Antistatic Agents Containing A Metal, Silicon, Boron Or Phosphorus Patents (Class 260/DIG16)
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Patent number: 6066442Abstract: An anti-static-treated film material having an electro-conductive layer is disclosed. The film material contains at least one selected from conductive particles and semi-conductive particles at an amount between 1 and 50 vol. % with respect to said electro-conductive layer and polymer particles having an average particle diameter of 0.01 to 5 .mu.m, and the absolute value of impedance of said film material under frequency at 20 Hz is between 4.times.10.sup.5 and 1.times.10.sup.20 .OMEGA.. The film material is suitably used as a support of asilver halide light sensitive material.Type: GrantFiled: October 21, 1996Date of Patent: May 23, 2000Assignee: Konica CorporationInventors: Yasuo Kurachi, Hidetoshi Ezure, Takayuki Sasaki, Masayoshi Yamauchi, Hitoshi Adachi, Eiichi Ueda, Yasuhiko Takamuki
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Patent number: 6004889Abstract: Disclosed is a compositions for antistatic finish, which is useful for antistatic stockings, comprising (a) 100 parts by weight of colloidal or ultrafine granular alumina on a solid basis, (b) 3 parts to 50 parts by weight of a binder on a solid basis, (c) 0.02 part to 2 parts by weight of at least one selected from the group consisting of silver salts, copper salts and colloidal silver on a metallic atom basis, and (d) 848 parts to 896.08 parts by weight of water (including water occasionally contained in the components of (a) to (c)).Type: GrantFiled: April 28, 1998Date of Patent: December 21, 1999Assignee: Kabushiki Kaisya NippankenkyusyoInventor: Yoshio Ichikawa
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Patent number: 5955526Abstract: An antistatic additive including a hexahalogenated ionic compound, and an antistatic additive composition for organic polymer compositions including an antistatically-effective amount of the hexahalogenated ionic compound, a solvent for the hexahalogenated ionic compound, and a diluent compatible with the hexahalogenated ionic compound, the solvent and the organic polymer composition. The hexahalogenated phosphate compound is preferably either potassium hexafluorophosphate, sodium hexafluorophosphate, and ammonium hexafluorophosphate. Organic polymer compositions containing the additive also are disclosed, as are methods of manufacturing both the additive and the polymer compositions.Type: GrantFiled: October 10, 1997Date of Patent: September 21, 1999Assignees: Cellular Technology International, Inc., Chemfoam International, Inc.Inventor: Dennis R. Spicher
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Patent number: 5549846Abstract: The invention relates to a method for the continuous preparation of vanadium pentoxide gel and an apparatus for implementing the method.According to the present invention, the vanadium pentoxide is raised to a temperature at least 100.degree. C. higher than its melting point; it is poured continuously into a quenching reactor 2 containing distilled water at ambient temperature; the gel obtained flows by overflowing to an ageing reactor 4, the contents of which are recirculated to the quenching reactor; the concentration of the gel contained in the ageing reactor 4 is measured continuously so as to adjust continuously the quantity of distilled water to be added to the quenching reactor 2; the contents of the ageing reactor are evacuated into a storage drum 9. Application to the manufacture of vanadium pentoxide for anti-static applications.Type: GrantFiled: December 3, 1993Date of Patent: August 27, 1996Assignee: Eastman Kodak CompanyInventors: Jean P. Tixier, Annie F. Legrand
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Patent number: 5491026Abstract: Process for applying an antistatic finish to synthetic fibers comprising of steps ofapplying to the fibers to be treated a composition comprising at least one salt of a phosphate partial ester containing a C.sub.12 straight chain alkyl group, a lubricant, and an anionic and/or cationic emulsifier; andautoclaving the treated fibers at a temperature in the range of from about 93.degree. to 150.degree. F.Type: GrantFiled: April 28, 1995Date of Patent: February 13, 1996Assignee: Henkel CorporationInventors: Elbert H. Mudge, Charles G. DeWitt
