Nitrogen Organic Compound Containing Patents (Class 252/394)
  • Patent number: 5078966
    Abstract: Carbohydrazide is an effective material for preventing hydrogen blistering and corrosion in the refinery overhead condensate systems of Fluid Catalytic Cracking Units.
    Type: Grant
    Filed: August 14, 1990
    Date of Patent: January 7, 1992
    Assignee: Nalco Chemical Company
    Inventors: Russell C. Strong, Veronica K. Majestic
  • Patent number: 5074991
    Abstract: Hydrogen sulfide gas evolution from water or hydrocarbons, especially during storage or transport of petroleum residua is suppressed by the incorporation of an effective amount of a diamine of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are independently an alky radical containing 1 to 14 carbon atoms, (CH.sub.2).sub.n --OR.sub.6 or cycloalkyl containing 5 or 6 carbon atoms and R.sub.5 is hydrogen or methyl. R.sub.1 and R.sub.2 and R.sub.3 and R.sub.4 can be alkylene groups joined together with their respective adjacent N to form a heterocyclic ring. R.sub.6 is hydrogen or an alkyl radical having 1 to 5 carbon atoms and n is an integer of 1 to 5.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: December 24, 1991
    Assignee: Petrolite Corporation
    Inventor: Jerry J. Weers
  • Patent number: 5071574
    Abstract: A process for reducing the corrosiveness of aerated aqueous solutions, which comprises stripping the oxygen with gas containing hydrogen sulfide after addition of a composition which is both catalytic of the reduction of oxygen by hydrogen sulfide gas and inhibiting of hydrogen sulfide corrosion, such composition comprising certain metallic salts and a water-soluble oxyethylenated amine.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: December 10, 1991
    Assignee: CECA, S.A.
    Inventor: Tang E. Pou
  • Patent number: 5069805
    Abstract: Compounds of the formula I ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the meaning given in claim 1 are formed by thermal rearrangement of the isomers of formula V ##STR2## especially in the presence of basic catalysts. The compounds are corrosion inhibitors for organic materials, in particular coating materials and lubricants. In these substrates they also act as antioxidants and light-stabilizers and are very stable to heat.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: December 3, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Adalbert Braig, Hans-Rudolf Meier, David G. Leppard, Robert C. Wasson, Emyr Phillips
  • Patent number: 5066461
    Abstract: Compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 when taken independently, each represent the monovalent group of formula: ##STR2## wherein Y is a monovalent group selected from hydroxyl and a group of the formula: ##STR3## wherein n is a whole number integer of 0 to 6; X is selected from the group consisting of hydroxyl and amino when n is from 1 to 6; and when n is 0, X is selected from monovalent groups of the formula:--0--alkylene--NR.sup.3 R.sup.4 (IV)wherein n has the meaning previously ascribed to it; R.sup.3 is selected from the group consisting of hydrogen and R.sup.4 ; and R.sup.4 represents a monovalent group of the formula--Alkylene--OH; (V)provided that R.sup.1 and R.sup.2 are not both a carboxyl group; and R.sup.1 and R.sup.2 when taken together represent the divalent moiety of formula: ##STR4## wherein A represents one of oxygen and ##STR5## wherein n has the meaning previously ascribed to it; and applied to oxidation prone metals to inhibit corrosion.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: November 19, 1991
    Assignee: Union Camp Corporation
    Inventor: Ewa A. Bardasz
  • Patent number: 5062992
    Abstract: A corrosion inhibitor formulation for oil and water systems which formulation is resistance to sludge formation and does not tend to stabilize oil/water emulsions when added to oil and water systems. The corrosion inhibitor include an imidazoline dissolved in an aromatic solvent, a 2-hydroxylakylcarboxylic acid such as glycolic acid and a glycol such as hexylene glycol. The imidazoline is preferably prepared from a long chain fatty acid and a polyamine in a molar ratio of about 1.5:1.
    Type: Grant
    Filed: May 9, 1990
    Date of Patent: November 5, 1991
    Assignee: Betz Laboratories, Inc.
