With Free Metal Patents (Class 252/503)
  • Publication number: 20040121237
    Abstract: A composite material including a first carbon foam structure including a network of pores and a second carbon foam structure including a network of pores. An intermediate bonding structure is disposed at least in part between the first and second carbon foam structures.
    Type: Application
    Filed: December 20, 2002
    Publication date: June 24, 2004
    Inventors: Kurtis C. Kelley, Charles F. Ostermeier, Matthew J. Maroon
  • Patent number: 6743381
    Abstract: A process for forming a thixotropic ink for use in manufacturing the ceramic of a zinc oxide varistor where the ceramic includes zinc, oxygen and a plurality of additive elements. The process includes the steps of calcining a mixture of powders of zinc oxide and the additive elements to form a calcined product having a particle size larger than the particle size of the zinc ozide powders, mixing said calcined product with an organic liquid, mechanically working the mixture to produce a calcined particulate material in the organic liquid having a particle size less than the particle size of said calcined product, adding an organic binder to the mixture and mixing the composition to produce said ink.
    Type: Grant
    Filed: September 4, 2001
    Date of Patent: June 1, 2004
    Assignee: Littlefuse, Inc.
    Inventors: Stephen P. Cowman, Derek A. Nicker, John M. Shreeve
  • Patent number: 6712997
    Abstract: The present invention relates to composite polymers containing nanometer-sized metal particles and manufacturing method thereof, which can be uniformly dispersed nanometer-sized metal particles into polymers, thereby allowing the use thereof as optically, electrically and magnetically functional materials. The method for manufacturing composite polymers containing nanometer-sized metal particles includes the steps of: dispersing at least one metal precursor into a matrix made of polymers in a molecule level; and irradiating rays of light on the matrix containing the metal precursors dispersed in the molecule level and reducing the metal precursors into metals and fixing nanometer sized metal particles inside of matrix.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: March 30, 2004
    Assignee: Korea Institute of Science and Technology
    Inventors: Jong Ok Won, Yong Soo Kang, Bum Suk Jung, Yeo Sang Yoon
  • Patent number: 6685854
    Abstract: A thermally stable electrically conductive polymer mixture, for use in forming electrically conductive molded articles, includes at least two additives for contributing to the polymer mixture's electrical conductivity. At least one of the additives concentrates at or near the surface of a molded article for electrical surface conductivity, while at least one other additive concentrates at or near the core of a molded article to heighten electrical core conductivity to promote electrostatic discharge.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: February 3, 2004
    Assignee: Honeywell International, Inc.
    Inventor: Timothy L. Memmer
  • Patent number: 6673953
    Abstract: The invention comprises a chemical composition with the structure shown below. The composition can be polymerized or pyrolyzed, forming transition metal nanoparticles homogeneously dispersed in a thermoset or carbon composition. The size of the nanoparticles can be controlled by manipulating the number and arrangement of functional groups in the composition and by changing the conditions of the polymerization or pyrolysis. The resulting thermosets and carbon compositions have useful magnetic, electric, mechanical, catalytic and/or optical properties.
    Type: Grant
    Filed: December 10, 2001
    Date of Patent: January 6, 2004
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M. Keller, Joseph Perrin, Syed B. Qadri
  • Patent number: 6652777
    Abstract: Disclosed are methods for manufacturing electromagnetic interference shields for use in nonconductive housings of electronic equipment. In one embodiment, the shield may include an electrically nonconductive substrate, such as a thermoformable film, coated with an electrically conductive element, such as an extensible ink or a combination of conductive fibers with an extensible film. In one embodiment, a compressible conductive perimeter gap gasket may be formed by using a form in place process.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: November 25, 2003
    Assignee: Amesbury Group, Inc.
    Inventors: Martin L. Rapp, Jeff McFadden, Frank T. McNally
  • Patent number: 6649090
    Abstract: A liquid composition is formed into a coating layer state in which negative ions are steadily released. The liquid composition includes a finely powdered mineral that generates negative ions mixed with a binder liquid that is conductive and/or a binder liquid in which a conductive substance is dispersed.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: November 18, 2003
    Assignee: Gantan Beauty Industry Co., Ltd.
