Carboxylic Acid Or Derivative (e.g., Acrylic, Etc.) Patents (Class 264/331.18)
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Publication number: 20040108623Abstract: High flow engineering thermoplastic compositions made from a thermoplastic host polymer and a low molecular weight flow modifier polymer, and products made therefrom. The flow modifier polymer is made by polymerizing at least one vinyl aromatic monomer and at least one (meth)acrylate monomer.Type: ApplicationFiled: November 18, 2003Publication date: June 10, 2004Applicant: JOHNSON POLYMER, LLCInventors: Gary A. Deeter, Thomas J. Greeley, Marco A. Villalobos
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Publication number: 20040104501Abstract: The invention relates to a process for producing mouldings by injection moulding the steps in the process being a) melting and mixing of a (meth)acrylate copolymer composed of from 85 to 98% by weight of C1-C4-alkyl (meth)acrylates capable of free-radical polymerization and from 15 to 2% by weight of (meth)acrylate monomers having a quaternary ammonium group in the alkyl radical, with from 10 to 25% by weight of a plasticizer, and also from 10 to 50% by weight of a dryers [sic] and/or from 0.1 to 3% by weight of a release agent, and, where appropriate, with other conventional pharmaceutical additives or auxiliaries and/or with an active pharmaceutical ingredient, b) devolatilizing the mixture at temperatures of at least 120° C., thus reducing the content of the low-boiling constituents with a vapour pressure of at least 1.9 bar at 120° C. to not more than 0.5% by weight, and c) injecting the devolatilized mixture at a temperature of from 80 to 160° C.Type: ApplicationFiled: June 27, 2003Publication date: June 3, 2004Inventors: Hans-Ulrich Petereit, Thomas Beckert, Manfred Assmus, Werner Hoess, Wolfgang Fuchs, Hartmut Schikowsky
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Patent number: 6740279Abstract: Compression molded pigmented door skins fabricated by compression molding a pigmented, curable, unsaturated polyester sheet molding compound containing a co-curable unsaturated monomer, a low profile additive, and a microvoid-reducing thermoplastic polymer, exhibit uniform stainability while maintaining a low linear thermal coefficient of expansion. Such door skins are suitable for preparing wood grain textured exterior insulated doors which exhibit minimal thermal deflection when exposed to interior/exterior temperature differentials, even at eight foot door heights. The doors may be stained without first applying a seal coat.Type: GrantFiled: January 4, 2001Date of Patent: May 25, 2004Assignee: TT Technologies, Inc.Inventors: Kenneth J. West, Greg W. Scheffel, G. Daniel Templeton, Eugene R. Davis, III
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Publication number: 20040093831Abstract: The invention relates to a method for the plastic shaping of a biaxially-drawn film, comprising at least one base layer, containing at least one polymer (I), made from at least one hydroxycarboxylic acid and ≧0.2 wt %, based on the weight of the layer, of a thermoplastic polymer (II), different from polymer (I). Said film is plastically moulded by application of pneumatic and/or mechanical forces.Type: ApplicationFiled: September 22, 2003Publication date: May 20, 2004Inventors: Detlef Busch, Marlies Rosenbaum, Manfred Rosenbaum
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Patent number: 6696148Abstract: A plastic window panel for an automotive vehicle comprises a plastic panel of a transparent noncrystalline organic high polymer. Silica particulate is dispersed in the plastic panel and has a particle size not larger than wavelengths of visible light. The plastic window panel is produced by one of a first method and a second method. The first method comprises (a) providing a first solvent in which the silica particulate having the particle size not larger than wavelengths of visible light is dispersed, and a second solvent in which the transparent noncrystalline organic high polymer is dissolved; (b) mixing the first solvent and the second solvent to obtain a resin composition; and (c) molding the resin composition under heating.Type: GrantFiled: March 31, 1999Date of Patent: February 24, 2004Assignee: Nissan Motor Co., Ltd.Inventors: Takashi Seino, Kouichi Handa
