: March 14, 1978Inventor: David S. Bosniack
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Patent number: 4069225Abstract: A new corrosion inhibitor for acid-pickled ferrous and nonferrous metals in the form of isoperthiocyanic and its .alpha.-hydroxy-substituted derivatives of the formula ##STR1## The metals are pickled in aqueous solutions of acid mixed with 0.1-1 wt.-% of said inhibitor.Type: GrantFiled: May 11, 1972Date of Patent: January 17, 1978Inventors: Vasily Efimovich Privalov, Evgeny Iosifovich Vail, Andrei Mefodievich Khanin, Evgeny Ivanovich Gromov, Viktoria Mikhailovna Petropolskaya, Lidia Mikhailovna Agarkova
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Patent number: 4066462Abstract: An anti-corrosive organic pigment is prepared by mixing a lignin type compound with urea, a urea derivative, melamine, a melamine derivative, ammonia or an ammonium salt, condensing the components of the mixture by heating the mixture in a molten form, and then pulverizing or dispersing the reaction mixture to form a pigment.Type: GrantFiled: August 24, 1976Date of Patent: January 3, 1978Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Shojiro Horiguchi, Michiei Nakamura, Yoshifumi Sugito
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Patent number: 4060522Abstract: Amidosulfocarboxylic acids, their preparation from primary or secondary amines and chlorosulfocarboxylic acids, and their use as anticorrosive agents.Type: GrantFiled: March 15, 1976Date of Patent: November 29, 1977Assignee: BASF AktiengesellschaftInventors: Wolfgang Kindscher, Martin Fischer, Karl Eicken, Guenter Vitt
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Patent number: 4057390Abstract: This invention relates to sulfur-containing Bis-Quaternaries of the idealized formula[N .sup.+ CH.sub.2 CH.sub.2 ].sub.2 Z 2X.sup.-where N is a quaternary amino group, Z is a sulfur-containing group, for example S, SO, SO.sub.2 and X is an anion; to methods of preparing such compounds; and to uses of such compounds.Type: GrantFiled: May 24, 1976Date of Patent: November 8, 1977Assignee: Petrolite CorporationInventor: Patrick M. Quinlan
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Patent number: 4029702Abstract: The oil-soluble azo compounds of this invention are useful as dispersants, corrosion inhibitors and anti-wear agents in lubricating oil and fuel compositions. The predominant oil-soluble azo reaction product may be represented by the following formulas: ##STR1## wherein R represents an oil-solubilizing, synthetic, polymeric organic radical containing at least 20 carbon atoms,Y is independently selected from the group consisting of --NR.sub.2 R.sub.3 and --SR.sub.4,R.sub.2, r.sub.3, and R.sub.4 are independently selected from hydrogen, alkyl, cycloalkyl, aryl, alkaryl and aralkyl,X is independently selected from oxygen, sulfur and =NR.sub.5, with the proviso that when X is =NR.sub.5, Y is --NR.sub.2 R.sub.3,R.sub.Type: GrantFiled: October 12, 1971Date of Patent: June 14, 1977Assignee: Rohm and Haas CompanyInventor: Richard J. Piccolini
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Patent number: 4000079Abstract: Corrosion-inhibiting aqueous solutions and corrosion inhibiting antifreeze agents based on glycols and aqueous solutions thereof are prepared by adding two such solutions and agents already containing conventional corrosion inhibitors, heterocyclic nitrogen compounds having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 are hydrogen or together with the carbon atoms to which they are attached represent an optionally substituted benzene ring;R.sup.3, r.sup.4, r.sup.5 and R.sup.6 independently of one another are selected from the group of hydrogen, lower alkyl, phenyl substituted by one or more lower alkyls;X is sulphur or an imino group (NH) optionally substituted on the nitrogen atom; andn is an integer from 1 to 13, added to an aqueous solution or antifreeze agent which contains at least one conventional corrosion inhibitor.Type: GrantFiled: June 27, 1973Date of Patent: December 28, 1976Assignee: Bayer AktiengesellschaftInventors: Christian Rasp, Artur Botta
