Antistatic Agents Containing A Metal, Silicon, Boron Or Phosphorus Patents (Class 260/DIG16)
  • Patent number: 6066442
    Abstract: An anti-static-treated film material having an electro-conductive layer is disclosed. The film material contains at least one selected from conductive particles and semi-conductive particles at an amount between 1 and 50 vol. % with respect to said electro-conductive layer and polymer particles having an average particle diameter of 0.01 to 5 .mu.m, and the absolute value of impedance of said film material under frequency at 20 Hz is between 4.times.10.sup.5 and 1.times.10.sup.20 .OMEGA.. The film material is suitably used as a support of asilver halide light sensitive material.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: May 23, 2000
    Assignee: Konica Corporation
    Inventors: Yasuo Kurachi, Hidetoshi Ezure, Takayuki Sasaki, Masayoshi Yamauchi, Hitoshi Adachi, Eiichi Ueda, Yasuhiko Takamuki
  • Patent number: 6004889
    Abstract: Disclosed is a compositions for antistatic finish, which is useful for antistatic stockings, comprising (a) 100 parts by weight of colloidal or ultrafine granular alumina on a solid basis, (b) 3 parts to 50 parts by weight of a binder on a solid basis, (c) 0.02 part to 2 parts by weight of at least one selected from the group consisting of silver salts, copper salts and colloidal silver on a metallic atom basis, and (d) 848 parts to 896.08 parts by weight of water (including water occasionally contained in the components of (a) to (c)).
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: December 21, 1999
    Assignee: Kabushiki Kaisya Nippankenkyusyo
    Inventor: Yoshio Ichikawa
  • Patent number: 5955526
    Abstract: An antistatic additive including a hexahalogenated ionic compound, and an antistatic additive composition for organic polymer compositions including an antistatically-effective amount of the hexahalogenated ionic compound, a solvent for the hexahalogenated ionic compound, and a diluent compatible with the hexahalogenated ionic compound, the solvent and the organic polymer composition. The hexahalogenated phosphate compound is preferably either potassium hexafluorophosphate, sodium hexafluorophosphate, and ammonium hexafluorophosphate. Organic polymer compositions containing the additive also are disclosed, as are methods of manufacturing both the additive and the polymer compositions.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: September 21, 1999
    Assignees: Cellular Technology International, Inc., Chemfoam International, Inc.
    Inventor: Dennis R. Spicher
  • Patent number: 5549846
    Abstract: The invention relates to a method for the continuous preparation of vanadium pentoxide gel and an apparatus for implementing the method.According to the present invention, the vanadium pentoxide is raised to a temperature at least 100.degree. C. higher than its melting point; it is poured continuously into a quenching reactor 2 containing distilled water at ambient temperature; the gel obtained flows by overflowing to an ageing reactor 4, the contents of which are recirculated to the quenching reactor; the concentration of the gel contained in the ageing reactor 4 is measured continuously so as to adjust continuously the quantity of distilled water to be added to the quenching reactor 2; the contents of the ageing reactor are evacuated into a storage drum 9. Application to the manufacture of vanadium pentoxide for anti-static applications.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: August 27, 1996
    Assignee: Eastman Kodak Company
    Inventors: Jean P. Tixier, Annie F. Legrand
  • Patent number: 5491026
    Abstract: Process for applying an antistatic finish to synthetic fibers comprising of steps ofapplying to the fibers to be treated a composition comprising at least one salt of a phosphate partial ester containing a C.sub.12 straight chain alkyl group, a lubricant, and an anionic and/or cationic emulsifier; andautoclaving the treated fibers at a temperature in the range of from about 93.degree. to 150.degree. F.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: February 13, 1996
    Assignee: Henkel Corporation
    Inventors: Elbert H. Mudge, Charles G. DeWitt
  • Patent number: 4950544
    Abstract: A water based antistatic coating composition comprising:(a) at least one water soluble antistatic agent which is acceptable for food packaging polymer films;(b) at least one water soluble or water dispersible film-forming polymer; and,(c) a solution or dispersion-forming amount of water.When applied to a polymer film substrate, the foregoing antistatic coating composition forms, upon drying, and adherent antistatic coating.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: August 21, 1990
