By Drawing Over A Form Patents (Class 264/292)
-
Patent number: 4923692Abstract: A process for producing pitch-type carbon fibers, which comprises melt-spinning pitch material in a gaseous atmosphere to form pitch fibers, gathering the pitch fibers in the presence of an oiling agent into a tow, followed by infusible treatment, carbonization treatment and, if necessary, graphitization treatment, of the tow of pitch fibers, characterized in that the tow of pitch fibers is brought in contact with a washing liquid to wash the surface of the pitch fibers prior to the infusible treatment.Type: GrantFiled: October 3, 1988Date of Patent: May 8, 1990Assignee: Mitsubishi Kasei CorporationInventors: Akira Nakagoshi, Hiroshi Tahara, Tetuo Yamada, Hiroyuki Sekiguchi, Hidemi Murata
-
Patent number: 4921686Abstract: A vertical apparatus for continuously carbonizing and activating various types of fiber materials. The apparatus comprising a chamber having openings at upper and lower portions thereof, at least one port through which an activating gas is passed for activation of the fiber material and a heater for keeping the temperature in the chamber, a means for vertically passing the fiber material in a continuous manner for the carbonization and activation, and a means for supplying the activating gas into the chamber. A method for continuously carbonizing and activating fiber materials in an efficient manner is also described.Type: GrantFiled: May 31, 1988Date of Patent: May 1, 1990Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Akihiko Yoshida, Atsushi Nishino, Ichiro Tanahashi, Yasuhiro Takeuchi
-
Patent number: 4921656Abstract: An acrylic multifilamentary material possessing an internal structure which is particularly suited for thermal conversion to high strength carbon fibers is formed via a specifically defined combination of processing conditions. The acrylic polymer while in substantially homogeneous admixture with appropriate concentrations (as defined) of acetonitrile, C.sub.1 to C.sub.4 monohydroxy alkanol, and water is melt extruded and is drawn at a relatively low draw ratio which is substantially less than the maximum draw ratio achievable. This fibrous material which is capable of readily undergoing drawing is passed through a heat treatment zone wherein the evolution of residual acetonitrile, the monohydroxy alkanol and water takes place. The resulting fibrous material following such heat treatment is subjected to additional drawing to accomplish further orientation and internal structure modification and to produce a fibrous material of the appropriate denier for carbon fiber production.Type: GrantFiled: August 25, 1988Date of Patent: May 1, 1990Assignee: BASF AktiengesellschaftInventors: Gene P. Daumit, Yoon S. Ko, Christopher R. Slater, Jozef G. Venner, Chi C. Young
-
Patent number: 4919860Abstract: The invention relates to a process for making porous carbon membranes and membranes which can made by this process. As starting material, a porous membrane from an acrylonitril-polymer is used. The starting material is pretreated with a hydrazine solution, followed by preoxidation and carbonization. The process enables carbon membranes to be made with selectively adjusted pore sizes and tight pore size distribution. The pore sizes can lie in the ultrafiltration or microfiltration range. The membranes are suitable for separation processes, in which chemically aggressive media are used and for high-temperature processes. They can be used wherever electrical conductivity of the membranes is required.Type: GrantFiled: July 13, 1988Date of Patent: April 24, 1990Assignee: Akzo NVInventors: Erich Schindler, Franz Maier
-
Patent number: 4917903Abstract: For the production of decorative seams on dashboards or the like, molded of thermoplastic material by the deep-drawing method, or the like, a soft heated embossing die having a negative decorative seam is pressed briefly, at the instant of the deformation of the dashboard or the like, against the molding tool covered with the film. Elastic embossing cushions are glued into the molding tool, thereby providing that the decorative seam will have a convex curvature.Type: GrantFiled: January 11, 1988Date of Patent: April 17, 1990Inventor: Kurt Mente
-
Patent number: 4917836Abstract: A process of producing carbon fibers, which comprises oxidizing polyacrylonitrile filaments having a tensile strength at 240.degree. C. of 0.3 g/d or higher and a tensile modulus at 240.degree. C. of 2.0 g/d or higher in an oxidizing atmosphere under a high tension of 0.2 g/d or higher, and carbonizing the oxidized filaments under a high tension.Type: GrantFiled: October 27, 1988Date of Patent: April 17, 1990Assignee: Toray Industries, Inc.Inventors: Shoji Yamane, Tomitake Higuchi, Katsumi Yamasaka
-
