Sulphur Organic Compound Containing Patents (Class 252/395)
  • Patent number: 11168402
    Abstract: The present invention provides a novel metal corrosion inhibitor containing a compound having a specific structure.
    Type: Grant
    Filed: February 18, 2019
    Date of Patent: November 9, 2021
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takeshi Takayama, Masashi Tonoya
  • Patent number: 9493600
    Abstract: To provide a novel polymer having an excellent non-specific adsorption inhibitory effect, a surface-hydrophilizing agent comprising the polymer, and a method for producing a substrate having a hydrophilic surface. The polymer comprises a hydrophilic repeating unit having a sulfinyl group in a side chain thereof.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: November 15, 2016
    Assignee: JSR CORPORATION
    Inventors: Naoki Hayashi, Toshihiro Ogawa, Shin-ichirou Iwanaga, Kazuhiro Iso
  • Publication number: 20150010429
    Abstract: The invention provides the use of a surfactant as a corrosion inhibitor, wherein the surfactant is selected from derivatives of alkyl polyglucosides and derivatives of terpene alkoxylates, and mixtures thereof, provided that the derivatives are not sulfosuccinates. Also provided is a method of preventing or reducing corrosion of a metal component that is in contact with, or will be in contact with, an aqueous fluid, wherein the method comprises providing a surfactant and applying the surfactant to the metal component or adding the surfactant to the aqueous fluid that is in contact with, or will be in contact with, the metal component, wherein the surfactant is selected from derivatives of alkyl polyglucosides and derivatives of terpene alkoxylates, and mixtures thereof, provided that the derivatives are not sulfosuccinates.
    Type: Application
    Filed: January 30, 2013
    Publication date: January 8, 2015
    Inventors: Kevan Hatchman, Alan Fellows, Christopher Raymond Jones, Gareth Collins
  • Publication number: 20140315004
    Abstract: Corrosion inhibition systems, including coated substrates, coating materials and corrosion inhibition compounds, and methods of making the same are disclosed. These systems and methods include corrosion inhibition compounds that are responsive to corrosion at a surface, releasing active inhibitor groups upon a corrosion stimulus. The active inhibitor groups are selected to block corrosion at the surface by inhibiting oxidation reactions, reduction reactions and/or by forming a passivation layer.
    Type: Application
    Filed: April 19, 2013
    Publication date: October 23, 2014
    Applicant: The Boeing Company
    Inventor: The Boeing Company
  • Patent number: 8828915
    Abstract: The invention relates to novel thixotropic corrosion protection additives, to carrier substances comprising these corrosion protection additives, to processes for their preparation and to their use for preservative liquids and lubricating greases.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: September 9, 2014
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Markus Kuilder, Steffen Sandhöfner
  • Patent number: 8795784
    Abstract: Aqueous oil-in-water emulsion comprising from 1 to 70% by weight, based on the total weight of the emulsion, of functional alkoxysilanes and/or condensed oligomers thereof and/or organoalkoxysiloxanes, at least one emulsifier and water, wherein the emulsion has a pH of from 5 to 9 and preferably a mean droplet size of the disperse phase of ?0.5 ?m, and the width of the droplet size distribution, expressed as the span (Formula I), is from 0.6 to 1.2. The preparation of the emulsions having the desired droplet size distribution is carried out in apparatuses having at least one pressure stage at a pressure of from 2 to 15 MPa. The emulsion can be used for hydrophobicizing porous mineral building materials.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: August 5, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Burkhard Standke, Kerstin Weissenbach, Bernd Bartkowiak
  • Patent number: 8779035
    Abstract: Non-chromated corrosion inhibiting primer formulations having one or more active corrosion inhibitors covalently anchored, or optionally covalently anchored, onto an organic and/or inorganic reactive specie are provided herein.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: July 15, 2014
    Assignee: Cytec Technology Corp.