    Inventors: Motokatsu Funaki, Teruo Tamanoi, Kouji Yanagimachi, Akifusa Funaki
  • Patent number: 6630080
    Abstract: A long-life encoder switch which can enable flexible production in which a wide variety of products are manufactured in low volume is provided by using a conductive resin composition which has both excellent conductivity and abrasion resistance as a material for a contact part. The contact part of the encoder switch is produced by making a pattern of the conductive resin composition by screen printing and the conductive particles of the conductive resin composition contain a conductive powder of carbon beads with silver-coated surfaces and a silver powder.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: October 7, 2003
    Assignee: Alps Electric Co., Ltd.
    Inventor: Satoru Matsumora
  • Patent number: 6627058
    Abstract: This invention is directed to a composition comprising: (a) platinum group metal powder, alloys, or mixtures thereof as a powder or deposited on graphite supports; (b) poly(glycol ether), derivatives, or mixtures thereof; (c) carbon-based electrically conductive filler; and (d) thermoplastic polymer or mixtures thereof. The invention is further directed to a process for dispersing platinum group metal powder, alloys, or mixtures thereof in poly(glycol ether), derivatives, or mixtures thereof. The invention is further directed to the above composition wherein the platinum group metal powder has been dispersed according to the above process.
    Type: Grant
    Filed: January 17, 2001
    Date of Patent: September 30, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Man-Sheung Chan
  • Patent number: 6616864
    Abstract: A Z-axis electrical contact may be formed using a resinous deposit containing conductive particles which may align along surface regions to form an electrical conduction path over the resinous material. If the resinous material is thermoplastic, the material may be heated to mechanically bond to contact surfaces. Advantageously, the resinous material may be formed by forcing a resinous matrix containing conductive particles through an annular opening in a stencil. The resulting member allows surfaces to be contacted which may be irregular or may be covered by native oxide layers.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: September 9, 2003
    Assignee: Micron Technology, Inc.
    Inventors: Tongbi Jiang, Edward A. Schrock
  • Patent number: 6607676
    Abstract: Carbonaceous semiconductor material is prepared by heating an organic polymer to carbonize the polymer and incorporating into the carbonized polymer one or more hetero atoms such as those of Group II, III, IV, V and VI of the Periodic Table. Carbonaceous semiconductor material is also prepared by heating an organic polymer containing one or more of the hetero atoms until the hetero atom-containing polymer is carbonized.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: August 19, 2003
    Assignee: Ube Industries, Ltd.
    Inventors: Masao Doyama, Shigehiko Yamada
  • Publication number: 20030151030
    Abstract: An enhanced conductivity nanocomposite having reduced conductivity path directionality dependence as a means for enhancing the electrical and thermal conductivity. The composition comprises a synergistic blend of metal (and their derivatives) and carbon (preferably nanotubes) powder both average particle sizes in the nanometer to micron size range. The carrier medium is selected from the group of interpolymers, polymers, gaseous and liquid fluids, and phase change materials. The synergistic nanocomposite, when mixed with a conductive medium, exhibits enhanced heat transfer capacity, and electrical and thermal conductivity, stable chemical composition, faster heat transfer rates, and dispersion maintenance which are beneficial to most thermal or electrical transfer systems.
    Type: Application
    Filed: March 18, 2003
    Publication date: August 14, 2003
    Inventor: Michael H. Gurin
  • Patent number: 6602438
    Abstract: A structure for polymeric thermistor device and method of making the same are disclosed. The polymeric thermistor makes use of a polymeric composite filled with conductive filler and show resistance variations at different temperatures. A polymeric substrate filled with conductive filler is cross-linked so that the whole polymeric composite structure filled with conductive filler is able to memorize shape. Then, the cross-linked polymeric composite undergoes a simple-sheared process and turns into a polymeric composite with a strain more than 1%. Therefore, the micro-structure and electrical properties of the conductive filler are changed.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: August 5, 2003
    Assignee: Protectronics Technology Corporation
    Inventor: Chen-Ron Lin
  • Publication number: 20030091891
    Abstract: A catalyst composition for a cell comprising catalyst-bearing conductive powder particles and fibrous carbon. A membrane-electrode assembly for a fuel cell comprising an electrolyte membrane and an electrode including a catalyst layer and a gas diffusion layer, the electrode being provided on each surface of the electrolyte membrane, wherein at least a portion of the surface of the gas diffusion layer which is in contact with the catalyst layer includes a layer containing a hydrophobic resin and fibrous carbon.