Patent number: 4915926Abstract: Carbon fibers having balanced properties comprising an ultra-high modulus greater than 100 Mpsi and a high tensile strength of greater than 500 kpsi. The carbon fibers are derived from a solvent fractionated pitch having a mesophase content of greater than 90% by weight and a quinoline insolubles content of less than 1% by weight. A crude pitch feed is sequentially heat soaked, solvent fractionated, and extruded to form as-spun fibers. The latter are stabilized or infusibilized and then carbonized by multistage heat treatments involving separate precarbonization, carbonization, and graphitization steps with an intermediate cooling step.Type: GrantFiled: February 22, 1988Date of Patent: April 10, 1990Assignee: E. I. DuPont de Nemours and CompanyInventor: Jacob Lahijani
-
Patent number: 4915984Abstract: A process for producing almost perfect graphite films and fibers at lower graphization temperatures wherein a film or fiber of a polymer selected from a defined group is subjected to a preliminary heat treatment at a temperature of 400.degree. to 700.degree. C., under tension, in vacuo or in an inert gas, and then heat treating the film or fiber at a temperature of at least 1600.degree. C. in vacuo or in an inert gas, to graphitize the film or fiber. The process can be modified to produce graphite films having excellent electric conductivity and mechanical properties, by heat treating a polymer selected from a second defined group at a temperature of at least 1800.degree. C. in vacuo or in an inert gas, impregnating the film with a binder component, and then heat treating the impregnated film at a temperature of not more than 1400.degree. C.Type: GrantFiled: June 7, 1988Date of Patent: April 10, 1990Assignees: Reserach Development Corp., Matsushita Electric IndustrialInventor: Mutsuaki Murakami
-
Patent number: 4913889Abstract: High strength, high modulus carbon fibers derived from high mesophase content pitch, having a plurality of sheets formed of planes of hexagonal carbon networks oriented, in the direction of the fiber axis and having a cross-sectional arrangement which does not carbonize to a graphitic structure are characterized by electron and X-ray diffraction pattern wherein the (10) band is not resolved into (100) and (101) lines, by an interlayer spacing greater than 3.38 angstrom and by negative magnetic resistivity when composed to graphitized fibers.Type: GrantFiled: November 12, 1987Date of Patent: April 3, 1990Assignee: Kashima Oil CompanyInventors: Yasuyuki Takai, Minoru Takabatake, Hideyuki Nakajima, Katsumi Takano, Masami Watanabe
-
Patent number: 4913861Abstract: A carbon fiber-reinforced composite material is prepared by molding a textile weave-reinforced composite material using a plain textile weave obtained by weaving multifilament yarns comprising a plurality of substantially non-twisted carbon fiber filaments which have been bonded to each other with a sizing agent, wherein a yarn disintegrating step of breaking each bond between the filaments of yarns constituting said textile weave is included as a step preceding a composite molding step.Type: GrantFiled: December 28, 1988Date of Patent: April 3, 1990Assignees: Ishikawa Prefecture, Nippon Oil Co. LimitedInventors: Tadao Mishima, Atsuo Mitani, Takashi Yamamoto
-
Patent number: 4904424Abstract: Ceramic alloys or solid solutions are formed by dispersing a powdery metal alloy or intimate mixture of two alloying metals in a precarbonaceous polymer such as polyacrylonitrile, forming the mixture into a molded article such as fibers, and heating the molded articles at a temperature and in a pyrolyzation atmosphere sufficient to carbonize the polymer and cause reaction of the metals with carbon and/or the pyrolyzation gas.Type: GrantFiled: May 29, 1987Date of Patent: February 27, 1990Assignee: Hoechst Celanese CorporationInventor: Robert E. Johnson
-
Patent number: 4902453Abstract: A preformed yarn useful in forming fiber-reinforced carbon composite articles is disclosed which includes a core of a multiplicity of inorganic reinforcing fibers, a mixed powder provided in the interstices between the fibers and including a finely divided carbonaceous binder pitch and a finely divided coke, and a flexible sleeve formed of a thermoplastic resin and surrounding the core.Type: GrantFiled: June 2, 1988Date of Patent: February 20, 1990Assignee: Across Co., Ltd.Inventors: Akimitsu Okura, Toshoku Cho, Takao Nakagawa, Shimpei Gomi, Takuya Ueda
-
Patent number: 4900483Abstract: A novel isotropically reinforced microcomposite is described. An entirely fluid-phase method has been devised for producing the net-shape filamentary structures. The process depends for its success on the ability to generate in situ, within a shaped mold, a three-dimensional random weave of carbon filaments by catalytic decomposition of a hydrocarbon feed. Almost any desired filament filler matrix combination can be produced by utilizing chemical vapor deposition to modify the surface and bulk properties of the filamentary structure. Infiltration of filler matrix materials can be achieved by adaptation of existing materials technologies.Type: GrantFiled: October 29, 1987Date of Patent: February 13, 1990Assignee: Exxon Research and Engineering CompanyInventors: Horst Witzke, Bernard H. Kear
-