    Inventors: Kunal Gaurang Shah, Dalip Kumar Kohli
  • Patent number: 8765020
    Abstract: Mitigating or preventing corrosion of metal may be achieved in systems that are alkaline, such as carbon dioxide capture systems. The method may include adding an additive to a system wherein the system is at an alkaline pH; the system has both O2 and CO2 present; or the system is at an alkaline pH and has both O2 and CO2 present. The additive may be selected from the group consisting of: quaternary aromatic amines; quaternary alkyl substituted aromatic amines; and combinations thereof. The corrosion inhibiting properties of the additives may be increased by use of synergistic combinants. The abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    Type: Grant
    Filed: May 17, 2010
    Date of Patent: July 1, 2014
    Assignee: Baker Hughes Incorporated
    Inventors: Ksenija Babić-Samard{hacek over (z)}ija, Lawrence N. Kremer, David J. Poelker, Vladimir Jovancicevic, Sunder Ramachandran
  • Patent number: 8642698
    Abstract: The invention relates to a copolymerizable emulsifier comprising (meth)acrylic acid esters, selected from compounds of the general formula (1) and (II), where: A is an acrylic group having 3 to 40 carbon atoms, x and y independently of each other are a hydrogen group or a methyl group, B is hydrogen or a sulfate or phosphate group, and n a number in the range of 0 to 40. The invention further relates to methods of using said copolymerizable emulsifier in the emulsion polymerization of olefinically unsaturated monomers to prepare polymers.
    Type: Grant
    Filed: November 26, 2009
    Date of Patent: February 4, 2014
    Assignee: Cognis IP Management GmbH
    Inventors: Ronald Klagge, Thomas Schliwka, Uwe Held, Thomas Mausberg, Katharina Hömberg, Stefan Busch, Shailesh C. Shah
  • Patent number: 8460445
    Abstract: The present invention relates to new coating materials for corrosion control.
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: June 11, 2013
    Assignee: BASF SE
    Inventors: Konrad Roschmann, Virginie Bette, Stephan Amthor, Hermann Bergmann, Marc Schroeder
  • Publication number: 20130142977
    Abstract: The present invention includes compositions and methods of supplying a corrosion inhibitor including placing a corrosion inhibitor attached to a nanostructure carrier, placing the nanostructure carrier containing the corrosion inhibitor at a location and the nanostructure carrier is capable of releasing the corrosion inhibitor.
    Type: Application
    Filed: January 28, 2013
    Publication date: June 6, 2013
    Applicant: NATIONAL OILWELL VARCO, L.P.
    Inventor: NATIONAL OILWELL VARCO, L.P.
  • Publication number: 20130055629
    Abstract: Compositions and methods for reducing stress corrosion cracking in steel vessels used for storing and/or transporting ethanol-containing fluids. Additives including oxygen scavengers and film-forming additives can be employed together in such ethanol-containing fluids (e.g., fuel grade ethanol) to mitigate stress corrosion cracking in steel vessels, such as pipelines, storage tanks, rail cars, and/or tanker trucks.
    Type: Application
    Filed: September 6, 2011
    Publication date: March 7, 2013
    Applicant: MIDCONTINENTAL CHEMICAL COMPANY, INC.
    Inventor: Philip S. Korosec
  • Publication number: 20130017612
    Abstract: Methods to produce pH-sensitive microparticles that have an active agent dispersed in a polymer matrix have certain advantages over microcapsules with an active agent encapsulated in an interior compartment/core inside of a polymer wall. The current invention relates to pH-sensitive microparticles that have a corrosion-detecting or corrosion-inhibiting active agent or active agents dispersed within a polymer matrix of the microparticles. The pH-sensitive microparticles can be used in various coating compositions on metal objects for corrosion detecting and/or inhibiting.
