High Energy Or Particulate Radiation (e.g., X-ray, Gamma Ray, Neutron, Etc.) Patents (Class 264/473)
  • Patent number: 11590677
    Abstract: The present disclosure is directed to a physically crosslinked, closed cell continuous multilayer foam structure comprising at least one foam polypropylene/polyethylene layer with a KEE cap layer. The multilayer foam structure can be obtained by coextruding a multilayer structure comprising at least one foam layer composition layer with at least one cap layer composition layer, irradiating the coextruded structure with ionizing radiation, and continuously foaming the irradiated structure.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: February 28, 2023
    Assignee: Toray Plastics (America), Inc.
    Inventors: Dan Ben-Daat, Jesse Jude Baldwin, Kaitlyn Michelle Bock, Pawel Sieradzki
  • Patent number: 11180648
    Abstract: The invention pertains to a fluoropolymer composition based on a combination of a thermoplastic fluoropolymer and a fluorinated thermoplastic elastomer, possessing improved impact resistance and outstanding flammability behaviour, to a method of making the same, and to a method of manufacturing shaped parts using the same, and to a method of manufacturing a mobile electronic device using said parts.
    Type: Grant
    Filed: March 13, 2018
    Date of Patent: November 23, 2021
    Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: David McIlroy, Keshav S. Gautam, Satchit Srinivasan
  • Patent number: 10471018
    Abstract: A computer-implemented method for image-guided delivery of a nanoparticle mixture to a target tumor located in a region of interest includes selecting a non-hypoxic delivery location within the region of interest for delivery of a non-bacteria-associated nanoparticle component included in the nanoparticle mixture and selecting a hypoxic delivery location within the region of interest for delivery of a bacteria-associated nanoparticle component included in the nanoparticle mixture. An image-guided delivery and monitoring process may then be performed.
    Type: Grant
    Filed: June 12, 2018
    Date of Patent: November 12, 2019
    Assignee: Siemens Medical Solutions USA, Inc.
    Inventors: Ankur Kapoor, Dorin Comaniciu
  • Patent number: 10022333
    Abstract: A computer-implemented method for image-guided delivery of a nanoparticle mixture to a target tumor located in a region of interest includes selecting a non-hypoxic delivery location within the region of interest for delivery of a non-bacteria-associated nanoparticle component included in the nanoparticle mixture and selecting a hypoxic delivery location within the region of interest for delivery of a bacteria-associated nanoparticle component included in the nanoparticle mixture. An image-guided delivery and monitoring process may then be performed.
    Type: Grant
    Filed: June 10, 2016
    Date of Patent: July 17, 2018
    Assignee: Siemens Medical Solutions USA, Inc.
    Inventors: Ankur Kapoor, Dorin Comaniciu
  • Patent number: 9931516
    Abstract: Methods are disclosed for treating cell components, cells, organelles, organs, and/or tissues with acoustic energy, electromagnetic energy, static or alternating electric fields, and/or static or alternating magnetic fields in the presence or absence of exogenous particulate agents for therapeutic applications.
    Type: Grant
    Filed: October 24, 2016
    Date of Patent: April 3, 2018
    Assignee: Board of Regents, The University of Texas System
    Inventor: Rinat O. Esenaliev
  • Patent number: 9017590
    Abstract: Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: April 28, 2015
    Assignee: Biomet Manufacturing, LLC
    Inventors: David W. Schroeder, Jordan H. Freedman, James E. Gunter, Brian D. Salyer, H. Gene Hawkins
  • Patent number: 8641959
    Abstract: Methods provide a non-eluting antioxidant doped UHMWPE in the form of an implant bearing component. The process includes the steps of: (a) providing a preform; (b) irradiating the preform with ?-irradiation to crosslink the UHMWPE; (c) doping the crosslinked preform by exposing it to an antioxidant composition at a temperature below the melting point of the UHMWPE; (d) removing the doped material from contact with the antioxidant composition; and then (e) annealing by heating the doped material at a temperature above 30° C. and below the melting point of the UHMWPE; followed by (f) making an implant bearing component from the doped material, wherein at least 1 mm but no more than about 15 mm of material are removed to make the component.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: February 4, 2014
    Assignee: Biomet Manufacturing, LLC
    Inventors: David W. Schroeder, Jordan H. Freedman
  • Publication number: 20130245772
    Abstract: Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
    Type: Application
    Filed: March 5, 2013
    Publication date: September 19, 2013
    Applicant: BIOMET MANUFACTURING CORP.