Patent number: 4898700Abstract: A process for producing preoxidized fibers, which comprises preoxidizing acrylic fibers having a fluorine-containing surface active agent and at least one phosphoric surface active agent selected from the group consisting of compounds represented by the following formulae (I), (II) and (III), and preoxidizing the acrylic fibers thus-obtained: ##STR1## wherein R.sub.1 represents an aliphatic hydrocarbon group having 1 to 17 carbon atoms, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, and each represents a hydrogen atom, a lower alkyl group, a hydroxyethyl group or a hydroxyisopropyl group, ##STR2## wherein R.sub.5, R.sub.6 and R.sub.7, which may be the same or different, each represents a hydrogen atom or a hydroxyethyl group.Type: GrantFiled: September 30, 1988Date of Patent: February 6, 1990Assignee: Toho Rayon Co., Ltd.Inventors: Osamu Yoshinari, Yoshifumi Kawakatsu, Hayashi Takahashi, Hideaki Fukuizumi
-
Patent number: 4898705Abstract: A method for producing a synthetic resin union joint, the method including the steps of forming a union nut having a screw portion and a union sleeve of an elastically softenable material, the union sleeve having a union swivel end and a connecting end, heating a length of the union nut at least equal to a thickness dimension of the flange part but not extending to the screw portion so as to elastically soften the length of the union nut, abutting one end of a truncated cone-shaped expansion guide with an end face of the union swivel end, shifting and enlarging the length of the union nut along the expansion guide so as to pass over the union swivel end and so that the union nut passes over the guide, and returning the length of the union nut to its original configuration due to a restoring force of the elastically softenable material so as to be positioned within the union swivel end and the connecting end.Type: GrantFiled: May 16, 1988Date of Patent: February 6, 1990Assignee: Kubotatekko Kabushiki KaishaInventors: Junsuke Kyomen, Masayuki Sakaguchi, Hiroto Fujii
-
Patent number: 4898723Abstract: A method for producing mesophase pitch based carbon fibers which enables to produce high strength high modulus carbon fibers at a relatively low temperature with stabilized production manner. This method comprises carbonizing infusibilized fibers, in an inert atmosphere under no tension state or a tension of 1 mg/denier or less in the first stage to give a specified interlayer spacing and a crystallite thickness and then carbonizing under a tension of 50-300 mg/denier at a temperature of 2600.degree. C. or more in the second stage.Type: GrantFiled: June 3, 1988Date of Patent: February 6, 1990Assignee: Petoca Ltd.Inventors: Yoshinori Suto, Toshiyuki Ito, Hideyuki Nakajima, Keiichiro Okamura, Shin-ichi Nayuki, Hiroyasu Ogawa, Harumitsu Enomoto
-
Patent number: 4897232Abstract: A liquid precursor system for a filament comprises an aluminium halohydrate complex, a magnesium salt and an organic silicate. The stoichiometry is such that a cordierite fibre is formed on firing the filament.Type: GrantFiled: June 1, 1988Date of Patent: January 30, 1990Assignee: Clinotherm LimitedInventors: Harold G. Emblem, Kenneth Jones, Jonathon M. Boulton
-
Patent number: 4897229Abstract: A shaped silicon carbide-based ceramic article having an improved mechanical strength is produced at a high efficiency by a process comprising the step of: forming an organic silicon polymer, for example, polycarbosilastyrene copolymer, into a predetermined shape, for example, a filament or film; doping the shaped polymer with a doping material consisting of at least one type of halogen, for example, bromine or iodine, in an amount of 0.01% to 150% based on the weight of the shaped polymer, to render the shaped polymer infusible; and pyrolyzing the infusible shaped polymer into a shaped SiC-based ceramic article at a temperature of 800.degree. C. to 1400.degree. C. in an inert gas atmosphere, optionally the halogen-doped shaped polymer being treated with a basic material, for example, ammonia, before the pyrolyzing step, to make the filament uniformly infusible.Type: GrantFiled: October 5, 1988Date of Patent: January 30, 1990Assignee: Teijin LimitedInventors: Toru Sawaki, Akio Nakaishi, Keizo Shimada, Takashi Watanabe
-
Patent number: 4895712Abstract: A process for producing carbon fiber or graphite fiber is provided. The process comprises spinning a carbonaceous pitch, doubling spun pitch fiber bundles, adding a heat resistant doubling treatment oil, passing the fiber bundles continuously and linearly through an oxygen rich gas, infusibilizing at a temperature of 350.degree. C. or less, then carbonizing or graphitizing infusibilized fiber bundles.Type: GrantFiled: April 22, 1988Date of Patent: January 23, 1990Assignee: Toa Nenryo Kogyo K.K.Inventors: Kikuji Komine, Hisao Kato, Tsutomu Naito, Takashi Hino, Hiroyuki Kuroda
-