    Inventor: T. Miles McCullough
  • Patent number: 5059339
    Abstract: A damping liquid for a hydraulic vibration-damping mount is composed of glycol, water and 2 to 20 weight % of age resistor having ozone resistance. The damping liquid gradually diffuses and infiltrates into a rubber member defining a liquid chamber of the hydraulic vibration-damping mount thereby remarkably improving the ozone resistance thereof.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: October 22, 1991
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Takamasa Suzuki, Katsumasa Takeuchi, Kazuya Ito
  • Patent number: 5034155
    Abstract: Composition for treating cooling water including a combination of ingredients for combatting a variety of problems, such as corrosion, scale control and microbiological growth. Composition obviates the necessity for separately feeding several materials. Compositon includes at least 1% sodium molybdate, at least 0.1% benzotriazole, at least 0.5% citric acid and at least 5% of a microbiocide.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: July 23, 1991
    Assignee: Jamestown Chemical Company, Inc.
    Inventors: Kenneth Soeder, Mitchel Helfeld
  • Patent number: 5019342
    Abstract: The present invention utilizes low volatility amines or alkanol amines to control caustic corrosion which can take place when a boiler system, treated with a coordinated phosphate/pH program, is "out of control".N-substituted hydroxyalkyl piperazines are also capable of mitigating caustic corrosion in coordinated phosphate/pH programs. Combinations of the compounds of the present invention and phosphate have also been shown to be efficacious at mitigating caustic corrosion in coordinated phosphate/pH programs.
    Type: Grant
    Filed: October 25, 1989
    Date of Patent: May 28, 1991
    Assignee: Betz Laboratories, Inc.
    Inventors: John A. Muccitelli, Nancy A. Feldman
  • Patent number: 4997583
    Abstract: A method is described for the inhibition of corrosion of carbon steels due to heavy brine corrosive attack, which employs As.sup.+z -containing composition.Corrosion inhibiting compositions comprising As.sup.+z, alone or in admixture with urea as a synergistic inhibitor, are also described.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: March 5, 1991
    Assignee: Bromine Compounds Ltd.
    Inventor: David Itzhak
  • Patent number: 4946616
    Abstract: A coolant composition for use in automotive engines is disclosed which comprises a liquid alcohol freezing depressant and a corrosion inhibitor consisting essentially of decanedioic acid, dodecanedioic acid and sodium tolyltriazole.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: August 7, 1990
    Assignee: The Dow Chemical Company
    Inventors: Daniel J. Falla, Peter H. Berchtold
  • Patent number: 4931196
    Abstract: The present invention provides a lubricant composition comprising a lubricating oil and, as a multifunctional additive, at least one compound of formula (I) ##STR1## in which R.sup.1 and R.sup.2 are, independently, hydrogen or C.sub.1 -C.sub.20 alkyl and R.sup.3 is hydrogen, C.sub.1 -C.sub.20 alkyl or a group of the formula ##STR2## wherein R.sup.4 is H or C.sub.1 -C.sub.20 alkyl. Most of the compounds of formula I are new.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: June 5, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Payne, Robert M. O'Neil
  • Patent number: 4911888
    Abstract: Specific sulfonamidocarboxylic acids in the form of the alkali metal or alkanolamine salts are used as corrosion inhibitors in aqueous systems.
    Type: Grant
    Filed: June 6, 1988
    Date of Patent: March 27, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Fikentscher, Gerold Braun, Chung-Ji Ischang, Christos Vamvakaris, Reinhold Kohlhaupt
  • Patent number: 4882413
    Abstract: A novel class of polymers and processes used in their preparation are described. The polymers are produced by a reaction between polyfunctional amines and quinones. Some are infusible and intractable. Others are eminently suitable for the production of coatings, adhesives, insulators, etc. Some polymers, in solution in appropriate solvents adhere to metals, siliceous materials, composites with sufficient affinity to displace water. The polymers can be cured by heat or chemicals to an impervious and insoluble material that is not wetted by water.