    Type: Application
    Filed: July 5, 2012
    Publication date: January 17, 2013
    Applicant: United States of America as Represented by the Administrator of the National Aeronautics and Spac
    Inventors: Wenyan LI, Jerry W. BUHROW, Scott T. JOLLEY, Luz M. CALLE
  • Publication number: 20130005626
    Abstract: A surfactant composition comprising alkylarylsulfonate molecules wherein more than 30 wt. % of the alkylarylsulfonate molecules of the surfactant composition are species of the formula: [R—X—Ar(SO3)?]a[Mn+]b wherein: X is a linear acyclic aliphatic hydrocarbyl chain; R is bound to a non-terminal carbon atom of X and is selected from H and C1 to C3 alkyl groups; X and R together have 10 or less carbon atoms, preferably 9 or 10 carbon atoms, most preferably 10 carbon atoms; Ar is an aromatic group; M is a cation or cation mixture, n is selected from 1, 2 and 3; and a and b are selected such that the alkylarylsulfonate molecule is electroneutral.
    Type: Application
    Filed: June 28, 2011
    Publication date: January 3, 2013
    Inventors: Burkhard Breitzke, Britta Jakobs-Sauter, Clemens Schröder, Udo Schoenkaes, Giuseppe Giuffrida, Lee Matheson, Kermit Kinsley, Michael Cox, Geoffrey Lynn Russell, John Barry Winder
  • Patent number: 8303850
    Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: November 6, 2012
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Junichi Shibata, Tadaaki Motoyama, Kazuhiko Endou
  • Publication number: 20120217443
    Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.
    Type: Application
    Filed: July 17, 2010
    Publication date: August 30, 2012
    Applicant: JX Nippon Oil & Energy Corporation
    Inventors: Junichi Shibata, Tadaaki Motoyama, Kazuhiko Endou
  • Publication number: 20120187344
    Abstract: The present invention relates to poly[2,2?-(3-alkyl-acetate)thiophene] polythiophenes of linear C1-C12 alkyls of formula (I) which are easily dispersible in alkyd and epoxy type paints, and the addition of 1% of the electroconductive polymer allows the use thereof as anti-corrosive additives and as anti-corrosion microparticles of regulatable properties. The addition of 1% of electroconductive poly[2,2?-(3-methylacetate)thiophene] (PTE) polymer in the alkyd and epoxy priming paint substantially improves the adherence, blistering and resistance to corrosion properties of steel, especially in marine and industrial environments, even with performances better than other polyaniline-based conductive polymers. The substitution of zinc and its derivatives with the electroconductive poly[2,2?-(3-alkyl-acetate)thiophene] (PTE) polymers in anti-corrosive epoxy and alkyd priming paints is technologically viable and, as a consequence, reduces the aggressive effect caused by these transition metals on the environment.
    Type: Application
    Filed: December 14, 2010
    Publication date: July 26, 2012
    Inventors: Elaine Armelin Diggroc, Carlos Alemán Llansó, José Ignacio Iribarren Laco, Francisco Liesa Mestres, Francesc Estrany Coda
  • Patent number: 8123982
    Abstract: Alternative inhibitors that offer an improvement over tolyltriazole in inhibiting yellow metal corrosion. The dithiocarbamate compounds and their salts were compared to that of tolyltriazole under identical conditions. These comparative tests were conducted in common corrosion testing systems, using both electrochemical corrosion cells and pilot cooling rigs, using various water conditions. The test methods included electrochemical studies such as linear polarization resistance, open circuit potential versus time, Tafel and cyclic polarization.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: February 28, 2012
    Assignee: Akzo Nobel N.V.
    Inventors: Eric C. Ward, Alvie L. Foster, Jr., Michael L. Standish, Ivonne C. Weidner
  • Publication number: 20110294710
    Abstract: The invention relates to novel thixotropic corrosion protection additives, to carrier substances comprising these corrosion protection additives, to processes for their preparation and to their use for preservative liquids and lubricating greases.