Patent number: 4893391Abstract: The method of making a round-rolled part for a heat exchanger comprises connecting the tubes and the irradiating elements to each other to form a rectilinear network, clamping both ends of the rectilinear network and stretching and bending the clamped network so that it assumes an arcuate shape. The premise adopted is that of a network of flat tubes consisting of rectangular tubes and irradiating elements between them, the tube network being bent round around a narrow side of the tubes. The network has one end rigidly gripped on the bending tool. The tubular network is wound onto it by rotating the latter. There is applied to the other end of the network a retaining force which counteracts the winding-on force and which maintains the tube network under tensile stress. The apparatus comprises a rotatable round bending tool and a clamping means which tangentially clamps the end of the network. Spaced from the round bending tool there is a mating holder for firmly gripping the other end of the network.Type: GrantFiled: June 15, 1988Date of Patent: January 16, 1990Assignee: Kuhlerfabrik Langerer & Reich GMBH & Co. KGInventors: Werner Zobel, Wolfgang Ostertag
-
Patent number: 4894198Abstract: In a process for producing hollow bodies of oriented thermoplastic material, a hollow blank having a bottom portion and a substantially cylindrical wall portion with an opening at its end remote from its bottom portion is subjected to pre-expansion in the region of the opening and then thermofixing in a subsequent treatment step. The thermofixing operation may be preceded by a mechanical expansion operation for orienting the plastic material forming the wall portion of the blank.Type: GrantFiled: December 4, 1987Date of Patent: January 16, 1990Assignee: Krupp CorpoplastInventors: Peter Albrecht, Karl-Heinz Balkau, Vinco Cujic, Tilman Doring, Claus Horwege, Wolfgang Reymann, Klaus Vogel, Walter Wiedenfeld
-
Patent number: 4892722Abstract: A method for producing high strength, high modulus carbon fibers having a modulus of elasticity of 75 tonf/mm.sup.2 or more and a tensile strength of 250 kgf/mm.sup.2 or more is provided. This method comprises graphitizing mesophase-pitch-based carbon fibers at a temperature of 2600.degree. C. or more for several seconds or for several minutes while stretching said fibers with a stretching ratio which satisifies specified relations.Type: GrantFiled: June 3, 1988Date of Patent: January 9, 1990Assignee: Petoca Ltd.Inventors: Yoshinori Suto, Toshiyuki Ito, Hideyuki Nakajima, Yoshiyuki Suzuki, Shin-ichi Nayuki, Hiroyasu Ogawa, Harumitsu Enomoto
-
Patent number: 4885120Abstract: Ceramic metal oxide fibers are made by intercalating graphitic graphite fibers with a mixture of metal chlorides and then heating the intercalated fibers to oxidize or burn off the carbon leaving a metal oxide fiber having generally the shape and structure of the graphite fiber precursors to make composite fibers, such as binary fibers of aluminum oxide-zirconium oxide and aluminum oxide-ferric oxide.Type: GrantFiled: July 5, 1988Date of Patent: December 5, 1989Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Barry W. McQuillan, George H. Reynolds
-
Patent number: 4879334Abstract: The invention relates to an organopolyarylsilane which comprises aromatic ring segments having a skelton mainly comprising an aromatic condensed ring structure derived from an organic solvent soluble pitch and organosilane segments randomly bonded thereto with an Si--C linkage intervening therebetween and is soluble in an organic solvent, and further relates to an SiC--C based continuous inorganic fiber exhibiting excellent heat resistant strength, oxidation resistance and electro-conductivity, which is obtained by spinning the above organopolyarylsilane into fiber, and after infusibilizing, heat-treating said fiber under a nonreactive atmosphere at a high temperature. The above organopolyarylsilane can be efficiently obtained in extremely high yields, by a process wherein low boiling substances produced by pyrolysis of the starting material, i.e.Type: GrantFiled: November 6, 1987Date of Patent: November 7, 1989Assignee: The Foundation: The Research Institute for Special Inorganic MaterialsInventors: Yoshio Hasegawa, Kiyohito Okamura
-
Patent number: 4877571Abstract: A cuppable composite thermoplastic foil with a PVDC layer is subjected to a cupping process at a definite temperature and the container is formed by the cupping process, especially a vacuum cupping process. To provide a stronger and more stable container for food packaging the composite foil is heated to a temperature above the crystallization temperature of PVDC and because of that the crystal structure of the PVDC is broken up. The crystallization degree of the composite foil is reduced at least 50%, after which the composite foil is quenched at a temperature of less than 75.degree. C., advantageously below 50.degree. C. The cupping process is performed immediately after the quenching.Type: GrantFiled: November 4, 1987Date of Patent: October 31, 1989Assignee: Reifenhauser GmbH & Co. MaschinenfabrikInventor: Hans Reifenhauser
-