    Inventors: David W. SCHROEDER, Jordan H. FREEDMAN, James E. GUNTER, Brian D. SALYER, H. Gene HAWKINS
  • Publication number: 20110272862
    Abstract: Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
    Type: Application
    Filed: July 18, 2011
    Publication date: November 10, 2011
    Applicant: BIOMET MANUFACTURING CORP.
    Inventors: David W. SCHROEDER, Jordan H. FREEDMAN, James E. GUNTER, Brian D. SALYER, H. Gene HAWKINS
  • Publication number: 20110256395
    Abstract: A pressure-sensitive adhesive consisting of a homogeneous mixture of at least one natural rubber component and at least one polyacrylate component displays significantly improved properties in cohesion and aging and weathering resistance compared to the individual components. Particularly good properties are achieved when the adhesive contains x% by weight of at least one natural rubber component, y% by weight of at least one polyacrylate component, v% by weight of at least one adhesive resin component and w% by weight of additives, where 10?×x?80, 10?y<95, 0?v?50, 0?w?10 and x+y+v+w=100. A single- or double-sided adhesive tape consisting of at least one support and at least one layer of such a pressure-sensitive adhesive therefore likewise has good cohesion and aging resistance properties.
    Type: Application
    Filed: December 7, 2009
    Publication date: October 20, 2011
    Applicant: TESA SE
    Inventors: Franziska Zmarsly, Sabine Thormeier, Christian Kreft, Axel Burmeister, Stephan Bunz
  • Publication number: 20110152810
    Abstract: Embodiments of the disclosure include elastomeric stretch fibers containing an anti-tack agent, methods of preparing the fiber, methods of using this fiber, articles including this fiber, and the like.
    Type: Application
    Filed: December 16, 2010
    Publication date: June 23, 2011
    Applicant: INVISTA North America S.a.r.l.
    Inventors: James Michael LAMBERT, Young D. Nguyen, Robert O. Waldbauer, JR., Hong Liu
  • Publication number: 20100324207
    Abstract: Relates to mono-backsheets for photovoltaic modules. These mono-backsheets are produced or producible from a molding compound, this molding compound being based on at least one polyamide. The photovoltaic module mono-backsheet according to the invention is characterized in that the at least one polyamide is synthesized from linear and/or branched aliphatic and/or cycloaliphatic monomers, which have an average of at least 8 and at most 17 carbon atoms. The monomers are selected from the group which comprises diamines, dicarboxylic acids, lactams, and amino carboxylic acids, as well as mixtures thereof. The polyamides PA 610 and PA 612 are excluded from the present invention, and the polyamides based on lactams and amino carboxylic acids are cross-linked.
    Type: Application
    Filed: June 17, 2010
    Publication date: December 23, 2010
    Applicant: EMS-PATENT AG
    Inventors: André STURZEL, Georg STOEPPELMANN, Dietmar ETZEL, Botho HOFFMANN
  • Publication number: 20100218974
    Abstract: An insulated conductor and method for making it are disclosed. The insulated conductor includes an elongate conductor and a two-layer insulation system. The two-layer insulation system has a first insulating layer including an aromatic thermoplastic material adjacent with the elongate conductor. The first insulating layer has a thickness along its length of less than about 0.051 mm (0.002 inch). The insulation system also includes a second insulating layer including a crosslinked fluoropolymer adjacent the first insulating layer. The volume of the first insulating layer is less than about 26% of the total volume of the insulation system.
    Type: Application
    Filed: February 27, 2009
    Publication date: September 2, 2010
    Applicant: Tyco Electronics Corporation
    Inventor: Ashok K. Mehan
  • Patent number: 7727441
    Abstract: A tubular tissue scaffold is described which comprises a tube having a wall, wherein the wall includes biopolymer fibrils that are aligned in a helical pattern around the longitudinal axis of the tube where the pitch of the helical pattern changes with the radial position in the tube wall. The scaffold is capable of directing the morphological pattern of attached and growing cells to form a helical pattern around the tube walls. Additionally, an apparatus for producing such a tubular tissue scaffold is disclosed, the apparatus comprising a biopolymer gel dispersion feed pump that is operably connected to a tube-forming device having an exit port, where the tube-forming device is capable of producing a tube from the gel dispersion while providing an angular shear force across the wall of the tube, and a liquid bath located to receive the tubular tissue scaffold from the tube-forming device. A method for producing the tubular tissue scaffolds is also disclosed.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: June 1, 2010
    Inventors: Michael J. Yost, C. Michael Gore, Louis Terracio, Richard L. Goodwin, Edie C. Goldsmith
  • Patent number: 7678841
    Abstract: A method of increasing the gas transmission rate of a packaging film comprises providing a packaging film that comprises at least about 0.001 weight % of fullerene material selected from spherical fullerenes, bowl-shaped fullerenes, multi-walled carbon nanotubes, carbon nanocones, and carbon nano-onions. The packaging film is exposed to an amount of radiation energy effective to increase the oxygen transmission rate of the packaging film by at least about 100 cc (STP)/m2. day (1 atm, 0% RH, 23° C.).