    Type: Application
    Filed: February 8, 2002
    Publication date: May 15, 2003
    Inventors: Tomoaki Yoshida, Toshio Morita
  • Publication number: 20030062511
    Abstract: An electric resistance material comprises an Fe—Cr—Ni alloy having composition of C up to 0.1%, Si up to 5%, Mn up to 6%, 9-32% Cr, 6-25% Ni, N up to 0.2%, 0-3% Mo, 0-4% Cu, 0-5% Al, 0-0.4% Ti, 0-0.4% Nb, 0-0.005% B and the balance being substantially Fe with the previsions that the value A defined by the formula (1) and the value B defined by the formula (2) are not less than 78 and not less than 14, respectively. The electric resistance material is high of resistivity with less temperature dependency, and a resistor made therefrom works well without noises during flow of electricity. 1 A = 0.008 × ( % ⁢   ⁢ Cr ) 3 - 0.43 × ( % ⁢   ⁢ Cr ) 2 + 8.03 × ( % ⁢   ⁢ Cr ) + 6.8 × ( % ⁢   ⁢ Si ) + 10.9 × ( % ⁢   ⁢ Al ) + 0.56 × ( % ⁢   ⁢ Mo ) + 0.
    Type: Application
    Filed: March 27, 2002
    Publication date: April 3, 2003
    Applicant: Nisshin Steel Co., Ltd.
    Inventors: Hiroshi Morikawa, Katsunori Babazono, Takahiro Fujii, Takashi Yamauchi
  • Patent number: 6540944
    Abstract: A current limiting device comprises at least two electrodes; an electrically conducting composite material between the electrodes; interfaces between the electrodes and electrically conducting composite material; an inhomogeneous distribution of resistance at the interfaces whereby, during a high current event, adiabatic resistive heating at the interfaces causes rapid thermal expansion and vaporization and at least a partial physical separation at the interfaces; and a structure for exerting compressive pressure on the electrically conducting composite material, wherein the electrically conducting composite material comprises at least one polymer matrix and at least one conductive filler.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: April 1, 2003
    Assignee: General Electric Company
    Inventors: Anil Raj Duggal, Andrew Jay Salem, Lionel Monty Levinson, Michael Leslie Todt
  • Patent number: 6537510
    Abstract: One embodiment of the present invention provides a conductive pigment powder, which includes indium oxide, tin and gold, and having a purple color tone. Other embodiments of the present invention provide a method of producing a conductive pigment powder; a dispersion solution and a transparent conductive film, which include the above-mentioned conductive pigment powder; a method of forming a transparent conductive film; and a cathode ray tube, which includes the above-mentioned transparent conductive film and a transparent substrate.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: March 25, 2003
    Assignee: Mitsubishi Materials Corporation
    Inventors: Toshiharu Hayashi, Hiroshi Yamaguchi, Daisuke Shibuta
  • Publication number: 20030008123
    Abstract: The present invention relates to a novel nanocomposite dielectric comprising a polymer matrix and a plurality of carbon nanotubes dispersed therein. A method for increasing a dielectric constant of a polymer matrix, as well as a laminate and mobile antenna comprising the novel dielectric are also disclosed.