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Patent number: 4950544Abstract: A water based antistatic coating composition comprising:(a) at least one water soluble antistatic agent which is acceptable for food packaging polymer films;(b) at least one water soluble or water dispersible film-forming polymer; and,(c) a solution or dispersion-forming amount of water.When applied to a polymer film substrate, the foregoing antistatic coating composition forms, upon drying, and adherent antistatic coating.Type: GrantFiled: November 14, 1988Date of Patent: August 21, 1990Assignee: Mobil Oil CorporationInventor: Robert E. Touhsaent
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Patent number: 4943380Abstract: An antistatic resin composition with transparency contains 90-99.9 wt % of a synthetic resin selected from polycarbonate or polymethyl methacrylate and 0.1-10 wt % of a heat-resistant antistat containing phosphonium sulfonate shown by the general formula (I) below: ##STR1## where A is alkyl group with 1-36 carbon atoms, alkenyl group with 4-24 carbon atoms, phenyl group, phenyl group substituted by alkyl group with 1-18 carbon atoms, naphthyl group or naphthyl group substituted by alkyl group with 1-18 carbon atoms, R.sup.1, R.sup.2 and R.sup.3 are identical, each being an aliphatic hydrocarbon group with 1-8 carbon atoms or aromatic hydrocarbon group, and R.sup.4 is a hydrocarbon group with 1-18 carbon atoms.Type: GrantFiled: February 27, 1989Date of Patent: July 24, 1990Assignee: Takemoto Yushi Kabushiki KaishaInventors: Masato Sugiura, Hideo Shimizu, Shigeru Imamura, Fumitoshi Sugiura
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Patent number: 4604416Abstract: A methacrylic resin composition having excellent impact resistance and antistatic property is described. This composition comprises (I) 50-99.8 wt. % of a methacrylic resin comprised of 80-100 wt. % of methyl methacrylate units and 0-20 wt. % of other copolymerizable monomer units, (II) 0.1-40 wt. % of a rubbery component which is a polymer containing an elastomeric portion comprising at least 50 wt. % of 1,3-butadiene and/or acrylic acid ester units, and (III) 0.1-10 wt. % of a specified compound.Type: GrantFiled: December 13, 1984Date of Patent: August 5, 1986Assignee: Mitsubishi Rayon Company Ltd.Inventors: Yoshio Nakai, Katsusuke Yamauchi, Masaaki Kishimura, Masamitsu Tateyama
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Patent number: 4579902Abstract: The present invention provides a permanently antistatic, injection moldable thermoplastic composition comprising a polybutylene terephthalate resin having an intrinsic viscosity in the range of about 0.7 to about 1.4 deciliters per gram measured in ortho-chlorophenol at 25.degree. C., an antistatic dopant comprising an electron acceptor compound, an electron donor compound, and polytetrafluoroethlene, and less than about 10 percent by weight based on the total weight of the molding composition of carbon fibers having lengths between about 0.1 and about 1.0 inch. Such a molding composition exhibits a volume resistivity of less than 1.times.10.sup.8 ohm-cm, exceptional low wear performance, excellent mechanical properties, and ease of manufacture.Type: GrantFiled: December 5, 1984Date of Patent: April 1, 1986Assignee: Celanese CorporationInventor: David P. O'Brien
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Patent number: 4568485Abstract: The invention relates to plastics materials of high electrical conductivity containing TCNQ complexes and stabilized against the emission of HCN and to mouldings, films and coatings of such materials, as well as to the use of the plastics material for the production of antistatic foils and coatings onto substrates.Type: GrantFiled: September 17, 1984Date of Patent: February 4, 1986Assignee: Bayer AktiengesellschaftInventors: Friedrich Jonas, Jurgen Hocker
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Patent number: 4552687Abstract: Thermoplastic polymers, having antistatic properties, are obtained by incorporating in the polymers a liquid mixture of trialkylphosphine oxides.Type: GrantFiled: July 8, 1983Date of Patent: November 12, 1985Assignee: FMC CorporationInventors: Harry H. Beacham, Paul R. Mucenieks