    Type: Grant
    Filed: August 19, 2005
    Date of Patent: March 16, 2010
    Assignee: Cryovac, Inc.
    Inventor: Michael D. Grah
  • Patent number: 7608216
    Abstract: Methods for preparing a shaped rubber article, comprising admixing at least one thermoplastic material and at least one elastomer material to provide a processable and dimensionally stable rubber composition, shaping the composition, and irradiating the composition to form the shaped rubber article. The dimensional stability of the uncured composition may be provided by partial dynamic vulcanization, high performance reinforcing fillers, fractional curing, or combinations thereof. The elastomer material is present in an amount greater than about 65% by weight based on the total weight of the thermoplastic and elastomer materials present in the admixture.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: October 27, 2009
    Assignee: Freudenberg-Nok General Partnership
    Inventors: Edward H. Park, Francis Joseph Walker
  • Publication number: 20090047455
    Abstract: The present invention relates to a polymeric film, particularly designed for use on packages, irradiated with at least an amount of ionizing radiation (2) sufficient to increase the barrier to gases, the dose of energy deposited onto it ranging substantially from 10 to 150 kGy, and its mechanical properties undergoing an alteration equal to or lower than 20%.
    Type: Application
    Filed: October 3, 2006
    Publication date: February 19, 2009
    Inventor: Angel Visentim Ortiz
  • Publication number: 20080274245
    Abstract: The present invention includes a multicomponent structure comprising at least two components having a tie layer or adhesive layer directly between them, the tie layer comprising at least one olefin unsaturated ester copolymer and at least one photoinitiator and optionally a crosslinking enhancer. The tie layer is preferably irradiated with sufficient actinic radiation to result in increased interlayer adhesion strength between the two components as compared with the interlayer adhesion strength before treatment with the actinic radiation or between the components having a tie layer of the same composition except without the added photoinitiator or crosslinking enhancer. Without the photoinitiator, optionally crosslinking enhancer, and radiation the interlayer adhesion of the components is preferably less than 55 N/m.
    Type: Application
    Filed: April 5, 2005
    Publication date: November 6, 2008
    Inventors: Eric K.C. Lee, John A. Naumovitz, Mladen Ladika
  • Publication number: 20080217820
    Abstract: A tubular tissue scaffold is described which comprises a tube having a wall, wherein the wall includes biopolymer fibrils that are aligned in a helical pattern around the longitudinal axis of the tube where the pitch of the helical pattern changes with the radial position in the tube wall. The scaffold is capable of directing the morphological pattern of attached and growing cells to form a helical pattern around the tube walls. Additionally, an apparatus for producing such a tubular tissue scaffold is disclosed, the apparatus comprising a biopolymer gel dispersion feed pump that is operably connected to a tube-forming device having an exit port, where the tube-forming device is capable of producing a tube from the gel dispersion while providing an angular shear force across the wall of the tube, and a liquid bath located to receive the tubular tissue scaffold from the tube-forming device. A method for producing the tubular tissue scaffolds is also disclosed.
    Type: Application
    Filed: February 25, 2008
    Publication date: September 11, 2008
    Applicant: University of South Carolina
    Inventors: Michael J. Yost, C. Michael Gore, Louis Terracio, Richard L. Goodwin, Edie C. Goldsmith
  • Publication number: 20080188789
    Abstract: A tube for a peristaltic pump comprises an elastically deformable tubular body (2) made from a PVC composition containing: 100 phr of a PVC resin having a K value, measured according to standard ISO 1628-2, of not less than 85, from 40 to 100 phr of DEHA plasticizer, from 0.05 to 1.0 phr of lubricant, from 0.3 to 15.0 phr of stabilizer and co-stabilizer. The deformable tube, which is usefully employed for liquid transport in a dialysis apparatus, enables a high level of fluid transport efficiency to be maintained, even after many hours of peristaltic pump operation.