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Patent number: 6670440Abstract: There is provided a technique for producing an aromatic polycarbonate which undergoes no deterioration in quality in a gear pump, has excellent hue and contains a small amount of foreign materials even when a production plant is scaled up. In producing the aromatic polycarbonate by melt-polycondensation, a molten polycondensate is fed continuously into a shaft seal portion of a self-lubricating gear pump disposed for transporting the polycondensate from a polycondensation vessel such that the following expressions: Q/S≧0.1 (cm/sec) wherein Q is a flow rate (cm3/sec) of the polycondensate, and S is a cross sectional area (cm2) of a passage provided for feeding the polycondensate to the shaft seal portion, and D≦2.9W1/3 wherein D is an internal diameter (cm) of a pipe, and W is a flow rate, are satisfied, thereby operating the gear pump. A polycondensation vessel therefor is also disclosed.Type: GrantFiled: August 7, 2002Date of Patent: December 30, 2003Assignee: Teijin LimitedInventors: Kyosuke Matsumoto, Masasi Simonaru, Toru Sawaki, Katsushi Sasaki, Keiichi Kaneko
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Patent number: 6656589Abstract: A polyamide resin pellet for a miniature part, comprising a polyamide resin (A) whose melting point as measured by DSC is in the range of 280 to below 330° C., which has an average volume of 0.001 to 21 mm3, the average volume determined by randomly sampling 50 pellets, measuring the weight and specific gravity of each of the pellets and dividing the weight by the specific gravity. The polyamide resin pellet exhibits low water absorption and is excellent in moldability, mechanical strength characteristics and heat resistance. Further, it has specified average volume, configuration, average diameter and average length, so that, in an injection molding, plasticization is smoothly effected to thereby enable obtaining a molded item or article which exhibits low dispersion of weight and strength and has excellent hue. The polyamide resin pellet is especially suitable for use in a molding material for forming miniature parts for motor vehicles and electrical or electronic equipments.Type: GrantFiled: December 19, 2001Date of Patent: December 2, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Yoshimasa Ogo, Tadayoshi Shiomura
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Publication number: 20030203140Abstract: An economical, three-dimensional reusable plastic article that is resistant to damage and stress caused by a variety of factors is disclosed. The plastic article comprises a polycarbonate/polyester plastic blend, and optionally further comprises a plastic insert. The polycarbonate/polyester blend may be fused directly to the optional plastic insert. Alternatively, the polycarbonate/polyester blend may be tied to the optional plastic insert through the use of an adhesive layer and/or a tie layer.Type: ApplicationFiled: April 24, 2002Publication date: October 30, 2003Inventors: Elena Sapatova, Rob Peterson, John Travers
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Patent number: 6613869Abstract: A branched polycarbonate resin suitable for making containers is disclosed. The polycarbonate is characterized in that at 260° C. and shear rate of 10 s−1 it has a melt viscosity of 5500 to 900 Pas, and in that at 260° C. and shear rate of 1000 s−1 it has a melt viscosity of 880 tom 1500 Pas, and in that it has a melt flow index (MFR) of 0.1 to 3.0 g/10 min. A container made of the polycarbonate exhibits great breaking strength.Type: GrantFiled: April 12, 2002Date of Patent: September 2, 2003Assignee: Bayer AktiengesellschaftInventors: Klaus Horn, Ralf Hufen, Wolfgang Alewelt, Peter Gebauer, Franky Bruynseels
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Publication number: 20030090017Abstract: Apparatus, methods and articles of manufacture are disclosed for installing an artificial eye in a realistic, life-like sculpture, comprising an artificial eye of partially hemispherical shape, as well as a manikin with an eye-mounting area adapted to mate with such an artificial eye without risk of subsequent movement of the eye or of distortion of the features surrounding the eye-mounting area of the sculpture. Eye mounting pieces for retrofitting existing sculptures having conventional eye mounting areas to permit the accurate and life-like mounting of artificial eyes are also provided.Type: ApplicationFiled: September 18, 2002Publication date: May 15, 2003Inventor: Brian Johnson
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Publication number: 20030075834Abstract: In order to obtain curable molding compositions and shaped plastics articles produced therefrom which have an improved hot-pot resistance, it is proposed that a curable molding composition for the production of shaped plastics articles contains, in addition to a liquid monomeric acrylate component and a particulate inorganic material, the latter in a concentration ranging from 45 to 85 wt % and preferably from 55 to 75 wt %, based on the molding composition, an additional portion comprising a particulate hydrophobic and/or oleophobic plastics material in a concentration of 0.5 wt % or more.Type: ApplicationFiled: April 11, 2002Publication date: April 24, 2003Inventors: Andreas Hajek, Stefan Harke, Josef Geier, Klaus Hock