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Patent number: 4393159Abstract: A thermoplastic material formed from a hydrocarbon chain is modified to inhibit the production of static charges. The thermoplastic material may be a polypropylene. A weak salt having properties of ionizing and having its positive ions bond chemically to the thermoplastic material is mixed in the thermoplastic material. A chemical agent is also dispersed in the thermoplastic material and is provided with properties of facilitating the dispersion of the positive ions of the weak salt throughout the thermoplastic material for chemical bonding to the thermoplastic material. The chemical agent may also be bonded chemically to the thermoplastic material. The weak salt may be cupric acetate and the chemical agent may be an ethoxylated amine when the thermoplastic material is polypropylene. The polypropylene is preferably mixed with a suitable material such as polyethylene to enhance the amorphous characteristics of the thermoplastic material.Type: GrantFiled: December 4, 1981Date of Patent: July 12, 1983Assignee: Bengal, Inc.Inventor: William Lybrand
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Patent number: 4391952Abstract: Polyethylene having a relatively high specific gravity is modified to inhibit the production of static charges. A weak salt having properties of ionizing and having its positive ions bond chemically to the polyethylene is mixed in the polyethylene. A chemical agent is also dispersed in the polyethylene and is provided with properties of facilitating the dispersion of the positive ions of the weak salt throughout the polyethylene of high specific gravity for chemical bonding to the polyethylene. The weak salt may be cupric acetate and the chemical agent may be an amine. The amine is preferably ethoxylated. The material of this invention may be formed as non-transparent bags or as sheets. The material may be formed by mixing the different chemicals and extruding the mixture under conditions of controlled temperatures and pressures and for controlled dwell times.Type: GrantFiled: December 4, 1981Date of Patent: July 5, 1983Assignee: Bengal, Inc.Inventor: William Lybrand
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Patent number: 4337188Abstract: A composition capable of being used for the manufacture of polyolefin film having so-called "cling" properties is disclosed. The composition consists essentially of(a) an intimate mixture of 75-98 weight percent of a first component and 2-25 weight percent of a second component, and(b) at least 200 ppm, based on the weight of (a), of an agent selected from the class consisting of(i) an organic compound having at least one polar group and at least one group selected from the class consisting of alkylene and alkylene interrupted by oxygen, said alkylene having at least eight carbon atoms and said compound being a liquid or a waxy solid;(ii) mineral oil;(iii) a liquid polyolefin; and(iv) an organic phosphate ester that is a liquid or waxy solid; and mixtures of such agents.A preferred agent is N,N-bis(2-hydroxyethyl) alkylamine where the alkyl group is C.sub.12 -C.sub.18 alkyl group. The first component is a blend of 10-100 percent of at least one homopolymer of ethylene having a density of 0.915-0.930 g/cm.sup.Type: GrantFiled: October 24, 1980Date of Patent: June 29, 1982Assignee: Du Pont Canada Inc.Inventors: David C. Climenhage, Walter R. Eadie
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Patent number: 4308332Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.Type: GrantFiled: May 1, 1980Date of Patent: December 29, 1981Assignee: Eastman Kodak CompanyInventors: Donald A. Upson, David J. Steklenski
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Patent number: 4301040Abstract: A static-free, polymeric surface mat to prevent the accumulation of static charge, particularly in the packaging and handling of electronic components and devices, which mat comprises a nonconductive, synthetic-material layer with a top surface, optionally an adhesive layer on the bottom surface of the synthetic material, and a solid or foam layer of a conductive material, such as an open-cell urethane foam impregnated with finely-divided conductive particles, and a film-forming binder material to secure the particles uniformly onto the foam.Type: GrantFiled: June 19, 1980Date of Patent: November 17, 1981Assignee: Charleswater Products, Inc.Inventor: George R. Berbeco