    Type: Application
    Filed: July 6, 2005
    Publication date: August 7, 2008
    Inventors: Francesca Galavotti, Carlo Giannella
  • Publication number: 20080161483
    Abstract: The present invention relates to a process for the preparation of discrete particles prepared from a cross-linkable PBT, at least one additive and/or at least one colorant, comprising the steps of mixing together the components, extruding the material, cooling and pelletizing the material, cross-linking the pellets using gamma radiation, electron beam radiation, or heating in an oven, and optionally grinding into particles with an average particle size between 1 and 1000 ?m. The present invention further relates to the use of said cross-linked PBT particles for making a polychromatic article which comprises a transparent or translucent thermoplastic material having said cross-linked PBT particles uniformly dispersed therein.
    Type: Application
    Filed: December 21, 2005
    Publication date: July 3, 2008
    Inventor: Thilo Kind
  • Publication number: 20080140196
    Abstract: Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
    Type: Application
    Filed: February 21, 2008
    Publication date: June 12, 2008
    Applicant: Biomet Manufacturing Corporation
    Inventors: David W. Schroeder, Jordan H. Freedman, James E. Gunter, Brian D. Salyer, H. Gene Hawkins
  • Patent number: 7344672
    Abstract: Solid-state deformation processing of crosslinked high molecular weight polymers such as UHMWPE, for example by extrusion below the melt transition, produces materials with a combination of high tensile strength and high oxidative stability. The materials are especially suitable for use as bearing components in artificial hip and other implants. Treated bulk materials are anisotropic, with enhanced strength oriented along the axial direction. The material is oxidatively stable even after four weeks of accelerated aging in a pressure vessel containing five atmospheres of oxygen (ASTM F2003). Because of its oxidative stability, the deformation processed material is a suitable candidate for air-permeable packaging and gas sterilization, which has thus far been reserved for remelted crosslinked UHMWPE.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: March 18, 2008
    Assignee: Biomet Manufacturing Corp.
    Inventors: David W. Schroeder, Jordan H. Freedman, James E. Gunter, Brian D. Salyer, H. Gene Hawkins
  • Patent number: 6858275
    Abstract: An irradiated multilayer film has a first layer and a second layer. The first layer is an outer heat seal layer containing a blend of a highly branched homogeneous polymer and a semicrystalline polymer. The highly branched homogeneous polymer has at least 40 branches per 1000 methylene groups, an Mw/Mn less than 3.0, and a density of less than 0.89 g/cc. The highly branched homogeneous polymer is present in an amount of from about 1 to 50 weight percent, based on layer weight. The semicrystalline polyolefin has a density of at least 0.90 g/cc. The semicrystalline polyolefin is present in an amount of from about 60 to 99 weight percent, based on total layer weight. The second layer contains a thermoplastic polymer in a crosslinked polymer network. A process for making a packaging article includes coextruding the first and second layers, irradiating the resulting multilayer film, and thereafter heat sealing the first layer to itself or another component of the packaging article.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: February 22, 2005
    Assignee: Cryovac, Inc.
    Inventors: Isabella Ferri, Slawomir Opuszko, Nathanael Rustia Miranda
  • Patent number: 6761965
    Abstract: An irradiated multilayer film has a first layer and a second layer. The first layer is an outer heat seal layer containing a blend of a highly branched homogeneous polymer and a semicrystalline polymer. The highly branched homogeneous polymer has at least 40 branches per 1000 methylene groups, an Mw/Mn less than 3.0, and a density of less than 0.89 g/cc. The highly branched homogeneous polymer is present in an amount of from about 5 to 50 weight percent, based on layer weight. The semicrystalline polyolefin has a density of at least 0.90 g/cc. The semicrystalline polyolefin is present in an amount of from about 50 to 95 weight percent, based on total layer weight. The second layer contains a thermoplastic polymer in a crosslinked polymer network. A process for making a packaging article includes coextruding the first and second layers, irradiating the resulting multilayer film, and thereafter heat sealing the first layer to itself or another component of the packaging article.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: July 13, 2004
    Assignee: Cryovac, Inc.