    Assignee: Mobil Oil Corporation
    Inventor: Robert E. Touhsaent
  • Patent number: 4943380
    Abstract: An antistatic resin composition with transparency contains 90-99.9 wt % of a synthetic resin selected from polycarbonate or polymethyl methacrylate and 0.1-10 wt % of a heat-resistant antistat containing phosphonium sulfonate shown by the general formula (I) below: ##STR1## where A is alkyl group with 1-36 carbon atoms, alkenyl group with 4-24 carbon atoms, phenyl group, phenyl group substituted by alkyl group with 1-18 carbon atoms, naphthyl group or naphthyl group substituted by alkyl group with 1-18 carbon atoms, R.sup.1, R.sup.2 and R.sup.3 are identical, each being an aliphatic hydrocarbon group with 1-8 carbon atoms or aromatic hydrocarbon group, and R.sup.4 is a hydrocarbon group with 1-18 carbon atoms.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: July 24, 1990
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Masato Sugiura, Hideo Shimizu, Shigeru Imamura, Fumitoshi Sugiura
  • Patent number: 4604416
    Abstract: A methacrylic resin composition having excellent impact resistance and antistatic property is described. This composition comprises (I) 50-99.8 wt. % of a methacrylic resin comprised of 80-100 wt. % of methyl methacrylate units and 0-20 wt. % of other copolymerizable monomer units, (II) 0.1-40 wt. % of a rubbery component which is a polymer containing an elastomeric portion comprising at least 50 wt. % of 1,3-butadiene and/or acrylic acid ester units, and (III) 0.1-10 wt. % of a specified compound.
    Type: Grant
    Filed: December 13, 1984
    Date of Patent: August 5, 1986
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Yoshio Nakai, Katsusuke Yamauchi, Masaaki Kishimura, Masamitsu Tateyama
  • Patent number: 4579902
    Abstract: The present invention provides a permanently antistatic, injection moldable thermoplastic composition comprising a polybutylene terephthalate resin having an intrinsic viscosity in the range of about 0.7 to about 1.4 deciliters per gram measured in ortho-chlorophenol at 25.degree. C., an antistatic dopant comprising an electron acceptor compound, an electron donor compound, and polytetrafluoroethlene, and less than about 10 percent by weight based on the total weight of the molding composition of carbon fibers having lengths between about 0.1 and about 1.0 inch. Such a molding composition exhibits a volume resistivity of less than 1.times.10.sup.8 ohm-cm, exceptional low wear performance, excellent mechanical properties, and ease of manufacture.
    Type: Grant
    Filed: December 5, 1984
    Date of Patent: April 1, 1986
    Assignee: Celanese Corporation
    Inventor: David P. O'Brien
  • Patent number: 4568485
    Abstract: The invention relates to plastics materials of high electrical conductivity containing TCNQ complexes and stabilized against the emission of HCN and to mouldings, films and coatings of such materials, as well as to the use of the plastics material for the production of antistatic foils and coatings onto substrates.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: February 4, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich Jonas, Jurgen Hocker
  • Patent number: 4552687
    Abstract: Thermoplastic polymers, having antistatic properties, are obtained by incorporating in the polymers a liquid mixture of trialkylphosphine oxides.
    Type: Grant
    Filed: July 8, 1983
    Date of Patent: November 12, 1985
    Assignee: FMC Corporation
    Inventors: Harry H. Beacham, Paul R. Mucenieks
  • Patent number: 4393159
    Abstract: A thermoplastic material formed from a hydrocarbon chain is modified to inhibit the production of static charges. The thermoplastic material may be a polypropylene. A weak salt having properties of ionizing and having its positive ions bond chemically to the thermoplastic material is mixed in the thermoplastic material. A chemical agent is also dispersed in the thermoplastic material and is provided with properties of facilitating the dispersion of the positive ions of the weak salt throughout the thermoplastic material for chemical bonding to the thermoplastic material. The chemical agent may also be bonded chemically to the thermoplastic material. The weak salt may be cupric acetate and the chemical agent may be an ethoxylated amine when the thermoplastic material is polypropylene. The polypropylene is preferably mixed with a suitable material such as polyethylene to enhance the amorphous characteristics of the thermoplastic material.
    Type: Grant
    Filed: December 4, 1981
    Date of Patent: July 12, 1983
    Assignee: Bengal, Inc.