    Type: Application
    Filed: June 10, 2002
    Publication date: January 9, 2003
    Inventors: Paul J. Glatkowski, David J. Arthur
  • Patent number: 6479028
    Abstract: Carbon material having at least a partially curved structure, such as a nanotube, produced by a displacement reaction in which a carbon halide, e.g. C2Cl6, is reacted with a metal compound, e.g., lithium acetylide in the presence of a catalyst, e.g., CoCl2. Some applications of the nanotubes of the present invention are use in magnetic data storage media, or use as conductors or semiconductors.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: November 12, 2002
    Assignee: The Regents of the University of California
    Inventors: Richard B. Kaner, Jennifer L. O'Loughlin, Ching-Hwa Kiang, Charles H. Wallace
  • Patent number: 6440331
    Abstract: A composition and method for applying an electrically conductive coating to an initially electrically nonconductive surface, such as a printed wiring board having through holes is disclosed. The method is carried out by applying a composition of electrically conductive carbon particles, a second conductive material, a water dispersible binding agent, and an aqueous dispersing medium to a nonconductive substrate to form a substantially continuous, electrically conductive coating. Enough of the carbon particles are present to provide an electrically conductive coating when the composition is applied to the substrate. Enough of the second conductive material is present to provide an improved electrically conductive coating when the composition is applied to the substrate. The resulting coating carbon coating has an improved conductivity over prior through hole coating compositions and processes and is capable of being exposed to molten solder without resulting in the formation of blowholes.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: August 27, 2002
    Assignee: Electrochemicals Inc.
    Inventors: Michael V. Carano, Frank Polakovic
  • Patent number: 6403697
    Abstract: Carbon black having boron solid-solubilized therein, which has an electrical resistivity of not higher than 0.1 &OHgr;cm, as measured in accordance with JIS K1469.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: June 11, 2002
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toshikatsu Mitsunaga, Yoshiteru Yamasaki, Hiroyuki Hara, Kazuyoshi Tsuruta
  • Patent number: 6358438
    Abstract: An electrically conductive polymer composition containing a polymer mixture containing a first crystalline polymer having a weight-average molecular weight of at least 50,000 and a second crystalline polymer having a weight-average molecular weight of at most 10,000, and a particulate electrically conductive filler has good processability and exhibits a low resistivity at 20° C. and a good positive temperature coefficient (PTC) behavior.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: March 19, 2002
    Assignee: Tyco Electronics Corporation
    Inventors: Tsutomu Isozaki, Masaaki Takahashi, Susan Melsa Jordan, Kevin Michael Stein
  • Patent number: 6337160
    Abstract: The invention relates to novel manganese dioxide electrodes comprising modified, electrochemically active manganese dioxide, to a method for fabricating these novel manganese dioxide electrodes and to the use of these in rechargeable cells.
    Type: Grant
    Filed: October 5, 1999
    Date of Patent: January 8, 2002
    Assignee: Merck Patent Gesellschaft mit beschrankter
    Inventors: Volker Hilarius, Gerhard Pfaff, Ralf Glausch, Dietmar Rahner, Waldfried Plieth, Matthias Kloss
  • Patent number: 6334964
    Abstract: A thixotropic ink for use in manufacturing a varistor comprising the following constituents: a) zinc oxide, b) ceramic structure influencing additives including bismuth oxide, boric acid, boron oxide, chromium oxide, cobalt oxide, magnesium oxide and tin oxide, c) a grain growth influencing additive selected from the group consisting of antimony oxide, silicon dioxide and titanium dioxide, d) an organic solvent carrier, e) an organic viscosity influencing additive, and f) an organic binder. The composition may serve as a ceramic ink for use in the manufacture of multilayer varistors, especially using a screen printing process.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: January 1, 2002
    Assignee: Littelfuse, Inc.
    Inventors: Stephen P. Cowman, Derek A. Nicker, John M. Shreeve
  • Patent number: 6332990
    Abstract: Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: December 25, 2001
    Assignee: The Regents of the University of California
    Inventors: Steven T. Mayer, Richard W. Pekala, James L. Kaschmitter
  • Patent number: 6312621
    Abstract: A via fill formulation including electrically and/or thermally conductive particulate filler, or non-conductive, electrically conductive polymer and a resin vehicle.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: November 6, 2001
    Assignee: Johnson Matthey Electronics, Inc.