    Type: Grant
    Filed: May 24, 1988
    Date of Patent: November 21, 1989
    Inventor: Semih Erhan
  • Patent number: 4880907
    Abstract: Novel oligomeric quinolinium salts are disclosed. These are formed by reacting quinoline oligomers with alkylating agents such as benzyl halide, p-.alpha.-xylenyl dihalide and alkyl sulfates. The novel oligomeric quinolinium salts are useful as metal corrosion inhibitors, and especially as aqueous acid corrosion inhibitors. The novel compounds are represented by the formulae: ##STR1## wherein n and m are integers, with n being greater than 2 and up to about 200 and m being equal to or greater than 1, R is H or an alkyl group having from 1 to about 20 carbon atoms, R.sup.1 is an alkyl group having 1 to about 20 carbon atoms, X.sup.- is a chloride, bromide or iodide and Z.sup.- is an anion selected from BF.sub.4.sup.-, SO.sub.4.sup.=, ClO.sub.4.sup.-, PF.sub.6.sup.- and HSO.sub.4.sup.-.
    Type: Grant
    Filed: February 12, 1988
    Date of Patent: November 14, 1989
    Assignee: Exxon Research and Engineering Company
    Inventor: Long Y. Chiang
  • Patent number: 4877578
    Abstract: Water soluble corrosion inhibitors which exhibit low hydrocarbon carryunder are prepared by reaction of alkylenepolyamines and formaldehyde.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: October 31, 1989
    Assignee: Petrolite Corporation
    Inventors: Michael J. Zetlmeisl, William F. Fahey
  • Patent number: 4859418
    Abstract: Use of the compounds of the formula ##STR1## in which R.sub.1 denotes C.sub.12 -C.sub.26 -alkyl or C.sub.12 -C.sub.26 alkenyl, n denotes a number from 0 to 5, K.sup.(+) denotes a group of the formulae ##STR2## or a group of the formula --(C.sub.2 H.sub.4 O).sub.x H, x denotes a number from 1 to 3, A.sup.(- denotes an anion, R.sub.9 denotes a group of the formula R.sub.1 '-(OCH.sub.2 CH.sub.2).sub.n --, C.sub.8 -C.sub.18 -alkylaryl or aryl-C.sub.8 -C.sub.18 -alkyl, R.sub.1 ' denotes C.sub.14 -C.sub.22 -alkyl or C.sub.14 -C.sub.22 -alkenyl, n denotes a number from 0 to 5 and the radicals R.sub.10 are identical and denote C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -hydroxyalkyl, as corrosion protection agents for metallic materials in aqueous media.
    Type: Grant
    Filed: June 26, 1986
    Date of Patent: August 22, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dieter Ohlendorf, Werner Interthal, Friedrich Stoll
  • Patent number: 4851149
    Abstract: Acid cleaning/pickling compositions for metal surfaces containing (A) at least one protein-derived polymer, sugar-derived polymer, sorbitol, tannin, or vinyl-based polymer, (B) at least one iodine or iodine-affording compound; acids solutions prepared therefrom; and methods for their use.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: July 25, 1989
    Assignee: Henkel Corporation
    Inventor: Carmen M. Carandang
  • Patent number: 4830827
    Abstract: Included are novel perhydro-s-triazine derivatives, tentacular-perhydro-s-triazines. For example, 1,3,5-triazine-1,3,5-(2H,4H,6H)triethanol dioleate; 1,3,5-triazine-1,3,5-(2H,4H,6H)triethanethiol trioleate; and 1,3,5-triazine-1,3,5-(2H,4H,6H)tris(morpholinoethane) are included. The derivatives are corrosion inhibitors for metals. the compounds may also be used as emulsifiers, lubricants and hydraulic fluids.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: May 16, 1989
    Assignee: The Dow Chemical Company
    Inventors: Andrew T. Au, Hugh F. Hussey
  • Patent number: 4798683
    Abstract: A method for inhibiting corrosion in aqueous systems comprising adding to the system being treated an effective amount of a composition comprising a molybdate ion source and a water-soluble component selected from polymaleic acid anhydride, amine adducts of polymaleic anhydride, maleic anhydride copolymers, carboxylic acid/sulfonic acid polymers, salts of the above-described polymers, phosphonates, phosphino carboxylic acids, polyphosphoric acid and esters of polyphosphoric acid.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: January 17, 1989
    Assignee: Calgon Corporation