    Inventor: William Lybrand
  • Patent number: 4391952
    Abstract: Polyethylene having a relatively high specific gravity is modified to inhibit the production of static charges. A weak salt having properties of ionizing and having its positive ions bond chemically to the polyethylene is mixed in the polyethylene. A chemical agent is also dispersed in the polyethylene and is provided with properties of facilitating the dispersion of the positive ions of the weak salt throughout the polyethylene of high specific gravity for chemical bonding to the polyethylene. The weak salt may be cupric acetate and the chemical agent may be an amine. The amine is preferably ethoxylated. The material of this invention may be formed as non-transparent bags or as sheets. The material may be formed by mixing the different chemicals and extruding the mixture under conditions of controlled temperatures and pressures and for controlled dwell times.
    Type: Grant
    Filed: December 4, 1981
    Date of Patent: July 5, 1983
    Assignee: Bengal, Inc.
    Inventor: William Lybrand
  • Patent number: 4337188
    Abstract: A composition capable of being used for the manufacture of polyolefin film having so-called "cling" properties is disclosed. The composition consists essentially of(a) an intimate mixture of 75-98 weight percent of a first component and 2-25 weight percent of a second component, and(b) at least 200 ppm, based on the weight of (a), of an agent selected from the class consisting of(i) an organic compound having at least one polar group and at least one group selected from the class consisting of alkylene and alkylene interrupted by oxygen, said alkylene having at least eight carbon atoms and said compound being a liquid or a waxy solid;(ii) mineral oil;(iii) a liquid polyolefin; and(iv) an organic phosphate ester that is a liquid or waxy solid; and mixtures of such agents.A preferred agent is N,N-bis(2-hydroxyethyl) alkylamine where the alkyl group is C.sub.12 -C.sub.18 alkyl group. The first component is a blend of 10-100 percent of at least one homopolymer of ethylene having a density of 0.915-0.930 g/cm.sup.
    Type: Grant
    Filed: October 24, 1980
    Date of Patent: June 29, 1982
    Assignee: Du Pont Canada Inc.
    Inventors: David C. Climenhage, Walter R. Eadie
  • Patent number: 4308332
    Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.
    Type: Grant
    Filed: May 1, 1980
    Date of Patent: December 29, 1981
    Assignee: Eastman Kodak Company
    Inventors: Donald A. Upson, David J. Steklenski
  • Patent number: 4301040
    Abstract: A static-free, polymeric surface mat to prevent the accumulation of static charge, particularly in the packaging and handling of electronic components and devices, which mat comprises a nonconductive, synthetic-material layer with a top surface, optionally an adhesive layer on the bottom surface of the synthetic material, and a solid or foam layer of a conductive material, such as an open-cell urethane foam impregnated with finely-divided conductive particles, and a film-forming binder material to secure the particles uniformly onto the foam.
    Type: Grant
    Filed: June 19, 1980
    Date of Patent: November 17, 1981
    Assignee: Charleswater Products, Inc.
    Inventor: George R. Berbeco
  • Patent number: 4298710
    Abstract: An antistatic resin composition comprises 100 parts of a nitrile copolymer comprising 7 to 100% of a nitrile graft copolymer with a graft ratio of 4 to 50% obtained by graft-polymerizing a monomer mixture of a specific composition onto a rubber trunk polymer predominantly comprising a conjugated diolefin and/or an acrylate, and 0 to 93% of a nitrile random copolymer of a specific composition; and 0.05 to 10 parts of a surfactant added thereto. This antistatic resin composition, wherein the rubber trunk polymer forms a bridge structure, not only has, per se, an excellent antistatic property but also an antistatic property which undergoes substantially no change upon washing, for example, with water.
    Type: Grant
    Filed: August 30, 1979
    Date of Patent: November 3, 1981
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masaki Ohya, Akio Kobayashi, Takeo Ogiwara, Yoshikatsu Satake
  • Patent number: 4256824
    Abstract: Disclosed are positively charged toner compositions comprised of a thermoplastic resin, a pigment or colorant, and a charge inducing additive containing an amido dialkyl hydroxy ammonium compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from hydrocarbon radicals containing up to 22 carbon atoms; and more specifically R.sub.1 and R.sub.2 are hydrocarbon radicals containing from 1 carbon atom to about 8 carbon atoms, R.sub.3 is a hydrocarbon radical containing from about 8 carbon atoms to about 22 carbon atoms; R.sub.4 and R.sub.5 are independently selected from alkylene radicals having up to 8 carbon atoms, and preferably from 1 carbon atom to about 5 carbon atoms; and A is an anion such as nitrate, dihydrogen phosphate, methyl hydrogen phosphate, and dimethyl phosphate. Developers containing these positively charged toner materials are prepared by adding carrier materials thereto.