    Inventors: Jesse L. Pedigo, Nancy E. Iwamoto, Alan Grieve, Xiao-Qi Zhou
  • Patent number: 6290878
    Abstract: The invention provides a solid polymer electrolyte comprising a polymer which is a polyacrylonitrile, a plasticizer made up of a lithium salt in solution in a liquid organic solvent, and a reinforcing agent which is an organic compound constituted by porous grains of a polymer having polyamide structural units.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: September 18, 2001
    Assignee: Alcatel
    Inventors: Michel Hilaire, Carole Moneuse
  • Patent number: 6265051
    Abstract: Disclosed are edge contacts for printed circuit boards comprising a copper lead coated with conductive ink comprising a binder and graphite powder, carbon black, and silver flakes. Also disclosed are printed circuit boards containing the contacts and methods for manufacturing the contacts and circuit boards.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: July 24, 2001
    Assignee: 3Com Corporation
    Inventor: Denis Jean
  • Patent number: 6251307
    Abstract: The present invention relates to the use of petroleum coke for the manufacture of carbonaceous anodes for the aluminum smelting industry. The inclusion of Group 4 and/or Group 13 metal compounds as additives to the petroleum coker feedstock diminish the oxidizing tendencies of the metal impurities inherent in the petroleum coke.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: June 26, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Steven Matthew LeCours, Arthur Warren Chester, Gary Lester Smith
  • Patent number: 6238596
    Abstract: Described is a compliant and crosslinkable thermal interface material of at least one malenized rubber with maleic anhydride adducted to the molecule and at least one hydroxyl terminated olefin rubbers, and a method of making and using same; as well as a method of improving thermal conductivity of polymer systems.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: May 29, 2001
    Assignee: Johnson Matthey Electronics, Inc.
    Inventors: My N. Nguyen, James D. Grundy
  • Patent number: 6183667
    Abstract: A composite material having a carbon matrix, and a titanium-copper alloy dispersed in the carbon matrix and containing 1-80% by weight of titanium and 15.4-99% by weight of copper. The titanium-copper alloy is present in an amount of 2-85% based on a total weight of the carbon matrix and the titanium-copper alloy. The composite material may additionally contain carbon fibers dispersed in the carbon matrix. The composite material is produced by incorporating powder or melt of titanium and copper or copper alloy into a shaped body of carbon.
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: February 6, 2001
    Assignees: Railway Technical Research Institute, Japan Powder Metallurgy Co., Ltd., Across Co., Ltd.
    Inventors: Shunichi Kubo, Jitsuji Ikeuchi, Hiroshi Tsuchiya, Yoshitaka Tomiyama, Kojiro Saito, Yoshinobu Morita, Takao Nakagawa, Yoshio Yoshihara
  • Patent number: 6099704
    Abstract: This invention covers a cathodic element free from asbestos fibres that can be obtained by deposition after filtration through a porous medium of an aqueous suspension comprising electrically conductive fibres, at least one cationic polymer, at least one electocatalytic agent, at least one pore-forming agent and at least one binder selected from among the fluoropolymers. The invention also covers a method for preparing such a cathodic element.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: August 8, 2000
    Assignee: Chloralp
    Inventors: Gerard Bacquet, Frederic Kuntzburger
  • Patent number: 6090313
    Abstract: A high temperature PTC device comprising a polymeric conductive composition that includes nylon-11 and a carbon-based particulate conductive filler has a switching temperature greater than 150.degree. C., preferably between about 160.degree. C. and 200.degree. C. The composition demonstrates a high PTC effect (at least 10.sup.3, and more typically 10.sup.4 to 10.sup.5 or greater) and a resistivity at 25.degree. C. of 100 .OMEGA.cm or less, preferably 10 .OMEGA.cm or less. High temperature PTC devices that comprise nylon-11 or nylon-12 compositions and that are manufactured by extrusion/lamination demonstrate good thermal and electrical stability compared with those manufactured by compression molding and do not require composition crosslinking for stability, although crosslinking may be used to further improve stability. The use of a high temperature solder for attaching electrical terminals to the device improves the PTC properties of the device.
    Type: Grant
    Filed: June 28, 1999
    Date of Patent: July 18, 2000
    Assignee: Therm-O-Disc Inc.