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Patent number: 4298710Abstract: An antistatic resin composition comprises 100 parts of a nitrile copolymer comprising 7 to 100% of a nitrile graft copolymer with a graft ratio of 4 to 50% obtained by graft-polymerizing a monomer mixture of a specific composition onto a rubber trunk polymer predominantly comprising a conjugated diolefin and/or an acrylate, and 0 to 93% of a nitrile random copolymer of a specific composition; and 0.05 to 10 parts of a surfactant added thereto. This antistatic resin composition, wherein the rubber trunk polymer forms a bridge structure, not only has, per se, an excellent antistatic property but also an antistatic property which undergoes substantially no change upon washing, for example, with water.Type: GrantFiled: August 30, 1979Date of Patent: November 3, 1981Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Masaki Ohya, Akio Kobayashi, Takeo Ogiwara, Yoshikatsu Satake
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Patent number: 4256824Abstract: Disclosed are positively charged toner compositions comprised of a thermoplastic resin, a pigment or colorant, and a charge inducing additive containing an amido dialkyl hydroxy ammonium compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently selected from hydrocarbon radicals containing up to 22 carbon atoms; and more specifically R.sub.1 and R.sub.2 are hydrocarbon radicals containing from 1 carbon atom to about 8 carbon atoms, R.sub.3 is a hydrocarbon radical containing from about 8 carbon atoms to about 22 carbon atoms; R.sub.4 and R.sub.5 are independently selected from alkylene radicals having up to 8 carbon atoms, and preferably from 1 carbon atom to about 5 carbon atoms; and A is an anion such as nitrate, dihydrogen phosphate, methyl hydrogen phosphate, and dimethyl phosphate. Developers containing these positively charged toner materials are prepared by adding carrier materials thereto.Type: GrantFiled: October 1, 1979Date of Patent: March 17, 1981Assignee: Xerox CorporationInventor: Chin H. Lu
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Patent number: 4237194Abstract: A coating composition useful in forming conductive layers comprises a latex having water as a continuous phase and, as a dispersed phase, hydrophobic polymer particles having associated therewith a polyaniline salt semiconductor. The coating composition can be coated on a variety of supports to produce conductive elements. The coating compositions are particularly useful in forming antistatic layers for photographic elements or conducting layers for electrophotographic and electrographic elements. Also disclosed is a preferred process for preparing a latex coating composition comprising the steps of loading polymer particles with the polyaniline component of the polyaniline acid addition salt semiconductor and then acidifying the latex to form a polyaniline salt coating composition.Type: GrantFiled: February 16, 1979Date of Patent: December 2, 1980Assignee: Eastman Kodak CompanyInventors: Donald A. Upson, David J. Steklenski
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Patent number: 4221830Abstract: A method for producing an antistatic film of a synthetic polymer consisting essentially of continuously printing over at least part of the surface of at least one side of the film with aluminum powder by suspending in solvent a composition consisting essentially of aluminum powder and a polyamide resin, setting the suspension down onto the film, and permitting the solvent to evaporate The films obtained have a surface resistivity of less than 10.sup.10 ohms/cm and are useful, in addition to conventional uses such as packaging, for preventing virus degeneration of plants by virus-carrying aphides by mulching the plants with the films, limiting the increase in soil temperature in warm environments by mulching the soil with the films, and reducing the calorific energy necessary to heat greenhouses with the films.Type: GrantFiled: December 7, 1976Date of Patent: September 9, 1980Assignees: Societe des Plastiques de Carmaux SCASAR, Societe Chimique des Charbonnages CdF ChimieInventors: Marcel Dalens, Armand Haas
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Patent number: 4203769Abstract: An antistatic layer of a radiation-sensitive element, such as a photographic film or paper, is formed by coating and drying of an antistatic composition comprising an aqueous solution of an amorphous antistatic material, the aqueous solution having been produced by forming a melt comprised of at least 80% by weight of vanadium pentoxide and casting the melt into a solubilizing amount of water. In addition to vanadium pentoxide, the melt can contain a glass-forming compound, such as an alkaline metal phosphate or polyphosphate, as well as an oxide of an element that exists in at least two valence states, such as an oxide of molybdenum. The radiation-sensitive element preferably includes a protective overcoat layer covering the antistatic layer.Type: GrantFiled: July 14, 1976Date of Patent: May 20, 1980Assignee: Eastman Kodak CompanyInventor: Claude Guestaux