    Type: Grant
    Filed: October 1, 1979
    Date of Patent: March 17, 1981
    Assignee: Xerox Corporation
    Inventor: Chin H. Lu
  • Patent number: 4237194
    Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.
    Type: Grant
    Filed: February 16, 1979
    Date of Patent: December 2, 1980
    Assignee: Eastman Kodak Company
    Inventors: Donald A. Upson, David J. Steklenski
  • Patent number: 4221830
    Abstract: A method for producing an antistatic film of a synthetic polymer consisting essentially of continuously printing over at least part of the surface of at least one side of the film with aluminum powder by suspending in solvent a composition consisting essentially of aluminum powder and a polyamide resin, setting the suspension down onto the film, and permitting the solvent to evaporate The films obtained have a surface resistivity of less than 10.sup.10 ohms/cm and are useful, in addition to conventional uses such as packaging, for preventing virus degeneration of plants by virus-carrying aphides by mulching the plants with the films, limiting the increase in soil temperature in warm environments by mulching the soil with the films, and reducing the calorific energy necessary to heat greenhouses with the films.
    Type: Grant
    Filed: December 7, 1976
    Date of Patent: September 9, 1980
    Assignees: Societe des Plastiques de Carmaux SCASAR, Societe Chimique des Charbonnages CdF Chimie
    Inventors: Marcel Dalens, Armand Haas
  • Patent number: 4203769
    Abstract: An antistatic layer of a radiation-sensitive element, such as a photographic film or paper, is formed by coating and drying of an antistatic composition comprising an aqueous solution of an amorphous antistatic material, the aqueous solution having been produced by forming a melt comprised of at least 80% by weight of vanadium pentoxide and casting the melt into a solubilizing amount of water. In addition to vanadium pentoxide, the melt can contain a glass-forming compound, such as an alkaline metal phosphate or polyphosphate, as well as an oxide of an element that exists in at least two valence states, such as an oxide of molybdenum. The radiation-sensitive element preferably includes a protective overcoat layer covering the antistatic layer.
    Type: Grant
    Filed: July 14, 1976
    Date of Patent: May 20, 1980
    Assignee: Eastman Kodak Company
    Inventor: Claude Guestaux
  • Patent number: 4149999
    Abstract: An antistatic liquid, and method of use thereof, comprising an ionizable electroconductive polymer, an alcohol and a suitable solvent, for suppressing electrostatic charges which might otherwise develop in certain procedures relating to the manipulation and transport of microspheres, microbeads, or other microscopic particles, as well as the suppression of the reformation of polymers which might otherwise interfere with such procedures.
    Type: Grant
    Filed: October 11, 1977
    Date of Patent: April 17, 1979
    Assignee: Lockheed Aircraft Corporation
    Inventor: John V. Butler
  • Patent number: 4144206
    Abstract: A static dissipating heat curable silicone rubber composition comprising a diorganopolysiloxane polymer, a filler and a peroxide curing catalyst and as the static discharging agent a polyether-polysiloxane copolymer.
    Type: Grant
    Filed: January 13, 1978
    Date of Patent: March 13, 1979
    Assignee: General Electric Company
    Inventor: Gerald E. Symeon
  • Patent number: 4123475
    Abstract: Thermoplastic compositions comprising a polyphenylene ether resin alone or in admixture with a styrene resin are rendered resistant to the accumulation of surface electrostatic charges by the inclusion, in a minor, effective amount, of an antistatic agent consisting of a mixture of triethanolamine, toluene sulfonic acid and sodium lauryl sulfate. Flame retardant embodiments are also provided.
    Type: Grant
    Filed: December 28, 1977
    Date of Patent: October 31, 1978
    Assignee: General Electric Company
    Inventors: Visvaldis Abolins, Arthur Katchman
  • Patent number: 4115334
    Abstract: A vinylidene chloride copolymer coating composition containing small amounts of a polybasic acid of phosphorus, such as orthophosphoric acid, or sulfuric acid, in combination with a mono- or diglyceride. Organic polymeric films, such as polyester and regenerated cellulose films, coated therewith exhibit excellent antistatic properties. Such coated films can be run on various types of machinery without problems due to static build-up.