    Type: Application
    Filed: February 18, 2011
    Publication date: December 1, 2011
    Applicant: RHEIN CHEMIE RHEINAU GMBH
    Inventors: Markus Kuilder, Steffen Sandhöfner
  • Patent number: 8025840
    Abstract: Methods and compositions are provided for corrosion inhibition treatment of aqueous systems such as cooling water systems. The methods include conjoint use of a polyvalent metal ion, such as Al or Mn and a corrosion inhibitor/deposit control agent (DCA) to the water system. The corrosion inhibitor DCA agent may be an organic compound such as a hydroxyacid, phosphonocarboxylic acid, polyhydroxysuccinic acid, or polymaleic acid or anhydride.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: September 27, 2011
    Assignee: General Electric Company
    Inventors: Rosa Crovetto, Claudia C. Pierce, Philip D. Deck
  • Patent number: 8021607
    Abstract: Methods are provided to inhibit corrosion of metals in contact with aqueous systems such as cooling water systems. In accordance with the methods, a hydroxyacid compound and orthophosphates are used to treat the system. Additionally, an adjuvant including poly(epoxysuccinic acids), an additional hydroxy acid, and a polycarboxylic acid, may be added to the system water.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: September 20, 2011
    Assignee: General Electric Company
    Inventors: Claudia C. Pierce, Philip D. Deck, Rosa Crovetto, Beena George, Rajendra Prasad Kalakodimi, Guruprasad Sundararajan, Donald Wayne Whisenhunt, Jr.
  • Patent number: 7820076
    Abstract: The invention relates to an oleaginous mildew and corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion and mildew. The composition comprises, in parts by weight, from about 20 to 60 parts of an oleaginous material such as a lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.0 to 5.0 parts of a water-displacing compound, an effective amount of a mildew-inhibiting compound, and from 0.0 to 1.0 part of a heterocyclic metal deactivator.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: October 26, 2010
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: El Sayed S. Arafat, Craig A. Matzdorf, James A. Whitfield
  • Patent number: 7776233
    Abstract: The invention relates to an oleaginous corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion. The composition comprises, in parts by weight, from about 20 to 60 parts of lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.1 to 5.0 parts of a water-displacing compound and from 0.0 to 1.0 part of a metal deactivator.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: August 17, 2010
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: El Sayed Arafat, Judy Butler-Kowalik, Kenneth Clark, David L. Gauntt
  • Patent number: 7686980
    Abstract: Compositions for actively inhibiting corrosion are described herein that include at least one active corrosion inhibitor compound, and at least one conventional corrosion inhibitor compound. In addition, methods for producing a composition that actively reduces corrosion are described herein and include providing at least one active corrosion inhibitor, providing at least one conventional corrosion inhibitor compound or corrosion protection compound, and blending the at least one active corrosion inhibitor and the at least one conventional corrosion inhibitor compound or corrosion protection compound to form the composition. In addition, a composition for actively inhibiting corrosion is described herein that includes at least one active corrosion inhibitor compound, wherein the at least one active corrosion inhibitor compound comprises a derivative or salt of a thio-, thia- or dithiocarbarnic acid, or a combination thereof and at least one conventional corrosion inhibitor compound.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: March 30, 2010
    Assignee: Teledyne Scientific & Imaging, LLC
    Inventors: Martin Kendig, Melitta Hon, Les Warren
  • Patent number: 7662312
    Abstract: A pigment grade corrosion inhibitor and a method of applying the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1?x M(III)x (OH?)2] [An?x/n.y H2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An? is an anionic species, preferably with the species present in a range of: 0.2?M(III)/(M(II)+M(III))?0.4. The guest species include: various phosphoric acids and derivatives thereof; boric acid; cyanamidic acid; nitrous acid; derivatives of thio- and dithiocarbonic acid; thio-organic compounds functionalized with at least one —SH group of acidic character, including: 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4 thiadiazole, trithiocyanuric acid (TMT), and dithiocyanuric acid.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: February 16, 2010
    Assignee: Wayne Pigment Corp.
    Inventors: John Sinko, Martin W. Kendig
  • Publication number: 20090286002
    Abstract: The present invention relates to multilayer coatings suitable for use in the painting of aircraft. More particularly, the invention relates to a radiation primer coat and a topcoat.