    Inventors: Bennett P. Boffardi, Susan P. Rey
  • Patent number: 4792464
    Abstract: There is disclosed a water-base coating composition and method for its use that forms a readily strippable protective film on metal surfaces. The composition includes a film former ingredient which is a terpolymer of polyvinyl butyral, polyvinyl alcohol and polyvinyl acetate. The water-base coating composition also contains a fugitive corrosion inhibitor, i.e., a corrosion inhibitor having a sufficient vapor pressure to impart corrosion resistance to surfaces coated with the film former composition. Suitable corrosion inhibitors are aromatic triazoles such as benzotriazole. A leveling agent such as morpholine is used to prevent the film from pulling from the edges during drying. Morpholine is particularly advantageous as it extends the working time when coating objects, and prevents the dispersion from clogging nozzles of spraying equipment. Morpholine also contributes to the corrosion inhibition of the coating.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: December 20, 1988
    Inventor: Irvin W. Martenson
  • Patent number: 4737159
    Abstract: A corrosion inhibitor for use in liquid hydrocarbon fuels or gasoline oxygenate blends is disclosed. The corrosion inhibitor contains from 35 to 70 wt % of a monoalkenylsuccinic acid wherein the alkenyl group has 8 to 18 carbon atoms, from about 30 to 65 wt % of an aliphatic or cycloaliphatic amine containing 2 to 12 carbon atoms and up to 50 wt % of total solvents consisting of aromatic hydrocarbons and alcohols of 1 to 4 carbons per molecule.The corrosion inhibitor can also be used in inhibited alcohol compositions such as those used in gasoline oxygenate blends.
    Type: Grant
    Filed: June 29, 1984
    Date of Patent: April 12, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Tayman A. Phillips
  • Patent number: 4687698
    Abstract: An improved makeready packing for preventing corrosion of cylinders of offset or lithographic printing presses which comprises providing a cylinder surface contacting packing element having a corrosion inhibitor applied thereto in such a manner that the inhibitor will effectively protect the entire surface of the cylinder.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: August 18, 1987
    Assignee: The Cromwell Paper Company
    Inventors: David M. Weil, Burton E. Lieberman, Ronald F. Adams
  • Patent number: 4686084
    Abstract: Benzoyl alanines of the formula ##STR1## in which R.sup.1 and R.sup.2 can be the same or different and represent hydrogen or an alkyl radical containing from 1 to 12 carbon atoms and R.sup.3 and R.sup.4 can be the same or different and represent hydrogen, an unbranched or branched alkyl radical containing from 1 to 10 carbon atoms, hydroxyalkyl, alkoxyalkyl, carboxyalkyl or alkylaminoalkyl radicals containing from 1 to 3 carbon atoms in the alkyl radicals and wherein R.sup.3 and R.sup.4 together can be the --CH.sub.2 CH.sub.2 --O--CH.sub.2 CH.sub.2 -- group or the --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 -- group which form with the nitrogen atom the morpholino or the piperidino ring, respectively; with the proviso that(a) when R.sup.1 is hydrogen or methyl and R.sup.2 and R.sup.3 are hydrogen, R.sup.4 cannot represent hydroxyethyl or carboxymethyl, and(b) when R.sup.1 is hydrogen or methyl and R.sup.2 is hydrogen R.sup.3 and R.sup.4 cannot both represent hydroxyethyl, and(c) when R.sup.1 and R.sup.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: August 11, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juergen Geke, Josef Penninger
  • Patent number: 4673436
    Abstract: Corrosion inhibition is obtained by treating a system containing corrosion susceptible metal with a corrosion inhibiting amount, preferably 1 to 10,000 ppm of a thio substituted quaternary ammonium salt, preferably of the general structure: ##STR1## wherein R.sub.1 is preferably H or an alkyl group of 8 to 18 carbon atoms, n is 2 or 3, R.sub.2, R.sub.3 and R.sub.4 are preferably alkyl groups of 1 to 18 carbon atoms and two of R.sub.2, R.sub.3 and R.sub.4 are methyl.