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Patent number: 4149999Abstract: An antistatic liquid, and method of use thereof, comprising an ionizable electroconductive polymer, an alcohol and a suitable solvent, for suppressing electrostatic charges which might otherwise develop in certain procedures relating to the manipulation and transport of microspheres, microbeads, or other microscopic particles, as well as the suppression of the reformation of polymers which might otherwise interfere with such procedures.Type: GrantFiled: October 11, 1977Date of Patent: April 17, 1979Assignee: Lockheed Aircraft CorporationInventor: John V. Butler
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Patent number: 4144206Abstract: A static dissipating heat curable silicone rubber composition comprising a diorganopolysiloxane polymer, a filler and a peroxide curing catalyst and as the static discharging agent a polyether-polysiloxane copolymer.Type: GrantFiled: January 13, 1978Date of Patent: March 13, 1979Assignee: General Electric CompanyInventor: Gerald E. Symeon
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Patent number: 4123475Abstract: Thermoplastic compositions comprising a polyphenylene ether resin alone or in admixture with a styrene resin are rendered resistant to the accumulation of surface electrostatic charges by the inclusion, in a minor, effective amount, of an antistatic agent consisting of a mixture of triethanolamine, toluene sulfonic acid and sodium lauryl sulfate. Flame retardant embodiments are also provided.Type: GrantFiled: December 28, 1977Date of Patent: October 31, 1978Assignee: General Electric CompanyInventors: Visvaldis Abolins, Arthur Katchman
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Patent number: 4115334Abstract: A vinylidene chloride copolymer coating composition containing small amounts of a polybasic acid of phosphorus, such as orthophosphoric acid, or sulfuric acid, in combination with a mono- or diglyceride. Organic polymeric films, such as polyester and regenerated cellulose films, coated therewith exhibit excellent antistatic properties. Such coated films can be run on various types of machinery without problems due to static build-up.Type: GrantFiled: May 20, 1977Date of Patent: September 19, 1978Assignee: E. I. Du Pont de Nemours and CompanyInventor: Clare William Gerow
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Patent number: 4113679Abstract: The invention provides thermoplastic molding compositions and shaped articles made therefrom having improved antistatic properties, which comprise an antistatic agent a tricomponent mixture of a quaternary ammonium salt, a partial ester of a polyol and an organic acid, and an inorganic or organic compound containing an ammonium, alkali metal or alkaline earth metal ion. This antistatic agent is especially efficient and does not adversely affect the processability and the physical properties of the molding compositions.Type: GrantFiled: September 8, 1976Date of Patent: September 12, 1978Assignee: Hoechst AktiengesellschaftInventors: Hans-Joachim Andrascheck, Rainer Mucke
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Patent number: 4107129Abstract: An antistatic acrylic fiber having an electrical resistivity of about 10.sup.8 .OMEGA. centimeters or less. The fiber comprises (A) an acrylonitrile homopolymer or copolymer and (B) an antistatic polymer comprising a plurality of polyether segments disposed in said polymer (A), and wherein electrically conductive carbon black is dispersed in antistatic polymer (B). Preferably antistatic polymer (B) extends in the form of long and slender stripes in the polymer (A).Type: GrantFiled: February 24, 1977Date of Patent: August 15, 1978Assignee: Toray Industries, Inc.Inventors: Hiroyoshi Tanaka, Teruo Koseki, Shigeru Fujii