    Type: Application
    Filed: August 17, 2007
    Publication date: November 19, 2009
    Inventors: Erick B. Iezzi, Mark P. Bowman, David N. Walters
  • Publication number: 20090277625
    Abstract: Described herein are compositions for reducing or preventing the degradation of equipment and articles exposed to hydrogen sulfide present in high concentrations in subterranean environments (e.g., oil and gas wells). The compositions are composed of a thermoplastic resin, a thermosetting resin, or a combination thereof, and at least one compound that interacts with hydrogen sulfide from the subterranean environment. In certain aspects, the compositions are coated on the article of interest. In other aspects, the composition is used to manufacture the article and, thus, is integrated throughout the article.
    Type: Application
    Filed: February 24, 2009
    Publication date: November 12, 2009
    Applicant: SCHLUMBERGER TECHNOLOGY CORP.
    Inventors: YUN BAI, TIMOTHY G.J. JONES, BERNADETTE CRASTER, AHMED HAMMAMI, TODD YAKIMOSKI
  • Patent number: 7601280
    Abstract: Methods and compositions are described for protecting a metal surface against corrosion. The method involves applying to the metal surface a coating formulation that comprises a radiation curable resin and a corrosion-responsive agent that is capable of releasing a corrosion-inhibiting ion in response to exposure to ionic species characteristic of those present on a metal surface undergoing oxidative corrosion; and exposing the coating formulation to radiation whereby the radiation curable resin forms a corrosion-resisting coating having a low spontaneous release rate of the corrosion-responsive agent into the environment.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: October 13, 2009
    Assignee: Lumimove, Inc. A Missouri Corporation
    Inventor: Patrick J. Kinlen
  • Publication number: 20090072199
    Abstract: A waterborne thermoset cured anticorrosion formulation includes a water dispersed or emulsified phosphonated or water dispersed or emulsified sulfonated epoxy resin that is cured with a phenoxy resin having a polyhydroxyl ether backbone and terminal alpha glycol moieties. Water is present as a predominant volatile in which the epoxy resin and phenoxy resin are present in a weight ratio of epoxy resin to phenoxy resin of between 0.1 and 3:1. An aqueous curative is provided to induce cure between the epoxy resin and phenoxy resin, A corrosion inhibiting metal salt is also present having a salt anion of phosphate, biphosphate or tetraborate and a metal cation with the proviso that the metal cation formulation as a whole is devoid of chromium, lead, cobalt, and cadmium. Ideal curatives include aqueous aminoplast crosslinkers, aqueous unblocked isocyanates, aqueous blocked isocyanates, and a mixture thereof.
    Type: Application
    Filed: September 18, 2008
    Publication date: March 19, 2009
    Applicant: Martinrea Industries, Inc.
    Inventors: Ronald J. Lewarchik, Scott Rier
  • Publication number: 20090065736
    Abstract: Chemically modified maleated fatty acid compositions and the salts thereof, especially chemically modified tall oil fatty acid containing compositions are useful in formulating corrosion inhibitors, as emulsifiers, as collectors in mining applications, and as cross-linking agents, such compositions find particular utility for petroleum-related applications.
    Type: Application
    Filed: July 2, 2008
    Publication date: March 12, 2009
    Applicant: GEORGIA-PACIFIC CHEMICALS LLC
    Inventors: Roger Scott Johnson, Phillip W. Hurd, John B. Hines, Brett Neumann
  • Patent number: 7491318
    Abstract: The invention relates to a method for prevention of corrosion by naphthenic acids in a refinery comprising the use of a compound of the formula HS—B—COOR, where B is a saturated bivalent 1-18 C hydrocarbon and R is H, alkaline or alkaline earth metal, ammonium, straight or branched alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl with 1-18 C atoms.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: February 17, 2009
    Assignee: Arkema France
    Inventor: Francis Humblot
  • Patent number: 7485177
    Abstract: A corrosion inhibiting mixture is disclosed comprising a carrier, a volatile corrosion inhibitor and a tracing agent which absorbs light in the ultraviolet and violet region of the electromagnetic spectrum, and re-emits light in the blue region of the electromagnetic spectrum.