    Type: Grant
    Filed: April 22, 1986
    Date of Patent: June 16, 1987
    Assignee: Exxon Chemical Patents Inc.
    Inventors: John A. Haslegrave, Daniel S. Sullivan
  • Patent number: 4668474
    Abstract: The present invention is directed to a composition and method for inhibiting the corrosion of copper and copper alloy metals in aqueous systems. The composition comprises mercaptobenzothiazole and added ferrous ions in a ratio of 1:1 to 1:10, by weight. The method comprises adding this composition to the aqueous system being treated.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: May 26, 1987
    Assignee: Calgon Corporation
    Inventors: Jasbir S. Gill, Richard G. Varsanik
  • Patent number: 4664884
    Abstract: A corrosion inhibitor for ferrous and non-ferrous aqueous systems comprising (a) a water soluble phosphonic acid or salt thereof, preferably an amino methylene phosphonic acid; (b) a phosphonocarboxylic acid, preferably a phosphonoalkane carboxylic acid; and (c) a triazole, preferably benzotriazole or tolyltriazole.
    Type: Grant
    Filed: June 14, 1985
    Date of Patent: May 12, 1987
    Assignee: Drew Chemical Corporation
    Inventors: Michael A. Mullins, Peter A. Thomas
  • Patent number: 4602958
    Abstract: Corrosion inhibitor compositions comprising a mixture of (1) a volatile amine selected from the group consisting of cyclohexylamine, isopropylamine and morpholine and (2) a tertiary C.sub.12-14 alkylammonium carboxylate selected from the group consisting of a C.sub.12-14 alkylammonium benzoate and a tertiary C.sub.12-14 alkylammonium-N-oleoyl sarcosinate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: July 29, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4600530
    Abstract: Corrosion inhibitor compositions comprising a mixture of a nitroalkane containing 1-3 carbon atoms and a tertiary C.sub.12-14 alkylammonium carboxylate selected from the group consisting of a C.sub.12-14 alkylammonium benzoate and a tertiary C.sub.12-14 alkylammonium-N-oleoyl sarcosinate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: July 15, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4597895
    Abstract: Corrosion inhibitor compositions comprising a mixture of a nitroalkane containing 1-3 carbon atoms and a cocoamide of diethanolamine. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: July 1, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4584021
    Abstract: Corrosion inhibitor compositions comprising a mixture of nitroalkane containing 1-3 carbon atoms and an amine neutralized phosphate ester selected from the group consisting of 2-ethylhexylamine salt of mixed mono- and di-isooctyl acid phosphate, tertiary C.sub.12 alkyl primary amine salt of mixed mono- and di-isooctyl acid phosphate, diethylamine salt of mixed mono- and di-butoxyethyl acid phosphate and 2-ethylhexylamine salt of mixed mono- and di-tridecyl acid phosphate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: April 22, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4557966
    Abstract: An improved sheet material for corrosion inhibition of the surfaces of packaged ferrous metal products which comprises a sheet material substrate having a vapor phase corrosion inhibitor composition applied as a printed pattern of uniformly distributed spaced - areas of predetermined size occupying about 25% of the total area of the treated sheet and consisting of a total dried weight of about 0.226 to 0.302 grams of the inhibitor composition per square foot of the treated sheet.
    Type: Grant
    Filed: April 6, 1984
    Date of Patent: December 10, 1985
    Assignee: The Cromwell Paper Company
    Inventor: David M. Weil
  • Patent number: 4556110
    Abstract: A corrosion-inhibiting composition of matter comprising (1) the reaction mass resulting from the reaction of an .alpha.,.beta.-unsaturated hydrocarbyl nitrile and a metal hydrocarbyl sulfonate, (2) an alcohol, (3) a hydrocarbon diluent, and optionally (4) an epoxy resin. The composition is particularly useful in the treatment of downhole metal surfaces in oil and gas wells for inhibiting the corrosion of the metal.