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Patent number: 6544453Abstract: Shrinkage of cured resins is reduced by mixing the crosslinkable resin with a low profile additive (LPA). The LPA is in the form of particles which comprise an SCC polymer (or a similar crystalline polymer which melts over a narrow temperature range). The system is cured at a temperature above the melting point of the crystalline polymer (Tp), and the system and the LPA are such that at least part of the LPA remains as a separate phase in the curable resin at temperatures below Tp. It is believed that at least part of the crystalline polymer remains as a separate phase in the resin as it cures. Preferably at least part of the crystalline polymer forms a separate phase in the cured polymer after it has cooled.Type: GrantFiled: December 11, 2000Date of Patent: April 8, 2003Assignee: Landec CorporationInventors: David D. Taft, Steven P. Bitler
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Patent number: 6544451Abstract: A process is disclosed for direct extrusion of an acrylic polymer highly filled with aluminum trihydroxide wherein a lubricant is introduced to permit the composition to be extruded at a temperature below about 200° C.Type: GrantFiled: June 26, 2000Date of Patent: April 8, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Barry J. Heitner, Clyde Spencer Hutchins
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Patent number: 6525122Abstract: In order to achieve, in the case of a plastics moulding, in particular a moulded part such as e.g. a kitchen sink, a washbasin or a work-top or similar, comprising a polymer phase formed from a curable reaction mass and,: embedded therein, a particulate filling material which contains a resin material filled with an inorganic filler, in addition to a good resistance to water whitening a high resistance to crack formation in the hot-cold cycle, it is proposed that the polymer phase contains up to 5 wt %, referred to the plastics moulding, of inorganic additive particles, that the particulate filling material is swellable in the curable reaction mass, that the filled resin material comprises a content of inorganic filler in the range from 50 to 80 wt % with an average particle size of approx. 5 to approx. 100 &mgr;m, and that the filling material has a particle size in the range from 60 to 8000 &mgr;m and is contained in the plastics moulding in a proportion of approx. 30 to approx. 75 wt %.Type: GrantFiled: March 18, 1999Date of Patent: February 25, 2003Assignee: Schock & Co. GmbHInventors: Friedrich Schock, Karl Schock, Gunter Hieber, Daniel Knospe, Horst Schlier
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Patent number: 6521162Abstract: This invention is a compression molded part useful for transportation vehicles and in construction and a process for making compression molded parts. These light weight parts are molded at pressures less than 500 psi (3.5 MPa) and are made from a sheet molding composition or bulk molding composition which incorporates a thixotrope such as fumed silica.Type: GrantFiled: March 12, 2001Date of Patent: February 18, 2003Assignee: Ashland Inc.Inventors: Bruce Ronald Colley, Terry Phillip VanHyfte, Carl William Lakatos
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Publication number: 20030006520Abstract: A method of making patterned artificial material marble/granite/solid surface material that makes artificial marble/granite/solid surface material with variable patterns by use of polymers. The polymers are combined with filler materials, an accelerating reagent or colorful material to compose basic materials and pattern materials in different colors. Molds with at least one pattern are used for curing of the basic materials and the pattern material to form the patterned artificial material and to make the artificial marble/granite/solid surface material integral.Type: ApplicationFiled: July 5, 2001Publication date: January 9, 2003Inventor: Kuo-Yuan Lin
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Patent number: 6454983Abstract: A process is provided for single screw extrusion of a composition or masterbatch comprising a polymer and an antistatic agent wherein the feed zone temperature is maintained below 385° F. in order to allow processability of the composition.Type: GrantFiled: December 3, 1999Date of Patent: September 24, 2002Assignee: Eastman Chemical CompanyInventors: Douglas Stephens McWilliams, Harold Eugene Dobbs, Scott Arnold Hanson, Emily Tedrow Bell
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Patent number: 6455618Abstract: Described is a thermoplastic molding composition comprising: a) 0.05 to 1.5 wt. %, with respect to the entire molding composition, of a fatty acid amide ester wax; b) 0.5 to 10 wt. %, with respect to the entire molding composition, of a silica selected from natural silica, synthetic silica and mixtures thereof; c) 0 to 1 wt. %, with respect to the entire molding composition, of a montan wax; and d) at least one thermoplastic elastomer. Also described are a method of preparing the thermoplastic molding composition, and methods of preparing articles from the thermoplastic molding composition.Type: GrantFiled: June 7, 2001Date of Patent: September 24, 2002Assignee: Wolff Walsrode AGInventors: Ralf Schledjewski, Hans-Werner Funk, Dirk Schultze, Rainer Brandt