    Inventor: Liren Zhao
  • Patent number: 6086790
    Abstract: The present invention discloses a double-layer structured low-resistance and low-reflectivity transparent conductive film, comprising a lower high-reflectivity conductive layer containing a fine metal powder in a silica-based matrix and a silica-based low-reflectivity layer, suitable for imparting electromagnetic shielding property and anti-dazzling property to a CRT.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: July 11, 2000
    Assignee: Mitsubishi Materials Corporation
    Inventors: Toshiharu Hayashi, Tomoko Oka, Daisuke Shibuta
  • Patent number: 6030553
    Abstract: Polymer thick film resistor pastes with dimensionally stability and excellent processibility, such as coating, printing, and extruding, are disclosed. The resistor paste composition in accordance with the present invention comprises a low-k cycloaliphatic epoxy resin vehicle loaded with electrically conductive particles, a cationic photoinitiator, a thermal catalyst, and optionally a reactive diluent.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: February 29, 2000
    Assignee: Industrial Technology Research Institute
    Inventors: Hui-min Huang, Chia-Tin Chung, Bin-Yuan Lin, Hsin-Herng Wang, Wun-Ku Wang, Te-Yeu Su, Su-Jen Chang
  • Patent number: 6015509
    Abstract: A composition containing a polymeric matrix and a conductive filler component is provided. The conductive filler component comprises conductive particles and a polymer selected from the group consisting of substituted and unsubstituted polyanilines, substituted and unsubstituted polyparaphenylenevinylenes, substituted and unsubstituted polythiophenes, substituted and unsubstituted polyazines, substituted and unsubstituted polyparaphenylenes, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophene, substituted and unsubstituted poly-p-phenylene sulfides and substituted and unsubstituted polyacetylenes, and mixtures thereof, and copolymers thereof. Compositions of the present invention are useful as corrosion protecting layers for metal substrates, for electrostatic discharge protection, electromagnetic interference shielding, and as adhesives for interconnect technology as alternatives to solder interconnections.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: January 18, 2000
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Vlasta A. Brusic, Teresita Ordonez Graham, Sampath Purushothaman, Ravi F. Saraf, Jane Margaret Shaw, Judith Marie Roldan, Alfred Viehbeck
  • Patent number: 5989459
    Abstract: Described is a compliant and crosslinkable thermal interface material of at least one malenized rubber with maleic anhydride adducted to the molecule and at least one hydroxyl terminated olefin rubbers, and a method of making and using same; as well as a method of improving thermal conductivity of polymer systems.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: November 23, 1999
    Assignee: Johnson Matthey, Inc.
    Inventors: My N. Nguyen, James D. Grundy
  • Patent number: 5985458
    Abstract: A composition containing a polymeric matrix and a conductive filler component is provided. The conductive filler component comprises conductive particles and a polymer selected from the group consisting of substituted and unsubstituted polyanilines, substituted and unsubstituted polyparaphenylenevinylenes, substituted and unsubstituted polythiophenes, substituted and unsubstituted polyazines, substituted and unsubstituted polyparaphenylenes, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophene, substituted and unsubstituted poly-p-phenylene sulfides and substiututed and unsubstituted polyacetylenes, and mixtures thereof, and copolymers thereof. Compositions of the present invention are useful as corrosion protecting layers for metal substrates, for electrostatic discharge protection, electromagnetic interference shielding, and as adhesives for interconnect technology as alternatives to solder interconnections.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: November 16, 1999
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Vlasta A. Brusic, Teresita Ordonez Graham, Sampath Purushothaman, Ravi F. Saraf, Jane Margaret Shaw, Judith Marie Roldan, Alfred Viehbeck
  • Patent number: 5965268
    Abstract: A carbon-based composite is made by the steps of(1) impregnating a fibrous material with a phthalonitrile thermoset polymer precursor,(2) curing the product of step (1) to form a fiber-reinforced thermoset polymer and(3) pyrolyzing the product of step (2) to form the carbon-based composite. The carbon-based composite may be made with only one cycle of the steps (1), (2), and (3).