Patent number: 4874563Abstract: A continuous, substantially uniform tow useful in forming composite molded articles is prepared by forming a continuous tow of continuous carbon fibers, forming a continuous tow of thermoplastic polymer fibers to a selected width, uniformly and continuously spreading the carbon fiber two to a width that is essentially the same as the selected width for the thermoplastic polymer fiber tow, intermixing the tows intimately, uniformly and continuously, in a relatively tension-free state, and continuosuly withdrawing the intermixed tow.Type: GrantFiled: December 5, 1986Date of Patent: October 17, 1989Assignee: BASF Structural Materials Inc.Inventors: Paul McMahon, Tai-Shung Chung, Lincoln Ying
-
Patent number: 4874502Abstract: The unwanted components from coal tars should be removed at a certain stage of the process for producing homogeneous spinning pitches which are suitable for use in the production of high-performance carbon fibers from coal tars. The unwanted components can be eliminated from coal tars in a very efficient manner by the following procedures: subjecting the coal tars to distillation or flash distillation so as to separate a heavy component having a boiling point higher than a predetermined temperature, dissolving the heavy component in a monocyclic aromatic hydrocarbon solvent, and subjecting the solution to filtration or centrifugation.Type: GrantFiled: July 19, 1988Date of Patent: October 17, 1989Assignee: Maruzen Petrochemical Co., Ltd.Inventors: Masatoshi Tsuchitani, Sakae Naito
-
Patent number: 4871491Abstract: A composite article is prepared by forming a continuous tow of continuous carbon fibers, forming a continuous tow of thermoplastic polymer fibers, uniformly and continuously spreading the thermoplastic polymer fibers to a selected width, uniformly and continuously spreading the carbon fiber tow to a width that is essentially the same as the selected width for the thermoplastic polymer fiber tow, intermixing the tows intimately, uniformly and continuously, in a relatively tension-free state, continuously withdrawing the intermixed tow and applying the tow to a mold and heating the tow.Type: GrantFiled: January 6, 1987Date of Patent: October 3, 1989Assignee: BASF Structural Materials Inc.Inventors: Paul E. McMahon, Tai-Shung Chung, Lincoln Ying
-
Patent number: 4869854Abstract: A process for manufacturing an organic silazane polymer which comprises reacting ammonia with a mixture of at least one compound selected from the group consisting of organic silicon compounds of the following formulae (I) and (II) ##STR1## and at least one compound selected from the group consisting of organic silicon compounds of the following formula (III) ##STR2## in which R represents hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical, R.sub.1 represents hydrogen or methyl radical, R.sub.2 represents hydrogen, methyl radical, ethyl radical, phenyl radical or vinyl radical and X represents chlorine or bromine; to obtain an ammonolysis product. The ammonolysis product is polymerized in the presence of a basic catalyst capable of deprotonation to obtain an organic silazane polymer. The silazane polymer may be further melted, shaped and infusibilized. The thus infusibilized product is finally sintered to obtain a ceramic material.Type: GrantFiled: October 27, 1987Date of Patent: September 26, 1989Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshihumi Takeda, Minoru Takamizawa, Akira Hayashida
-
Patent number: 4869856Abstract: A method for manufacturing carbon fiber strand from an acrylic polymer by steps of (a) wet spinning, (b) washing with water to obtain gelled fiber strand and (c) drying, wherein during the drying step the gelled fiber strand is shrunk by about 5 to 15% when the water of the gelled fiber strand is within a range of from about 100 to 20% by weight based on the weight of the dry fiber strand. An acrylic fiber strand without coalescence or entangling of filaments can consistently be obtained, from which carbon fibers with high quality and substantially no coalescence can be produced.Type: GrantFiled: August 7, 1987Date of Patent: September 26, 1989Assignee: Toho Rayon Co., Ltd.Inventors: Hayashi Takahashi, Tadasu Yagi
-
Patent number: 4865791Abstract: A method of forming a selectively expansible pocket or bulge in a thin plastic sheet to facilitate the use of the sheet as a surface protector or shield includes the step of applying oppositely directed forces to the sheet in a plurality of intermeshed closely spaced lines about a predetermined area in which it is desired to form a pocket. The forces are applied until stretching, thinning, and permanent deformation of the sheet takes place along the lines to produce a plurality of permanent corrugations to permit lateral deflection of the predetermined area.Type: GrantFiled: February 3, 1988Date of Patent: September 12, 1989Assignee: The Excello Specialty CompanyInventors: Salvatore D. Ferro, Robert A. Isaksen, Robert J. Stupi
-