    Type: Grant
    Filed: July 20, 2007
    Date of Patent: February 3, 2009
    Assignee: SKS Industries
    Inventors: Robin McConnell, Wesley Raymond Measel, Jr.
  • Publication number: 20080272341
    Abstract: Methods and compositions are described for protecting a metal surface against corrosion. The method involves applying to the metal surface a coating formulation that comprises a radiation curable resin and a corrosion-responsive agent that is capable of releasing a corrosion-inhibiting ion in response to exposure to ionic species characteristic of those present on a metal surface undergoing oxidative corrosion; and exposing the coating formulation to radiation whereby the radiation curable resin forms a corrosion-resisting coating having a low spontaneous release rate of the corrosion-responsive agent into the environment.
    Type: Application
    Filed: July 8, 2008
    Publication date: November 6, 2008
    Applicant: Lumimove,Inc. dba CROSSLINK POLYER RESEARCH
    Inventor: Patrick J. Kinlen
  • Publication number: 20080258114
    Abstract: A pigment grade corrosion inhibitor and a method of applying the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1-x M(III)x (OH?)2] [An?x/n·y H2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An? is an anionic species, preferably with the species present in a range of: 0.2?M(III)/(M(II)+M(III))?0.4. The guest species include: various phosphoric acids and derivatives thereof; boric acid; cyanamidic acid; nitrous acid; derivatives of thio- and dithiocarbonic acid; thio-organic compounds functionalized with at least one —SH group of acidic character, including: 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4 thiadiazole, trithiocyanuric acid (TMT), and dithiocyanuric acid.
    Type: Application
    Filed: November 1, 2007
    Publication date: October 23, 2008
    Inventors: John Sinko, Martin W. Kendig
  • Publication number: 20080187673
    Abstract: Aqueous oil-in-water emulsion comprising from 1 to 70% by weight, based on the total weight of the emulsion, of functional alkoxysilanes and/or condensed oligomers thereof and/or organoalkoxysiloxanes, at least one emulsifier and water, wherein the emulsion has a pH of from 5 to 9 and preferably a mean droplet size of the disperse phase of ?0.5 ?m, and the width of the droplet size distribution, expressed as the span (Formula I), is from 0.6 to 1.2. The preparation of the emulsions having the desired droplet size distribution is carried out in apparatuses having at least one pressure stage at a pressure of from 2 to 15 MPa. The emulsion can be used for hydrophobicizing porous mineral building materials.
    Type: Application
    Filed: December 8, 2005
    Publication date: August 7, 2008
    Applicant: DEGUSSA GmbH
    Inventors: Burkhard Standke, Kerstin Weissenbach, Bernd Bartkowiak
  • Patent number: 7396802
    Abstract: The reaction of the disulphided oil, as obtained from the caustic wash of liquefied petroleum gas, with 2,3,8,9,13,14-hexathia-5,6,11,12 -tetraazatricyclo [8.2.1.14,7]tetradeca-4,6,10,12-tetraene was carried out in one pot and one step to yield a corrosion inhibiting composition comprising predominantly of 2,5-bis(methyldithio)-1,3,4-thiadiazole, 2-methylthio-5-ethylthio-1,3,4-thiadiazole and 2,5-bis(ethyldithio)-1,3,4-thiadiazole, for application in fuels, lubes and greases.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: July 8, 2008
    Assignee: Indian Oil Corporation Limited
    Inventors: Pankaj Kumar Mondal, Khem Chand Dohhen, Rakesh Sarin, Deepak Kumar Tuli, Ram Prakash Verma, Akhilesh Kumar Bhatnagar
  • Publication number: 20080152931
    Abstract: A method of imparting corrosion resistance to an edge of a multilayer window film having a metal layer arranged between a pair of polymeric layers includes the step of treating the edge of the window film with a corrosion inhibitor.