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Patent number: 6447913Abstract: To provide a thermoplastic polyester resin composition which has a very good durability to alkaline solutions for a long period of time. That is, a thermoplastic polyester resin composition, wherein a thermoplastic polyester resin (A) is compounded with 1-25% by weight (in the total composition) of impact resistance rendering materials (B), 0.1-15% by weight (in the total composition) of a silicone compound and/or a fluorine compound (C), 1-50% by weight (in the total composition) of an inorganic filler (D), and 0.1-10% by weight of at least one polyfunctional compound (E) selected from the group consisting of an epoxy compound, an isocyanate compound and a carboxylic acid dianhydride. A molded article of the present invention has anti-stress properties even in a weld part thereof.Type: GrantFiled: January 25, 2001Date of Patent: September 10, 2002Assignees: Polyplastics Co., LTD, Denso CorporationInventors: Kazufumi Watanabe, Takayuki Ishikawa, Toru Katsumata, Tetsuya Hirose, Hiroyuki Wakabayashi
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Patent number: 6444776Abstract: The present invention relates to novel crosslinkable amphiphilic block copolymers of formula wherein the variables are as defined in the claims, a process for their preparation and their use for the manufacture of mouldings. The block copolymers of the invention are especially useful for the manufacture of ophthalmic mouldings such as in particular contact lenses.Type: GrantFiled: December 21, 1999Date of Patent: September 3, 2002Assignee: Novartis AGInventors: Troy Vernon Holland, Thomas Hirt, Jacalyn Mary Schremmer, Richard Carlton Baron, Wilson Leonard Terry, Jr., Aaldert Rens Molenberg
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Patent number: 6440566Abstract: This invention relates to a method for molding or curing a resin material using a multilayer release film as a barrier at the surface of the resin material. In one embodiment, the method comprises the surface of the resin material being in contact with the release film at a temperature of at least about 350° F. (about 180° C.). Here, the release film is non-oriented and comprises: (1) an enhancement layer which comprises a thermoplastic material; and (2) a first release layer which has a composition that is different from the enhancement layer, comprises a polymeric material, and is releasable from the resin material after the resin material is molded or cured. This invention also relates to a release film that may be used, for example, with the above method.Type: GrantFiled: October 1, 1999Date of Patent: August 27, 2002Assignee: Airtech International, Inc.Inventors: John Maligie, Thomas Malter
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Patent number: 6426024Abstract: A preform having a small content of acetaldehyde can be advantageously produced by forming a vent, from which air is exhausted during molding, at a specific position of a molding machine in order for an aromatic polyester to be advantageously exposed under reduced pressure in a molten state when a preform of the aromatic polyester is injection molded.Type: GrantFiled: September 23, 1999Date of Patent: July 30, 2002Assignee: Teijin LimitedInventor: Akio Komenoi
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Patent number: 6361730Abstract: The present invention relates to a process for forming composite shaped articles used for athletic shoe soles, tubes, pipes, transmission belts and conveyor belts, comprising a vulcanized elastomer directly or autogenously bonded, that is, essentially in the absence of adhesive, to a thermoplastic elastomer comprising recurring polyamide-6 and polyether structural units, such as thermoplastic polyetheresteramide elastomers, are provided. The article is prepared by a process comprising placing a thermoplastic elastomer component into a vulcanization mold, overmolding onto at least a portion of the surface area of one face surface of the thermoplastic elastomer component with a vulcanizable elastomer component, and vulcanizing the vulcanizable elastomer component at a temperature below the melting point of the thermoplastic elastomer component but over a wide temperature range, which can be about 40° C. or higher.Type: GrantFiled: May 8, 1995Date of Patent: March 26, 2002Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Christian Dousson, Loic Tron, Martine Cerf