Patent number: 4865807Abstract: A high pressure laminate comprising a plurality of heat molded sheets impregnated with duromeric synthetic resins characterized in that several of these sheets form on at least one surface of the laminate a heat-shapable surface layer (2,3) while the remaining sheets form a non-heat-shapable region which includes a core layer of the laminate.Type: GrantFiled: November 3, 1987Date of Patent: September 12, 1989Assignee: Isovolta Osterreichische Isolierstoffwerke AktiengesellschaftInventors: Georg Petershofer, Horst Felzmann
-
Patent number: 4863708Abstract: Disclosed herein is a process for producing pitch-based carbon fibers having the specific properties comparable to those of polyacrylonitrile(PAN)-based carbon fibers, wherein an optically isotropic pitch obtained by polymerizing naphthalene at a temperature of not more than 330.degree. C. and heating the thus obtained polymeric material at a temperature of 330.degree. to 440.degree. C. while introducing an inert gas thereinto to remove volatile components therefrom, is subjected to melt-spinning, infusibilization (therosetting) and carbonization and the thus obtained carbonized-fibers are subjected to heat treatment at a temperature of not less that 900.degree. C. to obtain the carbon fibers.Type: GrantFiled: January 3, 1989Date of Patent: September 5, 1989Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Ikuo Seo, Yasuo Sakaguchi, Ken Kashiwadate
-
Patent number: 4861653Abstract: Mesophase pitch centrifugally spun as described over a lip yields upon stabilization and carbonization with or without graphitization carbon fibers with a lamellar microstructure.Type: GrantFiled: September 2, 1987Date of Patent: August 29, 1989Assignee: E. I. Du Pont De Nemours and CompanyInventor: Robert G. Parrish
-
Patent number: 4861536Abstract: A method for manufacture of a sealing ring with a flanged sealing lip having hydrodynamically acting return transport properties in which a sealing lip is first generated by extrusion of a plastically deformable material through a ring nozzle having rotating inner and outer surfaces which are rotated relative to each other to impart a helical motion to the extruded material; the hydrodynamically acting return transport properties being a microscopically fine pleating of the surface of the extruded hollow cylinder. The extruded cylinder is then solidified and cut to a predetermined length. The cylinder is then widened in the radial direction at its front end by an assembly tool which shapes the cylinder into a trumpet-shaped sealing ring with a flanged sealing lip.Type: GrantFiled: June 12, 1987Date of Patent: August 29, 1989Assignee: Firma Carl FreudenbergInventors: Gunter Graf, Heinz Gross, Stefan Sponagel
-
Patent number: 4859381Abstract: A process for preparing pitch-type carbon fibers by melt-spinning a pitch-type material, rendering the material infusible and carbonizing it, characterized by the steps of passing molten pitch, before reaching the final nozzle, through a capillary portion of circular, otherwise shaped, or slit type to thereby apply a shearing stress at least 1/2 as high as the level of shearing stress to be exerted during the passage through the final nozzle orifice, maintaining the molten pitch in a state substantially free of shearing stress and then passing the pitch through the nozzle orifice for spinning.Type: GrantFiled: November 18, 1987Date of Patent: August 22, 1989Assignees: Osaka Gas Company Limited, Dainippon Ink and Chemicals Inc.Inventors: Hiroaki Morita, Kazutoshi Haraguchi, Eiji Tanigawa
-
Patent number: 4859382Abstract: A process for preparing a carbon fiber having an elliptical cross section, characterized by the steps of extruding spinnable pitch from a nozzle with an orifice rectangular or otherwise shaped in cross section and having a width/height ratio of more than 1, fully relaxing the molecules orientated by the nozzle on discharge from the nozzle, effecting continuous winding-up to obtain a pitch fiber elliptical in cross section, rendering the fiber infusible and carbonizing the same.Type: GrantFiled: November 16, 1987Date of Patent: August 22, 1989Assignees: Osaka Gas Company Limited, Dainippon Ink and Chemicals Inc.Inventors: Kazutoshi Haraguchi, Eiji Tanigawa, Kenji Nukina, Hiroaki Morita, Toyohiro Maeda
-
Patent number: 4856179Abstract: An electrical device is made by partially pyrolyzing polymer material by heating the material to between 500.degree. C. and 800.degree. C. Electrodes are applied to the material at two different locations to define an electrically active element therebetween. The device exhibits negative resistance in a portion of its voltage current domain and function as bi-directional electrical switches.This application is a continuation of application Ser. No. 859,709, filed May 5, 1986, now abandoned, which is a divisional application of application ser. No. 487,401, filed Apr. 21, 1983, now U.S. Pat. No. 4,642,644.Type: GrantFiled: January 5, 1988Date of Patent: August 15, 1989Assignee: Hoechst Celanese Corp.Inventors: Harris A. Goldberg, Ilmar L. Kalnin, Clyde C. Williams, Spain, Ian L.