    Type: Application
    Filed: December 21, 2006
    Publication date: June 26, 2008
    Inventors: Raghunath Padiyath, Josh D. Tibbits
  • Publication number: 20080001125
    Abstract: Corrosion induced by the presence of naphthenic acids in hydrocarbon fluids, particularly where such fluids are at elevated temperatures, may be inhibited or controlled through use of corrosion inhibiting compositions comprising a combination of a minor portion of a phosphorus-based constituent and a major portion of a sulfur-based constituent, nitrogen-based constituent, or combination thereof. In another embodiment the sulfur-based constituent and/or nitrogen-based constituent may be used without any phosphorus-based constituent. Where the compounds are appropriately selected, the compositions may inhibit corrosion to a degree comparable or nearly comparable to the inhibition provided by an equal amount of some conventional phosphorus-based compounds alone, but are significantly less likely to impair catalyst activity in downstream cracking and refinery operations.
    Type: Application
    Filed: November 17, 2006
    Publication date: January 3, 2008
    Applicant: Baker Hughes Incorporated
    Inventors: Michael J. Zetlmeisl, Bradley G. Harrell, Bradley G. Borgard, Scott Bieber
  • Patent number: 6974553
    Abstract: The corrosion of metals in contact with aqueous alkanolamine solutions in acid gas removal units is inhibited by adding to the alkanolamine solution a corrosion inhibiting amount of a polythiaether compound.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: December 13, 2005
    Assignee: GE Betz, Inc.
    Inventors: Zen-Yu Chang, Liliana Minevski, Ping Lue
  • Publication number: 20040076542
    Abstract: The corrosion of metals in contact with aqueous alkanolamine solutions in acid gas removal units is inhibited by adding to the alkanolamine solution a corrosion inhibiting amount of a polythiaether compound.
    Type: Application
    Filed: October 15, 2002
    Publication date: April 22, 2004
    Inventors: Zen-Yu Chang, Liliana Minevski, Ping Lue
  • Patent number: 6706214
    Abstract: A composition and process for inhibiting the corrosion of metallic substrates is revealed. The process utilizes an aqueous treatment solution comprising chitosan which has been reacted with an additive selected from the group consisting of phosphorus-containing compounds and sulfur-containing compounds and mixtures thereof. More preferably, the phosphorus-containing compound is a phosphonic acid and the sulfur-containing compound is a mercapto, thio, or thienyl containing compound or a mercapto functional silane. The composition and process are particularly useful in providing corrosion protection for aluminum and aluminum alloys.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: March 16, 2004
    Inventor: Gerald Wojcik
  • Patent number: 6699822
    Abstract: Sulfated dicarboxylic acids, amine salts thereof, or inorganic salts thereof may be used in various applications, including use as corrosion-inhibiting additives (e.g., in oil-field drilling applications and in metalworking applications), as emulsifiers (e.g., in metalworking applications), and as lubricity-enhancing additives (e.g., in metalworking applications).
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: March 2, 2004
    Assignee: Georgia-Pacific Resin, Inc.
    Inventors: Michael C. Bruner, Arnold Netzel, Phillip W. Hurd
  • Publication number: 20030232728
    Abstract: Sulfated dicarboxylic acids, amine salts thereof, or inorganic salts thereof may be used in various applications, including use as corrosion-inhibiting additives (e.g., in oil-field drilling applications and in metalworking applications), as emulsifiers (e.g., in metalworking applications), and as lubricity-enhancing additives (e.g., in metalworking applications).
    Type: Application
    Filed: June 7, 2002
    Publication date: December 18, 2003
    Applicant: Georgia-Pacific Resins, Inc.