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: October 12, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Satya B. Sastri, James P. Armistead, Teddy M. Keller
  • Patent number: 5959021
    Abstract: The present invention is a process for protecting articles from electrostatic discharge (ESD) in which a coating is applied directly onto the article in liquid form and the resulting coating provides a surface resistivity that protects the underlying article from ESD. The composition contains a carrier material, carbon black, and a transition metal. The composition forms a coating on an article when applied as a liquid and dried thereon. The ratio of carrier solids to carbon black is about 100 parts by weight polymer to about 0.5 to about 3 parts by weight carbon black. The ratio of carrier solids to transition metal is about 100 parts by weight about 6 to about 15 parts by weight transition metal.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: September 28, 1999
    Assignee: Lucent Technologies Inc.
    Inventor: John Philip Franey
  • Patent number: 5916702
    Abstract: The invention is a composition, comprising: a carbon-supported, dispersed platinum-zinc alloy having the formula Pt-Zn.sub.x /C wherein x ranges from greater than 0.05 to less than 1 wherein platinum is in the form of platinum particles ranging in size from about 20 .ANG. to about 30 .ANG. on a carbon support, wherein the carbon is in the form of high surface area carbon having surface area ranging from about 100 to about 500 m.sup.2 /g, and the platinum particles are present in an amount ranging from about 10 to about 40 wt % on the carbon support. The composition is made by the process of depositing on the carbon support a soluble zinc source selected from the group of zinc nitrate, acetate, halides, formates, oxalates, and acetyl acetonates and mixtures thereof; calcining to convert the zinc source to ZnO; and then reducing the zinc oxide at a temperature ranging from about 250.degree. C. to about 600.degree. C.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: June 29, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Elise Marucchi-Soos, John Lawrence Robbins, Richard James Bellows, David Terence Buckley
  • Patent number: 5908584
    Abstract: An electrically conductive material used for shielding against electromagnetic waves and comprising a binder, a mixture of graphite and amorphous carbon, and sand. It has been shown that this mixture has enhanced shielding properties, particularly in the 100 MHZ range. The graphite/carbon mixture preferably makes up 25-75% of the total weight of the material. The binder may be cementitious. Said material may also be used in conductive floors, electrical heating equipment, light conductors, heating elements, ground connections, resistors, capacitors and antennas.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: June 1, 1999
    Assignee: Elfinco S.A.
    Inventor: Ronald Wilfred Murdoch Bennett
  • Patent number: 5888430
    Abstract: The graphite is a composite between graphite particles and other fine, solid element particles, in which the graphite particles account for at least 40 atomic % and the other element particles have particle sizes of 900 nm or smaller and are dispersed in said graphite particles. The other elements may be Li and Si. Preferably, a part of said other elements forms an intercalation compound with graphite. The composite is suitable for a negative electrode of lithium secondary batteries having large discharging capacity, and as adsorbent materials of adsorbing various substances.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: March 30, 1999
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Hiroaki Wakayama, Yoshiaki Fukushima, Jirou Mizuno, Uichiro Mizutani, Toshiharu Fukunaga
  • Patent number: 5879747
    Abstract: An electroconductive composite material composed of a three-dimensional continuum of a porous metal with the pores filled with graphite and a resin, having a good heat resistance, wear resistance, strength and thermal conductivity, having a light weight, and particularly useful as electric armature brushes and other electric sliding elements.A process of producing the composite material comprises the steps of: filling pores of a three-dimensional continuum of a porous metal with a pasty mixture composed of graphite, a binder, and a solvent; treating the continuum for volatilization of the solvent; and then, forming and heating the continuum.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: March 9, 1999
    Assignee: Nippondenso Co., Ltd.