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Patent number: 3992306Abstract: Aqueous metal working liquids containing a bis-sulfonamidocarboxylic acid of the formula ##SPC1##In the form of its water soluble or water dispersible salt with an alkali or an organic base, as corrosion protection and metal-working agent wherein R.sub.1 denotes hydrogen, halogen, alkyl and/or alkoxy of 1 to 3 carbon atoms, R.sub.2 denotes an alkylene radical having a total of 1 to 5 carbon atoms, and x denotes an integer of from 2 to 6.Type: GrantFiled: June 12, 1974Date of Patent: November 16, 1976Assignee: Hoechst AktiengesellschaftInventors: Helmut Diery, Horst Frohlich, Rainer Helwerth, Horst Lorke
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Patent number: 3992313Abstract: A Mannich base and thiourea inhibitor composition and method of inhibiting the acid attack by aqueous hydrofluoric acid on ferrous metal surfaces, and in particular, highly reactive ferrous metal surfaces.Type: GrantFiled: July 14, 1975Date of Patent: November 16, 1976Assignee: Amchem Products, Inc.Inventors: James Douglas Anderson, Edgar S. Hayman, Jr., Edward A. Rodzewich
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Patent number: 3979311Abstract: A synergistic mixture of an alkynyl cycloalkanol and an N,N'-dicycloalkyl-thiourea is used as an inhibitor in protecting metals from acid attack when cleaning said metals with an acid solution.Type: GrantFiled: May 30, 1974Date of Patent: September 7, 1976Assignee: Universal Oil Products CompanyInventor: Herbert D. Clark
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Patent number: 3976593Abstract: This invention relates to the amine bisulfites which are useful as a combination corrosion inhibitor/oxygen scavenger. This is illustrated by heterocyclic amine bisulfites such as pyridine bisulfites.Type: GrantFiled: May 19, 1975Date of Patent: August 24, 1976Assignee: Petrolite CorporationInventors: Francis J. Hartke, James E. Davis
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Patent number: 3966623Abstract: A lubricating oil composition containing a synergistic corrosion inhibiting combination of 2,5-bis-hydrocarbyldithio-1,3,4-thiadiazole and a primary alkyl or alkenyl amine salt of 2-mercaptobenzothiazole.Type: GrantFiled: June 5, 1975Date of Patent: June 29, 1976Assignee: Texaco Inc.Inventors: Robert H. Krug, Clemence J. Henry
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Patent number: 3962104Abstract: Lubricating oils containing as an ashless detergent a quaternary ammonium salt derived from an organic acid, (e.g. carboxylic acid, sulphonic acid, alkyl phenol or phosphosulphurised hydrocarbon) and a cation obtained by the reaction of a tertiary amine, olefin oxide and water.Type: GrantFiled: June 24, 1974Date of Patent: June 8, 1976Assignee: Exxon Research and Engineering CompanyInventors: Swietlik Joseph Marian, Michael David Sexton
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Patent number: 3960758Abstract: A non-discoloring stabilizer system for trans-polypentenamer of:A. a sulphur-containing phenol of the formula: ##SPC1##In which R.sub.1 and R.sub.3 are alkyl groups with 1 to 8 carbon atoms, aralkyl radicals with 7 to 9 carbon atoms and cycloalkyl radicals with 5 to 7 carbon atoms, R.sub.3 represents hydrogen, alkyl groups with 1 to 8 carbon atoms, cyclohexyl, cyclohexenyl or methylcyclohexenyl, R.sub.4 represents alkyl groups with 1 to 12 carbon atoms or ##SPC2##Where R.sub.1, R.sub.2 and R.sub.3 are as defined above, andB. a phenol ester of phosphorous acid of the formula: ##SPC3##In which R.sub.5 represents an alkyl or cycloalkyl group with 5 to 10 carbon atoms, R.sub.6 and R.sub.7 are the same or different and represent hydrogen, alkyl and cycloalkyl radicals each with 1 to 7 carbon atoms.Type: GrantFiled: June 28, 1974Date of Patent: June 1, 1976Assignee: Bayer AktiengesellschaftInventors: Josef Witte, Dieter Theisen, Ernst Roos, Karl Nutzel