    Inventors: Isabella Ferri, Slawomir Opuszko, Nathanael Rustia Miranda
  • Publication number: 20040070104
    Abstract: The invention concerns a method which consists in: a) forming by extrusion an extruded thermoplastic tube (20) having, when coming out of the extruder, a diameter D1; b) then subjecting said extruded tube of diameter D1 to a radiation treatment, so as to produced a cross-linked tube (21); c) after bringing said cross-linked tube (21) to a temperature not less than a temperature substantially equal to the melting point of its crystalline phase, subjecting it, in displacement, to a radial monoaxial expansion for form an expanded tube (22) of diameter D2, then cooling it down to a temperature, typically room temperature, at which it can be cut into tube portions (23) with length substantially equal to the height of said caps (1); and e) assembling or forming a head (10, 100, 101, 102, 103) on said tube portion (23), so as to obtain a cap or top (1), with heat-shrinkable skirt, economical and having a homogeneous skirt (11, 12) free of axial connection line.
    Type: Application
    Filed: May 19, 2003
    Publication date: April 15, 2004
    Inventor: Jacques Granger
  • Patent number: 6660211
    Abstract: The present invention is directed to methods of making biodegradable films and biodegradable precursor films having enhanced breathability and ductility. The method includes blending a water soluble polymer and a biodegradable polymer to form a blended polymer mixture. The biodegradable polymer is preferably a biodegradable aliphatic polyester, and the water-soluble polymer is preferably polyethylene oxide and/or polyethylene glycol. The blended polymer mixture is formed into a precursor film. The precursor film is further processed to form a breathable biodegradable film.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: December 9, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Vasily A. Topolkaraev, Dave A. Soerens
  • Patent number: 6602457
    Abstract: The present invention relates to high dielectric non-woven fabrics and their synthetic process and more particularly, relates to a process for preparing high dielectric non-woven fabrics including the steps of (a) mix-spinning polyvinylidene fluoride (PVDF) and polypropylene (PP) to prepare a fiber, (b) polarizing the fiber prepared in the step (a) to improve the dielectric constant of the fiber, and (c) manufacturing non-woven fabrics from the fiber having improved dielectric constant, prepared in the step (b), and non-woven fabrics prepared according to the mentioned process.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: August 5, 2003
    Assignee: Clean Air Technology Co.
    Inventors: Choong-Joong Lee, Soon-Kyu Chung, Jin-Soo Joo
  • Patent number: 6602438
    Abstract: A structure for polymeric thermistor device and method of making the same are disclosed. The polymeric thermistor makes use of a polymeric composite filled with conductive filler and show resistance variations at different temperatures. A polymeric substrate filled with conductive filler is cross-linked so that the whole polymeric composite structure filled with conductive filler is able to memorize shape. Then, the cross-linked polymeric composite undergoes a simple-sheared process and turns into a polymeric composite with a strain more than 1%. Therefore, the micro-structure and electrical properties of the conductive filler are changed.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: August 5, 2003
    Assignee: Protectronics Technology Corporation
    Inventor: Chen-Ron Lin
  • Patent number: 6585926
    Abstract: A method of manufacturing a porous elastic membrane that may be used in a balloon assembly of a balloon catheter is described. In the method, an elastic membrane material is expanded beyond an intended deployment expansion to a hyper-expanded state. Apertures are then formed in the hyper-expanded material. After contraction, the now-porous membrane can be used to form the outer wall of the balloon assembly. An aperture formed in the hyper-expanded membrane will have a smaller diameter than when the balloon is inflated to a smaller deployment expansion in the patient's body.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: July 1, 2003
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventor: Daryush Mirzaee
  • Patent number: 6540953
    Abstract: A method of producing a microporous membrane comprising the steps of: extruding a polymer at a temperature of from (polymer melting point +10° C.) to (polymer melting point +100° C.); drawing the extruded polymer at a rate of 5˜120 m/min in 10˜150° C. to obtain a polymer film; annealing the polymer film at a temperature of from (polymer melting point −100° C.) to (polymer melting point −5° C.) for 10 seconds to 1 hour; irradiating both surfaces of the annealed polymer film with an ion-particle amount of 102˜1020 ion/cm2 energized at 10−2˜107 KeV, at an irradiating distance of 5˜100 cm under a vacuum of 10−2˜10−[torr; cold stretching the irradiated polymer film at a temperature of from −20° C. to (polymer melting point −40° C.); hot stretching the cold stretched polymer film at a temperature of from (polymer melting point −40° C.) to (polymer melting point −5° C.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: April 1, 2003
    Assignee: LG Chemical Ltd.