    Inventors: Youichi Murakami, Yoshitaka Natsume, Yoshio Satou, Yoshio Miyata
  • Patent number: 5855818
    Abstract: An electrically conductive elastomeric foam is presented. Preferably, the elastomeric foam comprises polyurethane foam and in accordance with an important feature of this invention, the elastomeric foam is rendered electrically conductive by incorporating therein electrically conductive fibers. As used herein, a "fiber" has a diameter greater than or equal to one micron, and an aspect ratio (length/diameter) greater than or equal to fifteen. In accordance with the method of the present invention, the elastomeric foam is prepared from a polyurethane stock comprised of a polyhydroxyl compound, an organic polyisocyanate compound, a catalyst, a foam stabilizer and an amount of electrically conductive fiber which is effective to render the elastomeric foam electrically conductive.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: January 5, 1999
    Assignee: Rogers Corporation
    Inventors: Poh Poh Gan, Michael Bessette
  • Patent number: 5851644
    Abstract: An anisotropically-conductive film or a substrate having a surface coated with an anisotropically-conductive coating, said film or coating being formed by solidifying a composition comprising(i) a solidifiable ferrofluid composition, the ferrofluid comprising a colloidal suspension of ferromagnetic particles in a non-magnetic carrier, and(ii) a plurality of electrically-conductive particles, dispersed in the ferrofluid,the electrically-conductive particles having been arrayed in a non-random pattern by application of a substantially uniform magnetic field to the composition in a liquid state and having been locked in position by solidification of the composition. The composition is solidified in an A-stage, usually involving a primary cure. In end-use application of the film or coating, the composition usually undergoes a B-stage or secondary cure. The film or coated substrate is an article of manufacture for bonding conductors in the electronics industry.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: December 22, 1998
    Assignee: Loctite (Ireland) Limited
    Inventors: Ciaran B. McArdle, Joseph Burke
  • Patent number: 5776587
    Abstract: A composition containing a polymeric matrix and a conductive filler component is provided. The conductive filler component comprises conductive particles and a polymer selected from the group consisting of substituted and unsubstituted polyanilines, substituted and unsubstituted polyparaphenylenevinylenes, substituted and unsubstituted polythiophenes, substituted and unsubstituted polyazines, substituted and unsubstituted polyparaphenylenes, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophene, substituted and unsubstituted poly-p-phenylene sulfides and substituted and unsubstituted polyacetylenes, and mixtures thereof, and copolymers thereof. The compositions of the present invention are useful as adhesives for interconnecting a semiconductor chip to a substrate.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: July 7, 1998
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Vlasta A. Brusic, Teresita Ordonez Graham, Sampath Purushothaman, Ravi F. Saraf, Jane Margaret Shaw, Judith Marie Roldan, Alfred Viehbeck
  • Patent number: 5772974
    Abstract: A battery electrode material having a large charge-discharge capacity and capable of providing a (non-aqueous solvent-type secondary) battery of a high energy density is provided in the form of a carbonaceous material having a microtexture suitable for doping with lithium (ions). Such a carbonaceous material is produced through a process of heating a starting organic material for carbonization including a step of heating the organic material in a halogen gas-containing inert gas atmosphere in a specific temperature range (800.degree.-1400.degree. C.) below the final carbonization temperature.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: June 30, 1998
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroaki Ohashi, Yoshiki Shigaki
  • Patent number: 5756007
    Abstract: The present invention is a process for protecting articles from electrostatic discharge (ESD) in which a coating is applied directly onto the article in liquid form and the resulting coating provides a surface resistivity that protects the underlying article from ESD. The composition contains a carrier material, carbon black, and a transition metal. The composition forms a coating on an article when applied as a liquid and dried thereon. The ratio of carrier solids to carbon black is about 100 parts by weight polymer to about 0.5 to about 3 parts by weight carbon black. The ratio of carrier solids to transition metal is about 100 parts by weight about 6 to about 15 parts by weight transition metal.
    Type: Grant
    Filed: November 16, 1995
    Date of Patent: May 26, 1998
    Assignee: Lucent Technologies Inc.
    Inventor: John Philip Franey
  • Patent number: 5755953
    Abstract: Provided are microparticle forms of carbon, carbon catalysts and carbon-containing electrically conductive materials which are covalently linked to peroxidase. The carbon:peroxidase conjugates are suitable for use as substrates in conventional electrodes. Surprisingly, the conjugates display very little sensitivity to known interfering substances and thus are suitable for use as interference free electrodes.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: May 26, 1998
    Assignee: Abbott Laboratories
    Inventors: Timothy P. Henning, Thomas G. Spring