    Type: Grant
    Filed: May 20, 1977
    Date of Patent: September 19, 1978
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Clare William Gerow
  • Patent number: 4113679
    Abstract: The invention provides thermoplastic molding compositions and shaped articles made therefrom having improved antistatic properties, which comprise an antistatic agent a tricomponent mixture of a quaternary ammonium salt, a partial ester of a polyol and an organic acid, and an inorganic or organic compound containing an ammonium, alkali metal or alkaline earth metal ion. This antistatic agent is especially efficient and does not adversely affect the processability and the physical properties of the molding compositions.
    Type: Grant
    Filed: September 8, 1976
    Date of Patent: September 12, 1978
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hans-Joachim Andrascheck, Rainer Mucke
  • Patent number: 4107129
    Abstract: An antistatic acrylic fiber having an electrical resistivity of about 10.sup.8 .OMEGA. centimeters or less. The fiber comprises (A) an acrylonitrile homopolymer or copolymer and (B) an antistatic polymer comprising a plurality of polyether segments disposed in said polymer (A), and wherein electrically conductive carbon black is dispersed in antistatic polymer (B). Preferably antistatic polymer (B) extends in the form of long and slender stripes in the polymer (A).
    Type: Grant
    Filed: February 24, 1977
    Date of Patent: August 15, 1978
    Assignee: Toray Industries, Inc.
    Inventors: Hiroyoshi Tanaka, Teruo Koseki, Shigeru Fujii
  • Patent number: 4085087
    Abstract: A method of reducing the electrostatic charge aquired by a plastic composition by incorporating therein an antistatically effective amount of a mixed oxide of phosphorus and one or more metals selected from the group consisting of silicon, aluminum, titanium and iron, said mixed oxide having been prepared by flame hydrolysis; as well as the plastic composition containing said mixed oxide.
    Type: Grant
    Filed: September 5, 1975
    Date of Patent: April 18, 1978
    Assignee: Wacker Chemie GmbH
    Inventors: Gunter Kratel, Johann Bauer, Engelbert Pichler, Hans-Peter Kalmuk
  • Patent number: 4044070
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: February 18, 1976
    Date of Patent: August 23, 1977
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 4038258
    Abstract: Conductive compositions useful in imparting antistatic properties in filaments and other articles are provided, which comprise N-alkyl polycarbonamides, polyesters or polyetheresters having a Tg (NMR) less than 25.degree. C and from 0.02 to 35 weight percent of a phosphonium salt of a phosphonate, phosphinate, or sulfonate.
    Type: Grant
    Filed: October 22, 1976
    Date of Patent: July 26, 1977
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gurdial Singh, Richard Edward Von Rutte
  • Patent number: 4035346
    Abstract: An antistatic synthetic polymer having a T.sub.g (NMR) of less than 25.degree. C., a log R.sub.s of less than 10 and containing phosphonium sulfonate groups can be used to improve the conductivity of synthetic fiber-forming polymers.
    Type: Grant
    Filed: October 22, 1976
    Date of Patent: July 12, 1977
    Assignee: E. I. Du Pont de Nemours and Co.
    Inventors: Harry Vaughn Samuelson, Gurdial Singh
  • Patent number: 4017449
    Abstract: A mixture containing a cold-curing liquid synthetic resin combination, an anti-sedimentation agent and aluminium grit is used for the manufacture of antistatic floor coverings or coatings, which are colorful or lightcolored and have a uniform electrical conductivity of good reproducibility.
    Type: Grant
    Filed: February 9, 1976
    Date of Patent: April 12, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Thaddeus Audykowski, Kurt Amsler
  • Patent number: 4006123
    Abstract: An antistatic synthetic polymer having a T.sub.g (NMR) of less than 25.degree. C., a log R.sub.s of less than 10 and containing phosphonium sulfonate groups can be used to improve the conductivity of synthetic fiber-forming polymers.
    Type: Grant
    Filed: February 25, 1975
    Date of Patent: February 1, 1977
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Harry Vaughn Samuelson, Gurdial Singh
  • Patent number: 4005057
    Abstract: Conductive compositions useful in imparting antistatic properties in filaments and other articles are provided, which comprise N-alkyl polycarbonamides, polyesters or polyetheresters having a Tg (NMR) less than 25.degree. C and from 0.02 to 35 weight percent of a phosphonium salt of a phosphonate, phosphinate, or sulfonate.