    Type: Grant
    Filed: August 30, 1984
    Date of Patent: December 3, 1985
    Assignee: Phillips Petroleum Company
    Inventor: Yulin Wu
  • Patent number: 4554090
    Abstract: A combination corrosion and scale inhibitor composition comprising the reaction product of a heterocyclic nitrogen containing compound (e.g., mixtures of alkyl substituted pyridines) and aldehyde (e.g., formaldehyde) and a phosphoric acid constituent (e.g., phosphoric acid or phosphonic acid). Such compositions exhibit, simultaneously, inhibition to oxidation corrosion (rusting of carbon steel); suppression of sulfide corrosion (H.sub.2 S in NaCl brine) and the prevention of mineral scaling (CaCO.sub.3 and CaSO.sub.4 scale precipitation).
    Type: Grant
    Filed: March 9, 1984
    Date of Patent: November 19, 1985
    Inventor: Loyd W. Jones
  • Patent number: 4552678
    Abstract: The invention relates to novel compounds which are particularly suitable as corrosion inhibitors for aqueous liquids for the cleaning of metals, and especially as corrosion inhibitors for oil-free aqueous liquids used for the working of metals, in particular those exposed to corrosion. The compounds according to the invention correspond to the formula ##STR1## The invention also relates to a process for their preparation.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: November 12, 1985
    Inventors: Francesco Cargnino, Giuseppe Natoli, Horst Lorke
  • Patent number: 4552686
    Abstract: A composition which is noncorroding to metals in contact therewith includes water, an alkylene glycol and/or a polyoxyalkylene glycol, a polyoxyalkylene amine and substantially no inorganic nitrite. The polyoxyalkylene amine replaces the previously used inorganic nitrite to reduce the toxicity of the noncorroding composition.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: November 12, 1985
    Assignee: Texaco Inc.
    Inventors: Betty J. Morris-Sherwood, Edward C. Brink, Jr.
  • Patent number: 4518519
    Abstract: An improved, highly penetrating rust remover and/or degreaser composition for metallic surfaces is provided which is chemically inhibited to substantially prevent oxidation-reduction reactions with a metal substrate and limit the action of the composition to a chemical attack on corrosion. The composition is preferably a single phase dispersion and includes respective quantities of an acid such as hydrochloric acid and phosphoric acid, an organic compound containing a nitrogen, oxygen or sulfur atom such as N-(2-hydroxyethyl) oxazolidine, an alcohol or other organic solvent for grease removal, water and one or more emulsifiers (e.g., a derivative of hydrogenated tallow) for stabilizing and lowering the surface tension of the resultant composition.
    Type: Grant
    Filed: July 22, 1983
    Date of Patent: May 21, 1985
    Inventors: Peter F. Lott, Reiner E. Jargosch
  • Patent number: 4515708
    Abstract: Corrosion inhibition of metals is obtained treating a system with a corrosion-inhibiting amount, preferably 1 to 10000 ppm, of an optionally-substituted .beta.-pyridyl-ethylamine or a salt thereof, which may be prepared by reacting an amine with a vinylpyridine, preferably in the presence of an acidic catalyst such as acetic acid. The .beta.-pyridyl-ethylamine is a compound of the general formula: ##STR1## wherein R is an alkyl, aryl, aralkyl, alkaryl, halo or amino group of a group --COX where X is hydrogen, alkyl, aryl, hydroxy, alkoxy, aryloxy, amino or halo group, n is zero or an integer from 1 to 4, and R.sup.1 and R.sup.2, which may be the same or different, each represent a hydrogen atom, an optionally substituted hydrocarbyl radical, an alkylamino radical, a heterocyclic radical or a group ##STR2## or R.sup.1 and R.sup.2 with the intervening nitrogen atom together represent a saturated or unsaturated heterocyclic ring optionally containing one or more additional heteroatoms.
    Type: Grant
    Filed: November 16, 1983
    Date of Patent: May 7, 1985
    Assignee: Exxon Research & Engineering Co.