    Inventors: Sang-Young Lee, Myung-Man Kim, Heon-Sik Song
  • Publication number: 20030015826
    Abstract: The present invention is directed to methods of making biodegradable films and biodegradable precursor films having enhanced breathability and ductility. The method includes blending a water soluble polymer and a biodegradable polymer to form a blended polymer mixture. The biodegradable polymer is preferably a biodegradable aliphatic polyester, and the water-soluble polymer is preferably polyethylene oxide and/or polyethylene glycol. The blended polymer mixture is formed into a precursor film. The precursor film is further processed to form a breathable biodegradable film.
    Type: Application
    Filed: April 23, 2001
    Publication date: January 23, 2003
    Inventors: Vasily A. Topolkaraev, Dave A. Soerens
  • Patent number: 6506333
    Abstract: The present invention provides a method for fabricating a medical tubing. The method includes the steps of: (1) providing a material selected from the group consisting of ethylene homopolymers and ethylene copolymers, wherein the ethylene copolymers are obtained by copolymerizing ethylene with a comonomer selected from the group consisting of lower alkyl olefins, lower alkyl esters of a carboxylic acid and lower alkene esters of a carboxylic acid, the lower alkyl and lower alkene each have from 3-18 carbons, or blends thereof; (2) providing an extruder with an extrusion die; (3) extruding the material into a medical tubing; (4) providing a surface modifier solution; (5) preheating the surface modifier solution to a temperature within the range of 50-80° C.; and (6) applying the preheated solution onto the tubing at it exits the extrusion die when the tubing is in a molten state or a semi-molten state.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: January 14, 2003
    Assignee: Baxter International Inc.
    Inventors: Chuan Qin, Patrick T. Ryan, Michael T. K. Ling, Donna L. Rostron, Yuanpang S. Ding, Lecon Woo, Susan R. Mizener, Birendra K. Lal
  • Patent number: 6503439
    Abstract: Disclosed is a method of producing a shaped article suitable for use as the load bearing component of a prosthetic device formed from ultrahigh molecular weight polyethylene. polyethylene.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: January 7, 2003
    Inventor: Albert H. Burstein
  • Patent number: 6485665
    Abstract: Polyurethane elastomer fibers with superior mechanical and heat distortion properties are obtained by a method in which (a) a segmented polyurethane polymer is produced on the basis of a macro-diol, an aliphatic diisocyanate, and a chain extender with at least two hydroxy and/or amino groups, where the polymer has a molar excess of isocyanate groups over the hydroxy and/or amino groups from the macro-diol and chain extender; (b) the polyurethane polymer is melt-extruded to form a fiber; and (c) The extruded fiber is subjected to a post-treatment. Steps (a) and (b) are carried out under temperature conditions and within a time interval where essentially no allophanate will be formed, while step (c) is performed under temperature conditions and within a time interval in which the polyurethane polymer is cross-linked through the formation of allophanate.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: November 26, 2002
    Assignee: Rhodianyl S.N.C.
    Inventors: Frank Hermanutz, Peter Hirt, Oliver Oess, Wilhelm Oppermann
  • Patent number: 6454987
    Abstract: A laminated substrate is prepared, the laminated substrate having two layers including a first film and a second film in tight contact with the first film, the second film being made of a material capable of being etched with synchrotron radiation light. A mask member with a pattern is disposed in tight contact with the surface of the second film of the laminated structure or at a distance from the surface of the second film, the pattern of the mask member being made of a material not transmitting the synchrotron radiation light. The synchrotron radiation light is applied on a partial surface area of the second film via the mask member to etch the second film where the synchrotron radiation light is applied and to expose a partial surface area of the first film on the bottom of an etched area.
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: September 24, 2002
    Assignee: Sumitomo Heavy Industries, Inc.
    Inventors: Takanori Katoh, Yanping Zhang
  • Patent number: 6368533
    Abstract: A process for forming fibers, films and fibrous webs from thermoset polymers is disclosed. The process includes first forming an energy activatable prepolymer composition. The prepolymer composition is extruded through a die in order to form polymeric articles. Once extruded through the die, the prepolymer composition is then contacted with an energy source which causes the prepolymer composition to irreversibly undergo a chemical transformation to form a thermoset polymer. The cured polymeric articles can then be collected onto a surface and used as desired. The energy source used to activate the prepolymer composition can be, for instance, a heated gas stream, ultra sonic sound waves, or a radiation source.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: April 9, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventor: Michael T. Morman
  • Patent number: 6207758
    Abstract: Compositions containing fluorinated thermoplastic elastomers with different moelcular weight and with different plastomeric phase/elastomeric phase ratio, essentially formed by: (a) 30-80% by weight, preferably 50-80%, of a fluorinated thermoplastic elastomer, having a block structure of A-B-A type, wherein A is a plastomeric segment and B is an elastomeric segment; (b) 10-50% by weight, preferably 20-40% of a fluorinated thermoplastic elastomer having a block structure of A-B-A type; (c) 0-30% by weight, preferably 0-15%, of a fluorinated plastomer preferably of the same kind as that contained in the component (a) and/or (b).