-
Patent number: 4857246Abstract: Aluminum nitride fibers or films are made by carbothermal nitridation of precursor fibers or films which contain a source of alumina and a source of carbon. Improved articles are obtained by providing a stoichiometric excess of carbon, by stabilizing the precursor prior to carbonization and nitridation, by removing excess carbon after nitridation and introducing a sintering aid to promote densification of the final structure.Type: GrantFiled: January 21, 1988Date of Patent: August 15, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: John D. Bolt
-
Patent number: 4857490Abstract: Boron-containing ceramics are formed from organoboron precermaic polymers which are carboralated acetylenic poolymers. The polymers can be formed by carboralating acetylenic or diacetylenic diols and condensing the diols to form carboralated polyesters. In an alternative process, polydiacetylene formed by the polymerization of diacetylene monomers having conjugated triple bonds are carboralated subsequent to polymerization. A process for obtaining readily soluble polydiacetylenes comprises heating a diacetylene diol in a high boiling solvent.Type: GrantFiled: November 18, 1988Date of Patent: August 15, 1989Assignee: Hoechst Celanese Corp.Inventor: Robert E. Johnson
-
Patent number: 4855091Abstract: A method of preparing carbon filaments which comprises exposing a suitable thermostable substrate which is covered with reduced monocrystalline metal particles with a diameter of at least 5 nanometers to a carbon containing gas mixture at temperatures of about 250.degree. up to about 700.degree. C. to 800.degree. C., for a period of time sufficient to form filaments of the desired length, and thereafter removing the substrate and/or the metal particles. The filaments are characterized by a crystalline graphitic structure and a morphology defined by a fishbone-like arrangement of the graphite layers along the axis of the filaments. A high carbide content is a prerequisite for the nucleation of the filamentous carbon with a fishbone like structure.Type: GrantFiled: April 15, 1985Date of Patent: August 8, 1989Assignee: The Dow Chemical CompanyInventors: John W. Geus, John W. Linowski
-
Patent number: 4855122Abstract: Disclosed is a method for producing carbon fiber chopped strands excellent in bundling of fibers, high in bulk density, uniform in fiber length and superior in molding operability which includes application of an inorganic and/or organic binder in an amount of 0.1-3% by weight in terms of solid to carbon fiber or graphite fiber strands or chopped strands made from a petroleum or coal pitch.Type: GrantFiled: January 3, 1989Date of Patent: August 8, 1989Assignees: Nitto Boseki Co., Ltd., Kawasaki Steel CorporationInventors: Tadanori Kitamura, Hiroaki Shono, Atsuki Kodama
-
Patent number: 4849200Abstract: A process for fabricating a carbon/carbon fiber composite characterized in that one or more kinds of fibers selected from the group consisting of a pitch fiber obtained by spinning a carbonaceous pitch, an infusiblized fiber obtained by subjecting the pitch fiber to an infusiblizing treatment, and a pre-carbonized fiber obtained by subjecting the infusiblized fiber to a pre-carbonizing fiber at 400.degree. to 800.degree. C. in an inert gas atmosphere, are woven, laminated or mix-pulverized together with a pitch-based carbon fiber, and then carbonized under the application of pressure or under pressing.Type: GrantFiled: April 1, 1988Date of Patent: July 18, 1989Assignee: Nippon Oil Company, LimitedInventors: Seiichi Uemura, Yoshio Sohda, Yasuji Ido, Shunichi Yamamoto
-
Patent number: 4849153Abstract: A process for the production of a molding from at least one preform, in which process the preform, which has been heated to 330.degree. to 400.degree. C., is pressed by means of a pressure difference which increases slowly during the shaping into or onto a rigid mold heated to about the same temperature, and is then cooled while the pressure difference is maintained and is released from the mold. During the shaping and cooling, the edges of the preform are secured in their original position. The process makes it possible to produce moldings which have a thin wall thickness and a good surface and which exhibit a residual shrinkage which is sufficiently small for most applications.Type: GrantFiled: March 9, 1988Date of Patent: July 18, 1989Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Michel, Martin Neumeier
-