    Inventors: John A. Haslegrave, Daniel S. Sullivan
  • Patent number: 4512552
    Abstract: A corrosion inhibitor for ferrous metals comprising four different components of (a) an inorganic acid component (such as molybdate or tungstate), (b) an aliphatic hydroxycarboxylic or aliphatic dicarboxylic acid or its salt (such as citric acid, gluconic acid or succinic acid), (c) an inorganic heavy metal compound (such as zinc chloride or stannous chloride) and (d) a water soluble polymer component having a molecular weight of 500-100,000 (such as acylic homo or copolymer), which is especially advantageous for use in water recycling system.
    Type: Grant
    Filed: November 16, 1982
    Date of Patent: April 23, 1985
    Assignee: Katayama Chemical Works Co., Ltd.
    Inventors: Sakae Katayama, Tadahiko Asano, Kazuo Marugame, Sadaoki Kanada, Yoshinari Kawasaki
  • Patent number: 4511481
    Abstract: Synthesized- and mineral-based industrial lubricants are stabilized with a triazole adduct of amine phosphates thereby providing excellent oxidation stability, antiwear and rust preventative performance for said industrial lubricants.
    Type: Grant
    Filed: August 31, 1983
    Date of Patent: April 16, 1985
    Assignee: Mobil Oil Corporation
    Inventor: Joosup Shim
  • Patent number: 4502979
    Abstract: Corrosion of metallic surfaces by aqueous alkanolamine solutions employed in acid gas removal is inhibited by combinations of particular vanadium compounds and an organic compound selected from the group consisting of nitro-substituted aromatic acids, nitro-substituted acid salts, and 1,4-naphthoquinone, preferably from the group consisting of p-nitrobenzoic acid, m-nitrobenzoic acid, 3,5-dinitrobenzoic acid, p-nitrophenol, m-nitrophenol, m-nitrobenzenesulfonic acid, 1,4-naphthoquinone, and mixtures thereof.
    Type: Grant
    Filed: November 29, 1982
    Date of Patent: March 5, 1985
    Assignee: Union Carbide Corporation
    Inventors: John G. McCullough, Kenneth J. Barr
  • Patent number: 4479917
    Abstract: An oxygen-scavenging and corrosion-inhibiting agent for fluidic systems comprising an aminoguanidine compound selected from the formula: ##STR1## or a salt thereof, wherein R is selected from H or a lower alkyl group having 1 to 4 carbon atoms; wherein X is selected from NH or NNH.sub.2 ; and Y is selected from --NH.sub.2 or --NHNH.sub.2.
    Type: Grant
    Filed: November 14, 1983
    Date of Patent: October 30, 1984
    Assignee: Olin Corporation
    Inventors: Eugene F. Rothgery, Steven A. Manke
  • Patent number: 4432847
    Abstract: Poly sulfoxides of the general formula ##STR1## where each R is a monovalent aliphatic radical bound to a sulfoxy group. Each R is defined as being individually selected from the group consisting of ##STR2## wherein R', R" and R"' are individually selected from the group consisting of alkyl moieties containing 1 to 22 carbon atoms, and aralkyl moieties, alkylated aryl moieties, heterocyclic alkyl moieties, cycloalkyl moieties containing 4 to 40 carbon atoms wherein the said moieties are joined to the sulfoxy group through the alkyl chain, the said moieties being unsubstituted and substituted, said substitutions being individually selected from the group consisting of halogen moieties, nitro moieties, alkoxy moieties, alkyl moieties, and dialkylamino moieties.
    Type: Grant
    Filed: July 29, 1976
    Date of Patent: February 21, 1984
    Assignee: Standard Oil Company (Indiana)
    Inventor: Ellis K. Fields
  • Patent number: 4382008
    Abstract: Corrosion inhibitors for aqueous media comprise a triazole, an alkali metal borate, benzoate, and silicate and an alkali metal salt of a C.sub.7 to C.sub.13 dibasic acid. They may be used in antifreeze compositions for motor vehicles. Since neither nitrites and amines are required the danger of forming toxic nitrosamines by the reaction of these materials is overcome.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: May 3, 1983
    Assignee: Imperial Chemical Industries Limited
    Inventors: William Boreland, John M. Dossor, Geoffrey S. Jaques
  • Patent number: 4376635
    Abstract: A novel fuel composition contains ethanol or gasohol plus, as a corrosion inhibitor, a reaction product of benzotriazole, formaldehyde, and an N-alkyl propylene diamine.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: March 15, 1983
    Assignee: Texaco Inc.