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: March 27, 2001
    Assignee: Ausimont S.p.A.
    Inventors: Giulio Brinati, Vincenzo Arcella
  • Patent number: 6165440
    Abstract: The present invention discloses a method/system utilizing interaction of electromagnetic pulses or ultrasonic radiation with nano- and microparticles for enhancement of drug delivery in solid tumors. The particles can be attached to antibodies directed against antigens in tumor vasculature and selectively delivered to tumor blood vessel walls. Cavitation induced by ultrasonic waves or local heating of the particles by pulsed electromagnetic radiation results in perforation of tumor blood vessels, microconvection in the interstitium, and perforation of cancer cell membrane, and therefore, provides enhanced delivery of macromolecular therapeutic agents from blood into cancer cells with minimal thermal and mechanical damage to normal tissues.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: December 26, 2000
    Assignee: Board of Regents, The University of Texas System
    Inventor: Rinat O. Esenaliev
  • Patent number: 6103178
    Abstract: The present invention relates to a method for the formation of amorphous boron silicon oxycarbide fibers and crystalline boron-doped silicon carbide fibers wherein the method comprises preparing a blend of a siloxane resin and a carborane-siloxane oligomer, forming the blend into green fibers, and then curing and pyrolyzing the fibers.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: August 15, 2000
    Assignee: Dow Corning Corporation
    Inventors: Duane Ray Bujalski, Kai Su
  • Patent number: 5976449
    Abstract: A method and an apparatus for measuring an electric insulated conductor, in particular a medium-voltage and/or high-voltage insulated conductor, are proposed. Seen in profile cross-section, the insulated conductor (50) includes a copper conductor, an inner semiconductor, an insulation and an outer semiconductor and is produced in an extrusion device (90) having an appropriately assigned crosslinking section (40). To achieve an even distribution of the two semiconductor layers and of the insulation layer, the insulated conductor (50) is radiated through immediately at the outlet from the crosslinking section (40) and a correction of the die setting in the extrusion device is carried out by means of values thus determined.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: November 2, 1999
    Assignee: Zumbach Electronic AG
    Inventors: Hannes Salzmann, Ulrich Jung, Wilfried Kotter
  • Patent number: 5958324
    Abstract: The present invention relates to a method for the formation of amorphous boron silicon oxycarbide fibers and crystalline boron-doped silicon carbide fibers comprising: preparing a blend of a siloxane resin and a boron-containing polymer, forming the blend into green fibers, and then curing and pyrolyzing the fibers.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: September 28, 1999
    Assignee: Dow Corning Corporation
    Inventors: Duane Ray Bujalski, Kai Su
  • Patent number: 5840242
    Abstract: The present invention relates to a method for preparing a ceramic fiber from alkenyl or alkynyl functional resins and to the ceramic fibers produced therefrom. The method comprises (A) forming a fiber from a siloxane resin comprised of R.sup.1.sub.a R.sup.2.sub.b RSiO.sub.(3-a-b)/2 units wherein R is an unsaturated carbon group; each R.sup.1 is selected from the group consisting essentially of an aryl group having from 6 to 10 carbon atoms and functional derivatives thereof; each R.sup.2 is selected from the group consisting essentially of an alkyl group having from 1 to 4 carbon atoms and functional derivatives thereof; a has a value of 0, 1 or 2; b has a value of 0, 1, or 2 with the proviso that a+b <2; (B) curing the fiber by exposing the fiber to high energy radiation to render it non-fusible; and (C) heating the non-fusible fiber in an inert environment to a temperature above about 800.degree. C. to convert it to a ceramic fiber.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: November 24, 1998
    Assignee: Dow Corning Corporation
    Inventors: William Henry Atwell, Duane Ray Bujalski, Jonathan Lipowitz, Kai Su, Gregg Alan Zank
  • Patent number: 5795531
    Abstract: A method and an apparatus for an exact measurement of the thickness of a plurality of individual semi-conductor and insulation layers and the determination of the centricity/eccentricity of a medium-voltage and/or high-voltage insulated conductor. The individual semi-conductor and insulation layers of the insulated conductor emerging from an extrusion device are penetrated with X-rays in at least two directions laying within a plane orthogonal to the axis of the insulated conductor. On carrying out a line-scan intensity detection of the X-rays having penetrated the insulated conductor, the thickness of the individual layers as well as the position of the conductor is computed. These values are compared with target ones, and, if necessary, the position of the extruder heads can be corrected accordingly.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: August 18, 1998