    Type: Grant
    Filed: September 17, 1975
    Date of Patent: January 25, 1977
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gurdial Singh, Richard Edward VON Rutte
  • Patent number: 4004054
    Abstract: A mixture containing a cold-curing liquid synthetic resin combination, an anti-sedimentation agent and aluminium grit is used for the manufacture of anti-static floor coverings or coatings, which are colorful or lightcolored and have a uniform electrical conductivity of good reproducibility.
    Type: Grant
    Filed: April 11, 1975
    Date of Patent: January 18, 1977
    Assignee: Ciba-Geigy Corporation
    Inventors: Thaddeus Audykowski, Kurt Amsler
  • Patent number: 3998905
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: February 18, 1976
    Date of Patent: December 21, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3976717
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: August 21, 1975
    Date of Patent: August 24, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3976719
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: August 21, 1975
    Date of Patent: August 24, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3976715
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: August 21, 1975
    Date of Patent: August 24, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3976716
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: August 21, 1975
    Date of Patent: August 24, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3976718
    Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.
    Type: Grant
    Filed: August 21, 1975
    Date of Patent: August 24, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3975325
    Abstract: Disclosed is an antistatic agent composition for incorporation in synthetic resins comprised of a blend ofA. a zinc salt of a C.sub.8-22 fatty acid or a mixture of a zinc salt of a C.sub.8-22 fatty acid and a calcium salt of a C.sub.8-22 fatty acid, andB. a tertiary amine component selected from the group consisting of those represented by the formulas ##EQU1## or 3. A MIXTURE OF TERTIARY AMINES (1) OR (2) WITH A HIGHER ALIPHATIC ALCOHOL REPRESENTED BY THE GENERAL FORMULAR.sub.3 OHwhere each R.sub.1, R.sub.2, and R.sub.3 is independently selected from the group consisting of alkyl and alkenyl radicals containing from about 8 to 22 carbon atoms and n is a number of from 1 to 5.
    Type: Grant
    Filed: August 27, 1973
    Date of Patent: August 17, 1976
    Assignee: ICI United States Inc.
    Inventor: William Penuel Long, Jr.
  • Patent number: 3962185
    Abstract: A durably antistatic polyester composition comprising a polyethylene terephthalate-based polyester and an antistatic agent including a phosphorous acid triester derivative therein containing a polyalkylene oxide chain in the molecule.
    Type: Grant
    Filed: August 7, 1974
    Date of Patent: June 8, 1976
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kazuya Chimura, Hiroshi Iwata, Kazunori Kagawa, Kazuhiko Ishida
  • Patent number: 3959404
    Abstract: Powder coating compositions are disclosed which, exclusive of pigments and non-reactive components, comprise a coreactive mixture of: (A) a copolymer of between about 8 and about 30 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and between about 92 and about 70 weight percent of other monoethylenically unsaturated monomers, said copolymer having a glass transition temperature in the range of 40.degree. to 90.degree.C and a number average molecular weight (M.sub.n) of between about 2500 and about 8500; and (B) a phenolic hydroxy terminated compound in the amount of between about 0.8 and 1.2 phenolic hydroxy groups for each epoxy group in the copolymer.
    Type: Grant
    Filed: December 18, 1973
    Date of Patent: May 25, 1976
    Assignee: Ford Motor Company
    Inventors: Santokh S. Labana, Ares N. Theodore
  • Patent number: 3933733
    Abstract: Halogen-containing resins, particularly polyvinyl chloride, are stabilized by the incorporation of a phosphite of the formula, ##EQU1## wherein one or two of groups R.sub.1, R.sub.2 or R.sub.3 has the formula, R(OC.sub.n H.sub.2n).sub.m --, in which R is an alkyl unsubstituted or substituted with at least one hydroxyl or chlorine, an alkenyl unsubstituted or substituted with at least one hydroxyl or chlorine, or an aralkyl, n has a value of from 1 to 4, and m has a value of from 1 to 8, and the remaining group R.sub.1, R.sub.2 and/or R.sub.3 is an alkyl unsubstituted or substituted with at least one hydroxyl or chlorine, an alkenyl unsubstituted or substituted with at least one hydroxyl or chlorine, an aralkyl or an unsubstituted aryl.
    Type: Grant
    Filed: May 9, 1974
    Date of Patent: January 20, 1976
    Assignees: Kyodo Chemical Company, Limited, Sumitomo Chemical Company, Limited
    Inventors: Osamu Kimura, Katsuhiro Mukai, Minoru Osada, Shizuo Nara, Yoshitaka Tanaka, Masuo Yukitomi