    Inventor: Rodney L. Sung
  • Patent number: 4364846
    Abstract: A method is provided for preventing haze formation in a carburetor detergent and corrosion inhibiting fuel additive which is prepared by reacting a mole of maleic anhydride with from about 2 to 4 moles of a mixture of N-alkyl propane diamines of a specific alkyl chain distribution in the presence of from about 0.5 to 5 weight percent based on the N-alkyl propane diamine mixture of a phenolic antioxidant.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: December 21, 1982
    Assignee: Texaco Inc.
    Inventor: Benjamin J. Kaufman
  • Patent number: 4354872
    Abstract: A highly stable metal oxide oil slurry useful in reducing slag, facilitating removal of deposits from boiler tubes, and reducing corrosion on the heating surfaces of boilers has been developed. Such a slurry consists essentially of about 50% by weight magnesium oxide or the entity of magnesium oxide and alumina oxide, together with an oil-soluble emulsifier such as alkanolamide and preferably ethanolamide, or an alkanol with a carbon chain greater than a C.sub.3 alcohol, an oil-soluble dispersant such as a C.sub.12 -C.sub.22 entity selected from an unsaturated or saturated fatty acid; e.g., oleic acid. Also, as a constituent is an anionic surfactant such as magnesium lauryl sulfate in an oil base such as No. 2 fuel oil. The alkanolamide is fashioned from heating alkanolamines and fatty acids either in a 1:1 ratio or 2:1 ratio. The reactant amino alcohol is in the range C.sub.10 -C.sub.24. The alcohol itself is greater than C.sub.3 and up to C.sub.16, with a preferred range C.sub.12 -C.sub.16.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: October 19, 1982
    Assignee: Nalco Chemical Company
    Inventors: George T. Kekish, Mei-Jan L. Lin, John H. Collins
  • Patent number: 4354028
    Abstract: Novel amide acetals of the formula ##STR1## wherein R.sub.1 is hydrogen, methyl or Y and Y is the remnant of a hydroxyl-containing compound are claimed. The compounds are useful as water scavengers in fluid compositions.
    Type: Grant
    Filed: April 9, 1981
    Date of Patent: October 12, 1982
    Assignee: The Dow Chemical Company
    Inventors: John Martin, George A. Doorakian, Lawrence G. Duquette
  • Patent number: 4351973
    Abstract: A stabilized methylchloroform for use in vapor degreasing which is stable in the presence of metals which contains pyrazine, dimethoxypropane, an acetylenic alcohol and a nitroalkane or a methylfuran. Such combination prevents corrosion of aluminum, iron, copper and zinc and the decomposition of the solvent.
    Type: Grant
    Filed: October 6, 1980
    Date of Patent: September 28, 1982
    Assignee: The Dow Chemical Company
    Inventors: Nobuyuki Ishibe, Warren F. Richey
  • Patent number: 4348302
    Abstract: Anticorrosive agent stable to hard water, which comprises an alkali metal salt, alkaline earth metal salt, or amine salt of a compound of the formula ##STR1## in which R.sub.1 is branched C.sub.6 -C.sub.13 -alkyl or C.sub.5 - or C.sub.6 -cycloalkyl, or polycycloalkyl having from 6 to 13 carbon atoms optionally substituted by 1 or 2 C.sub.1 -C.sub.4 -alkyl groups,R.sub.2 is hydrogen or C.sub.1 -C.sub.6 -alkyl, andR.sub.3 is C.sub.1 -C.sub.11 -alkylene in linear or branched chain.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: September 7, 1982
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Horst Frohlich, Rainer Helwerth