    Assignee: Zumbach Electronic AG
    Inventors: Hannes Salzmann, Ulrich Jung, Wilfried Kotter
  • Patent number: 5641450
    Abstract: A hollow polysulfonic fiber intended for a selectively transmissive membrane contains a hydrophilic polymer which is cross-linked into a water-insoluble form (for example polyvinylpyrrolidone) and is used in the form of a hydrogel containing water. A method for the production of a membrane module consists in spinning a hollow fiber by the use of a spinning solution containing a polysulfonic resin and a hydrophilic polymer, wetting the fiber above the saturated moisture content, and then, with the wet condition maintained, subjecting the fiber to the processes of module molding and radiation induced cross-linking, these processes being performed in either order. The method provides a selectively transmissive hollow polysulfone fiber membrane which displays less elution into water and a sharp molecular weight fractionation, so as to be usable safely in the fields of medicine and foodstuffs.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: June 24, 1997
    Assignee: Toray Industries, Inc.
    Inventors: Takuichi Kobayashi, Kazumi Tanaka
  • Patent number: 5605660
    Abstract: A process for the manufacture of a multilayer, cross-linked, heat shrinkable, polyolefin film, the film having at least one inner layer including a thermoplastic polymer sandwiched between two outer layers including a thermoplastic polymer different from the thermoplastic polymer of the inner layer, including the steps of coextruding the polymers into a tape; cross-linking the tape; and converting the cross-linked tape into a heat shrinkable film by orientation; wherein scrap material produced in the manufacture of the heat shrinkable film is incorporated by recycling the film into the coextrusion step in an amount up to 50% by weight of the total film weight.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: February 25, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Livio Buongiorno, Paolo Ciocca
  • Patent number: 5601762
    Abstract: The invention relates to strings for stringed musical instruments, fishing equipment, and sports racquets which are exposed to a suitable solvent or suitable elasticizer compatible with the materials contained in the fibers, bonding resins, or coating resins in the strings, such that partial dissolution of the material in the suitable solvent occurs or absorption of the suitable elasticizer occurs so as to increase the elasticity, increase the flexibility, increase the ductility, or increase the resiliency of the strings.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: February 11, 1997
    Assignee: Ferrari Importing Company
    Inventors: Harry M. Ferrari, Ronald H. Carr
  • Patent number: 5540876
    Abstract: Materials and items made of thermoplastic polyesters, such as poly (epsilon-caprolactone), synthetic rubber, such as Transpolyisoprene and Neoprene, and natural rubber, such as balata have improved properties when subjected to gamma radiation in the range from 0.5 to 30 megarads.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 30, 1996
    Inventors: Peter M. Larson, Lester M. Larson
  • Patent number: 5518681
    Abstract: A method and an apparatus for measuring an electric insulated conductor, in particular a medium-voltage and/or high-voltage insulated conductor, are proposed. Seen in profile cross-section, the insulated conductor (50) comprises a copper conductor, an inner semiconductor, an insulation and an outer semiconductor and is produced in an extrusion device (90) having an appropriately assigned crosslinking section (40). To achieve an even distribution of the two semiconductor layers and of the insulation layer, the insulated conductor (50) is radiated through immediately at the outlet from the crosslinking section (40) and a correction of the die setting in the extrusion device is carried out using the values thus determined.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: May 21, 1996
    Assignee: Zumbach Electronics AG
    Inventors: Hannes Salzmann, Ulrich Jung, Wilfried Kotter
  • Patent number: 5500163
    Abstract: A thermoplastic material, mainly to be used for splints and supports in orthopaedical, surgical and veterinary practice, is proposed for the fixation of body parts, the material including a copolymer of .epsilon.-caprolactone, polyurethane, and ethylene-butylene-styrene mixed with triallylcyanurate and oleic acid-imide, the copolymer mixture being gamma irradiated after processing, such that a degree of cross-linking of the molecules and a partially crystalline configuration results in a molded material with reproducible flexibility, elasticity and reciprocal stretch properties.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: March 19, 1996
    Inventor: Tom P. M. G. Ponnet