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Patent number: 4085087Abstract: A method of reducing the electrostatic charge aquired by a plastic composition by incorporating therein an antistatically effective amount of a mixed oxide of phosphorus and one or more metals selected from the group consisting of silicon, aluminum, titanium and iron, said mixed oxide having been prepared by flame hydrolysis; as well as the plastic composition containing said mixed oxide.Type: GrantFiled: September 5, 1975Date of Patent: April 18, 1978Assignee: Wacker Chemie GmbHInventors: Gunter Kratel, Johann Bauer, Engelbert Pichler, Hans-Peter Kalmuk
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Patent number: 4044070Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: February 18, 1976Date of Patent: August 23, 1977Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 4038258Abstract: Conductive compositions useful in imparting antistatic properties in filaments and other articles are provided, which comprise N-alkyl polycarbonamides, polyesters or polyetheresters having a Tg (NMR) less than 25.degree. C and from 0.02 to 35 weight percent of a phosphonium salt of a phosphonate, phosphinate, or sulfonate.Type: GrantFiled: October 22, 1976Date of Patent: July 26, 1977Assignee: E. I. Du Pont de Nemours and CompanyInventors: Gurdial Singh, Richard Edward Von Rutte
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Patent number: 4035346Abstract: An antistatic synthetic polymer having a T.sub.g (NMR) of less than 25.degree. C., a log R.sub.s of less than 10 and containing phosphonium sulfonate groups can be used to improve the conductivity of synthetic fiber-forming polymers.Type: GrantFiled: October 22, 1976Date of Patent: July 12, 1977Assignee: E. I. Du Pont de Nemours and Co.Inventors: Harry Vaughn Samuelson, Gurdial Singh
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Patent number: 4017449Abstract: A mixture containing a cold-curing liquid synthetic resin combination, an anti-sedimentation agent and aluminium grit is used for the manufacture of antistatic floor coverings or coatings, which are colorful or lightcolored and have a uniform electrical conductivity of good reproducibility.Type: GrantFiled: February 9, 1976Date of Patent: April 12, 1977Assignee: Ciba-Geigy CorporationInventors: Thaddeus Audykowski, Kurt Amsler
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Patent number: 4006123Abstract: An antistatic synthetic polymer having a T.sub.g (NMR) of less than 25.degree. C., a log R.sub.s of less than 10 and containing phosphonium sulfonate groups can be used to improve the conductivity of synthetic fiber-forming polymers.Type: GrantFiled: February 25, 1975Date of Patent: February 1, 1977Assignee: E. I. Du Pont de Nemours and CompanyInventors: Harry Vaughn Samuelson, Gurdial Singh
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Patent number: 4005057Abstract: Conductive compositions useful in imparting antistatic properties in filaments and other articles are provided, which comprise N-alkyl polycarbonamides, polyesters or polyetheresters having a Tg (NMR) less than 25.degree. C and from 0.02 to 35 weight percent of a phosphonium salt of a phosphonate, phosphinate, or sulfonate.Type: GrantFiled: September 17, 1975Date of Patent: January 25, 1977Assignee: E. I. Du Pont de Nemours and CompanyInventors: Gurdial Singh, Richard Edward VON Rutte
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Patent number: 4004054Abstract: A mixture containing a cold-curing liquid synthetic resin combination, an anti-sedimentation agent and aluminium grit is used for the manufacture of anti-static floor coverings or coatings, which are colorful or lightcolored and have a uniform electrical conductivity of good reproducibility.Type: GrantFiled: April 11, 1975Date of Patent: January 18, 1977Assignee: Ciba-Geigy CorporationInventors: Thaddeus Audykowski, Kurt Amsler
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Patent number: 3998905Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers one of which has at least two different functional groups while the other is qualitatively monofunctional and quantitatively polyfunctional. Ordinarily, the polymer having at least two different functional groups, will be quantitatively polyfunctional and qualitatively difunctional although it may contain more than two different functional groups. In the preferred embodiments, the first or difunctional copolymer of the blend has either (1) epoxy functionality and amide functionality, (2) epoxy functionality and hydroxy functionality, (3) carboxy functionality and amide functionality, or (4) carboxy functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: February 18, 1976Date of Patent: December 21, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976717Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976719Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976715Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976716Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3976718Abstract: Powder coating compositions are disclosed which comprise a blend of coreactable, thermosettable copolymers each of which have at least two different functional groups. Ordinarily, these polymers will be qualitatively difunctional, although they may contain more than two different functional groups, and quantitatively polyfunctional. At least one of the copolymers has epoxy functionality as one of its two or more different functionalities. Thus, in the preferred embodiments, the first copolymer of the blend has epoxy functionality and a second functionality selected from amide functionality, anhydride functionality and hydroxy functionality and is crosslinkable with the second copolymer through at least two different types of functional groups on the first copolymer.Type: GrantFiled: August 21, 1975Date of Patent: August 24, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3975325Abstract: Disclosed is an antistatic agent composition for incorporation in synthetic resins comprised of a blend ofA. a zinc salt of a C.sub.8-22 fatty acid or a mixture of a zinc salt of a C.sub.8-22 fatty acid and a calcium salt of a C.sub.8-22 fatty acid, andB. a tertiary amine component selected from the group consisting of those represented by the formulas ##EQU1## or 3. A MIXTURE OF TERTIARY AMINES (1) OR (2) WITH A HIGHER ALIPHATIC ALCOHOL REPRESENTED BY THE GENERAL FORMULAR.sub.3 OHwhere each R.sub.1, R.sub.2, and R.sub.3 is independently selected from the group consisting of alkyl and alkenyl radicals containing from about 8 to 22 carbon atoms and n is a number of from 1 to 5.Type: GrantFiled: August 27, 1973Date of Patent: August 17, 1976Assignee: ICI United States Inc.Inventor: William Penuel Long, Jr.
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Patent number: 3962185Abstract: A durably antistatic polyester composition comprising a polyethylene terephthalate-based polyester and an antistatic agent including a phosphorous acid triester derivative therein containing a polyalkylene oxide chain in the molecule.Type: GrantFiled: August 7, 1974Date of Patent: June 8, 1976Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuya Chimura, Hiroshi Iwata, Kazunori Kagawa, Kazuhiko Ishida
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Patent number: 3959404Abstract: Powder coating compositions are disclosed which, exclusive of pigments and non-reactive components, comprise a coreactive mixture of: (A) a copolymer of between about 8 and about 30 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and between about 92 and about 70 weight percent of other monoethylenically unsaturated monomers, said copolymer having a glass transition temperature in the range of 40.degree. to 90.degree.C and a number average molecular weight (M.sub.n) of between about 2500 and about 8500; and (B) a phenolic hydroxy terminated compound in the amount of between about 0.8 and 1.2 phenolic hydroxy groups for each epoxy group in the copolymer.Type: GrantFiled: December 18, 1973Date of Patent: May 25, 1976Assignee: Ford Motor CompanyInventors: Santokh S. Labana, Ares N. Theodore
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Patent number: 3933733Abstract: Halogen-containing resins, particularly polyvinyl chloride, are stabilized by the incorporation of a phosphite of the formula, ##EQU1## wherein one or two of groups R.sub.1, R.sub.2 or R.sub.3 has the formula, R(OC.sub.n H.sub.2n).sub.m --, in which R is an alkyl unsubstituted or substituted with at least one hydroxyl or chlorine, an alkenyl unsubstituted or substituted with at least one hydroxyl or chlorine, or an aralkyl, n has a value of from 1 to 4, and m has a value of from 1 to 8, and the remaining group R.sub.1, R.sub.2 and/or R.sub.3 is an alkyl unsubstituted or substituted with at least one hydroxyl or chlorine, an alkenyl unsubstituted or substituted with at least one hydroxyl or chlorine, an aralkyl or an unsubstituted aryl.Type: GrantFiled: May 9, 1974Date of Patent: January 20, 1976Assignees: Kyodo Chemical Company, Limited, Sumitomo Chemical Company, LimitedInventors: Osamu Kimura, Katsuhiro Mukai, Minoru Osada, Shizuo Nara, Yoshitaka Tanaka, Masuo Yukitomi