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Patent number: 6303069Abstract: A process for the production of moldings from a polymer alloy of multiphase morphology, in which the polymer alloy is prepared with the injection molding in one process step. For this, thermoplastically processable polymers which are incompatible or not very compatible with one another are introduced as granules, preferably having a particle size of greater than or equal to 3 mm, into the hopper of an injection molding machine and are subsequently plasticized, mixed thoroughly, and shaped in the injection molding machine; where at least one of the polymers employed is capable chemically, under the injection molding conditions, of association and/or copolymerization with at least one other of the participating polymers. The resulting polymer alloys are not inferior in their properties to corresponding conventionally produced alloys. The moldings are useful in orthopedics.Type: GrantFiled: November 6, 1997Date of Patent: October 16, 2001Assignee: Otto Bock Orthopaedische Industrie Besitz-Und Verwaltungs-KommanditgesellschaftInventors: Klaus-Peter Anhalt, Jürgen Deinert
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Publication number: 20010028132Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.Type: ApplicationFiled: March 16, 2001Publication date: October 11, 2001Inventors: Edward G. Nicholl, Navin B. Shah
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Patent number: 6255461Abstract: The invention relates to artificial antibodies that are prepared by molecular imprinting, where methacrylic acid, ethylene glycol dimethacrylate and a print molecule are combined to form an artificial antibody having spatially positioned binding sites dictated by the corticosteroid print molecule, and the antibodies can be used in separation and analytical procedures.Type: GrantFiled: April 5, 1996Date of Patent: July 3, 2001Inventors: Klaus Mosbach, Olof Ramstrom
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Patent number: 6238606Abstract: In the method of continuously producing pellets by continuously extruding a saponified ethylene-vinyl acetate (EVOH) solution in a strand form into a coagulation liquid and then cutting the resulting strand, the ratio between the weight X of the coagulation liquid and the weight Y of the strand of the saponified ethylene-vinyl acetate copolymer, namely the ratio X/Y, is set at 50 to 10,000. The coagulation liquid preferably contains 1 to 10,000 ppm of a carboxylic acid, 1 to 50,000 ppm of a carboxylic acid ester, or 1 to 15,000 ppm of a carboxylic acid salt. It is preferred as well that the water content of the continuously produced EVOH pellets be adjusted to 20 to 80% by weight and then brought into contact with an aqueous solution, having at least one boron compound, an acetic acid salt and a phosphoric acid compound.Type: GrantFiled: May 6, 1999Date of Patent: May 29, 2001Assignee: Nippon Gohsei Kagaku KogyoInventors: Makoto Kunieda, Koji Izumi, Kenji Ninomiya
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Patent number: 6235228Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.Type: GrantFiled: April 8, 1999Date of Patent: May 22, 2001Assignee: Morton International, Inc.Inventors: Edward G. Nicholl, Navin B. Shah
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Patent number: 6231799Abstract: Substantially sulfur free thermoplastic PMMA containing molding compositions are utilized with non-ferrous metal tools for the manufacture of molded articles. The use of such molding materials having a sulfur content of less than 50 ppm reduces the wear on the non-ferrous metal tools, particularly when utilized with injection molding and pressure molding. As a result of the use of sulfur free molding masses where it necessary to utilize tools of non-ferrous metal, there is a substantial economic advantage in the use thereof.Type: GrantFiled: February 17, 1999Date of Patent: May 15, 2001Assignee: Roehm GmbHInventors: Peter Kempf, Norbert Brand, Helmut Schwind, Stefan Roth, Holger Moritz
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Patent number: 6197240Abstract: An article of manufacture and method of making and implanting the article made of a polyolefin star or linear copolymer are disclosed in which the polyolefin copolymer is biostable and crack-resistant when implanted in vivo. The polyolefin copolymer is the reaction product of a rubbery component which when homopolymerized produces a polymer having a low level of hardness, and a hardening component which when homopolymerized produces a polymer having a high level of hardness. The polyolefin copolymer is elastomeric, has a hardness intermediate the low and high levels of hardness, and has a backbone in which the majority of polymer linkages along the copolymer chain are alternating quaternary and secondary carbon atoms.Type: GrantFiled: May 10, 1999Date of Patent: March 6, 2001Assignee: Corvita CorporationInventor: Leonard Pinchuk