Patent number: 4847032Abstract: A process for producing hollow bodies from oriented thermoplastic material wherein a cylindrical portion of a heated hollow preform which has a bottom thereon is subjected to stretching at a starting temperature which is below the vitreous transition temperature of the thermoplastic material, with the wall thickness of the preform being reduced in the stretching operation. Prior to the stretching operation the preform is heated in the portion in which the stretching effect begins, to a temperature higher than in the portion adjoining same. Stretching is preferably effected along the axis of the preform at different rates such that in the portion of the preform at which stretching begins, stretching is effected at a lower rate than in the portion adjoining same in the stretching direction.Type: GrantFiled: September 15, 1988Date of Patent: July 11, 1989Assignee: Krupp Corpoplast Maschinenbau GmbHInventors: Peter Albrecht, Adolf Appel, Karl-Heinz Balkau, Edward Clar, Claus Horwege, Wolfgang Reymann, Klaus Vogel, Walter Wiedenfeld
-
Patent number: 4847345Abstract: A process for manufacturing an organic silazane polymer which comprises reacting an organic silicon compound of the following formula (I): ##STR1## in which R represents hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical, R.sub.1 represents hydrogen or methyl radical and X represents chlorine or bromine, or a mixture of organic silicon compounds of the formula (I) above and an organic silicon compound of the following formula (II): ##STR2## in which R.sub.2 and R.sub.3 represent hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical and X represents chlorine or bromine with a disilazane of the following formula (III): ##STR3## in which R.sub.4, R.sub.5, R.sub.6 represents hydrogen, methyl radical, ethyl radical, phenyl radical or vinyl radical in an anhydrous state at a temperature of from 25.degree. to 350.degree. C. while distilling off by-produced organic ingredients out of the system to obtain an organic silazane polymer.Type: GrantFiled: February 23, 1988Date of Patent: July 11, 1989Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Minoru Takamizawa, Yoshihumi Takeda, Akira Hayashida, Tsutomu Takeno
-
Patent number: 4840762Abstract: A process for the preparation of high-performance grade carbon fibers, which comprises attaching a fine powder of at least one member selected from oxides and carbides of silicon, aluminum, titanium, and boron to a precursor fiber bundle of as spun pitch fibers, subjecting the fiber bundle to an infusibilization treatment, and subjecting the fiber bundle to a carbonization treatment.Type: GrantFiled: October 22, 1985Date of Patent: June 20, 1989Assignee: Teijin Ltd.Inventors: Toru Sawaki, Hideharu Sasaki, Tsutomu Nakamura, Jiro Sadanobu
-
Patent number: 4836764Abstract: An apparatus for the thermal pressure forming of plastic blanks into containers includes several elements. A heater brings the plastic blanks to a melt phase by heating them to a melting temperature sufficient to relieve internal stresses therein. A conveying arrangement takes the plastic blanks through the heater. This conveying arrangement includes a device for preventing the plastic blanks from reaching the melting point only along their outer peripheral edges so that the plastic blanks maintain dimensional stability. Thereafter, a press forms the plastic blanks into retortable containers.Type: GrantFiled: October 13, 1987Date of Patent: June 6, 1989Assignee: QuesTech Ventures Inc.Inventor: Keith Parkinson
-
Patent number: 4837076Abstract: The invention provides a non-flammable non-linear elongatable carbonaceous fiber having a reversible deflection of greater than 1.2:1 and an aspect ratio of greater than 10:1 which may be formed into a resilient structure and the method of preparing said fiber.Type: GrantFiled: October 22, 1987Date of Patent: June 6, 1989Assignee: The Dow Chemical CompanyInventors: Francis P. McCullough, Jr., David M. Hall
-
Patent number: 4832932Abstract: Oxidizing treatment of carbon fibers under specific conditions provides carbon fibers having oxygen concentration (O.sub.1S /C.sub.1S atom number ratio) in the surface part of the carbon fibers of 0.05 to 0.30 as measured by X-ray photoelectron spectroscopy, coefficients of water-extractable fraction of up to 2.0, and coefficients of tow spread of at least 1.times.10.sup.-3. These carbon fibers are excellent in adhesion to various matrix resins and when mixed as reinforcements with matrix resins, provide composite materials superior especially in impact resistance. The thus obtained composite materials are useful for aircraft, automobiles, and general industrial materials.Type: GrantFiled: August 7, 1987Date of Patent: May 23, 1989Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hisashi Tada, Masahiro Saruta, Takashi Murata, Akira Agata, Setuo Kashiyama