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Patent number: 3959177Abstract: This invention relates to corrosion inhibitors which are not only effective against metal loss corrosion but are also effective against corrosion of the cracking type such as (1) stress (continuing tensile stress) cracking, (2) hydrogen embrittlement or blistering, and (3) corrosion fatigue (alternating tensile stress).Type: GrantFiled: December 7, 1973Date of Patent: May 25, 1976Assignee: Petrolite CorporationInventor: Richard L. Martin
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Patent number: 3959158Abstract: Compositions and methods for the protection of steel and metal well equipment used in high temperature oil and gas wells above 250.degree.F and more particularly in the range of about 300.degree.-550.degree.F for bottom hole temperatures. The basic composition is a trimer acid salt of a primary mono-amine and particularly useful is a primary amine such as a primary tallow amine having C.sub.9 -C.sub.24 carbon length. Other ingredients include a sulfonate, particularly an alkaryl sulfonate, as well as a mixture of dispersing agents or solvents specially utilizing a combination of a lower alkanol and a highly aromatic solvent as make up. Optionally there may be included a minor amount of a water-in-oil demulsifier. The reaction of the trimer acid with the mono-amine affords less opportunity for any further deleterious reaction or polymerization than as previous formulations utilizing polyamines with dimer acids and the like.Type: GrantFiled: September 3, 1974Date of Patent: May 25, 1976Assignee: Nalco Chemical CompanyInventors: James R. Stanford, George D. Chappell
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Patent number: 3954639Abstract: A lubricating oil composition of improved rust inhibitory capability contains a small amount of the sulfate of an oxyalkylenated alcohol or phenol having a molecular weight of about 500-5,000.Type: GrantFiled: March 14, 1974Date of Patent: May 4, 1976Assignee: Chevron Research CompanyInventor: Thomas V. Liston
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Patent number: 3940248Abstract: A corrosion inhibiting composition which comprises an aqueus medium having dissolved therein an effective amount of at least one of water-soluble 8-hydroxy-s-triazolo[b]pyridazine compounds and watersoluble salts thereof, said water-soluble 8-hydroxy-s-triazolo[b]pyridazine compound having the formula of ##SPC1##Wherein R.sub.1 is hydrogen atom or an alkyl group having 1 to 4 carbon atoms: R.sub.2 is hydrogen atom, an alkyl group having 1 to 10 carbon atoms, phenyl, hydroxyphenyl, nitrophenyl, benzyl, hydroxybenzyl or nitrobenzyl group; and a method for inhibiting corrosion of a metal which comprises contacting a metal with said composition.Type: GrantFiled: June 13, 1973Date of Patent: February 24, 1976Assignee: Otsuka Kagaku Yakuhin Kabushiki KaishaInventors: Hideo Yamaguchi, Takashi Kawasaki, Shigeo Takahashi, Akiyoshi Inubuse
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Patent number: 3939084Abstract: Functional fluid compositions comprising polyphenyl thioethers, mixed polyphenyl oxy-thioethers and mixtures thereof containing certain pyrimidines as anti-corrosive agents have improved metal compatibility and are particularly useful as aircraft engine lubricants and hydraulic fluids.Type: GrantFiled: December 28, 1973Date of Patent: February 17, 1976Assignee: Monsanto CompanyInventor: James D. Sullivan
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Patent number: RE30283Abstract: Certain sulfonium salts are herein described which are useful corrosion inhibitors in aqueous acidic cleaning solutions, even in the presence of ferric ions.Type: GrantFiled: February 13, 1979Date of Patent: May 27, 1980Assignee: The Dow Chemical CompanyInventors: Wayne W. Frenier, William J. Settineri