    Inventors: Phillip W. Hurd, Michael C. Bruner, Arnold Netzel
  • Patent number: 6645399
    Abstract: Compositions and methods have been discovered for inhibiting corrosion of metals, particularly iron alloys, in contact with fluids, either hydrocarbons, alcohols, or aqueous fluids, employing mercaptoalcohols. The mercaptoalcohols should have at least one water solubilizing hydroxyl group. In particular, suitable mercaptoalcohols have the formula: (HS)n—R—)(OH)m where R is a straight, branched, cyclic or heterocyclic alkylene, arylene, alkylarylene, arylalkylene, or hydrocarbon moiety having from 1 to 30 carbon atoms; n and m each independently averages from 1 to 3; and the heteroatom in the heterocyclic moiety substituent, if present, may be N, O, S and/or P. Preferred mercaptoalcohols include 2-mercaptoethanol, 2-mercaptopropanol, 1-mercapto-2-propanol, and 2-mercaptobutanol, in part because they are soluble in many fluids. These corrosion inhibitors show improved inhibition of both generalized and localized corrosion, specifically in high shear and high flow environments.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: November 11, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: Young Soo Ahn, Vladimir Jovancicevic
  • Patent number: 6592781
    Abstract: A novel composition of thiazolidines of the following formula and a method to prepare the same are disclosed. The method involves reacting a dihydrothiazole with a mixture comprising formic acid and an aldehyde. These new thiazolidines are useful as corrosion inhibitors.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: July 15, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: Bernardus Antonius Maria Oude Alink, Benjamin T. Outlaw
  • Patent number: 6585933
    Abstract: A method and composition for controlling corrosion of metals, particularly ferrous-based metals in contact with aqueous systems is disclosed, which includes treating industrial waters with a combination of a tetrazolium salt of the general formula: where R1, R2 and R3 may be various organic or inorganic substitutents, where n may be 1 or 2, and at least one other aqueous system treatment material.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: July 1, 2003
    Assignee: BetzDearborn, Inc.
    Inventors: William C. Ehrhardt, Longchun Cheng, Dawn Stasney, Kim A. Whitaker
  • Patent number: 6583091
    Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of 4-sulfophthalic acid, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 24, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
  • Patent number: 6540844
    Abstract: A method for forming a sol-gel on a metal surface to provide an interface for promoting adhesion between the metal surface and an organic resin involves application of at least one metal alkoxide compound having at least one labile sulfur atom, and at least one metal alkoxide compound having at least one reactive moiety which is capable of bonding with an organic resin. The metal alkoxide compound having at least one labile sulfur atom is capable of bonding to various metal surfaces, including surfaces of noble metals, such as gold, by a sulfur-metal linkage with the metal surface. The metal alkoxide compound having at least one labile sulfur atom reacts with the metal alkoxide compound having at least one reactive moiety which is capable of bonding with the organic resin to form a sol-gel which bonds to the surface of the metal, and which includes reactive moieties which are capable of bonding with an organic resin.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: April 1, 2003
    Assignee: Corning Incorporated
    Inventor: Russell A. Crook
  • Publication number: 20030053927
    Abstract: Provided are compositions and methods for releasing oxygen scavengers into a coolant. The compositions include a controlled release component and an oxygen scavenger component which includes at least one oxygen scavenger. Methods and devices for releasing oxygen scavengers into a coolant are also provided.
    Type: Application
    Filed: October 15, 2002
    Publication date: March 20, 2003
    Applicant: Dober Chemical Corporation
    Inventors: Joseph C. Drozd, Thomas J. Blakemore, Yu-Sen Chen
  • Patent number: 6517617
    Abstract: The present invention relates to the application of a coating to a pipeline, FPS (Fire Protection System) or to pipe stock from which a pipeline is fabricated. A composition which when applied to the inside surface of the pipe prevents either chemical corrosion or microbiologically influenced corrosion is disclosed. Also disclosed is a method for utilizing this material to protect both existing pipelines and the raw stock used to construct pipelines and various apparatus for applying a coating of the composition, cleaning, and maintenance of the passive coating. Also disclosed is a method to recycle the composition to be used in other industrial pacification processes.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: February 11, 2003
    Assignee: WHI USA, Inc.
    Inventors: Douglas M. Chartier, Calvin L. Reid